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The smelting of the Broken Hill lead concentrates at the Broken Hill Asso,ciated Smelters produced, among other products, approximately 4,900 ounces of gold and 8,800,000 ounces of silver during the year ending June 30th, 1938. The following table shows the actual amounts of gold per ton of lead concentrate produced during this period at the important mines. The total gold in the period is calculated from the number of tons of lead concentrates produced, and by comparison with the production' of silver, shows thatthere is no constant relation between the amounts of gold and silver.The fact that no gold is seen during milling, even when gravity concentrating tables are employed, signifies that the gold does not occur as occasional coarse particles.Further, as the values increase considerably in the flotation slime, it can be inferred that the gold occurs as minute inclusions in one or more of the minerals in the lead concentrates.The four most abundant minerals in the lead concentrate are galena, zinc blende, chalcopyrite, and...

Jan 1, 1940

Refractory gold ores have been the subject of intensive metallurgical study in order to achieve more efficient recovery of contained values and at the same time to minimise environmental impact. Considerable innovative gold processing technology was introduced in New Zealand last century, the most notable being the first successful commercialisation of the cyanidation process by the Crown Mines Company at Karangahake in 1889. The Karangahake gold-silver deposit was second only +to the Waihi Martha mine in total bullion production from the region with active mining from 1882 until about 1920 and sporadic production between 1930 and 1944. Reevaluation at Karangahake with associated metallurgical testing has continued since that time becoming particularly active in the last decade as a result of increasing gold prices. Gold processing technology is reviewed and results of some recent test work are presented and discussed in the context of Karangahake history and future development possibilities. This work confirms the variability and complexity of the Karangahake deposit both mineralogically and metallurgically and suggests flotation followed by new and innovative smelting is the most appropriate processing route for the recovery of gold from the high grade ore which could be produced from the Karangahake workings in moderate tonnages.

Jan 1, 1993

Conservation and environmental issues are raising their profile with respect to both demand restraint and electricity supply options. In New Zealand, conservation pressures and energy efficiency need to be seen in relation to the supply system currently in place which has capacity for economic supply of electricity in quantities substantially in excess of the current market. Consequently, energy efficiency and conservation need to be interpreted in relation to the supply system as well as in relation to end use. The relationship between the environment and conservation is strongest when new generation is required. New Zealand's electricity supply system consists of a large proportion of hydro production and this has significant environmental benefits when considered in relation to concerns of global wanning and the greenhouse effect. However, environmental trade-offs in supply options need to take account of both the efficiency of electricity end use, the trade-off between hydro and thermal generation and the inter-regional effects of shifting development options from one region to another. The Electricity Corporation has a high level of consciousness with respect to environmental and conservation issues and this paper demonstrates its own moves to maximise energy efficiency and illustrate the environmental trade-offs for supply.

Jan 1, 1990

By Kelly E. G

NZ Steel's flushing slag typically contains 1.2 per cent V203. Extraction of vanadium from powdered slag using a salt (NaCI or Na2CO3) roast/leach process was investigated. With NaCl, optimum extraction conditions were a charge containing 10 per cent NaCI, roasting in air at 875°C for 4 hours, followed by leaching in dilute H2SO4. Extractions were typically 30-50 per cent. NaCI roasting did not chemically attack the slag; the phase transformations that occurred were due to high temperature oxidation. Slag particle size had a significant effect on extraction.Optimum conditions for extracting vanadium by Na2C03 roasting were 20 per cent Na2CO3 in the charge and roasting in air for 3-4 hours at 850-875°C followed by water leaching.Na2CO3 roasting involved chemical attack that resulted in the formation of perovskite (CaTiO3) and carnegieite (NaAISiO4).The extent of vanadium extraction depended on the amount of Na2CO3 added and the original slag SiO2 content.Compared to the separate roasting treatments, simultaneous treatment with NaCI and Na2CO3 gave lower vanadium extraction, while requiring considerably higher roasting times and temperatures.

