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By M. Celikin, M. Isac, R. I. L. Guthrie, S. Ge

Horizontal Single Belt Casting (HSBC) is a near-net-shape casting process in which molten metal is directly cast into thin strips, at high cooling rates (order of several 100°C/s), with the potential for high volume, friction-free, continuous production of metal strips. This casting process was used in the present work to produce strips of Al-Mg alloys in the AA5000 series, with additions of Sc and Zr. Such aluminum alloys show exceptional potential as a structural material for transportation/aerospace applications. To demonstrate the suitability of the HSBC process to manufacture competitive strip products of Al-Mg-Sc-Zr, the mechanical properties and microstructures of the strips produced using the HSBC process were compared with conventionally cast products. The effects of annealing on the mechanical properties of the strip-cast Al-Mg-Sc-Zr alloys were also investigated.

Jan 1, 2014

By Denghong Wang

Abstract- The Ashele Cu-Zn deposit is a recently discovered volcanogenic massive sulfide deposit in Xinjiang, China, hosted by Lower to Middle Devonian submarine bimodal volcanic rocks. The primary ores of this polygenetic deposit are represented by massive syn-depositional pyrite, chalcopyrite, and sphalerite, and were formed by submarine exhalation. Hydrothermal alteration consists of strong sericitization, chloritization, silicification, and carbonatization of the metavolcanic rocks beneath the massive orebodies. Depletion of Na2O is an obvious chemical change in the hydrothermal halo. Geological and geochemical evidence suggest that the Ashele Cu-Zn massive sulfide deposit was formed by submarine exhalation related to bimodal volcanic rocks, trapped in a rifting basin, then deformed by shearing, and thermally metamorphosed by the intrusion of dacitic porphyry. Sulfur and lead isotopic studies indicate that metals such as copper and zinc may have originated from spilites, but that volatile components, especially sulfur, were derived directly from submarine volcanic magmas.

Jan 1, 1999

By D. E. Salman, R. R. Maclachlan, R. J. Barclay

"There is a considerable resource of data for spherical charge cratering, both as single charges and in row-of-charge geometr(1). The data are. however, based on cratering performance to a single free planar surface.In practice. the more common circumstance involves an angular surf ace geometry. such as occurs at the toe of a bench or the wall of a stope. It is for the purpose of investigating this circumstance that the described test work was conducted.The test objectives were: (1) to observe the change in single-charge cratering performance between planesurface and angle geometry; (2) to identify the optimum performance of single charges cratering to a plane surface. cratering from a bench sub-grade position and cratering from a condition of zero sub-grade or stope wall geometry; and (3) to observe the performance of row-of-charges cratering to an angular surface at various row burials and spacing. The row charge burial and spacing dimensions were to be expressed in simple numerical multiples of single-charge depth-of-burial data."

Jan 1, 1981

By Sylvie Poirier

This paper focuses on new developments regarding thermal rock fragmentation applications. The technology consists in a strong burner powered by diesel fuel and air. The thermal reaction, which is created, allows for the enlargement of 125-mm to 450-mm holes by breaking the rock in a spalling effect. It has been used for over 30 years in Russian open pit mining. Following an agreement between Dynamitage T.C.G. Inc. and the owner of the technology, major improvements have been brought to this technology, allowing for the fabrication of a prototype suitable for the Canadian industry. In Russia and Ukraine, thermal rock fragmentation is actually used to drill large diameter holes in surface mining. Upon having acquired a better knowledge of this technology, it seems that it presents a great potential for selective mining in narrow-vein operations, for either surface or underground mining. Rocmec International Inc., a subsidiary of Dynamitage T.C.G. Inc., and Natural Resources Canada are technical partners in the evaluation of the operational parameters and environmental aspects, such as gas, heat, dust and fog emissions. Furthermore, Canada Economic Development is a financial partner in this project. This paper presents the technology and its history. It also reports on the changes brought to the equipment to adapt it to North American environments. A summary of the tests realized since 1995 is provided, along with the main conclusions obtained. The anticipated applications for the use of this technology in both surface and underground environments are described, such as open pit mining, bulk sampling and narrow-vein ore extraction. An estimate showing a comparison between the thermal fragmentation mining concept and the long-hole mining method is presented and, finally, the future developments planned are listed.

