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By S. K. Kawatra, T. C. Eisele

Under normal conditions, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. To reduce this pyrite recovery, it is first necessary to determine the primary recovery mechanism, because different measures are required for reducing entrainment, locked particle flotation or true hydrophobic flotation. In this paper, evidence is presented that suggests that hydrophobic flotation is not the major mechanism for recovery of liberated pyrite; instead, the bulk of the recovered pyrite results either from simple entrainment or from being physically locked with floatable coal particles.

Jan 1, 1993

By W. R. Penney, J. M. Richardson, J. Y. Oldshue

Introduction The mining industry has for years underrated the value of mixing in mineral processing unit operations. In present-day operations where leaching is playing an ever increasing role in the total profit picture, the need for good mixing is becoming more obvious. The engineer in the research laboratory and in the operations is by necessity becoming more familiar with the concepts of mixing. This section is designed to provide the engineer with mixing data and correlations sufficient to assist in the general planning of simple mixing systems.

Jan 1, 1985

By G. Thorsen

An alternative way to the normal practice of precipitation of jarosite, goethite, or hematite for removal of iron from zinc sulphate process liquors/ is to employ the techniques of solvent extraction. The process presented avoids the addition of any external alkali for the extraction of iron by integrating the leaching and solvent extraction steps in a hydrometallurgical zinc plant. By starting the leaching of zinc from the solid zinc calcine material with an organic solution of an acid liquid cation exchanger, the organic phase is loaded with the organic zinc salt from the direct reaction with zinc oxide. The residue from the organic leaching is transferred to a hot acid leach circuit where the remaining zinc oxide and the zinc ferrites will dissolve form¬ing an aqueous sulphate solution of zinc and iron. In the subsequent solvent extraction of iron from this aqueous leach solution, iron is exchanged with zinc from the organic phase. The commercial carboxylic acid Versatic 10 (Shell) is highly efficient for this integrated process of leaching and solvent extraction. The resulting iron-loaded organic phase is heated to 150-200 C in the presence of water whereby the iron will be directly precipitated from the organic phase as iron oxide of high purity and the regenerated organic acid is recycled to the organic leaching step for reloading with zinc.

Jan 1, 1980

By C. M. Bartley

In world-wide mining circles countries become known by the principal minerals they produce. The production of iron, copper, phosphate and sulphur in the United-States-has-been particularly significant and has provided the base for aggressive developments in heavy industry, agriculture and chemicals. Mention diamonds and gold-and you will think--South Africa; silver-Mexico; nickel and asbestos--Canada. The main purpose of this paper is to point out that potash mast be added to the list of minerals by which Canada is known in the mining World. The potash deposits of western Canada must be classed as a major world source of chemical fertilizer raw material. We believe that they are both the largest and the richest of all known deposits in the world. The most knowledgeable people in the industry avoid making estimates of reserves because even where the arithmetic is correct the total is so large that it appears to be ridiculous. In 1957 Marion Goudie made a carefully qualified estimate of 6 billion tons of recoverable potash above 3,500 ft, and grading 25 per cent K20 or better. This figure can now be increased by the amounts available through solution mining. No one has bothered to estimate how much this is because it is so large that the actual amount is not significant.

Jan 1, 1966

By Steve Rule, Jose Roberto Vago, Walter de Moura

Cerro Vangaurdia Gold Mine is a joint venture between AngloGold (the operator), Perez Companc and Formicruz and is situated in the southern province of Santa Cruz, in Argentina, approximately 2,150 km south of the capital, Buenos Aires. The mine is located in a severe, semi-arid environment with very cold winters and little annual rainfall (200mm). It is an open-pit operation, mining several narrow, shallow epithermal quartz veins with . gold and silver mineralisation. Commissioning of the plant commenced in September 1998 and the first dore bar was poured towards the end of the same month. The nominal capacity of the plant is 55,000 tonnes per month, with a design capacity of 60,000 tonnes per month. Prior to finalising the design, an extensive testwork programme was undertaken at Nova Lima, in Brazil, in which all parts of the process were evaluated together on a pilot-plant scale. The process flowsheet selected at Ce1rn Vanguardia is quite novel, in that it includes milling in cyanide, as well as a cyanide recovery and recycling plant on the tailings section of the treatment plant is included. The cyanide recovery process selected was a version of the acidification - volatilization - reabsorption (AVR) process, known as Cyanisorb™. The selection of the Cyanisorb™ process in the plant design was as a direct consequence of two factors:

