Search Documents

By E. L. Burwell

Application of the in situ recovery process to oil shale was tested during two field experiments near Rock Springs, Wyo. The results of these tests demonstrate that a self-sustaining combustion zone can be created in an oil shale body, that this zone can be moved through the oil shale, and that the process will produce shale oil. Evaluation of the combustion process by monitoring produced fluids for physical and chemical properties and volumes is described. The material and energy balance obtained is compared with a second evaluation based on extensive coring of the test area after the test was terminated. Several side results of the research are noted such as ground surface heating by underground burning and production of low-to medium-Btu gas during retorting.

Jan 1, 1973

By Edward L. McHugh, Charles Sabine, Louis J. Denes, Jami M. Girard, Peter Metes

The Spokane Research Laboratory, National Institute for Occupational Safety and Health, is investigating various remote sensing technologies as possible tools to detect, monitor, and mitigate hazardous situations in surface mines that could lead to catastrophic slope failure. Promising technologies include a field-portable spectro-polarimetric imager and a stationary interferometric radar device. Field tests were conducted of a prototype visible and near-infrared spectro-polarimetric imager (SPI) built at the Carnegie Mellon Research Institute. The SPI employs anacousto-optical tunable filter (AOTF) to control wavelength, a phase retarder to measure polarization signatures, and a digital camera and computer to capture data. Images obtained at the Mountain Pass and Castle Mountain mines in southeastern California showed that the instrument is capable of obtaining hyperspectral images of highwalls, outcrops, hand samples and drill core in the field. We have retrieved spectra from Mountain Pass images that closely match those of bastnaesite and have had some success in classifying images. Although radio frequency noise in the data limited spectral classification of imagery, we project that careful alignment of the AOTF should minimize the noise and greatly improve classification.

By Thomas E. Green

A solvent extraction procedure using 8-hydroxyquinoline and chloroform was investigated by the Bureau of Mines as a preconcentration technique for the determination of aluminum, calcium, cobalt, copper, iron, lead, magnesium, manganese, nickel, and zinc in large samples of high purity tungsten. X-ray spectrographic and atomic absorption methods were used to determine the trace metals after preconcentration. The presence of 10 grams of tungsten had a pronounced effect on the distribution of 8-hydroxyquinoline between the aqueous and chloroform phases. This change in the 8-hydroxyquinoline distribution in turn had an adverse effect on the extraction of the trace metals. Extraction efficiencies can also be adversely affected by an increase in the quantity of extractable metals present, as shown by radiotracer tests using 65Zn. Excess 8-hydroxyquinoline in the extracts did not interfere with the determination -of the serious interference in the combined ion exchange paper--X-ray spectrographic method. Although preconcentration by 8-hydroxyquinoline extraction was found to be partially successful, other preconcentrationn methods based on ion exchange and dithizone extraction were found to be superior.

Jan 1, 1968

By d&apos, Kathleen J. Amico

This summary appears in Minerals Yearbook volumes I and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The several commodity and area chapters contain further details on production. A summary table comparing world and U.S. mineral production also is included. Mineral production may be measured at any of several stages of extraction and processing. The stage of measurement used in the chapter is normally what is termed "mine output." It usually refers to minerals in the form in which they are first extracted from the ground, but customarily includes for some minerals the product of auxiliary processing operations at or near mines.

Jan 1, 1967

Spectrochemical methods were developed to determine beryllium in the concentration range 0.0015 to 4.0 percent in siliceous mineral beneficiation products. Two methods are described. They are (1) a fusion-pellet-spark procedure (spark method) and (2) a sustaining alternating-current arc procedure (arc method). In the spark method the sample is fused with lithium tetra-borate and vanadium pentoxide. The resulting bead is crushed, mixed with powdered graphite, and briquetted. This is analyzed spectrographically using controlled high-voltage spark excitation. In the arc method the sample is diluted with germanium metal, graphite, and vanadium pentoxide. Weighed charges are packed into cupped graphite electrodes and subjected to excitation with a sustaining alternating-current arc. Vanadium serves as internal standard for both methods. Effects due to matrix variations in samples and standards are eliminated either by fusion with lithium tetraborate in the spark method or by dilution with germanium and graphite in the arc method. Beryllium determinations show deviations from accepted chemical values of approximately 5 and 8 percent for the spark and arc methods, respectively. Analyses can be made more rapidly by the arc procedure with a sacrifice in precision and accuracy. Either method can be applied to the determination of beryllium in silicate rocks.

