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By P. J. H. de Graaf, S. D. N. Wessels

"Rio Tinto’s Western Australian expansion, combined with mining within structurally complex geology and increasingly below the water table, presents challenges in effective slope management to ensure safe and economic mining.The Geotechnical Management System (GMS) was developed by Rio Tinto Iron Ore (RTIO) to manage geotechnical risks identified during the design process and implementation, and to ensure feedback based on the ‘as-found’ conditions. The GMS utilizes a risk-based approach to geotechnical risk management and is centred on the geotechnical risk and hazard assessment management system (GRAHAMS). GRAHAMS is used to assess pre- and post-control risk for future potential risks (planned slopes), current risks (as-built slopes), and actual geotechnical hazards (realized risks) identified in the pit. This serves as a core operational risk management tool in identifying and prioritizing key risk sectors and management of critical controls. The system’s database reporting functionality supports effective communication of operational risks to operational personnel, as well as reporting the risk profile across operations to management.A rigorous engagement process between design engineers and sitebased engineers is implemented to ensure that key design assumptions, limitations, risks, and opportunities are understood by the site teams. This information, together with mine plan schedule details, is used to assess the design risk and develop appropriate controls. These controls typically include slope performance monitoring and slope reconciliation. The design feedback loop is closed through sharing of key slope performance and reconciliation data with the design teams.The GMS has been successfully implemented in RTIO pits and is fundamental to successful geotechnical slope management. Improved characterization of design assumptions has allowed for re-assessment of the pit design and improved hazard management in high-risk pits. The GMS, GRAHAMS, and other processes reduce the incidence of unexpected slope instability. Improved understanding of rock mass conditions has allowed for economic optimization through redesign of slopes, allowing for an improved understanding of risk and fewer unexpected conditions (surprises), hence an increased realized value."

Jan 1, 2016

By V. Oberholzer

The presence of fines (particles smaller than 6 mm in diameter) causes hydrodynamic problems in gasifiers and therefore it is of great importance to minimize the amount of fine coal in the feed. This serves as motivation for understanding coal?s breakage mechanisms, which could lead to the ability to predict the generation of fines. The aim of this project was to simulate the pulsating effect of the conveyor belt in order to investigate factors influencing the breakage. Results indicated that an increased initial particle size had an increasing effect in the amount of fines generated. Weathering had an insignificant effect on the breakage of coal. To conclude, a breakage model was developed to describe the rate of breakage out of the top size when a combination of two breakage modes is present.

Jan 1, 2009

By R. Singh, A. K. Dhawan, M. Dixit, H. Dev

ABSTRACT: The modulus of deformation of rock mass is an important engineering parameter required for the design of foundation of hydraulic structure and to study the interaction of rock mass and the structure at the foundation support. Different equipment and techniques are used to arrive at the design modulus value. Since any error in the estimation of modulus values results in multiplication of its effects in the analysis, it is necessary to know about the reliability of testing equipment and procedures. In the present study modulus values obtained by different in-situ equipment at different project sites have been compared. KURZFASSUNG: Der Verformungsmodul von der Felsenmasse ist technisch ein wichtiger Parameter, den man zur Konstuktion des Grunds fuer die Hydro – Tektonik, benoetigt um auch die gegenseitige Beeinflussung der Felsenmasse und der Tektonik am Traggrund zu betrachten. Verschiedene Geraete und Methoden werden angewandt, um den Ausfuehrungsmodul -Wert zu erreichen. Es ist erforderlich, die Zuverlaessigkeit der Pruefeinrichtung sowie des Verfahrens zu kennen, da irgend ein Fehler in der Abschaetzung von Modulwerten in der Analyse zu einer Vervielfachung ihrer Einwirkung fuehrt. In der vorligenden Arbeit werden die Modulwerte gewonnen aus unterschiedlichen Einrichtungen an Ort und Stelle and verschiedenen Projekt -Stellen mit einander verglichen. SOMMAIRE: Le module de deformation d’une roche est un parametre important pour la conception et realisation des ouvrages hydrauliques ainsi que pour etudier l’interaction de la roche et de la structure d’appuis de base. De divers equipments et techniques sont employes pour determiner la valeur de ce module de conception. Puisque l’effet d’une erreur d’evaluation du module devient multiplie dans l’analyse, il est necessaire de savoir la fiabilite des equipments et des methods qu’on ulilise. Dans cette etude, on a compare les valeurs des modules obtenues en employant les equipments in-situ aux sites differents de projets.

