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By E. Don Dilling, W. F. Holbrook, Lloyd R. Michels, James W. Pennington, Dwight L. Harris, Wm. F. Hergert, Cyrus L. Blogett, H. A. Doerner, Ernest A. Reige

"IntroductionA process for production of magnesium by carbothermal reduction was developed at Padentheirm, Austria, by the Austro Americanische Magnesit Corporation& an independent investigation of this and other processes was started in 1937 by the Bureau of Mines at Pullman, Wash., with the cooperation of Washington State College. 10/ A preliminary study of the Radentheirm pro¬cess, as revealed by the meager information then available, demonstrated the following two major disadvantages,The use of hydrogen for shock cooling requires an enormous volume of gas - about 1,000 cubic feet for condensing each pound of metal as a pyrophoric dust which must be completely separated from this gas. Then if the gas is to be recycled for repeated use, the CO produced by the reduction reaction must be separated from the hydrogen. These separations are costly from the standpoint of equipment and operation. 11/The condensate is an impure, pyrophoric metal powder that must be purified and converted to coherent form. This is accomplished by distillation or sublimation of the metal. Distillation on a large scale involves difficulties inherent in the high boiling point (1,107° C.) and the chemical activity of the metal. To avoid these difficulties, the metal is sublimed at 600° C. and of very low pressure. This is quite easily carried out as a batch operation but is a costly procedure. A continuous sublimation process has not been accompli shed."

May 1, 1945

By Lloyd H. Banning

Crucible-smelting tests at the Northwest. Electrodevelopment Laboratory and a pilot-plant test on electric smelting of western phosphate rock for the Westvaco Chlorine Products by the Tennessee Valley Authority indicated that the small vanadium content of the rock is concentrated in the ferrophosphorus by-product of Phosphorus smelting. This research is concerned' mainly with recovering vanadium and phosphorus froth the ferrophosphorus produced from western phosphate rock. Exploratory tests were made of several methods of treating vanadiferous ferrophosphorus. Attempts to separate vanadium as a carbide dross by saturating molten ferrophosphorus with carbon were unsuccessful. Volatilization of phosphorus from ferrophosphorus was accomplished to some extent, both with and without addition of sulfur in several forms, but elimination of phosphorus was not complete. Brief testing in a small experimental converter on oxidation of vanadium and phosphorus; into a slag by blowing with air showed promise. A method that comprised fusing vanadiferous ferrophosphorus mixed with soda ash under oxidizing conditions gave encouraging results and was tested beyond the preliminary stage. A slag product of the fusion contained most of the phosphorus and vanadium as water-soluble sodium phosphate and. virtually water-insoluble sodium vanadate. After leaching the sodium phosphate froth the slag, the leach residue was reroasted with soda ash and salt. This roasted product was leached again with water to extract the vanadium.

Jan 1, 1951

By Richard L. Sanford

This report summarizes the results of an update on a previous Bureau of Mines grant (G0264026), and includes 5 additional years of computer pro-gram development. The directory includes a sampling of computer usage in operating and manufacturing companies, consulting firms, computer companies, research organizations, universities, and various governmental agencies. References to computer applications throughout the industry are presented as well as comments on program availability. The work effort on the updated directory concentrated on programs that are available to the public and are well documented.

Jan 1, 1982

By Floyd G. Anderson

This report reviews and summarizes information on prevention and suppression of dust in mining, tunneling, and quarrying published in the United States from 1961 through 1967. Unpublished pertinent data developed or assembled by the Bureau of Mines during this period also are included.

Jan 1, 1969

By E. S. Shedd

Amenability studies were conducted by the Federal Bureau of Mines on an electrooxidation technique for the extraction of mercury from cinnabar ores, particularly those that are too low in grade to be furnaced or retorted economically. Oxidation was accomplished by electrolysis of the ore while slurried with brine. Mercury was dissolved through the formation of the soluble tetrachloro mercury complex, HgC142-. Mercury extractions ranged from 90 to 98 percent in 4 to 6 hours of processing time when tests were made on eight different types of cinnabar ores containing from 0.7 to 18 pounds mercury per ton ore. Salt concentration was varied from 4 to 10 weight-percent depending on whether Pb02 anodes and iron cathodes were used or whether graphite was used for both electrodes. Power consumption ranged from 17 to 64 kilowatt-hours per ton of ore treated. Ninety-nine percent of the mercury was recovered from pregnant solutions by precipitation on an active metal such as zinc, followed by distillation of the resulting amalgam at 600° C.

