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By S. Koski, J. Vanderbeek, J. Enriquez

"The Cerro Verde copper-molybdenum porphyry mine, majority owned and operated by Freeport- McMoRan Copper & Gold, is located 30 km southwest of Arequipa Peru. The concentrator, which produces copper and molybdenum concentrates, started operating in late 2006 with a 108,000 tpd design capacity, processing primary sulfide ore (mainly chalcopyrite and molybdenite). Plant capacity was recently increased to 120,000 tpd. The comminution circuit consists of one 60” x 113"" primary crusher, four MP-1000 secondary crushers in closed circuit with dry screens, four 2.4m x 1.6m High Pressure Grinding Rolls (HPGRs) in closed circuit with wet screens, and four 7.3m x 11m gearless ball mills in closed circuit with cyclones. The HPGR circuit is fed by the Secondary Crushing circuit product at a T80 of 35 millimeters, and the HPGR circuit product feeds the Ball Mill circuit at a T80 of 3000 microns.This paper describes operating experiences with HPGRs during these first four years highlighting improvements in operating practices and presentation of data regarding operational efficiencies, also discussed are the primary benefits provided by HPGRs such as production of micro fractured particles, reduced ore Bond Work Index, and reduced power consumption. Cerro Verde represents the first installation of HPGRs in both the copper industry and large scale hard rock mining."

Jan 1, 2012

By C. Sui, J. E. Nesset, M. Li, J. Y. Kim, S. L. Chryssoulis

"A plant study of zinc rougher flotation at Brunswick Mining was conducted using lime, soda ash and a combination of both as the pH modifiers in order to establish the effects on sphalerite and pyrite kinetics and mineral selectivity. The plant sampling and analysis was augmented by surface analysis using TOF-LIMS, SEM and XPS as well as fundamental precipitation and surface-charge studies in the sphalerite Ca/C03/S04 system.The results revealed the important role of carbonate ions in cleaning the sphalerite surface for effective activation by CuS04 to occur, and the beneficial role of combined soda ash and lime in increasing pyrite and galena depression.1.0 IntroductionThe studies reported in this paper were initiated as part of an investigation into the causes of a particularly pronounced seasonal deterioration in metallurgical performance at the Brunswick Mining concentrator during the summer of 1995. The concentrator treats a complex base metal ore having a typical feed composition of 9.0% Zn, 3.5% Pb, 0.4% Cu and 100g/t Ag at a current throughput of 9,000 TPD, although at the time of the problem in 1995, the average production rate was closer to 10,500 TPD. Zinc, lead, copper and bulk (zinc-lead) concentrates are produced with overall metal recoveries of 86% zinc, 63% lead, 60% copper and 60% silver; results which are typical of the lower recoveries associated with fine-grained, highly complex VMS and SEDEX type deposits. The main economic minerals of interest are an iron-containing (7% Fe) sphalerite, galena and chalcopyrite with the main diluent (about 60% wt) being pyrite.Figure 1 shows a simplified flowsheet of the Brunswick milling circuit while the seasonal decrease in summer metallurgy in 1995 is illustrated in Figure 2. Of significance is the rapid drop in copper and lead recovery in June while there is an apparent delay until late August-September before the zinc deterioration reaches its lowest point. A more typical seasonal effect within the experience of the authors is the reverse of the Brunswick situation, namely an improvement in summer performance thought to be associated with improved differential flotation kinetics during warmer weather leading to better mineral selectivity. The historical Brunswick experience was particularly severe during the summer of 1995 with estimated incremental losses of $10 Million for this period. The potential of the very significant economic benefits to be gained from understanding and hopefully improving the annual drop in performance led to an investigation involving the minesite metallurgical group, the Noranda Technology Centre (NTC) as well as researchers in Professor Jim Finch's group at McGill and the surface analytical services and interpretive skills of AMTEL."

