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By Aiyuan Ma, Kun Yang, Weiheng Chen, Jinhui Peng, Shiwei Li, Feng Xie, Libo Zhang

In this thesis, a new process of recovering zinc sulfide ores was developed. The novel synthetic coordination leaching process mainly included two steps: microwave assisted phase reconstruction and compound coordination leaching. By applying various techniques, such as chemical composition analysis, X-ray diffractometry (XRD) and Raman spectroscopy, it could be concluded that sulfide phases would directly oxidized to zinc oxides under the 500 ºC microwave roasting and adding 30% Na2O2. What’s more, zinc leaching rate reached to 61.16% within 2 hours. Compared to the current technologies, this procedure had the advantage of avoiding SO2 emission, high leaching efficiency, simple process, manipulate easily, and low cost, which could be expected tremendous application potentials.

Jan 1, 2016

By Z. Q. Chen, M. H. Loretto, Y. G. Li

"As-cast, As-forged, as-solution-treated, and solution treated and aged microstructures of Ti-15Mo (IMI205) with and without carbon were examined using optical microscopy, scanning electron microscopy .and transmission electron microscopy. Tensile testing was carried out at room temperature. It was found that carbon acts primarily as a titanium carbide former: Titanium carbides increase slightly the tensile strength, but decrease the ductility of IMI205. These observations are interpreted in terms of the titanium carbide morphology observed using SEM and TEM and the phase diagrams of Ti-Mo, Ti-C, and Mo-C.IntroductionIn a recent study on the development of a burn-resistant 13-Ti alloy, carbon was introduced· into the Ti-V-Cr system in order to optimise the mechanical properties. Research results[1, 2] demonstrate that carbon addition can refine the 13 grain size and improve the stability of the 13 phase in Ti-V-Cr alloys. The most attractive result is that carbon addition produced a marked improvement in the ductility of alloys when the carbon content is over 0.1 wt.% in this alloy system. Even after long exposure, the alloy with carbon addition maintains good ductility. One of the main reasons for the ductilising of the alloy is that titanium carbides can getter the oxygen from the 13 matrix.In view of the success of carbon addition in improving the properties and the stability of the Ti-V-Cr alloy, it is of interest to investigate the behaviour of carbon addition in other beta Ti-base alloys. The objective of the present work was, therefore, to assess the microstructures and mechanical properties of IMI 205, a metastable beta titanium alloy, with and without carbon addition using optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), wavelength dispersive X-ray (WDX) analysis, room temperature tensile testing."

Jan 1, 2000

By Shaohua Ju, Feng Jiang, Chuanhua Li, Jinhui Peng, Libo Zhang

A T-junction microchannel is proposed to overcome the existing problems in conventional solvent extraction of indium from zinc hydrometallurgical process. Experiments were performed to separate In3+, Fe3+ and Zn2+ from sulfate solutions using Di-(2-ethylhexyl)phosphoric acid (D2EHPA) as the extractant. The effect of parameters such as pH, microchannel size and contact time on the extraction behavior of In3+, Fe3+ and Zn2+ was investigated. At contact time of 2.52 s and initial solution pH of 0.48, the extraction efficiency of In3+, Fe3+ and Zn2+ was 99.13%, 8.31% and 2.45%, respectively and separation factor of In3+/Fe3+ and In3+/Zn2+ were almost 1229.54 and 4864.98, respectively. Then, the loaded organic phase was stripped in T-junction microchannel. At contact time of 33.6 s, 99.64% of stripping efficiency of In3+ and stripping equilibrium were reached, while concentration of Fe3+ and Zn2+ was lower than 0.01 g/L with good separation of In3+ from Fe3+ and Zn2+.

Jan 1, 2016

By Yuanbo Zhang, Zhixiong You, Zijian Su, Bingbing Liu, Guanghui Li, Guang Yang, Tao Jiang

Sodium stannate is widely used in the electroplating and tin alloy industry. But the traditional processes for sodium stannate production are characterized by long flowsheet, high production cost and strict requirement for the equipments, etc. In this study, a novel process for sodium stannate preparation from cassiterite concentrate and sodium carbonate via roasting in CO/CO2 mixed gas then followed by leaching was developed. The effects of roasting parameters on the Sn leaching efficiency were conducted. A Sn leaching efficiency of 77.2% was obtained under the optimal conditions. Sodium stannate (Na2SnO3·3H2O) with a purity of 95.8% was produced by the new process, which is better than that specified for the industrial first-grade product.

