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By R. J. Fantel

To determine the availability of phosphate rock from domestic re- sources, the Bureau of Mines evaluated the potential production of phosphate rock from the demonstrated resources of 130 mines and deposits. The evaluation included an estimation of resources, engineering methods, and capital and operating costs, and an economic analysis to determine each operation's average total cost of production over the life of the mine, including a 15-pct discounted-cash-flow rate of return on all investments. Quantified but not evaluated in this report are substantial phosphate resources at the inferred and hypothetical resource levels. The 130 mines and deposits contain 6.4 billion tons of recoverable phosphate rock product, about 20 pct from producing mines. At total production costs of under $30 per ton in January 1981 dollars, about 1.3 billion tons of phosphate rock product is potentially available, over 90 pct from producing mines. This study suggests that production from low- cost, high-grade phosphate mines now in operation will decline during the next decade, and new higher cost, Lower grade mines will have to be developed to satisfy demand into the next century, In addition to the demonstrated resources evaluated in this study, 7 billion tons of inferred-level and 24 billion tans of hypothetical- level phosphate rock are potentially recoverable, which, in part, includes material containing high amounts of magnesium, Much of this material could likely become available in the near future.

Jan 1, 1983

By Robert L. Mentch

CADMIUM is one of the metals apparently destined to remain relatively scarce. The en tire supply of primary cadmium is recovered as a byproduct, concurrently with the treatment of ores of other metals. Development of the cadmium industry is attributed to metallurgical improvements in the zinc industry; output depends almost wholly upon zinc production. Cadmium is a metal of specialized uses where its superior performance has developed a strong, expanding demand. The supply, however, has been relatively unresponsive to price because of its byproduct nature. Cadmium's outstanding properties would assure it a manyfold greater market if more were available at lower prices.

Jan 1, 1958

By H. E. Powell

A series of alkyl-dithiocarbamic acid amine salts was prepared and tested as collector for slimed lead minerals contained in the waste material from a commercial lead ore concentrator. The reagents, members of a homologous series differing only in the number of alkyl radicals in their structure, were prepared by reacting stoichiometric amounts of primary amines and carbon disulfide in a cold alcohol solution. Subsequent purification was by recrystallization from absolute ethyl alcohol solution. Evaluation was through froth flotation of a mill tailing containing 0.2 percent lead. Results show that maximum recovery (38 percent) was obtained with the reagent containing 8 alkyl radicals, but that maximum rougher concentrate grade (4.8 percent) was obtained with the reagents of intermediate number of radicals.

Jan 1, 1962

By Leonard Obert

The various underground rooms in the Bureau of Mines Oil-Shale mine, Rifle, Colo., have been open for periods ranging from 3 to 5 years. During this time 3 roof falls have occurred; 1 was induced, and the other 2 were unintentional. The three roof falls are described in this report. Two causative factors are discussed -a time-dependent deterioration of the roof rock and an unfavorable system of jointing that occurred in the strata overlying the present roof horizon. Irrespective of cause, the operating life of any stoping area would have been short com-pared with the life of the roof (1 to 4 in the most unfavorable instance), if a high-production system of mining had been employed. The report is concluded with several recommendations that should be considered in planning future mining operations.

Jan 1, 1958

By McHenry Mosier

A skull breaker has demonstrated its advantages for secondary breaking in a limestone quarry by entirely displacing secondary blasting . It has reduced safety hazards to workmen, increased the number of quarry operating days , and has lowered mining costs by 2.7 cents a ton. It is believed that the application of the skull breaker can be made economically advantageous in the surface mining of other commoditics .

Aug 1, 1948

By G. S. Rice, R. V. Wheeler

"FOREWORDThe cooperative mine safety research program was carried on successfully in the year 1930 in a manner similar to that described in the report for 1929It is believed that the results of such fundamental work as is being done are unquestionably of great benefit in their application in coal-mining operations, in the saving of life and health of minera. The research result compared and checked by investigations in the two organizations, and further by large-scale tests, as in the Experimental Mine, give confidence to mine operators, miners and State mining officials in the findings of the various researches.The annual report of the contact officers of the United. States Bureau of Mines and the British Safety in Mines Research Board to the Director of the Bureau and the Chairman of the Board respectively, follows:Annual Reports for 1930 To: The Director, Bureau of Mines.The Chairman, Safety in Mines Research Board."

