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By Richard Klimpel

"Over the last 15 years, there has been a number of plant scale sulfide mineral flotation tests organized by this author specifically aimed at understanding how flotation rate varies with reagent type and dosage. With regard to the Interaction of collector dosage, particle size, and frother type, the eight specific trends listed in the paper (Illustrated with data from two specific case studies) are qualitatively the same for almost all plants studied in some depth. The Interaction of flotation rate K and equilibrium (Infinite time) recovery R in the plant has been denoted as the R/K trade-off. The effect of collector dosage on the rate of flotation of specific particle size intervals is particularly interesting and once understood, is quite useful In understanding how industrial flotation plants respond to changing reagent type and dosage. The location and magnitude of the R/K trade-off can be different for various ores and various plant configurations, but the RIK trade-off is almost always present. The purpose of this paper is to clearly describe and illustrate the nature of this very Important flotation system Interaction so that operating engineers have a starting reference point for beginning successful plant Improvement studiesIntroductionIt is well recognized by industrial froth flotation plant operators that improving existing sulfide circuit performance is often difficult due to the self-compensating systems nature of the froth flotation system, e.g. Klimpel (1988, 1989, 1995). Extensive plant testing with existing and new reagents by this author throughout the world has clearly shown that one of the more important self-compensating mechanisms is the Interaction between collector dosage, frother type, and particle size. The term self-compensation in flotation simply means that as the plant operator consistently changes one parameter in the same direction, the nature of the froth flotation system Is such that the circuit will eventually begin to resist this controlled parameter change by automatic (uncontrolled) changes In other parameters and the overall circuit performance will go through a maximum or minimum (hence causing the operator to stop the parameter change)."

Jan 1, 1997

By W. J. S. Craigen, G. E. Wittur

"In the context of today's continuously changing world, there are many factors which must be considered when attempting to assess the ability of Canada's primary copper producers to remain competitive in the face of increasing competition in world markets. In this paper, we have attempted to document those factors that will have the greatest impact on the future viability of Canada's copper industry, and to suggest possible strategies to fully utilize whatever inherent advantages Canada may have to enhance its competitive position. Technological factors related to the efficiency of precious and by-product metals recovery, energy type and utilization efficiency, production and sale of sulphur by-products, and control of 502 emissions are given high priority in this evaluation of Canada's future needs to remain competitive. Particular emphasis is placed on assessing the relative viability of hydrometallurgical versus pyrometallurgical processes for copper; to address uniquely Canadian conditions and problems. Due consideration is also given to the economic incentives required to allow Canada's copper producers to compete under anticipated world market conditions and to facilitate the continued development of Canada's copper resources. IntroductionWhen we try to assess the viability or competitiveness of any industry the bottom line is still usually, ""Can we produce a pound of product cheaper than the competition?"" Canada's copper industry is certainly no exception. However, as with most resource-based industries dependent upon exports, there are many factors which have a significant effect on the cost components which make up the total cost of producing and selling a pound of copper. It is desirable therefore to have as clear a picture as possible of the cost components, the major factors affecting them, and how they compare with the competition, particularly the third-world copper producers.In this paper we have attempted to provide a brief outlook for world copper markets and a brief overview of Canada's competitive position. We have also attempted to document those factors which will have the greatest impact on future production costs, and have suggested possible initiatives to utilize inherent Canadian advantages to enhance our competitive position. Special emphasis has been placed on technological initiatives designed to make full use of these ""advantages"", to develop superior beneficiation and extraction! refining technologies. Major factors considered in the present study are:"

