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By Jacob Wood, Robert Matusewicz

The Outotec® Ausmelt Top Submerged Lance (TSL) Process has achieved widespread commercial acceptance over the past 40 years for the processing of copper, nickel, lead, tin, zinc and precious metal bearing feeds. The continual development and evolution of the technology during this period has resulted in a more intense smelting process with higher energy efficiency and lower operating costs. More recently, considerable effort has been invested in decarbonisation of the process through improvements such as increased oxygen usage, dry feed injection and use of low-carbon auxiliary fuels. This paper covers a number of these recent advances to the technology and highlights their impacts on energy consumption and CO2 emissions for a range of non-ferrous smelting flowsheets. INTRODUCTION Relentless demand for improvements in the profitability, safety and environmental performance of non-ferrous smelting plants has driven a continual development and evolution of processing technologies in this industry. In response to these demands, a number of bath smelting technologies have emerged over the past 40 years and have been implemented for the treatment of primary and secondary feedstocks. The Outotec® Ausmelt Top Submerged Lance (TSL) Process (henceforth Ausmelt Process) is one such bath smelting technology which has been widely adopted in a large number of greenfield projects and brownfield plant modernisations (Wood & Hughes, 2016). Emissions of CO2 from the production of non-ferrous metals represent approximately 4-5% of global totals (Rankin, 2012), comparable with the almost 10% attributed to iron and steel production. Despite significant improvements in the energy efficiency of modern smelting technologies (Coursol, Mackey, Kapusta & Cardona Valencia, 2015), primarily through increased oxygen usage, further innovation and development is still required to address their reliance on fossil fuels such as coke and coal. Transformation of the non-ferrous smelting industry to low-carbon technologies and process flowsheets is lagging behind the power and transport sectors, which have witnessed significant growth in clean/renewable energy technologies to reduce CO2 emissions and address the issue of anthropogenic climate change (IRENA, 2018; IEA, 2018).

Jan 1, 2019

By J. Chlan

"Dryer DescriptionProctor and Schwartz Continuous Conveyor DryerThe Proctor and Schwartz Continuous Conveyor Dryer has been in operation since July 1958, and comprises six unit• - an 8• wide single conveyor with roller extruder, insulated housing, type 304 stainless steel circulating and exhaust fall system, steam heating coils, temperature controls and discharge crusher rolls. Entire dryer dimensions are 52’ x 12'0""weighing 53,000 lbs,Extruder rolls - setting is 1/8"" (Drive 3 HP 1800 RPM) clearance off the extruder screen.Conveyor - consists of 151 interlocking pans, measuring 8"" x 8' (2 HP 1200 RPM) One Exhaust Fan (5HP - 900 RPM)Steam Coils -- l"" steel pipe - with steel fins -- each coil measures 16' 2’’- 64 coils in the No, 1 Compartment- 64 coils in the No, 2 CompartmentDryer OperationThe yellowcake slurry at 28% solids is pumped to an 81 x 8' Peterson Filter. The filter media presently being used is a Neotex 4372 blanket, being 100% staple fibre nylon, 12 oz per square yard with air porosity of 9 CFM's. The cake discharge at 45 - 50% moisture falls into the roller extruder. Extrusions are formed by forcing the material by rolls through a perforated plate moving back and forth and depositing the spaghetti-like extrusion on onto the dryer-conveyor.The conveyor now carries the extruded material through the heating chamber•, The feed end of the dryer will be referred to as No. 1 Compartment, with temperature control set at 280""F. The circulating fans take the hot air off the coils and circulate the heated air through the perforated openings in the dryer conveyor pane, After passing through the set of steam coils and circulating fan in No, 1 Compartment, the material then goes through No, 2 Compartment where the temperature is set at 305'F, Final material then discharges through a set of crusher rolls set at ~"". Moisture of final dried product runs at less than 2%.The dryer conveyor load is usually run to a 3"" - 4"" depth load. Conveyor speed at approximately 90 minutes for load to pass through. Load onto the conveyor is controlled by boot level and speed of the 8' x 8' filter. The dryer steam coils are water-washed twice a month."

