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By A. Chryss, L. Pullum

Shear-thickening suspensions abound throughout the hydraulic conveying industry; at least this is the perception of many engineers running plants where hydraulic conveying is commonplace. In reality, shear thickening behaviour is limited, in the main, to high concentrations of fine particles, including colloidal and biological suspensions, at moderate to high shear rates. In the authors? experience most cases of shear-thickening behaviour have been either simple ?coarse? particle interactions, poor instrumentation techniques, or both. In some cases these were obviously heterogeneous flows, while in others flows that were homogenous, or were thought to be homogenous. Examples, which illustrate this erroneous perception are given. However, the trend towards pastes and complex suspensions that use high concentration carrier fluids means that the underlying slurries for many of these flows may now be truly shear-thickening. Unfortunately, suspensions that might exhibit shear thickening also invariably exhibit slip, or wall-particle depletion. These separate phenomena are difficult to resolve experimentally and many observations of apparent shear-thickening behaviour are in fact obscured or convoluted by slip effects. A method is presented whereby the true flow properties of these high concentration suspensions, and hence accurate prediction of pipeline flows, can be made using a parallel plate rheometer.

Jan 1, 2007

By G. T. Lineberry, C. M. Baird, D. L. Silverstein

The University of Kentucky (UK), with an enrollment of 25,891 in fall 2002, is a comprehensive, public land-grant university located in the Bluegrass Region of Central Kentucky. As the State’s flagship university, UK has long been involved in distance education, first through traditional correspondence courses, followed by use of videotape and satellite delivery in the 1970s and1980s, but soon supplanted by use of interactive television (ITV) and on-line course delivery in the 1990s to date. Today, UK Distance Learning Programs annually administers approximately600 course sections, with services provided to over 5200 enrollees. Courses are offered via six media: interactive video, Internet, on-site, satellite, open-air and cable television, and videotape, with hybrid delivery becoming increasingly popular. The University of Kentucky College of Engineering experience with distance instruction prior to 1985 was limited to videotape non-credit offerings. The Department of Mining Engineering, a small department in terms of numbers of both faculty and students, was a University pioneer in distance education. The first University degree program offered in its entirety by distance delivery(initially by itinerant faculty) was the Master of Mining Engineering. Satellite delivery from Lexington to Cumberland, Kentucky, was a welcomed change of delivery mode in 1987–88,resulting in six hours less travel time for faculty each week. Shortly thereafter, other initiatives directed toward fulfilment of its land-grant mission were undertaken by the College. Use of satellite for course delivery rapidly declined due to limited interactivity, in favour of compressed video and on-site instruction. Classroom sites in the Kentucky Tele-Linking Network (KTLN) now number over 200. The Network links schools, colleges and universities, as well as public and private agencies throughout the State. The KTLN supports voice, video, and data transmission in a uniformly-equipped environment. Beginning in the early 1990s, transfer-critical pre-engineering courses were delivered from Lexington to Kentucky’s community colleges with the largest pre-engineering enrolments. Success was limited, but lessons learned were invaluable. In 1996, the University of Kentucky College of Engineering was asked by the Kentucky Council on Higher Education (the predecessor to the Council on Postsecondary Education) to expand engineering education in Kentucky, first by initiating cooperative B.Sc. degree programmes in Chemical Engineering and Mechanical Engineering on the campus of Paducah Community College (PCC), located 400 km from the UK campus in Lexington. The third partner in these programmes is Murray State University (MuSU), a public regional comprehensive university 80 km south of Paducah. The genesis of the new degree programmes, which were subjected to ABET review in October 2002, as well as a summary of the major accomplishments and challenges of the innovative programmes, will be offered. The limited use of distance technologies for course delivery in these B.Sc. degree programmes will be discussed. A ‘no-spin’ overview of other non-traditional distance-learning ventures within the College of Engineering will be chronicled, with an honest assessment of the motivation for these efforts and, where appropriate, their relative degree of success. Among these ventures are: a BScME and a Master of Engineering programme at Toyota Motor Manufacturing of Kentucky, Georgetown, Kentucky; course exchange in Chemical Engineering between the University of Kentucky and the University of Louisville; an ITV-based Master of Engineering programme for practicing engineers in Kentucky; proposed joint-degree programmes in Civil Engineering and Mechanical Engineering with Western Kentucky University; and a proposed part-time MScME programme in Paducah, Kentucky, with a start date of August 2002, threshold enrolment permitting. Keywords: distance learning, distance education.

