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By J. Petersen, H. Naderi, M. H. Nikzad, M. Karimi

In this research, the thermodynamic study of sodium persulfate (Na2S2O8) solution in the presence and absence of H2SO4 and Fe3(SO4)3 was done. Eh-pH and equilibrium distribution diagrams were constructed using Outotec HSC Chemistry Software and the main stable ionic species were determined. Also, the mean activity coefficient and Pitzer model coefficients were evaluated. Effects of system composition, sodium persulfate concentration and temperature were investigated. According to the results, HS2O7 -, HS2O8 -, S5O3 2-, S4O3 2-, S3O3 2-, HS- and NaSO4 - are the main stable species in these three systems. Increasing of sodium persulfate concentration resulted in disappearing of SO4 2- and the appearance of NaSO4 -. The main effect of increasing the temperature from 25 to 75oC, is changing the stability regions of HS2O7 -, NaSO4 -, SO4 2- and S2-. From equilibrium studies, it was concluded that at 25 and 50oC, increasing the persulfate concentration results in a 55-60% decrease for HS2O7 - and an 20- 30% increase for HS2O8 -. At 75oC, HS2O8 - becomes the main species and its percentage decreases with increasing the persulfate concentration. Keywords: Thermodynamic, sodium persulfate, activity coefficient

Jan 1, 2020

Spiral concentrators are compact, cost-effective and generally efficient gravity concentration separators for a wide range of applications (for example: coal, beach sands, iron ore, chromite and tantalite). Large mineral processing plants consist of thousands of spiral concentrators resulting in large plant footprints (capital intensive) and the adjustment of splitters is time consuming, impractical and is in many cases neglected?high capacity (HC) spiral concentrators aim to address these shortcomings. As a result Exxaro Namakwa Sands is currently investigating high capacity spiral technology for the spiral circuit upgrade at the primary concentrator plants (PCPs). This article summarizes the rougher spiral performance evaluation that was conducted on different types of spiral concentrators (the traditional MG4 spiral concentrator and the high capacity (HC) spiral concentrator) under different feed conditions. In addition, the effect of slimes on the spiral concentrator performance was also investigated. Slimes rheology was linked to the poor concentrator performance at the higher slimes concentrations. The test campaign shows a sacrifice in recovery under design-feed conditions can be expected when using high capacity spiral concentrators in the rougher stage when compared to traditional spiral technology currently in use. Both spiral concentrators show a detrimental impact of slimes on the performance, but the high capacity spiral concentrator is more sensitive to the higher slimes conditions.

Jan 1, 2010

By A. A. Rogozhin, S. I. Anufrieva, A. V. Kurkov

The results of development of technologies for flotation concentration of two types of complex beryllium ores are presented: beryllium-fluorite in apocarbonate metasomatites (Type I) and rare-earthberyllium in feldspar metasomatites (Type II). The researched samples of Type I ores contain a mineral complex that is difficult to separate by fatty acid flotation, including phenakite, bertrandite, fluorite, and carbonate minerals. The ores are characterised by an increased content of fluorite and carbonates. The sample of Type II ore contains such rare-earth minerals as bastnesite and orthite, and a beryllium mineral - cleiophane. The size of individualised grains of cleiophane does not exceed 0.04 mm, which significantly limits the possibility of extracting the mineral into the enrichment concentrates. For the Type I ores, a technological process for the extraction of fluorite using a phosphorus-containing reagent from the class of dialkylphenyl polyethylene glycol esters of phosphoric acid (DAPEGEPhA) has been developed. The use of DAPEGEPhA enables the production of a high-grade fluorite concentrate (95% CaF2). The production of commodity phenakite-bertrandite high-grade (10% BeO) flotation concentrate from the fluorite flotation tailings with using a fatty acid collector is based on binding calcium in the flotation pulp using soda, sodium hydroxide and sodium tripolyphosphate. The use of a combined collector based on fatty acids and DAPEGEPhA made it possible to produce a collective rare-earthberyllium- lithium concentrate with high REE extraction (88%) from the Type II ores. The concentrates obtained are suitable for production of commercial-grade hydrometallurgy products. Keywords: Beryllium ores, flotation, reagents, concentrates, hydrometallurgy products

