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By Sarkis G. Ampian

Crystalline silica (quartz, cristobalite, and tridyrnite) is regulated by the Mine Safety and Health Administration (MSHA) and Occupational Safety and Health Administration (OSHA) because of its potential for causing debilitating but nonmalignant lung diseases. In 1987, the International Agency for Research Against Cancer (IARC) conducted a review of the health literature and concluded that crystalline silica was a probable human carcinogen. As a result of this finding, OSHA was required to regulate crystalline silica under its Hazard Communication Standard (HCS). The standard requires that all materials handled by OSHA-regulated facilities be labeled according to the requirements of RCS and that workers receive proper training on the handling of the material if the crystalline silica content equals or exceeds 0.1 weight percent (0.1 %). MSHA currently is considering enacting its own RCS. This will be similar to OSHA's RCS. If the standard is enacted, most mineral producers will have to determine the respirable monitor filter and bulk crystalline silica contents of their ores and products so that workers and/or customers will know whether they are in compliance with the 0.1% HCS and/or the OSHA permissible exposure level (PEL) of 50 µg for an 8-hour workday for respirable crystalline silica as determined from monitor samples. Two major concerns with the RCS are the widespread occurrence of crystalline silica in nature and the suitability of current technology for routinely determining crystalline silica concentrations at the 0.1 % RCS level. Most ores are extracted from silica-bearing deposits and it is a common constituent of rocks and soils. OSHA's RCS will have the greatest impact on the producers of crushed stone, diatomite, dimension stone, gravel, industrial sand, perlite, pumice, pyrophyllite, sand, and talc because these materials frequently are shipped directly from the mill to the customer. MSHA's RCS would affect nearly all mineral producers. Those producers that have crystalline silica present in concentrations near the 0.1 % cutoff point will have the most difficulty with the analysis. Crystalline silica can be quantified at the 0.1 % level by X-ray diffractometry in simple systems containing one, two, and possibly three minerals if (1) none of the accessory minerals has X-ray diffraction reflections that coincide or overlap with those of crystalline silica and (2) the standard has a particle size distribution and crystallinity similar to those of the sample. In some instances, it may not be possible to determine the crystalline silica content of a sample with any degree of certainty using the recommended regulatory protocol. In all cases, it is recommended that a qualified mineralogist identify the minerals in a sample prior to any regulatory analysis. Additionally, the uncertainty as to whether some silica polymorphs should be classified as crystalline or noncrystalline and the suitability of metastable high-temperature standards, such as cristobalite and tridyrnite, for regulatory analysis at ambient temperatures should be addressed further. This overview is written both to highlight these problems and to serve as a guide for analysts, regulators, and industry personnel who are involved in the crystalline silica issue. It also covers some of the difficulties and/or shortcomings in quantifying crystalline silica, such as the ubiquitous mineral quartz, in the workplace.

Jan 1, 1992

By Ruth F. Brinkley

This report is the 16th of a series of reports originally issued annually and more recently biennially to acquaint the reader with the work of the Explosives and Physical Sciences Division, Region VIII.3/ In the majority of instances the results of the investigations are made available to the public through Government publications and journal articles. In certain instances (specifically as regards security-classified research, investigations of a confidential nature, and short-range programs of very limited scope) results are reported only to those immediately concerned.

Jan 1, 1957

By James R. Boyle

The value of Alabama's nonfuel mineral production in 1984 was $409.8 million, and established a new record high for value of nonfuel minerals in the State, at 13.4:% over the previous high of 1983. Output of nearly all nonfuel minerals increased; phosphate rock was one of the exceptions, with no recorded output in 1984. Cement, crushed stone, lime, sand and gravel, and clays were the major commodities produced in Alabama. Alabama led the Nation in the production of crushed marble; was second in bauxite; third in fire clay and kaolin; fourth in bentonite, ferroalloys, and dimension marble; fifth in masonry cement, lime, and recovered sulfur; and sixth in portland cement. Alabama ranked 22d in the Nation in value of nonfuel minerals produced.