Jan 1, 1998

By N. P. Hristov, L. V. Kuzev

"A simulation study of the fill factor of a drum mill was conducted using two types of grinding media: balls and tetraballpebs. Each medium was composed of equal number of grinding bodies having equal weight but different shape. The difference was in the density of the two grinding media.Standard spherical grinding bodies (balls), which were used in practice, and equivalent (by weight) grinding bodies in the shape of spheroidal tetrahedrons (tetraballpebs) were studied. The simulation was conducted in a module of a 1.2 m diameter drum mill, whose length exceeded twice the diameter of the corresponding grinding body. The grinding balls had a few percent (3 to 6) higher fill factor than the grinding tetraballpebs in the same shell.Vertical sections of the grinding medium were taken across the studied shell module along its axis. They showed the location of each grinding body in the fill volume. Defects in the packing of the grinding bodies and the contacts between them and with the inner surface of the shell were also show. Differences in the contact points of the balls and the tetraballpebs were noted. For the tetraballpebs, we observed contacts both between the spherical surfaces and with the edges and vertices of the grinding bodies.The topography of the grinding media is shown visually.INTRODUCTIONThe grinding balls have been studied extensively. It is the traditional grinding medium in ore processing industry. The parameter characterising the grinding medium is its density. It is the mass of the grinding medium per unit of volume. The parameter may have a range of values. It depends on:• The physical properties of the material they are made of;• The shape of the grinding body;• The dimensions of the body;• Size distribution of the grinding bodies in the grinding media.In comminution, the fill factor of the mill shell is the process parameter that is representative of the grinding medium. Some publications have indicated the disadvantages of ball grinding. For example, Wu, Xiang, Glen, and Duan (2008) note in the analysis of the mechanism of grinding that the balls are not the best grinding media and disadvantages include among others:• Easy over-grinding resulting from the point contact between the balls;• Attrition surface is the smallest in the grinding media;• Poor selective exposure of minerals resulting from the accidental and often significantly more powerful impact on the feed;• The grinding efficiency drops as the fineness of grind is increased;In the Handbook of mineral processing, Polkin (1950) noted that the shape of the grinding bodies determines the volume of the void spaces therein and therefore the shape affects the grinding efficiency per unit of volume of the grinding medium."

Jan 1, 2016

By M. Niinae, F. Nakahara, T. Kawamoto, T. Suzuki

"MgO was chosen as an As(V) immobilization agent and a series of immobilization experiments was performed to obtain insights into the behavior of As(V)and MgO during leaching tests. Our experimental and modeling results demonstrated that As(V) immobilization by MgO consists of the following steps: (i) an increase in soil pH, (ii) desorption of As(V) from the soil, and (iii) the re-immobilization of As(V) by MgO/Mg(OH)2particles. Regarding the behavior of MgO, the modeling results showed that when the MgO dosage was 25 mg MgO/4g-drysoilor less, the majority of MgO was used to increase pH, and less than 1% of MgO was used to sorb As(V), which was consistent with the result of leaching tests showing that a high level of As(V) was leached at the MgO dosages. On the other hand, when the MgO dosage was above 25 mg MgO/4g-drysoil, the percentage of MgO used for As(V) sorption increased up to 35%, and correspondingly, the As(V) leaching level decreased to below 0.01 mg/L As at an MgO dosage of 75 mg MgO/4g-drysoil.INTRODUCTIONOne of the major arsenictransport pathways causing groundwater contamination is the migration of arsenicfrom artificially or naturally contaminated surface soils. Therefore, in this study, the immobilization of arsenate (As(V)) in soils was investigated using commercial-grade magnesium oxide (MgO) as a potential cost-effective measurement to prevent the occurrence of groundwater contamination with As(V).With respect to the use of MgO for remediating As(V)-contaminated environmental media, MgO has been used in several studies to remove As(V)from water(Yu et al., 2011; Jia et al., 2013; Tresintsi et al., 2014). Although these studies demonstrated that MgO effectively removes As(V)from water in water-MgO systems, the behavior of As(V)in water-soil-MgO systems has not been evaluated in the literature, and several questions remain to be answered to comprehensively evaluate the use of MgO as an As(V)immobilization agent in soils. For instance, as is well-documented in the literature(Ford, 2002; Lenoble et al., 2002; Zeng et al., 2008), iron oxy-hydroxide (FeOOH) is one of the important adsorbents for As(V)in both natural and engineered systems. Therefore, it is anticipated that the presence of FeOOH in soils significantly influences the behavior of As(V)in water-soil-MgO systems and consequently, the immobilization performance by MgO. Another important question to be answered is the behavior of MgO during the immobilization treatment. In our previous studies (Suzuki et al., 2013a, 2013b), commercial-grade MgO was demonstrated to effectively immobilize lead and fluoride, and the immobilization effectiveness was indicated to last more than 100 years against the exposure to acid rain (pH 4.0). However, these studies focused on the behavior of contaminants. As a result, little is known about the behavior of MgO during the immobilization treatment. The lack of understanding of the behavior of MgO during immobilization treatment is one of the main concerns leading to relatively low public confidence in immobilization treatments."