Jan 1, 2020

By M. Bryson, G. Marap, M. Ntlhane, M. D. Hlahane

This study investigated flotation of phosphate from a low-medium grade 8-12% P2O5, 65-73% SiO2 sedimentary phosphate ore from Kropz Elandsfontein (herein referred to as Elandsfontein) in South Africa. Quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN) was used to determine apatite grain size distribution, liberation and mineral association in the F2 horizon sample. The mineralogy indicated that apatite was liberated and for the Elandsfontein plant to operate at the design throughput, the flotation feed has to be milled to a coarse grind ranging between 300 μm and 425 μm. Reverse flotation process routes using varying reagent dosages, and flotation feed top sizes that could possibly yield a final product of 31% P2O5,10% SiO2 at a reasonable +70% P2O5 recovery were investigated. Based on the results, a split circuit of coarse (-300+212μm) flotation and fine (-212+20μm) flotation, was mostly preferred as compared to treating the whole ore. A final combined concentrate of 31% P2O5 and 10% SiO2 with P2O5 recovery of 84% could be produced from the reverse split circuit. The robustness of reverse flotation for both coarse and fine fractions was further investigated. Reverse flotation of the fines fraction was found to be robust and produced a final product of 31% P2O5. It was however more challenging to achieve the required product grade and recoveries on the coarser fraction (-425+212μm), suggesting that reverse circuit was not adequately robust at fractions coarser than 300μm. Keywords: Phosphate, sedimentary, reverse flotation, particle size

Jan 1, 2020

By J. W. van der Merwe, A. M. Maleka, V. J. Matjeke

The 10.5–12.5% chromium, titanium-stabilized ferritic stainless steel (FSS) plates used to fabricate coal line jumbo wagons is susceptible to undesirable chromium depletion during welding with 309L electrodes. In this work, non-stabilized FSS plates were welded using 308L welding electrodes. The objective was to weld non-stabilized FSSs using gas-shielded metal arc welding without causing sensitization. The welding process was optimized by lowering the heat input. Sensitization was assessed by rigorous etching techniques and anodic polarization scans. In addition, the welds were subjected to tensile testing, and their fracture surfaces were examined for intergranular cracking. Non-stabilized FSS plates were successfully welded using gas metal arc welding.

Apr 5, 2023

By M. Ye. Scheglov, G. I. Voiloshnikov, S. M. Ryakhovsky, V. E. Dementyev, V. N. Alekseev, N. S. Voiloshnikova

Irgiredmet has substantial experience on RIP and RIL technology for gold recovery, having started development of ion exchange technology in 1964. Irgiredmet specialists were involved in the majority of RIL and RIP projects in the former Soviet Union and Russia, and took part in commissioning of practically all plants using ion exchange technology. Laboratory and pilot plant tests were conducted to develop process design criteria for designing 15 RIP plants of the former USSR using bifunctional macroporous anionite AM-2B or its analogs. This paper is devoted to the laboratory, pilot plant testing and introduction of RIP technology conducted in cooperation with GC Pertopavlovsk. Medium base resin PuroLite S992 (PuroGold) was used as adsorbent. Some adsorption regularities and the affinity of resin to metal cyanide complexes were studied. Laboratory batch and continuous pilot tests on resin-in-pulp process were held for oxidised ores from Pioneer, Albyn and Malomyr mines (Amur region, Russia) owned by the Petropavlovsk company. A simplified flowsheet for gold elution and resin regeneration was developed. Alkaline cyanide solution was used as gold eluent and gold was recovered from eluates by electrowinning. Process design criteria were developed on the basis of the testwork results, and the plants were designed and constructed by GC Petropavlovsk. The RIP plant at Pioneer was commissioned in May 2008, at Malomyr in August 2010, and at Albyn deposit in December 2011. These plants are currently in operation at design performance at throughputs from 3 to 6.5 Mt/year. The primary gold ores of Pioneer and Malomyr deposits are refractory to cyanidation; Irgiredmet also completed continuous testwork on RIP technology using medium-base resin for pressure oxidation (POX) residues derived from their flotation concentrates. In 2019 a hydrometallurgical plant for the treatment of refractory gold concentrate after POX was commissioned at Pokrovsky mine (Amur region). Keywords: Gold ores, cyanidation, RIP, RIL –processes, ion exchange resin, medium base resin, adsorption, elution, electrowinning

