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By A. J. Makoka, B. C. Qi

Reliable monitoring of corrosion is vitally important in the combat against corrosion and over the last two decades the interpretation of electrochemical noise has received considerable attention as a means to discriminate between different types of corrosion. To this end, many different analytical methods have been proposed, such as power spectral density analysis and analysis via various other stochastic criteria. However, although many corrosion systems are nonlinear and therefore not readily interpretable by the abovementioned analytical approaches, few studies in the analysis of electrochemical noise to date have exploited advances made in the analysis of nonlinear systems. In this paper, the use of phase space methods to analyze and detect change in corrosion systems via electrochemical noise is considered. In particular, the electrochemical noise data are used to reconstruct trajectories in the so-called phase space of the system and changes in the topology of these trajectories or attractors as represented by correlation dimension curves are consequently interpreted as an indication of change in the dynamics of the system.

Jan 1, 2005

By T. E. Wakefield

"Final Galloway (stage) designs for vertical drill and blast shaft sinking projects evolve from complex thought patterns which integrate operational processes, systems and methods of communication, power supply, drilling, blasting, ventilating, mucking, supporting, surveying, dewatering, sealing, concrete lining and shaft furnishing. Attention to ergonomic design detail at the shaftsman / structure interface is at the heart of safe and successful multi-deck working platforms. For economy the end product must have a low mass to reduce suspension rope end loads to be able to use smaller suspension hoists and have lighter headframe structures, be robust to withstand concussion damage, be easily constructible on site, be maintainable in the shaft barrel, and comply with safety and legislated standards. This paper’s ambition is to describe a systematic design framework and sequenced thought process that delivers a product that is engineered with excellence, illustrated by making use of two designs that evolved during recent Galloway projects, one destined for a large diameter man/material shaft, the other for a ventilation shaft. The stage engineering iterative process starts with mapping permanent and sinking hoisting layouts, followed by laying out horizontal deck plans, mostly constrained by the permanent shaft purpose and configuration, whilst maximizing openings to enable muck to be removed rapidly for the best sinking cycles. Concurrently the designer needs to understand the chosen sinking methodologies in conjunction with crewing to determine the number of decks and fix their spacing. Insufficient access to move and line up formwork, set reinforcing rods and pour concrete in the confined spaces of the stage is an inherent major risk to be mitigated. An iterative and integrative process follows for the primary configuration which delves into increasing design detail, accommodating all other methodology influences, resulting in 3D layouts for further risk assessment, review and fine tuning by seasoned shaftsmen. INTRODUCTION Documented colliery shaft sinking practice from the late 1800’s makes reference to purpose built walling (bricked lining) cribs with floors suspended in sinking shafts, thereby allowing shaft lining to proceed concurrently with the excavation. Improvements were made by Sir William Galloway who introduced two decks supported at the corners by angle irons. The sinking stage, or Galloway, has developed substantially over time to be the in-barrel heart of the sinking operation, with overwhelming complexity for those who have to design one for the first time."

Jan 1, 2019

By Fazel G. Jahromi, Ahmad Ghahreman

"Several studies were performed on the atmospheric leaching of copper sulfide minerals in the presence of activated carbon and a new catalyst, AF 5. AF 5 is a carbon based catalyst with similar properties to those of activated carbon however much better mechanical properties. The activated carbon surface chemistry has been investigated in various studies; however the connection of the surface chemistry of activated carbon and AF 5 with the sulfide minerals during the atmospheric leaching process is not well-understood yet. Based on the surface analysis, AF 5 showed higher surface area than activated carbon (AC). Adsorption and oxidation of copper, arsenic and iron ions in the presence of different activated carbon were investigated. Adsorption properties of both catalysts were similar and 18-24% of iron, 12-18% of copper and 10% of arsenic adsorbed on the catalysts surface form 5 g/L Fe(III) and Cu(II) and 2 g/L As(III) at 80°C. In oxidation experiments, both catalysts reduced Fe(III) and Cu(II) ions and re-oxidized the reduced species in the presence of oxygen and oxidized As(III) ions. The addition of oxidizing ions can enhance the oxidation process kinetics and increase the catalytic capability of carbon.INTRODUCTION Hydrometallurgical processes of copper sulfide concentrates are under development and various different methods have been proposed to increase the atmospheric leaching rate of copper sulfide minerals. These methods include using different media, reagents, and catalysts. Among different methods, leaching of the copper sulfide minerals in the chloride media has some advantages over sulfate media. Smaller scale of operation, increased leaching rates, and lower sulfate formation are some of the benefits of the chloride leaching media over other similar media. Moreover, using ferric and cupric ions as oxidants and utilizing activated carbon as a catalyst has been proven to enhance the leaching rate of copper sulfide minerals effectively. Activated carbon (AC) and AF 5 (micro porous carbon based catalyst) are two of the most efficient and practical catalysts in copper sulfide leaching processes. AC can enhance the copper recovery of enargite in chloride media from 69% to 92% after 96 hours of leaching under the similar conditions (Jahromi & Ghahreman, 2016). It has been shown that AC at acidic pH can generate hydrogen peroxide in the presence of oxygen which can leach copper minerals (Ahmumada et al., 2002)."

