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By M. J. Spendlove

A progress report is presented on a research program in which an attempt was made to develop a practical sulfide-volatilization process for recovering tin from low-grade Bolivian ores. Shaft-furnace designs and operating techniques were studied in a series of experiments in which the objective was to sulfidize cassiterite to stannous sulfide, remove the stannous sulfide by volatilization, reconvert the stannous sulfide to stannous oxide, and collect the resulting fume. A shaft furnace was developed and operated in a final test in which many of the previous difficulties were surmounted. Since the supporting funds were exhausted at this point, the project was discontinued; recommendations for further improvements in furnace design and operation were made on the basis of interpretation of experimental results obtained in shaft-furnace experiments and other related studies.

Jan 1, 1955

By W. C. Holliman

This report on the characteristics of commercial aviation gasolines is one of a series of such reports. It presents compilations of' inspection data furnished on their products by 15 manufacturers of commercial grades of aviation gasoline and special data obtained in Bureau of Mines laboratories on 68 samples of these gasolines. Data are presented for 18 samples of grade 80, 20 of grade 91/98, 21 of grade100/130, and 9 of grade 115/145 aviation fuels. The gasolines are designated January 1948 production, although some of the samples actually were produced at a later date.

Jan 1, 1948

By M. M. Wong

Electrolysis of titanium carbide and a material consisting of titanium, carbon, nitrogen, and oxygen as soluble anodes in Used electrolytes was investigated by the Bureau of Mines for the preparation of crude titanium metal. Tests made in all-chloride electrolytes showed only a low recovery of titanium as well as a substantial volatilization of titanium trichloride (TiC13) when present in the electrolyte. Electrolysis at 750° to 850° C in a mixture containing 85 percent NaC1-15 percent potassium floutitanate (K2TiF6) yielded as high as 91 percent recovery of titanium from titanium carbide and 62 percent recovery of titanium from the titanium-carbon-nitrogen-oxygen material. Problems associated with the preparation of crude metal by fused-salt electrolysis are discussed. The crude metals produced from both anode materials were electrorefined in a sodium chloride-titanium chloride (NaCl-TiC12) electrolyte, and ductile titanium metal was obtained.

Jan 1, 1963

By T. Kessler

As part of a respirable mine-dust research program at the U.S. Bureau of Mines, spark-source mass spectrometry has been used for the semiquantitative determination of trace elements (200 ppm weight or less) in raw coals. In addition, several minor and major elements have been determined using this technique. Sixty-four elements ranging in concentration from 0.01 to 41,000 ppm weight were determined in one anthracite, two mvb, four lvb, and six hvab raw coal samples. The samples represented 10 coal seams located in Pennsylvania, West Virginia, Virginia, Utah, and Colorado.

Jan 1, 1973

By C. A. Komar

The Bureau of Mines conducted experiments on one synthetic and three natural sandstone samples to investigate the effects of acoustic energy on the flow of brine in porous media. Ultrasonic energy at a frequency of 20 kc per second and an intensity of 55 watts per cm2 was irradiated in the direction of the fluid flow and in the opposite direction for distances of 1/2 and 2 inches between the vibrating device and the sample face and under conditions of suppressed and nonsuppressed cavitation. Forty tests were conducted: 32 with a pressure differential of 0.64 psi across the samples, 2 with 5 psi, and 6 with 15 psi. Acoustic waves altered the rate of flow of the brine through the samples, but this effect was observed only at low differential pressures and from a practical point of view was insignificant. As a result of irradiation, however, the samples exhibited reduced permeability. This reduction was probably caused by the shifting of solid particles dislodged by the acoustic waves.

Jan 1, 1967

By E. B. Kester

In the commercial evaluation of coal tars, a distillation analysis properly carried out is of considerable importance. Close attention must be given to this operation in order to obtain consistent results and to secure the minimum decomposition of the tar compounds, which in many cases are sensitive to undue heat effects. Low-temperature tars in particular contain compounds of this nature, while in the case of tars produced at high temperatures the large proportion of pitch present has an adverse influence during a distillation. If excessive cracking takes place, the composition of the distillate will naturally vary from the normal, with the result that all the analytical criteria subsequently obtained are affected. Where tars, produced over vide ranges of carbonization temperatures are investigated as in the survey of gas, coke, and by-product making properties of American coals nor being conducted at the United States Bureau of Mines Pittsburgh Experiment Station, the method of distillation must necessarily be the sane for all of the tars studied. Also, it must function equally well for both low and high temperature tar, permit accurate fractionation, and reduce adventitious decomposition to a minimum.

