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By G. Wang, L. R. Moore, Y. Xiong, A. Gorken

"Feldspar may represent 60% of the earth’s crust, but the mineral does not exist in a pure state. It is generally associated with quartz, iron containing minerals such as mica, and titanium containing minerals such as rutile. Feldspar itself can even exist in different lattices from those containing sodium to various divalent ions. As such, its beneficiation has become a process that is quite complicated, when compared to the beneficiation of other minerals. It is this complexity that has made feldspar beneficiation dependent on tailor made reagents to successfully yield the industry specified feldspar products. This paper reviews the mineralogical variations found from two feldspar mines and the development of collectors to specifically target a Fe+Ti concentration of < 0.05%, while maintaining a feldspar recovery greater than 90%.INTRODUCTION Feldspar is a class of aluminum silicates that represents the most abundant mineral on earth (Vidyadhar, 2002). This class of mineral can further be defined by the types or concentrations of cations present in the crystal lattice, MAlSi3O8 (M = K, orthoclase and microcline; M = Na, Albite; M = Ca, Anorthite) (Heyes, 2012). Feldspar is most commonly mined and processed for either the alumina used in glass making or for the alkalis used in ceramics. The alumina is known to improve product hardness, durability, and resistance to chemical corrosion. The alkalis act as flux, which means they not only lower the melting temperature of the mineral mixture, but also assist in connecting the other components present in ceramics. It was stated in 2009 that the world production of feldspar was in excess of 18.3 million tons produced, with the majority coming from China, Italy, and Turkey. Raw feldspar is typically found with quartz, iron containing minerals such as mica, titanium containing minerals such as rutile, and other feldspar minerals (Celik, 2001). Quartz is stated as having a negative effect on the melting point of the feldspar, whilst the iron and titanium based mineral contaminants are known to have negative effects on color and quality of the product produced; these mineral contaminants must therefore be separated prior to application (Barns, 1997 & Celik, 2001). Mineral flotation and magnetic separation are the most common means of feldspar beneficiation. However, conditions vary greatly from mineral contaminant to mineral contaminant (Table 1). Some literature suggests feldspar can be floated with an amine, but this generally yields lower than acceptable recoveries and often still requires the magnetic separation of iron based minerals to achieve the desired grade (Amarante, 1997 & Heyes, 2012). Feldspar flotation can be further improved with the addition of hydrofluoric acid (HF) as a silica depressant and feldspar surface modifier, but this still requires the removal of some of the other minerals first. Rutile can be floated with an anionic fatty acid collector at a pH range of 7-8 or with a petroleum sulfonate at a pH < 4 (Celik, 2001), while mica can be floated with a petroleum sulfonate or an amine collector at a pH of 3.5."

Jan 1, 2016

By Circe Verba, Scott Montross, Jon Yang

This work is a first-order study to assess the suitability of an organic acid lixiviant to extract rare earth elements (REE) from coal preparation fines refuse sourced from a Pennsylvania mine with a total REE of ~ 300 ppm. The extraction of REE using an organic acid, in this case 0.1Mcitric acid and 0.5Mtrisodium citrate solution, is compared against 0.5M(NH4)2SO4, 1MHCl, 1.2MH2SO4, and 0.5Methylenediaminetetraacetic acid (EDTA). Ashing the coal waste material prior to leaching tests with the citrate solution nominally improved REE extraction. Buffered citrate solution recovered 7% of the total REE in the as-received Isabella Fines as compared to 11% in ashed samples, whereas (NH4)2SO4 extracted 5–6%, respectively. EDTA recovered up to 33%of the total REE, most likely due to the higher coordination chelate bond. Mineral acids, however, outperformed the organic acids on ashed material (16–52%REE recovery), suggesting that organic acids may not be a suitable competitive option for REE extraction from these types of feedstocks.