May 1, 2002

By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By T. K. Akopyan, E. A. Naumova, V. V. Doroshenko, N. A. Belov

"A qualitative and quantitative analysis of the new Al-Ca-Mn-Fe phase diagram in the region of the aluminium corner is carried out using both thermodynamic calculations and experimental methods. Using the obtained data, the principal possibility of creating both cast and wrought sparingly alloyed aluminium alloys with calcium, manganese, scandium and zirconium at allowable iron contents of up to 0.4% that do not require solution treatment and quenching is justified. At the selected concentrations, the entire amount of manganese (1%) is practically included in the aluminium matrix, while calcium (~2%) and iron are in the multiphase eutectic, which has a fine structure. The joint introduction of 0.25% Zr and 0.1% Sc into the alloy leads to precipitation hardening due to the formation of the L12-Al3(Zr,Sc) phase during annealing. Based on the experimental data for the model multicomponent Al2CaMnFeZrSc alloy, it is shown that such alloys can combine high mechanical properties and good manufacturability during both casting and metal forming. This is due to the combination of a narrow temperature range of solidification with a fine eutectic structure.INTRODUCTION Hardening in branded aluminium alloys (both cast and wrought) is generally achieved by heat treatment of the T6 type, including quenching and artificial aging (Zolotorevskiy, 2007; Kaufman, 2004; Mondolfo, 1976). Heat treatment significantly increases the cost of the final products. Therefore, industrial companies are interested in developing alloys that can be hardened to the desired level without quenching. To solve this problem, alloys with scandium are the most suitable (Toropova, 1998; RØyset, 2005). This element (usually in an amount of ~0.3%) is one of the most effective hardeners in aluminium alloys, due to the formation of Al3Sc (L12) phase secondary precipitates, the size of which is less than 10 nm (Knipling, 2010; Fuller, 2005). These nanoparticles are formed during the annealing via decomposition of the supersaturated aluminium solid solution (hereinafter referred to as (Al)). This feature allows us to significantly increase the strength of aluminium alloys by simple annealing (at ~300°C), i.e., without heat treatment, including quenching. However, scandium is a very expensive metal, so its use as an additive is severely limited. The most effective method is the introduction of scandium together with zirconium (Lefebvre, 2009; Booth-Morrison, 2012). The optimal combination is the introduction of ~0.1% Sc together with 0.20–0.25% Zr, which, according to (Belov, 2006), gives approximately the same strengthening effect as the introduction of 0.3% Sc."

Jan 1, 2018

By D. H. Wilton, C. I. Godwin, A. J. Sinclair

"A computer-based drill core logging system used to examine computer-based drill core logging system used to examine copper mineralization hosted in volcaniclastic rocks at the Sustut deposit, in north-central British Columbia, has many advantages over conventional logging. A relatively simple format for recording geological information allows complex, but significant, geologic parameters to be recorded consistently, accurately and quickly. This allows graphical presentations and statistical interpretation of the data that lead to rapid and detailed analyses of the control and distribution of copper mineralization at the Sustut deposit.Ore mineralization is concentrated in lens-shaped bodies and is zoned from native copper cores through chalcocite, bornite and chalcopyrite to a margin containing pyrite. Chalcocite, the principal mineral, occurs mainly in volcaniclastic agglomerate characterized by a specific grain size, a narrow range of matrix and fragment proportions, and a specific sorting.IntroductionWe report here a case history of the practical application of a detailed computer-based drill core logging system applied to the Sustut copper deposit of Falconbridge Nickel Mines Ltd. The Sustut deposit, containing a few tens of millions of tons of ore grading slightly more than one per cent copper (Church, 1975), is in north-central British Columbia about 875 km north of Vancouver. The deposit is contained in volcaniclastic sedimentary rocks of the Upper Triassic Moosevale Formation, which is within the upper part of the Takla Group (Monger and Church, 1977) of basic volcanic and associated sedimentary rocks. Takla rocks occur along the eastern fringe of the Intermontane Belt in the Canadian Cordillera (Sutherland Brown et al., 1971). The deposit consists of concentrations of copper sulphides, native copper and pyrite within pods and lenses parallel to bedding in the host sedimentary rocks. These sheet-like deposits exhibit a mineral zoning from pyrite at the fringes successively through chalcopyrite, bornite and chalcocite to native copper at the core (Wilton, 1978; Wilton and Sinclair, 1979)."

