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By A M. Robertson, R Lefebvre

Air movement and associated oxygen transport through waste rock dumps has the potential to significantly enhance the rate of oxidation of pyrite-bearing material. While this is a desired outcome for most heap leach operations, airflow in waste rock storage facilities can result in significant increases in generation and acceleration of acid rock drainage. Hence, a good understanding of internal airflow through waste rock dumps is required to control ARD and minimise any associated liability. The principal mechanisms contributing to airflow and oxygen transport in a waste rock pile include: diffusion; advection due to a thermal gradient (chimney effect) and/or wind pressure gradients; and advection due to barometric pumping. While diffusion is typically limited to a near-surface zone of a few meters depth, advection and barometric pumping have the potential to move air (and oxygen) to much greater depths into the pile. In general, the more permeable the waste rock material, and the greater the height-to-width ratio of the waste rock pile, the greater is the potential for advective air movement. The reactivity of the waste rock material as well as the coarseness (hence air permeability), and the spatial variability of these properties within a pile, have a strong influence on the magnitude of thermally induced advection. In contrast, air movement due to barometric pumping is controlled by the waste rock porosity, changes in ambient air pressure and the heterogeneity of air permeability of the waste rock dump. Results of field monitoring and numerical modelling using TOUGH AMD are presented to illustrate the concepts on air movement in waste rock piles discussed in this paper. During the design and construction phase, airflow can be controlled by judicious placement of reactive waste rock and use of selective placement techniques to control the internal structure of the waste rock facility (eg introduction of horizontal layering, prevention of inclined, high-permeability, channels (æchimneysÆ)). Several closure measures are available to minimise airflow including: placement of a low-permeability cover to reduce air entry; and placement of a non-reactive cover material to isolate reactive material from the zone of active airflow and/or regrading of the waste rock pile to obtain a geometry and internal structure less susceptible to advective airflow.

Jan 1, 2003

By M Biesinger, R St C Smart

Diagnosis of the surface chemical factors playing a part in flotation separation of a value sulfide phase requires measurement of the hydrophobic and hydrophilic species that are statistically different between the concentrate and tail streams. Statistical methods, based on the monolayer-sensitive time of flight secondary ion mass spectrometry (ToF-SIMS) technique, have been developed towards this ultimate aim by measuring hydrophobic species (collector ions, dimers and metal complexes, polysulfides) as well as hydrophobic metal ions, precipitates and added depressant species. Reliable identification of specific mineral particles is central to this statistical analysis. A chalcopyrite/pyrite/ sphalerite mineral mixture conditioned at pH 9 for 20 minutes to study transfer of Cu from chalcopyrite via solution to the other two mineral surfaces, since this mechanism can be responsible for their inadvertent flotation in copper recovery, showed no statistical difference in the copper intensities on pyrite and sphalerite (selected from Fe and Zn images) after this conditioning. Principal component analysis (PCA) identifies combinations of factors strongly correlated (positively or negatively) in images or spectra from sets of data. In images, PCA selects these correlations from the mass spectra recorded at each of 256 ¦ 256 pixels in a selected area of particles. In the image mode, PCA has proved to be a much better method of selecting particles by mineral phase with clearer definition of particle boundaries due to multi-variable recognition. It has clearly separated a statistical difference in copper intensities between the sphalerite and pyrite phases. The PCA method has been applied to concentrate and tails samples collected from the Inco Matte Concentrator demonstrating extensive CuOH and NiOH transfer between the chalcocite (Cc) and heazlewoodite (Hz) minerals. Statistical differences illustrate the important discriminating depressant action of NiOH in flotation despite the activation of Hz by Cu transfer. The adsorption of the collector at specifically-identified Cu sites has been elucidated by the study. Importantly, the statistical analysis has been able to confirm some mechanisms and deny others proposed to control recovery and selectivity giving more focus on the control factors.