Jan 1, 1986

By Jose R. Hernandez-Aguilar

"Three models to predict the effect of bubble size (Db) on metallurgical response were tested in a pilot-scale flotation column at Teck Highland Valley Copper mine. The column was fed with slurry collected from the Cu/Mo separation circuit. The first model was the one developed by Gorain et al. (1997), which assumes that the collection zone rate constant (kc) is inversely proportional to Db. The second model was the one proposed by Hernandez-Aguilar et al. (2010), which considers kc as an inverse square function of Db. The third model was the one developed by Yoon and Luttrell (1989) which provides expressions to describe the efficiency of particle collection (E) based on first principles. The results showed a significant bias between experimental and predicted data using the model of Gorain et al. (1997), possibly reflecting the model’s inability to explain the impact of bubble size, bubble rise velocity and flow regime on E. The model of Hernandez-Aguilar et al. (2010) well described the experimental evidence. The model of Yoon and Luttrell gave accurate and unbiased predictions. However, Yoon and Luttrell’s approach calls for a criterion to determine whether the flow regime is potential or intermediate, a subject that requires more fundamental research.INTRODUCTIONParticle collection, i.e., bubble-particle collision followed by attachment, is the basis of flotation. In a quiescent environment (such as the one observed in a column, or away from the impeller in a mechanical cell), a collision event can take place as long as the “degree of turbulence” caused by the rising bubble does not prevent particle and bubble to flow in close proximity. Upon collision, the particle slides on the bubble surface for a period of time. If the particle is hydrophobic, attachment occurs when the “sliding time” is longer than the “induction time”, which is the time required to thin and rupture the intervening liquid (usually water) film forming a three-phase contact angle. While the induction time is largely influenced by the degree of hydrophobicity of the particle, the degree of turbulence is governed by the bubble size. Generally, direct control of bubble size is not exercised by most mineral processing practitioners, in spite of its obvious importance. Studies to model the effect of bubble size on particle collection using fundamental approaches have been conducted (e.g., Anfruns and Kitchener, 1977; Webber and Paddock, 1983; Yoon and Luttrell, 1989; Dai et al., 1999). However, these models have been validated under highly idealized laboratory conditions (micro-scale experiments using single minerals and uni-sized bubbles), far from resembling those existing in practical industrial applications. Fundamental studies to interpret the effect of bubble size on particle collection in industrial environments are largely absent in the literature. Partly because of this lack of practical knowledge, many mineral processing practitioners perceive laboratory “bubble size” studies to be valuable academic exercises, but not something that can be directly applied to daily production issues."

Jan 1, 2011

By D. Fodor

In Romania, there are significant lignite and brown coal reserves hosted by different regions of the country. The most important lignite bearing zone of the country situated in the North ? West part of Oltenia region and which covers a surface area of 2,500 km2 and host a total reserve of 3.0 billion tons of lignite, of which more than 95% can be exploited by open cast method. The paper deals with the existing geological and mining conditions of the zone , the distribution by mining basins and exploitation perimeters, the open cast working technologies and the economic outcomes obtained throughout the time. Years ago, for the improvement of the economic situation as a whole and in each unit, a large production reorganization, technology update and modernization process was started up. There are described the rehabilitation measures of the technological lines and modernization of the equipments of the production flow-sheet, measures developed at present, too and which will still continue in future. There are mentioned the equipments considered, the components under modernization and the economic outcomes obtained so far. At the end of the paper there are presented the future actions for the equipment modernization and perspectives of the lignite deposit exploitation to meet the national economy requirements of solid fuels.

Aug 1, 2013

By N. W. Byrne

THE study of diamond drill results at the Lake Athabaska property of Athona Mines, Limited, and the co-ordination of information secured, has demanded extensive application of methods for interpreting true conditions, both structurally and from the point of view of ore outlook. This work was in charge of a capable engineer, who, as the result of exhaustive study of the drill cores, has been able to issue maps and plans exceeding the expectations of the majority of engineers and geologists who visited the field during the past summer (1935); that is, having in view the fact that staking of the property had been completed but a few months beforehand and that geological conditions were practically unknown up to the time drilling began in April. The following pages present an outline of the work of the assay and engineering offices in co-ordinating and interpreting the results of the drilling. The writer desires to acknowledge the suggestions offered by A.P. Beavan, geologist and engineer at Athona Mines, whom he assisted during the drilling campaign, and also the co-operation of the drilling contractor's employees. The geological map, mine plans, and forms accompanying the paper are from the Company's engineering office files.