Jan 1, 1972

By T. R. Yu, D. B. Counter

"Kidd Creek Mines primarily employs sublevel blasthole stoping for underground mining operations. During pillar recovery in No.1 Mine and panel mining in No.2 Mine, the free standing fill exposures may reach a height of 100 m or more. Consequently, a competent consolidated rockfill has been required to fill the mined openings.Since 1976, a total of more than fifty stopes and pillars have been filled with over four million tonnes of backfill. Fill exposures, up to heights of 100 m, have stood up well after blasting adjacent to the backfill.The fill material consists of a graded aggregate, Portland cement and ground slag. Sand has been occasionally mixed in the fill material to serve as avoid filler. The aggregate is prepared in a fill crushing plant, transported underground through raises, and hauled to the filling stopes by conveyors in No. 1 Mine and by trucks in No.2 Mine.Two mixing methods are currently in use. No. I Mine utilizes the free fall of gravity; the fill materials are sprayed with cement slurry as the aggregate departs from the conveyor into a mixing culvert. The other is the use of a rotary mixer on a batch basis in No. 2 Mine.This paper describes the fill systems, filling operation s, and the backfill quality control practice, together with various testing results related to improving fill quality as well as reducing fill costs.IntroductionThe Kidd Creek minesite, located 27 km north o f the city centre of Timmins, Ontario, produces 4.5 million tonnes of copper, zinc, lead, and silver ores annually from its No. 1 and No.2 underground mining operations. Both mines employ a sublevel blasthole stoping method."

Jan 1, 1983

By A. Roy MacLean

This paper outlines the changes in modern-day coal mining that have been brought about by the increased cost of labour and the use of new and highly efficient equipment. In the latter category are mentioned the ramp-plate, the Bretby cable carrier, armoured face conveyors and the shearer-loader. Greater productivity and increased safety are emphasized.

Jan 1, 1969

By M. P. Du Plessis

"The paper discusses coal research in relation to the special needs of Western Canada, with its large resources of lignite and subbituminous coals. Research programs are presented under the following headings: Coal Liquefaction, Pyrolysis, Fluidized-Bed Technology, Underground Coal Gasification and Supporting Investigations. Typical processes are presented and their relevance to Canadian coals is described. The longterm plan of the Alberta Research Council for coal research and the steps taken for its implementation are discussed. Finally, some innovative concepts arising from basic research in coal chemistry are discussed.Canada's Coal ResourcesCanada is richly endowed with coal reserves. With estimated ultimate reserves of 600 billion tons in O.76-m (2.5-ft) thick seams under less than 762 m (2500 ft) of overburden, Canada rank s fourth after the USSR, the USA and Chinatu (see Table I) . Canada's reserves are incompletely explored and estimates are constantly being upgraded. Preliminary information from deeper test-hole logs suggest that similar , if not larger, tonnages occur at depths greater than 762 m (2500 ft).The types of Canadian coals and their regional Distribution(2) is shown in Figure 2. Alberta's subbituminous Plains coal represents about 70% of estimated national reserves. A large portion of the coal can be mined at relatively low cost by surface mining techniques, and it is currently being used exclusively for power generation in conventional thermal plants. This coal, however , also represents a large potential .source of liquid fuels which could equal or exceed that of oilsands and heavy oil. Table 3 compares Federal Government estimates for resources and reserves of fossil fuels in Canada and their recoverable oil content or equivalent.A conservation estimate of only the reserves of thermal coal represents an oil equivalent of 27.6 billion barrels , which equals the recoverable reserves of oil-sand bitumen and heavy oil. A more realistic estimate is probably several times this amount. Although coal can be converted to many other end products, such as fuel gas and synthesis gas for hydrogen and ammonia production, liquid fuels remain the most desirable product mainly because they can be transported more cheaply over long distances and their high energy density makes them uniquely suitable as fuels for transport and agriculture."

Jan 1, 1981

By Jean-Pierre Birat, François Hanrot, Gérard Danloy

Global warming presents an enormous challenge to the steel industry, which is both carbon-intensive and energy efficient. Lean production can provide some short-term emission mitigation, at the level of the Kyoto requirements. In the middle term, more use of scrap will also help alleviate emissions. But to reach much larger reductions in GHG emissions, on a par with the likely targets that will be set after the Kyoto period, the steel industry will have to imagine new production paradigms, which constitutes its most formidable challenge for the years to come. Carbon capture and sequestration, processes leaner in carbon use, electricity and hydrogen from green sources will have to be added together in a patchwork of process routes, which will have to be developed at great risk in the next decade, hopefully through broad international cooperation.