Jan 1, 2003

By C. Steyn, J. D. le Roux

A dynamic model is used to represent the single-stage closed grinding mill circuit at Mogalakwena North Concentrator. The circuit consists of a ball mill closed by a hydrocyclone. The circuit is modelled according to a semi-mechanistic non-linear dynamic model available in literature. An algebraic routine is used to fit model parameters to steady-state process data. Preliminary validation results against dynamic data indicate that the model is capable of capturing the main dynamic trends of the plant. Since classical system identification techniques proved insufficient to produce accurate models; the non-linear model can be used as a reliable source for model-predictive controller design. Keywords: Grinding, modelling, process control, parameter estimation

Jan 1, 2020

By Richard F. Link, Jr. Koch

"A mathematical simulation model has been devised to guide the layout of surface or underground mine workings, drill stations, and drill holes that are established in order to search for tabular ore bodies. The ore bodies may be contained within veins, sedimentary beds (including reefs), or other tabular structures.Programmed for a time-shared digital computer, the model contains both stochastic and deterministic variables. Stochastic or natural variables include the number of ore shoots and their sizes, orientations, locations and values. Deterministic or controllable variables include (i) locations and costs of workings (for underground exploration); (ii) drill station locations and costs; and (iii) drill hole azimuths, inclinations, lengths and deflections (if any).For various assumptions about the natural variables, the model is run while the controllable variables arc changed deliberately. Thus, layouts are devised to determine the percentages of the total number of assumed ore shoots found at different costs. In order to choose among the various layouts, cost-effectiveness measures are calculated."

Jan 1, 2014

By J. Sjöberg, T. Savilahti, S. B. Umar

"Sublevel caving in Malmberget mine results in mining-induced surface deformation. One of the currently mined orebodies is the Printzsköld orebody. As mining deepens there is need to assess the behaviour of the cave formed in the subsurface above this orebody. Numerical analysis was used to assess the effects of extraction to deeper levels and perform strength parametric studies. Stress redistribution was studied, and the results showed high stress buildups in the hangingwall and the crown pillar. Two failure mechanisms have been identified – shear and tensile. Reducing cohesion by 50% increased the area of the yielded zone by more than 100% in the hangingwall.IntroductionThe Malmberget mine is owned and operated by the Luossavaara-Kiirunavaara AB (LKAB) mining company. Iron ore is extracted by large-scale sublevel caving. The mine comprises a total of 20 orebodies, about 10 of which are in production today (Figure 1). The mine is located in the municipality of Gallivare, about 100 km north of the Arctic Circle (Figure 2).Successful sublevel caving requires progressive caving of the orebody after initial blasting. This results in caving of the hangingwall, sometimes all the way to surface, resulting in surface deformation. As mining progresses to deeper levels a larger area is affected by deformation. Over the years, extraction from the Malmberget orebodies has led to deformation of the ground surface, affecting residential areas and existing infrastructure.Forecasting the caving process is not straightforward as it can be rapid or slow, depending on the rock mass conditions, stress conditions, the failure mechanisms at work, etc. Moreover, several of the orebodies in Malmberget are non-daylighting, which makes reliable caving analysis even more difficult, primarily since there is less available experience from such cases. The present study was designed to improve the understanding of the caving and deformation mechanisms at Malmberget, and in particularly for the Printzskold orebody"

Jan 1, 2017

By P. K. Hofmeyr

Traditional fire assay dates back over 3000 years and has changed very little over that time. The only improvement is to replace the gravimetric finish with dissolution of the Precious Metal bead followed by AA or ICP analysis of the solution. The newly developed FIP A (Fast In-line Fire Assay) method allows full automation of the fire assay process from sample preparation to spark analysis of the Pb button. This results in fully quantitative analyses for Pt, Pd, Rh, Ru, lr, Au and Ag in typically less than an hour after a sample is entered into the system. Detection limits are theoretically Pt 0.08 ppm, Pd 0.002 ppm, Rh 0.002 ppm, Au 0.08 ppm and Ag 0.002 ppm but in practice the lower measurable limits are about double these figures. Few opportunities have been available to present data obtained using the FIFA system as all FIFA laboratories have been in the domain of a Pt mining company which prefers to keep all Pt analytical matters confidential. However, IMP has recently participated in the round robin exercise to establish recommended values for a new series of Merensky Reef and UO-2 Layer reference materials produced by African Mineral Standards. The precision of the results was excellent being on average Pt 2.05%, Pd 1.25%, Rh 4.08% and Ru 4.94% being expressed as Relative Standard Deviation. The excellent precision is a reflection of the efficient collection of POEs in the Pb buttons and the homogeneity of the Pb buttons. However, the accuracy was not as good. The poorer accuracy is interpreted as the calibration of the spectrometer not being as good as desired due to the difficulty in acquiring a suitable range of standards with reliable recommended values for the PGEs. The most recent spectrometer was calibrated with the greatest care and produced slightly better results for Pt, Pd and Rh and slightly worse for Ru.