Sep 1, 1931

This U.S. Bureau of Mines (USBM) report conveys the results of an economic analysis of minerals in the West Mojave Management Area (WMMA), including the Desert Tortoise Priority Habitat (DTPH), a proposed special land management area. Undiscovered mineral resources were estimated for the entire WMMA, which totals 8.7 million acres. Known mineral resources were studied for the DTPH, which is an area of 1.2 million acres contained within the WMMA. Federal lands within the WMMA are managed by the Bureau of Land Management (BLM). The WMMA includes Federal, State, and private lands in the western portion of San Bernardino County and the eastern portion of Kern County. The center of the study area is 20 miles northwest of Barstow, California (Figures 1 and 2).

Jan 1, 1993

By W. W. Adams

"The third annual safety contest for plants producing sand and gravel, which was conducted in 1911 by the United States Bureau of Mines in cooperation with the National Sand and Gravel Association, registered further progress in safety as compared with the two previous annual contests. Both the accident-frequency rate and the accident-severity rate were reduced.The period covered was the calendar year 1931; sixty plants participated, and 17 States were represented by the participating companies.The contest covered accidents and man-hours worked by all men at the participating plant who were employed by the same company; and it included work up to the point of delivery of the material directly to the consumer or to an independent agency of transportation--in other words, to the point of relinquishment of control of the material by the producer.The purpose of the yearly contests for producers of sand and gravel is to aid in the promotion of safety among the employees and in the reduction of accident costs to the companies. The contests develop friendly rivalry among the various plants and among the employees of individual plant in a concerted effort to prevent accidents.Two safety trophies are awarded annually, both of which are provided by Rock Products magazine. One of the trophies is for the host safety record among plants that were in operation the contest year 100,000 or more man-hours; the other trophy is for the best among plants that were in operation lees than 100,000 man-hours. Awards and the relative standing of the various plants are based upon statistical compilation by the Bureau of Mines of accident reports and employment reports furnished by the enrolled companies. are summarized at the close of each year, and the summaries are submitted to each company concerned for certification as to the accuracy of the summary and the completeness of the company's reports from which the summary was prepared. When the summery is returned signed by an official of the company, the records are considered to be a trustworthy basis for determining the relative standing of the various plants. The position of each plant is determined by its accident-severity rate; that is, the number of days of disability resulting from accidents for each 1,000 men-hours of work done by all employees at the plant."

Aug 1, 1932

By R. D. Leitch, W. P. Yant

"In the course of another investigation4 during 1926 and 1927, samples of water collected from a few abandoned coal mines indicated that their drainage was usually lower in acidity than water from active mines in the same locality. In order to determine whether this condition might have a bearing on the advisability of sealing abandoned mines, a number of such mines were visited, samples of drainage were collected, and as much information- as possible was obtained from officials of the mining companies and older residents of the district. The results of this work are the basis of the present report.The authors are indebted to E. W. Robertson, F. F. Spowart, J. H. Nagle, and W. D. Adams of the Northwest Mining & Exchange Co.; E. M. Fasset, Fred Lane, Wm. Humphreys, and Dr. T. A. Hutchison of Brockway, Pa.; C. W. .Faulk of the Shawmut Mining Co.; James Hau of Kersey, Pa., and to others for information received; and to Dr. R. R. Sayers of the Bureau of Mines, under whose direction the work was conducted.The Lower Kittanning is the most important bed in the locality studied. A great many of the abandoned mines examined are in this bed, and nearly all of the present active ones are. The Upper Freeport bed is also mined to some extent, and a number of the abandoned mines formerly worked this bed. As only three active mines are now (1927) working the Upper Freeport, the comparison of acidities is necessarily limited. Of these three, one had been idle since 1922 until shortly before it was sampled.The location of most of the mines was already known from previous work, but some of them had to be located by following up streams known to contain acid waters. A sample of the- outflow was collected in self-sealing bottles known as ""citrate bottles"" for the determination of dissolved oxygen by the Winkler method.5 Another sample was taken for the determination of acidity according to standard methods of water analysis.6 Ferrous iron was determined at the mine or very soon after taking the sample by titrating with a standard solution of potassium permanganate in acid solution. The hydrogen-ion value was determined by a standard double-wedge comparator.7From the total acidity values in each sample, which are the most important values, the total iron was calculated on the assumption that acidity as sulphuric acid was due to dissolved ferrous sulphate. This assumption is commonly made for mine waters, but is inaccurate to the extent that free acid is already present, and some of the iron is present as ferric, rather than ferrous, sulphate. The amount of ferrous sulphate may be a rough measure of the extent to which oxygen is lacking within the mine. The permanganate titrations just mentioned showed what part of this total iron was in combination as ferrous sulphate, and the difference .was assumed to be that in combination as ferric sulphate, after correcting for the amount of free acid already formed as shown by the titration values."

