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By R. L. F. Kay, T. A. Fletcher, A. J. Boyce, C. M. Rice

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The synorogenic, mafic Ordovician intrusion comprises orthopyroxene-rich xenoliths and mafic-ultramafic cumulates with low-grade pyrrhotite, chalcopyrite and pentlandite mineralisation. Despite abundant textural, mineralogical and O isotope evidence for significant assimilation of country rocks, S isotopes indicate only a modest uptake and suggest that mineralisation is dominated by magmatic sulphur. The preferred explanantion is that the magma was close to S saturation on emplacement. Uptake of elements such as Si and O led to early crystallisation of orthopyroxene, resorption of olivine and early segregation of a sulphide liquid. Post-magmatic interaction with a high-temperature, surface-derived fluid, whose movement may have been controlled by regional shear zones, reset biotite and whole-rock O isotope values but not those of orthopyroxene. This model identifies the presence of olivine-rich rocks and evidence of extensive assimilation as guides to prospectivity

Jun 19, 1905

By P. J. Rowsell, M. D. Waller

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. The applications of artificial intelligence systems in the upstream petroleum industry are reviewed. Particular emphasis is placed on current and potential applications in drilling engineering. Several recent advances in drilling technology have led to a large increase in the quality and volume of data available. This combined with the escalating cost, particularly of off-shore operations, is testing the traditional reliance on the skill and judgement of rig operators. AI systems offer enormous scope in enhancing and aiding the performance of these operations

Apr 1, 1994

By N. Krauland, A. Nystrom, M. Board, S. Sandstrom

Several deep Swedish cut-and-fill mines experience severe ground control problems, including roof collapse and wall sloughing, as a result of variable rock quality and high in situ stresses. A project to examine the problem included two main areas. The first was prediction of mining conditions at depth and the adaptation of cut-and-fill mining to such conditions; the second was the assessment and improvement of support methods at present and future depths. Simple, elastic, mine-scale numerical models were used to optimise stope sequencing and more detailed, stope-scale models to simulate the failure processes around a stope and the interaction of rock mass and support. Kristineberg was chosen for testing and calibration of the predictive methods because of its long history of severe ground conditions and the large base of observational and monitoring data available for comparison. Horizontal cut and fill was found technically suitable to depths beyond 1 000 m and economically viable if ore value covers support costs. Stability can be achieved with the present support technology down to 1 000 m but the 7-strand 15.2 mm cables have poor deformation properties (5% failure strain) compared with rebar rock bolts (17%). Reducing the intervals between levels from 100 m to 50 m will cut support costs and improve production reliability and capacity. Simulation of sill-pillar mining indicated that conditions would be most severe when pillar height was reduced to 15-20 m; mining of a sill pillar has been carried out successfully to the last 3 m, whose extraction is planned for the near future

Dec 1, 1995

By Xiao Min You, D. R. Swonbourne

Smelting of Cu anode slimes involves the use of a slag to hold the oxidised Cu, but some Ag is also inevitably oxidised to the slag. The solubility of Ag in sodium silicate slags at 1 100 and 1 150 degrees C has now been determined over a very wide range of oxygen partial pressures. Silver was found to be present in the slags both as neutral atoms and as AgO(0.5). The activity coefficient for atomic Ag was a very strong function of slag composition and temperature, whereas that for AgO(0.5) was much less affected by slag composition and was almost independent of temperature over the limited range examined. The results reveal that the dissolved Ag cannot be fully recovered by reduction of the slag with very reducing gases

Jun 21, 1905

By E. O. Afreh, R. J. Bowell, E. Hanssen, D. Pohl, S. Abe, R. K. Yao, N. d'A. Laffoley

In the largely preserved laterite profiles at Syama mine, in the savanna region of southern Mali, element geochemistry in the mottled-clay horizon and below can be related directly back to the protolith, but above this, in the ferricrete and cuirasse horizons, the hypogene signature is much modified by pedogenic processes. In tropical rainforest terrains extensive remobilisation can result in wide but weak geochemical targets for gold and pathfinder elements. At the Hire concession in central Ivory Coast, intense recent alteration of the largely intact laterite sequences has modified soil-geochemical dispersion patterns extensively, producing Fe-rich nodular stone lines and obliterating previous patterns and features. Where the upper horizons of the laterite profile have been removed or reworked, as at the Senoufo concession in northern Ivory Coast (savanna) or the Kubi prospect in Ghana (rainforest), all soil horizons can be related directly to hypogene geochemistry. In these truncated profiles, gold and base metal anomalies are essentially those of the lower weathering profile and form narrow but strong dispersion haloes. A good understanding of the geochemical processes active in deeply weathered profiles is required if targets are to be recognised effectively

