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By J. W. van der Merwe, C Strydom, D. C. Odendaal, M. I. Sampson

Keywords: Sphalerite, Bio leaching, Chemical leaching Sphalerite concentrates were prepared from tailings dam samples obtained from Rosh Pinah Mine in Namibia. The samples were subjected to froth flotation and concentrates containing between 7% and 14% Zn were prepared. Leaching of these froth flotation concentrates were studied in ferric chloride solutions at different Fe3+ concentrations for different times at different temperatures with the influence of other species on the kinetics in mind. Complementary to this research, GeoBiotics, LLC and Exxaro Resources have developed proprietary bioleaching technology for the oxidation of base metals concentrates using GEOCOAT bio heap leaching technology in a sulphate medium. The ferric chloride laboratory work was performed in a fluidising leach reactor. The studied material was obtained from flotation concentrate produced during an investigation into the recoverability of a tailings pile at Rosh Pinah mine in Namibia. The optimum conditions for the laboratory investigation were found to be a Fe3+ concentration of 0.3 mol/dm3 at 80°C. A control was performed by using synthetic zinc sulphide. GEOCOAT evaluation tests are performed for the purpose of evaluating the bioleaching of ore and flotation concentrates by means of mesophilic bacteria, Column tests were carried out on the flotation scavenger concentrate from Rosh Pinah to assess the application of the GEOCOAT® process for the oxidation of a low grade zinc concentrate. In this study an attempt was made to demonstrate the relationship between the Kinetic models and the experimental data by plotting the fraction of Zinc leached against time and applying the different equations to the data. The kinetic models were applied to the data obtained from both the test regimes. Habashi (1999) proposed that if a process is controlled by a chemical reaction at the interface (phase boundary controlled reaction), the following equation applies. kCt =1 ? (1-R) 1/3 Alternatively a process is controlled by diffusion through the product layer the following equation applies: [kt = 1 23- X (1 ? X) 2/3] As the anodic dissolution reaction progresses, reaction product forms either a more or less dense reaction product layer on surface As this product layer forms, a diffusion problem develops governed by the nature of the product layer. The conclusion from the study was that the kinetics is very dependent on the type of ore processed relating to the mineral composition of the ore body.

Jan 1, 2007

By R. D. Cromarty, J. Du Toit

"Penetration of matte into tap-hole bricks causes detrimental refractory wear, which can lead to furnace breakouts. The ability of the tap-hole clay to form a protective layer on the brick, thereby limiting matte penetration was investigated by examining the interaction between platinum group metal (PGM) matte, tap-hole clay, and alumina-chrome refractory bricks on a laboratory scale.Samples containing clay and brick as well as samples containing clay, brick, and matte were heated to different temperatures to establish the clay-brick interaction and the extent of matte penetration. The greatest degree of physical contact between the brick and clay was achieved at curing temperatures of 600°C. Poor clay-brick contact was observed in the sample that was heated to 900°C.Matte displaced the clay in the clay-brick-matte sample that was heated to 1350°C, with significant matte penetration into the brick. Less matte penetration was observed when the clay-brick-matte sample was heated to 1500°C. Less matte penetration was also observed in the claybrick- matte sample in which the clay and brick were pre-baked at 800°C, and the sample then reacted with matte at 1350°C. IntroductionFloatation concentrate from ore from the eastern Bushveld Complex of South Africa, specifically the Platreef, Merensky, and UG2 reefs, forms the feed to the Polokwane platinum smelter (Hundermark, De Villiers, and Ndlovu, 2006). The ore from the UG2 Reef has a high chromite content, which requires high operating temperatures (1500–1700°C) to avoid chromium spinel build-up in the furnace hearth. These high operating temperatures lead to matte superheats in the vicinity of 500– 600°C, which put increased demands on the refractory materials (Nelson et al., 2005).Upon tapping, the matte moves through the tap-hole, which consists of an aluminachrome refractory brick-lined tapping channel (Hundermark, De Villiers, and Ndlovu, 2006). The flow of molten matte is stopped by the injection of tap-hole clay to form a plug in the tap-hole. The tap-hole clay hardens and strengthens during curing to obtain the required hardness and refractoriness against penetration, corrosion and erosion (Nelson and Hundermark, 2014)."