Jan 1, 1982

By H Han, W Wang, E Zhou, D Duan

"In this study, physical, chemical and microscopic characteristics of high phosphorus oolitic hematite were studied firstly. Based on which, the new methods of high phosphorus hematite used in the æsolid state reduction by rotary hearth furnace - magnetic separationÆ and iron nugget by rotary hearth furnace direct reduction processes were discussed. The results showed that high temperature, low basicity and high carbon content is conducive for the apatite in iron ore to reduce into molten iron, but not conducive to the removal of phosphorus. Through optimisation of process parameters, dephosphorisation rate of high phosphorus hematite is more than 60 per cent by æsolid state reduction roasting-magnetic separationÆ process while that is up to 80 per cent by iron nugget process. This study can provide theoretical and technical basis on economical and rational use of high phosphorus oolitic hematite.CITATION:Han, H, Duan, D, Zhou, E and Wang, W, 2013. New methods for high phosphorus oolitic hematite dephosphorisation by direct reduction process, in Proceedings Iron Ore 2013, pp 391-396 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

At Copper Refineries Pty. Ltd., Townsville, two reverberatory furnaces of 420 tonnes capacity are used to melt 210000 tonnes/year of copper for subsequent anode casting. When the refinery commenced production in1959, these furnaces were of 300 tonnes capacity. The original furnaces featured a silica brick hearth, magnesite and chrome magnesite side 'walls, and a sprung silica brick roof, but were unsatisfactory because of thelow refractory life and high costs. With continuous expansion in production and the incentive to increase furnace life and capacity the design of these furnaces has changed greatly since that time.The present furnaces feature all basic brick, a flat suspended basic brick roof, very extensive use of watercooled copper sections, and are of substantially increased (420 tonnes) capacity. Particular attention has been concentrated on high wear areas such as the taphole, side walls, and charging door jambs. Each furnace in its 24 h cycle, is charged, the copper melted, impurities skimmed off, metal "poled" prior to casting, and cast.The service condition during each of these operations is important in considering furnace refractory life.The improvements in operating practices and furnace 'construction which enabled the capacity of the furnaces to be increased are discussed. The life between major repairs to side walls has increased from 90 charges to300 charges.The scope for future improvement is considered and areas for development are suggested.

Jan 1, 1977

By Everson P. T, Moyle F. J

Magnesite-rich and dolomite-rich ores from the Savage River region of Tasmania are being considered as potential feed material for a commercial process for production of magnesia.Two selected samples have been characterized by chemical analysis, X-ray diffraction, and differential thermal and thermogravimetric analysis. The materials differ in calcination behaviour, with magnesite decomposing at a significantly lower temperature than dolomite. Calcination conditions have a marked effect on the rate and percentage of magnesium dissolved as the bicarbonate when slurries of the calcine are leached with carbon dioxide. From a process point of view, the feed should have the highest possible magnesite/dolomite ratio, while the optimum calcination conditions are determined by the behaviour of the magnesite component of the feed.From batch calcination tests, it is apparent that the optimum calcination conditions for magnesite-rich ore are a temperature in the vicinity of 700°C and a calcination time of one hour.

Jan 1, 1981

The Morley Coal Measures (Upper Cretaceous) at Ohai Coalfield were deposited in an intermontane basin alluvial environment of entirely terrestrial aspect. Within this regional setting, three distinct types of depositional environment are recognised; these are: (i) a sand-dominated (South Saskatchewan type) braided river system characterized by channel-bed dunes and possibly compound bars; (ii) a well-drained floodplain environment frequently subject to crevasse-splay and overbank-flow sedimentation; and (iii) a poorly-drained, commonly peat-accumulating backswamp environment locally traversed by tributary drainage systems and occasionally inundated by crevasse splays and overbank flows. All major coal seams of the Morley Coal Measures originated within forest moors under predominantly telmatic (periodically inundated) conditions. The peat-forming vegetation comprised largely arborescent forms (dominantly conifers), in addition to pteridophytes and bryophytes. In-seam vertical variations in coal type indicate groundwater levels initially decreased and then increased during the lifetime of a particular peat swamp, possibly in response to a change in the migration direction of an adjacent fluvial system. The proposed depositional model for the Morley Coal Measures has the potential to be utilised during exploration programmes and mine development to impart greater objectivity to predictions concerning seam geometry and continuity, trends in coal type and quality, and likely roof and floor conditions.