Jan 1, 1980

By W. A. Gow, H. H. McGreedy

It is believed that many of the problems encountered in the operation of gold cyanidation plants are difficult to resolve due to the lack of sufficient and reliable in-formation regarding the variations and actual values of operating variables at any given time. The application of instruments to monitor the more important variables in the cyanidation process should result in more efficient plant operation and a better understanding of the process. The use of pH and conductivity sensing devices for alkalinity measurements, a monitor to determine the dissolved oxygen content of plant solutions, a continuous cyanide titrator and sonic control of grinding circuits are discussed. Although the discussion is oriented toward the cyanide process, much of the paper is applicable to other ore treatment operations.

Jan 1, 1966

By K. Hasselwander, K. Knabel

"A significant area of Outotec’s business involves fluidized bed roasting. With several decades of experience, more than 300 reference plants and strong R&D capabilities, the company provides several industries with optimum processing solutions. Applications include oxidation and sulfation of sulfides found in copper, pyrite and zinc concentrates. Gold production and de-arsenifying roasting are also within this scope. This paper describes the latest furnace developments and includes novel trends. Moreover, hot and wet gas cleaning systems are examined focusing on unit operations related to the removal of components such as dust, SO2 for sulfuric acid production, fumes, halides, Hg, hydrocarbons, nitrous oxides and metals.INTRODUCTIONGenerally, when defining roasting processes, it can be stated that the respective primary pyrometallurgical reaction is exothermic, of gas-solid nature and relates to a value solid product. These processes are a key focus within Outotec’s scope and include: (i) dead roasting (ii) sulfating roasting (iii) partial de-arsenifying roasting and (iv) two-stage, de-arsenifying roasting.Dead roasting involves the oxidation of a given sulfide, thus allowing for a subsequent leaching process, and has been applied to producing ZnO. Dead roasting of pyrite has also been extensively utilized with a primary goal of producing sulfuric acid. In contrast, sulfating roasting involves converting a sulfide to its sulfate, enabling a selective sulfation of components, such as Cu or Co, and their separation from ferrous components during leaching (produced sulfates are soluble). Partial roasting involves partially oxidating the metal sulfide to its oxide with the simultaneous production of gaseous As4O6, which is handled during gas cleaning. The solid product, containing hardly any As, is rich in S and can be fed to a respective smelter (e.g. in the case of Cu). Alternatively, if the production of oxide is required, a dead roasting step is added after the partial roasting step, with the overall process considered as two-stage roasting."

Jan 1, 2012

By W. H. S. McFarland

THE Yukon Consolidated Gold Corporation, Limited, a Canadian company, operates alluvial gold dredges in the Klondike goldfields of Yukon Territory. Its operations are of unique interest to Canadian mining as it is the only large-scale placer mining operation of this type in Canada. Its properties lie in the valley of the Klondike river and its tributaries, Bonanza, Hunker, Bear, Last Chance, and All Gold creeks, and in the valley of Indian river and its tributaries, Dominion, Gold Run, Sulphur, Eureka, Montana, and Quartz creeks. At the end of 1938, they consisted of 1,650 placer mining claims and 9 leases or concessions. They cover a belt with an area of approximately 1,000 square miles. This vast area covers in part claims which have been previously worked by other methods such as 'drift' and 'open-cut' mining, and areas which were too low grade for such methods. The ground held by the Company is not held in freehold but in the form of mining claims and mining leases granted by the Dominion Government under the provisions of the Yukon Placer Mining Act. Full-size creek claims are 500 feet in length by 1,000 feet on either side of the base-line. Hill and bench claims are 500 feet up and clown the valley and 1,000 feet at right angles to the valley. All claims are held on the basis of an annual renewal fee of $10 for each claim plus 'representation work' of an assessed value of $200 per claim per annum. For the purpose of such representation work, claims may be 'grouped'. This means that work done by one dredge is sufficient to 'represent' a comparatively large block of claims. It is only in this way that it becomes possible to consider operations on a large scale over a term of years, for such operations would obviously be impossible on law-grade ground if representation work had to be done separately on each individual claim in each year.