Jan 1, 1932

By M. R. Geer, H. F. Yancey

Fuel requirements of the Pacific Northwest have been increased greatly by the war . To the normal peacetime demands for fuel have been added the requirements of new industrial and metallurgical plants engaged in war production , the increased demand arising from expansion of existing industrial establishments , increased amounts of railroad fuel required to handle wartime traffic , and increased quantities of domestic fuel required by the influx of war workers . In the face of these augmented demands for fuel shipments of fuel oil have been curtailed , wood fuel which normally is an important factor in both industrial and domestic markets of the area is less abundant , and the production of coal in Washington has decreased sharply . The fuel requirements of the region have been met so far by shipping large tonnages of coal into the Pacific Northwest from Utah , Wyoming , Montana , and Colorado ; the quantity received from these States and Canada in 1943 amounted to 2,688,9124/ tons , 175 percent of the Washington production . or The proximity of the Washington coal mines to large centers of war production has resulted in widespread migration of miners to employment in shipyards and aircraft plants ; the ensuing shortage of miners largely accounts for the decreased production of coal in the State . Hence , strip mining , which requires relatively few workers and a shorter time for development , offers an attractive means of alleviating the local coal shortage and obviating the necessity of shipping coal from the producing areas of the Rocky Mountain States to the Pacific.coast . So urgent has been the necessity for augmenting local coal production that any coal property that promises to be amenable to strip mining , even though the coal may be inferior in quality , has warranted examination . Even low- grade coals that cannot compete in the normal market can be used locally , thus releasing better coals for shipment to critical centers. of consumption ... One such deposit of low- rank fuel examined by the Bureau of Mines is in western Lewis County , about 9 miles east of Toledo , Wash . The coal is lignitic and on the as - received basis has a heating value of 6,000 to 6,500 B.t.u. per pound . The property is of interest primarily because the physical conditions favor operation by stripping and offer opportunities for low- cost production with very low manpower requirement .

Jan 1, 1945

By Robert M. Becker

The evaluation of existing rock stresses from measurements of the change in diameter of a borehole that is stress relieved by overcoring has become a common practice, The stress evaluation has been generally based ,on isotropic relations whereas rock in varying degrees is anisotropic. A plane elasticity solution for a circular hole along one axis of an orthotropic medium is adapted for evaluation of in situ stress from borehole deformation measurements. A consistent triaxial testing approach for determining elastic properties of the overcore is also outlined. Comparison of isotropic with anisotropic interpretations of the state of stress show that large errors in evaluation may occur if the anisotropic character of the rock is neglected.

Jan 1, 1967

By Eliot J. White

The Bureau of Mines tested cores from 35 wells from 14 oil-producing zones in southern Illinois, southern Indiana, and western Kentucky to determine why rates of water injection were apparently low in some zones. Since these zones contain only minor amounts of clay minerals, it is concluded that permeability reduction results from movement of dislodged silica particles and other material, including the clays, that lines the pores. Both single-phase and two-phase permeability measurements, however, indicated that most samples had only low to moderate water sensitivity, so that permeability reduction due to such particle movement should usually not be of practical significance. The effective permeability to water was considerably lower than the effective permeability to oil during two-phase flow measurements, as is typical of most reservoir rocks. It can be concluded, therefore, that relatively high injection pressures will be required in waterflooding thin zones or zones having low permeabilities.