Jan 1, 2005

By D Lau

Traditionally X-ray diffraction (XRD) has not been significantly used by the cultural heritage sector, as the most commonly used technique, X-ray powder diffraction (XRPD), requires sample removal from the artwork or artefact, followed by grinding of the sample to a fine powder. With the development of micro-X-ray diffraction (micro-XRD) and other associated advances, non-destructive, in situ analysis of crystalline pigments on micro-areas of paintings and artefacts has become possible. This is illustrated with the application of this technique to the in situ analysis of propriety paints, paint cross-sections and small paintings. However, workers have noted that XRD can be insufficiently sensitive with pigment mixtures, due to matrix effects. This study obtained X-ray diffractograms of 17 single pigment preparations and determined relative amounts of crystalline content. The purity of single pigments was compared with Joint Committee on Powder Diffraction Standards (JCPDS) database diffractograms. The impact of pigments with high X-ray absorption coefficients on the detection limits of pigments with low X-ray absorption coefficients was further investigated by building on work done with the chromium oxide-zinc oxide series with the preparation of a second series of binary mixtures of zinc oxide (which has a high absorption coefficient and is almost fully crystalline) and ultramarine blue, which has a lower absorption coefficient but which is more crystalline. Semi-quantitative analysis, where baseline and absorption factor corrections are made, confirm detection limits as low as five per cent for chromium oxide and ultramarine blue when in a binary matrix with zinc oxide. However, this type of analysis is very time consuming. So in order to theoretically simulate issues that will be encountered with binary pigment mixtures, the single phase diffractograms were used to theoretically investigate the matrix effects of the three white pigments with the various coloured pigments. This illustrated that detection limits can be as low as five per cent or in non-ideal conditions, such as with partial peak clashes or where there are large differences in relative peak intensity, as high as 50 per cent. These results have significant implications for the analysis of painted surfaces on artworks or artefacts. It has been demonstrated that ideally this method is more suited to the investigation of surfaces where there is minimal mixing of pigments or where there is not a significant difference between the absorption coefficients of the mixed pigments.

Jan 1, 2008

By Bogar D. V

Often dewatering of coal tailings is inhibited by the presence of clays, making it difficult to obtain a high concentration, handleable coal tailings. The net result can be a low concentration, chocolate mousse-like tailings which poses significant sedimentation problems in a tailings dam and represents a significant environmental problem. This paper examines the coal tailings from a Hunter Valley colliery where the tailings properties are influenced significantly by the presence of montmorillonite clay. The influence of the calcium ion on the rheology and sedimentation/compression behaviour of coal tailings . containing montmorillonite already dispersed in water was investigated and revealed that very little improvement in the properties is achieved through the coagulation. The preliminary investigations also indicated that the properties of the tailings were dominated by the presence of the montmorillonite clay. Thus investigations were carried out on the clay alone in water. Investigations into the effect of dispersing samples of the clay alone in water and then coagulating with calcium compared with dispersing the clay directly into calcium ion solutions at the same calcium concentration showed huge improvements in the rheology, compressibility, sedimentation rates and sediment solids concentrations for the second dispersion method, which can be called controlled dispersion. The sediment volume fraction solids improved by more than a factor of two by controlling the dispersion of the clay. The reason for the improved properties lies in the suppression of the initial swelling of the clay, which is initially in the sodium form, thus maintaining the parallel orientation of the platelets that is present before wetting. While swelling is being suppressed, ion exchange occurs with the calcium which results in permanent swelling suppression. In the uncontrolled dispersion case where swelling is uninhibited, the clay is allowed to break up and despite the powerful coagulating nature of the calcium ion, the random orientation of the high aspect ratio clay platelets inhibits effective coagulation. Results indicate that the initial electrolyte concentration of the washwater in a coal washery is the critical factor controlling the dewaterability of clay tailings and the handleability of the dewatered product rather than the actual act of coagulating with the calcium ion. The results presented are of clear practical significance and indicate how coal tailings problems where clay dominates the rheology can be improved considerably by knowledge of the surface chemistry.