Jun 15, 2021

By John P. Capp

In recent years limited markets have been developed for fly ash, the dust removed from coal-burning powerplant stacks, but most of it is still dumped in spoils areas at a cost ranging from 20 cents to $1.75 per ton. Aside from this cost, the creation of huge spoils areas can present a considerable aesthetic problem. Since the present annual fly ash output of about 20 million tons will probably reach 30 million by 1970, and because satisfactory disposal areas are becoming more limited, markets for much larger quantities of the waste are needed to keep disposal costs from becoming a significant economic factor in coal-burning powerplant operation. Current stress on air-pollution control and beautification, plus the vital need for good powerplant economy, makes it imperative, therefore, that coal producers and consumers expand markets and develop new applications for fly ash. Markets for established uses can be increased by making a greater effort to sell fly ash. New large tonnage markets for fly ash should be sought via more intensive, coordinated research. The economics of fly ash utilization underscores the vital role that must be played by research. To be competitive with other products, processes for the conversion of fly ash into marketable materials face difficulty in regard to two important economic factors--transportation cost and product utility--the other economic factors are favorable. Raw material costs of fly ash, for example, are quite attractive, and supply is no problem because there are many coal-burning powerplants in operation and many more are planned. Demand for products made from fly ash will grow if their utility is established and a good sales program is initiated. The major problems then are transporta¬tion costs and development of useful products.

Jan 1, 1966

By Sidney M. Cohen

[Portland cement is a product made from a combination of limestone and argillaceous material which would supply the necessary amounts f calcium, silica, alumina and iron to form cementious compounds when fired at high temperatures. The resulting mixture, usually around 80% limestone and 20% argillaceous, is ground nine (80% -200 mesh), blended and then fired1 (2600-2700°F) to produce a cement clinker from which the final cement product is produced by grinding. The argillaceous component can be shale, clay, slate or other sources of the individual components of silica, alumina and iron. This paper deals with a case where a clay component was under consideration. The planned Plant site was to be located at a well defined limestone deposit. When it came to the argillaceous component, the nearest uniform deposit of clay was over 50 miles away and would require purchase of land or clay from the owner plus the daily delivery costs to the plant site. This situation made the plant site economically questionable. It was decided that a local clay deposit, which was available at the plant site but was orginally not considered due to lack of chemical uniformity and its high free silica content, would be reconsidered.]

Jan 1, 1983

By C. Villa Diniz

It is proposed that battery grade Mn02 can be produced directly from a manganese ore from Azul Mine in Brazil, by leaching with HCI to remove heavy metals selectively. We are working to find a way of selectively separating Cu, Ni, Co, Pb and Fe from the resulting acidic manganese chloride solution, to detoxify it and produce marketable chloride solution. Chelating ion exchange resins are proving more promising for this separation than solvent extraction with commercially available reagents. Results from batch and column ion exchange tests that characterize the behavior of copper, nickel, cobalt, lead and iron are reported.

Jan 1, 1999

By William R. Yernberg

Caterpillar introduced 21 new products during Caterpillar Press Days ‘96, held in June at the company’s proving grounds near Tucson, AZ. The event, billed as the largest product introduction ever held by Caterpillar, was attended by press from around the world. Most of the new products were demonstrated at Caterpillar’s Tinaja Hills Training Center in the Sierrita Mountains south of Tucson. Under the scorching Sonora Desert sun, the press was treated to demonstrations of the new equipment. After a display of the equipment’s power and capabilities, the press was given an opportunity to operate the new models and, in some cases, compare them with the old.

Jan 1, 1996

By H. Rush Spedden

A process has been developed and piloted to reject copper, lead, iron, phosphorus, bismuth, antimony, elemental sulfur, and insol from molybdenite concentrate without decomposing the contained molybdenite and rhenium. The impure concentrate is first heated with concentrated sulfuric acid at 260 to 290°C for 1 hour. This bake not only oxidizes the contaminating sulfides, but also activates the concentrate for later rejection of insol by flotation. Two stages of leaching follow the sulfation step. The first is an acidified water leach which extracts the oxidized copper, iron, and phosphorous; the second leach rejects the lead, bismuth, and antimony into a warm concentrated solution of sodium chloride. Final upgrading is achieved by conventional froth flotation. The chemistry of the process as well as results obtained from its implementation in a 5,000 lb/day pilot plant are presented.

