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By Faidel VV, Yushina TI, Yagodkina NG, Yatsimirsky AK, Chanturiya VA

Among the problems of the flotation of sulphides by the thiol collectors is the dependence and varieties of the flotation starting with the time and oxygen contents in the slurry. For sulphides, the flotation stage follows after the electrocatalytic oxidation of the collector with oxygen on the surface of the conductor minerals. The necessity of the oxygen for sulphide flotation (Plaksin and Bessonov, 1957) is in accordance with a corrosion model of a collector surface sorption (Salamy and Nixon, 1954). As Golikov and Nagimyak (1961) showed, the sulphides possess catalytic activity which provides the autoxidation of the xanthates in the sluny to the dixanthogen. This stage can be rather protracted, which limits the speed of the total process. Disulphides constitute important collectors for the sulphide flotation and the optimal degree of the xanthate oxidation is about 20 per cent for different ores (Abramov, 1978) or, following Chanturiya and Nazarova (1977) the surface compositions for various sulphide ores are different and an optimal oxidation degree is variable from five to 25 per cent according to the ore nature. The optimisation of the surface composition is possible by application of the dixanthogens, or by a partial chemical, electrochemical, or catalytic oxidation of xanthates (Desains, 1847; Schall, 1896; Vigdergauz, 1989). According to Rand (1977) and Vigdergauz (1991) sulphides possess different catalytic activities for oxygen electroreduction. In neutral solutions, for example, the following decrease in the order: FeS2 (Fe,Ni)9S8 CuFeS2 FeS; Cu5FeS4 Cu2S; PbS (Vigdergauz, 1991). For the cases of low catalytic activities of the sulphides, the preflotation oxidation of xanthate could be useful to optimise the process kinetics.

Jan 1, 1993

By Pigdon SP, Anderson RM

The production of stabilised backfill at mine sites commonly uses Portland cement as the binder. Calcined gypsum has cementing properties and is cheaper to produce than cement. This paper discusses the strength of fills stabilised with calcined gypsum. Laboratory tests were carried out on specimens prepared from tailings obtained from four different sites to allow for the wide variety of tailings found in practice. The results show that the gypsum-based fills can achieve a strength of I MPa using around two and a half to four times the corresponding amount of cement.

Jan 1, 1998

By Dodd SF

Valuation of mining companies and their underlying assets prepared by brokers' analysts are, by necessity, approximations. The reliability of the valuations is entirely proportional to the quality of available data, the reliability of forecasts and the nature of underlying commodity price assumptions. The latter is perhaps the greatest single cause of gross variations in company and asset earnings estimates and- valuations. Assumptions are often necessary regarding commodity price achievement based on commodity hedge positions. Public disclosure from listed companies provides a sound base from which to project earnings, cashflows and balance sheets. The uncommon disclosure of projected production and cost schedules often reduces the reliability of future estimates. The application of reserve and resource estimates is contentious with practitioners applying differing weightings to importance of resources in estimating mine lives (and therefore cashflow streams). Valuation methods applied in equity markets usually focus on relative value and the identification of pricing anomalies. The commonest ""rules of thumb"" applied in the valuation of mining companies (and therefore their underlying assets) is with the use of year specific price/earnings (P/E) and price/cashflow (P/CF) ratios, with low multiples suggesting undervalued assets, high multiples overvalued situations (but these rules can often be clouded by market expectations of underlying commodity price movements). Another simply applied valuation tool is to examine the examine the value placed on reserves and resources by the market. Inexpensive gold in the ground (expressed as $ of market capitalisation per ounce of reserves or resources) might indicate a buying opportunity, but the market does discount the value of gold in the ground prior to mine development and where development risk is perceived.

