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By Basillo CI

The adsorption mechanisms of various thiol collectors can be subdivided into four classes: chemisorption, EC-mechanism, catalytic oxidation and metathetical substitution. The chemisorption mechanism occurs at potentials below the thermodynamic potentials for the metal-thiol compound formation and is reversible. The EC-mechanism occurs when the mineral is sufficiently oxidised to liberate metal ions to form metal-xanthates; therefore, it is observed with more easily oxidisable minerals and/or with collectors having large pK values. Thionocarbamates adsorb on sulphide minerals via the EC-mechanism due to their large pK values. Although the adsorption occurs at very low potentials as compared to xanthates, it is irreversible with large overpotentials. On the other hand, the adsorption of modified thiophosphates and thiophosphinates occurs near the thermodynamic potentials because of the low pK values. The metathetical substitution is believed to occur only when a mineral is highly oxidised. These classifications are useful for studying the effects of electrochemical potentials and the molecular structure on the collector adsorption Mechanisms.

Jan 1, 1993

Current attitudes by exploration companies towards working on another party's exploration permit or equivalent vary widely. That this is so is due to the virtual absence, on the one hand, of anything in the mining legislation in any jurisdiction that establishes what are the exclusive rights to explore, as opposed to apply for a mining tenement, that the grant of such an authority conveys on the holder, and on the other hand, of any code of ethics or set of guidelines to proper practise. By contrast, in most states and territories, if not all, it is an offence to enter onto a mining tenement, other than to cross it, without the consent of the holder, although until recently most field personnel would have been unaware of this and most explorers would have transgressed at one time or another. A similar vacuum exists where aerial surveys are concerned. There are in fact no guidelines. It has always been assumed that a party wishing to carry out such a survey was free to do so, without even an obligation to notify the holders of any tenements or permits in the area to be surveyed, let alone make available to them any data from the survey. Concepts of 'geophysical trespass' now being tested in the US also raise the possibility that data won from adjoining ground using geophysical techniques may be privileged. Attitudes now appear to be changing. In the absence of legislation or any code of practise, what does the industry regard as ethical behaviour? Do we need to define the rights and obligations of various parties more clearly, and if so, what should they be and to what extent will it be necessary to confirm them by legislation as opposed to adopting a code of practise? Will the existence of such a code in fact improve corporate practise?

Jan 1, 1995

By K Voigt, B Bolton, C Rumble

The Ok Tedi copper and gold mine is owned and operated by Ok Tedi Mining Limited (OTML) and is located in the Star Mountains of the Western Province of Papua New Guinea. Waste materials (both sulfidic and carbonate materials) from mining operations, comprising 55 Mt of waste rock and 31 Mt of tailings per annum, are discharged into the headwaters of mine area creeks where erosion and sediment transport carries significant proportions of the total waste into the Ok Tedi and Fly River systems. The tailings are potentially acid forming (PAF) while the waste rock has been strongly acid consuming with an excess of acid neutralising capacity (ANC) due to the high proportion of limestone waste. Tailings and waste rock are eroded into the river system and transported to the lower Ok Tedi and floodplains where deposition takes place. Because of concern due to vegetation die back, a dredging operation commenced in March 1998 to remove the sand fraction from the main river channel. OTML identified a potential future ARD risk from the stockpiled sands due to reduce limestone production at the mine and sulfide/carbonate mineral segregation in the river system and in the dredge sand stockpiles. This paper describes the structure and framework of an empirical model developed to assist OTML in planning ongoing mining operations to control ARD. Modelling identified the need to provide additional mined limestone to prevent future ARD generation from material deposited in the mine area creeks. With the additional limestone, the ARD risk in waste rock storage areas and in the Ok Tedi and Fly River sediments is predicted to remain low due to the combined effects of high ANC, high alkalinity of natural waters and high moisture contents (mostly fully water saturated). However, monitoring and modelling indicate that the ARD risk from the stockpiled sands will increase substantially during the remaining years of the operation. OTML have initiated programs to identify and evaluate options to mitigate this risk.