Jan 1, 2016

By Aleksandar N. Nikoloski, Tendekayi Tapera, Glen P. O’Malley

Chalcopyrite (CuFeS2) and enargite (Cu3AsS4) are among the most important copper sulfides. At present, many known deposits of these minerals are uneconomic to process because they are of too low grade, insufficient size or too remote to be cost effectively treated with conventional technologies that can deal with their refractory nature. Therefore, developing an effective, low cost extraction process for recovery of copper from them is important. The research presented in this paper will deal with potentially cost effective strategies involving catalysed processing, studied under conditions relevant to recycle heap leach conditions. The present account summarises some of the main findings from the research program carried out at Murdoch University between 2014 and 2018 that has investigated the effects of the common leaching parameters, major and minor species present in the leach system and additives on the rate and extent of copper extraction from low-grade ores, in which primary copper sulfide minerals such as chalcopyrite and enargite were the dominant copper minerals. The study involved batch leaching tests, detailed structural and mineralogical characterisation and thermochemical modelling under conditions relevant to heap leaching. The results have demonstrated that silver in particular has a strong catalysing effect on the extraction of copper from ore under the leach recycle conditions and, at an adequate dosage, can effectively overcome surface passivation, enabling almost complete extraction of copper from chalcopyrite as well as enargite. The aim of this paper is to present the effect of the studied additives and to briefly elaborate on the mechanism of the silver catalysed leaching process. In addition, the presence of certain secondary agents was shown to lower the critical dosage of silver and promote extraction. The data from the study allowed the development of a theory for the silver catalysed reaction mechanism, which enables further optimisation and cost-effective application of this strategy in practice. INTRODUCTION Researching the extraction of copper from chalcopyrite is important as it is the most abundant copper mineral in the earth’s crust. The majority of ores containing this mineral are processed by flotation to produce a concentrate, followed by smelting and electrorefining. However, most reserves available nowadays are of low grade or limited in size, and therefore not suitable for this conventional approach. Hydrometallurgical processing via heap leaching with or without the aid of bacteria has been shown to be potentially economical. Chalcopyrite is refractory though and suffers from slow leaching kinetics and poor overall extraction, so understanding the mechanism of how it leaches has received significant attention by researchers working in this field over the past 50 years. The refractoriness, which is the main issue with the hydrometallurgical approach, is generally described as passivation of the chalcopyrite surface whereby a surface coating is formed that blocks the reaction interface or wetting of the chalcopyrite, limiting the copper extraction. Exactly what this layer is made of or how the issue could be overcome has been the subject of intense study and debate for many years. One of the limitations of the work to date is that much of the research focus has been on typical initial leaching conditions, while there has been relatively little research into how the leaching is affected under recycle solution conditions where certain metal ions (Fe, Mg, Al) have often accumulated in the liquor. This occurs because the leach solution exiting a heap contains many species from the dissolution of gangue minerals and typically this solution is returned to irrigate the heap, once the copper has been removed, leading to an accumulation of these species.

Jan 1, 2019

By J. P. Nowlan

"This paper is an attempt to outline the structural problems at the Cochenour Willans mine, in so far as their details have been tentatively worked out. It must be emphasized that there are considerable data that can be interpreted in more than one way, and that further work may modify or completely change some of the hypotheses presented herein. Certain features, however, are sufficiently constant to warrant reliance on them when searching for extensions of orebodies.As the individual ore shoots usually have relatively small dimensions, but are often very high grade, structural details are of more than usual significance in laying out a mining programme. An illustration of this is a small shoot recently located and mined as a result of studying a minor slip cutting off a part of high grade gold ore in No. 319 stope. The shoot, which is bounded on three sides by slips, and on the fourth by the original stoping, was roughly triangular in plan, 20 feet on the base, and 40 feet in length. The average width mined was 4.5 feet, but the gold obtained totalled over 1,800 oz.The property lies in Dome township, east of McKenzie island, and consists of an original group of thirteen claims acquired from the Cochenour Willans syndicate, plus one additional group of five claims obtained by purchase from the Kelson Red Lake Gold Mines, Limited, and one other claim that rounds out the southeast corner of the block.The claims of the original group were staked by W. M. Cochenour, Dan Willans, and Horace Young, during 1926 and 1927. The Cochenour Willans Syndicate was formed in 1928, and until incorporation of the present Company work was carried on at varying intervals by several different interests, including Ventures Limited, Hollinger Consolidated, who sank a shaft to open up the 150-foot level, and by the Syndicate itself. The first ore from the property was shipped to the Gold Eagle mill by the present Company in 1939, and amounted to 4,959 tons, from which 2,360 oz. gold was recovered. The first brick was poured in December, 1939, and production has been continuous since that date. To the end of June, 1946, gold having a value of $5,982,000 has been produced from 345,033 tons of ore treated."