Jan 1, 1994

By S T. L Harrison, J-P Franzidis, M Becker, N Dyantyi, J L. Broadhurst

Gold mining is a major contributor to the South African economy, but is associated with several environmental issues such as acid rock drainage (ARD). ARD is due to the oxidation of sulfides in gold tailings and is characterised by low pH, high sulfate content and elevated concentrations of heavy metals that contaminates scarce water resources and subsequently limits the use of such waters without treatment. Treatment strategies can only be implemented if the acid-generating potential of mine wastes is effectively predicted using common static and kinetic acid prediction tests. The choice of test performed is usually a trade-off between the number of samples, speed of the test, cost of the analysis and level of information obtained. Often the results of these various tests are not consistent with one another. This study uses mineralogy to analyse biokinetic test results of a Witwatersrand gold sample in order to improve the understanding of behaviour of mine wastes under different ARD prediction test conditions.All ARD prediction testing methods investigated in this study showed that the gold sample is considered to be potentially acid forming with net acid generation (NAG) pH of 2.5 and net acid producing potential (NAPP) of 36 kg H2SO4/t. Results of biokinetic test showed that ANC was consumed within four days confirming acid producing potential of the sample with low neutralising potential as observed from acid base accounting (ABA) (4.7 kg H2SO4/t) and mineralogy (4.9 kg H2SO4/t). Results generated in this study demonstrated importance of mineralogy in both understanding the controlling reaction mechanisms playing key role in ARD formation and its capability as a prediction technique. Future work will focus on the application of mineralogy in interpreting the behaviour of mine waste under different static test conditions with a view to assessing their applicability and reliability in estimating potential acid generating characteristics of gold tailings.CITATION:Dyantyi, N, Becker, M, Broadhurst, J L, Harrison, S T L and Franzidis, J-P, 2013. Use of mineralogy to interpret laboratory-scale acid rock drainage prediction tests - a gold case study, in Proceedings World Gold 2013, pp 519-526 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By T Isaksson, J Anderson

The procurement process for underground construction contracts, in particular those contacts involving tunnel boring machines (TBMs), is subject to many complex and inter-related variables, including national and local politics, public policy, community involvement and media attention û as well as strict environmental and legal requirements. Other restrictions include the time available to adequately investigate geotechnical conditions and viable technical options to determine the best construction methodologies û including selection of tunnel boring machine characteristics and, those construction means and methods suitable for the specific geotechnical and environmental conditions. The latter are, most often, quite imperfectly understood. æGetting it rightÆ implies that an optimal configuration û of machine type, characteristics and associated methodologies û can be found and successfully implemented for a particular project. æFrom the beginningÆ implies that the lack of time issue can be successfully resolved. Within an international context this paper highlights a number of issues of concern which relate to tunnel procurement systems and the ways in which certain key processes are managed during planning, design and construction. The authors argue that there is considerable room for improvement in the way tunnelling projects are undertaken and an approach is discussed which has the potential for substantial gains in cost and schedule and reduction of risk. Savings, however, may only be fully realised if the new methods can be fully implemented by all parties involved. This, we believe, will require the rejection of ætraditionalÆ forms of management and procurement with associated changes in the roles and responsibilities of owner, engineer and contractor. Additionally, risk identification, assessment and mitigation are essential cost and schedule control process which have, to this point, been underutilised by the underground construction industry.

Jan 1, 1999

By G R. Hancock, W D. D P Welivitiya

is placed in a waste rock dump, which is usually later reshaped to be erosionally stable, initiate and sustain vegetation and ultimately integrate with the surrounding undisturbed landscape. However, it is unclear how this exhumed material will weather and evolve for most sites. Also, there is a lack of data on the weathering of post-mining materials. If weathering is better understood, then there is the potential to improve rehabilitation outcomes. To improve predictions of the evolution of soil properties and weathering-limited erosion, estimating the rate at which fine, transportable material is produced from the weathering of larger, non-transportable particles and the resultant fragment size distribution and how that distribution evolves over time is necessary. This study examines the weathering process for four different coalmine waste rock materials for a Bowen Basin, Queensland site. Materials obtained from various areas of the coalmine were subjected to cyclic wetting and drying and heating and cooling. Particle size distribution and other material properties were explored after each experimental cycle to ascertain how the material changes during the experimental cycles. The particle size distribution data of wet and dry cycles were used as input data in a numerical weathering model to explore the dynamics of the weathering process for each material sample. A Monte Carlo framework was employed to assess the geometry of the weathering products, weathering rate and the number of daughter particles produced within a weathering cycle. Then the SSSPAM Landscape Evolution Model was used to evaluate the influence of weathering on erosion and landscape evolution of a post mining landform. SSSPAM simulations with: (i) active weathering and (ii) without weathering were run for each material. The erosion rate and the overall landform structure were then compared between weathering and non-weathering simulations.

