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By P. A. Gonzalez Contreras

Scorodite is considered as a secondary mineral formed from the product of weathering of primary minerals by chemical or biological reactions. In the case of biological scorodite formation, microorganisms mimic and accelerate what in nature takes a very long time, i.e. biocrystallisation. The goal of the biological scorodite formation is to form very stable arsenic crystals suitable for long-term and safe disposal. The biological formation of scorodite is a novel combination of biological oxidation, biocrystallisation, and proper bioreactor design to achieve the biological formation of scorodite crystals in one step. We have explored simultaneous biological arsenic and iron oxidation at 30ºC and at 70ºC leading to arsenic-jarosite phases and scorodite, respectively. As biologically formed scorodite crystals are very stable (TCLP < 1 mg/L As (V)), the risk of arsenic toxicity is minimized when leaching takes place. This process is suitable for arsenic concentrations above 0.5 g/l As achieving up to 20 mg/l As in the effluent. This biological scorodite formation system is a selfsufficient bio-oxidation system and therefore many new applications can be explored such as reprocessing of arsenic trioxide, orpiment or calcium arsenate to scorodite crystals for a stable and safe disposal.

Jan 1, 2014

By J. G. Schofield, C. G. Tan, R. J. Ord

"Most electric furnaces in the nickel and copper smelting industries are still fitted with conventional electrode holders which consist of water-cooled electrical contact clamps and a pressure ring. The water cooling exerts a significant cooling effect on the electrode column. The importance of controlling the temperature of the Soderberg electrode paste at the contact clamp area is examined, using in-plant experience and computer simulation of the paste melting and baking process. In addition to the effect of water-cooling, the effect of other variables, including the mantle air temperature, the electrode current, the furnace freeboard temperature and the electrode slipping rate are discussed. Ways in which the variable heating conditions in the paste melting zone can be controlled are outlined.IntroductionIn most non-ferrous electric smelting operations, the breakage of Soderberg electrodes is an infrequent, isolated occurrence. Occasionally, however, a rash of breakages may be experienced on a particular furnace for what appears to be no obvious reasons. The extent of the breaks may not exhibit a uniform pattern; sometimes the break may be less than half a metre above the electrode tip; at other times it may be at or just below the roof level. The latter type of break is, of course, the most dangerous since it is closest to the non-baked, weak portion of the electrode paste column. No matter where the breaks occur, they result in abnormal furnace power, charging and tapping conditions and loss of production while the new electrode section is slipped and baked. On a six-electrode furnace, breakage on one electrode has the immediate effect of reducing the total furnace power by one-third. On a three-electrode furnace, the effect is more drastic, one half of the power being lost."

Jan 1, 1995

By Rick Steen, Weldon Read, Morrism Tracy T.

Edging for starter sheet blanks used in conventional copper refineries has always been problematic for getting the edging to seal and adhere to the titanium material used for the blank so that copper is prevented from plating under the edging and cause undo problems in getting the copper sheets to separate from the blanks. A method was developed at the Amarillo Copper Refinery utilizing an injection molding process that better adheres the edging material to the titanium that makes the harvesting of starter sheets much easier to the point that robots are now used to strip with and which holds up very well to the unforgiving physical nature of the electroplating process. It is believed that this technology could be successfully utilized for permanent cathodes as well. INTRODUCTION ASARCO LLC (Asarco) was organized in 1899 as the American Smelting and Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co- products (Marcosson, 1949). Grupo México, S.A.B. de C.V acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, molybdenum, selenium and tellurium. Asarco operates three open-pit mines and mills and two solvent extraction-electrowinning (SX-EW) plants all in Arizona plus a copper smelter in Arizona and a copper refinery in Texas. Figure 1 illustrates how the copper metal comes out of the ground at the mine and ends up as a refined product at the refinery. The copper refinery in Texas is known as the Amarillo Copper Refinery (ACR) and is located in Amarillo, Texas. It was built in 1975 to replace 3 other aging refineries and was designed to produce 550,000 tons (500,000 MT) of refined copper per year using conventional starter sheet technology. At the time it was commissioned it was the largest tankhouse in the world at just under 1/2 miles long under one roof.