Jan 1, 2003

Australia is the Western world's largest producer of alumina, supplying one third of total needs. Western Australia's South-West has the greatest concentration of alumina production in the world, with a current annual production rate in the region of 6.8 million tonnes per annum, over 20 per cent of the total supplied to market economies. The value of this production in 1989-90 was 2.34 billion dollars, a very significant contribution to the economy of the State (1). This is despite the fact that the bauxite from the Darling Range is the lowest grade that has ever been commercially exploited, and despite the geographical isolation of the region. It is therefore of great importance to the National and State economies that this industry retain its competitive edge, particularly in the current times of economic downturn. One essential ingredient of this competetiveness is technology and innovation, which can be assured by the committment of the industry to an active program of Research and Development, with support from the public sector as Appropriate.

Jan 1, 1991

By Bisshop J. P W

Maximum recovery of sulphide minerals by flotation is achieved over a limited size range. Valuable particles above and below this range have a smaller probability of being recovered. In the normal grinding-flotation operation, not all valuables are reduced to the optimum size range, and therefore sub- stantial losses occur. A significant improve- ment in the size distribution is not usually possible within the conventional circuit, and a more complex arrangement may be necessary to obtain optimum recovery of the valuable mineral. This problem is considered with refer- ence to the Mt. LyeZl concentrator. The performance of the existing circuit is dis- cussed, and it is shown that losses in recovery occur in both coarse and fine sizes. Laboratory tests indicate that regrinding the coarse particles results in an increase in recovery of up to 4%. Redistribution of plant grinding capacity to reduce initial grinding power by 6% and use this capacity to regrind coarse particles was considered. It is con- cluded that overall plant efficiency would be increased by 2% provided that overloading of the regrind mill could be avoided.

Jan 1, 1977

The longwall system with caving is the most common mining system in Polish Collieries and the extraction is carried out simultaneously on several levels and in different seams. The extent and diversity of the methane hazard occurring is strictly connected to the specific geological and gas conditions as well as to the applied mining methods. Taking these factors into consideration the following methane drainage methods are applied as additional means of combatting the methane hazard in Polish gassy coal mines: 1. predrainage by means of boreholes drilled from the surface, 2. predrainage from stone drivages and devel- opment workings, 3. degasification of coal extraction workings, and 4. degasification of sealed-off areas/old goaves. Predrainage gave satisfactory results when holes were drilled from the surface or from underground workings, but only to depths to 300 m. It was necessary to adapt methane drain- age methods to the geological and mining con- ditions as gassiness increased with depth. The results of methane capture, both pre- drainage and post drainage were obtained by investigating several gassy mines.

Jan 1, 1982

By Kapoor M. L

Emf measurements on SE galvanic cell: SS; Ni-NiO I solid electrolyte/ZrO2 + CaO I [Pb + Bi]liq alloy; (PbO); SS were made in the temperature range 913-1034 K to determine the thermodynamic properties of oxygen dissolution in liquid lead. Bismuth alloys with bismuth in the dilute concentration range of 0 to 3.08 mass per cent and oxygen in the alloy varied by equilibrating the metallic system with a suitable (PbO) slag. Wagner's interaction parameter approach was used to calculate the ternary interaction parameter, eBiO at temperatures of 913, 953 and 993 and 1034 K and to observe the temperature dependence eBiO = 19 200/T - 17.454. Quasichemical fonnulation was employed to yield lnf BiO and reveal the effect of bismuth on oxygen in lead. The results obtained are discussed on the basis of theoretical models and the value of Wagner's energy parameter 'h' estimated to predict the results in a Pb-Bi-O system.

Jan 1, 1995

An examination has been made of the rate and extent of removal of carbon from scrap metal charges when the melt is exposed to atmospheres which are reducing or oxidising with respect to FeO at unit activity. The mechanisms of decarburisation of molten Fe-C-S- P-Mn-Si alloys with H2/CO/H20/C02 gas mixtures with controlled compositions at high or low concentrations of carbon in the melt in the presence and in the absence of sponge iron, in both slag free melts and in the presence of various slag forming additives are discussed. A significant quantity of carbon can be removed from the metal during the melting stage and under optimum conditions, a high percentage of metal recovery and low carbon can be obtained after exposure of melt to the above gas mixture with controlled compositions. The presence of ferrous oxide provided by poorly reduced ore in the charge and the use of controlled atmospheres facilitated the removal of carbon to very low level during the melting period.

