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By S. A. McGhee

ASARCO Incorporated embarked on a modernization and expansion program to improve overall operating efficiencies and to more effectively develop the large mineral reserve at the Ray Complex Open-Pit Mining operation located near Kearny, Arizona. Major elements of this Ray Modernization and Concentrator Expansion Project included engineering and construction of a 54,400 MTPD (60,000 STPD) In-Pit Crusher and Overland Conveying System. and a 24,200 MTPD (30,000 STPD) Copper SAG Concentrator and Tailings Disposal System. Detailed engineering, procurement, and construction management were initiated in November 1989 under contract with Bechtel Corporation. Field construction commenced in May 1990 leading to mechanical completion and start-up during February 1992.

Jan 1, 1993

By S. Makni, R. E. McIvor

Grate discharges historically outnumbered the overflow type of industrial wet ball mills. However, overflow discharge mills now strongly dominate. In order to understand their comparative advantages and disadvantages, Corem carried out a broad review of this topic. Where the data made it possible, the Functional Performance Equation was used to separate circuit classification from mill grinding effects. Batch tests were conducted in a torque-metered mill at different slurry levels. This paper presents the outcome of these investigations, which is a very strong case for the industry to once again consider grate discharges.

Feb 1, 2023

By A. H. Kaksonen

Numerous reactor designs for biological sulfate reduction have been reported. Fluidized-bed bioreactors (FBR) can efficiently retain biomass and allow high mass transfer and reaction rates. This work reviews the development of various sulfate-reducing FBR processes for treating acidic metal- and sulfate-containing waters and recovering metals from bioleaching liquors. The FBR process performance was evaluated with continuous flow experiments under various operational conditions: fluidization rates, influent pH values, metal, sulfate and salt concentrations, hydraulic retention times, electron and carbon sources, and temperatures. Substrate utilization and sulfide inhibition kinetics were determined with batch FBR-kinetic experiments. An artificial neural network (ANN) model was used to predict the performance of the FBR. Sulfate-reducing bacteria (SRB) were characterized in FBRs with molecular and culture-based approaches with the aim to gain a better understating of the bioprocesses. Based on the studies, FBRs are well suited for the combined removal of metals, acidity and sulfate from water.

Jan 1, 2010

By J. T. Carlson

Dolomite is an objectionable impurity in phosphate ores, due to its MgO content. Even though dolomite and apatite liberate at a coarse size, the very similar densities of dolomite and apatite makes density separations difficult. However, if operated correctly, jigging can be a very efficient process. This has led to the development of a unique laboratory scale jig that allows for easy alteration of effective jigging properties. Key jigging parameters have been investigated for the separation of dolomite from phosphate ores. It was found that a pulsation rate of approximately 200 pulses/minute worked best for separating dolomite from apatite.

Jan 1, 2010

By J. A. Bradbury

N. A. Degerstrom, Inc. has constructed and operated a processing plant approximately five miles north of Soda Springs, Idaho for processing a byproduct phosphate treater dust from Monsanto's elemental phosphorus plant, also located in Soda Springs. The plant is designed to produce agricultural-grade phosphoric acid, gallium, and silver. The design capacity of the plant is 54.4t (60 st) of treater dust per day, which can produce 16,326t (18,000 st) of phosphoric acid, 6,600 kg of gallium, and 6,033 kg (194,000 oz.) of silver per year.