Jan 1, 1937

By Shen Zhengchang, Dong Ganguo, Chen Dong, Zhang Ming

"It is advantageous to process low grade ores with large scale flotation cells. Large-scale flotation cells have been enhanced with effective volume scale-up. In this paper, the latest and largest flotation cell with effective volume of 680 m3 in China is investigated. The hydrodynamics and flotation kinetics characteristics are conducted using CFD simulation. The similar circulating flow is formed compared to the previous BGRIMM (Beijing General Research Institute of Mining and Metallurgy) flotation cell and it is a suitable fluid dynamics environment. It is demonstrated that the flotation cell produces good gas dispersion and solid suspension. It is indicated that kinetic eddy dissipation plays a key role on collision kernel and collision probability profile. The higher collision probability profile appears at the impeller and stator regions aiding good metallurgical performances. The properties of the large-scale flotation cell are assessed using hydrodynamic numbers. The variation of hydrodynamic numbers such as the power number Np, the Froude number Fr, the air flow number Na, etc with flotation cell volumes show similar properties to previous flotation cells proven to be good in engineering applications. This research would aid structure optimization of the 680 m3 flotation cell.INTRODUCTIONFroth flotation is one of the mains method used in the mineral industry, which is used to process the most of metallic minerals. The proportion of low grade ores has increased with the minerals exploited around world. The increased capacity of concentrators demands large-scale flotation cells. Therefore, flotation equipment has seen a significant increase in size, for which large-scale flotation cells have prominent advantages in improving metallurgical performances, reducing area of plant blueprint printer, lowering the power consumption of the unit ore, decreasing labor cost and overall capital cost. Since the end of 1940’s, flotation cell sizes have continuously increased. To the end of 1990’s, flotation cells with the effective volume of 200 m3 were developed. In the last two decades, flotation cells have achieved a dramatic increase in size. In 2003, an industrial experiment on 257 m3 Smart Cell flotation cells was carried out in Minera Los-Pelambres, Chile. In 2007, the first 300 m3 Tank Cell flotation cell was designed and obtained industrial application in Macraes gold ore, New Zealand. And 320 m3 BGRIMM flotation cells are also in good operation in Toromocho Copper Mine, Peru and Wunugetushan Copper Mine, China. However, flotation cells are conventionally designed using empirically derived relations and geometric similarity. The continual scale-up of flotation cells is still a significant developing process. A 500 m3 Tank Cell was designed for the industrial experiment in Finland and a 620 m3 Tank Cell have also been completed the design. A 660 m3 Super Cell also was manufactured for the industrial experiment released in IMPC 2014. So, the flotation cells with volume exceeding 600 m3 become a pioneering research field for researchers worldwide."

Jan 1, 2016

By J. G. Ross

IN the paper entitled Block Caving at the King Mine (1), which was presented at the Annual General Meeting held in April, 1934, at Quebec, it was pointed out that, owing to certain conditions and financial restrictions, it was advisable to provide a temporary shaft. This was raised from the )00-ft. level to the bottom of the pit, and a 45-degree incline track was constructed up the face of the pit to surface. The temporary shaft and incline were within the ore-body, but were to be used only until such time as the new shaft-the subject of this paper-could be sunk and made ready for operation. After a careful study had been made of all available information pertaining to the ore-body, including examination of diamond-drill core records and geological data, a shaft location was selected well outside the ore-body. Further, since the crusher and dryer buildings are located over part of the ore-body, it was necessary to plan the removal of these buildings and to construct a new crushing and drying plant. This, and the new shaft, must operate in conjunction with the present mill and rock storage bin, which would continue robe used as formerly. No part of this programme, with the exception of drifting toward the shaft site, was started prior to 1937. More than usual detail on technical features is given in this paper in the hope that some parts of it may be of assistance to other members of the Institute who have to undertake somewhat similar work. The engineering and operating staff designed and supervised the work, while at the same time carrying on regular production in four mines at the rate of 12,000 tons of rock mined per day, the output at the King mine being at the rate of 140 tons per hour. No additional engineers were required.