Jan 1, 2016

The January General Meeting of the Institute was held in Kelvin House, Johannesburg, on 15th January, 1969 at 4.30 p.m. Mr R. C. J. Goode (President) was in the Chair. There were also present eighteen Members, including Messrs F. P. Bath, H. Britten, J. K. E. Douglas, P. Lambooy, V. C. Robinson, W. T. Stobart and P. W. J. van Rensburg (Council Members), Messrs J. C. Hall, P. C. Pirow, Dr D. I. Legge, Messrs E. R. Rudolph, H. R. Reid, Dr N. Stutterheim, Messrs B. F. van der Merwe, L. W. P. van den Bosch, D. T. Watt, M. Youngworth and T. Zadkin. Two Associate Members, Dr P. R. Jochens and Mr D. A. Viljoen. Two Students, Messrs R. P. W. Henrard and D. Ossin. Sixteen Visitors, including Messrs I. Barnes, B. F. Bath, S. Botha, P. A. du Plessis, K. Edwards, Dr F. S. Fulton, Messrs H. Grant, B. Havenga, L. Kok, Dr D. Lasar, R. Sandler, C. W. Wolhuter and J. D. Young. Secretary, Mr D. C. Visser. Total present: Forty. MINUTES The President: "May we confirm the minutes of the meeting held on the 20th November, 1968, as published in the December, 1968, issue of the Journal?" Agreed. MEMBERSHIP The President: "I have much pleasure in announcing that the names of the under-mentioned candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following grades: Members: Basil James Jackson and James Petrie Archibald. Associate Members: Ronald Creasy, Hugh Angus McCallum and John Barton Cunliff. Graduate: Hermanus Isak Johannes van der Merwe. Affiliate: Edgar Ramsay. Student: Petrus Daniel Wolmarans. MEMBERS TRANSFERRED TO A HIGHER GRADE From Affiliate to Associate Member: Neil Bradfield and Mervyn Bayard Allman. "I welcome the newly elected members to the Institute and congratulate those members who have been transferred to a higher grade." (Applause). GENERAL BUSINESS The President: "Are there any matters to raise under this heading? If not, we will proceed to the next item on the agenda which is the presentation of today's paper."

Minutes of the Annual General Meeting Held at Harmony Country Club on Wednesday, 2nd August, 1978, at 7.30 p.m. Mr A. N. Shand (Chairman of the O.F.S. and Klerksdorp Branch) was in the Chair. Also present were:.... Induction of Chairman Mr A. N. Shand introduced Mr H. M. W. Eschenburg by briefly outlining his past career and achievements, and, in calling upon him to take the Chair, wished him a very successful year of office..... Address by the President of the S.A.I.M.M. The Chairman introduced Mr Von Wielligh by outlining his career and achievements. After completing his education, he joined J.C.I. in 1936 as a sampler, and from that time served the company in many capacities, culminating with his appointment to the Board in 1974.....

Jan 1, 1979

By C. Klutke

This paper outlines a simple methodology for mineral characterization, developed as part of the Australian Mineral Industry Research Association (AMIRA) managed research project P777 ?The Development of Heavy Suspension Techniques for High Density Separations (Replacement of Clerici?s Solution)?. The project was sponsored by De Beers, Rio Tinto and Iluka Resources. Heavy mineral characterization of samples arising from exploration, mining or metallurgical processes is frequently conducted using laboratory heavy liquid analysis. Unfortunately, there are only a limited number of high density (?heavy?) liquids and these tend to be more toxic as their density increases. Low-toxicity inorganic solutions, based on tungsten compounds, have been developed that can be utilized at relative densities (RD) up to 3.0. Beyond this value organic liquids can be used; however, this presents significant health and safety hazards. Diiodomethane (methylene iodide) having a relative density of 3.31 is commonly used. Mixtures of thallium formate and thallium malonate were found in the early 1900s by Clerici to provide liquids having specific gravities between 4.0 and 5.0. For the characterization of the heavy components of mineral sand deposits (e.g. anatase RD 3.9, rutile RD 4.2, ilmenite RD 4.4?4.7 and zircon RD4.6?4.8) there is currently no heavy liquid alternative to Clerici?s solution. Clerici?s solution is highly toxic and testing is now conducted by few laboratories worldwide, with costs reflecting the chemical costs, infrastructure costs and health and safety regimes (e.g. blood testing of exposed staff). A simple laboratory technique of density fractionation has been developed, employing suspensions of fine tungsten carbide particles in lithium heteropolytungstates solutions, that can replace Clerici?s solution in the evaluation of fine mineral sands samples (e.g. -250 +150microns). The developing methodology that can achieve low-cost, low-toxic separations at relative densities above 4.0 is outlined and the comparison of results with Clerici?s solution presented. In addition, preliminary work on density fractionation of zircon samples is presented. Zircon fractionation relates to their inclusion, radionuclide content and metamictization.