Jan 1, 1993

By M. L. Harris

Explosions in underground mines and surface facilities such as processing plants are caused by confined accumulations of combustible dust and/or flammable gas mixed with air in the presence of an ignition source. Underground explosions can be prevented by minimizing methane concentrations through methane drainage and ventilation, by adding sufficient rock dust to inert the coal dust, and by eliminating ignition sources. The effectiveness of rock dust in arresting explosion propagation was proven by experiment and practice (1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11). The precise mechanism by which rock dust (generally pulverized limestone dust) quenches flame has not been fully explained, but is believed to be absorption of thermal energy from the heated gases and absorption of radiant energy, which reduces the preheating of unburned coal particles ahead of the flame front. One measurable aspect of explosibility is incombustible content. In order to determine whether enough rock dust is applied, 30 CFR1 § 75.403, Maintenance of Incombustible Content of Rock Dust, requires at least 80% incombustible content on the roof, ribs, and floor of underground coal mines. 30 CFR § 75.403-1 further defines the incombustible content as follows: ?Moisture contained in the combined coal dust, rock dust and other dusts shall be considered as a part of the incombustible content of such mixture.? In order to determine the incombustible content of the mine dust, samples of deposited dust from specified areas in a mine must be collected, analyzed, and then compared with the minimum standard of 80%. The traditional low temperature ashing (LTA) approach to determine if a coal and rock dust mixture is compliant with the inerting requirement consumes the coal dust and considers the remaining material to be inert. Compliance with the law is then determined by comparing the measured percentage of inert material of the representative band sample with the pre-established requirement of 80%. The incombustible content of the sample includes rock dust, the amount of moisture as received at the lab, and the inherent ash in the coal. The LTA method is not itself a direct measure of explosibility but is a surrogate that calculates a single parameter associated with large-scale Bruceton Experimental Mine (BEM) explosion test results conducted with dry rock dust. This method assumes a homogenous mixture with no layering of rock dust and coal dust. Float coal dust is a serious explosion hazard if it accumulates on top of the rock dust and is not mixed with the rock dust (12). Mitchell and Nagy (13) studied the effectiveness of water as an inerting agent for the coal dust explosion hazard. The study emphasized that surface water evaporates readily from dusts. Thus, in a passageway where the dust is wet, changes in weather or the ventilation system could dry the dust and make it unsafe in a relatively short period of time. Where adequate rock dust has been applied, this drying effect is not a factor. However, if the mine depends upon the moisture content as part of the incombustible content, fluctuations in the dust surface moisture within a mine can render moisture content an ineffective and inconsistent measure of safety. Additionally, if sufficient moisture is absorbed and subsequently relinquished by rock dust, a cake can form and render the rock dust ineffectual. The trend has long been recognized that mine explosions occur primarily during the winter season when the humidity is low for long periods of time (14, 15, 16). In light of this trend and due to the potential variability of the moisture content of the dust, it may not be prudent to include variable surface moisture in the total incombustible content of the sample. Instead, surface moisture should be viewed as an additional safety measure as long as the rock dust is dispersible. However, moisture limits the ability of the rock dust to disperse and can significantly reduce its capacity to effectively inert propagating explosions (2, 13, 17, 18, 19, 20, 21, 22). Given the methods by which the as-received moisture and incombustible content are determined, dust samples from the 2010 MSHA database were assessed to determine the variability of the moisture content throughout a year and how often the measured as-received moisture might have affected the dust explosibility determination if removed. The findings were then verified by observation in laboratory studies and within the NIOSH OMSHR Safety Research Coal Mine (SRCM).

Feb 23, 2014

By Zhan-fang Cao, Hong Zhong, Li-feng Li, Shuai Wang, Xiao-yu Cao, Guang-yi Liu, Ming-ming Wang

"In recent years, there has been an increasing focus on the hydrometallurgical processing of molybdenite, with the decline of high-grade and easily handled molybdenum minerals. In this work, a novel method of selective extraction of complex molybdenite concentrate, which is characteristic of high-grade copper ore, has been investigated. The results show that the leaching of chalcopyrite was impacted by the pH of the electrolyte when sodium carbonate and ammonium acid carbonate were added to the electrolyte. The leaching rate of molybdenum reached 99.39%, but chalcopyrite could not be leached at all in 240 min under experimental conditions of liquid-to-solid ratio 25:1, concentration of NaCl 4 mol/L, pH=9, room temperature and agitation speed 400 rpm. The grade of copper in the residue was 21.84%, with a recovery 99.93%. The technology of selective electro-oxidation leaching of molybdenum and recovery of copper from complex molybdenite concentrate is an effective separation method. The diffusion control model can be used to describe the process of leaching of molybdenum. The activation energy of the leaching reaction was found to be approximately 9.21 kJ/mol.IntroductionWorldwide, high-grade and easy-to-handle ore is decreasing, while the proportion of low-grade and complex ore is increasing. Porphyry copper ores with associated low-grade molybdenite are very abundant in China. Molybdenum is a valuable byproduct in the processing of porphyry copper deposits where the molybdenum is present in low quantities in the form of molybdenite (MoS2). In the conventional processing of copper sulfide ores by froth flotation, most of the molybdenite in the ore floats along with the copper sulfides. In this way, a bulk copper-molybdenum concentrate is produced. Afterward, the bulk coppermolybdenum concentrate is treated by differential flotation to obtain a rougher molybdenum concentrate, which requires several successive cleaning steps to produce a final molybdenum concentrate. However, it is widely recognized that flotation alone cannot economically produce a high-grade molybdenite concentrate, i.e., with less than 0.5% Cu. Therefore, in most cases, it is necessary to use a final step of chemical purification of the molybdenite concentrate to reduce the copper content to a level suitable for the market (Antonijevic and Pacovic,1992; Gerhardt et al., 2001; Fu and Zhong, 2003; Reza et al., 2006, Rafael et al., 2013)."