Jan 1, 1966

By J. M. Mutmansky, L. Xu

"IntroductionSince the establishment of the star,just concentration of 2 mg/m3, a strong effort has made by mining engineers and researchers to provide better dust control equipment and procedures for underground coal mines.Particular areas of success have been implementation of better coal-cutting strategy to control dust generation, better design of water sprays for dust suppression and air movement, use of scrubbers, and improved design of face ventilation systems. A drastic improvement occurred over time such that the average dust concentrations for continuous miner operators dropped from 6.5 mg/m3 in 1968 to 1.3 mg/m3 in 1980 and for auger, cutter, longwall, and roof bolter occupations from 2.7 mg/m3 in 1973 to 1.6 mg/m3 in 1980 (Niewiadomski, 1983).While dust concentrations in mining sections have been dropping considerably, one problem area has been mining sections where quartz is a considerable portion of the airborne dust. The federal regulations require that quartz content must be held below 0.1 mg/m3 in the air regardless of the concentration of the total dust. This legislation limits the allowable dust concentration to a ""reduced standard"" of 10/ (% quartz) when the quartz content of respirable dust in the mine atmosphere is more than 5%. Today, approximately one-third of underground coal mining operations have designated areas with more stringent dust standards in place, and many mines experience considerable difficulty in meeting these standards (Jankowski, and Babbitt, 1989).It is well known that metal miners subjected to respirable dusts high in quartz have a higher incidence of silicosis than those exposed to dust low in quartz. However, the role of quartz in the development of coal workers' pneumoconiosis is still a highly controversial question, in spite of the large number of research projects devoted to this subject over the last 20 years. Because coal seams contain less quartz than metal ores and quartz often comes from sources outside the coal seam (e.g., roof and floor), it is difficult to relate studies that deal with the quartz content in coal seams and the incidence of coal workers' pneumoconiosis. Hamilton, Ogden, and Vincent (1983) have provided a plausible explanation for the incidence of the disease by hypothesizing that the quartz content does not affect the probability of developing pneumoconiosis until some threshold value (generally thought to be about 10%) is exceeded.The objective of the research studies summarized here was to obtain a better understanding of quartz occurrences in airborne coal mine dust by studying the variations of the quartz levels in different dust sizes and the relationship between the quartz content in airborne coal mine dust and the quartz content in the mined material. The implications of the results to control of dust in high-quartz sections will also be discussed."

Mar 1, 1992

By J. G. Kirby, F. S. LOTT

The mmber of petroleum refineries in the United States decreased during 1949 from 375 to 367 while the total crude-oil charging capacity of refineries continued to increase. A gain in the through-put capacity of 257,305 barrels daily raised the total to a new high level 6,696,300 as of January 1, 1950. The capacity of the average refinery to process crude-oil increased during 1949 from 17,171 barrels daily to 18,246. The four coastal refinery districts accounted for 178,900 barrels or 70 percent of the total capacity increase and the Illinois-Indiana- Kentucky district 57,950 barrels, or 23 percent. Slight declines in capacity were reported in the Texas Inland and the Arkansas-Louisiana Inland districts. The capacity building on January 1, 1950, 145,600 barrels daily, was less than half the amount under construction a year earlier. Most of the new construction involved enlargement of existing refineries and was confined to the East Coast and Indiana-Illinois-Kentucky districts. Two new refineries, however, were under construction, one in Oklahoma and the other in Texas. The shut-down capacity increased for the first time since 1946, and the 473,302 barrels daily reported on January 1, 1950, was the largest recorded since January 1, 1938. The only refining district showing a decline in the shut-down capacity was the Appalachian No. 2 district. The largest increases were reported in the Texas Gulf, Indiana-Illinois- Kentucky, California, and East Coast districts. The operating ratio of the petroleum refining industry, as indicated by dividing the January 1950 runs to stills of 5,483,000 barrels daily by the total installed capacity January 1, 1950, was 81.9 percent, compared with a ratio of 87.8 percent at the beginning of 1949.

Aug 1, 1950

By K. J. Miller

A two-stage froth flotation technique was developed in the laboratory to separate fine-size pyrite from coal. The process consists of the initial flotation of a 15-percent solids coal slurry with a minimum of frother; the coarse, free pyrite and other refuse are removed in the tailings. The froth product from this first stage is then repulped and treated with a coal depressant, a pyrite promoter, and a frother to float the remaining fine-size pyrite or pyrite attached to coal particles. With the two-stage process, the pyritic sulfur content of a Lower Freeport bed coal sample was reduced from 1.78 percent to 0.75 percent in the first stage, and from 0.75 percent to 0.27 percent in the second stage with good clean coal recovery.

