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By T. T. Campbell

This report describes the development of new electroplating baths from which tin-nickel alloy plate was deposited. Although tin-nickel plate can be deposited from an aqueous ammonium bifluoride bath, the corrosive nature of this bath has served as a deterrent to its use. The Bureau of Mines felt that more general acceptance of this new alloy plate would follow if neutral or alkaline baths could be developed. Promising results were obtained from electrolytes containing both tin and nickel chlorides dissolved in triethanolamine-hydrochloric acid or in ethylene glycol hydrochloric acid baths. Current efficiencies close to 100 percent were obtained with these baths. Research revealed that tin-nickel plate could be produced from organic solvents or from mixed aqueous-organic electrolytes. The composition of the alloy deposit - 65 percent tin and 35 percent nickel - was found to exhibit the same single-phase structure that is obtained from the commercially accepted fluoride-type bath.

Jan 1, 1959

By J. L. Stauffer, L. Gaydos, L. M. Demers, D. C. Kuhn

"Eicosanoids and cylokines produced by the pulmonary alveolar macrophage (PAM) are key mediators for the defensive role this cell plays in neutralizing the inhalation of particulate dusts and foreign microbes. However, these factors are also mediators of inflammation and their uncontrolled release may cause the lung injury and liorotic changes observed in individuals exposed occupationally to mineral dust. In vitro studies have suggested a link between the production of certain eicosanoids and cylokines released from the activated PAM. To this end, we have studied the release of eicosanoids (PGE2, TXB2 and LTB4) and cylokines (IL-1 and TNF) by cultured PAM, obtained from healthy human volunteers by bronchoalveolar lavage under basal culture conditions and following acute exposure to provocative agents such as the endotoxin lipopolysaccharide (LPS) and mineral dusts including silica. Studies were also carried out in the presence of specific cyclooxygenase inhibitors. The addition of LPS (10 µg/ml) to the culture medium produced a significant increase in PAM release of the eicosanoids: PGE2 (3.5 fold over baseline), TXB2 (2.8 fold over baseline) and LTB4 (4 fold over baseline). LPS also elicited a 2.5 fold elevation in IL-1 from these cells and a 9 fold increase in TNF release. The cyclooxygenase inhibitor, ibuprofen, significantly inhibited the LPS-induced rise in PGE2, TXB2 and TNF but had only a modest suppressive effect on IL-1 release. Exposure of these cells to silica dust elicited a similar augmentation in eicosanoid and cylokine release which was neutralized by prior exposure of the cells to ibuprofen. These results suggest that the enhanced production of eicosanoids and cytokines by PAM exposed to endotoxins and/or mineral dusts may be linked and that inhibition of eicosanoid release is linked to the production of TNF. IL-1 release however is not effectively neutralized by cyclooxygenase inhibition.INTRODUCTIONThe initial pulmonary cellular response to inhaled mineral dust involves the elaboration of potent inflammatory mediators from the pulmonary alveolar macrophage (1). These mediators include the eicosanoids (oxygenated metabolites of arachidonic acid) and cytokines (intercellular peptides) which are released into the alveolar space by the interaction of mineral dust with the PAM surface membrane. The eicosanoids and cytokines promote local nonvascular and vascular smooth muscle contractility changes, elicit the recruitment of additional mononuclear cells into the alveolar space, and enhance the activation, growth and differentiation of lung fibroblasts (2). In this study we sought to examine whether eicosanoid release and metabolism are linked to cytokine release when PAM are activated upon exposure to endotoxin or mineral dusts. Modulation of these pathways through inhibitory pharmaceutical agents may help attenuate the Injurious effects caused by a sustained release of these proinftammatory intercellular factors (3). To that end, we have studied the in vitro effects of endotoxin and silica on eicosanoid and cytokine release from cultured PAM obtained from healthy human volunteers."

