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By T. T. Chen

A detailed mineralogical study was carried out to characterize the products generated in a conventional copper refinery anode slimes treatment circuit. The anode slimes, which are first leached in sulphuric acid media under an oxygen pressure to dissolve the copper and much of the tellurium, were found to contain various Ag-Cu selenides, PbSO4, Ag, Au and BaSO4. The resulting Ag2Se, Ag3AuSe2, Se, Au, PbSO4, BaSO4, SnO2 and silicate-rich leach residue is dried and pelletized. It is subsequently roasted to convert the selenium to Ag2SeO3, volatile SeO2 and water soluble Na2SeO4. The roasted product, which was found to consist of Ag2Se, PbSe, PbSO4, BaSO4, Ag3AuSe2, Au and Sn02, is smelted and refined in a Dore furnace to produce a Dore metal that contains a (Ag,Au,Pd,Cu,Pt) alloy together with traces of CuO and a Cu-Pb oxide phase. Parting plant mud shown to contain AgC1, Ag, Au, (Au,Ag,Pd), Ag2Cu2O3 and Ag20, and scrubber mud containing PbSO4 and AgC1 are also fed to the Dore furnace. The Dore furnace sequentially separates a silica slag which was found to consist of Ag, Sn02, BaSO4, Pb-Sb oxide, Fe-Sb-Ni-Cr oxide and a Pb-rich silicate phase, a soda-rich slag containing Na2CO3.H2O and Na2(Se,Te)03, and a niter slag containing Na2TeO3, Na2(Se,Te)03 and a Na-Te-Se-Pb-Ba-Cu oxide phase. The Dore metal is electrorefined in Moebius cells to yield high-purity silver and a gold mud which was shown to consist of a (Au,Ag,Pd,Cu,Pt) alloy and traces of CuO. Silver is leached from the gold mud and the resulting gold sand is cast into anodes and electrorefined in Wohlwill cells to produce pure gold.

Jan 1, 2007

By K. Torigoe, S. Owad, C. Tokoro, Y Tsunazawa

The mechanism of an abrasion process to recover metal values by removing components from printed circuit boards (PCBs) is modeled using a discrete element method (DEM) simulation. To simulate the abrasion process, a model PCB geometry was constructed consisting of bonded particulates. The simulation allowed connections between particles to be broken if the bonding force calculated from DEM exceeded a threshold level. Simulation results were compared with experimental comminution data using an agitation mill with test PCBs on which nine capacitors were surface solder-mounted. Simulation results obtained from the DEM with the anchoring model corresponded to experimental observations.

Jan 1, 2011

By W. T. Gotheridge

The principal sources of coal-dust underground are, of course, coal, and the working of coal. Coal-dust is most dangerous when it is in the finest state of division. This class of dust is found mostly on the roads, being blown or shaken off the loaded trams in transit, or carried in suspension by air currents. The air current passing from the working faces may also carry dust in suspension into the return airway, and the air current from the surface may carry dust from the shakerscreens into the intake airways. The mosl dangerous dust we have to contend with is, (a) that which is most finely divided, and (b) that which contains the most volatile matter, including the inflammable occluded gases, and also oxygen absorbed from the air. According to experiments, coal-dust in a fine and dry state would intensify an explosion, in air free from fire-damp carrying in excess of 3 ozs. of fine dust or 6 ozs. of coarse dust per cubic yard. The volatile matter in the dust must be between 12 and 31 per cent. in the ash-free coal, the latter percentage giving the highest flame velocity. It is vary difficult to propagate flame where coal-dust contains a large percentage of stone-dust, (say 50 per cent.). Shale-dust or other incombustible dust containing no volatile hydro-carbons or carbonaceous matter will prevent the extension of an explosion if mixed with coal-dust in proportion of say 70 per cent., and if the dust is finely divided and dry.