Jan 1, 1939

By L. B. Hale

"Introduction This paper will discuss the current operations of Westar Mining Ltd. and give a brief history of the company and of the Crowsnest Pass area. Westar is an integrated company involved in mining, processing and marketing coal from its mines in southeastern British Columbia and shipping coal from Westshore Terminals at Roberts Bank, located just south of Vancouver, B.C. It is two-thirds owned by the B.C. Resources Investment Corporation and one-third owned by the Mitsubishi Corporation of Japan and a consortium of Japanese coal consumers. Operations in southeast British Columbia consist of four coal mines and two processing facilities (Fig. 1). The Elkview Coal Processing Plant near Sparwood, B.C. receives its raw coal from Balmer operations (Harmer open pit), Balmer South (Panel 6) an underground hydraulic mine, and Balmer North an underground room-and-pillar mine. The fourth mine, Greenhills, an open-pit operation, is located near Elkford, B.C. and has its own processing plant. The Balmer mining and processing complex is the largest metallurgical coal facility in Canada producing up to 7 .5 million tonnes of clean coal per year. The Greenhills operation, completed in mid-1983, has a capacity of 2.8 million tonnes. The high-grade metallurgical and thermal coal produced is primarily for export markets. The major customers are Japan, Korea, Brazil, Pakistan, Chile and Taiwan.Our coal and that produced by other mines in Alberta and British Columbia is shipped to the international markets through Westshore Terminals Ltd., a wholly-owned subsidiary. Westshore will have an annual capacity of 22 million tonnes of coal and accommodate ships of up to 250,000 dead weight tonnes by 1984 when its current expansion program is completed."

Jan 1, 1985

By P. West-Sells, B. Wassink, N. Fisher

Gold leaching from a commercial cyanide-amenable gold ore was studied at 25°C using sodium bisulfide-hydrogen sulfide solutions containing elemental sulfur. Gold extraction from the ore using 0.55 M NaSH, 4.1 atm (60 PSI) H2S, 1 g/L S8 and 26% solids by weight was about as good as the best extraction obtained by cyanidation. Maximum extraction was achieved in roughly 48 hours. Sulfur dissolves in the bisulfide solutions to form a mixture of polysulfides. Simple speciation calculations indicate that gold solubility as bisulfide complexes should be roughly ten times higher than in the absence of added zerovalent sulfur. The principal bisulfide complex is believed to be [Au(HS)2]-. Gold dissolution is favoured by increasing HS- concentration and by increasing H25 pressure. Polysulfide complexes of gold are also likely to be formed, and may contribute substantially to gold leaching. Two experiments using pure gold were also performed. Up to 100 mg/L gold was dissolved in 140 hours using 0.55 M NaSH, 1 g/L added elemental sulfur and 6.2 atm H2S.

Jan 1, 2005

By J. B. Gilliatt

The discovery of ore at Wabana was quickly followed by the mining of the ore beds where they outcropped in the land areas. The third phase, as at present carried out, consists of extensive submarine operations, which were commenced in 1908, by driving a pair of slopes out under Conception bay, opening. the mine for a distance of a mile and a half from the shore. Two other slopes, now driven just beyond the shore line, are being sunk to the submarine territory where, it is generally recognized, huge reserves of ore lie under the bay. The process of erosion of the land, the solution and re-disposition of its iron-bearing minerals in thick beds of ore have been considered elsewhere, but these bear small relation to the physical forces which have acted upon the ore-beds since the deposition of the strata. These physical changes are made manifest by jointing and cleavage and faulting. The discussion of these, the relation they bear to each other, and to the folding of the strata, is the purpose of this article. For the benefit of those who may not be familiar with the formation in which the ore occurs, I include a general summary of the geology of Be!! island and its environs; also a description of conditions that prevailed during the period of deposition, so that the reader may appreciate some of the later changes that took place during or subsequent to its emergence from the sea, and the folding or tilting of the strata to the position it now occupies.

Jan 1, 1924

By N. M. Soonawala

Detailed regional geophysical and geochemical surveys, ground surveys and drilling were undertaken to follow-up the federal-provincial Uranium Reconnaissance Program (URP) over the 27,OOO-km2 Kasmere-Munroe area in northwestern Manitoba. An analysis of the URP data showed a fair correlation between the regional airborne radiometric results and lake-bottom geochemical results, both of which also correlated with the regional geology. More detailed surveys defined anomalies with greater precision within the broad zones outlined by the URP. The ground follow-up indicated that URP anomalies can be caused by varying degrees of uranium concentration in the rocks. Mineralization of interest was found in leucogranites at several locations within the survey area. Anomalous uranium concentrations were also found in coarse pegmatites and Hudsonian granitic intrusions. It can be concluded that large-scale regional surveys can be followed up in relatively short periods of time to yield meaningful results if a properly planned exploration sequence is employed, each stage of which successively narrows the area of interest.