Jan 1, 2000

By Walter Hoecker

The dissolution of gold in cyanide_ leaching has been we11 published with the genera1 acceptance that gold is oxidised by oxygen and stabilized by complexation with cyanide [1]. The dissolution of gold is essentially an electrochemical process. The rate of the anodic gold dissolution is controlled by the cyanide concentration. - (2) While the cathode reduction of oxygen is controlled by dissolved oxygen concentration - (3) There are a number of factors influencing the concentration of oxygen, and if 1owered substanth.lly will effect the efficiency of the leaching plant. These include: "' salinity "' temperature "'partial pressure "'oxygen consumption rate The use of pure oxygen for· cyanidation is only beneficial if oxygen is rate limiting, Conversely a slurry saturated with air (typically 5 - 8 ppm) may not be enough for maximum leach rate. The diagram below shows the maximum dissolved oxygen levels obtainable with pure oxygen and air. DISSOLVED OXYGEN (MAXIMUM) IN WATER At steady state, the rate of the cathodic reaction must equal the rate of the anodic reaction. Thus the rate of gold dissolution is dependent on both the· cyanide and oxygen concentrations. - (4) Using an average of Do/Den =· 1.5 [2] (where Do and Den are the oxygen and cyanide diffusion coefficients) the table below illustrates the maximum effective oxygen concentrations for given cyanide levels in clean water [3].

Jan 1, 1992

By Andreas Rubo, Stephen Gos

Over the past couple of decades several endeavours have been made to develop lixiviants with the intention of replacing cyanide in gold leaching. In 1980s these endeavours were largely economically driven, due to cyanide shortages at that time. In more recent times, the driving force has shifted to occupational health and environmental considerations. It is often argued that the high acute toxicity of cyanide alone makes it worthwhile considering to replace it completely by less toxic alternative lixiviants. This has led to having to consider more criteria in the choice of any alternative lixiviants, which have often not been taken into account in the past. The intention of this paper is to review these alternative lixiviants and also review the criteria, which have ultimately led to most of these lixiviants never having found any large scale application, if they passed laboratory stage at all. It is also intended to show, that by handling and treating cyanide in a proper manner, the overall profile for the use of cyanide compared to these alternative lixiviants is very favourable. The question to really be answered is whether there is actually any chemical or process applicable to gold leaching that does not show the high toxicity potential of cyanide and that is still favourable with regard to looking at a broader spectrum of criteria and not only acute toxicity.

Jan 1, 2000

By Lorraine B. Yde

Successful implementation of computer systems deals with meeting final systems objectives and cost and schedule requirements, but the final success is dependent upon personal inter- action. This is a case history of the installation of responsibility reporting at The Anaconda Co.'s Twin Buttes operation, later to become Anamax. The study has been documented as it occurred in hopes that it will illuminate the "people" side of computer systems implementation. Systems implementation involves negotiating with people. "The cooperative approach to negotiation (Nierenberg, 1968) the approach which vostulates that all varties must come away having gained something is based on a simple but important premise. Negotiation takes place between human beings. You cannot negotiate with a computer." This is a look at the human side of a major system installation. An attempt is made to show how a reporting system enabled a company to take a new look at itself. It is also an example of statements made by Toffler (1970) in Future Shock. "As machines take over routine tasks and the accelerative thrust increases the amount of novelty in the environment, more and more of the energy of society (and its organizations) must turn toward the solution of non-routine problems. This requires a degree of imagination and creativity that bureaucracy, with its man-in-a-slot organization, its permanent structures, and its hierarchies, is not well-equipped to provide."