Jan 1, 1924

By H. Nakano

The codeposition behavior of impurities such as Ag, Bi, Fe, Ni, Pb and Sb with Cu was investigated galvanostatically at 5-3000 A/m2 using a Pt cathode at 60 °C in acidic copper (I) chloride (cuprous chloride) solution at pH1-2 containing 1.0 mol/L of Cu+ and 4.9 mol/L of Cl-. The impurities were classified into two groups: Group I (Ag, Bi) which codeposits with Cu as a metal, and Group II (Fe, Ni, Pb, Sb) which is slightly involved in the deposited Cu in nonmetal form from the electrolyte. Silver and Bi in Group I behaved as more noble metals than Cu, and significantly codeposited with Cu, showing typical features of regular-type codeposition. When Cu was deposited dendritically, the Ag and Bi content in the deposit increased with increased duration of electrolysis as a result of decreased net current density caused by increased cathode area. The current efficiency for Cu deposition in impurity-free solution was 95-100% over 100-1000 A/m2, but it abruptly decreased at above 1000 A/m2 when the limiting current density of Cu was attained. Although Fe, Ni, Pb and Sb in Group II were involved to 0.01-0.02 mass% in the deposit, they had no influence on the current efficiency or morphology of Cu.

Jan 1, 2007

By M. Mohammadi Zahrani

The morphological modification of primary and eutectic Mg2Si phases by bismuth (Bi) addition in Mg-5wt.% Si in-situ composite was investigated. It was found that with addition of 0.5wt.% Bi, the morphology of primary Mg2Si precipitates was altered from coarse dendritic to polygonal shape, and their mean size was significantly decreased from more than 20 µm to about 8 µm. Moreover, the rod-like eutectic Mg2Si in Bi modified Mg-Si alloy solidified much finer than that of the base alloy. Such improved microstructure of the modified alloy resulted in 10% tensile strength and 20% elongation improvement. The isotropic growth manner of primary Mg2Si particles in modified alloy was attributed to the poisoning of growth in preferred directions by dissolving Bi atoms in Mg2Si lattice. The reduction in size of eutectic Mg2Si was found to be the result of Mg3Bi2 compound formation around eutectic Mg2Si rods.

Oct 1, 2011

By R. P. Mahant

"Extensive pilot plant investigations were conducted both on partial roasting an d electric furnace smelting from September 1973 to August 1975.The objectives of the pilot plant investigations were:(I ) to confirm the application of available process technology to treatment of Falconbridge concentrate.(2) to examine partial roasting variables.(3) to investigate electric furnace smelting of roaster calcines .(4) to develop process design and operating parameters for a commercial plant.This part of the paper will cover the following topics:Partial Roasting InvestigationsPilot Electric Furnace InvestigationsPartial Roasting InvestigationsThe specific objectives were to:1. establish process variables for maximum oxygen efficiency and bed fluidi ation.2. determine the product distribution between the roaster and the various gas cleaning stages.3. produce a mass and thermal balance."

Jan 1, 1984

By M. K. Kim

This study presents a framework for quality inspection of precast concrete components using the 3D laser scanning technique. As precast concrete-based rapid bridge construction is getting standardized, quality assessment of the precast concrete becomes critical for preventing any failures during the construction process. Moreover, as Building Information Modeling (BIM) gains popularity in the construction industry, autonomous and intelligent inspection systems are needed. Current method for quality control of precast concrete components, however, heavily relies on visual inspection and contacttype measurements, which are time and labor demanding. Also, storage and delivery systems of inspection information such as the procedures and results of quality inspection are lacking. To overcome these limitations of the current quality assessment technique for precast concrete, this study aims to develop a BIM-based framework for efficient quality inspection of precast concrete with the use of a 3D laser scanner. First, we formulate practical guidelines including detailed inspection procedure, selection of optimized scanner and scan location, inspection criteria, and data storage and delivery system. Second, to investigate the applicability of 3D laser scanning to precast concrete quality inspection based on the proposed framework, a case study inspecting quality of a lab-scale object assumed as precast concrete component is presented for detecting defects.