Jan 1, 1962

By B. Z. Zhong, T. Ong, W. E. Wallace, W. Z. Whong, Z. W. Gu, M. J. Keane

"Abstract-Diesel emission particles (DEP) from an engine operating on the Federal Test Procedure VDC were dispersed in an aqueous mixture of dipalmitoyl lecithin (DPL). a major component of pulmonary surfactant and saline and were tested for genotoxicity using the unscheduled DNA synthesis (UDS) assay with autoradiography techniques in cultured Chinese hamster lung cells. A DEP sample from the same source was dispersed in dimethyl sulphoxide (DMSO) and subjected to the same assay. Both dispersions (in DPL and DMSO) were found to induce UDS in a dose-related manner. After separation of the sample into supernatant and sediment fractions. the activity of the DEP sample was found to reside in the supernatant fraction for the DMSO-dispersed sample; and in the sedimentary fraction for the surfactant-dispersed sample. These findings further indicate that genotoxic activity associated with DEP inhaled into the lung may become bioavailable through the dispersion properties of pulmonary surfactant components.INTRODUCTIONTHE mutagenicity of diesel emission particles (DEP) has been studied intensively (LEWTAS and WILLIAMS, 1986). Carcinogenic effects of diesel exhaust in exposed animals have been reviewed (NIOSH, 1988) and an evaluation of carcinogenic risks to humans from diesel engine exhausts has been published (IARC, 1989). Using components of pulmonary surfactant such as dipalmitoyl lecithin (D PL), dipalmitoyl phosphatidylethanolamine (DPPE) or dipalmitoyl phosphatidic acid (DPPA) dispersed in physiological saline, we have previously shown that diesel soots express mutagenic activities in the Salmonella histidine reversion assay system and in the sister chromatid exchange assay using the cultured Chinese hamster lung (V79) cells. Mutagenic activity of diesel soots dispersed in DPL, DPPE and DPPA was quantitatively comparable to and in some cases greater than, the activity expressed by an equal mass of soot extracted by dichloromethane-dimethyl sulphoxide (DCM-DMSO) (WALLACE et al., 1989).Unscheduled DNA synthesis (UDS) is accepted and frequently included, as one of the tests in the battery of assays used to assess carcinogenic-mutagenic potential -of chemicals (MITCHELL et al., 1983). In this study, induction of UDS in V79 cells by DEP, dispersed in the major component of pulmonary surfactant DPL, was carried out. The purpose of this study is to validate the suggestion generated from our previous work that mutagens associated with inhaled particles may be dispersed or solubilized in the phospholipid component of pulmonary surfactant and become active in such a phase (WALLACE er al., 1989) and to test the fractionated DEP sample using UDS assay for a more complete evaluation of its genotoxicity."

Dec 1, 1995

By David C. Oyler, Paul B. Stubbs

The Bureau of Mines and United States Steel Corp. are conducting a joint project to monitor formation pressures at a large (23-well) coal- bed gas drainage field near Oak Grove, AL. Three monitor holes were drilled in late 1981, and pressure monitoring began in December 1981. The Bureau of Mines direct method was used to obtain gas content data from cores taken in the monitor holes. Comparison of the 1981 gas con- tent data from the monitor holes with initial gas content values obtain- ed from the production wells in 1977 indicates a 50-pct reduction in ad- sorbed gas content inside the pattern and a 29-pct reduction at one point 500 ft outside the pattern. The combination of pressure and gas content data has also allowed an in situ isotherm curve, relating the formation pressure to adsorbed gas content, to be developed for the area of the production wells. From the current rate of pressure decline (1 lbf/inz per month), the observed changes in gas content, and the isotherm curve, it appears that most of the early gas production came from within the pattern, but since 1981 (and possibly earlier) most of the gas produced has been migrating to the wells from outside the pattern area.