Jan 1, 1984

By S Moradi

The thickener overflow of zinc concentrate, obtained from flotation process in the Angouran plant located in Iran, contains a large quantity of slimes which were transferred to the tailing ponds. These slimes have caused problems of storing and environmental aspects in the Angouran area. The objective of this research is to describe the extraction of zinc from these slimes by leaching method using sulfuric acid in pilot plant scale.Chemical analyses showed that these tailing materials contain 35 per cent of zinc. By XRD analysis, smithsonite is identified as the major constituent. Calcite, dolomite, and cerussite are found as carbonate minerals. A minimal amount of Zn occurs as hemimorphite. Quartz, kaolinite, clinochlore and muscovite are other silicate minerals in the slimes.In the optimal conditions, ie acid leach at pH of 1, temperature of 55¦C, reaction time of 120 minutes and solid-liquid ratio of 1:3 and neutralisation with Ca(OH)2 at pH = 4.5, temperature = 70¦C, time = 90 minutes, the total recovery of zinc obtained was 95 per cent.

Jan 1, 2004

By S M. C Verryn

The amount of raw material used in the production of cement can be reduced by partially supplementing it by pozzolanic waste material without changing its properties negatively. This paper discusses results of an investigation using slag from the Pt industry, from the production of steel using Midrex processes as well as fly ashes from different coal power plants in South Africa. These are blended in a 20 per cent slag or fly ash to 80 per cent cement ratio. The properties of the mixtures depend on the phase composition, chemistry, grain size and the sources of the materials. The results are promising, but show variable behaviour depending on slag and cement composition. Compressive strength tests as well have heat flow curves showing the hydration behaviour, indicating that 20 per cent addition of slag or fly ash to ordinary Portland cement is viable. There is a large potential to use slag in cement mixtures and this study can be used to develop cements that will positively influence CO2 emissions and help to reduce large slag and fly ash stockpiles.

Jan 1, 2008

By Liu H, Chen S

Natroalunite is one of colouring minerals in kaolin. In this investigation, natroalunite, on which Ca(II) was adsorbed, was flocculated by HPAM and kaolin was depressed in suspension. The adsorption of Ca(II) on the natroalunite surface was studied by zeta-potential measurement and Auger Electron Spectroscopy analysis. Ca(II) was adsorbed more on the natroalunite surface than on the kaolin surface. The mechanism of Ca(II) adsorption was considered to be chemical adsorption on natroalunite and to be physical adsorption on kaolin. It has been found that Na6P6O18 and Na2Si04 can strongly affect Ca(II) adsorption on the surface of kaolin, but weakly on the surface of natroalunite. The effects of degree of hydrolysis and the molecular weight of HPAM, the effect of pH and the effect of Ca(II) have been studied. The kaolin ore, containing SO3 1.05 per cent has been processed with this method. The products only containing S03 0.36 per cent and the weight ratio of concentrate 52.27 per cent were Obtained.

Jan 1, 1993

By Borgelt B. V, Perry A. J, Wellington H. K

There has been little change in the lead smelting practice at Mount Isa since 1939 when the metallurgy and general practice were outline by Raney and Blott.The purpose of this paper is to descriqe some of the operational details that have influenced the overall production. The slag fall hns been increased by the lowering of the lead content of the concentrate. Further, as it is the practice to include iron on the furnace charge and carry a higher lime content in the slag, both factors have produced notable results in furnace operations.All blast furnace gases are filtered in a baghouse and this unit is. being further extended to take all smelter gases, thus eliminating the existing Cottrell plant handling Dwight-Lloyd gases.The lead smelter was closed down from April 1943, to May 1946, during which time blister copper was produced.The report is subdivided as follows:-1. Filtering and Mixinga. Effect of calcium sulphate on cloth.b. Dwight-Lloyd charge composition.c. Main mixer.d. Return sintel sizing.2. Blast Furnace Operationsa. Introduction.b. Use of orehearth.