Jan 1, 2003

By J. L. Louw

The utilization of centralized blasting systems is progressively becoming a feature of the South African mining industry, owing to increased pressure from the Department of Mineral Resources (DMR) to ensure safer blasting conditions. The purpose of a centralized blasting system (CBS) is to ensure reduced blasting-related incidents and to improve the underground working environment for the mine?s employees. The brief from Samancor Western Chrome Mines (WCM) pertaining to this study was to explore?at a conceptual level?all variables pertaining to the implementation of the CBS. Studies have indicated that Sasol?s SafeBlast? was preferred due to low overall risks and user-friendliness. Empirical observations, however, indicated that attention should be given to the current shaft-clearing procedure and to the installation of additional transformers. This is required to co-ordinate the power supply from 2 level to 10 level with the required supply of the network slave station. A cost analysis indicated that an electronically initiated CBS will result in a R24 cost increase per panel, which relates to a mere 1% cost increase per panel. This cost, in addition to the R1.1 million capital cost, proved to be negligible in comparison to the possible direct and indirect costs incurred by the mine in the event of a blasting-related incident. It was found that Samancor should conduct further studies incorporating the necessary requirements to ensure a successful transition, while considering all stakeholders on the mine. This study proved that the transition to a CBS would ensure safe and efficient blasting at Samancor?s Mooinooi Mine.

Jan 1, 2012

By E. Uslu

The kinetics of the reduction of chromite from the LG-6 layer of the Bushveld Complex in Fe-Cr-C alloys were studied in the temperature range 15OO°C to 1680°C under an inert argon atmosphere. The rotating cylinder technique was used, and the rotational speed of the chromite cylinder ranged from 0 to 1000 r/min. The melt consisted of 30 to 80 per cent chromium and 2 to 8 per cent carbon. The initial chromium-te-iron ratios of the melts varied between 0,42 and 4,95. The reduction of chromite spinel was analysed in terms of the decarburization of the metal. It was found that decarburization increased with an increase in the temperature, the carbon content of the bath, and the rotational speed of the cylinder up to 400 r/min, after which it remained almost constant. Decarburization also increased with an increase in the chromium content up to about 50 per cent chromium but, at higher chromium contents, it decreased. In the early stage of the reduction, up to about 30 minutes of reaction time, the liquid-state mass transfer of oxygen was found to be the most likely rate-determining step. The apparent activation energy was calculated to be 84,864 kJ per mole of oxygen. In the later stage, diffusion of iron and/or chromium in the solid state is the most likely rate-determining step. The apparent activation energy for the diffusion was calculated to be 471,18 kJ/mol.

Jan 1, 1991

By H. G. Mosenthal

In any mining enterprise, the extraction of the ore from the orebody is of vital importance. This activity is stoping. The gold mines of the Witwatersrand and its extensions in the Klerksdorp, Welkom, and Evander areas form the most extensive goldfield in the world. This address reviews stoping technology and improvements in this technology since the end of the Second World War. Although the reefs that make up the Witwatersrand orebody are uniquely extensive, they are not suited to mechanized mining. This is due to a number of factors such as the depth of the orebody, its narrowness, and the hardness and abrasiveness of the quartzite forming the orebody. The most notable improvements in stoping technology have been brought about because of our beter understanding of rock-engineering problems. This has resulted in beter layouts, stoping geometry, systems of aleviating rock stresses, and support systems. It has enabled the industry, at ever-greater mining depths, to maintain and even increase productivity. These improvements, based on rock engineering, have significantly reduced the accidents due to rockbursts. There are many diferences between today's stoping and that practised forty years ago. Panels are shorter, concentrated mining has superseded bench mining, and the support systems are certainly better. Yet the face scraper is still used extensively, as are pneumatic rock drills. Some innovative stoping systems that have given rise to improved productivity are discussed. Explosives technology has shown spectacular advances during the period under review. Sadly, our local industry has had little to do with this research and development, but has been most adaptive in using the new products on offer.