Jan 1, 2004

By M. Bigdeli Karimi

In this study, the effect of strain level and holding time in semisolid temperature range via SIMA process on AS21 Mg alloy was investigated. Some cylindrical samples of this alloy with 1cm in height and 2.5cm in diameter (H/D=0.4) were compressed to 10%, 20%, 30% and 40% at 300-C. Then, the samples were reheated in semisolid temperature range at 614°C for various times. The results of optical microscopy and image analysis showed that with increasing of strain and holding time, dendritic structure changed to equi-axed structure, gradually. Also, the best conditions to obtain good globular structure were achieved. Furthermore, it was seen that after compression and reheating, Mg2Si intermetallics with Chinese script morphology converted to dispersed-fine particles which were distributed into the ci-Mg grains.

Jan 1, 2007

By SeyedBijan Mahbaz

Development of Geomechanical Earth Models (GEM) is a prerequisite to reservoir management, involving issues such as stress path analysis, prediction of induced seismicity and sanding initiation, and coupled flow-stress modeling that leads to more realistic predictions of oil rates and rock response. Part of GEM development is the stipulation of the 3-D lithostratigraphic disposition (geometry) which is used to choose the geomechanical units. The digital geological model is then populated with quantitative and semi-quantitative data on rock properties, fluid properties, saturations, initial conditions (p, T, [_]) and other information. Both fluid and solid properties are needed this requires integration of geomechanics skills with geophysical and rock physics skills, and this article deals with a subset of this integration process, with an example from two wells in southwest Iran.Rock physics approaches are used to predict reservoir rock and fluid properties with wellbore and 3-D seismic data, which are also used to interpolate rock mechanics properties to the inter-well regions. The first step in a generic rock physics approach is diagnostic and involves the introduction of a suitable Rock Physics model.Acoustic impedance (AI), shear impedance (SI), and density (_) are the fundamental rock properties usually derived using AVO equations, and these parameters, along with attenuation coefficients, can then be correlated to static rock mechanics properties that define deformability and perhaps even strength. In this study, Poisson Impedance is introduced as a new seismic attribute used for lithology and fluid differentiation in the FahliyanFormation (reservoir rock) in two oil wells in the southwest of Iran. To do this, a novel rock physics model was developed for this naturally fractured carbonate reservoir.Currently, these data are also being used to correlate to a limited rock mechanics data base to develop a more extensive GEM to serve as input to more general geomechanical and reservoir modeling tasks.

Jun 1, 2012

By Rene Klymowsky, Norbert Patzelt, Egbert Burchardt, Johann Knecht

"The challenge of ""ore bodies getting steadily harder and lower in grade"" was brought to light during the first oil crisis in the 70's. Shortly afterwards, HPGRs appeared on the scene with the promise of saving energy. This combined with developments in wear protection for the rolls ushered in a period of trade-off studies that considered the HPGR as an option to improve project economics or to even make projects feasible at all.Since then, applications of HPGRs at Cerro Verde (Freeport), PTFI Grasberg (Freeport), Mogalakwena (Anglo Platinum), Tarkwa (Goldfields), Boddington (Newmont), Penasquito (Goldcorp), and others have contributed to the creation of a formidable basket of operating experience. Collected through years of successful operation, this information has been used to validate design criteria, scale-up factors and establishing a clearer picture of what ""to do"" and what ""not to do"".This paper compares results from various mining operations using HPGRs in their processing plants. Some of the lessons learnt in different operating environments are reviewed in order to support proper implementation and operation of HPGR's. Some of the development programs that have been initiated to improve wear life of the tyres and to reduce overall operating costs are reviewed. It is timely to summarize today’s experience and analyse its implications for existing and new operations"

Jan 1, 2012

By Michael L. Free, Shukla. Abhijeet

The short-circuiting tendency of a copper electrowinning cell (EW) based on the roughness of cathode deposits was investigated with varying parameters such as Cu concentration, guar concentration, current density, and temperature. A bench scale EW cell was set up to produce copper under conditions similar to industrial Cu EW. In addition, a statistical analysis and finite element analysis were performed to analyze the deposited thickness, surface roughness and maximum feature height. Interaction data for the cathode deposits suggest that current density and Cu concentration together affect the roughness of deposit more than the combined effect of guar and temperature. Model predictions of roughness were similar to experimental values. The predicted time to short-circuiting was similar to the measured time. This study provides an industrial relevant baseline against which new operating parameters can be compared.