Jan 1, 1939

By P. Dinham, G. C. Summerton, N. McCulloch, S. Dowling, D. C. Craig

"Development of a process for the treatment of a nickel copper matte rich in the minerals heazlewoodite, chalcocite and bornite has demonstrated significant base metal recoveries and metal separation efficiencies. The determination of chemical and mineralogical changes occurring in the individual leaching stages in laboratory experiments has enabled a better understanding of the complex leaching chemistry. The chemistry and mineralogy of the piloting and laboratory processes are discussed.INTRODUCTIONThe nickel-copper sulfide ores of the South African Bushveld Complex are among the most important Platinum Group Metal (PGM) bearing ores, and contain the world’s largest reserves of platinum. The treatment used in the recovery of PGMs from these ores includes three types of processes, namely ore concentration using physical techniques such as flotation and gravity separation, concentration by pyrometallurgical means, hydrometallurgical extraction of the base metals followed by the PGMs. Following milling of the ore, flotation involves the separation of high value minerals from gangue by taking advantage of the differences in their hydrophobicity. These differences are generally maximized through the use of a surfactant or wetting agent. Concentrates are then thermally treated and melted which brings about physical and chemical changes that enable the recovery of base metals and PGMs. The main aim of the smelting and converting process is to separate and eliminate the valuable metals from the bulk of the unwanted gangue and essentially all of the iron and to concentrate the metal VALUES (into a high grade converter matte. The matte can be further enriched by magnetic separation, producing a PGM-rich magnetic fraction and a base metal-rich non-magnetic fraction. The magnetic fraction is treated by hydrometallurgical processes to produce a PGM concentrate which is further refined to separate and purify the individual metals. The non-magnetic fraction is treated to produce marketable metal VALUES (such as nickel, copper, cobalt and to a lesser extent PGMs. The principal objective of any hydrometallurgical extractive process is to leach the desired elements selectively into an aqueous phase so as to separate them from the bulk of the material. (Crundwell, Moats, Ramachandran, Robinson and Davenport, 2011; Hundermark, Mncwango, de Villiers and Nelson, 2011)."

Jan 1, 2012

"A 3-dimensional finite element model for stress/stability analysis of rock excavations in underground mines is presented. Developed for use on personal computer under OS/2 operating system, the model employs the 8-node isoparametric brick element and accounts for such loading conditions as in situ stresses and gravity loading of the rock mass. In addition, modelling of backfill in mine stopes as in situ stress-free material is incorporated. Material failure is assessed by Mohr-Coulomb or Hoek-Brown failure criterion. A mine design example is presented to illustrate the potential use of the model as a tool for stope design.IntroductionNumerical modelling of mine structures has become a vital tool for mine design in recent years. The need to maximize ore extraction ratio and to reach deeper mineral deposits underground has led the mining industry to employ numerical methods of analysis to undertake complex ground control studies in order to better understand the ground response to mining excavations and to evaluate the ground support requirements. Thanks to the rapid developments in computer technology, it is now possible to perform very comprehensive analyses including, but not limited to, 3-dimensional, elasto-plastic, or large deformation or time dependent nonlinear analyses on personal computer.During the past ten years or so, many researchers undertook 3-D finite element analyses of rock mechanics problems in mining engineering. The following is only a sample review. For example, Chan'!' used three-dimensional finite elements to study the mechanical response of jointed granite during shaft sinking at the Canadian Underground Research Laboratory. Wang et al.(2) performed 2-D and 3-D finite element analyses of room-and-pillar mining system with flat and rolling coal seams. Thatejatu used three-dimensional finite element method to examine the problem of branching tunnels. Dolezalovaw used three-dimensional finite elements for the analysis of tunnel-face advance with partial excavation as well as full-face excavation in combination with rein for cement of the face by long anchors. Peili (5) used three-dimensional finite elements for the simulation of rock-liner interaction near the tunnel face."

Jan 1, 1992

By C. Mills, A. O. Burt

"The paper examines the role of gravity concentration in both an historical context and within the modern mineral processing industry. It discusses the principles of the process on both a theoretical and practical level. The importance of more mineralogy and its effect on the choice of the wide range of equipment available is discussed. The paper concludes with a discussion on the relative merits of gravity concentration with other forms of processing.IntroductionIt is an unfortunate, albeit popular, misconception among otherwise enlightened engineers in the mineral processing industry that gravity concentration was a process developed in the dark ages, perfected in the middle ages, and abandoned in the modern ages.Gravity concentration was developed in the dark ages - long indeed before that. Agricolau: cited examples of gravity concentration, crude examples admittedly, being practiced over 3000 years ago. However, gravity concentration is not dead. Far from it. As recently as 1978 it was reported that the total mineral tonnage treated by this process in the United States was greater than that processed by flotation. Coal represents the bulk of the or e treated by gravity separation in the U.S.A., with iron ore representing a major portion of the balance."