Jan 1, 2007

By M. C. J. van der Merwe

"Carboxymethyl cellulose is an organic binder used in the iron ore pelletizing industry. The basic principles of how carboxymethyl cellulose (CMC) solutions behave during the pelletizing process and how these principles affect the drop and compression strengths of the pellets are poorly understood. The aim of the investigation was therefore to gain knowledge on the behaviour of CMC during the pelletizing of haematite concentrate.Haematite pellets with different additions of CMC (0.1–0.4 wt%), were subjected to drop tests, compression tests, and free moisture content analysis. The relationship between the drop strength, compression strength, free moisture content, elapsed time, and CMC concentration was analysed.The drop strength had a strong correlation with the free moisture content of the haematite pellets, with a correlation coefficient of 0.94. The compression strength of the CMC-bonded haematite pellets increased as the free moisture content decreased, reaching a maximum upon depletion of the free moisture content. Haematite pellets with CMC concentrations of 0.1 and 0.2 wt% developed most of their strength within the first day after pelletizing, whereas pellets with concentrations of 0.3 and 0.4 wt% developed most of their strength between one and two days after pelletizing. The time within which CMC-bonded haematite pellets develop most of their strength is therefore dependent on the CMC concentration. IntroductionFines are produced during the beneficiation of iron ore. These fines are separated from the lump ore and can be upgraded to produce a concentrate, which is used as a raw material for the production of pellets. Pellets in turn form a key burden material for direct reduction processes as well as the blast furnace (Zhu et al., 2015).Inorganic binders such as bentonite have been used predominantly in the iron ore pelletizing process to obtain pellets with suitable properties (Eisele and Kawatra, 2003). These binders, however, have the disadvantage of introducing impurities into the pellets. This has resulted in organic binders being pursued as suitable replacements for inorganic binders, of which carboxymethyl cellulose (CMC) shows good potential. Although CMC has been used as an organic binder in iron ore pelletizing, the fundamental principles of how it behaves during pelletizing and how these impact on pellet properties are poorly understood."

Jan 1, 2017

By G. L. Gomes-Sebastiao, W. W. de Graaf

"Gomes Sand is a quarry operation that produces sand and aggregate for the construction industry. The quarry is experiencing inconsistencies in the fragmentation and poor pit conditions as a result of poor drilling and blasting practices. This results in excessive downtime in the load and haul and crushing processes.A benchmarking exercise of the blasting practices was conducted to evaluate the effect of the inconsistency on the mining cycle. After changes in the blasting practices the downtime was reduced, which improved the crushing plant utilization by 4.9%. The improved blasting practices and more consistent fragmentation decreased the average number of loads lost each month due to jaw crusher blockages from 9.2% to 3.9% of plant throughput. The change in blasting practices also improved pit conditions. IntroductionGomes Sand is a quarry operation that has been in operation since 2009, producing sand and stone for the construction industry. The quarry was experiencing unacceptable blasting results. The repercussions included uneven pit floors, large amounts of oversize rock (>500 mm), and inconsistent fragmentation.The blast results affected the load and haul operations as well as the efficiency of the crusher. This resulted in downtime in the daily operations, and consequent production and revenue losses.The crusher product should have a top size of 50 mm. A blast fragmentation of <50 mm would improve the downstream operations and the crusher throughput.An investigation into the blasting practices was carried out to assess whether the downstream delays can be eliminated by improving the blast results. The exercise included:* Assessing if the designed blast layout is adhered to on the bench* Observing the quality and control of drilling* Observing the charging procedure of the blast-holes* Benchmarking the fragmentation consistency of the blasted rock using current blast design and practices* Analysing the throughput of the crushing plant* Investigating the power consumption of the crushing plant and determine if a change in blasting practices will affect this* Evaluating the hours spent by the hydraulic hammer on secondary breaking."