Jan 1, 1990

By SAIMM Journal

COLLOQUIUM ON COMMINUTION The Institute has arranged a colloquium on the above topic to be held on 13th March, 1973, at Kelvin House. The following papers will be presented: 'Peripheral Discharge Mill', by A. H. Mokken, Union Corporation Limited

Jan 1, 1974

NIM reports Report no. 1970 List of unrestricted NIM publications issued from 1966 to 1978. (30th Jun., 1978). Report no. 1976 The preparation and certification of two samples of chromium ore. (9th Sep., 1978). Report no. 1982 The resistivity of mixtures of Mamatwan manganese ore and reducing agents. (31st Aug., 1978). Report no. 1984 Commissioning of the AEI MS702 mass spectrometer. 31st Aug., 1978). Metallurgical slags The Basic Science Section of the Canadian Institute of Mining and Metallurgy is sponsoring an International Symposium on Metallurgical Slags, which is to be held in Halifax, Nova Scotia, during 24th to 28th August, 1980. Mining machinery An international conference on mining machinery is to be held in Brisbane, Australia, from 2nd to 6th July, 1979.

Jan 1, 1979

By J. W. van der Merwe, C Strydom, D. C. Odendaal, M. I. Sampson

Keywords: Sphalerite, Bio leaching, Chemical leaching Sphalerite concentrates were prepared from tailings dam samples obtained from Rosh Pinah Mine in Namibia. The samples were subjected to froth flotation and concentrates containing between 7% and 14% Zn were prepared. Leaching of these froth flotation concentrates were studied in ferric chloride solutions at different Fe3+ concentrations for different times at different temperatures with the influence of other species on the kinetics in mind. Complementary to this research, GeoBiotics, LLC and Exxaro Resources have developed proprietary bioleaching technology for the oxidation of base metals concentrates using GEOCOAT bio heap leaching technology in a sulphate medium. The ferric chloride laboratory work was performed in a fluidising leach reactor. The studied material was obtained from flotation concentrate produced during an investigation into the recoverability of a tailings pile at Rosh Pinah mine in Namibia. The optimum conditions for the laboratory investigation were found to be a Fe3+ concentration of 0.3 mol/dm3 at 80°C. A control was performed by using synthetic zinc sulphide. GEOCOAT evaluation tests are performed for the purpose of evaluating the bioleaching of ore and flotation concentrates by means of mesophilic bacteria, Column tests were carried out on the flotation scavenger concentrate from Rosh Pinah to assess the application of the GEOCOAT® process for the oxidation of a low grade zinc concentrate. In this study an attempt was made to demonstrate the relationship between the Kinetic models and the experimental data by plotting the fraction of Zinc leached against time and applying the different equations to the data. The kinetic models were applied to the data obtained from both the test regimes. Habashi (1999) proposed that if a process is controlled by a chemical reaction at the interface (phase boundary controlled reaction), the following equation applies. kCt =1 ? (1-R) 1/3 Alternatively a process is controlled by diffusion through the product layer the following equation applies: [kt = 1 23- X (1 ? X) 2/3] As the anodic dissolution reaction progresses, reaction product forms either a more or less dense reaction product layer on surface As this product layer forms, a diffusion problem develops governed by the nature of the product layer. The conclusion from the study was that the kinetics is very dependent on the type of ore processed relating to the mineral composition of the ore body.