Jan 1, 2014

By J-N. Oyourou, R. McCrindle, C. J. S. Fourie

"Many mines in South Africa were inappropriately closed and left unattended during the last century. These old mines are potential sources of environmental pollution and may pose a health risk to local populations, since the surrounds contain elevated levels of toxic elements. Soil from the old Edendale lead mine property in Mamelodi Extension 11, east of Pretoria, which was suspected to be contaminated with lead, was analysed. The mine, which primarily extracted galena, was decommissioned in 1938. During this study, the old mine property and surrounds were screened for zinc and lead using a field-portable X-ray fluorescence (pXRF) spectrometer. The metal concentrations, which ranged from 18 to 7 300 mg/kg for zinc and from 50 to 21 000 mg/kg, for lead, were plotted together with the GPS coordinates to produce a concentration distribution map for lead and zinc. This map revealed three anomalies of unacceptably high concentrations, possibly corresponding to areas where ore had been piled or dumped to waste from the old mine. Thirty-six of the soil samples that were analysed by pXRF on site were selected and analysed in the laboratory using inductively coupled plasmaoptical emission spectrometry (ICP-OES) for verification purposes. The zinc and lead concentrations obtained from the two analytical methods were compared using linear regression analysis. Excellent correlation was obtained between the results from the two methods (r2 = 0.99 for zinc and r2 = 0.95 for lead). IntroductionEarly economic development in South Africa was based mainly on mining. However, these activities left a legacy of approximately 6 000 improperly closed mines scattered throughout the country (SAI, 2009; van Schie, 2012). Due to their proximity to settlements, these abandoned mines may pose a potential health risk to humans and an environmental hazard. Mining activities generate large amounts of waste, mostly in the form of overburden and process tailings, which often contain high concentrations of toxic elements. Bioavailable toxic elements can contaminate crops growing in the polluted area (Kala, 2010; Marwa, Meharg, and Rice, 2012) or eventually migrate and detrimentally affect the groundwater (Rösner and van Schalkwyk, 2000). Moreover, sulfides accumulated in mine waste generate acid minewater (Rösner and van Schalkwyk 2000). Unfortunately, owners of mines, closed before the promulgation of the Minerals Act more than twenty years ago (Act 50 of 1991), avoided the compulsory rehabilitation of the environment enforced by this legislation. Toxic elements, such as lead, which were confined within ores, may become exposed through mining and are therefore more easily mobilized within the environment. Elements essential to human and plant metabolism, such as zinc, when exposed by mining activities, may become hazardous due to elevated concentrations (Aslibekan and Moles, 2003; Wuana and Okiemen, 2011). Humans exposed to potentially toxic metals may experience harmful effects as discussed elsewhere (Nriagu and Pacynar, 1988; Wayne and Ming-Ho, 2005)."

Jan 1, 2019

By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluoridesl.2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02?SiO2) with the ammonium acid fluoride (NH4F?XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo-dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012