Jan 1, 1979

By B. K. Mishra, R. K. Rajamani, P. Songfack

Primary grinding in SAG mills is gaining more importance with respect to the conventional crushing, rod and ball milling operations. This is due to the reduced operating costs generated by lower steel consumption. However. SAG milling is inherently susceptible to more severe risks and problems since it attempts to combine several stages of the conventional crushing and grinding into a single stage. This paper analyzes the SAG milling operation by predicting the motion of rocks and steel balls. The well-known discrete element method (DEM) is used to calculate the trajectories of individual entities, and their collision with one another. A computer code previously used for studying the motion of grinding media in ball mills is enhanced to handle the interaction between heavy spherical steel balls and light chunks of rocks, usually ellipsoidal in shape. The DEM based software called MILLSOFT can animate the charge motion for different design of liners. A case study of a 9.75-m diameter SAG mill is presented and the effects of lifter bar height and configuration on the overall dynamics of the charge are discussed. Also the effect of spacing between liners on lifting the charge is presented. This new approach has a large potential because it shows in detail the effect of each design or operating parameter on the performance of SAG mills.

Jan 1, 1998

By Brock H. Morrison

One of the major criterion of any mechanised tunnelling operation is to minimize downtime of the tunnelling machine by employing the most efficient muck handling system space and economic factors permit. A tunnelling machine which remains idle during a large percentage of the available shift working time is a luxury no contractor can afford. There are several possible reasons for non-productivity of a tunnelling machine ... the inability of the muck handling system to keep pace with the tunnelling machine on a continuous basis is one major cause. In large diameter tunnels, where several trains or more than one muck hauling unit can operate simultaneously, downtime of the tunnelling machine may be kept to an acceptable level. On small to medium diameter tunnels, 8 feet to 14 feet in diameter, the muck removal support system is normally restricted in capacity, resulting in an excessive tunnelling machine downtime as the tunnel extends from the shaft. There is a need for an efficient, continuous and economical muck removal system for small to medium size tunnels being driven by a hard rock machine. This paper is intended to provide an insite into pneumatic conveying, and explain the Radmark System; its development and utilisation in the tunnelling and mining fields. STATE OF THE ART Pneumatic conveying is the transportation of bulk materials

Jan 1, 1997

By Yuuichi Umeki, Yuusaku Tominaga

In order to keep good air condition in any specific branch such as coal face and/or heading in an underground coal mine, effective factors of all the branches with respect to the specified branch have been investigated, using computer simulation. Main results of the paper are as follows; 1) A branch in a network is classified to one of three classes of effectiveness to increase, to decrease and not to change airflow rate in the specific branch by altering aerodynamic resistance in the branch. 2) Distribution of position of branches, belonging to each class, related to a specific branch is one of the macroscopic characteristic of a network which is the inherent property of every network. 3) A relation of the aerodynamic resistances of any two branches to keep a constant airflow rate in the specified branch is shown as a monotonous curve. 4) Ventilation transition diagram with the rate of airflow in the two branches as coordinates, and for different rates of airflow in the specific branch as the parameter, is found to be straight lines. 5) Existing range of airflow rates In the specified branch is given as a parameter in the enclosed area in the ventilation transition diagram. Moreover, an expert system to assist ventilation control using a transition diagram of airflow rate is introduced in this paper.

Jan 1, 1991

By S. W. Kan, M. G. Kakarkis, J. Zelanco

Grouting has been used in underground mining for more than 20 years. Chemical grouting is often used as a remedial measure when the implemented ground-control program is unable to completely prevent structural failures or when there is a need for preventing a structural member from unraveling. The utilization of polyurethane grout is restricted by its limited range of physical and mechanical properties. To overcome some of the drawbacks of polyurethane, research is being conducted on a newly developed polyester based grout. The polyester resin, identified by Sandvik as Strata Grip, provides a number of features, including variable gel times and a much-reduced chemical hazard. Equally important are the mechanical properties of the product. The strength and deformability of any chemical grout must be compatible with the intended purpose of grouting and the expected deformation of the rock that is to be grouted The assessment of the mechanical properties of polyester grout is the focus of this work. Field experiences and laboratory research defined the properties of an effective grouting material. Experimental results indicate that the polyester grout meets or exceeds the recommended properties for many injection applications. Furthermore, the results suggest that the ability to adjust mechanical properties via resin formulation has the potential to expand the applicability of chemical grouting in ground control.