Jan 1, 1954

By J. M. Cormie

"The orebodies of the East Malarcic mine are interesting from a geological standpoint because of the very small amount of vein quartz, the occurrence of much of the ore in soft greenstone schist, the presence of innumerable bodies of porphyry and diorite, and their obvious relationship to structural features .The property lies in the northeast part of Fourniere township in western Quebec, and within the important fault zone that geological mapping in recent years has shown is traceable wesrward through the Noranda and Kirkland Lake camps and eastward to beyond the Val d'Or region . The claims included in the property were staked by J.P. Norrie and L. K. Coffin in 1932, but gold was not discovered until i934. Production began late in 1938. The total amount of ore milled up to the end of 1945 was 2,837,091 tons from which gold having the value of $16,631,758 was recovered.The region is underlain by an alternating series of Early Precambrian sediments and volcanics cut by innumerable intrusives. These are more fully described in the works of Gunning, Ambrose, and Norman. The East Malanie property is underlain by three formations, which, named from north· to south, are : the Cadillac sediments, the Blake River volcanics, and the Kewagama sediments. In addition, there are countless intrusions of porphyry and diorite, particularly in the greenstone, occurring in all sizes up to those measurable in hundreds and even thousands of feet . These constitute a large proportion of the greenstone in places. In many parts of the ore zone there is more porphyry and diorite than schist. The greenstone itself is not homogeneous but includes peridotite, andesitic lava, and soft talcose schist.Orebodies have been found in both the Blake River volcanics and the Kewagama sediments. They are not known to occur in the Cadillac group. The ore occurs in a zone of pyrite mineralization in which almost no other metallic minerals and very little vein quartz are present. Generally, the grade varies directly with the amount of pyrite. The mineralization is later than all the rocks of the area. Diorite was a particularly favourable rock for mineralization and contains the highest grade of ore, but any rock in the fault zone may be ore-bearing, whereas the same type away from the zone is not."

Jan 1, 1954

By Scott D. Long

"Abstract-Grass roots exploration has an emphasis on good precision at low (sub-economic) concentrations of an element, in order to identify "anomalies" which may lead to drilling targets. Although it is wise to have well-defined quality controls in place during early stage sampling, the control procedures at this stage tend to be rudimentary. When a deposit warrants detailed delineation, the need for accurate geological characterization and assaying of ore-grade rock must be supported by appropriate quality control procedures.As a project returns more promising results, and the likelihood of the project warranting a prefeasibility study increases, it is time to tighten quality assurance requirements and quality control protocols. Delays in instituting adequate quality control and verification procedures may lead to costly remedial actions that can also delay completion of the prefeasibility or feasibility study. Sometimes, as a project matures, the quality control and quality assurance aspects fail to keep pace with the changing nature of the work: an increasing emphasis on precise and accurate assaying of oregrade rock.A resource model is like a house of cards. The foundation of the house is the geological observations, the sampling methods and the geological interpretations performed upon those samples. Upon the sampling, which includes all the sub-sampling steps of sample preparation, rest the assay results. The quality of the assays can be no better than the quality of the sampling. Good assaying technique will preserve all biases and imprecisions introduced during sampling and sample preparation; it cannot remove them. If the sub-samples and/or assays are bad and must be redone, all the succeeding levels of the house of cards must also be rebuilt, or at least patched up.From geological observations, a geological interpretation is built, the quality of which is critical to the construction of an acceptable resource model. Geological elements are difficult to assess, and are not discussed here; they are dependent upon the expertise of the geologists involved. Geological knowledge contributes essential quality control elements to resource/reserve determinations (Sinclair and Postolski, 1999; Postolski and Sinclair, 1999).This paper consists of five sections: (1) overview of quality control protocols, (2) maintaining quality control of databases, (3) quality control of drill sampling, (4) optimizing crushing and grinding requirements, and (5) quality control of assay data acquisition."

Jan 1, 1998

By Behzad Vaziri Hassas, Firat Karakas, Esra Tanisali, Mehmet S. Çelik, Ahmad Hassanzadeh

Coagulation is basically an aggregation process where particles settle under the influence of interfacial forces with electrostatic forces playing a governing role. Although particle morphology consisting of shape and roughness dictates the physical encounter of two particles, their eventual coagulation is not only influenced by columbic forces but also other interfacial forces such as hydrophobic interaction, which affects the extent of aggregation of particles through increasing the distance of interaction. Roughness is well known to increase the effective contact angle on hydrophobic surfaces and also enhance interfacial forces. In this study, the effect of morphology of particles and particularly roughness on the settling velocity and in turn coagulation tendency was investigated. Batch settling tests (BSTs) of different particle morphologies were investigated as a function of pH. Two different morphologies of silica particles were utilized with the same particle size distribution (PSD) including smooth-spherical and rough-spherical (Etched). Rough particles were prepared by acid etching technique using hydrofluoric (HF) at different time intervals (15-300 sec). Etched samples were identified and quantified by optic profilometry. Settling test results showed that the settling velocity of particles in a suspension of 2% solids in the massive settling region is significantly affected by particle morphology of the suspension. Coagulation results further revealed that aggregation of rough particles is faster than smooth-spherical particles. Coagulation results are elucidated on the basis of particle morphology and its effect on distance of separation through hydrophobic forces.