Jan 1, 1975

By E. S. Leaver

The gold that is not recovered by a particular process is refractory to that process. A study to determine how the refractory gold is associated in the ore constituents usually indicates the needed improvement in the process or additional methods for bettering recovery. In preliminary work, segregation of the various minerals, gangue or impurities, and data showing the reactions of each in the recovery method readily confines the refractory gold to a certain part on which extensive research can be directed. In this dissecting plan, the microscope is an important aid in locating the refractory gold but should be supplemented by chemical tests.

Jan 1, 1934

By J. W. Paul, J. N. Geyer

"GENERAL STATEMENTThe purpose of this report, which is the first of a series of three covering mines in the Fairmont district of West Virginia, is to give the result of a' study conducted in seal mines to ascertain the nature of the safeguards employed to prevent injury to the workmen from falls of roof and coal. In presenting the subject matter, consideration must necessarily be given to factors, features, and conditions such as method of mining, timber regulations and practices, supervision and natural conditions; and, for comparative purposes, a certain amount of statistical matter bearing upon the relation of fatalities and injuries to their causes, tonnage produced, men employed, days worked, and time lost.Those features and practices found to promote safe protection are summarized and suggestions made for such additional safeguards and practices as appear to give greater protection against injury from falls of roof or coal.ACKNOWLEDGMENTSThis study of falls of roof and coal in mines in Harrison County has been conducted by the U. S. Bureau of Mines in cooperation with R. M. Lambie, chief of the Mining Department of the State of West Virginia who assigned L. W. Brown, a district mine inspector, to assist in the field work and in the preparation of individual reports on each mine visited in this study. The writers acknowledge the helpful suggestions and cooperation given by these officials, the latter of whom assisted in the field work and prop red most of these sketches for the individual reports which wore submitted to the operator by the chief of the department. Thin report is a summary of the contents of the individual reports heretofore furnished the individual operator."

Aug 1, 1931

By Joan T. May

Federal Bureau of Mines studies showed that some organic amine hydrochlorides can be used as dehydrating agents for producing anhydrous magnesium chloride from hydrates and brines. Laboratory-scale tests showed that double salts are formed by reacting 35 percent magnesium chloride brine or spray-dried magnesium chloride with pyridine hydrochloride. Heating decomposed these double salts to anhydrous magnesium chloride and recycle pyridine hydrochloride. Pyridine hydrochloride also chlorinated any magnesium oxide in the spray-dried magnesium chloride. The anhydrous magnesium chloride obtained by the method described contained less than 0.8 percent oxygen. More than 98 percent of the organic amine hydrochloride was recovered.

Jan 1, 1978

The National Institute for Occupational Safety and Health (NIOSH), in partnership with stakeholders in the mining and surface drilling industries, con-ducted research to develop engineering control technologies that reduce workplace noise exposure. The result of this research partnership is the development of a partial cab.