Jan 1, 1971

By George A. Savanick

Borehole (slurry) mining, in which a tool incorporating a water-jet cutter and a downhole slurry pump mines phosphate through a borehole, was field tested in northeastern Florida as part of a Bureau of Mines program to increase the domestic availability of critical minerals. Approximately 1700 tons (1.54x106 kg) of phosphate ore were mined at 40 tph (10.1 kg/s) from a depth of 250 ft (76 m). The borehole was filled with water during mining for roof support and to assist slurry pumping. Underwater cutting was enhanced with an air-shrouded water jet. Mined cavities were backfilled to prevent subsidence after abandonment. Roof subsidence during mining was avoided only when the cavity was filled with water. Environmental monitoring before, during, and after mining included hydrological studies and measurements of water quality. Significant water quality changes occurred only in the zone being mined and were confined to the immediate area of the borehole.

Jan 1, 1983

By C. Ernst

The underground operation at Barrick?s Cortez Mine, located near Elko, NV, required the construction of a 12 foot diameter smooth-lined ventilation shaft. Barrick preferred to mechanically excavate from the ground surface without putting people in the excavation and considered blind drilling by Frontier-Kemper Constructors the best option. Design and construction challenges arose throughout both the excavation and lining stages. A large portion of the rock to be drilled was highly fractured. Important risks that were addressed included water loss into the formation, zones of squeezing ground, damage to drilling tools caused by blocky ground and fallout, and potential hazards during cast-in-place concrete lining. Detailed explanations of these challenges and the methods used to overcome them will be described.

Feb 23, 2014

By Theodore Feldsher, Seung Han Kim, Mourad Attalla, John Roadifer, Chu-Chieh Jay Lin

Lifelines in seismic regions of the world seldom can escape crossing active faults. Cities in California have been mitigating this risk by constructing improved fault crossings. This paper discusses the analyses and design of the lining for a tunnel carrying a water conveyance pipeline through a fault that can potentially displace during a major earthquake event. The paper presents expected fault displacement, fault width and orientation respective to the tunnel, characterization of the ground surrounding the tunnel and its interaction with the lining, and performance required of the lining. Several other fault crossings will also be presented and discussed

Dec 1, 2022

By Inkap Choi

Asbestos is a broad term embracing a number of fibrous silicate minerals. These minerals look extremely fragile, yet their fibers have a tensile strength equal to that of piano wire. Chrysotile asbestos is the only mineral that can be woven into cloth, and its fibrous structure is, if anything, even more amazing than its remarkable ability to withstand heat. Because of its unique physical properties asbestos has achieved great industrial importance, and more than 3,000 current uses are known, ranging from use in the kitchen to use in space missiles. Because their minuscule fibers are eminently respirable, asbestos minerals have also found their way into the lungs of humans, where they apparently produce serious biological effects such as asbestosis and lung cancers. 1, 2,3 Because of both their usefulness and their hazardous properties, these minerals have attracted a good deal of attention from research workers during recent years. For example, the surface properties of asbestos minerals have been studied by many investigators. 4, 5, 6, 7, 8, 9 However, even for the important mineral chrysotile, the literature data are more or less conflicting. Pundsack4 measured a PZC (point of zero charge) of 10.1; Martinez and Zucker5 measured 11.8; Chwastiak reports 10.8-11.0; and Raddick measured three sepa-rate apparent PZCls at about pH 8.3, 10.0 and 10.9. More recently Trivedi8 reports 10.11. Naumann and Dresher9 have studied surface charge enhancement of chrysotile by metal ions, and describe how the mineral reacts with contaminantions. In the present paper, the mode of dissolution of magnesium and hydroxyl ion from asbestos minerals placed in water was studied by kinetic experiments involving rate at which these items leave the minerals. Also, some study was made of interaction between dissolved species.