Mar 1, 1992

By William D. Monaghan, Thomas H. Dubaniewicz, Kenneth L. Cashdollar

Emerging laser technologies are quickly gaining acceptance in the industrial workplace. Besides the risk of human exposure, one safety concern with the more intense lasers is the potential for ignition of flammable gases, vapors, dusts, fibers, or flyings often found in hazardous (classified) industrial settings. In underground coal mines, lasers are being considered for remote measurement of explosive methane gas. Current federal safety regulations for underground mines contain no specific guidance for evaluating the safety of optoelectronic components such as diode lasers. The National Institute for Occupational Safety and Health is conducting research to help provide a scientific basis for developing appropriate safety guidelines for optical equipment in the presence of flammable methane gas and/or coal dust. One phase of the study is an experimental evaluation of methane-air ignition by laser heated small particles. Minimum observed igniting powers for laser energy delivered by 200-, 400-, and 800-um core diameter fiber optic cables and directed onto selected targets in methane-air atmospheres were 0.6, L l, and 2.2 W, respectively. Comparisons are made with other ignition phenomena, including heated wires.

By Anthony T. Lannacchione, Donald G. Puglio

The Bureau of Mines developed data on the methane content of the Hartshorne coalbed, Haskell and Le Flore Counties, Okla. The methane content is calculated to be between 1.1 and 1.5 trillion cubic feet, based on an estimate of total coal in place of 2.4 to 3.2 billion short tons. Methane increases with depth, but the rate of increase decreases with greater depths. Degasification in advance of mining is recommended for all mines operating at depths greater than 500 feet to reduce hazards and methane explosions, decrease mine ventilation costs, and conserve the natural gas that would be otherwise wasted.

Jan 1, 1979

By T. H. Dubaniewicz, J. E. Chilton

Fiber-optic technology is progressing rapidly, including the development of fiber-optic sensors for many applications. These sensors have the advantages of high sensitivity, light weight, small size, high bandwidth, and freedom from electromagnetic influences. The U.S. Bureau of Mines is investigating the use of fiber-optic technology to monitor mine atmospheres. This report describes a methane monitor based on differential absorption of infrared light. The monitor can detect methane concentrations as low as 0.2 vol pct as far away as 2 km via fiber-optic cable. The upper range is 100 vol pct methane. Since the system requires no electrical power within the mine, it is intrinsically safe.

Jan 1, 1992

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

C 2 Complete Hoisting Systems A Above Ground Installations A total of seven companies were identified who supply complete emergency escape hoist units for above ground installations The units have been designed predominately to meet the needs of coal mine operators to satisfy the requirements of the Coal Mine Health and Safety Act of 1969. The seven companies are as follows 1 Dover Conveyor and Equipment Co. 2. Coeur d' Alenes Co. 3. Connellsville Corp. 4. Scott Midland 5. W W Williams Co. 6. Equipment Corporation of America 7. Timberland Ellicott Table VIII contains detailed specifications and price information on each of these units. The units have a number of similarities

Jan 1, 1976

By J. A. Eisele

As part of its goal of maintaining an adequate supply of minerals to meet national economic and strategic needs, the Bureau of Mines has studied the removal of iron from simulated aluminum nitrate leach liquors by solvent extraction. Iron must be removed from aluminum nitrate liquor produced by leaching calcined kaolinitic clay with HN03 to reduce the iron level in alumina to less than 0.02 wt-pct Fe203 for use in reduction cells. The parameters reported are for (1) extracting iron from a feed containing 1.5 g/l Fe with di(2-ethylhexyl) phosphoric acid (EHPA), (2) stripping loaded organic phase with 20-pct HCI, and (3) water washing of loaded and stripped organic phase. Recommended operating conditions are two extraction stages using 15 vol-pct EHPA in kerosene and three stripping stages using 20-pct HCI. Results are also given for tests using other extractants and stripping agents.

Jan 1, 1982

By Steven J. Page

Accurate measurement of workplace respirable dust concentration is an essential step in eliminating lung disease in any occupational setting. In the United States (U.S.) coal mining industry, this measurement process has relied upon a personal sampler that includes a 10 mm Dorr-Oliver (DO) nylon cyclone operated at a flow rate of 2.0 L min-1 to collect a respirable dust sample. Dust concentrations measured with this sampler are multiplied by 1.38, which was empirically derived, to convert them to measurements approximating the United Kingdom British Medical Research Council (BMRC) definition of respirable dust upon which the health effects of coal mine dust are based. The International Organization for Standardization (ISO) subsequently refined the respirable dust definition and the U.S. National Institute for Occupational Safety and Health (NIOSH) 1995 Criteria for a Recommended Standard presented a conversion multiplier of 0.857 to apply to the 2.0 L min-' DO (in addition to thel.38 multiplier) to obtain equivalent ISO concentrations, as approximated by the 1.7 L min-1 DO. However, the conversion multiplier 0.857 was derived indirectly from a limited size distribution data set rather than a direct comparison of the DO samplers. The present analysis focuses on providing a more accurate conversion multiplier derived from direct comparisons of the 2.0 L min-1 (with 1.38 BMRC equivalency multiplier) and 1.7 L min-1 DO cyclones. A weighted linear regression analysis of this database suggests that a more accurate estimate of the conversion multiplier is 0.815.