Jan 1, 1979

By A. G. Spencer

"The horsepower required to drive large grinding mills has increased dramatically during the past ten years. Limitations on the amount of power which may be transmitted by a single gear and pinion have resulted in the application of multimotor drives, with consequent loadsharing problems. It has also sparked the development of some entirely new drive concepts. In addition, the severe demands made upon the electrical system during the acceleration period have required that the selection of motors and electrical system design be closely coordinated. Moreover, the installation of such large process units results in downtime being very costly. The equipment selected and the plant maintenance philosophy must therefore be such as to minimize the risk of unscheduled downtime."

Jan 1, 1972

By D. K. Matlock, D. J. Hamre, J. G. Speer

Ultrafine ferrite (UFF) grains may be produced in surface layers of plate steels using controlled intermediate cooling followed by deformation. Experiments were conducted using a 0.12 C - 1.26 Mn steel on a Gleeble 1500 hot deformation simulator. Taguchi designed experiments were used to evaluate prior austenite grain size, intermediate cooling rate, intermediate cooling temperature, intermediate hold time and amount of reduction in order to observe the effects of variables and their interactions on the final microstructure while minimizing the number of required test runs. Evaluation of resulting microstructures and mechanical properties revealed a preferred thermal and mechanical history for developing ultrafine microstructures in surface layers of plate steels. Application of the fundamental concepts of phase transformations to industrial plate rolling is considered.

Jan 1, 2004

By S. Constantinides

"A major use for many of the rare earths is in permanent magnets. While alternate technologies are in research or already exist, rare earth magnets are unlikely to be supplanted as a major input to clean technologies and high efficiency consumer and industrial devices. We’ll examine where and how the magnet rare earths are utilized and the size of the market. Market growth forecasts based on global markets will be presented. A brief explanation of materials research in the US completes the material.INTRODUCTIONRare earth magnets, first commercialized c.1969, have become essential for a wide range of consumer, industrial and military devices. They are used in the speakers and vibrator motors of cell phones. Rare earth magnets spin the hard discs within the drives and rare earth magnet voice coil motors position the read/write head over the spinning platter. Rare earth magnets are the heart of motors and generators used on airplanes – they are smaller and lighter weight than alternative materials/devices. Now rare earth permanent magnets are being introduced into electric vehicles and wind power generation.Rare earth minerals are difficult to extract from the ores and to separate from one another. The increase in use of rare earth magnets has placed a severe strain on established sources of supply. The establishment of new mines and processing facilities is costly and requires upwards of 15 years to become productive. The combination of rapid rise in use of rare earth minerals coupled with supply shortages has caused rapid price increases and threat of non-delivery of product. The result of this disruptive situation has been a profound response at several levels: corporate, industry-wide and governmental. Let’s learn more about why rare earth magnets are so important to modern society."