Jan 1, 2014

By S. Fabich

Since the very beginning of Polish copper mining, special consideration of sink shaft techniques through highly saturated Cenozoic rocks was required. Shaft freezing has been chosen as a method to consolidate these rocks. Due to the rock mass structure and water inflow potential, shaft sinking without freezing was considered dangerous. In the course of time, rock mass freezing technology and experience were evolved and this technology became safer and more reliable. New techniques appeared not only in the technical method of freezing, but also in the matter of designing. Computer aided techniques allow engineers to make a detailed analysis and view of freeze wall development. Nevertheless it is important to determine basic thermal rock properties. In this paper, the evolution of knowledge and engineering experience taken in Polish copper mines and current knowledge level in that matter were shown.

Aug 1, 2013

By D. Neely

As Saskatchewan potash mines grow in age and size, mining reaches greater depths.  The stress-relief design principals which were empirically derived at shallower depths are beginning to show fault.  Nutrien Vanscoy Potash has began to encounter new ground support and panel design challenges which were previously had negligible effect.  While the initial reaction was to reduce extraction and implement distance buffers between operating machines, it eventually became clear that these would only provide short term relief and that in order to continue safely and efficiently mining broad areas, a fundamental change in the mine design would provide the long-term protection required.  Presented is a case study with an overview of the challenges encountered at Vanscoy Potash in areas of greater depth along with an account of the design changes considered, implemented and recommended for future success. 

May 4, 2025

In Canada and other countries, legislation dealing with accurate factual disclosure for mining projects is being expanded to include more metallurgical design information. Grinding characteristics, metallurgical recovery of contained metal and environmental hazards associated with tailings disposal will be part of the Canadian package. This paper will examine only that portion of the plant design standard practice that relates to grinding ? in SAG mills and ball mills that grind ore from as received crushed material to final ground product that is fed to downstream plant recovery processes. Since grinding plants represent a significant portion of the overall concentrator cost, accountability in grinding design should no longer be left to chance, opinion, or hidden proprietary information. This is the 21st century. It is reasonable to expect that a factual basis will be needed so that a Qualified Person (QP) reviewing the grinding mill design can understand it. That will also involve how many and what quality of samples are taken to define the characteristics of the deposit, the accuracy of the tests used to measure ore hardness and the method by which the dimensions and power of the mills are determined. If these criteria are not met, the QP may have no choice but to call attention to the lack of convincing information regarding the grinding mill design for the project. At the same time clients are expected to demand getting the correct design information at a cheaper price, results in a more timely way, and accurate design to the point where the risk of tonnage shortfalls are reduced or eliminated. Tables will be presented to show how this can be done to current standards using existing technologies. At the same time it is acknowledged that current standards are ill-defined and that to achieve consensus among those involved in SAG mill design work, it may require that a consortium funded project be set up to establish what tests and methods for grinding design are suitable to meet the new standards for metallurgical disclosure. By running parallel design methods on several major projects over a period of 5 years, the process of how to design grinding circuits will be better understood because the projects will start at the design stage, include procurement of the mills and will end with a benchmark test on the plant. Selecting the samples and the best schedule for doing test work on core samples submitted and mill design, will be discussed in this paper. The issue of completing the grinding design in time for early procurement decisions is on the critical path for most major projects. Discussions between mining engineers, geologists and process engineers are needed early in the development cycle, at the scoping study level (SS), preliminary engineering assessment (PEA), prefeasibility study (PFS), and at the feasibility study stage (FS), to ensure that proper planning for design sample selection is done. Using adequate sampling and testing methods in a timely way allows early procurement of the grinding mills and minimizes project risk.