Jan 1, 1985

By William L. Crentz

1. SALES PUBLICATIONS

Nov 1, 1949

By R. M. Ray

The Bureau of Mines evaluated five commercial badge-type carbon monoxide dosimeters. Color changes in the badge reagent indicated the presence of carbon, monoxide. Possible effects of ambient conditions on dosimeter response to CO during or after coal mine fires or explosions were studied. Temperature and humidity changes did not change dosimeter sensitivity to CO. Contaminant gases such as CO2, N02, S02, and H2S had effects that varied with brands of dosimeters ranging from no effect to increased sensitivity to CO. Dosimeters tested after 6 months of storage showed an increase in failure rate as high as 25 percent. Tests were conducted to determine the effects on dosimeter time-for-color change caused by observer's sight (colorblind); lighting, and coal dust on dosimeters. No significant effects were observed. Observer variance was the most pronounced factor observed in all tests.

Jan 1, 1975

By Manuel Gomez

Dehydrogenation factors, proximate analysis, and ultimate analysis were examined as predictors of the low-temperature -carbonization properties of coals varying in rank from lignite through anthracite. All factors studied contributed to reduction in variance of the sample populations investigated. Response surface regression models based on variables from proximate and ultimate analyses of coal were constructed for eight low-temperature carbonization assay product and gas component Fields. These models were tested with independent samples that included drill cores, sized fractions, petrographic fractions, and run-of-mine coal. The models developed were used to predict low-temperature carbonization yields or coals from major fields of Wyoming. This information was cast in the form of contour plots describing the potential low-temperature carbonization product yields of Wyoming coals and the properties of the resultant char or coke. The variables used as input v the models may be measured and collected during exploration; thus, the carbonization properties of a seam can be determined in advance of mining. The information presented in this report is useful in that it broadens the deciionmaking base for management when either mine locations or coal conversicl plant sites, or both, are being considered.

Jan 1, 1971

By M. M. Hassan

This report describes the analysis tools developed at West Virginia University which can be implemented to optimally design coal mine electrical systems. The basic analytical tools for all power systems are the load-flow and short-circuit analysis. Well known programs have been developed for analysis of ac transmission and distribution systems, but they are not applicable to a system which has combined ac/dc distribution, such as a coal mine power system. Furthermore, the topology of a coal mine electrcal system changes continuously due to the movement of the locomotives on the track. In the first section of this report, algorithms for carrying out load flow and short-circuit analysis of a coal mine electrical system are described. Results from the study of a typical coal mine system are presented. In the second section a method is described to optimally size power cables for cyclic loads. The method is based on the development of a thermal-electric model for a low-voltage power cable. Results from experimental verification of the model are also presented. These techniques are useful in the safe, efficient, reliable and economical design of the coal mine electrical power systems.

Jan 1, 1979

By C. Özgen Karacan

Degasification and methane control in underground coal mining is an important area augmenting conventional ventilation in order to prevent possible fires and explosions due to excessive methane emissions. Coal bed reservoir engineering has been applied for many years to coalbed methane production. In recent years, modeling the flow and draining methane, not only from coal bed itself but also from the overlying strata, have been recognized as important areas of expertise for supplementing underground ventilation. This paper demonstrates the applications of coal bed reservoir engineering and modeling techniques for optimizing and controlling methane emissions in longwall and continuous miner sections. Practical applications and some considerations are presented for reservoir modeling, borehole performances, and face emission predictions for various coal bed and borehole configurations. A section on field reservoir studies and well bore log analyses for methane control are also presented as a complementary way of controlling methane and optimizing ventilation.

Jan 1, 2009

By H. B. Brunot

A complete list of permissible mine equipment, tested and approved by the Bureau of Mines previous to January 1, 1947, was published as Information Circular 7432.2/ A list of permissible mine equipment tested and approved by the Bureau of Mines during the calendar years 1947, 1948, and 1949 was published as Information Circular 7569. The present list supplements Information Circulars 7432 and 7569 and includes all of 'the equipment approved during the calendar year 1950. Information Circular 7465, which included a list of permissible mine equipment tested and approved by the Bureau of Mines during the calendar year 1947 therefore is superseded.