Jan 1, 2017

The Institute of Lighting Engineers of South Africa The Institute of Lighting Engineers of South Africa (ILESA) was constituted in May 1972 and now has over 70 members. The first Annual General Meeting was held on 15th August, 1973, at the Philips Auditorium, when the first presentation of membership certificates was made. Book Reviews Der Hochofenprozess. Das kinetischdynamische Simulationsmodell des Vereins Deutscher Eisenhiittenleute.Diisseldorf, Verlag Stahleisen M.B.H., 1973. Jones, M. H. and Woodcock, J. T. Ultraviolet spectrophotometry of flotation agents with special reference to the determination of xanthate in flotation liquors. London, Institution of Mining and Metallurgy. 1973. 25 pp. £2,50. Notice VI INTERNATIONAL CONGRESS OF ENGINEERS The above congress is to be held in Barcelona from 6th to 10th October, 1974. NIM reports Report No. 1568 A computer programme for the estimation of parameters in flotation. Report No. 1571 The commissioning of a direct-reading spectrometer for the analysis of silicate rocks by use of the graphite-pellet technique. Report No. 1579 The determination of tin tn geochemical- survey samples. Report No. 1587 A preliminary investigation of the flotation of copper-activated sphalerite without the use of collectors. Report No. 1589 Preliminary investigations into the flotation of tin dioxide, cassiterite, and some related gangue minerals. Professional . engineers Reference (18/19/1) 22nd November, 1973 Dear Sir/Madam, From time to time questions are being asked publicly concerning registration of professional engineers. These questions mainly concern the time it takes to finalise applications, especially those of applicants who do not hold a recognised engineering qualification. Professionele . . Ingenleors Verwysing (18/19/1) 22 November 1973 Geagte heer/dame, Van tyd tot tyd word daar vrae in die openbaar gestel oor die registrasie van Professionele Ingenieurs. Vrae gaan veral oor waarom dit so lank neem om aansoeke af te handel, veral van aansoekers wat nie &apos;n erkende ingenieurskwalifikasie besit nie.

Jan 3, 1974

By T. Ito, N. Tokashiki, H. A. Bilgin, Ö. Aydan, T. Akagi

This study is concerned with the electric potential induced by deformation, fracturing and sliding of non-piezoelectric geomaterials. In experiments, the acoustic emissions together with electric potential measurements were also measured in order to see how the so-called seismic electric signals are associated with new fracture occurrence and propagation and sliding in case of existing discontinuities. The outcomes of this experimental study may explain why such electric potential variations may occur during the fracturing and sliding of non-piezoelectric geomaterials. On the basis of these outcomes, their possible implications in geo-engineering and geo-science are discussed. Ce travail concerne 1e potentiel électrique produit par la déformation, 1a fracture ou le glissement du matériel géologique non-piézoélectrique. Aux expérimentations, on a mesuré 1es émissions acoustiques avec le potentiel électrique afin de constater la relation entre les phénomènes de glissement ou de formation et de propagation de nouvelles fractures le long des discontinuités existantes. Les résultats de ce travail expérimental expliquent pourquoi de telles variations de potentiel electrique se produisent durant le glissement ou la fracture du matériel non-piézoélectrique. Sur la base de ces résultats, on a discuté de leurs éventuelles implications dans les domaines de 1a géologie et de 1a géo-ingénierie. Diese Studie befasst sich mit dem elektrischen Potential das durch die Deformation, Bruchbildung und Gleiten von nicht-piezoelektrischen Geomaterialien induziert wird. In Experimenten wurden die akustischen Emissionen zusammen mit elektrischen Potentialmessungen gemessen, um zu sehen, wie die so genannten seismischen elektrischen Signale mit neuer Bruchbildung und Ausbreitung sowie Gleiten im Falle von vorhandenen Diskontinuitäten verbunden sind. Die Ergebnisse dieser experimentellen Untersuchungen könnten erklären warum elektrische Potential Schwankungen während der Bruchbildung und dem Gleiten von nicht-piezoelektrischen Geomaterialien entstehen. Auf der Basis dieser Ergebnisse, wurden ihre möglichen Implikationen in Geoingenieurwissenschaften behandelt.