Jan 1, 2017

By K. Östcrdahl

We are developing a cost-saving and environmentally friendly process with low energy consumption to recover the metal content and recycle the acid from spent pickle baths. The metals are precipitated as metal fluorides, which can be turned into metal oxides and hydrofluoric acid by thermal hydrolysis. In the proposed process the solution is concentrated by nanofiltration and the metals are precipitated in a subsequent crystallization step. Different nanofiltration membranes have been evaluated in experimental batch tests. The membrane MPF-34 from Koch Membrane Systems offered both good flux and acceptable metal retention even after long periods of acid storage. The solubility of B-FeF3.3H20 has been measured at varying acid concentrations and at different temperatures. The solubility decreases with increasing hydrofluoric acid and nitric acid concentrations. This suggests that the crystallization process should be operated at high acid concentrations. The crystal growth rate of B-FeF3.3H2O is found to be quite low but increases significantly with temperature. This suggests that the crystallization process should be operated at higher temperatures (40 - 60°C). Within the project a pilot plant has been constructed where the spent pickle bath solution is concentrated by nanofiltration to the desired metal fluoride supersaturation, and B-FeF3.3H2O is crystallized in a 10 L continuous crystallizer.

Jan 1, 2006

By Hiwa Salimi, Foley. Stephen R, Loghman Moradi

Common water-miscible organic solvents including DMSO, DMF, methanol, ethanol, acetone and THF in combination with HCl and low concentrations of H2O2 were investigated for dissolution of gold. THF showed the best result demonstrating that gold powder could be completely dissolved in 1.5 hours in 1.0 mol/L HCl and 0.2 mol/L H2O2. No complete gold dissolution was observed for the rest of solvents even after 24 hours. The rate of gold dissolution was measured by dissolving gold wire in THF/HCl/H2O2 mixture. The rate of gold dissolution in optimised condition was 75 g m-2 h-1 at room temperature and significantly increased to 590 g m-2 h-1 by raising the temperature up to 60 oC. Although a THF/HCl/H2O2 mixture showed a slower dissolution rate in comparison with aqua regia, however the applied conditions are considerably milder which is highly promising for gold leaching in an industrial scale.

Jan 1, 2015

By Robert Strachanm

The East Kootenay coal-field, situated close to the boundary between the provinces of Alberta and British Columbia, is composed of four small areas locally called the Crow's Nest Pass, the Upper Elk, the Flathead and Crown Mountain, and comprises an area of about 3 78 square miles. From eleven to twenty-five seams have been exposed of two feet and over in thickness, with a total thickness of about 200 feet of coal, and reckoning about one hundred feet to be workable, gives an estimate of coal available of about thirty-seven billion tons. The coal is a high-grade bituminous, occasionally tending towards anthracite, and the majority of the seams furnish a. very good quality of coking coal as well as an excellent steam coal. The coal-field is found in the mountain ranges in long narrow strips. The age of the fonnation and the thickness of the covering beds have had considerable influence on the character of the coal, and lateral pressure and disturbances in the process of mountain-building have wrought great changes. With such an abundance of coal, it has been a disappointment that the East Kootenay field has not figured larger industrially. So far only one portion of the coal-field has been utilized. This is the Crow's Nest, where, in 1898, the Crow's Nest Pass Coal Company commenced development. Access to the coal seams was easily obtained, the mountain creeks having eroded away the covering, and mines were driven into the coal seams. In that year about ten thousand tons of coal were produced from the mine at Coal Creek.