Aug 2, 2023

By S Wainio, P J. Beckett, T Miller

Lichens are a symbiosis of fungi and algae. Air borne elements and gases are absorbed very efficiently over the entire surface of the lichen, because they have no protective structures such as a waxy cuticle or stomata. A survey in 1977 (one year before the Sudbury Regreening program began), indicated that several Cladonia spp had invaded the soil in Sudbury’s open birch woodlands. Pollution sensitive species such as Cladonia rangiferina and C. mitis occurred 20–25 km from the smelters. It was anticipated that the improvements in air quality and reclamation efforts would allow a natural invasion of pollution sensitive species into what once was a lichen desert that surrounded the smelters. The purpose of this project was to study the invasion of terricolous (soil-inhabiting) communities of lichens and mosses on reclaimed land in the Sudbury region 45 years after commencement of the Sudbury Regreening Program.

Aug 2, 2023

By Falbo A, Barbaro M, Esposito MA, Passariello B

Acidic reductive leaching is one of the best known and most widely employed chemical processes for beneficiating minerals of industrial interest. Conventional acidic leaching with sodium dithionite (Na2S2O4), employed to bleach industrial minerals used in the production of ceramics, glassware, paper etc, does not always allow products of high quality to be obtained. In the work reported here two reducing agents, ascorbic acid and oxalic acid, have been employed in a medium acidified by means of sulphuric acid. Continuous systematic tests have been performed on a kaolin sample containing 0.8 per cent Fe2O3, adopting various operating parameters such as, leaching time, temperature and reagent concentration. In each case the total quantity of bi- and trivalent iron dissolved was ascertained. Removal of 80 per cent and 100 per cent of iron with ascorbic and oxalic acid respectively was obtained, while less than one per cent of iron was dissolved in the presence of sulphuric acid only. Products having a very good degree of whiteness (92 - 94 per cent) were obtained, whereas with sodium dithionite the degree of whiteness was in the 85 to 88 per cent range. The best conditions identified were applied to a sample of quartz for the removal of ferric impurities.

Jan 1, 1993

By Jarvis ST

Colliery spoil is the major constituent of colliery spoil 'rockpaste' which has been used to infill abandoned limestone mines in the West Midlands of England since the early-1980s. The other constituents of rockpasle are pulverised fuel ash, lime and water. A key property of the rockpaste is its ability to flow within the mine workings over considerable distances before setting. This paper describes the work carried out to identify suitable sites as sources of colliery spoil for making rockpaste and goes onto consider the flow properties of the material and the monitoring methods used on-site. A full-scale trial comprising mulling a 6600 nt' section of an abandoned mine was conducted prior to the mulling of the Littleton Street Mine which had a volume of about 500 000 m'. As well as describing the methods used for monitoring the movement of rockpaste material, a description is also given of a dip-meter developed specifically for the purpose of measuring the level of paste in the mine. This paper shows how a colliery spoil based paste has been successfully rued for infilling abandoned mine workings. The monitoring systems developed for use in the two case studies presented in this paper are now being used extensively for infilling other abandoned mine workings. To-date over I I mines with a total volume exceeding two million cubic metres have been backfilled.

Jan 1, 1998

By R Strand, B Usher

Environmental compliance and mine designs are increasingly including assessment of flows and water qualities as a key driver to decision-making over life-of-mine. Integrated site-wide water quality models linked to dynamic water balances have been used for regulatory submissions, feasibility studies, operating mines and mine closure studies. These models, developed in GoldSim, link aqueous chemistry to the physical system of the site-wide water balance. Geochemical mechanisms included are determined from geochemical characterisation and site water monitoring, depending on the data availability at each site. External geochemical modelling using PHREEQC, version 2 (by D?L?Parkhurst and C?A?J?Appelo) and Geochemists Workbench (GWB), (by C?M?Bethke and The Board of Trustees of the University of Illinois) identifies the most important geochemical processes to be included in the model as a series of geochemical mechanisms which include source term loading rates, pH-buffering and equilibration of water quality. Water balance components include seasonal flow variability; waste facility water storage and system lags; run-off variability; milling processes and tailings production as a function of ore types; simulation of automated and scheduled maintenance of settling ponds; water re-routing for water treatment and freshwater demand, usage and storage.Case studies illustrating the use of these models for regulatory submissions and mine feasibility studies in a variety of climatic and regulatory environments show the utility and applicability of these models. Site-specific examples of these models developed by Klohn Crippen Berger Ltd are currently used at operating mines across the world. One of the larger mines where this is used is a mature poly-metallic mine in South America where the model has aided mine managers in understanding how various planned initiatives and potential water options will result in changes to flows and water quality. It is used regularly to inform water and waste management to minimise impacts to the receiving environment as a consideration of both flows and concentrations. The mine has also used the model in support of water treatment design, regulatory submissions and mine closure planning.Further examples of feasibility and operational/compliance assessment in arid and strongly seasonal environments for planning, regulatory and closure consideration of mine wastes and pits have shown the utility and usefulness of these approaches for a range of mining operations at various stages of mine life.CITATION:Strand, R and Usher, B, ?2014. Integrated site water balances and water quality models for decision-making over life-of-mine, in Proceedings Life-of-Mine 2014 , pp 271–284 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By J Poniewierski, Varcos D