Jan 1, 2019

By J. Poplawski

In mineral processing plants, cyclones typically perform the classification duty prior to the downstream recovery process. Particle size distribution of the cyclone overflow is an important parameter and can be viewed as the product of the comminution process. Too coarse of a product will likely have poorly liberated valuable minerals and make recovery difficult. Too fine of a product may represent a missed opportunity to increase plant throughput and/or also result in low recovery due to poor kinetics. “Near-line” particle size measurement instrumentation has been in place for several decades, its availability and low measurement frequency have typically been inadequate for reliable use in automatic control. CiDRA Minerals Processing has developed a novel and robust technology that provides a highly reliable and low maintenance system for “on-line” measurement of the particle size in the overflow of individual cyclones. The system is based around a wetted sensor design with no moving parts and provides a real-time trend of the desired target grind size parameter. The system does not require sampling and associated sample transfer piping that is prone to plugging, thus avoiding high maintenance requirements. Plant data and benefits realized from the latest installations of the CYCLONEtrac PST will be presented. INTRODUCTION Impact-based real-time hydrocyclone particle size measurement Acoustic impact-based particle size tracking is a unique method for measuring and controlling the particle size in cyclone overflow streams. The implementation of this technology is centered upon a sensor probe that is inserted into the overflow slurry stream via a two-inch (50 mm) hole in the overflow pipe (Figure 1). Particles within the slurry stream impact the surface of the probe generating travelling stress waves within the probe. A sensor converts these travelling stress waves into an electrical signal and proprietary signal processing techniques convert these signals into a particle size measurement that is output every four seconds. The sensor is constantly in contact with many particles in the slurry stream, thus obtaining information from orders of magnitude more particles than traditional sample-based technologies. The sensor has no impact on cyclone performance because it is located downstream of the hydrocyclone and the presence of an air core ensures there is no change in the back pressure seen by the hydrocyclone.

Jan 1, 2019

By W. Díaz, R. A. Parra, L. E. Arias, C. A. Toro, M. Marin, E. Balladares, V. Parra, G. Reyes, S. N. Torres, D. Sbarbaro

This work presents visible-near infrared (VIS-NIR) spectroscopy measurements, and signal analytical techniques to characterize minerals and relevant pyrometallurgical process variables for the copper extractive industry. Data signal processing techniques such as baseline correction and numerical analysis are used to estimate the continuous and discontinuous spectral components. Such spectral components are used to estimate the process temperature, and patterns such as the integrated radiation. Also, metal combustion emissivity calculation are depicted. Our findings suggest that VIS-NIR spectroscopy may be a suitable technique to assess the process condition state, appearing as an interesting sensing alternative. INTRODUCTION Although the flash smelting process is one key stage in the copper extractive industry, representing about 40% of copper matte production worldwide (Cantallopts, 2017), few attention is dedicated to develop sensing solutions to assess process variables, such as mineralogical composition and temperature, in the feeding and bleeding stages, compared to the steel industry (Strakowski, et al., 2014). In this process and other industries, e.g. the thermoelectric power generation one, combustion and particularly the generated flame are the production chain’s heart. Since the flame is a highly radiative emitting process where chemical and physical transformations take place, many works had been dedicated to characterize the combustion state by sensing its radiation using optical and photonic technologies (Ballester & García-Armingol, 2010). In this context, this work aims to contribute with visible-near infrared (VIS-NIR) spectroscopy and pyrometry techniques to retrieve relevant information from a laboratory scale flash smelting process. On the other hand, since photonic instrumentation allow us to perform contactless measurements of emitted, absorbed, transmitted or scattered radiation, it appears as a suitable technique for sensing process properties in harsh environments, e.g. high temperature processes. One of these techniques is the Visible- Near Infrared (VIS-NIR) spectroscopy, which provides information about the spectral radiation intensity distribution, in this work, the emitted flame’s radiation. It is well known in combustion research that the spectral emission from a flame is composed by a black body continuous radiation background, molecular emissions, elemental emissions and additive noise features (Arias et al., 2011). To make sense of such information signal processing techniques are needed, here we propose to analyse the continuous and discontinuous spectral components separately.