Jan 1, 1986

Reduce haulage truck accidents resulting from blind spots, with a special emphasis on reducing accidents during backing operations.

Jan 1, 1997

By Hugh D. Pallister

Alabama probably has the most extensive deposits of high-grade flake graphite in the United States and was the largest producer during World War I. Therefore, with the outbreak of World War II, users of flake graphite turned again to Alabama to supply their requirements. Flake graphite is the most important ingredient contained in graphite crucibles used in melting crucible steel and special alloys essential for war purposes. Early in World War II the Army and Navy placed flake graphite on the list of critical war materials. During World War I, when the supply of Ceylon graphite (then in demand) was cut off, large quantities of flake graphite were produced in Alabama, and about 40 mills were built. Most of these were abandoned after the war when imports of the cheaper Madagascar flake (which gradually replaced Ceylon graphite) began to reach this country. With the beginning of World War II, the Madagascar supply was cut off', and consumers were again compelled to look to domestic sources for their supplies. They found only one small mill in operation, that of the Ceylon Graphite Co. in Coosa County, Ala. The Bureau of Mines made a preliminary examination of the Alabama flake graphite deposits in 1940. Samples were taken and tested at the Southern Experiment Station at Tuscaloosa.

Jan 1, 1948

By John R. Bradley

The available supply of fuel and power is a subject of importance at all times and particularly at this time. The following brief survey of fuel and power in the United States appraises the extent of the several primary sources of energy the approximate monthly demand, 1929-40; the chief centers of production and consumption; and shifts in the principal uses from 1929 to recent years. The period covers the boom year 1929, the years of the great depression, the more normal year 1937, the recession in 1938, the year 1939, and 1940 (which was affected by armament programs). In some instances, the data for 1939 and 1940 are preliminary. The four primary sources of fuel and power are coal, petroleum, natural gas, and water power. Wood fuel, important in some regions, and foreign trade in natural gas and hydroelectricity represent a relatively small part of the energy supply and are not considered in this study. The tonnages shown are in terms of coal, based upon the calorific or B. t. u. equivalents of the several sources of power. In practice, the usable heat or energy varies according to the type of equipment available for its use. For example, the efficiency of turbine water wheels and internal-combustion engines is much higher than that of steam plants and household-heating devices.

Jan 1, 1941

By J. P. Capp

This experiment, one of a series on underground gasification of coal, was an investigation by the Federal Bureau of Mines of hydraulic fracturing as a means of increasing the air acceptance of a coalbed to permit introducing combustion air and removing product gases. Specific objectives of the investigation included: (1) Fracturing a coalbed; (2) determining the distance the coal was physically affected; (3) ascertaining the effect of the fracture on air acceptance of the coalbed; and (4) gasifying the coal. The coal was fractured with a fluid consisting of 15,000 lb. of sand mixed with 10,000 gal. of fuel oil and 5,000 gal. of kerosine, injected at pressures up to 900 p.s.i.g. and rates up to 425 g.p.m. The oil served as the fracturing medium, and the sand as a propping agent to hold the fracture open. From the fracture point, (the place in the bed where the fluid was injected), the fracture extended 200 ft. or more along the face cleats, somewhat less along the butt. cleats, and was confined to the coalbed. At the fracture point, the bed accepted about 500 std. c.f.m. of air, which was an etghtyfold increase. Fracture effects were extensive, as airflow was noted from old mine workings and outcrops 600 to 800 ft. from the fracture point. It is probable the actual fracture was much less than 600 ft. and that normal coalbed permeability beyond the fracture limits was responsible for this flow. This indicated that effects of the fracture extended beyond the area of coal physically affected. Although no attempt was made to gasify coal more than 200 ft. away, these effects plus the natural permeability of the bed likely would permit combustion beyond the outer limit of the fracture. As these experiments continued for more than 2 years, and greater air acceptance due to the fracture was observed at the beginning of each test, it is apparent that the effects of the fracturing persist for a considerable time.