Efficient blasting requires constant vigilance with respect to the actual layout being used in the field. Objective measurement techniques are required in laying out a pattern as the 'by eye' or 'thumb suck' methods cannot guarantee consistent results in layout. Erratic blast results are the consequence of such an approach. In a case study at Sons of Gwalia mine, it was demonstrated that incorrect front burdens had a snowballing effect on otherwise carefully laid out blasts, resulting in both excessive amounts of boulders caused by preconditioning of bench fronts and tops, and tight digging. Both problems caused lower excavator productivity and excessive excavator damage, as well as making it difficult to set out subsequent blasts correctly. Several field measurement methods are available to aid in determining correct blast layouts and one is described in this paper.

Jan 1, 1994

WaihiÆs Cornish Pumphouse is located on the edge of town in a dynamic and changeable area where history affects the future. As in any successful project, ingenuity and team work have been significant factors in the planning and implementation of the buildingÆs relocation.   Work around the Pumphouse site commenced circa 1900 with preparation to sink the No 5 shaft. Construction of the pumphouse and the steam driven C pump was completed by 1904 with hints of what was to come evident in 1905 as the No5 Shaft collar had sunk 350mm in four years. By 1907 surface cracking developed over the Milking Cow cave area and in 1913 200 mm was cut off the main pumping rod as the ground was sinking at a rate of 25 mm per year.   In 1913 ground around No 6 shaft had subsided 600 mm.It was also the end of an era as steam gave way to hydroelectricity and electric pumps replaced the C Pump. C Pump was maintained as a backup from 1913 to 1929 and then finally scrapped. 25 years of underground caving operations removed approximately 400 000 cubic metres of ore leaving a 7 ha collapse crater that eventually became known as the mine lake.   On the edge of town a tension zone over the Royal Lode began to develop 50 m diameter chimney collapses as large scale blocks relaxed into unfilled stopes in the old Martha underground mine. After the 1999 collapse part of the main street was closed and after the 2001 collapse Hazard Zones were declared, more streets closed and areas evacuated and retired from residential use.   By 1984 the Pumphouse has approximately one degree of tilt and in 2002 tilt on the Pumphouse accelerated briefly and then settled down. Tilt accelerated again late in 2004 and a scoping study was initiated to define protection options for the pumphouse. The Martha Mining Licence requires Newmont to 'Take whatever precautions are necessary to protect the old Cornish Pumphouse adjacent to No5 shaft' and viable solutions needed to found.   Any work on the Pumphouse comes standard with a wide range of stakeholders, governing agencies and legal framework to consider. Land Information New Zealand (LINZ) is owner and administrator of the pumphouse.