Jan 1, 2020

By P. M. Solozhenkin, O. I. Solozhenkin

Currently lead nitrate is used as the recommended activator in Au-Sb flotation. However, due to high levels of hazard, the application of lead nitrate constitutes a potential risk for human health and ecosystems. To mitigate the harmful impact of activators on the environment, further research on activation by alternative reagents has been launched to promote the efficiency of antimony ores. In the present study, adsorption of lead, copper and zinc cations has been investigated by nuclear quadrupole resonance (NQR), which has revealed copper and zinc cations penetration into the mineral lattice, although lead cations remain adsorbed on the mineral surface. However, the combination of zinc and copper cations leads to preferential volumetric adsorption of zinc in the mineral lattice and further surface adsorption of copper which positively affects the activation process. It has been established that activation of stibnite can be achieved effectively with the mixture of Cu2+:Zn2+=1:1 as much as with lead cations in antimony ore flotation. As a part of this work, the computational modelling has been used in prognosis of reagent activity evaluation (PRAE) for stibnite and aurostibite flotation by sulfhydryl collectors. The lower PRAE value the stronger the ability of a collector to form a stable complex with a mineral. PRAE has shown a strong negative trend to complex formation on the mineral surface of aurostibite and stibnite. Based on these studies, several collectors have been proposed for effective flotation. To verify the feasibility of proposed collectors tetramethyl (ethyl) thiuram disulfides (TMTD and TETD) have been used for flotation of stibnite, sphalerite, pyrite and arsenopyrite. Flotation performance has been improved significantly with TMTD that allows the avoidance of lead nitrate application and increases the recovery of antimony by 8,16%. Keywords: Stibnite, aurostibite, activation, lead, copper, flotation reagents

Jan 1, 2020

By JOURNAL SAIMM

SYMPOSIUM ON PELLETS AND GRANULES During October 1974, the Newcastle branch of the Australasian Institute of Mining and Metallurgy is to hold a symposium on pelletizing and granulation, with particular reference to the iron ore, fertilizer, and cement industries.

Jan 12, 1973

By B. McFadzean, S. Pikinini, C. T. O’ Connor

Sperrylite (PtAs₂) comprises about 21% of the platinum group minerals (PGMs) in the Platreef ore and regularly reports to the tailings due to its poor floatability. Hence, improving its recovery will be of great economic value to the South African PGM industry. The reasons for its poor floatability are not yet clear. This paper seeks to understand the interactions occurring between PtAs₂ and common thiol collectors, viz. potassium normal butyl xanthate (PNBX), sodium normal dibutyl dithiophosphate (SNBDTP) and sodium normal mono butyl dithiocarbamate (SNBDTC). By understanding its interactions with these collectors, it is hypothesised that it will be possible to suggest ligands that may help improve the floatability of sperrylite. Mineral-collector interactions were studied by determining the molar energy of interaction using isothermal titration calorimetry and electrochemical techniques. The hydrophobicity of the mineral before and after adsorption of the collectors was determined by heat of immersion and its flotation response determined by microflotation tests. Microflotation tests using synthetic sperrylite at pH 9 showed low collectorless recovery of 34.8% and after adding the equivalent of one pseudo-monolayer of the PNBX collector, the recovery of 32.5% was obtained. Moreover, the addition of up to three pseudo-monolayers coverage of PNBX did not result in any increase in flotation recovery. A small recovery improvement was noted when synthetic plant water with the ionic strength of 0.0484 mol/L was used, but this did not hold for all collectors, with SNBDTP exhibiting higher recoveries in distilled water. Keywords: Sperrylite; flotation; recovery; adsorption energy; collectors; 2SPW (synthetic plant water)