Jan 1, 2019

By T. J. Bruce, G. E. Agar, R. Stratton-Crawley

"A technique by which the design of a flotation circuit may be optimized is described and examples of the application of this methodology are given.Three interrelated criteria are defined and the application of these criteria to the selection of the optimum residence time for each stage of a flotation circuit is demonstrated. The criteria are:(1) Add no material to the concentrate that is lower in grade than the feed to that separation stage.(2) Maximize the difference in recovery between the desired mineral and the gangue.(3) Maximize the separation efficiency.Three independent systems were examined experimentally and it was shown that application of any of the criteria yielded similar results.It was demonstrated how the application of rate measurements (Criterion #2) could lead to the selection of a set of optimized times for several stages in a flotation circuit and that these could in turn be used to simulate the results of a locked cycle test. The predictions were checked against the experimental results from a locked cycle test and there was substantial agreement between the predicted and observed results."

Jan 1, 1980

By I. C. Edwards, E. O. Lilge, H. H. Mccreedy

"Introductory and GeneralTHE DRIESSEN CONE bas been used fairly extensively commercially as a classifier. Its use as a concentrator in the upgrading of ores at a fairly high ratio of concentration with concomitant recoveries has been almost negligible. Certain known features about the cone, however, such as its high throughput capacity, cheapness of construction and operation, and simplicity of design have attracted the attention of mill men. An inadequate knowledge of the operating characteristics of the cone when used as a concentrator seems to have been the main reason for its lack of use. It was for this reason that the present investigations§ were undertaken to determine the operating characteristics of the cone and its application to the concentration of uranium ores, with particular emphasis being placed on the concentration of low-grade uranium ores.The investigations were started in December, 1951, and have continued uninterrupted to the present. The initial work was confined chiefly to investigating the operating characteristics of the cone in order to establish the trends that certain variables would exert on the general metallurgy of uranium concentration. Optimum metallurgy was therefore not the prime initial objective."

Jan 1, 1955

By H. Henao, F. Canales

The present work evaluated the use of copper ore flotation tails as flux in the process of smelting copper concentrates. For this purpose, experimental and simulated liquidus lines were obtained at different ratios of tail/flux. Experimental variables included temperature, partial pressure of oxygen and sulfur dioxide and the conditions of tridymite or spinel saturation. The results indicate the feasibility of replacing the flux by increasing the temperature of the smelting process by 20°C. Results of simulation using FactSage and HSC confirm that the required increase in temperature can be achieved by increasing the flow of concentrate, enrichment of oxygen or increasing the matte grade. INTRODUCTION In the pyro-metallurgical process of copper production, the smelting stage produces two liquid phases, a sulphide phase rich in copper and another composed mainly of oxides called slag. The slag phase is the product of oxidation of the iron contained in the flotation concentrate. The smelting process which is carried out at temperatures of 1250°C, require the addition of silica as a flux and the injection of air enriched in oxygen (Schlesinger 2011). Currently, one of the most important aspects of the mining industry is the minimization of costs, the optimization of the use of available resources and the reduction of environmental impact. Under this context, the use of flotation tails from as a flux in the copper smelting process has the potential of reduced production costs and generate an environmental benefit by reduce the disposal amount of this waste material Regarding the use of copper tails as flux in the copper smelting process, a thermodynamic simulation study using the FactSage software had been reported in the literature (Parra et al., 2011). The results indicated an increase of 35°C in the temperature the liquidus for the equilibrium matte/spinel and a subsequent requirement of energy in the process of approximately 350 [MJ/ton slag]. Given that the calculated viscosity remains in the same order of magnitude, the melting temperature is a more relevant parameter for the evaluation of the use of tailings as flux.

Jan 1, 2019

By E. Faria

"The Santa Rita mine is located in north eastern part of Bahia in Brazil and is owned and operated by Mirabela Mineração do Brasil Ltda. Typical SABC circuit was designed as the preferred option for the 4.0 mtpa (500tph) to produce a P80 of 125um for flotation. Although the SAG was originally designed to operate with conventional radial pulp lifters, later it was fitted with Outotec’s Turbo Pulp Lifters – TPL (Latchireddi, 2005). The milling circuit commenced commissioning on the 24th of October 2009 and the milling circuit achieved the nameplate capacity within days. with small and relatively simple measures to rectify. Since commissioning, the SAG mill has been working in fully autogenous grinding (FAG) mode with no balls (in contrast to the estimated 10% ball charge) and has been consistently treated up to 650tph.This paper examines the comminution design process, the operating philosophies, start-up experiences, post commissioning optimization and future development works. An evaluation of mill performance relative to the design criteria for the project life to date is also included."