By R. J. Durrheim, B. Manzunzu, V. Midzi

Selecting ground motion prediction models (GMPM) is crucial in assessing seismic hazard levels in a specific region. This study investigates the influence of ground motion model (GMM) selection on seismic hazard assessment in Johannesburg, South Africa. Most seismic events affecting Johannesburg are related to mining activities and water ingress into the underground mine voids. The most seismically active regions in South Africa include areas around Klerksdorp, Welkom, and Carletonville. These regions experience a significant number of earthquakes, with mining activities being a major factor contributing to seismic events. Ten ground motion prediction equations were selected from regions of similar tectonics setting and were assessed to see if they correspond to the available local data. Six of these were also compared to the ground motions produced by the earthquake of 14 August 2014, which occurred in the Orkney area, one of the mining areas in South Africa. Sensitivity analyses were also carried out to assess the influence of ground motion prediction equations (GMPE) on the seismic hazard of Johannesburg. The results indicate that the choice of GMPM significantly affects the estimation of seismic hazard levels in Johannesburg. Different GMM can lead to varying ground shaking intensity predictions, impacting risk assessments and engineering design considerations. The findings highlight the importance of carefully selecting appropriate GMM tailored to Johannesburg’s specific geological and tectonic characteristics. Understanding how different models perform in this region is essential for accurate seismic risk mitigation strategies.

Jan 12, 2025

By R. G. B. Pickering

Successful management of mining operations depend on the accurate and reliable measurement of performance as a monitoring instrument in a feedback and control loop. However, when changes are being considered, the probable effect of the change on bottom line results requires different measuring techniques incorporating an in depth understanding which can identify hot spots in the operation which exhibit strong sensitivity to change. The CSIR's Division of Mining Technology has therefore been devoting a considerable effort to the establishment of techniques which enable changes to be analysed in terms of their impact on the two key parameters describing mine performance, i.e. profitability and safety. This paper describes these techniques, outlines their application to some example situations and discusses planned enhancements. The first section of the paper addresses the profitability model, and this is followed by a section considering the mine safety model.

Jan 1, 1996

By N. Naudé, J. de Villiers, C. P. Bergmann

It is proposed that the physical and chemical composition of individual mineral particles are an appropriate basis from which to model the performance of minerals processing equipment. Such a particle-based approach enables modelling across disciplines such as comminution, classification and flotation and automatically generates the traditional mass and chemistry balances. The general approach followed is to generate full grade-recovery curves for a separator by sampling product and tailings at varying mass yields. AutoSEM characterisation of each sample provides particle data that is used to reconcile mineral deportment and liberation to the measured size and assay data. In this way, partition surfaces can be generated and modelled. In this paper, an empirical model for the performance of a gravity spiral concentrator treating fine chromite ore is proposed. The model is based on the combination of two partition surfaces and is able to accommodate both forward and reverse gravity concentration effects per size fraction. The results show that this approach is well suited to represent spiral performance for the cases evaluated. The effect of two feed particle size distributions on the performance of the Multotec SC21 and SC25 spirals is demonstrated. Simulations are run in an Excel environment, linked to Python-enabled routines for enhanced data management and calculation speed. Keywords: Spiral concentrator, gravity separation, particle-based modelling

Jan 1, 2020

By J. C. Barry, J. H. van Laar, P. L. Crouse, H. Bissett, I. J. van der Walt

"Plasma-assisted spheroidisation of metal powders offers several technical advantages with respect to both the ease of materials handling and powder-metallurgical item manufacturing. Advantages include improved flowability, increased powder packing density, elimination of internal component cavities and fractures, changes in morphology resulting in decreased friction between particles and contamination during pneumatic transport and enhanced particle purity. In this empirical study, spherical iron particles were produced using a microwave plasma operating at atmospheric pressure and characterized using optical microscopy and SEM techniques. Iron powders were fed into the system at fixed operating conditions, resulting in particles with spherical structures. The theoretical estimate of the time required for melting to occur is 1.6 ms, an order of magnitude smaller than the actual residence time. IntroductionParticle design and functionalization has become an increasingly popular aspect of materials synthesis and powder-metallurgical item manufacturing. One such technique involves the spheroidisation and densification of feed materials, typically in the form of chemical powders with wide particle size distributions. The major benefits of powder spheroidisation include improved powder flowability, increased powder packing density and powder purity, reductions in internal voids and defects, as well as the ability to manipulate the particles surface morphologies (Boulos, 2004). Thermal plasma processing has the potential for scale-up and for producing industrial quantities of spheroidised powder.Thermal plasma technologies offer a wide spectrum of material synthesis and treatment options, amongst others the synthesis and spheroidisation of nano-sized ceramic and metal particles (Kumar and Selvarajan, 2006). The spheroidisation process occurs within the plasma discharge via in-flight heating and melting of the powder feed material, given high enough plasma temperatures (Fridman, 2008, p. 495). Surface tension in the molten droplets results in spherical, or nearly, spherical, powder particles being formed upon exiting the plasma discharge where the droplet undergoes rapid cooling and freezes. Quite often, the bulk density of these spherical particles is higher than that of the starting material (Boulos, Fauchais and Pfender, 2013, p. 42). The different plasma spheroidisation techniques reported include radio frequency (RF) induction thermal plasmas (Jiang and Boulos, 2006; Karoly and Szepvolgyi, 2005; Yuming, Junjie and Yanwei, 2013), nontransferred direct current (DC) thermal plasmas (Chaturvedi et al., 2014; Kumar and Selvarajan, 2008; Suresh, Selvarajan and Vijay., 2008) and microwave-assisted plasma processing methods (Chen, Gleiman and Phillips, 2001; Vanamu et al., 2004; Weigle et al., 2004)"