Jan 1, 1995

By Cairncross A. A

Papers on technical aspects of the Melbourne Underground Rail Loop project are being presented at this conference or have been presented previously or will be presented at other forums. This paper provides the framework for these papers by presenting the overall engineering tasks. The conceptual design, the special investigations undertaken, the management of the project and the construction development are highlighted.

Jan 1, 1981

By M Surtees

The Limpopo region in southern Africa is considered to be a favourable target for the discovery of base and precious metal mineral deposits. The integration of gravity, geomagnetic, LANDSAT data and geotectonic history is used to formulate an ore deposit model which can be used in the implementation of mineral exploration programmes. Field work was carried out to test and refine the model.

Jan 1, 1993

By Owen D

A central part of mine planning is to ensure the protection of the beneficial uses of water. Integrated mining software does not generally provide tools to help the mining engineer to achieve this objective. This paper identifies some of the requirements which are desirable for such a tool and discusses how object oriented modelling can help achieve an effective design.

Jan 1, 1995

By L R. B M Sß

This paper presents the results of a liberation study made on a sulfide copper ore from Carajßs, Brazil, in a mini pilot plant flotation test. The aim of the research was the methodological evaluation of a liberation study using a sample crushed at 1 mm and a sample ground for flotation testing to a target size of 80 per cent

Jan 1, 2005

The mine planning and operational aspects of applying Continuous Surface Miner (CSM) technology to Australian coal strip and open cut mines is investigated for both existing and planned deposits. CSM produc- tivity as a function of geomechanical properties, formation thickness, mechanical availability and in-pit physical constraints, are considered. Productivity and operational costs are derived from current production machines and from first principles.

Jan 1, 1989

Experience in evaluating grade control at operating mines has shown that a number of similar errors re-occur in diverse settings. These can be broadly classed as technical errors, and procedural or grade contra management errors. Examples of typical errors are presented a; generalised case studies. A brief explanation of why the recommender solution worked is also presented for each case.

Jan 1, 1993

Numerical modelling is a valuable tool for simulating the fundamental processes that take place during a heating. The models presented in this paper have enabled a quantitative assessment of the effects of initial pile temperature, pile size and mass and coal particle size on the development of a heating. All of these parameters have a certain criticality in the coal self-heating process.

Jan 1, 2005

The results from three quick methods for the determination of W03 in scheelite ore samples, mill products and concentrates were compared with gravimetric results and tested with standard samples to establish which was the most reliable. Summaries of the methods, two X-Ray fluorescence and one colorimetric, are given. The best method was X-Ray fluorescence, with samples cast as glass discs.

Jan 1, 1988

When a fire or explosion occurs underground the ventilation maybe disrupted and the atmos- phere may become oxygen deficient and filled with noxious and flammable gases. The basic survival technique for:any man alive underground is to escape and this may be achieved and rescue workers may enter such atmospheres to carry out rescue work underground by using appropriate breathing apparatus.

Jan 1, 1983

During the past seven years silver recovery has been increased from 9 per cent to over 61 per cent. The changes in plant practiee which have led to this increase are described. Gold room clean-up procedure has been varied, so that half the additional silver is obtained as pure silver chloride, which.is converted to silver bullion for marketing.

Jan 1, 1964

By I Lipton

Dilution and ore loss have an important bearing on the success of open pit mining projects. Their impacts on production costs, revenues and production rate require that they are correctly modelled in the long-term mine plan. The estimation of dilution and ore loss is therefore an essential part of any Ore Reserve estimate or mine schedule. Large open pit mines are driven by the economies of scale that are achieved at the cost of less selectivity in the discrimination of ore and waste. Planning for these mines is facilitated by the use of block models for mine design, scheduling and the conversion of Mineral Resources into Ore Reserves. This paper reviews various approaches to the estimation of dilution and ore loss, as implemented in computer block models. In the case of orebodies with well-defined sharp boundaries, rather than irregular stockwork mineralisation, the geological interpretation is a critical factor. Variability in the geometry of orebodies is common within large open pits and must be taken into account when estimating dilution and ore loss. A method of regularisation, controlled by the wireframed geological model, is demonstrated, using examples from large open pit stratiform copper and magnetite deposits. This can be carried out without special computer software modules.