Jan 1, 1985

By G J. Lyman, S A. Tittlemier

International regulations exist to manage the concentrations of mycotoxins such as Ochratoxin A (OTA) and deoxynivalenol (DON) in grains and prevent health risks from excessive exposure to OTA and DON. Since the permitted levels of these mycotoxins are very low (existing maximum levels are in the range of 5 ppb for OTA and 1–2 ppm for DON), sampling for these mycotoxins is potentially challenging. Given that the distribution of infected kernels in a consignment of wheat can be highly heterogeneous, detection by current sampling methods is subject to a high variance. Furthermore, the concentrations of mycotoxins in individual kernels vary over orders of magnitude, intensifying the heterogeneity of the bulk grain.In these circumstances, there is much interest in developing sampling plans that inform regulatory agencies, and mitigate the risk of misclassifying grain shipments as compliant or non-compliant within the global grain trade, when correctly implemented.Experimental data from laboratory and field studies describing individual wheat kernel concentrations of OTA and DON were combined with experimental data describing the variance due to the analytical methods used for OTA and DON to calculate the sampling distribution for wheat having various levels of contamination. This work has focused on quantifying the heterogeneity of samples at the point of submission for analysis and within subsequent sample preparation to arrive at total sampling distributions that include uncertainties due to the intrinsic heterogeneity and the analytical uncertainties. The sampling uncertainty that relates to the difference between the primary sample analysis and the true lot analysis is not included as it has been dealt with elsewhere.CITATION:Lyman, G J and Tittlemier, S A, 2017. The sampling characteristics of grains contaminated by mycotoxins, in Proceedings Eighth World Conference on Sampling and Blending , pp 281–294 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

Deposits of the Reefton Goldfield, West Coast, New Zealand, are hosted on N-NE striking, upright folds of the Greenland Group. High-grade quartz lodes are hosted on axial planar shears, typically have short strike lengths, and form shoots that pitch steeply on the hosting shears. Deposits within the field area of a detailed structural study share these characteristics. Field mapping and microstructural analysis have demonstrated that the Greenland Group was affected by a multideformational sequence. Gold mineralisation is hosted on shears axial planar to the F2 folds, but occurred during a subsequent deformation event (D4). Deformation during D4 resulted from N-NE directed shortening, near parallel to the trend of the F2 folds. This event produced F4 kink folds that were accommodated by layer parallel slip on S2 parallel shears, gold mineralisation during D4 being confined to the dilational hinges of F4 kink folds. The semi-brittle nature of D4 allowed the formation of stockwork veining and disseminated mineralisation within the F4 hinge zones. Most deposits within the goldfield are similar to those within the field area, and are interpreted to have been mineralised during D4. The two largest known deposits within the goldfield, however, are distinct. The Blackwater Deposit, striking parallel to the hosting folds, has a combined strike length of 1 km. The Globe-Progress Deposit is hosted on an E-W striking discordant shear in which a brittle zone of disseminated mineralisation encompasses high-grade quartz lodes. The characteristics that distiguish the Globe and Blackwater deposits may be due to formation before and after D4 respectively. Detailed field mapping in the vicinity of known deposits throughout the goldfield will further refine the relationships between the F2 folds, later deformations and the localisation of ore deposits. Additional mapping may also help constrain the position, orientation and extent of additional orebodies.