Jan 1, 2016

By B. Larsen

The Søderberg electrode was invented about 95 years ago by the company Elektrokjemisk, later known as ELKEM. It is still the most commonly used electrode system in submerged-arc furnaces for ferroalloys, platinum smelting, and slag cleaning operations. The size of the furnaces and electrodes has increased over the years and electrode diameters up to 2000 mm are today in use. Such large electrodes can be challenging to manage, and large electrodes are also more demanding when it comes to the electrode paste used in the electrodes. Although electrode sizes and equipment around the electrodes have changed, the main principles of the Søderberg electrode processes are the same. To assists in proper understanding of the electrode processes and to optimize electrode management, Elkem has developed several mathematical tools covering various aspect of the process. Both temperatures and thermal stresses can be calculated during dynamic conditions. The paper demonstrates, with examples, how the tools are used in both education and as practical input to improved electrode performance.

Jan 1, 2012

By A. G. Journel, CH. Huijbregts

"Centre de Morphologie MathématiqueSpecial problems arise in the evaluation of lateritic-type orebodies (Ni-Co, bauxite) or, more generally, orebodies affected by surface weathering. In this type of orebody, the vertical grade distribution shows, from the hangingwall downwards, a systematic increase followed sometimes by a certain decrease, or vice-versa. These trends appear together with irregular variations from one drill bole to the other.The problem is to characterize a vertical structure that is representative not only of the drill hole but of an entire panel or zone of influence, in order to define mineable thicknesses for given cut-off grades. The vertical grade distribution observed on the drillhole is replaced by a new curve, called 'derive' (drift), which is computed by 'universal kriging'.Once the vertical study is completed, new 'service-variables' are defined in the horizontal plane, such as mineable thickness and the corresponding average grade, economical functions (combination of the grades of several minerals). The local and global estimation of these variables can then be performed by a simple bi-dimensional kriging plan. The global estimation is summed up by several tonnage-cut-off grade curves.The practical valuation according to the above scheme of a New Caledonian lateritic nickel orebody is presented."

Jan 1, 2014

Plurigaussian simulation allows constructing lithofacies or rock type models that reproduce the contacts between facies in accordance with the geologist?s interpretation. Its implementation requires inferring the local facies proportions, but the uncertainty in the true proportions is not accounted for. The simpler model with constant facies proportions may not yield realistic results, due to the possibility of obtaining facies at locations where it is geologically unlikely to find them. This article presents a variation of the plurigaussian model, in which the facies proportions are represented by random fields. The realizations can be made conditional to soft geological informati onto account for local changes in the facies proportions. The model is illustrated via a case study of a porphyry copper deposit where four Gaussian random fields are simulated conditionally to drill hole data and to constraints on the probability of finding a given facies at specific locations (control points) in the deposit. Then the first two fields are truncated using the random thresholds defined by the last two, generating a three-facies model. The proposed random proportion model proves to be simple to use and to account for spatial variations of the geological characteristics and for the uncertainty in the facies proportions. Keywords: categorical variable; lithofacies; truncated plurigaussian simulation; regionalized proportions