Jan 1, 2016

By K. John

"THE most recent estimate of minteable coal reserves in Saskatchewan was made by the Federal Royal Commission on Coal (1944- 6). Saskatchewan was then estimated to have some 24 per cent of the Canadian reserves and two-thirds of this is located in what is called the Souris-Estevan area, which lies in the southeast corner of the Province and border's on the International boundary. It is also estimated that there are some 61/2 million thousand-tons in this area of lignite coal which grades 8,000 B.t.u. or less and has a moisture content ranging from 30 to 33 per cent. Ownership of coal rights in the Province is widely dispersed between the Crown, individuals, and corporations, and a recent survey disclosed that 40 percent of ownership was vested in the Crown and 60 per cent in private individuals and corporations. Coal rights on Crown lands may be leased at an annual rental of $ 1.00 an acre. Under such leases, a royalty of 5 cents a ton is levied on all coal mined. A royalty of 7 cents a ton is levied on coal produced from lands where mineral rights were purchased from the Federal Government prior to the transfer of jurisdiction over natural resources to the Province, in 1931. An annual mineral tax of 50 cents per acre has also been imposed by the Provincial Government on all coals within a defined producing areas."

Jan 1, 1952

By S. C. Tadolini

"Roof bolts are the primary means of roof support in underground mines in the United States. Presently, post installation loads are measured on about 10% of the expansion anchor and combination bolts by using standard torque wrenches that Unit the accuracy of the measurements to about ±30%. No system has been available for measuring the loads generated on full-column resin grouted bolts. Mine roof bolts are long, slender, non-uniformly sized, roughly forged, and placed in a corrosive environment, creating obstacles for researchers trying to utilize ultrasonic reflection techniques to measure strain. A complete measurement system has now been developed by the U.S. Bureau of Mines, Denver Research Center. This system is being used successfully in determining loads measured on expansion anchor and combination bolting systems, examining the transfer mechanics of full-column, resin-grouted bolts, and measuring loads generated on bolts in an underground roadway support system.IntroductionMillions of roof bolts are used each year to provide structural support in underground U.S. metal, non-metal, and coal mines. Approximately 45% of the bolts used are expansion anchor, 45% are resin-assisted combination or full-column resin-grouted, and 10% are friction anchored. The effectiveness of these bolting types is dependent on a number of factors including rock density, bolt length, in situ stresses, rock properties, bolt pattern, installation tension, etc. When implementing expansion anchor and resin assisted combination bolts , installation and post-installation tension, or load, is a major determinant of support quality and subsequent behaviour of the reinforced roof. The method by which these systems carry roof loads is well understood and documented(1,2).The importance of these installation and long-term bolt tension measurements is well recognized and are required in the federal government regulations(3). A statistical sample of the bolts, lout of 4 during installation and lout of 10 inby the last open crosscut, is required to be measured using current torque wrench technology. The disadvantages of this system are the disturbance and weakening of the anchorage and limitations of accuracy to approximately ± 30%. The method by which resin-grouted bolting systems carry roof loads is much less understood, mainly because testing procedures used to evaluate point-anchor systems are not effective on resin-grouted bolts.Due to these problems, the U.S. Bureau of Mines designed a measurement technique that provided a highly accurate, low cost-per- bolt system that led to the development of ultrasonic pulse echo instrumentation. The original system was designed to measure the tension only on expansion anchor bolts. Recent developments and system modifications have permitted measurements on resin-assisted and full-column resin-grouted bolts. The use of these types of support systems has been increasing steadily in underground coal mines.The development of this instrumentation has provided laboratory and field results that help to explain the mechanics and relationships between the applied loads and the interaction between the grouted bolt system consisting of the bolt tendon, grout, and rock."