Jan 1, 1924

By Gyeonghye Moon, Inhyeok Choi, Jyothi Rajesh Kumar, Jin-Young Lee

"This paper deals with the recovery of the tungsten and vanadium from spent SCR catalyst leach liquors by different hydrometallurgical methods. The first part consists of pressure leaching of spent SCR catalyst using caustic soda followed by metal recovery by liquid-liquid extraction. In a leaching process, the following experimental parameters were tested and optimized: NaOH, particle size of feedstock, temperature, and solid to liquid ratio. The optimum condition for leaching of tungsten and vanadium was under the following conditions: NaOH 3 mol/L, temperature 250°C, particle size <300 µm, and solid to liquid ratio 0.4. From these optimum conditions in this experiment, the dissolution efficiency of vanadium and tungsten was 91.5and 87%, respectively. Liquid-liquid extraction following commercial extractants were tested: TBP, Cyanex 272, D2EHPA, Aliquat 336, Primeme JM-T, Alamine 308, Alamine 304-1, and methyl-tri-octyl-ammonium chloride. The conditions for both valuable metal recoveries were optimized.INTRODUCTIONSelective Catalytic Reduction (SCR) catalyst has become the most effective to reduce nitrogen oxide (NOx) emissions from stationary segments such as power plants and waste incinerations around the world due to the reinforcing regulatory trend and emerging environmental issues (Forzatti, 2001; Spivey, 2002; Li et al., 2011).Currently, the most widely used SCR catalyst is V2O5-WO3/TiO2 system due to its great catalytic properties (Li et al., 2011; Marshneva et al., 1995; Marbergeret al., 2015). In general, the composition of the SCR catalyst used in the stationary application is 0.5 to 1 wt% of V2O5and 7 to 10 wt% of WO3(Marberger et al., 2015; Chen &Yang, 1992, Vuurman et al., 1991; Alemany et al., 1991). Currently spent SCR catalysts are treated as waste and disposed of in landfills. This causes a lot of waste of secondary resources of vanadium and tungsten. In terms of industrial value of vanadium and tungsten (Gupta &Mukherjee, 1990; Moskalyk &Alfantazi, 2003) and reduction of pollutant emissions, it should not be disregarded for their recovery for their material recycling from spent SCR catalyst. However, investigations for recovery of metal values from spent SCR catalyst has been rarely carried out."

Jan 1, 2017

By Chantale Doucet

L?utilisation du remblai en pâte dans les exploitations en vrac est de plus en plus importante. Puisque la technologie existe pour fabriquer du remblai en pâte sans construire une usine coûteuse, il est maintenant possible d?élargir le domaine d?utilisation du remblai en pâte pour y inclure des gisements filoniens où le besoin annuel de remblai est moindre. Dans certains cas, l?utilisation du remblai en pâte pourrait permettre de réaliser d?importantes économies telles que la réduction de la dilution, la stabilité des ouvertures, la récupération d?une plus grande partie du minerai par la réduction de la taille des piliers et l?entreposage de moins de résidus à la surface. L?ampleur des économies est parfois difficile à chiffrer mais il est tout de même important d?en tenir compte lors de la décision d?utiliser du remblai en pâte puisque ce sont souvent ces économies qui seront déterminantes. Différentes méthodes d?extraction avec remblai en pâte appliquées aux mines filoniennes seront présentées. Des défis et les solutions reliés à l?utilisation du remblai en pâte à la Mine Doyon seront discutés.

Oct 1, 2001

By M. W. Grabinsky, B. D. Thompson

ABSTRACT: Use of cemented paste backfill (CPB) offers economic and environmental advantages over other backfill methods. However, many operations have limited knowledge of how their CPB behaves in situ. Therefore, to avoid over-pressuring containment barricades, backfilling strategies necessarily tend to be conservative. In situ monitoring at Barrick Gold Corporation’s Williams Mine and Inmet Mining Corporation’s Cayeli Mine has been conducted and factors controlling barricade pressures are demonstrated, including rise rates, binder content, stope geometry, and tailings properties. The application of barricade pressure monitoring on a stope-by-stope basis can increase backfilling efficiency and, thus, reduce stope cycle times, while maintaining optimal safety.