Jan 1, 2012

By S. Banisi, J. Marois, A. R. Laplante

"This paper compares the behaviour of gold and ore in the grinding circuit of Hemlo Gold Ltd. Particular attention is given to grinding kinetics, classification behaviour, and liberation. For grinding kinetics, laboratory grinding of gold flakes and silica, 840-1200 um in size (14/20 mesh), was also performed to provide a standard for comparison and to study in a controlled environment the mechanisms of breakage, folding, smearing and impacting.Grinding kinetics were characterized at laboratory scale with breakage and selection functions. The breakage function showed that 75% of gold disappearing from the 840-1200 um class reported to the 600-840 um; this figure is much higher than for silica ( 46%) or most other minerals, and implies that comparatively fewer fine fragments are produced from the breakage of gold flakes, on account of gold's malleability. The selection function of silica was four times that of gold. At plant scale, the ratio of the selection function of ore and gold increased from 6 for at 50-100 um to 20 at 500-1000 um.Observation of original flakes and their fragments with the scanning electron microscope showed that the main mechanism of ""grinding"" from the 840-1200 um to the 600-840 um class was folding rather than actual breakage. This was confirmed by a measure of individual flake weight. The postulated breakage cycle is that relatively globular flakes become increasingly serrated through grinding; they can then regain their original shape through folding and reflattening into cylindrical and spherical shapes, as the majority does; however, some fragments will at this point undergo actual breakage. Photographic evidence is presented to support the proposed mechanisms.Smearing of gold unto silica was observed when silica was ground after a gold, and embedding of silica into gold flakes when gold was ground after a silica. Both mechanisms occur whenever gold and harder minerals are jointly ground, and result in ""unliberation"" of gold. It is postulated that smearing of gold onto other minerals plays an important role in explaining how gravity recovery can increase overall gold metallurgy, especially when used ahead of flotation.Classification of gold in the primary hydrocyclones takes place at a much finer cut-size than ore, 20 vs. 57 um. This and the slower grinding kinetics result in high gold circulating loads in the primary loop, 6700%, and a gold content in the primary cyclone underflow (PCUF) is twenty four times that of the ore. The gold size distribution for primary cyclone overflow is much finer than that of the ore, although they are essentially similar in the PCUF.Liberation, or more accurately ""gravity recoverability"", was assessed with a 7.5 cm (3"") Knelson concentrator. It varied between the thirties for the primary mill discharge and two cyclone overflows, to highs of 89 to 92% for the PCUF and secondary mill discharge, 89 and 92%, respectfully."

Jan 1, 1991

By T. Beamish, I. Vasilev, T. Nikolov, E. Marinov, D. Kirilov, P. Barrios

In April 2005, Umicore Copper de-merged from Umicore Group and created a new independent Copper company called Cumerio. As a separate company, Cumerio is a major European copper smelter and refinery and a leading producer of copper products such as wire rod, billets, cakes and specialty rod with a total production capacity of copper products in excess of 500,000 tpy with production plants in Belgium, Italy and Bulgaria. The Pirdop Smelter is the only state-of the-art smelter in South East Europe and it makes Pirdop the natural hub for the copper industry in the region. In order to be competitive in the international market the main challenges facing Cumerio are to maintain its low cost structure and to achieve higher production volumes while reducing its impact to the environment and striving for continuous improvement of the production process. Cumerio's state-of-the-art smelting facility in Pirdop has recently increased the anode production capacity to 250,000 tpy by the installation of the third evaporative cooler on the converters section that allows operating with three-hot converters. In April 2007 a general shut-down for repair and modification on the Flash Smelting Furnace and Waste Heat Boiler is envisaged. At this time a revamp of one of the existing Sulphuric Acid Plants is planned, resulting in a further copper capacity increase to 275,000 tpy with modest Capex. In 2005 Cumerio received from the Bulgarian Ministry of Environment and Water the Complex Permit under the EU IPPC criteria. Accordingly an Environmental Compliance Program was defined targeting a large reduction in the secondary emissions. The system will be commissioned in May 2007. In order to better integrate the smelter and refinery in Pirdop and to respond to the growing demand for cathodes in the region, a new state-of-the-art Electrolytic Refinery with an installed capacity of 180,000 tpy will replace the existing refinery. The new refinery is expected to be fully operational as from early 2008. This paper describes the challenges and the projects.

Jan 1, 2007

Leadership "Organizing a group of people to achieve a common goal" Paradigms ? Rush to produce or cut costs. ? The most important thing after safety is production. ? We?ll take care of ??this?? once in production. ? I know what to do, 30 years of experience in mining. ? I want a 100% reliable operation.