Jan 1, 1960

By Arno C. Fieldner

From July 1, 1949, to July 1, 1950, the Bureau of Mines conducted the research and technologic work on coal and coal products that is summarized in this report. The research, described in this fifteenth of a series of resumes, is presented in more detail in publications (see footnote references) that appeared during the fiscal year, though in some cases research data are given that have not been published elsewhere. Results of research in the experimental coal mine, on explosives, and on gas and dust explosions will be found in Bureau of Mines Report of Investigations 4228, Annual Report of Research and Technologic Work on Explosives, Explosions, and Flames, Fiscal Year 1950. An over-all view of our coal, oil, end natural-gas reserves was presented, and the future possibilities for the, production of synthetic liquid fuels from coal were delineated.3/

Jan 1, 1951

By Thomas M. Barczak, Joe Bower, Jinsheng Chen

Pumpable roof supports provide an alternative longwall tailgate roof support and have grown in usage during the past few years. Heintzmann Corporation has been installing pumpable roof supports at the RAG Resources Emerald Mine in western PA since 1998, where they have provided effective roof control in their longwall tailgates. Despite the success of these supports in this application, questions remain regarding critical design issues for optimizing the use of this support technology. The support loading profile is characterized by a high initial stiffness with peak loading occurring at less than one inch of convergence, followed by significant load shedding with a post failure capacity comparable to that of wood cribbing. Therefore, the key to optimizing the support utilization is to provide sufficient load density to prevent convergence from occurring beyond the peak loading capacity. This requires an understanding of how the supports interact with the ground conditions, hence measurement of the ground reaction curve. In order to obtain this information, pumpable roof supports were instrumented to measure support loading. Roof deformation and roof-to-floor convergence measurements in the vicinity of the instrumented supports were also made. The experimental parameters for the installation were the support spacing and water-to-solids ratio of the grout, which controls the grout strength and ultimately the maximum capacity of the support. The study clearly shows that at this mine a 24-inch diameter support is fully capable of providing adequate ground control under depths of cover of 750 ft as only 50 pct of the available support capacity was utilized outby the longwall face. It was also shown that the 2.00 to 1 water-solids ratio, despite providing a slightly softer support response, is sufficient for maintaining the same degree of roof control provided by the traditional 1.75 to 1 grout mix. The 10-ft spacing of the supports did not cause any ground control problems outby the face. However, inby the face the performance of the support is degraded once the peak capacity of the supports is exceeded. It appears that the large load shedding behavior, which is characteristic of this support following peak loading, allows the immediate roof to separate. When this happens, the support is unable to regain control of the roof in time to prevent failure of the immediate roof beam.

By Gregory J. Chekan

The Bureau of Mines, in an effort to improve planning and development in coal mining, is investigating strata interactions associated with mining of multiple coalbeds. Two common interactions that occur between adjacent coalbeds are subsidence and pillar load transfer. The study described involves underground observations and measurements conducted at two Pennsylvania mines, each affected by one of these interactions. At the mine affected by subsidence, measurements show that undermining had little effect on upper mine pillar stability, but had a more severe effect on the development and maintenance of entries. Roof-to-floor measurements recorded over four times more convergence in entries developed over gob as compared with entries developed over support pillars in the lower mine. At the mine affected by pillar load transfer, Initial in situ measurements have shown the existence of a pressure arch in the lower workings. Prior research has shown that arch interaction between two adjacent openings can create stress concentrations in the in-nerburden. Underground measurements and results obtained from both mine sites correlate with theoretical and photoelastic multiple-seam models, and eventually these field data will serve to refine model accuracy. Further study of multiple-seam interaction mechanisms will lead to improved mine planning, increased resource conservation, and a safer working environment.