Jan 1, 2014

By Animesh Jha

The carbothermic reduction of chalcopyrite has been studied in the temperature range 1073 to 1273K in presence of lime. The role of lime during the reduction process is explained and the phase equilibria leading to the metallisation of copper and iron are discussed. The effect of coal and carbon monoxide on the reduction process have been studied and the rate governing steps are identified. This investigation also cites examples of possible mechanisms of physical separation of metallic Cu from iron during the reduction process.

Jan 1, 1992

By Bing Ji Yan, Cui Wang, Ya Peng Zhang, Chuan Hui Li, Hong Wei Guo, Jian Liang Zhang

There are a lot of research of the chlorine element’s influence on blast furnace, and mainly pay close attention to the harm to gas pipes and equipment. There are three kinds of chloride in the blast furnace gas, including HCl, NH4Cl, and NaCl (or KCl, ZnCl, etc.). This paper mainly analyzes all kinds of phenomenon of the chlorine element overflowing blast furnaces in Jinan Steel, and puts forward some different viewpoints, which are that the chloride overflowing out of blast furnace in the types of HCl, NH4Cl, or NaCl (KCl) not only has much to do with raw materials of chlorine load level, at the same time with the blast furnace burden distribution. On this basis, comes up with countermeasures for the different situation, such as adjusting the burden distribution matrix to guarantee the central gas flow smooth and changing the kind of raw materials to reduce the chlorine quantity, which will be helpful to prevent the harmful influence of chlorine element.

Mar 1, 2017

By Yong-ming Chen, Chao-bo Tang, Yun Li, Long-gang Ye, Sheng-hai Yang, Hao-tian Xue

In order to achieve high recovery of Cu and Co during cobalt-bearing copper sulphide ore smelting process, reducing agent (coke) and sulphidizing agent (pyrite) were added into molten smelter slag for reducing-sulphidizing smelting to product Cu-Co matte. Effects of reductive atmosphere, pyrite dosage, smelting temperature and smelting duration on Cu, Co, Fe distribution behaviours were investigated. The results show that the distributions of Cu and Co are mainly enriched in Cu-Co matte, and the distribution ratio, LCu and LCo, improve with increasing of coke amount or pyrite addition, whereas above 6 wt.% coke or 20 wt.% pyrite, Cu and Co tend to transfer from matte to cleaned slag. A properly high temperature(1300) and smelting duration(3h) are beneficial to the enhancement of the distribution ratio of valuable metals, and under the given set of conditions, LCu > LCo generally. However, an undesired high Fe contents in matte limit further increase of LCu and LCo.

Jan 1, 2015

By Yan Wen

For the impurities in the copper smelting waste acid, SO3, Cu, As, Pb, Zn, Re and other elements enter the waste acid and generate a lot of arsenic residue, gypsum and neutralized residue, in which Cu, Zn and Re metals have not been recycled. Cu, Re and As are separated by step-wise vulcanization. The valuable metals of Cu, Zn and Re are recovered by separating zinc through pH adjustment. Calcium injection is conducted for boiler for reducing the amount of SO3. The residues generated in the form of arsenate and hydroxide will be returned together with arsenic filter cake for smelting treatment so as to achieve the purpose of valuable metal recycling and solid waste reduction and harmless treatment.

By D. H. H. Quon

Results of a study conducted to determine the properties of iron ore pellets made from Mount Wright and Carol Lake ore concentrate fines with partial and full substitution of bentonite by several organic binders are presented. Carboxy methyl celluloses 7H and 6TL, hydroxy ethyl cellulose (natrosol) and modified guar gum all produce pellets of acceptable wet, green and dry strength. However, when fully substituted, an inorganic binder such as calcium carbonate is required for satisfactory strength development after induration. Mixing the Carol Lake ore with Mount Wright ore in a 50-50 ratio also achieves the same result. The failure of the Carol Lake ore in the pelletization process is attributed to the low hematite content of the ore. The results are very similar to those from the extrusion studies reported earlier (8).