Jan 1, 2007

By R. D. Cromarty, J. Du Toit

"Penetration of matte into tap-hole bricks causes detrimental refractory wear, which can lead to furnace breakouts. The ability of the tap-hole clay to form a protective layer on the brick, thereby limiting matte penetration was investigated by examining the interaction between platinum group metal (PGM) matte, tap-hole clay, and alumina-chrome refractory bricks on a laboratory scale.Samples containing clay and brick as well as samples containing clay, brick, and matte were heated to different temperatures to establish the clay-brick interaction and the extent of matte penetration. The greatest degree of physical contact between the brick and clay was achieved at curing temperatures of 600°C. Poor clay-brick contact was observed in the sample that was heated to 900°C.Matte displaced the clay in the clay-brick-matte sample that was heated to 1350°C, with significant matte penetration into the brick. Less matte penetration was observed when the clay-brick-matte sample was heated to 1500°C. Less matte penetration was also observed in the claybrick- matte sample in which the clay and brick were pre-baked at 800°C, and the sample then reacted with matte at 1350°C. IntroductionFloatation concentrate from ore from the eastern Bushveld Complex of South Africa, specifically the Platreef, Merensky, and UG2 reefs, forms the feed to the Polokwane platinum smelter (Hundermark, De Villiers, and Ndlovu, 2006). The ore from the UG2 Reef has a high chromite content, which requires high operating temperatures (1500–1700°C) to avoid chromium spinel build-up in the furnace hearth. These high operating temperatures lead to matte superheats in the vicinity of 500– 600°C, which put increased demands on the refractory materials (Nelson et al., 2005).Upon tapping, the matte moves through the tap-hole, which consists of an aluminachrome refractory brick-lined tapping channel (Hundermark, De Villiers, and Ndlovu, 2006). The flow of molten matte is stopped by the injection of tap-hole clay to form a plug in the tap-hole. The tap-hole clay hardens and strengthens during curing to obtain the required hardness and refractoriness against penetration, corrosion and erosion (Nelson and Hundermark, 2014)."

Jan 1, 2016

The January General Meeting of the Institute was held in Kelvin House, Johannesburg, on 15th January, 1969 at 4.30 p.m. Mr R. C. J. Goode (President) was in the Chair. There were also present eighteen Members, including Messrs F. P. Bath, H. Britten, J. K. E. Douglas, P. Lambooy, V. C. Robinson, W. T. Stobart and P. W. J. van Rensburg (Council Members), Messrs J. C. Hall, P. C. Pirow, Dr D. I. Legge, Messrs E. R. Rudolph, H. R. Reid, Dr N. Stutterheim, Messrs B. F. van der Merwe, L. W. P. van den Bosch, D. T. Watt, M. Youngworth and T. Zadkin. Two Associate Members, Dr P. R. Jochens and Mr D. A. Viljoen. Two Students, Messrs R. P. W. Henrard and D. Ossin. Sixteen Visitors, including Messrs I. Barnes, B. F. Bath, S. Botha, P. A. du Plessis, K. Edwards, Dr F. S. Fulton, Messrs H. Grant, B. Havenga, L. Kok, Dr D. Lasar, R. Sandler, C. W. Wolhuter and J. D. Young. Secretary, Mr D. C. Visser. Total present: Forty. MINUTES The President: "May we confirm the minutes of the meeting held on the 20th November, 1968, as published in the December, 1968, issue of the Journal?" Agreed. MEMBERSHIP The President: "I have much pleasure in announcing that the names of the under-mentioned candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following grades: Members: Basil James Jackson and James Petrie Archibald. Associate Members: Ronald Creasy, Hugh Angus McCallum and John Barton Cunliff. Graduate: Hermanus Isak Johannes van der Merwe. Affiliate: Edgar Ramsay. Student: Petrus Daniel Wolmarans. MEMBERS TRANSFERRED TO A HIGHER GRADE From Affiliate to Associate Member: Neil Bradfield and Mervyn Bayard Allman. "I welcome the newly elected members to the Institute and congratulate those members who have been transferred to a higher grade." (Applause). GENERAL BUSINESS The President: "Are there any matters to raise under this heading? If not, we will proceed to the next item on the agenda which is the presentation of today's paper."

Minutes of the Annual General Meeting Held at Harmony Country Club on Wednesday, 2nd August, 1978, at 7.30 p.m. Mr A. N. Shand (Chairman of the O.F.S. and Klerksdorp Branch) was in the Chair. Also present were:.... Induction of Chairman Mr A. N. Shand introduced Mr H. M. W. Eschenburg by briefly outlining his past career and achievements, and, in calling upon him to take the Chair, wished him a very successful year of office..... Address by the President of the S.A.I.M.M. The Chairman introduced Mr Von Wielligh by outlining his career and achievements. After completing his education, he joined J.C.I. in 1936 as a sampler, and from that time served the company in many capacities, culminating with his appointment to the Board in 1974.....