Jan 1, 2003

By Sabine Verryn, Johan de Villiers

"Through the application of the Rietveld method, X-ray diffraction analysis has developed into a fully quantitative method for phase analysis. The Rietveld method itself has progressed from an unstable method that required constant operator intervention to a stable and robust method suited even for routine analysis. The method however, requires a good initial calibration and periodic checks on its precision and accuracy.Several examples from minerals processing, pyrometallurgy, and materials science show the strengths and applicability of the method. The limitations and sources of error are also discussed.1. IntroductionDiffraction of X-rays by matter has been used for more than 80 years, initially to elucidate the structure of crystalline matter, and to investigate the bonding between atoms. The first development of powder diffraction cameras and the later development of X-ray diffractometers saw the development of methods to identify phases and to try to quantify them in mixtures. A comprehensive database and search-match techniques have been developed over the ensuing years. Effective and accurate quantification had to wait for the so-called Rietveld&apos; analysis where the total diffraction pattern is used and where the crystal structure data for the constituent phases are needed as input. Overlapping of diffraction peaks of different phases is handled without difficulty and reliable results can be obtained in spite of this occurrence.The development of methods for structure analysis from powder data has also progressed rapidly and more and more complex structures are being solved from first principles, i.e. without knowledge of unit cell or space group data. Because of the ease of use of the Rietveld method, it is finding increased application in metallurgy, especially in the quantification of phases of importance in minerals processing, in pyrometallurgical processes, and in materials characterization. This study will examine the principles of the Rietveld method, its application in metallurgy, and finally also the common pitfalls that need to be avoided.2. Rietve1d AnalysisAs the Rietveld method compares the experimental diffraction pattern with one calculated from known crystal structure data, the following data are needed:•,An XRD Pattern with as Iowa background as possible. This should have good resolution and high diffraction peak intensities. With modem X-ray detectors, this can be achieved in minutes rather than hours.•,Instrumental parameters such as goniometer radii and slit sizes are needed. These are the so-called ""Fundamental parameters"". They are used to calculate the shapes of the resultant diffraction peak profiles that are caused by the instrument. The parameters are used to correctly separate the instrumental effects on the diffraction pattern from the sample effects."

Jan 1, 2014

By K. L. Riemer

The West Wits Line first began yielding gold in the mid-1930s and is among South Africa&apos;s leading gold-producing areas. Gold mining operations are carried out amidst the occurrence of seismic events which cause both damage to underground excavations and injury and loss of life to production personnel. The feasibility of establishing a system to minotor the seismicity on all the Gold Fields mines was investigated during the early 1980s. This led to the establishment of a centralized seismic network in 1981. The system was structured around three major objectives. It uses Perkin Elmer (now Concurrent Computer Corporation) 16 and 32 bit mini-computers. The hardware in use at both the central and remote sites is outlined, giving a good insight into the role of computers in the system. The system software reveals the fast flow of data through the network; it can be divided into three categories: (1) data logging and transmission - remote sites, (2) data capture and communications - central site, (3) applications and research - central site. Several examples are given which show how the system is measuring up to its objectives. These case studies also indicate how the computers are effective in representing the seismic data collected. It is concluded that the use of computers enables the pin-pointing of seismic events on the West Wits Line within about 3 -4 minutes of their occurrence. The choice of hardware is largely dependent on the objectives of system, and the Gold Fields Network has chosen mini-computers because of the speed of communication and the large amount of data and storage required for research applications.