Jan 1, 1953

The Burragorang Valley lies approx. 95 km by road south west of Sydney and some 35 km west of Camden. It is over 80 km in length and varies in width from 3 km to over 16 km. Geologically, the history of the Burragorang Valley is of interest. It was referred to by early geographers and N.R.M.A. booklets as the largest sunken valley in Australia. This description is incorrect as it is a water worn valley formed by the dissection of an uplift in the south western portion of the large Sydney Sedimentary Basin. Ages2 ago there extended right across the Blue Mountains, a continuous tableland into which the Nattai, Wollondilly and Cox's Rivers have carved out the formation of the Burragorang. This dissection together with other valleys such as the Megalong, Jamieson and Grose, formed part of the eastward drainage pattern of the uplifting tableland into the Pacific ocean. The lapse of time since the streams in the Burragorang began their work of erosion can

Jan 1, 1976

The precious metallogenic belt and its geoloqical-tectonic location in eastern China.The precious metallogenic belt of eastern China is located in the western part of the Pacific gold metallogenic belt, and occurs in the upper levels of the continent cut by a deep fault structure tending NNE and NE, and active during the Mesozoic. The precious metallogenic period ranges mainly from Late Jurassic to Early Cretaceous (160 Ma-110 Ma); subordinate mineralisation occurred during the Hercynian period, and was rare in the proterozoic.Seven precious metallogenic belts are recognised from east to west, i.e. from continent to the margin active belts, as follows:1. Au-Ag-Te metallogenic belt of East Shandong Province2. Au-Ag-Pb-Zn metallogenic belt of west Liaoning-Miyun area3. Au-Os-Ir-Cr-Cu Mo metallogenic belt of Chengde Pingquan area4. Au-Ag-Pb-Zn metallogenic belt of Zhang Xuan area5. Au-Ag-Pb-Zn metallogenic belt of Zhejiang province6. Au-Ag-Se metallogenic belt of East Qinling area7. Au-Pd-Cu-Mo metallogenic belt of Wansu area

Jan 1, 1990

By Boyack DJ

DEFINING AN ECONOMIC TARGETExploration usually begins with the corporate goal of finding a minimum tonnage and grade of a selected mineral. Sometimes this is expressed more simply as a minimum quantity of contained metal without any indication of the desired grade or implied profitability. Such a goal is useful in the selection of exploration areas and the planning of initial drilling programs. However, it should be reviewed as soon as significant mineralisation has been identified. To make rational decisions about exploration expenditure, the potential return from a deposit must be estimated from the outset and re-esti-mated frequently.The potential return will depend on:1. The proportion of mineral which can be economically recovered from the deposit by mining (the mining recovery).2. The quantity of valuable constituent that can be recovered after dilution with waste rock during mining and losses due to incomplete metallurgical recovery.3. Expectations of price and markets.4. Capital and operating costs applying to the selected mining and processing methods, and to transportation and marketing. Increasingly, environmental costs and constraints must also be considered.

Jan 1, 1990

By R Witt, M Lowing

Tanking of tunnels is now often specified when inflows exceed as little as 1 L/s/km with a unit distance of 100 m. To demonstrate inflows over a 100 m segment of a tunnel are less than 0.1 L/s with a standard error of 0.01 L/s by timed, gravity filled, volume measurement up and downstream of the segment, the measuring cylinder volume (L) must exceed 10 Q, where Q is the flow in L/s, and the number measurements taken and averaged must exceed 20 . If a standard error of 0.02 L/s is acceptable then 5Q2 measurements must be taken and averaged. If gravity filling is not possible then the number, n, of repeat pumped container measurement required is given by: where: is the 100 m section leakage is the volume filling time is the standard error of volume measurementZ is the standard normal variateK is a coefficient dependent on physical measurement conditions Based on analysis of field data an indicative coefficient of variation of volume measurement is ~0.05.