Jan 1, 1985

By R. A. Crouse

The Tanco pegmatite at Bernie Lake, in the Lac du Bonnet mining district of southeastern Manitoba, is a unique deposit of Li, Rb, Cs and Ta, with substantial reserves of Be and several industrial minerals. This paper summarizes the present state of understanding the regional geology, structural setting, zoning, mineralogy and geochemistry of the pegmatite, and the mining and ore-processing methods used in its exploitation.

Jan 1, 1979

By T. Ouellet, F. Chiesa, J. Carignan, D. Levasseur

Common practice for the preparation of permanent mold for aluminum casting is to coat the mold with a ceramic suspension to obtain a chemically stable interface with the aluminum melt. This practice serves two purposes: first, it helps the thermal regulation of the mold and second, it prolongs its life. The possibility of increasing the coating durability by applying it by thermal spray is appealing. Plasma spray of zirconium oxide based coatings was performed on H13 tool steel to study the coating’s thermal fatigue resistance. A unique dip test setup was used to characterize the thermal fatigue resistance of the coatings and of bare H13 steel. Observations of the failure mechanism bring an insight on the requirements of the coating to maximize its durability.

Jan 1, 2014

By A. Dave Mackintosh

The Current demand for potash has pushed world prices to record levels and allowed Saskatchewan producers to operate at maximum capacity. Several years of strong demand has resulted in a permitting rush not seen since the 1960?s. Even though Saskatchewan has a huge potash resource, mining and processing constraints will limit the areas of economic development. Introduction In 1969 M. E. Holter prepared a report ?The Middle Devonian Prairie Evaporite of Saskatchewan?, published by the then Dept. of Mineral Resources. Holter?s report has remained the bible of geologists working in potash ever since. It is astounding that a report written before there was really much potash mining history in the province, is as valid today as when it was first published. This paper re-iterates much of Holter?s report and adds a little mining experience to essentially confirm the importance of his work.

May 1, 2008

By Stephen C. Tadolini

"The use of a torque wrench to establish the amount of actual load developed on an expansion anchor bofting system dates back to work completed in the early 1950s. The advent of ultrasonic measurement systems and hydraulic torque wrenches has made it possible for the U.S. Bureau of Mines to perform torque-tension measurements in the laboratory and the field much more accurately. The results indicate that the amount of initial boft preload may be overestimated by amounts in excess of 45% of the expected load using torque wrenches. This inaccuracy is primarily due to the friction that occurs between the bearing plate and the head of the boft. These parameters become extremely important when the support system is being used to prevent joint members from slipping relative to each other or when the boft acts as a heavy spring to clamp two or more sections together. Methods to overcome the frictional losses are presented in conjunction with a laboratory method to determine the actual torque-tension ratios for expansion anchor and combination bolting systems.IntroductionMechanically anchored roof bolts have been widely used in the mining industry since their introduction in 1947. Estimates made in 1989 indicate that out of 85 million fixtures, approximately 49 million bolting fixtures still use applied tension to complete the reinforcement necessary to maintain stable openings. Nearly 85 million bolts are used yearly. The most widely used bolt is the resin-anchored headed rebar, followed by standard mechanical roof bolts, specialty bolts (mechanically anchored, resin enhanced fixtures) , and combination bolts . Po st-tensioned resin rebars, combination systems, and friction stabilizers make up the remaining 10% of the units used (Fig. I).For mechanical, combination, and tension rebar bolts, the bolt tension is the primary means of reinforcing the roof, but in many cases, because of poor installation procedures, the bolts are ineffective. Mine operators recognize the importance of proper installation procedures. Long-term bolt tension measurements are required in the Code of Federal Regulations (CFR)In each bolting cycle, the actual torque or tension of the first tensioned bolt installed with each drill head shall be measured immediately after it is installed. Thereafter, for each drill head used, at least one roof bolt out of every four installed shall be measured for actual torque or tension. If the actual torque or tension of any roof bolts measured is not within the range specified in the roof control plan, corrective action shall be taken."