Jan 1, 2007

By S Freij, P W, R Gunawan, D Zhang, B Feng

The Mt Whaleback iron ore mine is located adjacent to Newman, approximately 1200 km north of Perth, in the Pilbara District of Western Australia. Approximately 15 per cent of the waste materials are in the zones with high concentrations of sulfide and carbonaceous minerals and are referred to as æreactive shaleÆ. The reactive shale has the potential to undergo self-heating and can react with the ammonium nitrate (AN) based explosives used in mining operations, resulting in spontaneous combustion and spontaneous explosion. The sulfide-rich shales also have the potential to produce acid rock drainage (ARD). In the present study, over 200 shale samples have been collected from different locations in the Mt Whaleback iron ore mine, including blasthole drill cuttings, fresh mine faces and waste dumps. These samples have been systematically characterised for their geochemical properties. Based on the characterisation results, a pH test was developed as a cost-effective, fast and efficient tool for the assessment of reactive ground in the mining industry. This paper summarises the results of the sample characterisations and discusses the key findings arising from the interpretation of results. These results have significant implications in the safe storage of the reactive shales and the prevention of spontaneous explosion, spontaneous combustion and ARD.

Jan 1, 2005

By Andrew R. L

The Kintyre uranium deposit was discovered in 1985 in the course of following up radio- metric anomalies generated in an earlier air- borne survey. The latter survey was conducted primarily to acquire aeromagnetic data for diamond exploration and the uranium discovery was made during a subsequent campaign of base- metal exploration. CRAE commitment to the Rudall area for a range of commodities over a period of 13 years made a significant contrib- ution to the discovery of Kintyre. Other con- tributing factors included CRAE's multicommod- ity approach to exploration, management support and continuity in the geological team. The Kintyre uranium deposit (Fig. 1) is located on the northern margin of the Rudall Metamorphic Complex, 60 kilometres south of Telfer and 260 kilometres north northeast of Newman, in the Paterson Province of northern Western Australia. It is 700 metres inside the northern boundary of the Rudall River National Park (15695 sq. km) and lies between the Great Sandy Desert and the Little Sandy Desert (Beard, 1969). Intense weathering since the Permian has produced a subdued landscape around the deposit. Resistant rock types still retain an older plateau surface but it is incised by more recent streams. Other Proterozoic and Permian rocks form low, sometimes rocky, areas largely covered by aeolian sand.

Jan 1, 1988

By Lin C, Jiaxiang D

A series of experiments were carried out with Hallimond tube in order to test the effects of different reagents. A good result has been obtained when potassium-n-butyl xanthate is used as collector for molybdenite and graphite complex are depressed by the depressor mixed with nigrosine and iron (III) chloride. The separating mechanism has been studied with help of many modem instruments.

Jan 1, 1993

The Paracale gold region had been known for hundreds of years, but the first professional attempts to work the lode and alluvial deposits were made only in the 1890s by the London-based Philippines Mineral Syndicate. Complex ores, transportation problems, and the Philippine Insurrection halted operations. Ultimate success went to American firms, though Frank Karuth's Philippines Mineral Syndicate had pioneered the field.

Jan 1, 1987

INDEX OF CONTENTSIntroduction.Systems of classification of coals.RankClassification of Australian coals.Defects of systems in use in other countries.Indexing by Fuel Ratio.Classification by Ultimate Carbon/Ultimate Hydrogen.Relationship between Fuel Ratio and ultimate composition.Suggested convention for classification.Origin and Evolution.Notes on directions of change of composition on Carbon Hydrogen chart.Summary and conclusion.Acknowledgments.Bibliography.Appendix.

Jan 1, 1948