Jan 1, 2011

By J. S. Stachulak

"The main ventilation design features adopted at Inco to safeguard personnel against the effects of fires are described in this paper. Measures taken to prevent and detect fires due to spontaneous combustion, and fires involving conveyor belts, are described in detail.IntroductionConsidering the over-all picture of present-day mining operations, the expenditure required to provide a proper system of mine ventilation and fife control should be regarded as a sound investment that will pay back in increased mining efficiency, improved safety, health, and morale of the miners.Mine ventilation control and mine fife detection and fighting are inseparable, because a ventilation system can spread deadly products of combustion just as efficiently as it does life-sustaining oxygen. Therefore, the possibility of a mine fife occurring is of particular concern.The first objective is to prevent a fife.The second objective is to design the ventilation system so that a positive fresh air supply can be ensured on each main level regardless of the location of the fife.The third objective is to be able to detect the fife at an early stage and to extinguish it before it can develop into a major fife. Accordingly, at Inco, very extensive measures are taken to prevent fires and to locate, isolate and extinguish them rapidly. To obtain an early warning, it is not sufficient to know that a fife has started, but it is also necessary to know where the fife is burning."

Jan 1, 1994

By J. S. Stacbulak

"The main ventilation design features adopted at Inco to safeguard personnel against the effects of fires are described in this paper. Measures taken to prevent and detect fires due to spontaneous combustion, and fires involving conveyor belts, are described in detail.IntroductionConsidering the over-all picture of present-day mining operations, the expenditure required to provide a proper system of mine ventilation and fife control should be regarded as a sound investment that will pay back in increased mining efficiency, improved safety, health, and morale of the miners.Mine ventilation control and mine fife detection and fighting are inseparable, because a ventilation system can spread deadly products of combustion just as efficiently as it does life-sustaining oxygen. Therefore, the possibility of a mine fife occurring is of particular concern.The flirt objective is to prevent a fife. The second objective is to design the ventilation system so that a positive fresh air supply can be ensured on each main level regardless of the location of the fife. The third objective is to be able to detect the fife at an early stage and to extinguish it before it can develop into a major fife.Accordingly, at Inco, very extensive measures are taken to prevent fires and to locate, isolate and extinguish them rapidly. To obtain an early warning, it is not sufficient to know that a fife has started, but it is also necessary to know where the fife is burning."

Jan 1, 1994

By M. Silver, R. H. McCorkell

The effects of covering materials on radon emanations from uranium mine mill tailings were investigated. Granular materials with air in the spaces allow radon to pass freely. Moist covers of compost or soil decrease radon emanation from tailings. Water-saturated covers were more effective, and freezing the tailings with these covers further decreased radon escape. Water itself is a poor radon barrier probably due to circulation. Plants had no effect on radon emanation through soil. Although radon diffusion through water-saturated powders appears to be very slow and inefficient, about 25% of the radon escaping from the grains in water-saturated tailings diffuse to the surface and emanate when no cover is present. The radon escaping from tailings through covers of water-saturated compost or soil is no more than could be accounted for by radon produced in the covers themselves.

Jan 1, 1987

By Jamie W. Pardy

The objective of the Canadian International Development Agency program is to facilitate the efforts of the people of developing countries to achieve self-sustainable economic and social development in accordance with their needs and environment. The British Columbia Ministry of Energy and Mines (BCMEM) is the executing agency for the four-year Peru Minerals and Metals Public Sector Assistance Project which began in December 1998. The primary beneficiary is the Ministerio de Energía y Minas del Peru (PMEM). The project is designed to address mine health & safety, environmental management and mineral resource information. Project activities currently underway include joint development of: an inspection system, a mine rescue system, an enhanced and e-Commerce capable mineral information website, environmental guidelines for industry and standardized ministry evaluation criteria for environmental impact assessments and closure plans. In addition, reports on management options for mineral concentrate transportation, storage and handling, and on mine reclamation security policy have been delivered at workshops.