Jan 1, 1951

By Everett A. Sondreal

Data are presented on the characteristics of lignites with emphasis on the composition and fusion properties of the ash. Differences in the analyses of commercial-grade lignites are related primarily to variations in moisture and ash contents. Lignite ash is generally characterized by high concentra¬tions of alkaline earth oxides and a greater tendency for retention of sulfur in the ash than higher-rank coals. Composition of ash varies significantly within and between mines. The differences within mines are significant for short distances and may be eliminated under certain circumstances by normal mixing occurring during mining. The sulfur in lignite averages 0.6 percent and is found primarily in the organic or pyritic forms with only a trace of the sulfate. During the stan¬dard laboratory asking procedures, from 60 to 100 percent of the original sul¬fur is retained in the lignite ash. Trace elements, such as uranium and germanium, in the ash from commercial¬-grade lignites are present in low concentrations, but others, primarily copper and silver, are present in specific samples in concentrations approaching those found in some commercial ores.

Jan 1, 1968

By Richard F. Link

The principal procedures for the statistical analysis of gold assay and other trace-element data depend on applying either the normal frequency distribution or the lognormal frequency distribution. The consequences of applying both methods are examined through reference to example data from United States and South African gold mines. It is concluded that for estimation of average grades, except for certain data with a very high coefficient of variation (ratio of standard deviation to mean), use of the lognormal distribution is ordinarily undesirable because bias may be introduced and little efficiency can be gained. However, if biased average grades can be tolerated, as in the examination of data from surveys in exploration geochemistry, use of the log-normal distribution may be desirable. Various statistical analyses are detailed, and the tables presented to implement the analyses are more complete than those previously published.

Jan 1, 1971

By C. E. Coleman, Joseph D. Davis

During some distillation experiments conducted by the Bureau of Mines in cooperation with the Trent Process Corporation it was observed that amalgams of heavy petroleum oils and finely pulverized coal tended to produce a denser coke than that obtainable from the coal when retorted alone . Even anthracite coal when retorted with oil yielded a coke . This led the writers to believe that by mixing a lowrank coal ( sub-bituminous or even lignite ) - with asphaltic oil and retorting it, a coke suitable for domestic fuel could be made . Thus there was contemplated the production of domestic coke and the utilization of a low- grade oil in one operation . - In order to decide on the practicability of this process , it was necessary to know the value of products obtainable by such a method , as compared with those obtained by separate distillation . A laboratory method was therefore devised , and while it was realized that no small - scale testing apparatus for destructive distillation gives results that are directly applicable to commercial - scale operations , by keeping distillation conditions uniform for comparative tests , results were obtained valuable for purposes of comparison . The plan was to distill mixtures of coal and oil in a laboratory retort , and then distill the constituents separately under the same conditions . The comparative quantities of products yielded were thus directly obtained , and their quality was determined by analysis . The following are the main points investigated : ( 1 ) Quantity and quality of coke ; ( 2 ) Quantity of oils boiling below 221 °C . ( gasoline stock) and oils boiling at 221 to 300° C . ( kerosene stock) ; and ( 3) Quantity and quality of gases .

Jan 1, 1922

By T. L. Joseph

The purpose of this article is to describe briefly the operation of a 6-ton blast furnace on a charge of bauxite, limestone, iron ore, and cast-iron turnings and to point out the bearing which smelting such a charge has upon the production of alumina cement. One object of the experiment, conducted by the Bureau of Mines in cooperation with the Aluminum Co. of America, was to determine whether tae so-called Pedersen process3 can be applied to the blast furnace. This process consists of smelting a charge of bauxite, iron ore, and. limestone, and results in to products. One is a slag containing about 50 per cent of A1203 and is intended for use in manufacturing aluminum, and the other is iron low in sulphur. Complete details of the test are published in other reports4. Blast-furnace slag is now recognized as a satisfactory and economical raw material for making Portland cement, Wm. A. Forbes5 has recently reported that in 1926 an important steel interest used well over 1 million tons of slag in producing about 24 million long, tons of cement. This is equivalent to about ½ ton of slag for each ton of cement. Alumina cement can be made direct in the blast furnace. Its physical character would have to be changed by grinding, but no change in its chemical composition would be necessary.