Jan 1, 2020

By N. Mangadoddy, M. Padhi

The simulation of multi-component classification with modified viscosity model is the key focus in the current study. The classification of the ores using hydrocyclone is a renowned process and has a convoluted flow separation phenomenon. The highly turbulent flow inside hydrocyclone depends on the operating and design parameters apart from the feed mixture. Slurry viscosity also plays a dominant role in the classification of solid particles under the centrifugal settling action. A heterogeneous mixture with different components would result in different settling and rheological behaviour of particles’ suspension in the water medium. The newly proposed multi-component viscosity model (Mandakini et al. 2020) is implemented as a user-defined function to define the material property during the CFD study of the mixture rheology inside hydrocyclone classifier. The multiphase and turbulence model is solved using the modified Algebraic Slip Model and Large Eddy Simulation model. A comparison of the predicted component performance curves is evaluated with and without the corrected viscosity model. The density and size effect on the particle phase distribution inside the classifier are compared, where the misplacements of the finer particles are carefully assessed. Validation of the component classification in hydrocyclone with the laboratory experiments found a close agreement with the rheology based CFD data. Keywords: Dual-component, multi-component viscosity model, double-gap rheometer, computational fluid dynamics, high solids concentration

Jan 1, 2020

By Z. Luo, W. Chen, Y. Zhao, Y. Fu, L. Dong

The gas-solid dense-phase fluidised bed includes a complex multiphase fluid-particle system; different complex exchanges significantly affect the stability of the fluidised bed. To elucidate the characteristics of fluidisation in a gas-solid dense-phase fluidised bed, this study used experimental performance tests to obtain the static density characteristics, and the attachment and flow characteristic of the dense medium. The results indicate that the bulk density of the dense medium increases first and then decreases with the increase of particle size. The airflow rate difference is used to quantify the wall attachment characteristics of dense medium and the average pressure gradient in the axial direction of the bed is approximately 20 Pa/mm under the fluidisation results. At the same settlement location, with the decrease of fluidisation number, the settlement velocity of large and small particles becomes slower, the boundaries of settlement displacement and location probability are gradually disrupted, and the falling velocity of particles with a radius of 20 mm is faster than that of materials with a radius of 15 mm. This work also established a theoretical basis for regulating the stability and separation characteristics of gas-solid dense-phase fluidised bed. Keywords: Fluidised bed, different size particles, fluidisation characteristics, flotation bubbles, settling motion

Jan 1, 2020

By G. Sahasrabudh, G. DeIulii, K. P. Galvin

A novel agglomeration process has been developed, utilising a concentrated water in oil emulsion as a binder. The binder is typically 95 wt% water, the remainder being an organic phase containing kerosene and the emulsifier— sorbitan mono oleate (SMO) in equal mass portions. The binder can selectively agglomerate hydrophobic particles in less than 7 seconds. The agglomeration has proven to be highly effective in recovering any particle of virtually any size, provided the particle is hydrophobic. The approach has previously been applied to coal, magnetite and silica. In the paper, sodium isobutyl xanthate (SIBX) and its much longer chain version, potassium tetradecyl xanthate (C14X), were used separately as collectors to selectively agglomerate chalcopyrite from the ore. Xanthates attach to metal sulphides, thus hydrophobising sulphide mineral particles. Chalcopyrite is a sulphide mineral; however, it hydrolyses quickly in the presence of water. Ethylenediaminetetraacetic acid (EDTA) was used to remove the oxide layer formed at the surface of the mineral particles after wet grinding, leaving behind a freshly generated metal sulphide surface. After the EDTA treatment, the ore particles were quickly conditioned at an optimised pH as well as collector concentration and agglomerated. The agglomeration achieved a copper recovery of 75% within 7 seconds, consistent with the recovery achieved by flotation over much longer time scales. Keywords: Chalcopyrite, agglomeration, froth flotation, interfacial chemistry, X-ray fluorescence, selective hydrophobisation