Jan 1, 1972

By Michael Clar

Total suspended solids (TSS), generally referred to simply as sediment, is one of the four major parameters of water pollution associated with surface mining activities. The other three para¬meters are iron, manganese and pH. Currently the Environmental Protection Agency (EPA) is in the process of developing and implement¬ing effluent limitations for these pollutants pursuant to section 301 of the Federal Water Pollution Control Act Amendments of 1972, 33 USC 1811.1 To date, effluent guidelines for existing point sources have been published, and guidelines for new sources are forthcoming. The effluent limits which have already been developed for TSS have been subjected to some controversy.1 Some industry spokesmen have indicated that they may be unable to meet these effluent limitation guidelines for TSS. The industry claims that in certain areas the suggested limit is unattainable since high suspended solid loads already exist in streams due to numerous and various sources of nonpoint pollution which include agriculture, silviculture and urban construction for which no TSS effluent limits have been set. An opposite viewpoint asserts that the TSS limitations are too lenient since permit data from the Regions (U.S. EPA Regions) indicates present compliance for several companies under more stringent TSS limits. The experience at the Centralia mine in Washington is one example.2

Jan 1, 1977

By P. J. Arps

Cyanide (CN) is used to recover gold from its ores in many locations worldwide. In spite of the established history of gold mining in Alaska, modern cyanidation methods have been used at only one location, the Ryan Lode Mine at Ester Dome, near Fairbanks. Ore was processed by heap leaching between 1987 and 1989, when permitting issues caused operations to be terminated. Those issues have since been resolved, and plans to reopen the mine are currently being discussed. Plans are also proceeding to develop several other ore deposits in the state, all of which include the use of cyanide for gold recovery [6]. Since tailings and effluent water produced from these mines will require treatment, it is important to develop detoxification methods suitable for the Arctic and sub-Arctic conditions found in Alaska. Several methods exist for removing cyanide from mining wastewater. However, most industrial users prefer chemical treatment systems, and typically use sodium hypochlorite, hydrogen peroxide, or sulfur dioxide/air/copper to oxidize free and complexed cyanides [9]. Biological treatment has been used successfully at two sites in the United States [30,32] and field tested at several others [20,27,28]. In addition, one mine uses "natural processes", which include natural oxidation, photodegradation, and degradation by naturally occurring bacteria [33].

Jan 1, 1994

By E. Hsieh

Proximity detection in the open pit mine can be used effectively as an operator assist strategy which improves digging production through enforcement of best practices, although it is normally thought of first as a safety tool, and second as a step toward full automation when combined with object avoidance.

Feb 23, 2014

By W. Bakiewicz

The Lower Indus Basin deposits form a substantial unconfined alluvial aquifer of excellent quality. This aquifer contains basically highly saline groundwater, overlain in places by considerable amounts of freshwater whose origin can be traced to the present and historical courses of the River Indus. In the past the main source of groundwater recharge has been direct river seepage and water tables were generally deep. Since the establishment of a perennial irrigation regime however, deep percolation from the increased irrigation supplies has predominated and the water-table has risen to within a few feet of the surface. The river system itself is being progressively developed for irrigation and very shortly a situation will arise where the entire low winter flow will be utilised. Fresh groundwater will then be exploited to supplement the surface supplies, and at the same time a drainage system, mainly based on wells will be used to stabilise the water-table at safe depths. This paper discusses some of the methods used to ensure optimum-economic development of the fresh groundwater and describes the general design philosophy evolved by the authors firms for both irrigation and drainage wells, with respect to both well configuation and operation. Water quality standards are discussed in as much as they affect subsequent use of the groundwater. A few particular aspects are considered, including that of the values of the relevant aquifer constants, the construction of wells and the determination of screen losses. A major problem solved during the Lower Indus Project investigations has been the design of wells to-produce fresh water from layers overlying saline water. This solution is also discussed.