Jan 1, 1972

By R. V. Ramani, J. Qin, R. A. Jankowski

"Longwall mining is generally recognized as safer, more productive and economic when compared to room and pillar underground coal mining. There has been, however, increasing concern for the control of airborne coal dust concentrations in long wall faces. The airborne dust cloud at a longwall face is a complex aerosol system containing particles of varied size, density, shape and state of aggregation. For the development of more effective dust control practices in longwall faces, it is necessary to understand more clearly the characteristics of the longwall dust cloud.In this paper, results of a research study on dust concentration distributions along longwall faces are presented. The objective of this study is to characterize the longwall dust cloud behaviour and provide necessary fundamental data for a better understanding of the longwall dust problem. MSA personal samplers and gravimetric total dust samplers were employed to collect respirable and total airborne dust samples. The size distribution of these samples was determined by MicroTrac SPA. The instantaneous respirable airborne dust concentrations were recorded using RAM-I. The dust concentrations are related to face operations, particularly the shearer location and activities. The size distribution of airborne dust, instantaneous respirable airborne dust concentration, and air quantity distributions along longw all faces reveal a complex dust flow phenomenon. Additional fundamental studies are needed for characterizing the temporal and spatial behaviour of the dust cloud at longwall faces.IntroductionModern mechanized longwall mining was introduced in the United States in the 1960's and has become more common in the last twenty years. United States longwalls are multiple-entry retreating faces. According to a recent survey, 91 of the 102 longwall faces employ double-drum shearers (1). Several recently installed longwall faces have consistently produced over 4 000 to 5 000 tons per shift over extended periods of operation. The trend in under-ground coal mining in the U.S. certainly is toward the introduction of longwalls. This trend is true not only for new mines but also for renovation of existing mines. While longwall mining has many advantages over other mining methods, including improved safety, such as higher pro-duction. greater productivity and enhanced reserve recov-ery, it is associated with severe problems of dust control. The increase in longwall production has been accompanied by an increase in respirable dust problems which limit realizing the full potential of the longwall mining system. Despite the efforts to develop improved equipment and operational procedures to control the dust levels at longwall faces, it is still difficult to bring several double-drum shearer operations into compliance with the Federal stand¬ards of 2,0 mg/m 3 respirable dust without loss of produc¬tion. In fiscal year 1987, fifty-eight of the longwall sections were found to be in non-compliance once, and an additional 31 were cited two or more times'''. If the full potential of the longwall mining method is to be realized, new measures must be implemented to control the dust concentration to mandated levels. There is a need for detailed and extensive sampling of longwall faces to understand the dust source-sink relationships and the transient ambient concentrations. These must be related to the mining activities on the face. This paper is to characterize the longwall dust cloud behavior through a series of experiments in operating faces and provide necessary fundamental data for further studies to develop improved dust control practices."

Mar 1, 1992

By Nicholas Kyriazi

A joint effort by the U.S. Bureau of Mines (USBM) and the U.S. Mine Safety and Health Administration (MSHA) was undertaken to determine how well self-contained self-rescuers (SCSR's), deployed in accordance with Federal regulations (30 CPR 75.1714), held up in the underground environment with regard to both physical damage and aging. This report presents findings regarding laboratory-tested SCSR's in the fourth phase of testing from 1989 to 1993. The SCSR's were tested on human subjects and on a breathing and metabolic simulator (BMS). These results indicate that most of the apparatus, if they pass their inspection criteria, perform as expected except units with manufacturing defects. However, when the apparatus are carried in and out of the mine daily and stored at the working section, they may suffer abuse. Physical signs of abuse, unless extremely obvious, are frequently not detected by the miners or mine operators. In addition, some apparatus collected for this study had not been returned to the manufacturer in a recall effort for correction of a manufacturing defect. In both cases, the apparatus would have presented problems in emergency use. Recommendations include improved training in inspection procedures and better enforcement of recall notices.

Jan 1, 2010

By X. C. Shi

Bacterial mutagenicity and mammalian cell chromosomal and DNA damage in vitro assays were performed on a diesel exhaust particulate material (DPM) standard in two preparations: as an organic solvent extract, and as an aqueous dispersion in a simulated pulmonary surfactant. U.S. National Institute for Standards and Technology DPM SRM 2975 expressed mutagenic activity in the Salmonella reversion assay, and for in vitro genotoxicity to mammalian cells as micronucleus induction and as DNA damage in both preparations: as an acetone extract of the DPM mixed into dimethylsulfoxide, and as a mixture of whole DPM in a dispersion of dipalmitoyl phosphatidyl choline. Dispersion in surfactant was used to model the conditioning of DPM depositing on the deep respiratory airways of the lung. DPM solid residue after acetone extraction was inactive when assayed as a surfactant dispersion in the micronucleus induction assay, as was surfactant dispersion of a respirable particulate carbon black. In general, a given mass of the DPM in surfactant dispersion expressed greater activity than the solvent extract of an equal mass of DPM.