Jan 1, 2001

By R E. Myers, G N. Phillips

Many of the worldÆs larger iron ore deposits are hosted by rock sequences of Archaean to early Proterozoic age. Most models for the genesis of these deposits are influenced, either directly or indirectly, by the nature of the atmosphere at the time of their formation, and more specifically by the presence or absence of oxygen in the early atmosphere. Since the early-1950s, the geological literature suggests that the Archaean atmosphere was æreducingÆ, and that it may not have contained significant amounts of free oxygen until ca 2 Ga. There are many different definitions of the term æreducingÆ, but the criterion adopted here is whether crustal iron was limited to Fe2+, or whether Fe3+ was also widespread, ie was there scope for redox changes in the state of iron? Significantly, major Australian banded iron formations span this period of inferred atmosphere transition, eg Mt Goldsworthy, Mt Tom Price, Middleback Ranges. Geological evidence for a reducing Archaean atmosphere is both ambiguous and controversial (see review by Phillips, Law and Myers, 2001). Many earlier ideas (eg no Archaean redbeds; all very large iron ore deposits being post-Archaean) have been disproved by dating, whereas other evidence (eg homogeneous detrital gold grains, inferred palaeosols) has not withstood geological scrutiny. The interpretation of some data sets (eg inferred detrital uraninite and pyrite in some Archaean meta-sedimentary rocks) is still controversial. In fact, some lines of evidence now suggest that oxygen was present in the atmosphere well before 2.5 Ga (eg sulfates in the Pilbara craton, carbon distribution in clastic sedimentary rocks). An oxidising Archaean atmosphere has important implications for the development of iron formations. First, the atmosphere is an obvious potential source of oxygen to stabilise ferric iron minerals. Second, reduced fluids in equilibrium with ferrous iron are commonly inferred to transport iron in solution to the depositional site. The redox state of the atmosphere thus provides critical constraints on the solution chemistry of surface waters, effective transport paths for iron and particularly on viable precipitation mechanisms. Iron formations developed from fluids in equilibrium with the atmosphere also have the potential to provide important constraints on the evolution of EarthÆs early atmosphere. If an oxygenated atmosphere is a necessary condition for the development of iron formations, then the Archaean atmosphere must have been oxidising since at least 3.5 Ga. If the redox state of the atmosphere is not a necessary condition, then the time distribution of iron formations cannot be used to provide constraints on atmospheric evolution. Given these uncertainties, models for the genesis of iron ore deposits of Archaean or early Proterozoic age should not rely on a reducing atmosphere in the absence of independent evidence and the alternative of an oxidising atmosphere should also be considered.

Jan 1, 2002

By M Begbie, R J. Norris, D J. MacKenzie

The Otago Schist is crossed by numerous deformation zones that formed in the latter stages of metamorphism and uplift of the metamorphic belt. These deformation zones are long (tens of km) linear features at the regional scale, and are generally narrow (km scale or less). Many of these structural zones separate schist domains with different rock types and structural/metamorphic histories. The Hyde-Macraes Shear Zone is one such deformation zone, and this zone hosts the active Macraes gold mine. The Rise & Shine Shear Zone, 80 km NW of Macraes, is also enriched in gold and has been mined historically. Mineralisation in both these shear zones occurred during the transition from ductile to brittle deformation as the schist belt was uplifted from greenschist facies metamorphic conditions. Recrystallisation of quartz and micas in the early stages was overprinted by cataclasis, with sulfide and gold precipitation throughout. Many of the other late metamorphic deformation zones formed under similar greenschist to sub-greenschist facies conditions, with similar overprinting of recrystallisation textures and folds by more brittle textures such as breccias. Under these conditions, originally regionally pervasive deformation at the highest metamorphic grades was evolving towards more focussed high strain zones at lower temperatures and pressures. Shear zones initially focussed fluid flow along microshears and mineral grain boundaries, resulting in 1 to 100 m scale alteration and replacement in the host schist, with only local development of quartz veins. Fluid flow was not controlled by open fractures, and the rate of fluid movement was probably slow and pervasive. After uplift into the brittle regime, the schist belt underwent tectonic extension. Extension was accompanied by development of swarms of steeply dipping veins, with localised mineralised normal faults. Hydrothermal fluid flow throughout this uplift history was a normal consequence of late stage devolatilisation of the metamorphic belt. Hence, all late metamorphic deformation zones should be considered prospective for gold accumulation.

Jan 1, 2005

Pressure drops were measured in a column packed with glass spheres and wax particles, both in random and preferential distributions. Variables investigated included wax content, gas flow rates, and temperatures.It is shown that for random distribution of wax, pressure drop is exponentially related to wax content above the melting point of wax and that below this it increases with increasing gas rate and temperature.For preferred distribution of wax the highest increase in pressure drop is obtained with horizontal distribution of wax and the least with vertical distribution.Comparison with operating blast furnace data and application of results to practice are also included.