Jan 1, 2012

By H. A. Gorrell, S. R. L. Harding

"The potash beds in the Saskatchewan portion of the Williston Basin occur in the upper portion of the Prairie Evaporite formation of the Devonian Elk Point Group. They represent the late stage of a major evaporitic cycle. Two other evaporitic cycles are known in overlying beds, but these apparently never reached the stage of potash salt deposition. The basin in which salt deposition took place extended from the northwestern corner of Alberta southeastward across Saskatchewan into Manitoba, North Dakota and Montana. Deposition of potash salts was apparently restricted to the southeastern portion of the evaporite basin. On a regional basis, five major stratigraphie divisions of the potash-bearing strata have been made. Locally, several of these units may be divided into correlatable sub-units. The potash-bearing strata are separated and overlain by predominantly halite layers of varying thickness. Cross sections show the regional correlation of the potash-rich zones, and maps show the present distribution of the individual potash-bearing zones and the areas of richer development for each zone. The maps tend to substantiate the interpretation of considerable subsurface solution of salt and potash beds."

Jan 1, 1967

By J. D. Campbell

"Coal is one of Alberta's major fuel resources, but its distribution, especially in the flat plains region, has been somewhat obscured by surficial deposits. After a period of neglect, easily strippable plains coal is presently approaching a position of dominance in electrical power production, a position it is likely to retain for a number of decades in the face of strong competition from hydro and nuclear power. Accordingly, the Research Council of Alberta has undertaken an inventory survey of the province's supplies of this resource.In the southern part of the province and in the north-central forest-fringe area, some strippable coal is found in the Belly River Formation and its equivalents, but major strippable coal reserves in large areas of central Alberta occur within the Edmonton Formation. The survey is planned on a reconnaissance scale, drilling test holes at 2-mile intervals in selected large areas. It appears to show that, in well-settled regions, large reserves of strippable coal are only to be expected where they have long been known; major presently unknown bodies of coal must be sought in unsettled regions or at depths too great for strip mining. However, such bodies might still be economically competitive with hydro and nuclear power in the production of electric power for some time to come."

Jan 1, 1967

By D. Thibault, A. Akhiate, M. Brochu, E. Braud

Cast martensitic stainless steels, 13%Cr-4%Ni, having carbon contents between 0.018 wt% and 0.067 wt% were normalized, air quenched, and tempered at two different temperatures (550°C and 610°C). Their microstructures were characterized by optical microscopy and X-ray diffraction (XRD). Macro and microhardness, tensile strengths, and impact resistance were quantified for each material and condition. Results show that the prior-austenite grain size is constant through the materials but the percentage of reformed austenite, contained in the martensitic matrix, depends strongly on the material chemistry and on the tempering temperature and on its duration. It is observed that, independently of tempering conditions, an increase in carbon content increases the material hardness and tensile strengths, whereas the elongation remains constant. In contrast, the results of Charpy type impact toughness tests show a different trend. The material containing the average carbon content (0.034 wt%) is significantly tougher than the two other alloys. Surprisingly, the toughness of the steel containing 0.034 wt% carbon was found independent of the reformed austenite content. It is thus concluded that carbon and reformed austenite contents are not the only parameters affecting the toughness of these steels.