Jan 1, 1986

By T. M. Garland

This report presents a Bureau of Mines assessment of crude oil and associated gas production and reserves that would result from different drilling efforts in the lower or contiguous 48 States during the 1972-85 period. The drilling effort was based upon five growth rate assumptions from the 1971 level. Additions to crude oil reserves were computed for nine cases resulting from the use of three equations for findings per foot drilled and three constant revision factors. The results indicate that the United States will not become self-sufficient in crude oil production by 1985 and also illustrate the lead time required to reverse the decline in oil production. Discussion is limited to three of the nine cases to provide high, intermediate, and low results. More emphasis is on the intermediate case because it is indicative of the most probable trends. The methodology and statistical data are included in the appendices.

Jan 1, 1974

By K. O. Bennington

Cancrinite is one eonstituentof "red muds," a high-volume waste product of alumina production by the Bayer process. The Bureau of Mines determined the thermochemical properties of cancrinite as part of a program to provide such data for minerals of industrial importance. Cancrinite [Na7.68(A16Si6024)(N03)1.68 (H2O)4.1] was synthesized by reacting aluminum silicate gel with a solution of NaOH and NaN03, and the composition was determined by chemical analysis, differential scanning calorimetry, and thermogravimetric analysis. The heat of solution was determined by hydrofluoric acid solution calorimetry. The standard enthalpy of formation at 298.15 K, ?Hf°298, is ?Hf°298 = -3,487.97 ±2.6 kcal/mol, and the standard enthalpy of formation from the oxides and NaN03, ?H°298, is ?H°298 = -215.20 ±l.8 kcal/mol.

Jan 1, 1983

By D. L. Soreck

The hazards to the public posed by abandoned mine shafts are well documented. As private development encroaches on previously mined areas, the potential for fatalities and serious injuries from abandoned mine shafts increases. The U.S. Bureau of Mines has conducted research into cellular concrete as a material for sealing these openings. The current work involves testing the characteristics of cellular concrete before and after it had been pumped or dropped from different heights into a simulated mine shaft. Cellular concrete was pumped vertically up to and subsequently dropped from heights of 18 and 37 m into concrete forms. Wet density measurements were made at multiple sampling points in the test circuit. Air content determinations and uniaxial compressive strength testing were conducted. Research results showed significant loss in air content and changes in the characteristics of cellular concrete during pumping or dropping from various heights. Recommendations on effective use of cellular concrete for sealing abandoned mine shafts are made.

Jan 1, 2010

By Howard W. Kilau

The U.S. Bureau of Mines is investigating surfactants added to water sprays to enhance the control of dust during coal mining operations. The objective of the present work was to establish the general applicability of adding sulfate ion to anionic surfactant solutions in order to improve wetting action. This was pursued through laboratory wettability testing of four anionic surfactants and one nonionic surfactant in combination with various concentrations of sulfate ion. The experimental results demonstrated that the addition of sulfate ion enhanced the wetting characteristics of all the anionic surfactants when applied to hard-to-wet coals, while easy-to-wet coal showed more complex wetting behavior. Sulfate ion in the presence of nonionic surfactant enhanced wetting only slightly or not at all. Surface tension measurements of the dilute aqueous surfactant-sulfate anion solutions indicated this property was not important in coal-wetting phenomena, as long as the value was below the critical value for coal. Sulfate ion helps surfactant reduce surface tension but primarily appears to affect wetting action by altering the adsorption characteristics of surfactant on the coal surface.

Jan 1, 1990

By Philip C. Tully

[This bibliography contains 3,655 different citations to technical and scienfic literature on helium and alpha-particles, abstracted by 13 abstract service iblicatlons during 1964. Multiple subject classification increases the total number of entries to more than 5,800. Helium citations are listed by 22 major assifications, alpha-particles by 12]

Jan 1, 1970

By Lowell B. Moon

Concern over possible wartime shortages finally resulted in passage of the Strategic Materials Act in 1939. As authorized by one section of this legislation, the Bureau of Mines proceeded to investigate deposits of seven strategic minerals with the objective of developing tonnages of low-grade material that could be mined in an emergency. During the war, the size of the program and the number of strategic minerals were increased, and the objective was the more immediate one of aiding production. Since the war, the size of the program has been reduced, but the number of minerals on the strategic list continues to be large. The objective has returned to that of 1939. In the course of the program, more than 10,000 examinations were made and about 1,300 projects were run on deposits of 33 different commodities. A considerable contribution to war production was made in six of the commodities investigated, and a minor contribution was made in twelve others. Substantial reserves have been indicated in 19 minerals. Private interest is currently active in some of the deposits developed in 14 commodities.