Jan 1, 1987

By C. R. S. Needes, M. J. Nicol, G. T. W. Ormrod, N. P. Finkelstein

The industrial application of a dioxide electrode uranium by C. R. S. NEEDES, Ph.D. (London) (Visitor), M. J. NICOL, Ph.D. (Rand) (Visitor), N. P. FINKELSTEIN M.Sc. (Rhodes), Ph.D. (Liverpool) (Fellow), and G. T. W. ORMROD (Visitor) A correlation between the potential of a U02 electrode and the rate of recovery of uranium has been proved in laboratory and plant trials. When the recovery rates change because of variation in the concentrations of Fe(III), Fe(II), SO4 &apos;and H+, a positive correlation is observed. However, an 2- increase in the concentration of phosphate in solution produces an increase in the U02 electrode potential but a decrease in the rate of leaching of U02. The correlation between the U02 electrode potential and the rate of leaching of U02 is then negative. It is concluded that, as a control device, the electrode cannot compete with the platinum electrode for use on certain plants. Nevertheless, the U02 electrode will act as a useful warning device if the total concentration of iron in solution decreases to below a level concomitant with the economic recovery of uranium. Furthermore, because of the positive correlation between the U02 electrode potential and the phosphte concentration, the electrode will also be of value in the detection of an increase in the phosphate level in solution. When it was incorporated in a suitable industrial probe, the electrode was found to be able to withstand the rigours of the leaching conditions in a large pilot-plant pachuca, and only failed after six weeks&apos; operation.

Jan 11, 1975

By G. G. Rogers, A. Vna Der Linde, N. B. Strydom, W. H. Van Der Walt

Changes in the level of serum vitamin C in mineworkers by N. B. STRYDOM, M.Se., Ph.D. (Illinois) (Fellow), G. G. ROGERS, M.Se. (Pta) (Visitor), W. H. VAN DER WALT, B.Se. (Poteh.) (Visitor), and A. VAN DER LlNDE, B.Se. (O.F.S.) (Visitor) The levels of serum vitamin C in the blood of mineworkers were determined on the first and fifth days of the normal heat-acclimatization period (i.e., before and after exposure to heat) and again after I, 2, and 4 months of underground employment. Supplementary vitamin C was administered to the men during the heat-acclimatization period. Six groups of 20 men featured in the study and, except for one of the two 4-month groups, all the values were obtained after a full shift of underground work. It was found that adequate levels of serum vitamin C were maintained during the heat-acclimatization period, and the 250 mg of vitamin C given daily to each man must therefore be regarded as sufficient. The serum vitamin C decreased significantly with time of exposure to underground conditions, showing that the vitamin C utilized during heat stress is more than that provided in the men&apos;s diet. At the end of 4 months, not a single subject had more than 0,4 mg of serum vitamin C per 100 ml, most of them having only 0,3 mg per 100 ml; 90 per cent of the men had had more than 0,4 mg per 100 ml during the acclimatization period. It is therefore recommended that the mineworkers&apos; diets should be supplemented with 100 to 200 mg of vitamin C per man per day.

Jan 5, 1977

By J. D. Flint

A description is given of the extraction of pillars in a seam of coal which normally varies in thickness from 10 feet to 14 feet using conventional trackless mechanised units. By using the pocket and fender method of pillar extraction, the high capital cost of hydraulic supports is eliminated, and a volumetric extraction of 85% to 90% of the seam of coal is possible. This method of mining opens up the possibility of extracting vast tonnages of coal which hitherto would have been left in situ as pillars. The major benefits likely to accrue from this technique are seen as follows: 1. Greater volumetric extraction of the seam; 2. Longer panel life with less frequent transferring of sections; 3. Preservation of our natural resources. The authors deal with the history of this development at Springfield Colliery, discuss the present results and outline the future trends in the light of current experience.