Jan 8, 2007

By C. G. Maier

Relatively infrequent use by metallurgists of the term "sponge chromium" as contrasted to more than occasional reference to "sponge iron" may be ascribed to the fact that the former material is not a commercial product, while the latter has been known and used, at least in one form (Swedish sponge iron), for several decades. It is doubtful whether a true sponge chromium ever has been prepared heretofore in the laboratory by more than one or two investigators. Nature presents a much. more difficult problem to the investigator endeavoring to make sponge chromium than pertains to the production of more easily reducible elements such as iron or nickel. Recent widespread interest among metallurgists in the possibilities of powder metallurgy is ample incentive to explore the feasibility of producing pure chromium metal in finely divided form. The shift in terminology of this statement from "sponge" to the "finely divided form" is deliberate in emphasis of distinction between terms that occasionally have been used loosely. It would seem desirable that a uniform usage descriptive of finely divided metals be adopted. While to some it might seem preferable that the terra "powdered" metal be reserved for a finely divided form produced by mechanical means, as, for example, chromium produced by the mechanical comminution of electrolytic sheets or flakes, current usage of the term "powder metallurgy' involves no distinction as to source type of material. It is usually accepted, however, that a sponge metal is one reduced from oxide or other combined form at temperatures below the melting point of metal or oxide so that the particles of metal are pseudomorphic, at least macroscopically, with the source material, and, in consequence of the loss of material without change of external shape of the particles necessarily have an open, porous, or "spongy" structure.

Jan 1, 1942

By Mary S. Esfandiary

U.S. scientists attempting to maintain continuous surveillance of scientific information are confronted with two acute problems: The steady, even spectacular; increase in the volume of such information and the fact that much of it is published in unfamiliar foreign languages, According to the National Science Foundation, almost one-third of the world's scientific literature is published in languages that are read by less than 5 percent of U.S. scientists. Most scientists in the United States must rely on abstract journals and translations to obtain information on developments in research and investigations conducted in the non-English-speaking countries. However, there are problems involved in procuring suitable abstracts and translations and in obtaining such information as cheaply and rapidly as possible.

Jan 1, 1961

By Robert T. MacMillan

An essentially chemical technique has been developed on a small scale for the efficient utilization of certain domestic titaniferous iron ores. Three main steps are involved: (1) Sintering the ore at 1,050° C. with carbon and soda ash to reduce the iron to metal powder, retaining the titania in the slag, (2) separating the powdered iron from the slag, after wet grinding, by magnetic or gravity methods, and (3) sulfuric-acid decomposition of the titania fraction to produce pigment and certain byproducts. The technique was first applied to the tailings from the Bureau of Mines bauxite-concentrating plant at Bauxite, Ark. A good grade of powdered iron was produced from this material. Subsequently, the work was diverted to the study of the titaniferous magnetite from the MacIntyre Mine at Tahawus, N.Y., because of the potentially higher recoveries of iron, titanium and vanadium. Ninety percent of the iron in this ore has been recovered as an iron powder analyzing 90 percent metallic iron and containing 2 to 3 percent TiO2. The remaining titania was found in the slag and was recovered as pigment-grade TiO2 by application of a suitable technique. The vanadium was distributed between the TiO2 fraction and the alkaline liquor resulting from the wet-grinding and magnetic-separation operations, with only a minor proportion retained by the metallic iron.

Jan 1, 1950

By Dwight L. Sawyer

To provide technology that can help decrease the dependence of the U.S. aluminum industry on imported bauxite, the main ore of aluminum, the Bureau of Mines is investigating the extraction of aluminum from abundant domestic reserves of kaolinitic clay. Miniplant studies of the continuous leaching of calcined kaolin with boiling 25-pct HC1 acid resulted in a 93- to 99-pct extraction of the acid-soluble alumina in the calcined kaolin feed. Data are presented for an acid leaching study carried out in three or four continuously stirred tank reactors (CSTR) in series, feed rates of 100 to 250 lb/hr of calcined kaolin, and total nominal residence times of 0.7 to 2.3 hr. A material balance for a 176-lb/hr calcined kaolin feed rate in a circuit consisting of three reactors, four classifiers, and five thickeners is given. Data provide detailed compositional and physical information for calcined kaolin, process liquors, and acid-leached residue solids.