Jan 1, 1989

By Junwei Han, Wenqing Qin, Dawei Wang, Fen Jiao, Wei Liu

The removal of iron impurity from zinc calcine was studied by magnetization roasting and magnetic separation. The effects of roasting temperature, magnetic intensity, ore grinding, and leaching pretreatment on iron grade and recovery were investigated. The results indicated that iron recovery increased with the increase of roasting temperature or magnetic intensity, while iron grade was always less than 22%, depending on the fact that the magnetite were not liberated completely. The good liberation was difficult to be achieved by ore grinding but was easier by acid leaching, since the magnetite grains were very fine. After the leaching pretreatment, the recovery of 76.31% with iron grade of 53.24% was obtained by one roughing and cleaning. The SEM/EDS analysis showed that a part of sphalerite, zinc ferrite and other gangues were mixed into the iron concentrate, while some of fine magnetite was reported to the tailing.

Jan 1, 2016

By J. D. McCain

Magma's San Manuel smelter has adopted new operating techniques resulting in 21% increased productivity and 87% reduction in lost time accidents. Reverberatory furnaces were converted to coal firing from expensive natural gas and fuel oil. Slag and matte flow problems and safety were improved by implementing hydraulic slag stopping and matte tapping machines. Coordination of furnaces, converters and acid plant was improved by using a computer-aided converter controller/scheduler function. Manual mudding of converter lips after each collar pull was replaced with a gunning system for coating the mouth castings. One converter punch car was automated using robotic technology. An automatic anode take-off was installed with fewer moving parts and a mechanism for ear twisting one cell contact. Anode copper refining was improved by replacing propane/hydrogen mixtures with high pressure/velocity natural gas tuyeres. Improved converter scheduling increased acid plant production 43% with more autothermal operation time. Six dedicated computers/microprocessors are utilized for automation, data acquisition, process monitoring and on-line air quality information for the Supplementary Control System.

Jan 1, 1983

By Bora Derin

This study is a collection of both newly published and/or presented works on impurity capacity predictions in molten melts which were carried out by Derinetal. Some sulfide capacity prediction results of iron oxide containing ternary silicate melts and industrial lead and copper slags using the Reddy-Blander model and some impurity capacity predictions of multicomponent oxide and salt melts obtained using a Artificial Neural Network Approach are discussed.

Mar 1, 2017

By Ajit Kumar Jaiswal

"Electric Arc Furnace (EAF) being a power-intensive equipment, EAF based industries are highly dependent on scarce electric energy. This is the reason Government of India is highly concerned about this and laid emphasis on the conservation of electric energy.This paper highlights factors contributing to reduction in specific electric energy consumption in EAF and suggests measures not only for power saving, but also for productivity improvement. To name a few, these are proper sealing of furnace, introduction of oxy-fuel burners, foamy slag practice, increased usage of hot metal/DRI, post-combustion of CO gas for preheating of scrap, improved selection & design criteria of electrics, power demand management, and process automation. Few cases also have been cited, where the above measures have helped in reaping significant benefits.IntroductionFor a long time, Government of India had focused on increase in energy supply, in particular, through electricity generation. Now the emphasis of Government of India has shifted from electricity generation to its conservation for following two reasons:??Power plants have become very cost-intensive??By saving energy, more of it can be delivered at lower cost to the consumersPower generating units, transmission & distribution agencies as well as consumers all have roles to play in the area of energy conservation. By energy conservation, we mean curtailing energy requirement by reducing energy wastages and taking up measures to improve energy efficiency of electric equipment/appliances. In almost all cases, this would be economically beneficial.India’s cost-effective energy conservation potential has been estimated by the Planning Commission at 23 per cent of total commercial energy generated ?1?. A national movement for energy conservation can significantly reduce the need for fresh investment in energy supply systems in coming years. It is imperative that we make all-out effort to realize this potential. Whether a household or a factory, a small shop or a large commercial building, a farmer or an office worker, every user can and must make this effort for his own benefit and for the nation’s benefit as well."