Oct 1, 1928

By James D. Noll, Jon A. Hummer, Aleksandar D. Bugarski, George H. Jr. Schnakenberg, Steven E. Mischler, Larry D. Patts

The National Institute for Occupational Safety and Health conducted a study to determine the effects of selected, state-of-the-art emission control technologies on the ambient concentrations of particulate matter and gases emitted by underground diesel-powered mining equipment. Tests were conducted in an isolated zone of an underground mine to evaluate the effectiveness of alternative fuel formulations, namely, water-fuel emulsions, blended biodiesel fuels, ultralow sulfur diesel fuel, and #1 diesel; and selected exhaust after treatment devices, namely, diesel oxidation catalysts (DOCs), diesel particulate filter (DPF) systems, and filtration systems designed around high-temperature disposable filter elements. The results showed that using a cold-weather and warm-weather water-fuel emulsion formulation reduced mass concentrations of elemental carbon (EC) by about 70% and 85%, respectively. The 20% and 50% soy biodiesel blends reduced EC by 49% and 66%, respectively. The reductions were slightly less pronounced for the 20% and 50% yellow grease biodiesel blends—33% and 56%, respectively. EC concentrations were unaffected by using ultralow sulfur diesel in place of #1 diesel. Use of the reformulated fuels did not substantially alter the concentrations of nitric oxide and carbon monoxide. However, a measurable increase in the nitrogen dioxide (NO2) peak concentration was observed during the biodiesel tests. The ArvinMeritor (AM) fuel-burner DPF system with a palladium-catalyzed DOC reduced EC concentrations by 92%. The diesel filter elements from Donaldson Co., Inc., and Filter Service & Testing Corp. reduced the EC concentration of the mine air by 92% and 70%, respectively. When the palladium-based DOC was used with the AM DPF, it raised the average and peak downstream NO2 concentrations by a factor of three. Tests of the AM DPF system with a platinum-catalyzed DOC and CAP/ETG catalytic particulate oxidizer system had to be terminated because the elevated NO2 concentrations threatened to overexpose the operator. The tests with only a selected DOC also resulted in increased NO2 concentrations in mine air.

Jan 8, 2006

By Ludwig Schmidt

Investigations conducted by the Bureau of Dines pertaining to the reduction of evaporation losses of petroleum have shown that such losses may be reduced 70 to 80 per cent by the use of vapor-tight tanks equipped with vacuum and pressure relief valves, and vapor-tight thief hitches. Additional studies have shown that it is often economical to supplement this type of construction with other measures that will reduce evaporation losses still further. Water-cooling systems, insulation, and light colored paints are the measures most often used in connection with vapor-tight tanks. Painting with light colored paints probably is employed in the greater number of cases. On account of the cost of insulation, or of installing water cooling systems, the use of these methods are restricted to tanks containing gasoline or crude petroleum with a very large content of low-boiling fractions. The effect of cooling systems has been discussed in a previous report.2 In choosing paints for tanks many factors must be considered. Probably the three most important are cost, protective value, and color. Many companies have adopted a standard color for all of their tanks in this way they reduce the initial cost of paint by buying in large quantities. The tank farms of such companies usually have a neat appearance, resulting from the uniform painting of all tanks. This procedure also has advertising value. Unfortunately, most of the paints used to protect steel are of the darker colors, usually red or black. These colors accelerate the rate of evaporation. Several companies have solved this difficulty by using a dark colored metal-protective paint as a primer coat, and a paint of any desired color for the final coat. Special metal-protective primers to be used under light-colored cover coats have been placed on the market by several paint manufacturing companies.