Aug 1, 2013

By Amir Karami, Derek Kinakin, Catherine Schmid

The Mathews Stability Graph Method (Mathews et al., 1981) has been used by geotechnical engineers and mining engineers for over 40 years to estimate the performance of longhole open stopes in underground mines. The method is widely used and accepted by practitioners because it is relatively simple to use and can be modified to account for observed performance at a given mining operation. While the simplicity of the method increases its accessibility and utilization, it does not intrinsically account for variability in the various inputs, including rockmass quality, structure, stress, or stope orientation. This paper presents a modified approach for the Stability Graph Method, whereby Python scripts are used to process available geotechnical datasets and combine them with actual or potential distributions of Q parameters, induced stress, structure, or stope orientation. The resulting Stability Numbers are then plotted as a contoured distribution on the Stability Graph.  This allows the practitioner to quickly incorporate large datasets into the analyses, while also developing an understanding of how variability in rockmass quality, induced stress, structure, or stope orientation could affect stope stability.  This paper presents the fundamental principles of the Stability Graph method, the Python script and workflow, and two case studies to demonstrate the utility of the tool.

Oct 1, 2024

By Lee Nichols

The Oil Sand Industry in northern Alberta, Canada, disposes of the by-products of bitumen extraction into tailings ponds. The mix of tailings sand and mature fines, with gypsum added as a flocculent, constitute a waste stream called Consolidated Tailings or Composite Tails (CT). The two main challenges of the tailings disposal process are a chronic shortage of economical containment and the potential mobility of CT deposits in the event of breaching by, for example, long term erosion, which makes abandonment of tailings ponds more complicated. Thick deposits of CT do not consolidate in adequate time to provide reassurance for abandonment of the CT containment facilities and that is why the containment must be adequately robust or the properties of CT improved for long term stability. This paper addresses potential solutions to these problems by applying the gravity drainage of CT and quasi-homogeneous construction for containment facilities. Gravity drainage is suggested as a mechanism to facilitate the consolidation of CT in critical areas of the ponds by inserting internal sand layers within the body of the deposit. Critical CT areas are defined as areas around the perimeter of containment. The advantages of this solution are long-term stability of the disposal area by creation of stiff deposits around its perimeter and facilitation of reclamation efforts on its surface. The present solution for containment of CT deposits is not favourable from a materials balance point of view. In general, sand has become a valuable resource as it both forms the primary component of the CT matrix and becomes the containment building material. If sand is required for CT, less is available for dyke construction. This puts additional pressure on the industry as a whole to maximize the use of overburden and interburden for construction of tailings containment structures. Typically, only 50 percent of dry mine waste (overburden + interburden) is incorporated into dyke construction. The remainder of dry waste is stored either in waste dumps or in tailings ponds, consuming valuable in-pond space originally allocated to CT material. Quasi-homogeneous dykes are proposed to contain CT deposits rather than traditional minimum cross-section dykes built of overburden and/or cell sand. The quasi-homogeneous dyke may change the unfavourable material balance and lessen the construction constraints that are presently imposed on the mine/waste disposal process.

May 1, 2004

By J. Peace, J. R. Fletcher

"British Steel has increased its usage of stainless steel for bunker, silo and chute linings to reduce maintenance costs and improve productivity.A generation of low cost 12% Cr steels has been specifically developed to satisfy the needs of hardness, flow promotion and through life costing which are demanded by bulk solids handling industries.The range of stainless steels include:• a very hard martensitic grade which is particularly suitable for high stress applications where impact and abrasion are predominant;• a titanium stabilized duplex steel for structural applications, as well as low friction , medium abrasion resistant wear liner plate; and• a ferritic stainless steel with rubber backing for low stress application where flow promotion of product is the predominant requirement.Industrial applications and experiences along with methods of fixin g the stainless steels will be discussed in conjunction with the relative through-life costs of the products.IntroductionBritish Steel has become one of the most efficient steel manufacturers in the world, with improvements seen in productivity, quality, delivery, performance and response to the needs of the worldwide market place.Part of this success stems from reductions in engineering downtime in the key areas of its operations, by the introduction of better engineering design and the use of enhanced materials where significant cost benefits have been identified.The nature of producing iron and steel requires the use and handling of a number of raw materials with wide ranging properties, each calling for a different approach to solving the difficulties encountered in storing and transporting these materials to their respective point of use. Figure 1 shows steel production for 1988-89 where over 30 million tonnes of raw materials were handled in making 14 million tonnes of liquid steel at British Steel's five integrated works.Typically solid raw materials include, iron ore, coal, limestone, ferro alloys and scrap. Intermediate products such as coke and sinter create their own specific handling and wear problems.Coals and ores are shipped into the United Kingdom from several sources, and have a great variety of properties. Some coals can be extremely wet and sticky, whereas others are dry and dusty . The ores handled can vary from wet concentrate and fines to heavy angular rubble and pellets. These raw materials are off-loaded, stored and conveyed through British Steel's own port facilities at Port Talbot, Immingham, Redcar and Hunterston. British Steel also produces the majority of its own coke and all its own sinter. Coke and sinter are frequently handled at elevated temperatures which cause other handling problems."