Jan 1, 2012

By Robert A. Brown

"The O'Brien mine is in the west-central part of Cadillac township along the Cadillac 'break', which extends for 7,500 feet from west to east across the property.The ground was staked in 1924 by A. Dumont and W. Hermeston, prospecting for M. J. O'Brien, Limited. The first vein discovered is that now known as No. 1. The No. 4 vein was later exposed on the surface; the other veins known to be present were revealed by underground work and diamond drilling carried out both from the surface and underground.The mine is developed from three vertical shafts: No .. 2 extending from the surface to 2,000 feet; No. 3 from the surface to 1,500 feet; and No. 4 from 2,000 to 3,000 feet. There is on the property a mill of about 200 tons a day capacity, the usual shops, and a townsite housing about forty-five families. Gold production to the end of September, 1944, amounted to 295,824 fine oz. from ore having an average grade of 0.505 oz. a ton. In addition, the mill recovered 3,237 tons of arsenic trioxide having a purity of 83 per cent As2O3.GENERAL GEOLOGYThe four main groups of rocks of the Cadillac area- the Cadillac, Blake River, Kewagama or Pontiac, and Malartic- are found within the boundaries of the property. However, as these rocks have been fully described in · various government reports (1,2,3,4,5,6) and all the known orebodies occur within one group- the Blake River-a detailed description of the geology will be dispensed with here. The known ore deposits lie south of the Cadillac 'break' in a group of rocks that includes 'greenstones', greywackes, conglomerate, porphyries, and a rock of gabbroic composition that may be intrusive. Both flows and tuffs can be recognized in the 'greenstones'. The two bands of porphyry that trend easterly across most of the property have been considered by some observers to be dyke rocks and by others to be flows. Certain evidence points to their being dykes that were intruded as sills considerably prior to the emplacement of the gold-bearing veins, but the possibility of flow origin cannot be fully rejected. North of the talc-chlorite-carbonate schist zone forming the 'break' the rocks are conglomerate and greywacke with iron formation, in which there are no known veins of ore grade. Within the schist zone are minor acid and basic intrusives. The general trend of both bedding and schistosity is a few degrees south of east. The dip is generally vertica1 or steep to the south."

Jan 1, 1954

By F. Flores

With the World Summit for Sustainable Development planned for 2002 in mind, nine of the world's largest mining companies decided to initiate a project to examine the role of the minerals sector in contributing to sustainable development, and how that contribution could be increased ? the Mining, Minerals and Sustainable Development Project (MMSD). This project assumed from the start that sustainable development could provide a useful framework to guide the minerals sector which main goal was integrating economic activity with environmental integrity, social concerns, and effective governance systems. The broad steps of MMSD project strategy can be grouped into four major categories: increase understanding of sustainable development; create organizational-level policies and management systems for implementing the principles of sustainable development; collaborate with others with common interests to take joint steps towards sustainable development, and; increase our ability to work towards sustainable development at the local, national, and global levels. In opinion of the article's author, to go ahead with the MMSD strategy and achieving the sustainable development objectives, it is necessary to consider the concept of self-organization, fundamental of the emergent new scientific paradigm, and the consequent epistemology and values that conform a supporting culture for sustainable development.

Jan 1, 2007

By I. A. Menshikh, S. A. Kotov, N. L. Shinkarkin

All the cycle for conversion of natural and reprocessed uranium of ROSATOM’s “TVEL” Fuel Company is concentrated at the Siberian Chemical Plant. Conversion capacities are located on two sites, i.e. the Radiochemical Plant, which refines feedstock, and the Conversion Plant, which produces uranium oxides and uranium hexafluoride. Liquid radioactive waste arising in the process, after pretreatment, is transferred to a dedicated national operator for underground disposal. Environmental strategies pursued by the Fuel Company involve the introduction of process solutions intended to eliminate liquid radioactive waste and convert it into a solid phase. In the 5–7 years coming, work will be performed to refurbish and upgrade conversion facilities of the Siberian Chemical Plant that will principally change its radioactive waste management scheme. This paper describes the current waste management scheme and sets out planned schemes for management of natural and reprocessed uranium waste, which will be implemented in the refurbishment of conversion facilities of the Siberian Chemical Plant. The new technologies for the management of liquid radioactive waste from uranium conversion described in the present paper have an undeniable advantage over the current technology mainly due to significantly less environmental harm.

Jan 1, 2020

By M. A. N. Rosa, L. C. R. Machado, R. A. Fonseca, A. M. Mendonça

"Sossego Mine was the first Vale SAG mill operation to process copper-gold ore. It is located in the state of Para, in the south-eastern Amazon region of Brazil. In the first six years of continuous operation, Vale investigated different alternatives for improving circuit performance by investigating operating conditions, mainly focusing on the SAG mill.Today, after a steady increase over five years the annual production rate seems to have stabilized. It is hoped this work will show how the SAG operating practice have been perfected with time and as new data are collected. Historical data of mill grind-outs and crash stops helped create operation curves depending on the ball charge volume and total charge volume. Also noted were impacts on throughput due to the effect of reducing liner weight and the ore type characteristics."