Jan 1, 1979

By C. Klutke

This paper outlines a simple methodology for mineral characterization, developed as part of the Australian Mineral Industry Research Association (AMIRA) managed research project P777 ?The Development of Heavy Suspension Techniques for High Density Separations (Replacement of Clerici?s Solution)?. The project was sponsored by De Beers, Rio Tinto and Iluka Resources. Heavy mineral characterization of samples arising from exploration, mining or metallurgical processes is frequently conducted using laboratory heavy liquid analysis. Unfortunately, there are only a limited number of high density (?heavy?) liquids and these tend to be more toxic as their density increases. Low-toxicity inorganic solutions, based on tungsten compounds, have been developed that can be utilized at relative densities (RD) up to 3.0. Beyond this value organic liquids can be used; however, this presents significant health and safety hazards. Diiodomethane (methylene iodide) having a relative density of 3.31 is commonly used. Mixtures of thallium formate and thallium malonate were found in the early 1900s by Clerici to provide liquids having specific gravities between 4.0 and 5.0. For the characterization of the heavy components of mineral sand deposits (e.g. anatase RD 3.9, rutile RD 4.2, ilmenite RD 4.4?4.7 and zircon RD4.6?4.8) there is currently no heavy liquid alternative to Clerici?s solution. Clerici?s solution is highly toxic and testing is now conducted by few laboratories worldwide, with costs reflecting the chemical costs, infrastructure costs and health and safety regimes (e.g. blood testing of exposed staff). A simple laboratory technique of density fractionation has been developed, employing suspensions of fine tungsten carbide particles in lithium heteropolytungstates solutions, that can replace Clerici?s solution in the evaluation of fine mineral sands samples (e.g. -250 +150microns). The developing methodology that can achieve low-cost, low-toxic separations at relative densities above 4.0 is outlined and the comparison of results with Clerici?s solution presented. In addition, preliminary work on density fractionation of zircon samples is presented. Zircon fractionation relates to their inclusion, radionuclide content and metamictization.

Jan 1, 2007

By M. C. J. van der Merwe

"Carboxymethyl cellulose is an organic binder used in the iron ore pelletizing industry. The basic principles of how carboxymethyl cellulose (CMC) solutions behave during the pelletizing process and how these principles affect the drop and compression strengths of the pellets are poorly understood. The aim of the investigation was therefore to gain knowledge on the behaviour of CMC during the pelletizing of haematite concentrate.Haematite pellets with different additions of CMC (0.1–0.4 wt%), were subjected to drop tests, compression tests, and free moisture content analysis. The relationship between the drop strength, compression strength, free moisture content, elapsed time, and CMC concentration was analysed.The drop strength had a strong correlation with the free moisture content of the haematite pellets, with a correlation coefficient of 0.94. The compression strength of the CMC-bonded haematite pellets increased as the free moisture content decreased, reaching a maximum upon depletion of the free moisture content. Haematite pellets with CMC concentrations of 0.1 and 0.2 wt% developed most of their strength within the first day after pelletizing, whereas pellets with concentrations of 0.3 and 0.4 wt% developed most of their strength between one and two days after pelletizing. The time within which CMC-bonded haematite pellets develop most of their strength is therefore dependent on the CMC concentration. IntroductionFines are produced during the beneficiation of iron ore. These fines are separated from the lump ore and can be upgraded to produce a concentrate, which is used as a raw material for the production of pellets. Pellets in turn form a key burden material for direct reduction processes as well as the blast furnace (Zhu et al., 2015).Inorganic binders such as bentonite have been used predominantly in the iron ore pelletizing process to obtain pellets with suitable properties (Eisele and Kawatra, 2003). These binders, however, have the disadvantage of introducing impurities into the pellets. This has resulted in organic binders being pursued as suitable replacements for inorganic binders, of which carboxymethyl cellulose (CMC) shows good potential. Although CMC has been used as an organic binder in iron ore pelletizing, the fundamental principles of how it behaves during pelletizing and how these impact on pellet properties are poorly understood."