Jan 1, 1991

By Y. Nishida, Y. Nara, T. Ishida

Understanding time-dependent deformation and fracturing in rock is essential, because the information of the long-term stability of rock is required for many sub-surface structures excavated in a rock mass. Time-dependent fracture propagation has been invoked as a potential key mechanism responsible for the increase in seismicity preceding earthquake ruptures. In engineering projects and in preventing natural hazards, the study of time-dependent fracturing is necessary. Subcritical crack growth is one of the main causes of time-dependent fracturing in rock. For silicate rocks, subcritical crack growth has been investigated by various researchers. It has been clarified that surrounding environmental conditions (temperature, humidity, and existence of water) have strong influence on subcritical crack growth in silicate rocks. Therefore, the information of subcritical crack growth in silicate rocks has already been enough. On the other hand, information of subcritical crack growth in carbonate rocks is not enough. Especially, the influence of surrounding environment on subcritical crack growth in carbonate rock has not been clarified yet. In this study, we investigate subcritical crack growth in carbonate rock experimentally using a fracture mechanics testing method. Marble obtained in Skopje in Macedonia is used as a carbonate rock sample. The Double Torsion method is used to measure the crack velocity and stress intensity factor. Especially, influence of water on subcritical crack growth in Macedonian marble is investigated. It was shown that the crack velocity in water is much higher than that in air at the same temperature. Based on the results of subcritical crack growth measurements, the long-term strength is evaluated for marble. It was clarified that the long-term strength in water is lower than that in air in marble. It is concluded that water has a remarkable influence on subcritical crack growth in marble. It is also considered that the long-term stability of carbonate rock masses should be ensured in a dry environment.

Jan 1, 2015

By G. R. Webber, P. J. Whittaker

"A multielement (Au, Cu, Pb, Zn, Ni, c-, Ag, As, Hg, Co, and S) geochemical rock sampling survey was carried out in 1977 in the Munro Township area of Ontario to assess the application of rock geochemistry for gold exploration in the region. Detailed sampling with analysis for gold and arsenic was done in 1986 in the immediate vicinity of the Croesus Mine.Samples of quartz veins and rock formations were taken in regional traverses and in more detail near old showings, prospect pits, and trenches. Quartz, graywacke, carbonate rock, and rhyolite contain the highest concentrations of gold for samples taken away from the old workings. Ultramafic rocks and gabbro have uniformly low gold. Basalt samples have slightly higher geometric means, but individual samples contain high gold concentrations. Multielement highs are mostly in mineralized quartz samples. Gold distribution is independent of other elements in most other rock types. Samples near old showings possess elevated concentrations of gold indicating that prospecting for individual mineral deposits by bedrock sampling is feasible. Concentrations of gold greater than 100 ppb are mostly within 30 m of old workings. Those samples which contain greater than 1000 ppb Au were obtained from quartz veins, basalt, graywacke, and rhyolite.High concentrations of gold were not notably concentrated near the Contact Fault although some anomalous samples came from near and on both sides of the fault. Arsenic concentrations are elevated near the Contact Fault. Detailed sampling near the Croesus Mine suggests that gold was introduced with faulting, alteration and quartz veining. Gold and arsenic have been added to the wallrock in the vicinity of the main veins."