Jan 1, 1990

By J. A. Rogers

"The Arthur W. White Mine (formerly Dickenson Mine) is a structurally controlled, hydrothermal gold deposit. A gold producer since 1948, it has, to December 31, 1990, processed 6.9 million (m) tons (T) of ore grading 0.45 ounces per ton gold (oz/T Au). As of December 31, 1991, Proven and Probable Ore Reserves were 3.2 m. T. at 0.32 oz/T Au. The mine is located just east ofPlacer Dome Inc. 's Campbell Mine, within the Cochenour-Gull.rock Lake deformation zone. It is situated on the hanging-wall side of a southeast-plunging anticline in a sequence of metamorphosed Archean volcanic, sedimentary and plutonic rocks of the Red Lake greenstone belt. Ore-bearing structures, found mainly within basaltic rocks, are brittle within greenschist-facies rocks to the northwest, but become more ductile toward the southeast, in amphibolite-facies rocks. Within and proximal to these structures, carbonate and arsenopyrite alteration decreases, whereas biotite, actinolite, pyrite and pyrrh otite all increase to the southeast.Ore and shear structures occur symmetrically about the northwest-trending, steeply southwest-dipping, flattening foliation . The three most common ore trends are on average: (A) northwest trending with a 55 degree to 85 degree dip to the southwest; (B) north-trending with a 40 degree to 50 degree dip to the west; and (C) due east-west-trending with a vertical dip. In general, the dominant direction of economic gold concentrations are explained and thus predicted by considering deformation style (brittle or ductile), rock anisotropies such as bedding and lithological contacts, and direction/magnitude of relative block movement. Direction ""A"" can be found adjacent to both right- and left-handed faults. Direction ""B "" occurs with dominantly right-handed systems and direction ""C"" is found with predominantly left-handed movement. Major faults active prior to, during, and after ore formation can have offsets in the order of 2500 feet. Movements along these faults were transpressive while their conjugate breaks were dilatant, thus creating zones for alteration and ore solution emplacement. A series of faults , each with offsets up to 30 feet were established under lower temperature brittle conditions during late- to post-ore formation. In more complex zones, formed during more ductile deformation, these faults controlled the localized geometry and, thereby, the depletion and enrichment of ore shoots, causing a high nugget effect.Although an important aspect of production planning and monitoring, grade control is also very important within a complex ore zone so that the nuggets are not missed. Detailed observation of structure at the hand-sample scale and detailed mapping at the stope scale give valuable clues to interpreting the structures on a mine-wide scale. Determining the relative movement along fault structures is very important so that using an action-reaction- type logic, potential dilatant areas can be predicted and targeted for development and diamond drilling."

Jan 1, 1992

By W. B. Evans, D. P. Taylor

"ANFO has two major disadvantages as an explosive low density and no water resistance. ANFO can be blended with more dense, water-resistant explosives to form ""Heavy ANFO"". The use of emulsion or slurry explosives as a matrix is an attempt to correct deficiencies on the basic ANFO while maintaining cost effectiveness.This paper will deal with four main topics.1. Product description, general properties, strengths and weaknesses.2. Technology of ""Heavy ANFO"" , the emulsion matrix concept and the range of products.3. Relative performance and economics in various rock types.4: Current status in Canada and worldwide, and the expectations for future use.IntroductionANFO has been in use for roughly three decades and remains the explosive of choice where conditions are suitable. ANFO has not become the universal explosive - despite its undoubted superiority in cost effectiveness - because it has serious flaws as an explosive. The most serious of these flaws are the low density and absence of water resistance in ANFO. Low density implies a low concentration of explosive energy in a borehole. The amount of energy available can be increased by. adding an energetic material, generally aluminum, or by drilling more holes. Both solutions add considerably to the over-all costs. The absence of water resistance in ANFO is inherent and can only be overcome by changing the fundamental nature of the product. The history of research in the explosives industry since the advent of ANFO is mainly the story of the various attempts to overcome one or both of ANFO's shortcomings.Many technologies and products have been developed to compete against ANFO, among them slurries, emulsion s and the so-called Dense ANFOs (ANFO with an extra nitroalkane liquid sensitizer). None of them was cost-competitive with ANFO so their market penetration has been limited to wet holes or specialized applications. The exception to this result is Heavy ANFO. The aim here was to have the best of both worlds, the high density and water resistance of emulsions or slurries plus the low cost of ANFO. The concept is very simple. ANFO is about 50 % air, roughly 30% in the prills and 700,10 between the prills . The air in the prills provides the necessary sensitivity but the air between them is waste volume. If one fills this volume with a high density, waterproof product, the resultant mix will be denser and more water resistant than ANFO and with very little added cost. This basic concept was invented by B. Clay in the 1970s and is covered by Canadian Patent No. 1 115 959. The water resistance and/or density of the mix can be tailored by changing the emulsion level. Because Heavy ANFO is relatively inexpensive while providing good in-hole densities and water resistance, it can compete successfully against all other bulk products. It competes against ANFO and Al / ANFO by allowing pattern expansion and reducing over-all costs while it competes against emulsions and slurries on price."

Jan 1, 1987

By P. E. Auger, J. E. Gill

"The zinc deposits to be described are in Lemieux township a few miles south of the Tabletop mountains, in the central part of Gaspe peninsula, Quebec. Although they have not been worked, they constitute a potential source of zinc and lead and structurally are of considerable interest.GENERAL CHARACTER OF THE OCCURRENCEThe deposits are in sharp-walled quartz-carbonate veins and breccia zones carrying locally, and in varying amounts, sphalerite, galena, pyrite, marcasite, chalcopyrite, and specularite. Those so far investigated strike generally north-south, have steep dips, and cut through sediments of Lower Devonian age, mostly calcareous argillites or siltstones. Wall-rock alteration is negligible.BROADER STRUCTURAL FEATURESThe principal known occurrences are in the south-central part of a dome structure measuring 6 by 5 miles. The argillaceous sediments are overlain, on the flanks of the dome, by sandstones and lavas. These have been stripped from the central part of the dome, revealing the veins in the argillites beneath. The veins formed after the volcanics, but the fractures and breccia zones in which the deposits formed are confined mainly to the argillite series, presumably because of the greater strength of the lavas.The argillite series is cut by dykes, sills, and small stocks of diorite and acidic 'porphyries' that are older than the veins.THE FEDERAL HILL AREAThe distribution of known veins is shown in Fig. 1. The characteristic features of the veins are well illustrated by the Federal Hill area shown in Figs. 2, 3, and 4, and described below."