Jan 1, 2017

By G. L. Gomes-Sebastiao, W. W. de Graaf

"Gomes Sand is a quarry operation that produces sand and aggregate for the construction industry. The quarry is experiencing inconsistencies in the fragmentation and poor pit conditions as a result of poor drilling and blasting practices. This results in excessive downtime in the load and haul and crushing processes.A benchmarking exercise of the blasting practices was conducted to evaluate the effect of the inconsistency on the mining cycle. After changes in the blasting practices the downtime was reduced, which improved the crushing plant utilization by 4.9%. The improved blasting practices and more consistent fragmentation decreased the average number of loads lost each month due to jaw crusher blockages from 9.2% to 3.9% of plant throughput. The change in blasting practices also improved pit conditions. IntroductionGomes Sand is a quarry operation that has been in operation since 2009, producing sand and stone for the construction industry. The quarry was experiencing unacceptable blasting results. The repercussions included uneven pit floors, large amounts of oversize rock (>500 mm), and inconsistent fragmentation.The blast results affected the load and haul operations as well as the efficiency of the crusher. This resulted in downtime in the daily operations, and consequent production and revenue losses.The crusher product should have a top size of 50 mm. A blast fragmentation of <50 mm would improve the downstream operations and the crusher throughput.An investigation into the blasting practices was carried out to assess whether the downstream delays can be eliminated by improving the blast results. The exercise included:* Assessing if the designed blast layout is adhered to on the bench* Observing the quality and control of drilling* Observing the charging procedure of the blast-holes* Benchmarking the fragmentation consistency of the blasted rock using current blast design and practices* Analysing the throughput of the crushing plant* Investigating the power consumption of the crushing plant and determine if a change in blasting practices will affect this* Evaluating the hours spent by the hydraulic hammer on secondary breaking."

Jan 1, 2017

The Institute of Lighting Engineers of South Africa The Institute of Lighting Engineers of South Africa (ILESA) was constituted in May 1972 and now has over 70 members. The first Annual General Meeting was held on 15th August, 1973, at the Philips Auditorium, when the first presentation of membership certificates was made. Book Reviews Der Hochofenprozess. Das kinetischdynamische Simulationsmodell des Vereins Deutscher Eisenhiittenleute.Diisseldorf, Verlag Stahleisen M.B.H., 1973. Jones, M. H. and Woodcock, J. T. Ultraviolet spectrophotometry of flotation agents with special reference to the determination of xanthate in flotation liquors. London, Institution of Mining and Metallurgy. 1973. 25 pp. £2,50. Notice VI INTERNATIONAL CONGRESS OF ENGINEERS The above congress is to be held in Barcelona from 6th to 10th October, 1974. NIM reports Report No. 1568 A computer programme for the estimation of parameters in flotation. Report No. 1571 The commissioning of a direct-reading spectrometer for the analysis of silicate rocks by use of the graphite-pellet technique. Report No. 1579 The determination of tin tn geochemical- survey samples. Report No. 1587 A preliminary investigation of the flotation of copper-activated sphalerite without the use of collectors. Report No. 1589 Preliminary investigations into the flotation of tin dioxide, cassiterite, and some related gangue minerals. Professional . engineers Reference (18/19/1) 22nd November, 1973 Dear Sir/Madam, From time to time questions are being asked publicly concerning registration of professional engineers. These questions mainly concern the time it takes to finalise applications, especially those of applicants who do not hold a recognised engineering qualification. Professionele . . Ingenleors Verwysing (18/19/1) 22 November 1973 Geagte heer/dame, Van tyd tot tyd word daar vrae in die openbaar gestel oor die registrasie van Professionele Ingenieurs. Vrae gaan veral oor waarom dit so lank neem om aansoeke af te handel, veral van aansoekers wat nie &apos;n erkende ingenieurskwalifikasie besit nie.