Jan 1, 1989

By A. J. Hyett, N. Hedrick, J. Blackall

The Garford bulb anchor is a modified cable geometry developed and patented by Garford Ply Ltd. of Australia, and which has recently become widely available in Canada. It is produced by deforming the seven wires (including the central kingwire) of a standard cable into a bulb" (Fig. 1). Laboratory cable pull tests indicate that the bond capacity of the 25 mm Garford bulb anchor is comparable to the nutcase cable, in excess of the birdcage cable, and significantly higher than standard 7-wire strand. Its comparative advantage over the latter is most significant for tests at low radial confinement and high water:cement ratio grout, which corresponds to operational conditions of low quality rock (i.e. weak, highly fractured rock masses, foliated hanging walls, failed ground, etc.) and poor installation quality control (perhaps the most common explanation for cable bolt failures). It is under such conditions that cable bolting is often ineffective. The most impressive result is that for a reduction of the effective rock mass modulus by a factor of five, the Garford bulb cable capacity remains virtually unchanged.

Jan 1, 1995

By John Eggert, Paul Benford

"Since 1982, Placer Dome Inc. -Dome Mine has steadily increased mill throughput. Tonnage has increased from a nominal design capacity of 3000 short tons per day, attained in 1985, to 4130 stpd by the end of 1992. Many minor and major circuit adjustments were tried to maximize tonnage.Having utilized most conventional means of increasing tonnage, further increases required a newer approach. This paper discusses the Dome experience in the development and implementation of an expert system.The Comdale/C system was chosen for a controlled trial. The criteria for acceptance were: increased tonnage had to be sufficient to pay for the system; the increase had to be visibly sustainable and the mill operators had to be willing to accept the system.The criteria for purchase were met during the trial and the system was purchased. The system continues to perform well. The tonnage throughput increase has been sustained while operator acceptance remains high.IntroductionPlacer Dome Inc. -Dome Mine is Canada's oldest operating gold mine. The mine was among the first established in the Porcupine camp in what is now Timmins, Ontario. The City of Timmins is located approximately 500 miles or 800 kilometres north of Toronto. Figure 1 shows a map of the province of Ontario and the mine location.In 1912, milling began at a rate of 350 short tons per day. With two minor exceptions, milling has been continuous since this time. The first of these shut downs was in 1918 during the first world war. The war created labour shortages which forced the mine to stop production for more than a year. The second was in 1930 when fire destroyed the mill."

Jan 1, 1994

By Jan Rosenkranz, Anders Sand, Lisa Malm, Nils-Johan Bolin

Within flotation technology the general trend is towards very large cells. Scale-up is usually done by postulating geometrical similarity, which implies keeping the aspect ratio constant when increasing cell volume. Consequently, the design of flotation circuits typically involves several cells of identical geometry within a bank. Using a few standard sizes in a flotation plant simplifies design, manufacturing and maintenance of the cells, but does not necessarily guarantee optimal performance and selectivity of the flotation process. Geometry parameters for a given cell volume that influence flotation cell performance include cell height, which causes changes in the hydrostatic pressure and suspension hydrodynamics, and also influences the travel distance of particle-bubble agglomerates as well as the homogeneity of the mixing. Also the thickness of the froth layer depends on the aspect ratio of the cell. The objective of this work is to gain a better understanding of material distribution and properties within a flotation cell and, based on this information, elucidate how alterations of the cell geometry can influence separation efficiency. For this purpose systematic measurements and analyses of the spatial distribution of the different phases within a 160 m3 flotation cell have been carried out with a particular focus on an industrial, low-grade copper ore beneficiation process. The concepts for sampling at different vertical and lateral positions of the flotation cell are introduced. The results from the experimental work give an understanding of internal material distribution within flotation cells. Based on the measured phase distribution and concentrations as well as particle properties at various positions within the cell, the implications for an optimized scaling and design of individual flotation cells within a flotation circuit are discussed.