Aug 1, 2013

By A. Dogan Paktunc

Abstract - The Mechanic Settlement pluton is a small body of mafic and ultramafic rocks of tholeiitic affinity, occurring in the Late Neoproterozoic volcanosedimentary rocks of the Avalon terrane of the Appalachian Orogen. The lenticular-shaped intrusion is layered and consists of ultramafic and mafic lithologies in at least six cyclic units that are relatively thin or short-lived. The lowermost exposed portion of the intrusion is characterized by the cumulate sequences of olivine and olivineclinopyroxene and display relatively flat rare earth element profiles. In the overlying lithologies, plagioclase is the dominant cumulus phase following olivine in the crystallization sequence. Olivine ranges in composition from Fo73 to Fo85 and plagioclase from An62 to An89. Variations in the compositions of orthopyroxene and clinopyroxene are within Wo0-4En52-87Fs11-45 and Wo39-50En23-50Fs3-19. These mineral compositional variations in part reflect cryptic patterns and correspond to normal fractionation trends in cyclic units. Elevated Pt and Pd concentrations of up to 2.6 ppm occur in ten zones within the central cyclic series in association with both the peridotitic and gabbronoritic rock types. The mineralized zones are about several meters thick and appear to have lateral continuities over several hundred meters, suggesting that they are stratiform. Platinum-group elements (PGE) occur as discrete platinum-group minerals (PGM) including vysotskite, merenskyite, michenerite, sperrylite, stillwaterite, and hollingworthite that are associated with magmatic sulfides composed of pentlandite, pyrrhotite, and chalcopyrite. PGM grains range in size from a few micrometers to well above 20 µm. Sulfur isotope ratios and the Se/S ratios of the mineralized rocks are typically higher than the mantle values. Sulfide saturation probably occurred as a result of assimilation of crustal rocks and magma mixing during emplacement of subsequent pulses of magma. Repetition of the PGE mineralization in rather thin cyclic units suggests that the replenishing magma probably had high PGE levels and was saturated with respect to sulfide during emplacement. Ingression of the replenishing magma into the chamber in a turbulent plume and its mixing with the resident magma was probably responsible for the formation of the PGE mineralizations in the Mechanic Settlement pluton.

Jan 1, 2000

Increasing depths and mechanization of underground mines have led to the production of large amounts of gaseous and particulate contaminants. Over 100 000 lives have been lost due to methane gas and dust explosions in coal mine workings in both the United States and Canada since 1900. There is, therefore, the need to constantly assess and evaluate the performance of existing mine ventilation systems to maintain safe and acceptable mine environmental conditions. This paper advances research initiatives in the control of methane gas in underground mine environments. It uses the results of continuous monitoring of methane gas concentrations conducted in selected coal mines in North America to assess the effectiveness of existing auxiliary ventilation systems to control methane gas concentrations. The results show that the average quantities of fresh air required to dilute, disperse and remove methane gas concentrations within set levels of one minute varied from 5.43 m3/sec. to 27.97 m3/sec. in the development headings. The average dilution times in the headings studied were less than eight minutes. The calculated dilution efficiencies of the auxiliary ventilation systems in the headings varied from 12% to 139%. These efficiencies ranged from poor to excellent. This implies that the auxiliary ventilation systems were capable of controlling the methane gas concentrations below statutory levels but may not be able to cope with large and unusual methane gas concentrations in the headings. This study is significant in the control of methane gas and coal dust explosions in coal mines.

Sep 1, 2001

By Benedetto Corain

The production and dispersion of metal nanoclusters onto inorganic supports and amorphous carbon rest on well consolidated technologies belonging to the realm of industrial catalysis and of basic catalysis research (1). In spite of the existence of a variety of specific synthetic strategies, their very rationale relies on three main approaches i. e.: A: precursors of both the metal nanoparticles and of the relevant supports (or the support itself) are intimately mixed (even let to react) at ambient conditions and then thermo-reduced according to very controlled protocols (2); B: precursors of metal nanoclusters are let to be adsorbed onto suitable supports from the gas or liquid phase and subsequently thermally decomposed (3); C: metastable size-controlled metal nanoclusters are previously generated in a liquid medium and subsequently transferred onto pre-formed support particles (4). The production and dispersion of metal nanoclusters onto organic soluble supports is also a rather well documented academic praxis (5, 6, 7, 8) able to provide e.g. size-controlled Au0 nanoclusters of 4.4±1.7 nm (5). Our group started in 1997 developing (9) an innovative approach to the synthesis of metal nanoclusters dispersed inside insoluble, albeit accessible (see below) mechanically robust gel-type resins (10), which procedure was tested so far on palladium metal. Metal ions are previously dispersed upon ion-exchange inside of the polymer framework, followed by chemical reduction and by the aggregation of born metal atoms into nanoclusters, the size of which is templated (11, 12) by the three-dimensional intercommunicating meshes that build up the overall polymer framework (Figure 1).

Oct 1, 2003