Jan 1, 2009

By C. L. Brown

Coal has been transported by belt conveyors in mines for many years; however, only since the beginning of the general mechanization period have complete transportation system of this type been employed. Aside from my complete belt-conveyor transportation systems, belt conveyors are frequently used in conjunction with other transportation. Many early installations, for the most part, were made without standards as a guide. As a result, some States have outlined certain requirements based more or less on experience following mine fires. Correlation of these regulations should result in more uniformity in connection with standardization of regulations. The National Electrical manufacturers Association has published standards for mining-belt-conveyor installations2/ that should be helpful to the coal-mining industry generally. Bureau of Mines Schedule 2F3/ requires certain controls for permissible-belt- conveyor drives, and similar requirements are listed in Bureau of Mines bulletin 514.4/ Committees of the American Mining Congress have prepared much valuable information concerning operation of belt conveyors, and a subcommittee on fire-resistant belting has been active. 5/

Jan 1, 1956

By T. H. Jeffers

Significant amounts of cobalt, a strategic and critical metal, are present in readily accessible spent copper leach solutions. For example, recovery of cobalt at two major u.S. copper operations could produce about 1,300,000 lb Co annually, about 13 pct of domestic consumption. However, techniques such as solvent extraction and precipitation have not proven cost effective in separating and recovering the cobalt from these low-grade domestic sources. The Bureau of Mines has devised a procedure using a chelating ion-exchange resin to extract cobalt from a pH 3.0 copper leach solution containing 30 mg/L Co. Cyclic tests in 4-ft-high by 1-in-diam columns gave an average cobalt extraction of 95 pct when 65 bed volumes of solu-tion were processed at a flow rate of 4 gpm/ft2 of resin area. After an impurity scrub, eluates contained, in grams per liter, 0.4 Co, 0.2 Ni, <0.001 Cu, 1.3 Fe, 2.8 Zn, and 0.008 AI. Solvent extraction procedures to remove impurities, reject nickel, and concentrate cobalt produced a cobalt sulfate solution containing 80 g/L Co, 0.05 g/L Ni, and not more than 1 mg/L Cu, Fe, Zn, or AI. Based on data from commercial electro-winning operations, this solution appears suitable for production of metallic cobalt.

Jan 1, 1985

By Brian White, Hamid Maleki

Sudden, violent failures of rock around mine openings influence access, ventilation, and safety in both hard-rock and coal mines. To develop predictive tools for assessing the potential for violent failure, the authors initiated a comprehensive study using (1) multiple linear regression and numerical modeling analyses of geological and mining conditions at 25 sites to identify the most significant factors contributing to stress bumps in coal mines and (2) investigations of the geological and mining factors contributing to rock bursts in the Coeur d&apos;Alene Mining District of northern Idaho, particularly the influence of preexisting structures on rock bursts. Twenty-five factors were initially considered in the study of coal bumps. The most important variables were identified as (1) mechanical properties of strata, (2) gate road geometry and/or gate pillar factors of safety, (3) roof beam thickness, joint spacing, and stiffness characteristics, and (4) stress gradients associated with previous mining and anomalous geologic conditions. In the Coeur d&apos;Alene district, burst damage related to preexisting structures results primarily from (1) sudden buckling and crushing of rock layers where surfaces of development and production openings lie at low angles to bedding, faults, or other planar structures and (2) disturbance of loose ground caused by seismic fault-slip on preexisting faults or previously sheared bedding planes that intersect veins near pillar-stope margins.