May 1, 2001

By A. A. Goss

We investigate the relationship between corporate financial performance (CFP) and environmental and social performance (CSP) in a sample (n=165) of large, publicly traded U.S. mining and oil and gas firms. Using optimally scaled principal components analysis to generate aggregate measures of CSP strengths and concerns, we find higher concerns are related to higher volatility of unexpected earnings and discount rates. Furthermore, these earnings shocks are more likely to be negative as concerns increase. Decomposing this relationship shows that negative environmental performance dominates proactive environmental management as a driver of unexpected earnings, but proactive community efforts increase the magnitude of earnings shocks. We document some evidence of the strategic use of CSR, with those firms that have greater risk investing more proactively in CSR.

Aug 1, 2013

By C. Stamberg, W. McGuire, R. C. Carlson, L. W. Vollmer

"The selection of materials and pre-cautionary measures for handling natural gas and condensate containing aqueous hydrogen sulphide are presented. Based on the results of a pilot production test and laboratory studies, together with several years . of operating experience, it was found that the behaviour of materials in sour gas environments can be predicted sufficiently accurately for engineering purposes.The selection of proper materials is essential for preventing sulphide-stress cracking. Where high strength materials are not required, low car-bon steel is used. Components requiring high tensile strength and hardness characteristics should be made from K-monel or properly heat-treated carbon-manganese-molybden-um and AISI 4140 steels. Welded connections are a potential source of sulphide-stress cracking. Consequently high quality welding and strict inspection are suggested as the most economical precautionary measures available.A maintenance program based,. where possible, on visual inspection of equipment and/or test spools located at strategic points should be used to follow weight loss and putting corrosion in sour gas environments. If severe weight loss or pitting corrosion is encountered, inhibitors have been found to be an effective deter-rent."

Jan 1, 1960

By W. A. Green

To those who may not be familiar with the history and organization of the Flin Flon mining property from the rime of its examination and option by the Harry Payne Whitney interests until the present start of operations by the Hudson Bay Mining and Smelting Company, Limited, this paper may give a better understanding of the property. More technical discussions are being presented to you by the men most closely connected with the various operations of the property. Location The Flin Flon mine is situated along the boundary line between the Provinces of Manitoba and Saskatchewan at approximately. 54° 45? north latitude, but largely in Manitoba. Prior to the advent of the railway, the property was quite isolated. The summer route was over a course of some 175 miles, consisting of a 125-mile boat trip from The Pas, first up the Saskatchewan river, then across Cumberland and Sturgeon lakes to Sturgeon? Landing. From Sturgeon Landing, a .16-mile portage was necessary to Camp 2 on lake Athapapaskow. From Camp 2 the route consisted of a canoe trip of 32 miles across lake Athapapaskow, up the northwest arm of Schist lake, then up Ross creek to the Company&apos;s docks, and finally a 2-mile walk to the property. The winter route was just under 100 miles in length, the difference being due to the fact that a more direct route could be followed over the frozen lakes. It went up the Saskatchewan river for a short distance above The Pas and then, leaving the river, the road followed Reeder, Rocky, and Sturgeon lakes to Sturgeon Landing, and from there over the same route as the summer one, only across the frozen lakes.

Jan 1, 1930

By J. H. Starkey

Large differences between macro and micro grindability relationships have been discovered for mill design measurements using the patented SAGDesign(TM) test. Crushing, Rod and Ball Mill Wi tests, and breakage parameter measurements have previously been used to design SAG mills but have not revealed the true magnitude of these differences. A SAGDesign(TM) test measures the SAG/Bond Wi Ratio (defined below) for every sample tested and gives a good design result because the F80 of the SAG stage test feed is 19 mm and because the test includes a Bond Ball Mill Work Index on SAG ground ore. Good flotation operation demands properly sized grinding mills and steady feed to the flotation circuit.