Jan 1, 2014

By B. Misra, B. S: Sastry, Kollu S. Rao

"This paper reports the results of a finite element study of the geothermal heatflow into dry mine airways. For isotropic and unsteady state conditions the heatflow into mine airways is studied for a range of surface heat transfer coefficients between rock and air, and age of the airway. Dimensionless temperature gradient values are presented in tables for different values of Boit and Fourier numbers and the results are compared with Starfield tables and Gibson algorithm. It is found that Starfield tables have consistently over-predicted the G values with errors ranging from 2% to 10%. The differences between results obtained from the finite element study and the G values calculated from Gibson&apos;s approximation method are mapped. The small error values over a large range of Fourier and Biot numbers confirm the suitability of Gibson&apos;s algorithm to rapidly calculate G values for estimating the heat transfer from surrounding rock to mine air.IntroductionIn many underground mines heat is a major problem, and the provision of acceptable working conditions requires considerable expenditure on ventilation systems. The rational design and operation of these systems depend upon an understanding of the various sources of heat in the mine. The natural source, i.e. geothermal heat, contributes up to 80% of total heat added to mine air and it is difficult to analyze and predict the heat owing to a number of influencing variables. The problem of geothermal heat flow has been studied by many investigators (Goch, 1940; Starfield, 1966; Hemp, 1987; Amano et al., 1982; McPherson, 1986).The primary concern of this paper is to develop a better ready reference dimensionless transient temperature table for estimating heatflow at any stage of mine airway life."

Jan 1, 1994

By Richard Stewart

There are highly competitive world markets in most of the minerals being mined today. The high standard of living we enjoy in North America results in ever increasing productivity through mechanization and automation. Conventional underground and open-pit mining practices throughout the world are constantly changing to reflect the engineering advances of our technology. New records in tunneling, shaft sinking and excavating are being established. Larger and faster equipment is in production. Mining operations are being studied in detail to improve materials, methods and machines. Standards and controls are being established to measure the performance of people and equipment. These steps all tend to improve our present performance. In addition to these short-range improvements, however, there are the basic research and applied research studies which are aimed at developing entirely new approaches to our mining problems. Basic research in rock mechanics is coupled with applied research in rock penetration, fragmentation and stabilization.

Jan 1, 1963

By G. J. Borbely, E. A. Devuyst, V. A. Ettel

"A new method for oxidative destruction of cyanide in industrial waste waters and slurries, such as gold mill barren liquors, tailing slurries and flotation tailings has been developed at the Inca research laboratories. Rapid decomposition of cyanide and related species is attained by treating the waste waters with a mixture of S02 and air at controlled pH and in the presence of a small amount of copper which acts as a catalyst. The approach selectively oxidizes cyanide and metal cyanide complexes, and also removes iron cyano complexes which are not removed by alkaline chlorination.The new method is shown to be less reagent intensive and therefore more economical than alkaline chlorination for treating gold mill and flotation waste waters. INTRODUCTIONOver 90% of the gold mined in Canada is extracted from the ore by ""cyanidation"". Wastes from the process consist of tailings which contain free cyanide, cyanide combined with heavy metals, thiosalts and thiocyanates. Because of the concern over the effect of toxic cyanides on the environment, all cyanide containing effluents will have to be treated in the future to meet certain government set concentration limits."

Jan 1, 1982

By C. H. Ash

"Abstract-The Red Chris Cu-Au deposit (522.7 Mt at 0.35% Cu and 0.27 g/t Au), northwestern British Columbia, is one of several pre-accretionary porphyry systems in the Cordillera of western Canada. It is hosted by an Early Jurassic hornblende monzonite to quartz monzodiorite porphyry which forms part of a suite of dikes and stocks that intrude Late Triassic volcanic strata. Major and trace element chemical data suggest that these Early Jurassic intrusions have compositions which fall on the boundary between alkalic and calc-alkalic compositions. Alteration and mineralization in the Red Chris deposit are more typical of calc-alkaline porphyry systems with abundant potassic, sericitic and argillic assemblages and quartz-rich stockworks. It lacks Na- and Ca-bearing silicate assemblages which characterize the alkalic porphyry deposits of British Columbia. One of the more unusual features of the deposit is the abundance of carbonate alteration and veins which occur throughout the hydrothermal history of the deposit. This type of alteration and veining is more typical of alkalic porphyry deposits. The composition of the carbonates vary both temporally and spatially with different alteration zones. Potassic zones, which are characterized by orthoclase±albite±quartz±chalcopyrite±bornite± magnetite±hematite and Au/Cu ratios of 1:1 (g/t Au:% Cu), contain minor siderite veins and alteration. Quartz-sericite-carbonate (QSC) zones overprint earlier potassic alteration and comprise quartz+ankerite+sericite+pyrite+chalcopyrite with Au/Cu ratios of 0.5:1 (g/t Au:% Cu). Ankerite is the main carbonate in this stage but has a variable composition with a more Fe-rich variety associated with mineralized veins. Localized chlorite-carbonate alteration zones, characterized by chlorite+ carbonate+quartz±kaolinite±pyrite±gypsum and high Au/Cu ratios [2 to 3.5:1; (g/t Au:% Cu)], contain predominantly calcite. Late stage carbonate-gypsum veins have an ankerite to dolomite composition which is very similar to the regional carbonate alteration and veins."