Jan 1, 1991

By A. Ghahreman, M. Oliazadeh

"Heap leaching is an attractive process for low grade deposits where the metal content of ore does not justify the high cost of milling and agitated leaching. In general, the heap leaching capital cost is low, construction is rapid, and production costs are low. The primary disadvantage of heap leaching is low recoveries (typically 65% of agitated leach recovery); thus, recovery improvements could convert more lower-grade deposits into minable reserves. This will also allow to process primary sulfide ores and result in a dramatic expansion of the technology, as ~80% of total ore types are sulfidic in nature. The old gold operations tailings are another massive source of low-grade gold material that can be retreated by the heap leach process. The major parameters affecting the recovery rates are ore characteristics (mineralogy, particles size of metal and host minerals, ore permeability), and operational conditions (segregation of ore, compaction, leach cycle time, lift height, and solution application rates). The design of a percolation leach process is based on a limited number of coarse ore bottle roll and/or column tests under ideal conditions. The economics of the projects and engineering design of the process facilities are developed based on the bench scale test work results and the application of the conventional engineering scale up factors. This paper will deal with the parameters affecting the HL efficiencies and focus on the potential improvement of gold heap leach recoveries. This would include design of heap leach operation and evaluation of processes such as fine crushing and bioleaching.INTRODUCTION Gold heap leaching is a hydrometallurgical process designed to treat amenable low-grade gold ores that contain typically 0.5 to 1.5 g/t gold (Marsden and House, 2006; Wong Wai Leong and Mujumdar, 2010). Ore is stacked by various types of equipment on an impermeable barrier, and a sodium cyanide solution is applied to the surface of the stacked ore. Gold, silver, and other metals contained in the ore are dissolved to various degrees by the cyanide application, as it percolates downward through the stack of the ore. The pregnant leach solution (PLS) is then collected at the bottom of the heap. The PLS is then sent to the gold recovery plant where the metals are extracted. The barren leach solution (BLS) is then reapplied to the top of the pad. Ore is placed on a pad or previously leached lift by various means, including ramp conveyor belts, radial-arm and self-leveling stackers, and trucks. Once trucks are used to construct the pads, the pad can be compacted and hence the pad should be graded and ripped or scarified (roughened up) with wheeled or tracked equipment to produce shallow cuts to increase surface area exposure to the leachate."

Jan 1, 2019

By Ali M. Ghazi, Ronald J. Goble, Lowell S. Whiteside

"Geerite (Cu1.6S) is a rhombohedral copper sulphide which occurs naturally in epitactic replacement of sphalerite; cell dimensions closely approximate those of the host sphalerite.Geerite-type structures can be produced by leaching digenite (Cu1.8S) in ferric sulphate solutions. X -ray diffract ion and electron microprobe studies indicate that eight metastable geeritetype structures can be produced, depending upon the concentration of f erric sulphate solution used and the duration of the each. Although compositions cluster on or near values observed for natural phases, optical properties indicate that we are dealing with polymorphs of these phases. Leaching of chalcocite (CU2Sj in dilute f erric sulphate solutions produces similar results. In contrast, leaching of chalcocite in more concentrated solutions seems to produce true analogues of natural minerals.During froth flotation, sphalerite is activated with a monolayer of floatable copper sulphide with the composition, CuS, of the mineral covellite. However, covellite is not significantly more floatable than sphalerite, and has an incompatible structure because of the presence of covalently-bonded atoms of sulphur. Leaching ofdigenite was used to produce a polymorph of covellite with a geerite-type structure, compatible with that of sphalerite. This polymorph has a flotational behaviour similar to copper-activated sphalerite, suggesting that the monolayer has a geerite-type CuS structure. IntroductionIn an ideal close-packed sulphide structure the distance between sulphur layers, D, is equal to 2R 2/3, where R is the radius of the sulphur atoms. In sulphides with covalently-bonded sulphur layers, such as covellite (Fig. I), D will be an average of the number of covalentl y-bonded and close-packed sulphur layers, weighted as to the relative number of each type of layer. Both D and R are spacings which are readily identifiable structurally and on X-ray diffraction patterns. Goblel has shown that for copper-iron sulphides with metal-to-sulphur ratios between 0 and 2 and copper-to-total metal ratio s between 113 and I there are strong correlations between composition and measured D and R distances (Fig. 2). D can be represented by a single empirical equation relating interlayer spacing to composition; R must be represented by three equations relating the radius of sulphur atoms to composition. One of these equations (R, in Fig. 2) represents ideal close-packed behaviour, the other two represent sulphur radii greater than (R1) or less than (Rh) the ideal."

Jan 1, 1988

Abstract - A method to extract certain types of error variance information from paired data is presented, which constitutes an important tool for the calibration of Gy’s formula for variance predictions in the sampling of broken ores. The research summarized here complements publications by others on geochemical precision. The model and method proposed for treating duplicate data provide a practical means of deriving separate estimates of the purely analytical and aliquot sampling variances, from a unique set of duplicate assays, and, hence, proposes a new avenue for estimating effective mineral grain size.

Jan 1, 1998