Jan 1, 2009

By E. Godfrey

The average man one meets on the street thinks of an explosive as a medium of death and destruction, something unstable which should be given a wide berth, because he knows little or nothing about its use or its stability. Briefly, explosives are compounds that develop very large quantities of heat and gas in an extremely short time and in a small space, thereby exerting enormous pressure upon surrounding bodies, and by the rapid expansion of this highly heated gas are able to perform a considerable amount of useful work. The amount of heat generated and the volume of gas produced by the decomposition of an explosive determines the amount of mechanical work it can do, and the time occupied by its change from solid or liquid condition to gaseous condition determines its shattering effect. Explosives manufactured by reputable people are not extremely dangerous, on the other hand they are quite safe if handled in a proper manner. Furthermore, before an explosive can be placed on the Canadian market a sample must be submitted to the Explosives Division of the Mines Department, who may condemn or permit its manufacture, according to their findings regarding its safety in handling and its stability during storage.

Jan 1, 1926

By P. Karimi, G. Mollataheri, A. Amini, H. Abdollahi, A. Mirzaeian

"Chah-Palang tungsten deposit is one of the two tungsten indexes in Iran. Based on ore characterization techniques (including optical mineralogy and XRD analysis), quartz, chlorite, atacamite, azurite, malachite, ferberite, illite, goethite and calcite were distinguished as major minerals. The representative sample was analyzed qualitatively by using X-ray fluorescence and chemical assay. Results showed that grade of tungsten oxide and copper were 1.76 and 7%, respectively. Also precious metals such as gold with grade of 1 ppm was reported in the sample. By using the mineralogical studies on the prepared sample, the liberation degree of tungsten minerals in –0.6 mm size fraction was obtained 80%. Several tabling tests were carried out on the original sample which at the optimum conditions and as a result, the grade and recovery of tungsten in concentrate reached to proximately 23 and 59%, respectively. To increase the grade of tungsten in the final concentrate, acidic leaching were performed on the tabling concentrate and its appropriate results indicated that the grade of tungsten increased to 27%. Also more than 90% of copper was extracted as a byproduct in the fallowed process.INTRODUCTIONTungsten, a unique hard, heavy heat-resistant metal, is distributed erratically in economic concentrations throughout most continents, occurring mostly as small irregular deposits that are not readily adaptable to large-scale, low-cost mining methods. The diverse physical characteristics and mineral composition of tungsten ores also present problems in beneficiation, requiring complex hydro- and pyrometallurgical treatment to yield high-purity concentrates suitable for the production of ferro alloys, carbides and super alloys in the steel industry (Hausen, 1989; Kholmogorov & Kononova, 2005). Tungsten is most frequently used as tungsten monocarbide, which has hardness close to diamond, in cemented carbides. The most well-known use of tungsten is in lighting filaments, and other important applications include improving steel properties and use in tungsten alloys, electronics, and chemical products (Hausen, 1989; Kholmogorov & Kononova, 2005)."

Jan 1, 2016

Energy benchmarking is widely applied across industries to determine the potential to improve energy performance. Unlike the many technologies for which energy benchmarks and efficiency rating systems are already in maturity, benchmarking of mining processes is still in its infancy. Benchmarking energy usage in mining operations, where energy costs are high and represent a significant portion of overall operating expenses, is challenging due to the uniqueness of each mining operation. Mines vary in terms of geology, geographic setting, ore body geometry, mineralogy which impact the mining method, material handling, processing and waste management. In order to gauge the opportunity for reducing the energy intensity of individual operations and also to compare the energy performance of operations on a global scale, the deployment of new benchmarking methodologies, models and frameworks is necessary. As a step towards the establishment of an accurate framework for benchmarking the energy consumption of mining operations, comminution, one of the more energy intensive mining sub-processes, was selected as the focus of a new energy benchmarking method. The methodologies and processes used to onset fragmentation in a rock mass to the crushing or grinding of rock to a size that is suitable for economic extraction are predominantly dependent on the ore properties. For this reason, site specific factors, such as the size reduction requirements and ore hardness were included in an energy benchmark model so that the energy performance of comminution processes at different operations could be normalized and compared on a global scale. Single particle compression breakage has been identified by several prominent researchers in the field of comminution as the upper limit of energy utilization in size reduction processes. For this reason single particle compression breakage was proposed as the basis of a work index for ores to be used as an input for the benchmark model. Overall, the new method showed that the energy benchmark for mineral comminution can be normalized and subsequently compared for a range of mining operations once the ore hardness has been appropriately characterized.

Aug 1, 2013