By C. F. Vos, J. D. Miller, J. C. Davidtz

"This work presents the potential for improving the flotation recovery of slow-floating sulphide minerals with the use of starvation dosages of a normal dodecyl (n-C12) trithiocarbonate (TTC) co-collector, together with a sodium isobutyl xanthate (SiBX) and dithiophosphate (DTP) collector mixture.At potentials below –150 mV (SHE), addition of nC12-TTC with SiBX improves the hydrophobicity of pyrrhotite, yielding captive bubble contact angles greater than those measured for SiBX or nC12-TTC alone, suggesting a low potential synergistic effect. This synergistic effect is further studied using Fourier transform infrared (FTIR) spectroscopy, the results indicating an increase in the surface concentration of the collector species when in a mixture. Thus, nC12-TTC with SiBX may act as an immobile surface anchor to which SiBX/SiBX2 molecules bond, increasing the localized concentration of collector species.Bench-scale flotation tests using mixtures of SiBX/DTP/nC12-TTC on a platinum group element (PGE)-bearing ore from the Bushveld Complex in South Africa confirm an improved metallurgical performance at very low substitutions (approx. 5 molar per cent) of SiBX. The improved recoveries for PGE, Cu, and Ni are correlated with improvements in the flotation kinetics of their slow-floating components. IntroductionShort-chain (less than C6) xanthates are very effective for the bulk flotation of sulphides (Fuerstenau, 1982), and early work (Leja, 1968; Gaudin, 1957; Plaksin and Bessonov, 1957; Taggart, Giudice, and Ziehl, 1934) indicated that the presence of oxygen in flotation slurries is necessary for the oxidation of the xanthate collector at the sulphide mineral surface to induce hydrophobicity. Fundamental research into the chemistry and adsorption mechanisms of xanthates over the years (Finkelstein and Poling, 1977; Woods, 1976; Winter and Woods, 1973) has revealed that for iron-bearing sulphide minerals, adsorption occurs predominantly through a charge transfer process. Oxidation of the adsorbed collector to the corresponding dimer takes place if the mixed potential of the system is greater than the reversible potential for dimer formation. In oxygenated slurries the rate of adsorption and oxidation of the collector depends greatly on the substrate surfaces. For chalcopyrite (Guler et al., 2005; Leppinen, 1990; Roos, Celis, and Sudrassono, 1990) and pentlandite (Hodgson and Agar, 1989) a two-step interaction with xanthate is proposed in which the chemisorbed xanthate is further oxidized to the dimer. The initial interaction of xanthate with pyrrhotite is through physisorption where xanthate physisorbs onto positive surface sites followed by oxidation to dixanthogen (Khan and Kellebek, 2004; Bozkurt, Xu, and Finch., 1998). This process is, however, slow and increased reaction time is needed to improve flotation recovery (Buswell and Nicol, 2002)."

Oct 1, 2018

By R. J. Davidson, W. D. Douglas, J. A. Tumilty

SYNOPSIS Two pilot plants operating on different types of carbon were used to generate steady-state adsorption data in the treatment of gold-plant solutions of high and low tenor. A pilot plant comprising three 4 m long columns and using 3 mm extruded activated carbon was used to treat pregnant solutions with a gold concentration of 5 to 8 g/t at pH 10 to 11,5. Column influent was pumped at a super¬ficial flow velocity of 0,5 m/min while the carbon was moved daily so as to effect gold loadings on the carbon of 5 to 10 k /t. With a carbon-bed depth of 12 m, an adsorption efficiency of 99,9 per cent was obtained in a bed depth of 9 m, which was subsequently reduced to 8 m when the depth of the carbon bed was reduced to 8 m. This improvement in efficiency was attributed to the reduced residence time of the carbon from 12 to 8 days. A corresponding decrease in adsorbed silica indicated that some silica fouling of the carbon had occurred. A second pilot plant, comprising a single column 6 m in length and using coconut-shell carbon of 1,0 to 2,4 mm, treated a solution with a gold concentration of 0,7 g/t at pH 8,0. Feed solution was pumped at a superficial flow velocity of 1,0 m/min while carbon was moved every 8 hours to give gold loadings of more than 5 kg/t. An adsorp¬tion efficiency of 99,5 per cent was indicated at steady state. Intermittent washing of the column with dilute hydrochloric acid was shown to have a beneficial effect on the gold adsorption and to reduce the pressure drop across the column. Intermittent washing with dilute sulphuric acid indicated that there had been some passivation of the car¬bon during the treatment of a solution with a gold concentration of only 0,2 g/t. Compared with other adsorption systems, the countercurrent moving bed appears to offer significant advantages in terms of metallurgical efficiency and capital investment. The inability normally associated with moving-bed systems to treat solutions containing suspended solids may be overcome to a degree by the use of relatively coarse extrud¬ed carbon.