Jan 1, 1925

By M. H. Rinkenbach, C. A. Taylor

The detonating compound cyanuric triazide was discovered*** and patented**** by Erwin Ott, and on account of his claims, the Bureau of Ordnance, U. S. Navy, desired more complete data, so an investigation was made. The results obtained were such that the Bureau of Crdnance recommended publication thereof for the benefit of the explosives industry. Some of the patent claims regarding cyanuric triazide are as follows: 1. It is not poisonous in contradistinction to fulminating mercury and lead azide. 2. In contradistinction to the hitherto employed priming agents it is fusible, and its fusion point (94°C) is so low that the product melted by a single heating in water or steam bath, can be poured without danger in the capsule shell. It solidifies therein after cooling, and shows the density of 1.5. 3. It has been determined that the cyanuric triazide, in spite of its very much higher priming actions, is much less brisent then ful- minating mercury and lead nitride. 4. The chemically pure cyanuric triazide (C3M2) constitutes colorless crystals melting at 94°0., and is not volatile. It is not affected by cold water, and only slowly saponified by hot water. It is relatively insensitive to friction and not too strong concussion, but explodes by impact or when hea ted to 170°C., or when heated suddenly. It is not more sensitive to friction and shocks then fulminating mercury. 5. The preparation of the triazide is preferably carried out by acting with an excess of sodium azide in an aqueous solution; in the cold, on cyamric chloride gradually suspended in the said solution.

Aug 1, 1923

By G. E. Walden

The Bureau of Mines is currently engaged in a continuing investigation of the thermodynamic properties of certain inorganic compounds. As a part of this investigation, the heat contents of bismuth and cerous chlorides were measured throughout the temperature ranges of 370° to 630° K. and 370° to 1,200° K., respectively. Equations representing heat contents as a function of temperature were derived from the data by the method of least squares. These equations were used to calculate heat contents at selected temperature intervals ranging from the ice point to 650° K. for bismuth chloride and to 1,200° K. for cerous chloride; also, the heats of fusion of both compounds were calculated at their respective melting points. EXPERIMENTAL Materials The cerous chloride used in this investigation was supplied by the National Carbon Company of Cleveland, Ohio. A chemical analysis indicated Ce 56.57 percent and Cl 43.39 percent. No attempt was made to purify the compound or identify impurities since the analysis showed only about 0.04 percent total impurities. Reagent grade bismuth chloride was used without additional purification.

Jan 1, 1961

1. In 2002, a total of 4,311 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA). The major industrial classifications in stone mining are dimension stone (used for construction purposes), crushed and broken stone (aggregates), cement, and lime. Stone mines comprised 29.7% of all mining operations. • Mines producing crushed and broken stone (n = 3,372) comprised 78.2% of all stone mining operations.

Jan 1, 2004

By L. E. Dalverny

This Bureau of Mines report describes the deployment, 5-month operation, and lessons gained from a continuous gas monitoring system using sampling-tube bundles at an underground mine fire in West Virginia. Research information gained indicates the utility of relating certain gas concentration ratios to events during fire development, mine reventilation, and mine recovery. In addition to monitoring the quality of remote fly ash seals, the system provided timely warning of dangerous gas concentrations which developed during surface and underground recovery activities. An evaluation of system components is supplemented by recommendations for improvements.

Jan 1, 1975

By Allen D. Look, Stanley M. Walker, Van Fleet. Leonard A.

"INTRODUCTION The hazards to be encountered in temporarily or permanently abandoned underground mines, quarries, and open pits are numerous, and hardly a year goes by without several reported cases of fatal or serious injuries occurring to unwary people who enter these old mines. Persons visiting mining areas for the first time, tourists, and young people, especially, proceeding in the spirit of adventure common to youth or to the venturesome have suffered many such accidents during exploration trips. The possibility of salvaging salable or usable equipment prompts men and boys to go into old mines, some through ignorance of the attendant hazards, but some jeopardize their lives hopeful of gain (in some cases pitifully small), thinking the hazards are not dangerous and that they can ""get away with it.""Persons fall into unprotected holes, some seek shelter from storms under high banks, and quarries and open pits are often chosen as places for recreation, picnics, swimming, etc; all such uses of these places are likely to be hazardous and to lead to accidents, frequently fatal.These hazards are known to men in the mining profession, and the danger to the public is realized by most of them. A solution to the problem has been sought at many mining meetings, and it is recognized that complete prevention of entry into old mine workings and surface mining areas is the ideal solution, but this, unfortunately, is not always practical; better education of the public, particularly children, should help to reduce the number of such accidents and will be effective in direct proportion to the extent and vividness of such education."