Jan 1, 2009

By L. A. Haas

Hydrogen sulfide was decomposed to elemental sulfur in an electrical discharge. With He, N., or Ar diluents, a threshold voltage between 1 and 3 kV was required for the decomposition reaction to occur in a laboratory ozonizer. Above the threshold voltage, the HAS decomposition rate increased with increasing voltage, but the increase was more pronounced with argon diluent than with either nitrogen or helium. In common with other reactions in an electrical discharge, the B2S decomposition decreased with increasing temperature in the range of -410 to +61° C. The reaction did not appear to be rate-controlled by a solid-gas sorption step because the introduction of activated charcoal into the electrical discharge zone did not significantly affect the decomposition yield. In the presence of polymeric chlorofluoro-carbon oil, 90 pct conversion of the 3 pct H2S in helium was obtained at 14 kV, 60 Hz, a 2-mm electrode gap, and a gas-residence time greater than 1 min. Under the same experimental conditions in the absence of oil, the conversion was only about 50 pct.

Jan 1, 1973

By R. E. Cerullo

Many computer programs have been written which are capable of performing a least squares fit, both linear and nonlinear, to data gathered by the petroleum researcher. However, when the petroleum engineer tries to program methods of analysis he has used manually in the past, such as forecasting production by decline-curve analysis, more than a knowledge of the use of existing least squares programs becomes necessary. It is the intent of the authors to report the techniques used in the development of such a decline-curve program.

Jan 1, 1970

By Richard W. Watson

Card-gap and projectile impact sensitivity data are presented for a wide variety of explosive compositions tested at the Bureau of Mines in more or less standard test geometries. The results of both tests are in good agreement in that they provide the same sensitivity ordering for different subclasses of explosives. Least sensitive were homogeneous liquids that did not exhibit a tendency to undergo low-velocity detonation, ammonium nitrate-fuel oil, and most cast military explosives. Of intermediate sensitivity were pressed and powdered military explosives, cast pentolite, permissible and non- permissible water-based explosives, and one commercial two-component explosive. The most sensitive were permissible and nonpermissible dynamites and explosives susceptible to low-velocity detonation.

Jan 1, 1973

By Floyd G. Anderson

The Federal Bureau of Mines promotes the use of safe and effective dust-collecting devices for rock drilling in coal mines. To insure that such devices are available to the coal-mining industry, the Bureau issues certificates of performance for dust-collecting systems and certificates of approval for dust collectors and rock drills or other mining equipment with integral dust-collecting systems that meet the requirements of an established Schedule.4/ Investigations are conducted under the provisions of the current revision of this Schedule by engineers of the Branch of Health Research. This circular describes briefly the requirements and procedure for obtaining certificates of performance or approval and lists equipment that has been certified as permissible under Schedule 25 or its revisions as of January 31, 1961. The names and addresses of companies to which certificates have been issued are listed alphabetically at the end of this circular.

Jan 1, 1961

By J. P. Bennett

The Bureau of Mines is investigating the acid resistance of ceramic materials to identify construction materials for emerging technology in chemical and metallurgical processes. Eight commercial ceramic materials, including two red shale, two fireclay, a silica, a silicon carbide, a carbon, and a high-alumina brick, were evaluated. Samples were exposed to 40 wt pct HN03 at 70° and 90° C and 60 wt pct HN03 at 50°, 70°, and 90° C for time periods of 110 days. Statistically significant changes in cold crushing strength were generally small or not detected, except for a strength drop in the high-alumina brick, which decreased in strength when exposed to the chosen acid concentrations at 90° C. Vol-ume and weight changes were also measured. The leach rates of Al, Ca, Fe, K, Mg, Na, Si, and Ti were monitored. Increasing temperature or a decrease in the acid concentration resulted in an increased ion leach rate. Of the conditions tested, the most severe corrosion occurred at 90° C for a 40-wt-pct-HN03 solution. The silica brick had the best overall acid-resistant properties, followed by a red shale and a fire-clay brick. The carbon and silicon carbide bricks are not recommended for service.

Jan 1, 1984