Jan 1, 2012

By W. S. Urbanski, A. L. Devernoe, R. W. Stuart, M. S. Walker

"Although many investigators have successfully achieved separations using variations of a concept wherein particles are buoyed upwards against gravity in a magnetically attracted fluid, none have succeeded in separating fine particles in a manner that is practical tor mineral beneficiation. This paper describes laboratory tests and preliminary economic analyses for a new mineral separation process which provides enhanced magnetic buoyancy and separation capabilities. The process provides a means of gravity separation in a regime where conventional gravity separation is inadequate; that is for small differences in mineral densities and for very fine particles. Although early interest centers on gravity separation, the process has also been successfully used for precise magnetic separation.Tests were conducted on a variety of mineral mixtures, ore samples and concentrates including; a sphalerite ore, pyrochlore ores and concentrates, cassiterite pre-concentrates, a chromite pre-concentrate, and heavy mineral placer samples. Separations requiring high discrimination between fine particles narrowly different in density or weak magnetic properties were obtained. Of particular interest is the ability of the process to concentrate or remove oxide minerals or gangues, especially silicates. Potential applications are discussed."

Jan 1, 1985

By A. K. Debnath

Coal is the mainstay of Indian energy supplies. The many-fold increase in demand for coal puts a huge pressure on augmenting production, primarily from opencast mines. The increase in production necessitates heavy blasting in overburden and coal benches of opencast mines, which poses numerous challenges in carrying out blasting operations techno-economically. Presently, the consumption of industrial explosives and accessories in Coal India Limited (CIL) has touched a whopping figure of $350 million USD per annum and CIL will be spending approximately $1 billion USD between 2012?2013 to 2014?2015 for procuring explosives and accessories. This paper discusses some of key challenges faced in various mines of CIL during blasting, where blast instrumentation at the mine level will prove to a harbinger for practicing blasting engineers. Presently, the problem of scattering in surface detonators and down-the-hole detonators affects the blast performance significantly by increased blast induced ground vibration and reduced fragmentation. The paper discusses a case study carried out at Umrer opencast project of CIL to investigate the effect of scattering by using blast simulation techniques (i.e., JKSimblast) and observing the actual blast results with the help of a high-speed camera and multi-channel high frequency data acquisition systems. The fragmentation assessment was carried out by adopting Digital Image Analysis techniques and using the granularity software viz. Wipfrag. The blast instrumentation in the case study mine resulted in improvement in fragmentation of 12.76% and a direct savings in explosives cost of 28%. Geophysical techniques such as the seismic survey method have been used at Umrer Project, CIL to characterize the rock mass using the Multi Channel Analysis of Surface Waves system for selecting the explosives technoeconomically. The minimum deck thickness for mines of CIL using drill cuttings as decking materials should be 10 D, where D is the drill diameter. The estimation of blast performance on the basis of prescribed Powder Factor (i.e., kg of explosives per m3 of rock) is technically unscientific as the criterion of a good blast depends on many factors (i.e., good heave, loose muck, muck profile angle, ease of digging, uniform fragmentation). The present paper proposes a new methodology for techno-economic evaluation of blast performance. The new methodology involves four significant factors viz. specific energy consumed by the loading equipment, charge factor, productive yield and diggability index for assessing blast performance. The use of user-friendly, accurate, reliable, rugged and handy instruments in blasting will significantly improve mine productivity, equipment efficiency and economics. The improvement in blast performance, even by 1%, will provide a significant savings of $3.5 million USD per annum to CIL. It may be concluded with high degree of confidence that blast instrumentation at the mine level will influence the mine productivity and economics.

Aug 1, 2013

By M. Tanaka, Y. Sato, H. Narita, S. Alam, T. Ogata

To ensure a stable supply of rare earth elements (REEs), it is highly necessary to establish the corresponding recycling technologies for RE magnets and phosphors in inplant wastes and endoflife products. Solvent extraction using 2ethylhexylphosphonic acid mono2ethylhexyl ester (EHPNA) is often applied in the separation and purification of REEs. In this study, the equilibrium distribution ratios of neodymium and dysprosium between 1 mol/L nitrate solution and the EHPNA in an alkane diluent were measured at 298K. The experimental data were analyzed by correcting the nonideal behavior of the organic phase using the Alstad empirical equation under the assumption that a complex with a molar ratio of 1:6 (REE:extractant monomer) was formed. The model correlated well with the experimental data and the extraction equilibrium constants were obtained. The extractant equilibrium constants obtained by this methodology would be useful in the design of REE recycling processes using solvent extraction.

Jan 1, 2014