Jan 1, 1950

By Robert S. Dalzell

Following the introduction of roof shields to the U.S. longwall mining scene in 1975, the number of shield faces (faces supported by shields) has increased steadily, and the occurrence of accidents associated with ground control inadequacies at longwall operations has shown a downward trend. However, ground control problems in longwall mining still exist. New mining systems, however efficient, have run afoul of roof control. Shield faces have suffered extended stoppages because of roof cavities. In this report, the Bureau of Mines addresses the problem of longwall roof control. The report presents a review of foreign remedial and strata replacement techniques for longwall faces and evaluates their potential for domestic application. The technology reviewed includes meshing, chemical rock stabilization, cribbing, strain-absorbent modules, inflatables, synthetic foam, and monolithic fills.

Jan 1, 1985

By J. Bongarra

This report describes the development of the instructional design and content of a training program for shaft construction miners and supervisors. The recommended training approach is based on the results of a needs, task, and competency analysis of the jobs performed by conventional shaft sinking and raise drill personnel. Learning objectives were derived from the task analysis and the appropriate training delivery system was chosen using a selection technique which employed learning algorithms. The training described is aimed at improving the safety and efficiency of constructing shafts by new hire and experienced miners and supervisors. A self-paced, self-teaching, modular approach to training, using criterion-referenced tests was proposed. Recommendation was made to divide the training into three parts: Orientation and Safety; Task Instruction; and Practical Exercise. Training requirements for conventional shaft sinking and raise drilling were described. Training program content was detailed in the form of module and lesson design approaches. In addition, the report recommends a method for developing, implementing and validating the training program. The authors conclude that such an implementation would meet the major objectives of improving the safety and efficiency of shaft construction work operations.

Jan 1, 1979

By Merwin H. Howes

In constructing the NORAD Combat Operations Center, controlled blasting techniques were employed to achieve smooth walls and to avoid shattering the rock beyond excavation lines. Extraordinary measures were taken to stabilize the rock to permanently preserve the openings. Rock stabilization was accomplished by means of reinforced concrete and gunite linings, rock boltings, installation of chain-link fabric, and epoxy resin and cement grouting. A particular zone of weakness at a vital location was supported by exceptionally thick reinforced concrete lining, rock bolts, and cement grout.

Jan 1, 1966

By Alex C. Smith, Michael J. Sapko

A series of explosive detonation experiments was conducted in NIOSH’s Bruceton and Lake Lynn Experimental Mines to evaluate low level (<6 psig) detonation wave propagation behavior in single and multiple entry configurations. Entry cross-sectional area varied from 5 to140 m2 and explosive weights of Pentolite ranged from 0.24 to 2.4 kg. Behavior of the detonation wave was evaluated through recording of the pressure as a function of time and distance from the explosive detonation in single and multiple entry interconnecting tunnels. Peak pressure from detonation of an explosive in an underground mine maintains magnitude for a greater distance than is the case on the surface and is shown to follow the simple scaling rela-tionship P = 702.8(W/Vt)0.514(0.65)n, where P is the peak detonation pressure in kPa, W is the weight of the explosive charge in kg, Vt is the total volume in m3, and n is the number of splits, n = 0, 1, 2, …n. The total energy, or impulse, I, generated by these detonations can be expressed as I = 1.34(W/A)0.64n, where W is the weight of the explosive charge in kg, A is the area of the main tunnel in m2, and n is the number of side en-tries, n = 0, 1, 2, …n.