Jan 1, 1999

By M. A. Marticorena, R. Stratton-Crawley, C. I. Basilio

Diethylenetriamine (DETA) is a selective depressant for nickeliferous pyrrhotite during pentlandite flotation. Laboratory flotation tests conducted on ore and process samples showed that pyrrhotite rejection is greatly improved by small additions of DETA; however, the effectiveness of this depressant is most noticeable when the mineral sample is oxidized. LIMS and XPS analyses conducted on flotation products and pyrrhotite specimens showed that the difficulty in pyrrhotite rejection arises from inadvertent activation of the mineral by heavy metal ions, such as Ni2+, cu2+ and Ag+, that are present in the process water. In the presence of DETA, however, the mineral is deactivated under oxidizing conditions. The deactivation mechanism may involve oxidation of the activation products, which are likely in the form of heavy metal sulfides, followed by solubilization by DETA. FTIR spectra of pyrrhotite electrodes contacted with DETA showed no trace of the reagent on the surface, substantiating the view that its role is one of complexing agent that enhances the dissolution of activation products under oxidizing conditions. FTIR spectra of pyrrhotite contacted with amyl xanthate solutions showed that both dixanthogen and iron xanthate are formed on the surface, the latter becoming more predominant at higher potentials. In the presence of DETA, however, only a small amount of xanthate is adsorbed on the mineral at potentials (Eh) approximately 200 mV higher than the case without DETA.

Jan 1, 1995

By James Sheridan

Risk can generally be defined as the possibility or chance of a loss corresponding to uncertainty. Analysis is the process for examining the components and relationships of a complex system in order to determine the impacts of its variables. Risk analysis is therefore a course of action taken to analyze multiple variables of a system that is subject to speculative outcome. When risk analysis is applied to mine development, it becomes the means for assessing and measuring those parameters that contribute to economic viability. Mining can be a risky business. It is composed of an assortment of factors that contribute to its financial outcome. Of these factors, the most consequential output is the net present value (NPV). Applying risk analysis in mine development can identify those factors having the most significant impacts and applying limits to those impacts. Mathematical computer modeling using Monte Carlo techniques is available and can be customized to suit specific mine development ventures. Essentially, those parameters that are not fixed values can have input variability. Rationally deduced engineering estimates should be the basis for determining the initial values applied as inputs in the models. Risk analysis therefore provides the user a means to identify, rationalize and assess the risks in mine development in an informed, calculated, and unbiased format for making economic decisions.

Jan 1, 2002

By Gian-P. Lozej, Ross Y. Black, Sami S. Maddah

The Zabirah bauxite is a Cretaceous paleolaterite exposed by postTertiary uplift and erosion of the Phanerozoic sequence. The laterite profile, which is preserved in situ, occupies a prominent angular unconformity over a sequence of sandstones, siltstones and mudstones ranging from Late Triassic to Early Cretaceous in age, and is overlain by a Late Cretaceous terrigenous and carbonate package. The profile is known to be preserved over an area of 250 sq km and at depths below the present surface of up to 80 m. The bauxite layer is hard, compact and predominantly pisolitic, with a variety of subordinate, superimposed textures resulting from post-formation alteration. The bauxite minerals are boehmite and gibbsite. Boehmite generally predominates, and the boehmite:gibbsite ratio averages 2:1, with a marked tendency for the proportion of boehmite to increase down the profile. Kaolinite, a major constituent of the profile, is concentrated in two zones, one above and one below the pisolitic bauxite layer. Iron content is variable and bears a direct relationship to parent-rock lithology. Genesis and preservation of the bauxite are due to the favourable coincidence of a number of geological controls of which the most significant are the local structural and sedimentary regimes, the lithology and chemistry of the parent rocks, and the Cretaceous paleogeography of the region.