Jan 1, 1970

Several Approaches to Enhance the Bioleaching of Enargite Some approaches were investigated to enhance the recovery of Cu from enargite by bioleaching with Acidithiobacillus ferrooxidans using the galvanic interaction with pyrite and activated carbon, and with thermophilic bacteria, Acidianus brierleyi. Addition of pyrite initially enhanced Cu leaching by the Galvanic effect, but after that the formation of secondary minerals passivated the surface of enargite in inoculated batches. Activated carbon improved Cu recovery from enargite much better than pyrite, when it is contacted with enargite. Recovery of Cu from enargite has been recorded to at largest 2.4 per cent within 30 days in the presence of activated carbon when mesophilic bacteria were inoculated at 25¦C. The recovery of Cu from enargite was drastically enhanced by inoculation of thermophilic bacteria, Acidianus brierleyi, up to 60 per cent within 40 days at 70¦C and still not leveled off after 40 days unless the formation of Fe(III) precipitates occurred. After 40 days dissolved molar ratio of Cu/As is around 5.2, suggesting that metal-deficient sulfides and/or ferric arsenate might be formed on the surface of enargite.

Sep 13, 2010

Air tabling of zircon-rich non-conductor products containing quartz enables most of the fine quartz present to be rejected without a markedloss of zircon. The coarser quartz in the air table feed can be separated from the zircon by screening one or more air table products, the oversize products containing most of the quartz and little of the zircon. Air tabling, with or without screening, is more efficient than wet tabling alone for the removal of fine quartz, but not for the removal of coarse quartz. Practically all of the quartz can be separated from the zircon by using wet tabling in conjunction with hydraulic classification, or by using air tabling in conjunction with dry launder treatment, in which a degree of sizing takes place that is advantageous for subsequent air tabling.INTRODUCTIONBack-dune and inland beach sand deposits usually contain fine wind-blown quartz, and neither spiral nor wet table concentration, alone or in conjunction, makes a clean separation of heavy minerals from quartz. Many rutile plants recover rutile and zircon from a low-quartz, wet-table concentrates by means of magnetic and electrostatic separation; some rutile and zircon are lost in the table tailings. Other rutile plants, and two of the ilmenite plants in Western Australia, recover rutile or ilmenite respectively, from a spiral concentrate containing several per cent of quartz, and then subject the non-conductor product to an additionalgravity concentration process to separate the zircon from the quartz. Some zircon is lost in the additional gravity process, but all of the rutile or ilmenite in the spiral concentrate is, or should be, recovered as high-grade concentrate. The higher recovery of rutile or ilmenite by this treatment method is offset by the expense of drying part of the feed twice, as a wet process is usually used to separate the quartz...

Jan 1, 1962

During the course of the major research in the Metallurgy Department of the University of Melbourne into the creep characteristics of lead and .its dilute alloys, it has been the practice to prepare the majority of test specimens from rolled strip. From time to time during the progress of the work, certain variables involved in. the rolling of the experimental ingots have been investigated. It is proposed to collect together in this paper the results of these experiments. Some general features relating to the type of deformation produced have been discussed in a previous paper.While it is admitted that the conditions prevailing through this work differ' in some respects from those of industrial rolling practice, it is felt that many of the factors investigated have an important practical significance. Some of the work described forms a continuation of the researches of R. S. Russell (2) , (3) , (4), into the recrystallization of various pure leads after deformation by rolling.MATERIALS USEDIn this work, a variety of "pure" leads and certain dilute alloys made from the purest of the basis leads have been studied. The compositions of the basis leads and the corres...

Jan 1, 1940

Increasing demands on quality of metallurgical grade alumina and for lower production costs led to the development of a new fluid bed calcining process. The process, jointly developed in Germany by Vereinigte Aluminium Werke A. G. and Lurgi Gesellschaften m.b.H., takes advantage of modern chemical engineering methods such as counter-current flow of combustion air and solids, direct heat-exchange between combustion air and fine solids, and near stoichiometric combustion of oil in a fluid bed. Using a two-stage Venturi-type suspension preheater for heat-recovery from combustion flue-gases, the circulating fluid bed technique with internal oil combustion at 220°F for the calcining step and a five-stage fluidized bed cooler for heat-recovery from calcines, the process gives an outstanding heat-efficiency. In a first industrial plant for 560 sh. tons/day of alumina heat consumption figures of less than 1·400 B.T.U./lb Al203 g were achieved.