Jan 3, 1974

By Sabine Verryn, Johan de Villiers

"Through the application of the Rietveld method, X-ray diffraction analysis has developed into a fully quantitative method for phase analysis. The Rietveld method itself has progressed from an unstable method that required constant operator intervention to a stable and robust method suited even for routine analysis. The method however, requires a good initial calibration and periodic checks on its precision and accuracy.Several examples from minerals processing, pyrometallurgy, and materials science show the strengths and applicability of the method. The limitations and sources of error are also discussed.1. IntroductionDiffraction of X-rays by matter has been used for more than 80 years, initially to elucidate the structure of crystalline matter, and to investigate the bonding between atoms. The first development of powder diffraction cameras and the later development of X-ray diffractometers saw the development of methods to identify phases and to try to quantify them in mixtures. A comprehensive database and search-match techniques have been developed over the ensuing years. Effective and accurate quantification had to wait for the so-called Rietveld&apos; analysis where the total diffraction pattern is used and where the crystal structure data for the constituent phases are needed as input. Overlapping of diffraction peaks of different phases is handled without difficulty and reliable results can be obtained in spite of this occurrence.The development of methods for structure analysis from powder data has also progressed rapidly and more and more complex structures are being solved from first principles, i.e. without knowledge of unit cell or space group data. Because of the ease of use of the Rietveld method, it is finding increased application in metallurgy, especially in the quantification of phases of importance in minerals processing, in pyrometallurgical processes, and in materials characterization. This study will examine the principles of the Rietveld method, its application in metallurgy, and finally also the common pitfalls that need to be avoided.2. Rietve1d AnalysisAs the Rietveld method compares the experimental diffraction pattern with one calculated from known crystal structure data, the following data are needed:•,An XRD Pattern with as Iowa background as possible. This should have good resolution and high diffraction peak intensities. With modem X-ray detectors, this can be achieved in minutes rather than hours.•,Instrumental parameters such as goniometer radii and slit sizes are needed. These are the so-called ""Fundamental parameters"". They are used to calculate the shapes of the resultant diffraction peak profiles that are caused by the instrument. The parameters are used to correctly separate the instrumental effects on the diffraction pattern from the sample effects."

Jan 1, 2014

By T. Ito, N. Tokashiki, H. A. Bilgin, Ö. Aydan, T. Akagi

This study is concerned with the electric potential induced by deformation, fracturing and sliding of non-piezoelectric geomaterials. In experiments, the acoustic emissions together with electric potential measurements were also measured in order to see how the so-called seismic electric signals are associated with new fracture occurrence and propagation and sliding in case of existing discontinuities. The outcomes of this experimental study may explain why such electric potential variations may occur during the fracturing and sliding of non-piezoelectric geomaterials. On the basis of these outcomes, their possible implications in geo-engineering and geo-science are discussed. Ce travail concerne 1e potentiel électrique produit par la déformation, 1a fracture ou le glissement du matériel géologique non-piézoélectrique. Aux expérimentations, on a mesuré 1es émissions acoustiques avec le potentiel électrique afin de constater la relation entre les phénomènes de glissement ou de formation et de propagation de nouvelles fractures le long des discontinuités existantes. Les résultats de ce travail expérimental expliquent pourquoi de telles variations de potentiel electrique se produisent durant le glissement ou la fracture du matériel non-piézoélectrique. Sur la base de ces résultats, on a discuté de leurs éventuelles implications dans les domaines de 1a géologie et de 1a géo-ingénierie. Diese Studie befasst sich mit dem elektrischen Potential das durch die Deformation, Bruchbildung und Gleiten von nicht-piezoelektrischen Geomaterialien induziert wird. In Experimenten wurden die akustischen Emissionen zusammen mit elektrischen Potentialmessungen gemessen, um zu sehen, wie die so genannten seismischen elektrischen Signale mit neuer Bruchbildung und Ausbreitung sowie Gleiten im Falle von vorhandenen Diskontinuitäten verbunden sind. Die Ergebnisse dieser experimentellen Untersuchungen könnten erklären warum elektrische Potential Schwankungen während der Bruchbildung und dem Gleiten von nicht-piezoelektrischen Geomaterialien entstehen. Auf der Basis dieser Ergebnisse, wurden ihre möglichen Implikationen in Geoingenieurwissenschaften behandelt.