Jan 1, 1984

By R. E. Vivas, J. Garcia

"INTRODUCTION Freeport-McMoRan is a leading international natural resources company that operates large, long-lived, geographically diverse assets with significant proven and probable reserves of copper, gold, molybdenum, cobalt, oil and natural gas. Freeport-McMoRan is the world’s largest publicly traded copper producer and largest producer of molybdenum. The Sierrita mine is an open pit truck and shovel operation from which copper and molybdenum are produced. An important key to Sierrita’s success lies in their ability to realize their plans in the field. In certain circumstances, the mine plans are not achieved, and the operation fails to meet its targets which is an issue revealed in reconciliation reports. This technical session discusses the methodologies and procedures used at Sierrita to monitor the implementation of the mine plans, measure the performance of the operation and reduce the variance between plan and actual. Ensuring the operation stays on target is vital so mine productivity and profitability can attain its maximum potential. PROJECT OVERVIEW The Sierrita mining complex is located in Pima County, approximately 20 miles southwest of Tucson, Arizona as shown in Figure 1. The first mining claims at Sierrita date back to the late 1800s while underground mining activities started in the early 1900s. However, open pit development of Sierrita began more than 50 years ago to become the modern mining complex it is today. In 2009, Freeport-McMoRan purchased the adjacent Twin Buttes copper mine, providing significant synergies in the Sierrita minerals district. This venture included the potential for expanded mining activities, operations growth for mining copper and molybdenum, and reclamation activity. It should be noted that in addition to copper and molybdenum, the Sierrita mine produces rhenium which is a rare and highly value metal. The ore deposit contains oxide and sulfide mineralization. The oxide ore is delivered to the leach process while the sulfide ore is routed to the crusher and mill circuit 4,700 jobs on Arizona’s economy Freeport-McMoRan partners with the communities near Sierrita to provide programs that contribute to their sustainability"

Jan 1, 2015

By John Keay, Douglas R. Shaw, Gregory J. Olso

Rhodes Mining NL, Perth, Australia, is developing the Lahoca Gold Project which is located in Hungary, about 30 km from the town of Eger. The preliminary resource is estimated to contain approximately 1.5 million ounces of gold. The project is being evaluated for an annual process capacity of 2 million tonnes. The test samples contain just over 2 g Ault and 6% sulfur as sulfide. Copper and arsenic levels are approximately 0.2 and 0.1 %, respectively. The ore is refractory due to submicroscopic gold occurrences and structural associations with pyrite. A small amount of the gold is finely encapsulated in quartz. Approximately 30% of the gold in the crushed ore is soluble in cyanide and up to about 55% is cyanide-recoverable with ultra­fine grinding. The ore has little preg-robbing ability. Metallurgical test work done by Colorado Minerals Research Institute (CMRI) and other investigators has shown that as much as 85 to over 90% of the gold was recovered by the relatively severe conditions of pressure oxidation or roasting of the whole ore or a flotation concentrate. The Lahoca ore responds to flotation with gold recoveries of 87% into a low grade concentrate. Subsequently, with a view toward defining a process route with potentially more attractive economics, Rhodes Mining and CMRI conducted an extensive review of biooxidation technologies and concluded that, in particular, heap biooxidation methods promised lower process costs which normally are associated with heap leaching. Based on the study, which included the analysis of the closely related practices of copper dump/heap bioleaching now well established in that industry, CMRI conducted simulated heap biooxidation experiments which evaluated factors such as ultra fine ore crushing, agglomeration techniques, heap design, forced aeration oxygen supply, and whether or not the heap is irrigated. Separate flask biooxidation tests at Little Bear Laboratories showed that the finely crushed ore is biooxidized readily, with a near linear relationship between sulfide oxidation and gold cyanide solubility. Gold recoveries of as high as 66% have resulted after biooxidation of crushed ore. This paper highlights the metallurgical developments of the Lahoca project, and focuses on recent biooxidation laboratory test work aimed at enhancing the treatment of crushed ore.

Jan 1, 1997

By William Mayrsohn

INTRODUCTION The net smelter return (NSR) calculations made on various smelter-refiner alternatives, is usually done by taking the gross metal value less metal deductions, smelter-refiner charges and transportation-insurance costs. An important further step in the calculations is the financial charges imputed by refining time, transportation delays, to the time gold is returned (if tolled) or paid for if bought by the refiner. Metal that is priced in advance of payment also requires a forward premium that the mine may or may not be getting. This is a hidden cost that is often omitted from the calculations. Segmentation of each of the above costs are vital to see where improvements can be made through negotiations, better choice of metal pricing or transportation alternatives. BASIC NSR CALCULATIONS SMELTER-REFINER CHARGES Payable Metals - Treatment Refining Charges: Since these can vary from one smelter to another, the effect of a $25 per ounce price increase/decrease should be calculated and kept in mind. This effect is compared to differences in refining/treatment charge and a total smelter/refiner cost on a cost per ounce of dore, gold, or a dry ton of concentrate. Transportation - Insurance: Research has to be done on transportation alternatives perhaps with some assistance from the smelters, railroads or trucking companies. For dore, the U.S. postal service is viable and inexpensive. For railroads, deal with the regional office ie., B&N El Paso, if production warrants regular bulk shipments. Spot rates tend to be higher. A small mine producing concentrates usually goes to the nearest smelter due to extremely high transportation costs. Here is where a refiner can help. Insurance-Quotes for rates on dore/ concentrates are easily obtainable, but the mine has to shop for the best rates. Your insurance broker is the best source of this information. Differences between Mine and Smelter/Refiners Metal losses can be caused by the following: - Concentrate dry weight differences caused by moisture determination or faulty scales (often at the mine). - Sample bias by poor preparation practices on either side ie., grinding of the sample removing gold; or a poorly mixed concentrate. Dore bullion has no such difficulties.