Jan 1, 1983

By E. G. Baglin

As part of an effort to decrease U.S. dependence on imports of critical and strategic metals, the Bureau of Mines investigated three leaching methods for extracting the base metals and recovering platinum-group metals (PGM) from matte prepared from Stillwater Complex flotation concentrates. Because of a limited supply of natural material, synthetic matte of composition similar to matte prepared from natural concentrates was used to devise the extraction sequences. The validity of the sequences was verified with matte prepared from Stillwater concentrates. In two-stage matte leaching, first-stage H2S04 leaching extracted 99 pct of the nickel and iron from the matte but negligible amounts of copper and PGM. Second-stage oxidative leaching with Fe2(S04)3 or FeC13 solubilized more than 98 pct of the copper and no precious metals. Sequential leaching, in which acid and oxidizing lixiviants were added sequentially to the matte without an intervening filtration step, extracted 99 pct of the Fe, Ni, and Cu. A roasting-leaching technique, in which the residue from first-stage leaching was roasted between 360° and 500° C before a second leaching with H2S04, solubilized 98 pct of the copper. The three leaching methods yielded high-grade PGM residues containing more than 98 pct of the PGM in the matte.

Jan 1, 1982

By H. R. Shell

The work on synthetic mica and related subjects is being reported in a series of technical articles (see Supplementary Bibliography), each of which describes some special aspect of the subject. This is the final report on chemical analysis of the fluoride-containing silicates. A condensation of this report has been published (26).3/ Chemical analysis affords one of the best means of ascertaining the final com-position of either a heterogeneous mass or a single pure crystal, particularly where some constituents may be volatile. The analysis of fluoride-containing silicates was not so well known or understood that highly accurate results were commonplace. For example, on synthetic mica a university laboratory reported 11.6 and 9.2 percent fluoride when at least 13.3 and 11.3 percent were present, respectively; a commercial testing laboratory reported 9.14 percent as compared to 12.6 percent; and a glass company reported 7.0 percent as compared to 9.0 percent present. No intimation is made that these analysts could not have done better, but the point to be stressed is that the methods in use were long, tedious, and generally required a certain familiarity for best results.

Jan 1, 1956

By R. Lincoln

A surplus of vanadium has resulted from the tremendous output of uranium, of which vanadium is a byproduct. More knowledge of the properties and characteristics of vanadium as a pure metal has been needed so that industry can take advantage of its availability and use it according to the best principles of conservation. Besides the problem of utilization, there is the ever present need of finding new materials which will satisfy specific and demanding requirements of science and engineering; vanadium or one of its alloys may possess the latent potential for filling some of these needs. Thus this? research project was undertaken by the Bureau of Mines to determine and examine some of the physical and mechanical properties of pure vanadium. A corallary investigation was the determination of the effect of the interstitial contaminants, oxygen, nitrogen, and carbon, on unalloyed vanadium. The vanadium used for these determinations was principally the product of experimental production of the Bureau. The evaluation of this material, as small quantities became available, provided most of the data that have been obtained.

Jan 1, 1962

By Christopher C. Jobes, Alan G. Mayton, Timothy J. Matty, Joseph P. DuCarme

Mining injury statistics show that a significant number of back, neck, and head injuries are linked to exposure from vehicle vibration. Use of a suspension seat is a common way to isolate the vehicle operator from the adverse effects of vibration exposure. Thus, researchers at the National Institute for Occupational Safety and Health1 – Pittsburgh Research Laboratory (NIOSH – PRL) performed laboratory studies on four passive and two semi-active seat suspension designs. These are typical of seat suspensions commonly found on large off-road heavy surface mining, construction and agricultural vehicles as either replacement or original equipment manufacturer (OEM) systems. One included a pneumatic (air bladder) spring mechanism. The fifth and sixth suspensions were a NIOSH magnetorheological (MR) semi-active damper design based on the pneumatic (air bladder) and one of the coil spring suspensions above. These suspensions were modified with a commercially available MR damper substituted for the OEM damper. These six seat suspension systems were tested and analyzed, for vertical vibration only, using the ISO 5007 Standard [1]. This paper describes the laboratory vibration tests using a MTS® shaker table and discusses the results obtained for the different suspension designs and highlights the rheonetic technology studied. Implications of the seat suspension designs relative to their capabilities for isolating vehicle operators from vibration exposure are discussed. Results for suspensions 1 through 3 showed frequencies of isolation from 2.1 to 3.0 Hz using the 40-kg (88-lb) mass and from 1.65 Hz to 1.8 Hz using the 80-kg (176-lb) mass. Suspension #4, in tests with only the 80-kg (176-lb) mass, showed an isolation frequency of 3.7 Hz. With the MR damper added to seat suspension #4, the peak transmissibility was lowered from 1.3 to 0.95 and showed a corresponding downward shift in frequency from 2.25 Hz to 1.4 Hz. In fact, the results for suspension #5 (the MR damper added to seat suspension #4), using test #3 conditions of the programmed control algorithm, showed isolation (attenuation of transmitted vibration) throughout the test frequency range from 1.0 to 6.0 Hz.