Jan 1, 1954

By Eric Pirard

"A mineralogical and trace element analysis was performed on the Küre historical slags in order to evaluate the possible recovery of copper and cobalt. Reflected light microscopy, electron microprobe and image analysis were combined to determine the Cu and Co distribution in the slag.The results indicate that 81% of the total cobalt is chemically combined in the fayalite whereas only 3.4% is in the mechanically entrapped sulphides. The remainder being in hercynite and wiistite. On the other hand, 95% of the total copper is in the sulphide phase.This kind of applied mineralogical investigation gives invaluable information when it is performed preliminary to metallurgical experiments.IntroductionThe recycling of metallurgical slags is a growing business. The operation is directed toward recovering base metals (Cu, Pb, Zn), and by-products (Floyd and Mackey, 1981).Two reasons are invoked to explain metallic losses in slags: (1) mechanical entrapment of matte globules in the silicate melt; and (2) chemically combined metals in the slag-forming phases. Obviously, a chemical analysis of the slag cannot distinguish between those two modes. Grinding and flotation of the liberated sulphides have often been used to evaluate the importance of mechanical entrapment (Mechev, 1970; Imris , 1982).Recent studies in applied mineralogy of pyrometallurgical products (Bérubé et al., 1987; Pignolet et al., 1986) have demonstrated the benefits of quantitative mineralogical analyses of slags. Optical microscopy together with electron microprobe and image analysis offers a powerful and easy way of quantifying the relative importance of mechanical and chemical losses."

Jan 1, 1991

By F. Ford, J. Dong

"Laboratory and miniplant testwork was carried out to reject uranium from an Iron Oxide Copper Gold (IOCG) deposit that contains an average of 60-70 ppm uranium with high variability. The dominate copper bearing mineral is chalcopyrite with minor bornite and trace covellite. The main gangue minerals are iron-rich chlorite, quartz and magnetite. The main uranium-containing mineral is uraninite (UO2). Downstream processes require the maximum uranium level of no more than 80 ppm in final copper concentrate.Mineralogical examination reveals that uraninite particles are finely disseminated with grain size of less than a few microns in the deposit requiring fine regrind in order to liberate uraninite from chalcopyrite particles. A lab flowsheet was developed to include ultrafine regrind of the rougher concentrate to the particle size of 80% passing 11-13 µm with up to four stages of recleaning in flotation columns. Finer regrind to 80% passing 5-6 µm may continue to improve liberation but does not decrease uranium level in the final concentrate. In each of the successive recleaning stages by flotation column after fine regrind, uraninite is rejected into the column tailings, with the final copper gold concentrate containing less than 70 ppm uranium from a feed containing 83 ppm uranium. The conceptual flowsheet was further tested in an integrated, continuous miniplant showing average 94% copper recovery with average 74 ppm uranium. The uraninite particles that report to the final concentrate are either locked with chalcopyrite or entrained as liberated particles of less than 5 µm in size."

Jan 1, 2016

By Peter Harben

"This paper discusses the benefits of industrial minerals, their sources of supply, price and marketing trends, and their increasing use as substitute materials and ""strategic"" minerals. IntroductionKaolin finds have yet to spark the kind of frenzy associated with the 1849 California gold rush; no dolomite deposit has ever gained the notoriety of the Comstock Lode; and few industrial minerals are counted among the currently fashionable list of "" strategic mineral s"". Nevertheless, the glamorous zhine associated with metals may be somewhat superficial; further digging provides perhaps the real foundation of modern society - industrial minerals.They are often tagged as common, everyday materials that are simply dug out of the ground, crushed and hauled to a local point of consumption. Although this description is accurate in the case of road aggregates, sand and gravel, and the like, there are many exceptions to this rule. The term industrial minerals is rather nebulous, covering as it does the mundane and esoteric, the chemically active and the refractory, the $2 and the $10m-a-ton product. All of these minerals influence every facet of modern life from fertilizers to fire retardants, ceramics to cars, construction to clothes, and toothpaste to tennis courts. Their usefulness is well illustrated by the variety of industries they serve; the main ones are listed in Table 1. It is now time to dismiss the notion of non-metallics as the ""third world"" of natural resources business after the metallic and energy products by dispelling some of the myths regarding abundance, variety and value of the group's sixty-plus products."