Jan 1, 2006

By T Laing, M A. Abdalla, P Hagan

Open pit operators are facing a number of challenges in the area of blasting and blasting processes, such as wall control, quality of fragmentation, explosives consumption and vibration. Remaining financially viable is one of the most significant objectives for mining professionals as they work through the blasting challenges within the mining chain of processes. This objective is such a significant challenge, primarily due to the high consumption of materials and the direct consequences on the downstream processes in the mining work flow, including loading, hauling, crushing, milling and mineral concentration. This paper reviews and discusses a technique to achieve this objective, namely air-decking. The performance in a number of mines around the world is reviewed focusing on the economic contributions of air-deck blasting. Various scenarios are investigated and simulated, covering both conventional and air-deck blasting, using JKSimblast software. The scenarios explore a range of issues and found that optimum results could be achieved with a minimum amount of explosives. The results obtained from the simulations were verified with blasts at Rixs Creek Coal Mine, Australia. Based on the verification results the simulations were then modified to more accurately model the actual conditions and parameters on site and to ensure that the models derived meet the production and control requirements at the mine site. Ultimately, overall analysis and comparisons were applied to the outcomes of the conventional and air-decking blasts revealing a reduction in material consumption of around 25 per cent with consequential savings and up to a 30 per cent reduction in ground vibration.CITATION:Abdalla, M A, Laing, T and Hagan, P, 2012. The contribution of air-deck blasting to open pit mining economics, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 7-12 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By L Alem

In the field of mineral extraction, complex technologies are being introduced in mines, operators/technicians rely on assistance from an expert (or more) in order to keep their machines functioning. Personnel with such expertise, however, are not always physically on-site. There is a growing need for innovative technological solutions to support effective delivery, just in time, of remote guidance between an offsite expert and an on-site maintenance operator. To meet this need, we have, as part of our Human System Integration project within the CSIRO’s Minerals Down Under (MDU), Transforming the Future Mine theme, explored the usefulness of a number of emerging technologies including: augmented reality, wearable systems and touch table interfaces. This paper presents ReMoTe, an augmented realty system for remote guiding using a touch table interface for the expert station and a combination of augmented reality and a wearable system at the operator end. In designing this system we were interested in exploring the extent to which it can increase the productivity and safety of maintenance personnel. This paper also presents Mobile ReMote, our recent development of a fully mobile remote guiding system. In Mobile ReMote, both the expert and the operator are using a near eye display and wearing a light computer in a back pack. The expert is able to guide the operator using his/her hands on the virtual display, while the operator is able to see the instructions on the rear eye display. Workers in the mining industry are highly mobile, a mobile expert and operator station will meet this need.

Nov 22, 2011

By Gregg PEH, Horne D, Bolan N, Stewart RB

The Tui mine site is situated on the NW flank of Mt. Te Aroha, at approximately 400 m altitude. During underground mining operations two lead-copper-zinc ore bodies were exploited and processed on site. The legacy of the mining operation is a barren dam containing over 100,000 m3 of sulphide-rich tailings. The Tui mine site is arguably the worst case of environmental degradation resulting from past mining activity in New Zealand. Although the impacted area (approximately 4 ha) is extremely small by international standards, acid mine drainage (AMD) emanating from the abandoned tailings dam and mine adits has severely contaminated local streams and prevented natural plant recolonisation of the site for more than 20 years.

Jan 1, 1995

By S S Solomons

In 1991 the uranium spot market price dropped to approximately US$7/Ib U308, a historical low in real terms and the short-term outlook for the industry in the next five years was grim. At this time the Ranger operation was producing uranium concentrate at its design capacity of approximately 3 000 tonnes/year. The loss of two major long-term contracts owing to price and reduced power utility demand due to excess inventories meant that the company could not match production to sales. Continuance at this production level would have resulted in a rapid buildup of product inventory and the tie-up of significant cash reserves. After analysing various options, an innovative operating strategy was devised such that production and sales were approximately balanced without a significant impact on the unit production cost or a long term effect on the plant or operation. A campaign mining/milling operation commenced and approximately 40 per cent of the workforce were retrenched. Multi-skilling of all employees was a critical aspect of ensuring a successful outcome. This paper examines the strategy and reports on the success of the operation two years after the restructuring exercise was effected in November 1991.

Jan 1, 1994

By Marshall T. E, Finfinger G. L

Gulf Coast domal salt mining operations have had sporadic encounters with methane gas emitted without any warning. In virtually all confirmed cases, the methane was localized in methane enriched zones. In a few cases large quantities of methane were expelled rapidly with salt outbursts, resulting in dangerous methane concentrations. Estimates of methane liberated by face blasts in methane-enriched areas is needed in determining how much air should be supplied to the face for proper dilution. A relationship between the gas content of salt samples collected from the face and the amount of methane liberated would be helpful in estimating how much methane will be produced by a face blast. Little is known about the layering or stratification of methane in large area-low velocity airways. This publication reports on three tests conducted by the Bureau of Mines which monitored the immediate return air of four faces during blasting. The test locations were in a methane gas-enriched section that had previously experienced two large outbursts and many smaller ones. A comparison was made between gas content values of face salt samples from the dissolution test and the gas liberation quantities. The characteristic movements of the methane in a large room with low air velocities were charted. This will help to better understand the factors involved in proper placement of methane sensors as a warning system.