Jan 1, 1997

By S. Banisi, J. A. Finch, A. R. Laplante

"A technique for on-line simultaneous estimation of gas and solids holdup (volume fraction), based on a combination of conductivity and pressure difference measurements, is proposed and tested in a laboratory flotation column (10cm in diameter and 447cm in height). Fundamental concepts underlying this technique and the effect of relevant parameters are discussed. In the studied range, 3-30 %v/v gas holdup and 2-18 % v/v solids holdup, experimental results showed good agreement between the estimated and actual holdup values (as determined by an isolating technique). The relative accuracy of the solids holdup estimation increased when solids density or solids concentration increased. Frequent re-calibration of pressure transducers was found necessary for accurate phase holdup estimation.IntroductionGas holdup is a key parameter in controlling the performance of flotation columns. For example, flotation rate is affected by bubble size and gas rate both of which, in turn, affect gas holdup. Moreover, gas holdup also determines the slurry residence time which indicates a direct influence of gas holdup on recovery.Gas holdup determination has been the focus of many studies (e.g., Castillejos, 1986; Marchese et al., 1992). Some of the techniques which have been used are given in Table 1."

Jan 1, 1994

By Liu Yulin, Zhao Yi, Tan Qi, Liu Lei

"Hydrotalcite is one kind of layered double hydroxides, and has special crystal chemical characteristics. Due to its good thermal stability, hydrotalcite used as the PVC heat stablier has attracted scientists’ attention. In this study, nano-hydrotalcite was synthesized by the method of mechanochemistry/crystallization, using brucite, Al(OH)3 and Na2CO3 as raw materials, and added into PVC to investigate the effect of hydrotalcite on thermal stability of composites. The synthesis mechanism was suggested by virtue of XRD, FE-SEM, FT-IR. It has been indicated that at the first of dry milling process, the parical sizes of brucite and Al(OH)3 decrease, while specific surface areas of them increase by the action of mechanical force, until produced amorphous particles. In the process of wet milling, metal ions in the amorphous body, which has high surface energy, can easily react with H2O, and produce the precursor of Mg6Al2(OH)18•4.5H2O, which has the same crystal structure as hydrotalcite. Under the hydrothermal condition, anions of OH- in the interlamination of precursor are exchanged by CO32- in the solution and nano-hydrotalcite is generated at last. The thermal stability was characterized by Congo red method. The results have revealed that hydrotalcite is one kind of long-term heat stabilizer, and residual stability time increase with the rise of added hydrotalcite amounts.INTRODUCTIONHydrotalcite, one kind of anionic clays, has been attracted a great interest for researchers because of their unexpected physical and chemical properties. The general formula is Mg6Al2(OH)16CO3·4H2O, where Mg2+ and Al3+ occupy octahedral positions in the brucite-like layers, and CO32- is an interlayer anion (Hoyo, 2007). Hydrotalcite is widely used in the fields of chemical engineering, materials engineering, environmental protection, medicine, and so forth, owing to its unique capability of adsorbability, ion exchange and thermal stability (Rozov, Berner, & Taviot-Gueho, 2010; Iwasaki, Yoshii, & Nakamura, 2012; Ay, Zümreoglu-Karan, & Temel, 2011; Cavani, Trifiro, & Vaccari, 1991; Li & Duan, 2005; Lin, Wang, & Evans, 2006). As a result, the study on synthesis and application of hydrotalcite has received considerable attentions."