Apr 1, 1996

By J. A. Every-Brown

Case studies are presented of three derelict sites in Kent and Essex that provide a good cross-section of opportunities for second-generation commercial uses of former chalk, limestone, clay and gravel workings. A 240 ha abandoned chalk quarry at Grays in Essex, now known as Chafford Hundred, is undergoing mixed development to include leisure facilities, a range of housing and commercial areas and an enhanced environment. The 120 ha of Stone Marshes now comprises the Crossways business park and the Dartford international ferry terminal. Reclamation and servicing required more work than had been anticipated and the fact that the area was within the green belt added to the delays, but Blue Circle was eventually able to provide a comprehensive development of the entire area to a high environmental standard. Stone Pit 1 landfill, at Dartford in Kent, is a former chalk quarry 40 ha in area and with an original average depth of 35 m. Landfilling commenced in 1976 and during the period 1979-1984 the site operator designed, developed and installed a gas collection and flaring system. From 1986 a gas plant supplied up to 5 000 000 therm/yr of landfill gas to a local cement works and in 1989 a 1 MW power generation scheme, later expanded to 3 MW, was commissioned. Gas is currently also supplied to a metal refining company for use in internal combustion engines

Aug 1, 1994

By P. H. Morris

The profile of a delta formed by fine-grained mineral processing wastes, disposed of as aqueous slurries by subaerial deposition from a pipeline, has a significant bearing on the volume that is available for waste and water storage in a given containment structure. Earlier field data and laboratory experiments suggested that mine waste delta profiles could be predicted with high levels of accuracy using data from small-scale laboratory deposition tests. The relationships between the profiles of full-size and laboratory-model deltas were analysed using the principles of kinematic similarity and a recent theory of delta formation based on engineering hydraulics. Measured profiles of full-size and model coal-mine tailings deltas are compared and the prediction of full-size profiles discussed. It is shown that the data-derived laboratory-model deltas are insufficient to allow accurate prediction of full-size delta profiles. Initial slope data or other, equivalent data for the full-size delta are also required

Apr 1, 1996

By A. Ersoy, M. D. Waller

The principal factors which require consideration in predicting drilling rates are the bit-type, the bit operating parameters and the characteristics of the penetrated rock. A single index is not a sufficient basis for predicting performance. A variety of rock types were drilled in the laboratory with polycrystalline diamond compact (PDC) and impregnated diamond core bits using a fully instrumented drilling rig at different rotational speeds and with a range of weights on the bit. Quantitative determinations of a wide range of textural, mechanical and intact rock properties were also made. Multi-variable linear regression analysis was then used to develop predictive models of rates of penetration from the operating and rock property data. The models have been verified by statistical tests. The analysis indicated that the models for the pin and hybrid PDC bits have potential for practical application. However, although the model for the impregnated diamond bit appears to be reasonable from a purely statistical point of view, it may not be satisfactory for drilling uses as it is based on two measures of rock hardness alone. The application of multiple regression analysis to PDC drilling performance is novel and the technique shows promise for the prediction of rock drillability with PDC bits. The ability of the technique to provide a mathematical characterisation of the performance of new drill bits in specific rocks may prove to be of value to drill manufacturers and users

Aug 1, 1995

By G. S. Camm

Gwynfynydd is a small, high-grade black shale-hosted vein-gold deposit. The Chidlaw Link Zone is the only area being mined and contains 24 000 t ore grading 15.2 g/t gold. Within the Link Zone a complex vein structure occurs consisting of a mother vein up to 5 m thick and narrow (less than 0.5 m) leader veins. The former shows minor variations in dip, strike and thickness, whereas the latter show marked changes in all three. The leader veins are hosted within the footwall zone of the mother vein and both are composed of quartz with galena, sphalerite, chalcopyrite, pyrite and minor arsenopyrite. The vein system is transected by a series of cross-vein and intra-vein dip-slip faults. Pockets of gold occur at vein intersections or branches and within the complex footwall zone and are often related to variations in vein attitude and/or geometry. The Chidlaw Link Zone displays a complex, erratic distribution of gold mineralisation and a multi-stage history of structural activity, fluid flow and mineral deposition