By Liming Yuan, Charles D. Litton

This paper presents experimental results for conveyor belt flame spread from tests conducted in a small-scale tunnel. The purpose of this study is to investigate the effects of belt type, ventilation velocity, belt surface-to-roof distance and ignition source power on the flame spread properties. The tunnel used was 4.9 m long by 0.46 m square with the ventilation velocity ranging from 0.7 to 3.2 m/s. The ignition source was an impinged methane jet burner with heat output ranging from 7 to 21 kW. The belts tested included non-fire resistant rubber belts, fire-resistant rubber belts, fire-resistant neoprene belt and fire-resistant PVC belt with belt samples measuring 0.23 m wide by 2.5 m long. Experimental results show that with a ventilation velocity of 1.02 m/s all conveyor belts could be ignited, and that with sufficient ignition source power, flames spread the full length of the belt sample. The data showed a coupling effect of the ventilation air velocity and the belt surface-to-roof distance on the flame spread rate. For instance, flames could not spread with a ventilation velocity higher than 1.52 m/s and a surface-to-roof distance of 0.22 m. The use of the measured CO/CO2 ratio as an indicator of combustion stoichiometry is also discussed.

By Alfred E. Schwaneke

A versatile torsion creep tester was instrumented with electromechanical and servomechanical components to operate automatically and unattended, producing digital printed outputs. The apparatus uses an electrical system for applying torsional stresses, and a unique angular transducer as a null detector operating a servocontrolled strain measuring system with the digital readout. The tester is designed to measure the creep in single-crystal or polycrystalline zinc, zinc alloys, magnesium, magnesium alloys, or other metals and alloys. Applied stresses may be varied from zero up to 2,000 psi in the outermost fibers of a 1/8-inch-diameter, 4-inch-long specimen. Strain readings to 0.001 degree, equivalent to a strain of 2.73 X 10-7, may be made automatically from one every 5 seconds to one per month. The apparatus has provisions for programed temperature control and special atmospheres or vacuum operation. A discussion of applications of the system to other mechanical testing apparatus is included.

Jan 1, 1970

By E. K. Kleespies

The Bureau of Mines determined the kinetics of the reaction of titanium-iron alloys with titanium trichloride dissolved in sodium chloride to provide a basis for understanding the reactions occurring in metallurgical processes involving reduction of the metal halides or alloy refining in fused salts. The rate of the heterogeneous reaction was determined between titanium-iron alloys and titanium trichloride to elucidate the effects of alloy composition on the rate. Measurements were made in an inert atmosphere with a high-temperature thermobalance using high-purity reactants. The rates of the reactions were about 1 x 10-5 g Ti/cm2-sec, and the reaction was phase-boundary controlled. Titanium alloys of the body-centered cubic beta structure reacted faster than those with the hexagonal close-packed alpha structure. The inter-metallic compound, TiFe, reacted very slowly, whereas TiFe2 was inert. Alloys containing above 89 atomic percent iron gained weight by reacting with titanium species in the salt solution and depositing titanium in the alloy. The effect of TiCl3 concentration on the reaction rate was determined from 2 to 12 weight-percent TiC13 and at various alloy compositions. At high iron contents, above 50 atomic percent, the TiC13 concentration effect was small. At lower iron contents, the TiC13 concentration effect was greater for beta-crystalline alloys than for alpha-crystalline alloys. The temperature dependence of the reaction between titanium alloy containing 8.7 atomic percent iron and titanium trichloride was measured over the temperature range 1,062° to 1,220° K, and the energy of activation was 7.7 kilocalories for the reaction.