Jan 1, 2016

By Nitin Bhavsar, Kaushik Vakil, Lakshmikanth Reddy, Sanjay Sarkar, Tathavadkar. Vilas, Bhavin Desai, Raghavendra Adiga

Gold and platinum group metals (PGM) do not dissolve in sulfate electrolyte from anode during electro-refining of primary copper. The PGM form solid ‘slimes’ which accumulates at bottom of the electrolytic cell. Typically, 8 to 10 ppm silver is present in copper cathodes, which is equivalent to almost 2% of silver loss during electro-refining. The silver can be cemented with cathode copper as soon as it is dissolved into the electrolyte from anode or during entrapment of slime particles in cathode. Over a period of time, the concentrates grade has deteriorated and change in type & amount of impurities in concentrate has resulted in higher silver loss during refining process. Therefore, an in-depth investigation was carried out in both fire- and electro-refining processes to understand the root causes of higher silver loss in copper cathodes. The detailed characterization and the plant data analysis were carried out. The results of study revealed that higher silver loss in 3rd crop cathodes as compared to 1st and 2nd crop cathodes from same anode. In anode silver was present in two forms, dissolved in copper (solid solution) and in slime phases such as Cu2-xAgxSeTe. SEM-EDX study of anode cross section confirmed higher silver and oxygen content in central region (core) of anode as compared that in both air and mold sides. This is due to non-uniform cooling of anode which was confirmed by the solidification modeling. Higher concentration of oxygen & silver at core of anode rised Ag+ concentration in electrolyte and slime particles during 3rd crop. The results of study were used to optimize the anode cooling process and also electrolyte chemistry to reduce the silver loss. The details of study carried out are discussed in this paper using the results of modeling, characterization and experimental studies. INTRODUCTION In the electrolytic refining of copper, fire refined copper anodes are used as raw material. Anodes contains copper of the range 99.5 to 99.6%, rest being the impurities. Hence, the purpose of the refining is (1) to remove the impurities so that final cathode conforms to the LME specifications and also (2) to recover the precious metal from the anode copper. When anode is dissolved, most of the impurities reports to the anode slime settled at the bottom of the cell, and rest dissolves in the electrolyte. Dissolved impurities remains in electrolyte and are removed during electrolyte recycling. However, sometime dissolved impurities and slime particles get entrapped in cathode due to disturbances in operational conditions. Metals dissolving in the electrolyte are the elements such as Ni, Co, Fe, Zn. The electrode potential of As, Sb and Bi being close to that of copper, these elements partly dissolve in the electrolyte. Noble metals like Ag, Au, Pt and Pd are generally insoluble and are thus expected to report to the anode slime. A small amount of the sliver content from the anode is dissolved in the electrolyte. Because the dissolved silver electroplates on the cathode at a smaller applied potential than copper, the cathode typically contains up to 8 ppm of silver. This is referred to as ‘silver loss’ in cathode (Cooper, 1987). Fortunately, silver is a rather benign impurity in copper due to its electrical conductivity being higher than copper. However, higher silver loss in cathode is loss of revenue for Copper smelter due to significant difference in their LME price.

Jan 1, 2019

By S. Espley, G. Tan

"Inco&apos;s Little Stobie Mine is a low-grade nickel operation producing approximately 4()()() tons per day. Backfill has never been an economical option at the mine; therefore, the only viable type of mining in the upper zones has been by sub-level cave. This mining method allows for the draw-down of a rock cover into the empty stopes to provide stability to the over-all rock mass. In the lower areas of the mine, bulk blasthole mining methods have taken place, without rock fill, resulting in extremely large open stopes. As the mine reaches its final stage of recovery, it is inevitable that the hangingwall of the large voids will undergo tensile failure via spoiling.This paper deals with the collaborating efforts of Inco&apos;s Rock Mechanics group and the Little Stobie mining operations toward the successful recovery of the ore zone remnants such that the inevitable failure, and time of failure, of the rock mass is ""controlled"". Within the mining scheme, several key requirements had to be met to satisfy the operations: (1) production rates; (2) good blast fragmentation; and (3) secure pulling-horizons. A full-scale rock mechanics study was carried out involving: numerical modelling studies; pulling ellipse analyses; blast design, monitoring and analyses; laser profiling; and time domain rej7ectometry (TDR) instrumentation. The final recovery scheme, employing a controlled failure, involves recommendations on: (1) blasting techniques; (2) support systems; (3) mining sequences and scenarios; and (4) monitoring systems."

Jan 1, 1994