Jun 18, 1905

By K. Nielsen, J. Kristiansen

A series of laboratory blasting and grinding tests on three types of hard and competent rock (coarse-grained monzonite, fine-grained granite and very fine-grained gabbro) showed that a higher level of applied explosive energy enhanced grindability and produced a larger amount of fine (-0.106 mm) material. This confirmed reported industrial experience and the results of previous investigations. However, the results did not provide any information on the quantitative relationship between the energy applied in primary blasting and that required in subsequent comminution. Only about 1% of energy consumed in conventional grinding is used to create new surfaces, while power efficencies in cone crushers have been estimated at 70-80%. In blasting, up to 20% of explosive energy may be transmitted to the surrounding rock as elastic strain energy, leading to both primary rock breakage and the generation of microcracks

Dec 1, 1995

By G. M. Zhao

The gasification of lump coke with CO2 was studied in a fixed-bed reactor. The effective diffusivity of the gas was evaluated from measurements of the reactivity of the lump coke, produced by BHP Steel in New South Wales, and from kinetic parameters that were determined from the reactivity of fine grains. The grain model of effective diffusion in porous media was adopted to express the gasification rate of the lump coke and was found to fit the experimental data well. The relationship between reactivity and textural characteristics of the coke was examined

Jun 18, 1905

By F. J. Tavera, J. A. Finch

A probe suitable for on-line measurements of gas hold-up in industrial flotation systems has been developed. It is based on an open cell for measurement of slurry-gas conductivity and a novel syphon cell for measurement of slurry-only conductivity. The desired behaviour of the two cells was demonstrated and estimates of gas hold-up were shown to be in good agreement with independent measurements. The gas hold-up probe was used as a diagnostic tool to assess the operation of flotation columns. Differences in gas hold-up between baffled sections in two industrial columns were detected

Jun 18, 1905

By J. A. Hudson, X. D. Pan

A rock mass responds to excavation according to the properties of the intact rock, the network of contained discontinuities and the susceptibility of the rock mass to weathering. Large deformation often occurs when one of these components causes the rock mass to have a low strength relative to the stress conditions. Analysis of such large deformations forms a significant feature of current numerical modelling in rock mechanics. A practical large deformation problem of roadways in a coal mine is described, demonstrating the requirements for improving numerical techniques. The development of a numerical model is then summarised with particular attention to several concepts pertinent to large deformation analysis in geomechanics. A numerical case study is presented in which the developed finite-element model is used and the results are compared with the in-situ measurements. Conclusions are drawn for rock engineering that are also relevant to both civil engineering and mining engineering projects

Sep 1, 1991

By F. C. Gennari, D. M. Pasquevich

With the gradual exhaustion of natural rutile, there has been extensive research into its synthesising from lower-grade titanium minerals. The removal of Fe from pseudobrookite (Fe2TiO5) by chlorination was studied, using both isothermal and non-isothermal thermogravimetric measurements. Correlation of the results obtained from element distribution maps, scanning electron microscopy, energy-dispersive X-ray analysis and phases detected by X-ray diffraction in the chlorinated samples showed clearly two associated processes. First, the pseudobrookite particles reacted with chlorine and iron was removed selectively as FeCl3(g), leaving a solid residue rich in the TiO2 phases anatile and rutile, separated from an inner layer of unreacted pseudobrookite by a distinct interphase boundary. Second, chlorine allowed TiCl4(g) to form in the reaction bed, where it removed iron from the Fe2O3 crystals as FeCl3(g) and substituted Ti through a pseudomorphic reaction

Jun 21, 1905

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By P. H. Williams, D. J. Morris

The co-disposal of coarse and fine coal wastes by combined pumping through a pipeline to subaerial deposition was pioneered in Australia in 1990 by Jeebropilly colliery in Queensland. Significant segregation of fines is found to occur in its co-disposal delta, leading to the formation of distinct mainly coarse upper and fine-dominated lower segments; the upper delta drains rapidly and is able to support traffic on its surface immediately after deposition. An existing theory of subaerial deposition, originally developed for mine tailings alone and later extended to trial co-disposal, is shown to apply also to the upper segment of the full-scale Jeebropilly delta