Jan 1, 2015

By E. Oraby, S. Garcia, A. Thurgood, D. Bertoldi, G. O’Malley

Mining and Process Solutions (MPS) most advanced process, GlyCatTM is the only process that can be easily adapted to existing cyanidation plants in the market today whose real advantages over cyanidation are when treating copper containing ores, concentrates or tailings. With such complex material, GlyCatTM requires 70-90% less cyanide addition to achieve the same precious metal extraction. However, GlyCatTM is not simply cyanidation with added glycine. It is a completely different process where the solution chemistry and conditions needed to effectively leach the precious metals are quite different. Downstream however, the process is largely unchanged as the recovery of the leached gold and silver uses existing known processes such as conventional activated carbon or zinc cementation (Merrill-Crowe process). Another advantage is lower SCN, OCN, WAD and no free cyanide in the effluent which can substantially reduce cyanide detoxification requirements and decrease the OHS and ESG risk of the operation. This paper outline some of these differences and presents testwork, piloting and process examples to highlight the advantageous of this new process over conventional cyanidation.

Feb 1, 2023

By A. Noble

"In coal and mineral processing, several numeric parameters are used to quantify the separation performance of unit operations. For density-based separations, the partition curve is used as the starting point for many stages of diagnostic analyses. The curve is often quantified by its midpoint slope sharpness, and this single value is subsequently used for technical evaluation, benchmarking, and comparison. While this analytical approach does depict misplacement by relative density class, it inherently prioritizes middling separation and does not consider process economics or the micro-price value of individual classes. Alternatively, the organic efficiency parameter does consider process economics; however, it does not reveal information on the root cause of lost revenue or misplacement. In this paper, a new analytical approach is introduced which reconciles the technical misplacement data derived from the partition curve with the economic data derived from micro-pricing. The result is a new analytical procedure which reflects a better use of performance data. INTRODUCTION Partition curves are commonly used in the characterization, evaluation, and simulation of various physical separators. In mineral processing, partition curve analysis is routinely applied to hydrocyclones, screens, and density separators. Graphically, the partition curve depicts the recovery of particles as a function of a physical property on which the separation is based (e.g. particle density, size, magnetic susceptibility, etc.). Given the probabilistic nature of many real separators, the partition curve often exhibits a characteristic “S” shape (Fig. 1), similar to a cumulative normal distribution. Other geometric features of the curve are also depicted in Fig. 1, including the high and low closeout (or bypass) values, the midpoint slope, and the separation cut point (property value with 50% recovery). Partition curve analysis was originally proposed to evaluate coal washability (Tromp, 1937). Given the limited computational resources at the time, the analytical methods relied heavily on graphical construction and interpretation of the curve. Owing to the simplicity of the calculation and interpretation, many of these graphical approaches are still widely used for performance analysis today. The most common calculations are based on the slope of the partition curve at the midpoint. Increased slopes correspond to enhanced separation performance, since a perfect separation exhibits a stepwise transition from 0 to 1 at the desired cut point (i.e. an infinitely large slope). One common formulation of this slope, the Ecart Probable (Ep), is derived by evaluating the slope between the 25% and 75% recovery points:"

Jan 1, 2015

By Laszlo Valentyik

Heavy media separation (HMS) is one of the most widely used gravity methods in the mineral industry. The feed is separated, according to the specific gravities, into two products; float (light) and sink (heavy) particles. The universal acceptance of the process is due to simplicity, efficiency and robustness for ease of control. However, if optimum separation is desired during the operation of heavy media plants, a delicate balance of a number of variables is essential. Among the variables, the two which are generally the most frequently checked and controlled are specific gravity and consistency of the medium. The latter is a function of the settling rate of the media. The medium is generally made up of finely ground ferrosilicon, magnetite, galena, shale, quartz sand, clay contaminants and water. The frequently present clay in the medium acts as a stabilizing agent, since the coarse heavy medium solids (called media) would quickly settle if they were mixed only in water. Clay concentration of the medium varies between 3-7% by height (1,2). Although clay is essential for reasonable media stability, clay concentration greater than 7-8% imparts too high a viscosity to the medium, and the feed cannot accurately stratify and therefore separate into the required products. To be on the safe side, plant operators clean the medium from most of the clays, and would rather work at a lower stability than have a very viscous medium on their hands. The most recent advance in the area of consistency control rlas made by the introduction of atomized (spherical) ferrosilicon (3). This extended the upper limit of the use of ground ferrosilicon from 3.3 to approximately 3.6, broadening the range of the optimum operating conditions. A viscosity control method was also worked out by the use of low cost additives which lower viscosity while retaining a favorable low setting rate (4). Recently (5) polymers have been successfully used in oil well drilling muds then the requirements were mainly to suspend and transport cuttings during the periodic shutdowns and dril1ings respectively. The rheological properties of these polymer suspensions are such that they present an infinite viscosity to