Aug 1, 1948

By K. K. Kelley, L. B. Pankratz, W. W. Weller

Mullite is a substance of prime importance in ceramic technology . Despite this fact , its thermodynamic properties have received little attention . A Bureau of Mines literature survey disclosed the absence of lowtemperature heat capacity data , the absence of an experimental entropy value for 298.15 ° K , and the lack of heat content data beyond the temperature range from 298° to 576 ° K. Data supplied in this Bureau report fill these gaps in the thermodynamic knowledge of mullite . According to equilibrium phase studies of Aramaki and Roy ,3 the mullite phase melts congruently at 2,123 ± 15 ° K , and the equilibrium crystallinephase composition extends from Al Si2013 to Al6.8 Si₂ Q4.2 . The results in this report are for the stoichiometric composition , Al Si¿Qз . • Heat capacity measurements were made over the temperature range from 50 ° to 298 ° K , and the entropy at 298.15 ° K was evaluated . Heat content measurements covered the temperature range from 298 ° to 1,800 ° K. Heat content

Jan 1, 1963

By Walter D. Holland

LFE Environmental performed an Industrial Hygiene survey of the Paraho Oil Shale Mining and Processing facility in Anvil Points near Rifle, Colorado, on August 6 and 7, 1975. This survey consisted of an investigation of the underground operations for diesel emission contaminants and of the above ground work areas for all inhalation contaminants other than silica dust. Samples were collected to investigate the following contaminants: respirable dust, total dust, NO2, NO, H2SO4, formaldehyde, CO2, S02 and CO. None of the determinations of contaminants in the underground operations indicate air concentrations exceeding their standards. The results for the samples collected above ground indicate only one operation where the employee's exposure exceeds the standards. It is a welding operation where the standards for total dust and lead are exceeded. Since the survey the employer has installed an exhaust ventilation system which has significantly reduced the welder's exposure.

Jan 1, 1976

By C. W. Smith

The Bureau of Mines conducted laboratory-scale beneficiation tests on a sample of corundum gneiss from Montana to devise a method for beneficiating corundum for use as a substitute for refractory-grade bauxite. A flotation process utilizing petroleum sulfonate as the collector in an acid circuit was devised. Results showed that two flotation schemes each produced a concentrate exceeding the national stockpile specifications for calcined bauxite. From a feed containing 28 pct corundum concentrates containing up to 92.5 pct alumina (A1203) were produced with a corundum recovery of 78.5 pct.

Jan 1, 1987

By Cecil E. Lester

Since the advent of coal mining, the minimal lighting in the under¬ground working place has been an obstacle to the safe and efficient performance of the miner's many tasks. Compounding this problem is the fact that the machines being operated in the working place are so large that the vertical and horizontal clearances around the machinery are severely limited. Consequently, in these poorly lighted and congested working places, the machine operator is unable to utilize his peripheral vision. He cannot see hazards as they develop and, too often, cannot react in time to avoid serious injury or death to himself or his fellow miners. The greatest hazard to miners inby the last open crosscut is from falls of roof which are often preceded by warning signs such as falling rock fragments, roof supports taking weight, or a sudden reduction in the height of the working place. These warning signs often go undectected because the machine operator's attention is focused on the small circle of light emitted from his cap lamp. Congress recognized the illumination deficiencies, and, in the Federal Coal Mine Health and Safety Act of 1969, charged the Secretary of the Interior with the authority and responsibility for development and promulgation of minimum standards for illuminating working places in coal mines. These standards have been developed and, as stated in the April 1, 1976 Notice, Federal Register, Volume 41, No. 64, will be promulgated on October 1, 1976, as mandatory regulations under Section 75.1719, Title 30, Code of Federal Regulations. The regulations require that the designated surfaces within the miner's normal field of vision be illuminated to 0.06 foot-lamberts while self¬propelled mining equipment is being operated in the working places. The term "working place" is defined in the Act as "the area of a coal mine inby the last open crosscut".

Jan 1, 1976