Jan 1, 1967

By Richard C. Mayberry

Phosphate reserves have been and still are a controversial subject. Some published estimates are particularly conservative and have caused concern in government and political circles that southeastern phosphates are a dwindling resource. "Ores and ore bodies" are a function of economics that relate to a time/demand factor. The history of phosphates and other mineral commodities is one of mineral deposits (resources) ever becoming ore (reserves) via a long term logic based on price, supply, and demand factors operating through time and improved technology. Projections indicate that southeastern phosphates are sufficient for several centuries of operations at present production rates.

Jan 1, 1981

By Thomas A. Thorson

Bentonite is a common name applied to a variety of clays that develope swelling properties when associated with water. Useful bentonite deposits occur in many Western and Southern states. Their origins may consist of the alteration of volcanic sediments or the decomposition of shallow lake deposits. The specific type of bentonite that will be discussed in this review will be only the Western or high swelling sodium type bentonite that is mined primarily in Wyoming. Wyoming bentonite first entered the market in the late 1880&apos;s when it was used as an oil absorbing cosmetic. In the 1920&apos;s it was discovered that superior binding properties were present which created new opportunities in pharmaceutical, animal feed, and steel foundries. The swelling properties that were exhibited by the high swelling Wyoming bentonites soon led to its use in oil exploration when the rotary drilling process developed a need for multipurpose fluids. Bentonites in general and Wyoming bentonite in particular have fascinated chemists and process development specialists since the 1920&apos;s. There exists a long list of industrial uses that has led to hundreds of patents and extensive literature reviews. The binding and swelling properties are developed as a result of large surface areas and high cation exchange properties. Water, being a di polar molecule, attaches to the ionic vacancies and forms a network of tightly held water particles which in turn produces an impermeable seal or a binding characteristic in unconsolidated powder. Newer uses for Wyoming bentonite that once again utilized the binding and swelling properties include the pelletizing of iron ore and a vast array of civil engineering applications including slurry trenching, lagoon sealing, and garbage landfill sealing.

Jan 1, 1983

Water conservation and compliance strategy can be cause for success or failure of a new or existing mining operation. Water accounting at outset, and pit and waste dump planning, may not fully consider total inflows, or sediment loads encountered during mine life. Environmental impact assessments, and permitting often dictates the rules, and these may change, to be more stringent, during course of mine development. This paper will identify techniques to control unprojected fresh water, or increased surface water flows in surface mine operations.

Feb 23, 2014

By Kadri Dagdelen, Lee J. Zamalloa

Modern surface mining operations are always seeking for minimizing costs while increasing production rates, among the optimization of other specific tasks that have an impact on the economics of the mine. Specifically, the cost related to the production fleet operation (shovels and trucks), the maximization of the overall performance of the equipment, and the uncertainty to meet the goals at the end of the operational time horizon are always topics of discussion with no apparent simple answer. On the other hand, truck-shovel dispatch systems based on Linear/Non-Linear Programming Algorithms have been in operation since mid-1990’s with different levels of success depending on the correct arrangement of operational resources and the complexity of the mine, but having in most cases some important shortcomings related to the way these systems deal with the decision making of the operational objectives, being necessary to have a human agent (dispatcher) to guide the system when the operational parameters change, creating the possibility of suboptimal decisions due to the human factor. This paper discusses the implementation of a novel methodology based on AI techniques to assist in the decision making of the best goal selection when operating a Fleet Management System, taking into consideration time periods as variables and integrating them as part of the analysis, providing a better overview of the forecast plan completion with respect to previous production numbers and evaluating best alternative to handle future events to minimize losses or maximize profits, resulting in better truck assignments, minimum shovel idle times and overall productivity improvements of the operation at the end of the time horizon.

Jun 25, 2023

By Dirk van Zyl

Pad construction costs can impact the overall economics of heap leach projects. Pad construction costs for single-and double-lined pads, using various designs, are listed for a typical small and large project. Double-lined pads are now more often required by regulatory agencies. Unless such designs reduce the risk of site specific contamination significantly, the extra costs cannot be justified from an economical viewpoint. Specific attention is given to the short project life (typically five years) of heap leach projects. A few numerical examples are presented to demonstrate the overall economic impacts of these costs on economic parameters.

Jan 1, 1990