Jan 1, 1972

Cadmium occurs in the Broken Hill Lode essentially as a camouflaged element, substituting diadochically for zinc in the sphalerite.Analyses of a series of zinc concentrate flotation products, prepared from samples of ore taken at intervals throughout the developed lengths of the several orebodies forming the lode, have revealed a pattern in the distribution of cadmium relative to zinc. This pattern appears to reflect the temperature and order of deposition of the several orebodies, and the direction of movement of the mineralizing solutions.INTRODUCTIONThis investigation into the distribution of cadmium in the several orebodies of the Broken Hill lode was undertaken by the Mineragraphic Section. of C.S.I.R.O. in conjunction with the Broken Hill Geological Research Committee, as part of a study of Broken Hill mineralization.It arose from the examination of cadmium and zinc assays supplied by Mr. T. A. Read, Chief Metallurgist of the Broken Hill South Ltd.; of experimental zinc concentrates prepared from localized samples of the No, 2 and No. 3 orebodies in the Broken Hill South Mine. These assays suggested that the two orebodies were characterized by distinctive ZnjCd ratios.In view of the possible sigmficanc'e of such a difference, comparable data were sought from each of the other mines. The necessary samples of ore were collected by the geological staffs of the several mines. The preparation of separate zinc concentrates and lead concentrates from these samples, and their assaying, was conducted by Mr. Evan Hardy, for the North Broken Hill Mine, and its assodated leases, and by Mr. D., Swan, under the direction of Dr. J. C. Nixon, for the Zinc Corporation and New Broken Hill Consolidated Mines. Additional tests on the Broken Hill South Mine were made by Mr. C. W. Reilly, under the direction of Mr. T. A. Read. The samples were...

Jan 1, 1955

By J Law, S Jahanshahi, R Holmes

Iron ore is AustraliaÆs largest commodity export and is vitally important to AustraliaÆs current and future prosperity. However, while major expansions are currently in progress to satisfy demand, the industry is also undergoing major transformations. Reserves of traditional high-grade Brockman ores that have underpinned the Australian iron ore industry since its inception are slowly being depleted and alternative ore types such as Marra Mamba bedded iron deposits, Yandi and Pannawonica channel iron deposits and magnetite deposits are now being developed. However, the impurity levels in some of these alternative ores are higher and they require blending and/or upgrading as well as an advanced knowledge of their downstream processing characteristics to facilitate cost-effective utilisation by overseas customers. The research challenge is to use advanced techniques for mineral exploration, ore characterisation, mineral beneficiation, agglomeration and sustainable processing to identify and develop innovative and breakthrough options for locating, unlocking and enhancing the value of AustraliaÆs iron ore resources. Furthermore, to sustain the steel industry and hence secure the demand for iron ore, there is a growing need to enhance the environmental and business performance of the industry through reductions in wastes and emissions. Therefore, cost-effective breakthrough and enabling technologies that massively cut waste generation, CO2 emissions and water consumption are also being developed. These include the use of renewable fuels and reductants, waste heat recovery and conversion of by-product slag into a saleable substitute for Portland cement. A number of examples of recent developments in the above areas are provided in this paper.CITATION:Holmes, R, Jahanshahi, S and Law, J, 2013. Research and innovation for the iron ore to carbon steel value chain, in Proceedings Iron Ore 2013 , pp 3-6 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

This paper considers three aspects of cemented fill practice and research in Mount Isa. Firstly, an account is given of the use of Portland cemented hydraulic fill, considering mainly the role and specifications of the fill used but including û brief description of fill preparation and placement. Data resulting from a Portland cemented hydraulic fill sampling, curing and testing campaign covering about 18 months of operating practice are presented, analysed and discussed. These yield information indicating the mode of operation of a fully-automated fill preparation station, as well as a means of comparing field and laboratory strength results. A technique with potential for use as a fill quality control without actual strength testing is also described. Results of a fill research program conducted by the author in Mount Isa since early 1968 are presented, involving both Portland cemented hydraulic fill and alternative, cheaper, additives for cementing hydraulic fill.

Jan 1, 1971