Jan 1, 2008

By Holliday RJ

The Imperial Smelting Furnace (ISF) was developed in Britain during the 1950's as a process which could produce zinc from a blast furnace. Since then it has evolved into an efficient means of producing zinc and lead from lower grade raw materials, both of primary and secondary origin. These changes have been in response to the need to improve the cost competitive position of the ISF in a climate of decreasing metal prices. The improvements at the Cockle Creek smelter of Sulphide Corporation Pty Limited have resulted from work undertaken in four main areas: 1. Changes in plant design and operating practice to give more stable furnace operation. 2. Improvements to the quality of sinter being charged to the furnace. 3. Improved monitoring of process variables and the formulation of control strategies based on the improved data. 4. Increased understanding of the processes occuring within the furnace shaft to allow predictive modelling to be undertaken. Work in these areas is still progressing but the work to date has resulted in a significant improvement in the production rate and efficiency of operation.

Jan 1, 1984

In 1989 Henry Fairlie wrote a cover story for The New York Republic, 'Fear of Living'. He noted, `The first Apollo space craft caught fire during a test on the launch pad. Three astronauts were killed, the nation was shocked and horrified, all the more because the screams and scrambles of the astronauts could be clearly heard'. After a brief delay in manned flights, the Apollo program resumed with strong public support; within 18 months, Apollo 11 landed on the moon. Fairlie contrasts the Apollo tragedy to the 1986 Challenger disaster. `The prevailing mood in America so panicked NASA that it took almost three years to send up another shuttle', he observed. `In 19 years between these tragedies, the idea that our individual lives and the nation's life can and should be risk-free has grown to be an obsession threatening to create an unbuoyant and uninventive society.' Taking risks is a normal part of our daily routine. The act of living involves minute-by-minute decision-making focused on survival through the practical management of risks. The act of breathing exposes each individual to the risk of infection while the act of crossing the road could almost be considered suicidal. We deal with these constant threats by observing simple rules of hygiene, safety or what may be labelled as common sense. The rules of community, designed to minimise risk in society, can at times lose focus and result in the imposition of schemes that have a far greater cost than the issues from which they protect. Effective management of risk, whether in the community or a business is about awareness and balance and the elimination of unacceptable risk. Risk cannot be eliminated from our lives or our working environment. However it can be managed if it is properly understood, monitored and controlled. The purpose of my presentation today is not to provide a comprehensive technical risk inventory but to capture the essence of risk and the application of management strategies designed to deal with it in a positive fashion. The basis of our differential financial reward system is risk. The key to successful management is to deal with the downside risks in such a fashion that the benefits of enterprise are not eliminated. The key question any investor must consider is `can the major risks assQciated with a venture be managed or eliminated while retaining a greater proportion of upside potential'. The answer to this question is the ultimate value an investor would assign to any project. In reviewing the relevance of risk to our industry the range of papers to be presented today provide examples of how management deals with specific components of risk. In each case the value of the business has been enhanced by the practical application of balanced risk management. The ultimate success of the industry depends very much on this concept as it also provides a public showcase upon which we are judged. Therefore, from all perspectives the effective management of risk is a cornerstone from which to build a stable and progressive mining industry.

Jan 1, 1994

Distal rhyolitic tephras from the Taupo Volcanic Zone are widespread in the Auckland urban region. Some are primary air fall or flow deposits but most are reworked. Their presence indicates potential hazard for the Auckland urban region from future eruptions of central North Island volcanoes and associated secondary effects. Geotechnical problems occur as a result of weathering of the tephras yielding sensitive materials.

Jan 1, 1990

By Hu Y, Li D, Qu G

In this paper the structural mechanism of the gold - lixiviant complex is investigated. The results show that there are two common characteristics in the outer orbitals for all the gold lixiviants: a) a (Y -type of HOEO to form the L-*Au co-ordination bond, and b) a it type f LUEOs, with symmetry the same as that of 5d orbitals of Au, to form L

Jan 1, 1993