Jan 1, 1971

By T. M. Gurr

Large quantities of phosphate rock are mined and processed in Central Florida (Figure 1). The phosphate rock from the mines is further processed in "chemical plants" to produce phosphoric acid (Figure 2). A by-product of the processing' of the phosphate rock to produce fertilizer chemicals is an impure form of gypsum referred to as phosphogypsum. For each ton of phosphate rock processed, approximately 1.5 tons of phosphogypsum is produced (Figure 3). The typical method to dispose of this by-product gypsum is to stack it in large piles, locally referred to as gypsum stacks or gypsum fields (Figure 4). These gypsum stacks have been the focus of many studies in recent years in an attempt to identify the potential for ground water and/or air pollution associated with the stacks. This paper attempts to discuss some of the ground water impacts and current attempts to minimize these impacts.

Jan 1, 1990

By D. R. Nagaraj

Secondary Ion Mass Spectroscopy (SIMS) was used to study copper ion adsorption, and its effect on subsequent sulfide collector adsorption, on pyrite and pyroxene minerals under flotation related conditions. Copper was found to adsorb on both of these minerals and cause enhanced sulfide collector adsorption. The distribution and depth profile of copper and collector on these mineral surfaces were obtained by using SIMS in the imaging mode. The results of this study have provided a valuable insight to understanding pyrite and gangue flotation observed frequently in operating plants.

Jan 1, 1995

By B. Bag

Saturated and unsaturated fatty acids are used in the flotation of iron values present in iron ore. Among the several fatty acids, oleic acid and its sodium salt are widely used. To substantiate the flotation results, the quantum chemical calculations of a few such acids have been carried out by adopting the semi-empirical AM1 method. These acids have been further optimized in the presence of an iron atom. The electronic interaction of the polar carboxylic head group of oleic acid with the iron atom is higher compared to the other acids. The numerical results support the flotation behavior of iron ore with oleic acid. Key words: Iron ore, Flotation, Fatty acids, Quantum chemical calculations, Semi-empirical AM1 method

Jan 1, 2009

Stillwater Mining Company (SMC) has an extensive history with tunnel boring machines (TBM) at the Stillwater and East Boulder underground PGM mines in Montana. The most recent TBM used is for the Blitz Project, where a 5.5m (18ft) diameter main beam unit, commissioned in Q3 2012, is being utilized to drive a 6,975m (22,500 ft) ventilation and haulage level East of the Stillwater Mine for the Blitz expansion project. The assembly/commissioning of the TBM, institution of the planned diamond drilling program, application of ground control systems, and the current tunneling metrics will be covered.