Jan 1, 2003

By K. L. Riemer

The West Wits Line first began yielding gold in the mid-1930s and is among South Africa&apos;s leading gold-producing areas. Gold mining operations are carried out amidst the occurrence of seismic events which cause both damage to underground excavations and injury and loss of life to production personnel. The feasibility of establishing a system to minotor the seismicity on all the Gold Fields mines was investigated during the early 1980s. This led to the establishment of a centralized seismic network in 1981. The system was structured around three major objectives. It uses Perkin Elmer (now Concurrent Computer Corporation) 16 and 32 bit mini-computers. The hardware in use at both the central and remote sites is outlined, giving a good insight into the role of computers in the system. The system software reveals the fast flow of data through the network; it can be divided into three categories: (1) data logging and transmission - remote sites, (2) data capture and communications - central site, (3) applications and research - central site. Several examples are given which show how the system is measuring up to its objectives. These case studies also indicate how the computers are effective in representing the seismic data collected. It is concluded that the use of computers enables the pin-pointing of seismic events on the West Wits Line within about 3 -4 minutes of their occurrence. The choice of hardware is largely dependent on the objectives of system, and the Gold Fields Network has chosen mini-computers because of the speed of communication and the large amount of data and storage required for research applications.

Jan 1, 1987

By C. R. S. Needes, M. J. Nicol, G. T. W. Ormrod, N. P. Finkelstein

The industrial application of a dioxide electrode uranium by C. R. S. NEEDES, Ph.D. (London) (Visitor), M. J. NICOL, Ph.D. (Rand) (Visitor), N. P. FINKELSTEIN M.Sc. (Rhodes), Ph.D. (Liverpool) (Fellow), and G. T. W. ORMROD (Visitor) A correlation between the potential of a U02 electrode and the rate of recovery of uranium has been proved in laboratory and plant trials. When the recovery rates change because of variation in the concentrations of Fe(III), Fe(II), SO4 &apos;and H+, a positive correlation is observed. However, an 2- increase in the concentration of phosphate in solution produces an increase in the U02 electrode potential but a decrease in the rate of leaching of U02. The correlation between the U02 electrode potential and the rate of leaching of U02 is then negative. It is concluded that, as a control device, the electrode cannot compete with the platinum electrode for use on certain plants. Nevertheless, the U02 electrode will act as a useful warning device if the total concentration of iron in solution decreases to below a level concomitant with the economic recovery of uranium. Furthermore, because of the positive correlation between the U02 electrode potential and the phosphte concentration, the electrode will also be of value in the detection of an increase in the phosphate level in solution. When it was incorporated in a suitable industrial probe, the electrode was found to be able to withstand the rigours of the leaching conditions in a large pilot-plant pachuca, and only failed after six weeks&apos; operation.

Jan 11, 1975

By G. G. Rogers, A. Vna Der Linde, N. B. Strydom, W. H. Van Der Walt

Changes in the level of serum vitamin C in mineworkers by N. B. STRYDOM, M.Se., Ph.D. (Illinois) (Fellow), G. G. ROGERS, M.Se. (Pta) (Visitor), W. H. VAN DER WALT, B.Se. (Poteh.) (Visitor), and A. VAN DER LlNDE, B.Se. (O.F.S.) (Visitor) The levels of serum vitamin C in the blood of mineworkers were determined on the first and fifth days of the normal heat-acclimatization period (i.e., before and after exposure to heat) and again after I, 2, and 4 months of underground employment. Supplementary vitamin C was administered to the men during the heat-acclimatization period. Six groups of 20 men featured in the study and, except for one of the two 4-month groups, all the values were obtained after a full shift of underground work. It was found that adequate levels of serum vitamin C were maintained during the heat-acclimatization period, and the 250 mg of vitamin C given daily to each man must therefore be regarded as sufficient. The serum vitamin C decreased significantly with time of exposure to underground conditions, showing that the vitamin C utilized during heat stress is more than that provided in the men&apos;s diet. At the end of 4 months, not a single subject had more than 0,4 mg of serum vitamin C per 100 ml, most of them having only 0,3 mg per 100 ml; 90 per cent of the men had had more than 0,4 mg per 100 ml during the acclimatization period. It is therefore recommended that the mineworkers&apos; diets should be supplemented with 100 to 200 mg of vitamin C per man per day.

Jan 5, 1977