Jan 1, 2016

By Alexander Levran

The main thrust of this presentation is to illustrate the growing contribution of solar energy to the mining industry by replacing existing mechanical and pneumatic tools and equipment with more effective and efficient electrical tools due to the increased efficiency and lower cost of solar energy generation. LCOE (levelized cost of energy/electricity) for solar energy is becoming highly competitive with other conventional sources of energy. The distributed architecture of solar power plants allows the supply of energy to highly remote and abandoned geographies. We will focus on the trend for this contribution to the mining industry over the next three years. Water desalination and delivery to the mining area will be topic of discussion regarding the contribution of solar systems in Latin America (LATAM) and other geographies. INTRODUCTION Increasing price pressure on the mining industry has generated a strong interest for mining companies to investigate energy costs and consumption. Currently, energy costs in mining economics contribute15% to 25% of the total commodity cost. In the past, most mines were operated by diesel gensets. Very high logistics costs for diesel supply, high and fluctuating diesel prices and theft led to very high energy prices. To overcome this problem, the mining industry has turned to solar energy, employing two main solutions: (i) adding a small scale (single level MWp energy supply) solar to an existing diesel system to create a hybrid solution operating as a microgrid environment; and (ii) replacing the existing diesel system with a large scale grid connected photovoltaic system financed by utilities or private IPP owners that signed a long-term power purchase agreement (“PPA”). In both applications, the near-term trend is to add storage and weather controls to optimize the electrical performance of the system. Use of concentrated solar solution (CSP) in the past was employed in a few remote sites to provide electrical energy to the mines. Currently this technology is not competitive with the photovoltaic (PV) systems. In some installations we have seen usage of a small hybrid system that is designed as relocatable, containerized and delivers scalable electrical power. In addition to the evolution of electrical energy sources, we see the trend of reduction of energy consumption in the mines by optimizing energy efficiency and generating load shifting solutions. Many studies of electrical energy in the mining industry support the growth of this trend in the mining industry.

Jan 1, 2019

By Christopher R. Davis

Resource modelling is the basis for any economic appraisal of a mining project and includes a number of steps from data acquisition and validation to resource reporting and classification. At each step in the modelling process it is necessary to define the specific objectives, the methodology proposed to achieve those objectives and to establish a set of checks and validation tools to assess the effectiveness of the proposed methodology. The data used has to be both reliable and relevant for the purpose of the modelling. QA/QC for database validation requires verification of sample location; including correct collar location, topographic modelling and down-hole surveying. Validation is also performed on assaying information such as checks for sampling bias and accuracy of core splits, proper use of pulp duplicates and standards, handling of calculated values, explicit/implicit absent data and data entry errors. The second step involves identifying the mineralized domains resulting from the mineralization process. This step requires a geometric interpretation of all relevant geological features that have influenced the spatial distribution of the mineralization including dykes, faults and alteration. In addition, a geologic reference system rather than a standard Cartesian system is established to measure distances between samples. Once the mineralized domains are established and the database has been validated, statistical and spatial description of the mineralized samples are examined in order to establish the histogram and the variogram of all variables of interest and their correlation. Results are also used to calibrate the global resource estimate within the mineralized domain and to establish the search strategy for grade interpolation. The mineral envelope is filled with polyhedral cells representing mining blocks. The average grade of these blocks is estimated using kriging techniques in order to eliminate global bias and to minimize the local error in the block grade estimate. Visual checks are made to validate the spatial trends in grade distribution while global bias and smoothing effect are assessed from the declustered sample statistics. When required, smoothing correction may be applied using ?change of support? techniques. Simulations are used to perform sensitivity analysis and the simulation models are used if severe smoothing of spatial variability makes the interpolated model inappropriate for mine planning. The keys to successful resource estimation are an integrated team of geologists, geophysicists, geostatisticians and mine engineers using the best available technology and reviews by independent auditors. The resource team is also responsible for performing a QA/QC program in order to measure the effectiveness of the methods in meeting the specific objectives at each step of the modelling process.