Jan 1, 2009

By Khalid Hattar, Alexander McGinnis, Buchheitm Thomas, Paul Kotula, Luke Brewer

"Understanding the effects of extensive radiation damage in structural metals provides necessary insight for predicting the performance of those metals considered for application in the extreme radiation environment. Predicting mechanical performance after long term radiation exposure is of great importance to extending the life of current nuclear reactors and for developing future materials for the next generation of reactors. A combination of finite element modeling, nanoindentation, and TEM characterization were used to rapidly determine the microstructure and mechanical properties influences of ion irradiation on a standard 3 l 6L stainless steel sample. The results of this study found that ion irradiation and small scale mechanical property testing can be used to characterize extensive levels of radiation damage structure, only when significant consideration is given to ion irradiation depth, surface roughness and polishing condition, the irradiation temperature, and many other experimental parameters.IntroductionFor either the success of next generation nuclear reactors or the extension of current nuclear reactors significantly beyond their designed lifetimes, research is needed into the degradation of the microstructure and mechanical properties governing the performance of the reactor alloys exposed to extreme environments. Although the exact dose and temperature of these nuclear reactor plans may vary, the cladding and other structural components will be exposed to greater dose and at elevated temperatures. To acco=odate these severe exposures, established cladding materials are being testing to longer exposure and new alloy compositions are being considered. [1-3] For neutron test facilities to reach 100 dpa level, exposure times often span several years, significantly limiting the down-select process of potential new materials for extreme radiation environments. Ion irradiation has been used as a technique to provide a look at the effect of irradiation damage on materials in a significantly shorter time frame. Previous work using proton irradiation provides a deep, broad, and relatively uniform defect profile compared to heavy ion irradiation; however, using this type of radiation still requires weeks to months to reach the 100 dpa level. [4] In this research, we investigated the feasibility of using heavy ion (nickel) irradiation and small scale mechanical testing to provide in a few days a first order screening technique for potential alloys that are being considered for advanced testing."

Jan 1, 2012

By A. J. Meir, Paul G. Schmidt

"We present a novel approach to the mathematical analysis and computational simulation of fully three-dimensional, nonlinear, viscous, incompressible MHD flow in complex configurations involving several liquid and solid conductors. Such configurations arise in numerous metallurgical processes. Employing the current density rather than the magnetic field as the primary electromagnetic variable, it is possible to avoid artificial or highly idealized boundary conditions for electric and magnetic fields and to account exactly for the electromagnetic interaction of the flow region with the surrounding space. In addition, the approach lends itself naturally to finite-element based discretization techniques. As an application, we simulate the stationary flow of an electrically conducting fluid around a solid spherical particle of arbitrary conductivity, in the presence of crossed uniform electric and magnetic fields, and compute the Lorentz, pressure, and viscous forces exerted on the particle. This problem arises in connection with the electromagnetic filtration (purification) of molten metals before the casting stage.IntroductionNumerous metallurgical processes are governed by MHD effects resulting from the macroscopic interaction of liquid metals with applied or induced currents, electric and magnetic fields. Frequently these effects are technologically exploited in order to drive or to control the flow of metallic melts. Typical examples include the electromagnetic stirring of molten metals before the casting stage [1]; electromagnetic turbulence control in induction furnaces [2]; electromagnetic damping of buoyancy-driven flow during solidification [3]; and the electromagnetic shaping of ingots in continuous casting [4]."

Jan 1, 1999

By R. C. Hubli

A chemical model has been developed to investigate the dissolution of sulphide minerals in brine solutions containing copper and iron chlorides. The model has been employed to study the dissolution .of synthetic NiS using different initial concentrations of Cu(II), Cu(I), Fe(III) and temperature. The speciation of copper with particular reference to the formation of hydroxy-chlorides as a function of total chloride and H+ has been computed. The model predictions are in agreement with experimental results. It has been found that addition of Fe(III) results in the maintenance of a high Cu(II)/Cu(I) ratio leading to enhanced rates of dissolution and suppresses the loss of Cu(II) due to the formation of hydroxyl-complexes.

Jan 1, 1997

This report presents overview of the authors' results of thermodynamical investigation of some important metallurgical processes and phenomena. Among them: carbo thermal reduction of silica, and boron oxide, silicon carbide obtaining from different precursors, investigations on copper and manganese ores processing, investigations on pollution from different sources. Special attention is paid-to thermodynamical approach to investigation and estimation of multi component multi element compositions stability, developed by the authors. Also are discussed some auxiliary but' important for the thermodynamical investigations issues.