Jan 1, 1928

By A. B. Whitehead

A spectrographic method for the determination of 18 impurities in cerium is presented. The carrier distillation technique is utilized to separate the spectra of impurities from the complex spectrum of cerium. Metal samples are ignited to the oxide, mixed with silver chloride carrier containing an internal standard, and excited with a 20-ampere direct-current arc. An additional exposure, made after carrier depletion, provides for the determination of refractory elements. Experiments to determine the best carrier, sample-carrier ratio, electrodes, arc current, exposure conditions, internal standards, and any matrix effect are described. The relative standard deviation of the method at the 20- and 200-part-per-million levels is about 25 and 15 percent, respectively. The average relative error is about 20 percent in the 10- to 1,000-part-per-million concentration range.

Jan 1, 1962

By Charles A. Kumbe

"INTRODUCTION The Sullivan Mine was examined by Thomas L. Chapman, an engineer of the Bureau of Mines, in March 1943. Samples taken from the few mineralized exposures justified further investigation of the property. To determine whether extensive exploration of the property would be warranted, the Bureau did a small amount of trenching and underground work during April 1943, 3/ under Bureau project 1462.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its, primary objective the, more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratary project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurigical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests.The investigations of the and Metallurgical Branches of the Bureau, as reported in this paper, were supervised by J. Hedges, district engineer for Arizona, and S. R. Zimmerly, regional engineer for the Western Region, respectively."

Feb 1, 1947

By N. S. Dalal, B. Jafari, F. H. Y. Green, M. M. Suryan, V. Vallyathan

"Freshly ground and aged anthracite and bituminous coal samples were investigated by electron spin resonance (ESR) spectroscopy to detect the presence, concentration and reactivity of free radicals. Freshly ground anthracite coal produced greater concentration of free radicals than the bituminous coal, and the radical reactivity was also greater for the anthracite. The reactivity of the newly produced free radicals in the anthracite dust correlated with the dust's toxicity. Furthermore similar coal-based free radicals were detected in the lung tissue of autopsied coal miners, suggestive of persistent reactivity by the embedded coal dust leading to the progressive disease process. Results of the studies on the severity of coal workers' pneumoconiosis (CWP) and free radical concentration m lung tissue support this hypothesis.INTRODUCTIONCOAL WORKERS' PNEUMOCONIOSIS (CWP) has been an important topic of concern to miners, mining engineers, epidemiologists and medical researchers for decades. It is well known that the prevalence and severity of CWP differ markedly between different regions and mines despite comparable exposures to respirable dust (REISNER and RoBOCK, 1977; HURLEY et al., 1979). These variations in pathogenicity of coal mine dusts can only partially be explained by differences in the mineral composition and by rank of coal (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). Cytotoxity studies on mammalian cells do not correspond well with the human disease pattern (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al.,1980; VALL YA THAN et al., 1988). For example, while epidemiological studies of coal miners (REISNER and ROBECK, 1977; HURLEY et al., 1979) indicate that the prevalence of CWP correlates roughly with the rank of coal, such correlation has not yet been established in biological studies, despite considerable effort (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). In order to help resolve this apparent paradox we have undertaken a systematic study to evaluate whether any correlation exists between the concentration of free radicals present in fresh or aged coal dusts from two well-characterized U.S. coals. This study was also prompted in part by observations reported in the literature that organic free radicals can be formed on the surface of freshly fractured coals (LEBEDEV et al., 1978; DULIBA and CLARKSON, 1984). In particular, ARTEMOV and REZNIK (1980) noted that the decay lifetimes and, hence, the reactivity of the organic free radicals formed on crushing Russian coals, .depended"

Jan 1, 1989