Jan 1, 1985

By K. A. Annan

The last seven hot rolling passes of the ferritic stainless steel AISI430 were simulated on a Gleeble-1500D® thermo-mechanical simulator to investigate the effect of temperature, strain rate, and interpass time on the texture. The compression tests were carried out over a wide range of strain rates (0.1 s-1 to 5 s-1) and temperatures (1100°C to 820°C) with different interpass times (2, 10, 20, and 30 seconds). The dynamic recrystallization to dynamic recovery transition temperature was determined from examining the relationship between the mean flow stress and the inverse of the deformation temperature in multi-pass tests. It was found that the texture in the central layer of the compressed sample is a strong recrystallization-type. The through-thickness textural and microstructural banding, to a large extent, were found to be weakened by hot deformation in the two-phase (a+ ?) region, as opposed to the single-phase (a) region.

Jan 1, 2013

Council Members 1988/1989, left to right: Row 1 (seated): H.E. James, P.W.J. van Rensburg, Dr H. Wagner, B.C. Alberts, C.E. Flvaz (President), H.G. Mosenthal, R.D. Beck, Professor A.N. Brown, Dr P.R. Jochens Row 2 (standing): P.C. van Aswegen, J.P. Hoftman, D. Wllson, P.M.T. White, K.A. van Gessel, Dr LA. Cramer, J.S. Freer, V.J. Moore, G.A. Brown, R.A. Snodgrass, J.D. Austin Row 3 (standing): Dr G.A. Fourle, Dr J. Lurle, A.M.P. Henderson, R.P. Mohring, J.A. Cruise, J.L. Nel, H. Scott Russell, J.P. Deetlefs, D.A.J. Ross-Watt Inserts, top row: K.R. Beard, N.J. De~ine, R.J. Dlppenaar, G.T.G. Emere, Dr J-P. Franzidls, Professor R.P. King, J.G. McCallum. Bottom row: G.Y. Nisblt, Professor R.P. Plewman, Dr R.E. Roblnson, Dr O.K.H. Steften, P.A. van Wlelllgh

Jan 1, 1989

By V. E. Ross

These effects were investigated in batch flotation studies, and by the measurement of rest and pulp potentials. At Iow additions of sulphurous acid as the pH regulator, flotation rate increased with increasing concentrations of dissolved oxygen. The recovery of chalcopyrite dropped significantly below a pH value of about 6,5 at 25 p.p.m. of dissolved oxygen, and below a pH value of about 6 at a dissolved-oxygen concentration of 8,2 p.p.m. The rest and pulp potentia Is measured indicated that dixanthogen is the dominant species formed on chalcopyrite surfaces during flotation with sodium ethyl xanthate. The results suggested that the same species might have formed on galena surfaces in the pulp after the ore had been milled in a ceramic mill under nitrogen. Increased additions of sulphurous, sulphuric, and hydrochloric acids increased the rest potentia Is, while the addition of sodium sulphite decreased these potentials.

Jan 1, 1985

Interpretation of Leached Outcrops, by Roland Blanchard. Published by Nevada Bureau of Mines, University of Nevada, Reno, Nevada, 89507, 1968, 188 pages. Price $7.50 (R5.40). This book contains a summary of the author&apos;s knowledge of leached outcrops, derived from some 30 years&apos; experience as a geologist operating mainly in the United States of America and Australia. Part 1 of the book provides a comprehensive coverage of the various processes and substances involved in the oxidation of many minerals, under different climatic conditions, to form the final leached products. In Part 2, details are given of the appearance and composition of the oxidation products of the following minerals: pyrite, pyrrhotite, arsenopyrite, cha1copyrite, cha1cocite, bornite, tetrahedrite, oxidized copper minerals, galena, cerussite, sphalerite, molybdenite, chromite, hematite, magnetite, manganite, pyrolusite, calcite, siderite, fluorite, salite and supergene silica. The illustrations, the black and white photographs and the colour plates of oxidation products are of a high standard. The material is presented in a logical order and in terms which are not over-technical; hence it is useful to persons other than trained geologists. Despite the advances in geophysical and geochemical prospecting, the location and interpretation of gossans remains an important method of discovering ore bodies, particularly so since the correct interpretation of a leached material can prevent the fruitless and expensive prospecting of an underlying body of uneconomic concentration. Therefore it is considered that this volume will be a valuable addition to the libraries of universities, exploration companies and geologists. It is of interest to note that the author, who died in 1966, presented a paper, under the same title as this book, to the Chemical, Metallurgical and Mining Society of South Africa in 1939. For this work he was awarded the Society&apos;s Gold Medal. W.T.S.