Jan 1, 1982

By G. Labonté, J. Truskoski, A. Kerr, A. Bouchard, J. Barrett

"Improving mill grade recovery relationships is always good business. Inco’s Clarabelle mill has just undergone a $16 M process upgrade that was designed to improve nickel recovery by 2%. The “Mill Redesign Project” was completed on time, under budget and delivered the promised improvement in recoveries.This paper describes the methodology of the Mill Redesign Project team, details of the process improvements and the critical success factors that helped the team deliver on its promises.With a payback of under one year, the Mill Redesign Project will play a key role in ensuring a competitive edge as Inco embarks on its second century of operation. IntroductionIt is not uncommon in milling operations to encounter a crisis. That is the point when the process does not behave as expected and fails to respond to the increasingly desperate efforts of the metallurgists and operators. Flowsheet and process changes are attempted and abandoned. With luck, one or more of the changes achieves some mitigation of the original problem or more usually, the original cause of the problem disappears. Regardless, the metallurgist can sit back and bask in the apparent success of his or her endeavours.Less common is when a problem is carefully diagnosed, a team put together to explore all avenues and recommend a path of action that is implemented on time, on budget and immediately delivers on the promises which are sustained over time. This is one such story. It is the story of the Mill Redesign Project at Inco’s Clarabelle mill in Copper Cliff, Ontario."

Jan 1, 2003

By T. Hidayat

The distributions of minor elements between slag/metal and slag/matte in equilibrium with tridymite in the Cu-Fe-O-S-Si-Al-Ca system have been investigated in the range of conditions of interest to the high- temperature copper production, refining, and recycling processes. An improved experimental methodology has been used involving high temperature equilibration in controlled gas atmospheres, rapid quenching, and quantitative microanalysis techniques using Electron Probe X-ray Microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrum (LAICPMS). The effect of oxygen partial pressure on the distributions of minor elements between slag/metal and slag/matte has been accurately measured. The effects of slagging components (Al2O3 and CaO) on the distributions of minor elements between slag/metal have also been experimentally determined. The present study is a part of a larger integrated experimental and thermodynamic modelling research program in the systems relevant to high-temperature copper processing. INTRODUCTION In the high temperature processing of copper, minor elements are distributed between different phases, i.e. liquid slag, liquid matte, and liquid metal. From a processing perspective, it is desired to have the valuable minor elements distribute predominantly in the metal and matte phases rather than in the slag phase, and to have the non-valuable minor elements distribute predominantly in the slag phase rather than in the metal and matte phases. Knowledge of the distributions of minor elements between phases in the smelting, converting, and refining processes is required if the distributions of minor elements between phases in these processes are to be optimized.

Jan 1, 2019

By I. Ueda, S. Ishikawa, T. Nagata

“O-SR process” in which the S-Furnace of the Mitsubishi process is followed by existing reverberatory furnaces (RFs) and Peirce Smith (PS) converters has been operated since December 2007. The S-Furnace smelts copper concentrates to produce molten matte containing 58-62%Cu which is then settled in the RFs and converted to blister copper in the PS converters. The SO2 gas generated from the S-Furnace and PS converters is converted to sulfuric acid in the acid plants. In addition to the smelting copper concentrates, the O-SR process has advantages in terms of recycling various waste/secondary materials. Automotive Shredder Residue (ASR) has been treated in the RF to reduce fossil-fuel consumption in RFs, and to recover various metals included in ASR as well, since 1993. Electronic circuit boards (E-scrap) has also been processed in order to recover not only copper but also rare resources such as gold, silver and PGMs since 2013. Strategic modifications have enabled expansion of the processing volume of E-scrap. Enhancing recycling of wastes and scraps from urban mines while reducing the consumption of natural resources in the “O-SR” process will be demonstrated and discussed in the present paper. INTRODUCTION Onahama smelter and refinery has been operating as a custom smelter since 1965. Smelting facilities were subsequently expanded to two green-charged RF furnaces and five PS converters in 1973. Since RF is a conventional old-fashioned smelting furnace that necessarily consumes a huge amount of fuel to smelt copper concentrates, saving fuel cost has been an important objective. In early 1980’s the fuel was changed from bunker oil to pulverized coal, while utilizing the combustion heat of waste tires. Furthermore, treatment of combustible waste such as shredder residue (SR) was initiated in order to save fossil fuel for smelting concentrates in the RFs. Since enhancing of the treatment of SR requires a reduction in concentrate smelted in the RFs, most concentrates were dried and injected through tuyeres into the PS.converters. These modifications enabled to reduce the amount of the pulverized coal combustion and to increase SR treatment in the RFs. SR treatment capacity has increased to 12,000mt/month because the SR market has grown after the enforcement of the Vehicles Recycling Law. Such business environment has been attributed to establish the thermal-materials recycling system of SR in which the RFs have changed their role from copper concentrates smelting furnaces to waste materials combustion furnaces.

Jan 1, 2019