Jan 1, 2020

By P. J. Foster

This paper summarizes a behavioural safety project undertaken in seven quarries in the UK in order to investigate its applicability as a means of raising the standards of health and safety in the UK quarrying industry. A behavioural safety methodology was developed and trialed at two quarry sites in the UK. During the study the number of unsafe acts and minor accidents had decreased and at one of the quarries there was a 95% reduction in the number of working days lost. It was then introduced at a further five sites of varying sizes and within this focused specifically on lone workers as well as behaviours that affected quality and environmental issues. Positive improvements were noted in most of these operations. The project also looked at the effectiveness of health and safety performance indicators. Here, the common lead and trailing indicators for both safety and health that are commonly used by industry were identified. In consultation with the UK quarrying industry these were then used to identify specific performance measurement criteria that can be used by the quarrying sector to measure performance. Following on from this, a quarry specific health and safety management system specification was developed for large and small quarries.

Jan 1, 2008

By E Matinde, M. Mnisi, I. C. Thobadi, W. Clark, J. D. Steenkamp

Pyrometallurgical smelters utilise tap-holes, through which liquid metal, matte and/or slag are tapped at regular intervals. However, tap-hole failures can have a devastating impact on smelters, which includes loss of equipment, human life and business interruptions. Contributing factors to tap-hole failures include poor and/or incorrect refractory material selection, including tap-hole clays. The functions of tap-hole clays in smelters include their ability to be extruded and drilled with ease at the end and beginning of a tap, and their ability to resist chemical wear due to molten metal and slag during tapping. Mintek is currently developing methods of evaluating properties of tap-hole clays with a specific focus on workability, and wear mechanisms of clays due to ferrochrome alloy and slag. Of particular interest to this study was the characterisation of various tap-hole clays. This paper evaluates the chemical and phase chemical properties of three different tap-hole clays. The bulk chemical composition of the tap-hole clays was determined by inductively coupled plasma optical emission spectroscopy, proximate analyses and combustion methods. The bulk phase compositions and specific phase chemical compositions were studied using quantitative X-ray diffraction, scanning electron microscope and electron probe microanalyses techniques. Keywords: Tap-hole clay, chemical analyses, phase chemical analyses, ferrochrome

Jan 1, 2020

By T. Uysal

Various morphological parameters that affect the flotation recovery of sphalerite were modelled and optimized using the response surface method (RSM). The effects of roughness value, shape factor, and collector concentration were investigated using the central composite full design method. The results were evaluated by analysis of variance. The optimum roughening time was found to be 25minutes, the optimum roughness value was 2.9071 μm, and the optimum collector concentrationwas 0.001 M. Using these values, a flotation recovery of 98.01% was obtained. Similarly, in shapefactor studies, the optimum grinding time was 15 seconds, the optimum roundness value 0.7421, and the optimum collector concentration 0.0009 M, which resulted in a flotation recovery of 94.30%. The average error between the optimization results and the experimental results was estimated to be less than 6%, and the R2 values were greater than 90%. The study shows that RSM can be effectively applied in finding the economic optimum condition for obtaining maximum flotation recovery with minimum reagent consumption.

Sep 6, 2023

"SAMPLING: THE IMPACT ON COSTS AND DECISION MAKING1. INTRODUCTIONFor years those in the minerals industry have been taking samples to assist them in making decisions; whether they be about investing billions of rand in a new mining operation, or simply whether a truck load of mineralised material should go to the mill or the waste dump, - we need a sample to help us make our decisions. This paper emphasises the importance and significance of sampling as a process, some of the associated technical problems and some of the advantages, especially in the light of traditional approaches that has usually left mine sampling to the least educated and lowest paid individuals on the mine. Perhaps the most important aspect that requires attention is the variability, usually measured in terms of precision, that tends to infect the sampling procedures. Francis Pitard 12 has stated: ""There is no such thing as reliable feasibility studies, unbiased ore grade control, accurate environmental assessments or effective process control, if you cannot identify and minimize the seven (ten) major sources of sampling variability. "" It is these ten sources of sampling variability and the way they arise that are briefly investigated. Variability is measured in terms of variances and rather than being self-compensating, there is good evidence to indicate that they are in fact additive at every step in the sampling and analytical process."