Feb 23, 2014

By John E. Frost

Duval's (now Battle Mountain Gold Co.) copper and gold deposits in the Battle Mountain District in Nevada are in two subdistricts - Copper Basin and Copper Canyon - about 18 km (11miles) apart. Location of the two subdistricts is shown in Fig. 1. The two centers of mineralization have distinctive geologic and ore characteristics that required different innovative approaches to exploration and development. Nearly all of the copper from Copper Basin has been recovered by heap leaching. Because of relatively high gold and silver values in the Copper Canyon ores, a significant part of the sulfide copper ores has been recovered by a conventional flotation mill at Copper Canyon. Recently, this mill has been converted to the recovery of gold that is mined from zones peripheral to the copper deposits. Prior to Duval's entry, small amounts of copper, gold, silver, lead, zinc, and antimony had been mined in the district over a nearly 100 year period, beginning in 1866. The bulk of the $13 million total production to 1962 was derived from copper and gold lode ores and gold placers. Duval's interest in Battle Mountain-arose directly from a submittal by Asarco, which controlled key claims in both the Copper Basin and Copper Canyon subdistricts. Asarco acquired its holdings in the district in 1959 and undertook limited exploration until mid-1961. At that time, the company decided to dispose of its interests. Duval was invited to evaluate Asarco's properties and accepted. On Dec. 6 and 7, 1961, J.E. Frost, R.C. James, R.W. Sayers, and H.A. Schmitt, representing Duval, and K. Richard and E.W. New- man, representing Asarco, visited Copper Basin and Copper Canyon. Frost concluded that the properties were of considerable interest and prepared, by Jan. 12, 1962, a voluminous report recommending that Duval acquire and explore Asarco's properties. Furthermore, he recommended a large initial exploration program that included not only geologic mapping, geochemistry, and geophysics, but also the extensive drilling that was to involve, as the first phase of exploration, 49 drill holes in Copper Basin and 21 drill holes in Copper Canyon. Following property agreements between Duval and Asarco, and Duval and several other claim owners, geologic mapping, geochemical surveys, and drilling began in August 1962. Exploration drilling was completed in July 1964 and engineering studies in April 1965. Development of the Battle Mountain properties was authorized in July 1965, and production commenced in the first quarter of 1967. Because of the unusually high oxide copper content of the ore bodies, particularly in Copper Basin, a much larger than typical proportion of the copper in the deposits has been recovered by heap leaching. The generalized geology and ore zones of the Copper Basin are as shown in Fig. 2 and of Copper Canyon in Fig. 3.

Jan 1, 1991

By S. Lu, J. P. Barta, T. W. Meikle

Three nutrient amendments and a biological seed inoculant were evaluated for use in establishing vegetative cover on waste rock substrates. Randomized blocks were placed on three substrates. Treatments included two types of organic fertilizer, mineral fertilizer, Azospirillum bacterial inoculant, plus controls. The seed mix consisted of native grass species adapted to low nutrient conditions. Canopy cover has been monitored for three growing seasons. Results indicate : 1) two of three substrates support plant growth following amendment with organic fertilizers; 2) organic fertilizers increase cover substantially over mineral fertilizer; and 3)Azospirillum had no effect on canopy cover.

Jan 1, 1999

By Angelus S. C. Owili-Eger

Although the foundation of a unified treatment of fluid flow in variably saturated porous media was established more than seventy years ago, no serious attempt was made to develop it until the early 1970's. Ever since, a number of unsaturated-saturated numerical models have been reported in the literature. However, none of these models have treated multidimensional, multiphase flow in deforming media, parts of which may undergo extensive secondary fracturing. A situation such as this is not uncommon in coal mining operations in which the longwall method of extraction is employed. The present model has been structured to handle such physical systems. This paper presents the mathematical formulation, the numerical algorithm, and a further validation and evaluation of the modified model. The model treats a multiphase flow in a three- dimensional regime and handles mining excavations of complex and changing configurations.

Jan 1, 1980

By J. R. Maxwell

The development, commercial installation, and operating performance of large capacity Maxwell Flotation Cells. Volumes ranging from 300 cubic feet to 2,000 cubic feet per flotation mechanism.

Jan 1, 1971

By A. J. Guse

The primary limiting factor for hoisting capacity from great depths is the self-weight of steel wire ropes. Steel wire ropes are very suitable for mine hoisting due to their high strength and durability, but have the negative characteristic of a low strength/weight ratio. Also, as hoisting depths increase, the service life of steel wire ropes decreases due to the higher stresses and physical effects on the ropes. The significantly higher strength/weight ratio of synthetic ropes offers the primary advantage of hoisting a larger payload with a similar size rope and hoisting plant. The beneficial properties of synthetic ropes could be used to improve the overall economics of deep underground mining both for new deep shaft projects and for existing mining operations expanding to deeper orebodies. A research and development program has been initiated to evaluate the suitability of a fully synthetic rope for the mine hoisting application.

Feb 23, 2014

By A. Noble

For the past 30 years, process flowsheet design has been accomplished largely through modeling and simulation. This approach provides circuit designers the freedom to test various separation approaches while minimizing physical and human resource requirements. The Limn® software provides a unique approach to process simulation, through a Microsoft Excel interface. While the software comes with standard process models for numerous unit operations, the Excel calculation environment and the accompanying VBA platform provide a convenient interface for custom model integration, even for non-experienced programmers. This feature is especially useful for university students in introductory process modeling and simulation-assisted flowsheet design courses as well as experienced practitioners with proprietary process models. This paper shows how the Limn® software may be used to solve basic process engineering problems as well as more comprehensive circuit design challenges. Industrial examples as well as opportunities for training and education are presented.

Feb 23, 2014