Jan 1, 1967

By E. D. Gardner

"The Bureau of Mines receives many inquiries concerning favorable areas in which to prospect for gold, procedure to be followed, equipment required, and allied subjects. This circular has been prepared for use in reply to these inquiries.Interest in gold mining and prospecting for gold remains steady. From time to time many people take to the field to search for new gold deposits. A large percentage of them have had no previous experience in prospecting for lode gold; this paper has been written with the hope that it might assist these newcomers.A majority of the metal mines in the United States have been discovered by qualified prospectors who were searching for valuable minerals at the time. Chance, however, always has played a large part in finding mineral deposits. Some of the discoveries of the past were made by men on other errands, such as rounding up burros or hunting game. Accidental discoveries of ore bodies have been made in building roads and trails and in excavating for mine struc¬tures. Evidence of ore has been brought to the surface by burrowing animals and by ants; gold found in the craws of fowl has led to discoveries of deposits. Important discoveries have been made by men who had no knowledge of rocks or minerals; on the other hand, many ore bodies have been found by experienced prospectors, sometimes after hundreds of untrained men had already passed over the ground.The prospector who carries on his work diligently and intelligently is of course more likely to be rewarded for his efforts than the lazy or unintelligent worker; nevertheless, it is obvious that if valuable deposits are not present at the place being prospected none will be found. Conscientious and painstaking efforts to trace gold to its source usually disclose nothing more valuable than some narrow, unworkable seams; however, many deposits that were developed into profitable mines were found by this method of prospecting. Although some prospectors have made several lucky strikes, many others have spent their working lives searching for gold without finding anything worth while. Probably only one prospector out of several thousand ever finds anything worth developing. Moreover, only 1 out of every 300 or 400 properties developed becomes a profitable mine.Prospecting was begun in the Western States in the fifties as the miners looked for the source of gold found in placers. The search for gold has been continuous since that time; the number of prospectors in the field at any one time, however, has varied greatly. Except in some desert regions, practicallyall of the placer fields now being worked were discovered by old timers; more-over, most of the important gold districts were found by early prospectors. Important discoveries of lode mines, however, have been made from time to time. Most of the area in the mining regions of the West has been searched many times by prospectors, and nearly all of the easily found deposits have been located, but it is reasonable to expect that new gold mines will continue to be found. Most of the future discoveries undoubtedly will be of deposits that do not outcrop. Prospecting for such deposits requires considerable digging.Several important discoveries were made in 1934. One of these, the Rogers-Gentry gold mine at the edge of Antelope Valley in Los Angeles County, Calif., was found by an experienced prospector on an old patented homestead a number of miles from the nearest producing mine. The initial discovery at this mine was an iron-stained, decomposed, silicous limestone outcrop, with no vein structure evident at the surface, near a small, barren quartz outcrop and a water seep. Another discovery, the Silver Queen gold mine, in the same general region and near Mojave, Calif., was found by an experienced miner on an open fraction 400 by 1,400 feet in size between two old properties that were thought to have been worked out years ago. The Silver Queen discovery was made as the result of finding a"

Feb 1, 1950

By J. G. Croeni

The titanium-iridium alloy system was investigated to determine whether alloys of this system would merit further development as control-rod material for nuclear reactors. A study was made to determine the titanium-iridium phase diagram by using melting-point, thermal analyses, X-ray diffraction, dilatometric, electrical resistivity, and metallographic techniques. The titanium-iridium alloy system was investigated between 500° and 2,400° C. Results indicate the formation of two intermetallic compounds, Ti3Ir rind TiIr3, and one intermediate solid solution centered about the 50 atomic percent iridium composition. A eutectic reaction occurs at 1,475° C, and 19 atomic percent iridium. The Ti3Ir decomposes peritectically at 1,520° C. The intermediate solid solution exhibits a maxima of 2,140° C. at 50 atomic percent iridium. This phase is also believed to undergo an order-disorder transformation at 1,750° C. Another eutectic reaction takes place at 2,000" C. and 60 atomic percent iridium. The compound TiIr3 formed at 75 atomic percent iridium decomposes peritectically at 2,115° C. Further increases in iridium content result in the formation of an iridium-rich terminal solid solution. Information obtained below 900° C. in titanium-rich alloys indicates that iridium acts as a beta stabilizer in titanium, and the authors believe that a eutectoid decomposition of beta-titanium occurs near 500° C. and 10 atomic percent iridium.

Jan 1, 1962

By Robert F. Holub

The Bureau of Mines has evaluated four working-level radiation-measurement methods and optimized them from the inherent and statistical error standpoint. Optimization with respect to various sampling and measurement times yielded no marked improvement over the existing methods. However, when appropriate approximations are made and evaluated, these two-measurement methods can be reduced to simple formulas, eliminating a need to use nomograms. These modified methods also have improved inherent error characteristics. A new method--a combination of two existing methods--with improved inherent and statistical errors has been suggested. All the pertinent equations are given, together with the computer program, so that any two-measurement method can be readily evaluated.