May 1, 2001

"This paper discusses the use of risk assessment and risk management techniques within the Australian underground coal mining industry, within the context of geotechnical risk. The industry works within a pro-active, “enabling” legislative framework, where companies and management apply a range of risk assessment tools as part of their everyday management processes. Different geotechnical risk factors and approaches are reviewed, together with application examples – ranging from mine planning and design, operations, and accident investigations.A particularly powerful resource in each of the above stages of geotechnical management is the RISKGATE system. RISKGATE is an assembled “body of knowledge” structured under different topics across the Australian coal industry, of which three topic areas address rock mechanics issues for both the underground and surface mining sector. This paper will provide an overview of RISKGATE in the context of risk-based rock mechanics applications in underground coal mining."

Jan 1, 2015

By E. Ghali, W. Zhang, C. Su, N. Sorour, G. Houlachi

"Zinc electrowinning process is sensitive to the presence of metallic impurities such as lead ions that could substantially and negatively affect the power consumption and surface morphology. Effect of various concentrations of manganese ions and traces of lead ions up to 2.5 mg L-1 added to the electrolyte during electrowinning have been investigated by electrochemical polarization techniques such as galvanostatic, cyclic voltammetry and potentiodynamic. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to examine the surface morphology and crystallographic orientation, respectively. Microwave plasma-atomic emission spectrometry has been used to determine the lead content in the deposit and in the electrolyte after electrodeposition. It was found that lead ions added to the zinc electrolyte led to the increase of cathodic overpotential and current efficiencies of zinc deposit. However, addition of Mn2+ into the zinc electrolyte resulted in the decrease of cathodic potential and current efficiency of zinc deposit. It can be stated as example that galvanostatic polarisation at 40?C and 52.5 mA cm-2 in presence of lead up to 0.1-0.2 mg L-1 in the electrolyte and 8-12 g L-1 Mn could be better considered as practical working parameters for electrowinning process.INTRODUCTIONApproximately 85% of the global production of zinc metal is produced by electrolytic process (Sinclair, 2005). The main goal of the zinc plant is to obtain pure zinc deposits with high current efficiencies. Smooth and pure deposits with high current efficiency (CE) are always obtained from pure electrolytes (Alfantazi & Dreisinger, 2001). The presence of metallic impurities in the zinc sulphate electrolyte is a major problem for the zinc electrowinning industry, since decreases in current efficiency, changes in deposit morphology and cathodic polarization are observed for electrolytes containing small concentrations of impurities (Ault & Frazer, 1988; Muresan, Maurin, Oniciu & Gaga, 1996). Low level concentrations as parts per million of these impurities are reported to influence negatively the zinc electrodeposition (Beshore, Flori, Schade & O'Keefe, 1987)."

Jan 1, 2016

By G. Agar

"E. Joe We have been working for some years on the elimination ofCANMET thiosulphates from solutions as a means of protecting ground water and fish streams. Alot of these thiosulphates result from the mill use of S02. Is there any possibility that thiosulphates will be generated by this process?Reply I don't know the answer to your question. I can speculate that there is no question that when one adds SO2 and air to a sulphide pulp one generates a host of unsaturated poly¬cyanates. I unfortunately cannot remember the reactions which arise in the cyanide destruction scheme. I think that if thiosulphate was generated the process wouldn't work. It is not oxidizing enough to destroy the cyanide.R. Wagner Would you comment on the actual cost/ton at the Scottie goldPamour mine concentrator? Would $2.50/ton be typical or is thisPorcupine just a ball park figure.Reply We wouldn't disclose Scottie's costs even if we knew them. I depends on the amount of cyanide and thiocyanate in the effluent. I have given you a hypothetical case. With the conditions stipulated the figures I Have given are realistic.K. Konigsmann I do not believe the use of S02 adds significantly to the thio Noranda Mines salt problem Certainly we use SO2 in many of our mills and thio-salt levels in a number of them haven't changed whether we use or don't use S02. For instance, Orchan and Matagami mills treating the same ore side by side in which one was using S02 and the other wasn't, the thio-salt level was virtually the same in both pulp streams. In the case of Brunswick where alot of SO2 is used (20 tons/day) there is a thio-salt problem but it is relatively insignificant.Reply Thank you for that comment. It serves to reassure us that we are not polluting the environment."

Jan 1, 1984