Jan 1, 2014

By I. J. Kotzé, R. T. Jones

Conventional PGM matte smelting requires the presence of a certain quantity of base metal sulphides in order to collect the platinum group metals in a molten sulphidic matte phase in the furnace. Furthermore, the quantity of chromium oxide in the feed materials is controlled in order to avoid the build-up of high-melting chromite spinels in the furnace. Mintek has developed a process for smelting difficult PGM-containing feed materials that contain low amounts of sulphur and/or high amounts of chromium oxide. A DC arc furnace is used to provide the appropriate conditions to generate an iron alloy that collects PGMs very effectively, leaving extremely low residual quantities of PGMs in the slag. Various feed materials have been treated successfully in furnace campaigns running at power levels up to 1.5 MW. The longest of these campaigns was run continuously for more than four months, treating more than two thousand tons of materials such as low-grade concentrates, revert tailings, and converter slag. The campaigns demonstrated the robustness and versatility of the process, and proved that it is possible to sustainably produce a PGM-containing alloy and discardable slags containing an average of less than 1.4 g/t of PGMs over the entire campaign. Keywords: DC arc, smelting, furnace, platinum, PGM, revert tailings, converter slag, ConRoast

Jan 1, 2004

By R. Asamoah, P. Forson, S. Xu, W. Skinner, M. Zanin

In most auriferous hydrothermal deposits, gold is preferentially associated with pyrite and arsenopyrite minerals, with higher economic gold values noted for the latter and arsenian pyrite minerals. In this paper, surface (Cryo-XPS) and solution (EDTA extraction) analysis were used to characterise pyrite and arsenopyrite minerals under different aqueous conditions involving electrokinetic study and collector interactions to better understand ways of improving the separation of pyrite and arsenopyrite. The evidence showed higher surface oxidation at solution pulp pH values in the range of 4-11 for arsenopyrite relative to pyrite. The observed highest ratio of pyrite to arsenopyrite selectivity was 1.7 at collector concentration of 50 g/t and decreased with an increase in collector concentration. Keywords: EDTA extractable iron, selectivity index, differential flotation, grade engineering

Jan 1, 2020

By P. C. Pistorius, D. Kruger, Y. Kacar

Because of its superior properties, stainless steel has been widely used for many applications. Nonmetallic inclusions can influence the quality of stainless steel products. A set of samples was used to track the response of inclusion composition during processing of a heat of titanium-bearing 18% chromium steel, from deoxidation after decarburization, to the solidified slab. The oxide inclusions responded as expected to additions of deoxidizers and calcium treatment, changing from silica to alumina and spinels, and then to calcium aluminates. The samples confirmed that titanium nitride can nucleate on liquid calcium aluminate during steel solidification.

Aug 1, 2021

By D. Marcotte, R. V. Dutaut

In most exploration or mining grade data-sets, the presence of outliers or extreme values represents a significant challenge to mineral resource estimators. The most common practice is to cap the extreme values at a predefined level. A new capping approach is presented that uses QA/QC coarse duplicate data correlation to predict the real data coefficient of variation (i.e., error-free CV). The cap grade is determined such that the capped data has a CV equal to the predicted CV. The robustness of the approach with regard to original core assay length decisions, departure from lognormality, and capping before or after compositing is assessed using simulated data-sets. Real case studies of gold and nickel deposits are used to compare the proposed approach to the methods most widely used in industry. The new approach is simple and objective. It provides a cap grade that is determined automatically, based on predicted CV, and takes into account the quality of the assay procedure as determined by coarse duplicates correlation.

May 1, 2021