Jan 1, 1987

By W. Holding

Since the 1975 International Mine Ventilation Congress in Johannesburg there has been a trend in South Africa towards making the mine ventilation departments responsible for monitoring the total environment. This includes the taking of noise and illumination measurements and there is in fact a debate taking place as to whether the departmental title should be changed to 'Environmental Control Department'. The organisers of the 2nd international Mine Ventilation Congress have decided that noise and illumination will not be included as Congress subjects and 'Total Environment' includes only those facets which are open to debate at the Congress. The choice of mine is significant in that while most Congress papers from South Africa will be devoted either to coal mining or to the somewhat unique deep level gold mines, Prieska Copper Mine is a mine which can easily be identified with similar mines in many other parts of the world. The mine is situated some 750 km south west of Johannesburg and about 600 km north east of Cape Town. Current production (ore and waste) is about 340 000 tons per month and the total underground labour force is just over 2 000. The ore body is a massive sulphide, the main minerals being copper and zinc and the method of mining is sub-level open stoping. Daily average surface temperature conditions range from 85°F (29.5°C) dry bulb and 69.8°F (21°C) wet bulb in mid-summer to 42°F (5.5°C) dry bulb and 36.5°F (2.5°C) wet bulb in mid winter. The information presented in-this paper is limited to what can be gathered by mine ventilation staff as part of an on-going exercise and is obviously not as comprehensive as would be the case if a fully equipped research establishment were to become involved. The paper will be divided into three sections 1) Gases 2) Dust 3) Heat In each section statutory and/or other standards will be set down followed by a discussion of assessment and in some cases control methods.

Jan 1, 1980

By W. M. Jr. Aubrey, R. L. Stone

INTRODUCTION Most metallic minerals and some industrial minerals have a relatively high specific gravity and most have at one time or another been concentrated by gravity methods. The principles of gravity concentration are straightforward, well documented and easy to understand, but in practice there are many pitfalls that await the engineer in the development of an integrated flowsheet. Gravity concentration equipment has a long history of use and there is a great diversity available. The equipment is capable of treating material over a broad size range, only falling off in efficiency in the very fine sizes. Gravity concentration is also inexpensive, generally free of environmental problems, and commercial equipment can process large tonnages of ore with a minimum of capital cost. As might be expected of an efficient and low cost process, the bulk of the tonnage quickly and inexpensively. Another obvious application is treating mineral deposits such as hematite and manganese ores that are sufficiently liberated after a minimum of crushing to allow production of a coarse concentrate that will meet market specifications. Except for hand picking and mechanical sorting, there is no competing process on coarse size material. Conversely, it is sometimes obvious that gravity concentration does not warrant consideration. Examples are ores that require very fine grinding to attain liberation, for ores where the minerals of interest have a gravity similar to the gangue, and ores that are strongly magnetic. Actually a mineral processing engineer may not know if gravity is the best way to concentrate an ore, but he should have little difficulty recognizing when gravity concentration deserves consideration based upon specific gravity differences and liberation gravity concentration has wide use. size. His challenge then is to At times its selection as the identify and test the applicable primary concentration process is processes, to develop a obvious. Low grade placer deposits metallurgical balance and flowsheet of tin, gold and beach sands usually for the best process, to estimate are only profitable because gravity production rate over the life of concentration is able to throw away the deposit and to make equipment

Jan 1, 1986