Jan 1, 1997

By Duclerc Fernandes Parra, Vijaya Kumar Rangari, Washington Luiz Oliani, Danilo Marin Fermino, Ademar Benevolo Lugao, Nilton Lincopan, Luiz Gustavo Hiroki Komatsu

Polyethylene is widely used for packing applications. Different grades of polyethylene, LLDPE and LDPE play a major role in the film blowing industry. The use of nanoclay in polymer matrices (non-polar) requires the use of a compatibilizer agent, ethylene graft maleic anhydride copolymer (PE-g-MA), which acts as a bridge for nanoclay-matrix-interaction. In our study, blown films of LLDPE, LDPE, and their blends were produced using a twin screw extruder. The combination of PEs as matrix, montmorillonite (MMT) and silver nanoparticles (AgNPs) intended to improve mechanical and thermal properties. Nanocomposites films with 1 wt% of montmorillonite and 0.5–1.0 wt% silver nanoparticles were prepared by blow extrusion and evaluated. Nanoclay intercalation/exfoliation degree was investigated by X-ray diffraction spectroscopy (XRD) and scanning electron microscopy (SEM). Mechanical and thermal properties were evaluated. The results showed optimum dispersion at intercalation/exfoliation levels for polyethylene nanocomposite (PENC), slight increasing in mechanical and especially improvement in thermal properties.

Mar 1, 2017

By Yoji Imai, Akio Watanabe, Masakazu Mukaida

"To clarify the feasibility of alkoxides and acetylacetonates as precursors for laser CVD of metal oxides, vapors of tantalum or titanium alkoxides and zirconium acetylacetonate were irradiated by KrF excimer laser and deposits were characterized by XRD and XPS measurements. As for tantalum and titanium, non-stoichiometric crystalline oxides grew nearly phototropically, however, zirconium oxides deposited showed only halo-pattern by XRD measurements. Electric conductivity measurements of tantalum oxides implied the improvement of the insulating properties by the addition of activated oxygen to the ambient.IntroductionThere has been renewed increasing attention to the metallic oxide thin films because ofits promising usefulness in many applications, such as high-Tc superconductors and ferroelectric devices. A variety of thin film preparation techniques have been studied such as sputtering, chemical liquid deposition (sol-gel and metalorganic decomposition), pulsed laser deposition and chemical vapor deposition (CVD). Among them, we think CVD is the most promising method because it offers a high controllability of morphology and good step coverage at relatively high growth rate. Preparation of oxide films by CVD can be achieved using a precursor containing metallic element and oxygen containing gas such as N20 at the same time. However, metalorganic (MO) compounds which contain both metallic element and oxygen, directly bonded to metallic element, seems to be more favorable because some of MO has a good properties for CVD such as a rather high vapor pressure, stability in ambient and low toxicity."

Jan 1, 1998

By F. Rivard, L. Rao, P. Carabin

"Advances in thermal plasma torches have resulted in this technology becoming a commercially viable solution for chemical and metallurgical processes. The main advantages of plasma are its ability to control process chemistry and to build small footprint reactors due to its high energy density and reactivity of the free radicals that are produced. This paper focuses on thermal plasmas produced by DC torches and their applications for waste treatment, production of high purity metals, and nanomaterials. Both transferred and non-transferred torches have been used as either a source of heat or as a reagent in various industrial processes. Retrofitting plasma torches in place of fuel oil burners lead to lower operating costs, capital cost and greenhouse gas emissions.INTRODUCTIONPlasma technology has become an ideal solution for many industrial chemical, metallurgical and mechanical processes [!]. Thermal plasma powered systems are typical used for their unique characteristics such as high energy densities, high temperatures, small installation sizes, rapid start-up and shutdown features, controlled process chemistry and use of electrical energy as a heating source resulting in decoupling the heat source from the oxygen flow rate [2]. Depending on the nature of the main plasma forming gas used, thermal plasma systems offer a high temperature heating source coupled with a highly reactive plasma plume rich in free radicals and ions which promote otherwise hard to drive chemical reactions, as well as high heat transfer rates."

Jan 1, 2013