By Ferdinand Roehlich

An evaluation of the use of manually activated, installed,. dry chemical fire protection systems on underground metal and nonmetal mine vehicles is described. In addition, an assessment of the possible health risks posed by the dry chemical extinguishing agents used in such systems is provided. Work involved installation of fire protection hardware on an operating piece of underground metal/nonmetal mine equipment and, via actual fire tests, a determination of the effectiveness of the hardware in extinguishing on-vehicle fires. Two fire protection systems were installed on a Caterpillar 988 front-end loader in St. Joe Mineral's Fletcher mine, near Viburnum, Mo. Both a fully pressurized Safety First CM-20 and a nonpressurized cartridge actuated Ansul A-101 were installed for comparative purposes. Both systems operated satisfactorily during an 8-month endurance trial period which preceded the actual fire tests. Each system was able to extinguish an 18" x 4" class B test fire placed in the engine area of the machine. The health hazards analysis of dry chemical powder consisted of a detailed search of published literature relating to these multipurpose agents. This data was verified via a controlled laboratory analysis of two monoammonium phosphate based powders (Safety First Unikem and Ansul Forey) and an analysis of air samples collected at various locations on the test vehicle during the fire tests. Although the powder was found to be nontoxic, two potentially dangerous thermal decomposition products were identified--ammonia and phosphoric acid. However, later analysis indicated that an operator would not be exposed to dangerous concentrations of either compound if he were to remain outside of the powder cloud. A "Selection and Use Manual for Manually Activated, Fixed Fire Suppression Systems on Underground Metal and Nonmetal Mining Equipment" was prepared both as an, appendix to the report and for distribution under separate cover.

Jan 1, 1977

By B. T. Brady

Recent theoretical, experimental, and field studies conducted by the Bureau of Mines suggest that rock failures may be predicted and, in some instances, controlled. Theoretical studies that were later corroborated by laboratory and field studies predict that a seismic anomaly will precede rock bursts and/or roof falls in mines. The seismic anomaly is predicted to consist of an increase in the number of seismic events occurring in the immediate vicinity where the failure 1s nucleated. This increase will then be followed by a dramatic decrease of seismicity in a broad region that surrounds the location of the impending failure. The dimensions of this region allow a preliminary estimate of the time to failure (measured from the time the seismicity increase began) as well as an estimate of the energy that will be released at the instant of failure. Field observations indicating that this predicted behavior does precede rock bursts and a roof fall are presented in this report. Implications of results to the problem of failure control in mines that experience massive rock failures are discussed.

Jan 1, 1978

By C. A. Cole

This work consists of research in cable fault location and the construction of four field-test units based on the research. Swept-frequency sounding of mine cables with RF signals has been the technique most thoroughly investigated. The swept-frequency technique is supplemented with a form of moving target indication (MTI) to provide a method for locating the position of a technician along a cable and relative to a suspected fault. Separate, more limited investigations involved high-voltage time domain reflectometry and acoustical probing of mine cables. Particular areas of research included microprocessor-based control of the swept-frequency system, a microprocessor-based fast Fourier trans-form for spectral analysis, RF synthesizers, transmit-receive switches, RF receivers, cable dispersion-compensation techniques, low-voltage multielement display systems, and techniques for injecting or recovering RF energy through cable walls in support of clamp-on fault locators.

Jan 1, 1982