Jun 19, 1905

By T Grenne, R. B. Larsen

Paper presented at the conference on Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. Paper originally entitled: Processes in a newly discovered sulphide-PGE mineralisation in Norway. The Stormyrplutten mineralisation is hosted by a minor tholeiitic metagabbro of low-Ti composition intruded at a high level in the volcanic lithology. It is thought to be the subvolcanic counterpart of submarine basalts generated during an extensional episode of ensimatic arc evolution. The sulphide-PGE mineralisation occurs as stratabound pyrite, pyrrhotite and chalcopyrite disseminations with average grades of 376 ppb Pd, 313 ppb Pt, 40 ppb Au, 0.5% Cu and 0.08% Ni in a deposit 15-25 m thick. Locally the PGE content peaks at 2 ppm over 1 m. Microprobe analysis isolated 14 different platinum-group minerals, dominated by sperrylite, temagamite and borovskite and occurring as 1-20 micron compounds embedded in the main sulphide minerals or along the sulphide/silicate grain boundaries. Mantle-normalised plots reveal strong depletion in Os, Ir and Ru and enrichment in Pt, Pd, Cu and Au. The general decrease in Pd and Pt and increase in S up through the stratigraphy is similar to PGE distribution in the Darwendale subchamber of the Great Dyke in Zimbabwe, and may reflect strong fractionation of Pd and Pt in favour of the first droplets of sulphide melt; two reversals of the trend at the 4 and 12 metre levels represent replenishment with fresh magma and repetition of the cycle. In contrast to the Darwendale system, Cu and Ni also show peak concentrations in the first-formed liquids and Pt appears to have fractionated more strongly into the sulphide melt than Pd

Aug 1, 1995

By R. Allington, G. Walton

The approach has been applied with success to the restoration of chalk workings in southern England, and research and trials relating to restoration blasting and the replication of limestone dale landforms have been undertaken. An essential prerequisite for application of the technique is rigorous geomorphological analysis of the locality to ensure that final quarry landforms are consistent with the local geomorphological and landscape setting. It is always important to ensure compatibility of the final landform with the intended after-use, and to achieve this it is also essential that such restoration schemes have a sound geotechnical basis. A disadvantage of the approach is that final slopes tend to be flatter, especially in weaker strata where natural slopes are not steep; the implications for reserves may be unacceptable, particularly in quarry extensions

Aug 1, 1994

By P. E. J. Pitfield, S. D. G. Campbell

The regional shear zone runs along or near the southern margin of the Chinhoyi greenstone belt. It hosts four of the seven mines in the southern part of the belt with recorded production above 100 kg Au, including the top two current producers. Displacement occurred in the late Archaean, producing a shear zone with a trend ranging from northeast at Golden Kopje to east at Muriel. The orebodies at the two mines formed synchronously with the shearing and show strong but contrasting structural controls on mineralisation. The Golden Kopje orebodies plunge to the southwest, parallel to the intersection of curved foliation with discrete shear planes and sub-perpendicular to local stretching lineations. The Muriel orebodies plunge steeply west but parallel to local stretching lineations. The greatest fluid flow during mineralisation of the shear zone was along either the intersection of fabrics (Golden Kopje) or the extension direction (Muriel). There is no unique relation between the orebodies and the extension or shear direction. Where earlier mining has not established the directions of the oreshoots it is essential to understand the possible structurally controlled geometries of orebodies before planning a drilling programme to evaluate their potential

Apr 1, 1996

By S. P. Ball, A. J. Monhemius

In a laboratory study under acidic oxidising conditions, the thiocyanate system gave results at least as good as cyanide and considerably better than thiourea, with modest consumption of SCN (less than 1 kg/t ore). For both cyanide and thiocyanate lixiviants a residence time of about 24 h was required for maximum gold extraction, which was generally in the range of 92-96%. The adsorption of gold from thiocyanate leach liquors was found to be rapid, but activated carbon catalyses the autoreduction of ferric iron to ferrous iron in thiocyanate solutions, suggesting that ion exchange may be a better recovery route

Dec 1, 1995