Jan 1, 1980

By Ann G. Kim

The Bureau of Mines investigated factors that influence the formation of methane and other hydrocarbon gases in coal, which is an integral part of the coalification process. Coalification begins with a biogenetic stage in which plant debris decomposes and peat is formed; methane and CO2 are the predominant gases produced during this stage. During the diagenetic stage of coalification hydrogen and the hydrocarbon gases methane, ethane, ethylene, propane, propylene, butene, iso-and normal butane, and pentane are formed by dissociation of the organic material. Methane may also be produced by a secondary reaction of hydrogen with unsaturates or by the reduction of CO2. The gas contained in coalbeds is a mixture of methane, C2 through C5 alkanes, CO2, O2, N2, H2, and He; its heating value is equivalent to that of natural gas. The gas content of coal depends on many variables, but an empirical relationship between adsorptive capacity, rank, and depth has been observed.

Jan 1, 1978

By Lloyd A. Morley, Robert Stefanko

1. Anonymous (Berggewerkshaftliche Versuchsstrecke), "75 Jahre Berggewerkshaftliche Versuchsstrecke, 1894-1969," 1969. 2. Anonymous, British Symposium on Flameproofing and Intrinsic Safety, IEEE Conf. Report Series No. 3, 1962. 3. Anonymous (Ministry of Fuel and Power), "A Review of Electrical Research and Testing with Regard to Flame-Proof Enclosure and Intrinsic Safety of Electrical Apparatus and Circuits," 1943. 4. Australian Standard Specification, ASC-98, "Electrical Equipment for Explosive Atmospheres," 1970. 5. Belgium Standard Specification, Norme NBM 286, "concernant la protection par enveloppe antideflagrante," 1965. 6. Bossert, J.A., "Approval for Electrical Equipment for Hazard Locations," paper PCI 66-33, IEEE 16th Annual Petrol. and Chem. Ind. Conf., L. A., California, Sept. 15-17, 1969. 7. Bossert, J.A., "Intrinsic Safety in Canada," Electrical Safety Practices, ISA Monogram, vn. 112, 1969. ,8. British Standards, BS229, "Flameproof Enclosure of Electrical Apparatus," 1957. 9. British Standards, BS4683 Part 1, "Classification of Maximum Surface Temperatures," 1971. 10. British Standards, BS4683 Part 2, "The Construction and Testing of Flameproof Enclosures of Electrical Apparatus," 1971. 11. Brown, G.R., and Silver, S., "An Explosion Hazard Due to Inflam¬mation of Aluminum Particles in Flat Flanges of Flameproof Enclosures," CEAL No. 197, Canadian Explosive Atmospheres Labor¬atory, 1969. 12. Campbell, J.D., and Chudleigh, J.P., "Problems Encountered in Designing Electrical Systems for Hazardous Areas," paper PCI-69¬31, IEEE 16th Annual Petrol. and Chem. Ind. Conf., L. A., California, Sept. 15-17, 1969. 13. Canadian Standards Association, C22.2 No. 30, "Explosion-Proof Enclosures for Use in Class I Hazardous Locations." 14. Dainty, E.D., and Brown, G.R., "Explosion Gas Temperatures at the Entrance to Flanges of Enclosures Containing 8.5% Methane-Air Mixtures," CEAL No. 196, 1969.

Jan 1, 1974

By Martin S. Oudenhoven

This report describes the results of a Bureau of Mines investigation in which the stress concentrations and distributions caused by inclusions in a strained elastic plate were determined, Finite element analyses were made for 168 models containing single inclusions of elliptical, ovaloidal, and rectangular shape. The variables studied included: horizontal-to-vertical loading ratios, (Sh/Sv) of 0,0.33,0.5, and 1.0; width-to-height ratios (w/h), of 0.25, 0.5, 2, and 4; and Young&apos;s modulus of inclusion to Young?s modulus of plate ratios (K ratios) of 0.33, 0.5, 2.0, and 5.0. The results show that the theory for elliptical inclusions can accurately predict the average stress along the x and y axes of symmetry for circular, ovaloidal, and rectangular inclusions from the width-to-height and K ratios. The actual inclusion shape was insignificant, suggesting that the average stresses in other inclusions of irregular shape (orebodies) can be estimated with the theory for an elliptical inclusion. An application of this technique to mining problems is presented. The stresses in the elliptical inclusions were uniform throughout the inclusion for all the models studied.

Jan 1, 1972