Jan 1, 2008

By А. V. Aksenov, S. G. Rybkin, А. Y. Senchenko

For gold plants in Russia, it is very complicated and costly to use cyanide leaching for efficient processing of gold refractory ores, where gold is closely associated with sulphide minerals and the significant amount of natural carbonaceous matter present. Oxidative roasting of gold refractory concentrates is a well-known method, making it possible to obtain a high recovery rate of precious metals to a target product. The use of oxidative roasting is limited in general by the expense of capturing and neutralising the harmful components of roasted gas, mainly sulphur (SO2, SO3) and arsenic (As2O3) oxides. This paper addresses testing and development of an optimised technology to process gold refractory gravity and flotation concentrates by means of oxidative roasting which stabilises arsenic as calcium arsenate. The process involves roasting of a gravity or flotation refractory ore concentrate in a mixture with lime and calcium chloride, with a supply of oxygen, and at 600-700°С. During the roasting a carbonaceous matter of the concentrate burns out and sulphide components transform into harmless calcium sulphate (CaSO4) and calcium arsenate (Ca3(AsO4)2), and iron passes into the form of hematite (Fe2O3). After disintegration, the roasting cinder is concentrated on a table to obtain a high-grade gravity concentrate and gravity tailings. The high-grade gravity concentrate is subject to smelting in a mixture with fluxing agents, which results in alloyed gold and slag. The gravity tailings are ground and reported to cyanide leaching. In the case of a flotation concentrate, the roast cinder is ground to minus 30 μm and subject to sorption cyanide leaching. High gold recovery (90-95%) of the target product and environmental safety are typical of the improved technology under consideration. Two national patents were granted for the methods developed to treat refractory concentrates bearing precious metals. Keywords: Gold concentrates, oxidative roasting, cinder, cyanide leaching, smelting, alloyed gold

Jan 1, 2020

By V. Jokovic

Hydrocyclones are the most commonly used classifiers in the mining industry. The reason for this is their low operating cost and a small footprint. Data from plant trials where screens replaced hydrocyclones indicated that lower bypass of fines and sharper separation could improve breakage rates, with a positive effect on flotation circuit performance throughput. Despite the importance of classification, hydrocyclones have not received as much attention as more expensive comminution units, and their technological progress has been incremental. Noticeable water split (Rf) reductions of a semi-inverted hydrocyclone have been reported in the past. According to theory, the hydrocyclone with reduced Rf will improve classification of fines. A classification study using semi-inverted hydrocyclones was conducted to determine if a hydrocyclone could be operated in a way that would minimise misclassified fines. The classification performance of a semi-inverted hydrocyclone will be presented in this paper and other potential applications will be discussed. Keywords: Semi-inverted hydrocyclone, water split, misclassification of fines

Jan 1, 2020

By B. Amankwaa-Kyeremeh, W. Skinner, R. K. Asamoah, C. Greet

With the continuous increase in ore mineralogical complexity coupled with decreasing head grades, there is a need for mining industries to process large tonnages of material to meet global metal demands. Smarter, cheaper techniques are required to better map ore mineralogical variations proceeding to pre-concentration (flotation) stages for higher performance and metal recoveries. This paper is aimed at briefly reviewing previous studies on different selected ore mineralogy, with the focus on their pulp chemistry, to identify relationships which aid quicker flotation feed variation monitoring. Very little published work exists linking pulp chemistry parameters to flotation feed mineralogical variation. A successful application implies maximising grades at higher metal recoveries and reducing the cost of reagent for a better performing flotation circuit. Keywords: Mineralogical variation, flotation, pulp chemistry

Jan 1, 2020

By J. Petersen, K. Shaik

The traditional route utilised for the recovery of Platinum Group Minerals (PGMs) in South Africa involves the concentration of ore by flotation, followed by smelting to produce a PGM rich matte, which is then digested hydrometallurgically to solubilise base metals and Platinum Group Elements (PGE). HCl/Cl2 is conventionally used for PGE dissolution from concentrated material, which is an aggressive reagent associated with high maintenance costs as well as environmental concerns. Of interest is the leaching of PGMs directly from mineral ores, low grade concentrates and tailings in a cyanide-ferricyanide system as a more sustainable alternative. This system has shown favourable Pt recoveries among the Pt minerals, but with sperrylite (PtAs2) displaying highly refractory behaviour. The dissolution of sperrylite is investigated in a cyanide-ferricyanide system in the context of an electrochemical study involving OCP, chrono-amperometry and cyclic voltammetry. This approach allows the assessment of leaching characteristics as well as the investigation of surface passivation, which is believed to contribute to poor Pt recoveries. Some evidence is presented that such passivation is related to the formation of arsenide species on the mineral surface. Keywords: Sperrylite, PGMs, cyanide, ferricyanide, electrochemistry

Jan 1, 2020