Jan 1, 1988

The purpose of this paper is to look at the costs of tailings disposal, and in particular the comparative costs of different disposal methods in different situations. Costs are often the hidden design parameter. We know that they are important but sometimes feel that it is not very respectable to talk about them in public. It is better from a public relations point of view for it to appear that the decision-making process is driven by environmental factors or best practice rather than looking for the cheapest option. But this presumes that the two are mutually exclusive and this need not be so. These issues are discussed later in the paper. It is also commonplace for the scale of the mining operation to change with time, typically involving increased throughput rates and total tonnage. New ideas in tailings disposal make their appearance. The regulatory attitude can change. Having made a decision about the disposal method at the time of original feasibility study and design it is easy to suppose that the mine is æstuck with itÆ. But that also need not necessarily be so. Careful costing of options may reveal that a switch in method could be cheaper in the long run. The designer will often tend to think in terms of initial earthworks and site development costs. Aspects of power consumption, labour, and periodic campaigns to move tailings pipelines and carry out embankment raises are either overlooked or not given the same emphasis. This can distort the evaluation process. It is productive to think in terms of dollars or cents per tonne as a basis of comparison, not just the total sums. Tailings disposal can cost from as little as 10 - 20 ó/t to over $1.00/t which is a big range. There may be good and unavoidable reasons for the high figure but there would need to be to justify being so far over the industry average. At the same time, mining and processing costs, at least for gold, are around $15 - 20/t. Viewed from this perspective tailings disposal will always be a relatively small component of the annual budget.

Jan 1, 2000

By S D. Golding, K Baublys, V Nanjappa, C J. Moran

Water reuse is becoming an integral component of the water management strategy on mine sites. This practise is being driven by corporate sustainability goals, community and societal pressures to demonstrate improved water stewardship, as well as climate and regulatory pressures. However, water reuse often results in water quality compromise which can then result in decreased recovery through problems in processing circuits, product quality, and an increased likelihood of discharge of water that cannot meet environmental regulatory requirements. On most mine sites, there is usually a disjuncture between water quantity management and water quality management with the latter being managed solely as an environmental problem. It is becoming increasingly clear that water quality and quantity must be managed as an integrated system. In order to integrate water quality and quantity management to achieve multiple objectives the dynamics of water and constituents must be understood. Using examples from a study being conducted at a coal mine in the Bowen Basin, this paper will outline the dynamics of water and salts on the site.

Jan 1, 2009

By D Craw, C Smith, C Martin

The Wangaloa coal mine closed in 1989, and an attempt to grow Pinus radiata on quartz-rich overburden dumps was not successful. The site is currently being rehabilitated with re-profiling and native plant establishment. Plants are being established in a range of substrates that consist of variably disaggregated Tertiary coal measure sediments derived from the mine sequence. This material has low organic matter content (typically <10 %), originating from coal fines or carbonaceous sediment. Substrate samples were collected during December 2003 from a range of sites varying in age, slope, and parent material. Nutrient analysis includes nitrate, ammonia, total N, total P, available P and readily exchangeable base cations. Total nitrogen and phosphorus are low on areas of recently disturbed, quartz-rich overburden, with total N =1200 mg/kg, and total P =200 mg/kg. Background forested areas have total N ranging between 2800 - 3300 mg/kg and total P of 420 - 500 mg/kg. Quartz-rich overburden sites contain available nitrogen levels of less than 6 mg/kg, while background forested areas are generally >20 mg/kg. The soils and water runoff are generally acid, with pH down to three. Water samples have been collected from both ground and surface resources on a monthly basis since December 2003. The main lake on the site had pH of 4.6 in 1999, and this remained relatively unchanged when 850 tonnes of lime were added in 2002. However, the lake pH changed to 6.4 within a one month period in 2004, and has fluctuated since that time.

Jan 1, 2004