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By A Goldstone, M Fitzpatrick

Contemporary mine wastewater flows are subject to stringent water quality standards before discharge to local waterways. Strict criteria are often applied as a result of fears of extensive acid mine drainage; a feature of the many abandoned mine adits around the Coromandel, Central Otago, and the West Coast. In most cases the USEPA water quality criteria have been used to set treated wastewater discharge water quality standards. In future it is possible that the recently published ANZECC water quality criteria guidelines will be used for this purpose. The ANZECC guidelines also provide for the establishment of discharge criteria at specific sites, rather than accept the trigger values. The use of site-specific criteria for treated wastewater mine discharges was pioneered at the Golden Cross gold mine, near Waihi, in the late 1980s. The procedure used to derive water quality criteria was based on USEPA guidelines. In developing the Golden Cross criteria, only species that occur, or are similar to those that occur in the Waitekauri River were used. The mine commenced discharge of treated wastewater in 1991, and macroinvertebrate communities in the vicinity of the discharge point have been regularly monitored twice a year for the past 12 years. Despite fluctuations in community composition and abundance over that period, no permanent significant changes in the macroinvertebrate communities occurred between sites above and below the treated wastewater discharge. The success of the site-specific criteria at Golden Cross has shown how the application of this methodology can result in the protection of aquatic life while allowing for the discharge of treated mine wastewater.

Jan 1, 2003

By J Abols, T Hughes

The selective recovery of gold and silver from solutions containing other metals, such as copper, is possible using AuRIX«100 resin in conjunction with the Gekko Resin Column. Selectivity is driven by controlling the solution pH, which enables activities such as loading copper, gold and silver and then selectively stripping copper before gold and silver. Alternatively gold and silver can be loaded and the copper left in solution. The selective loading of gold while reducing the silver loading has also been demonstrated, opening the possibility of producing high grade gold dorT from high grade silver pregnant leach solutions. This paper reviews the AuRIX«100 resin and Gekko Resin Column Technologies, discusses the uses of AuRIX«100 in the recovery of gold and silver and the chemistry relating to several projects for which AuRIX«100 is being tested.

Jan 1, 2005

Coal mining in the Bulli seam in the Southern Coalfield in New South Wales has experienced the dangers of outbursts of coal and gas. These incidents present a major risk to the safety of mine workers and consequently a threat to the overall viability of the mining operations. Since the occurrence of a major outburst incident in the South Bulli Colliery in 1991 involving three fatalities, the primary contributory factors associated with coal/gas outbursts in the Bulli coal seam have been identified and a strategy for the management of the outburst risk has been formulated by the cooperation of mine operators, mine workers and the Department of Mineral Resources. Utilisation of risk management techniques in combination with modern gas drainage technologies and geological control methods have led to the formation of this effective outburst management plan. Clause 15 of the Coal Mines (Underground) Regulation 1999 in NSW has made it mandatory in an area of outburst to carry out mining in accordance with a code or guidelines developed for mining in outburst prone areas (DMR, 1999). In this paper an outburst management system is discussed which was developed for collieries in the Southern Coalfield that brings together all the available information including past experiences and risk management techniques in a documented form in order to maximise safety of mine workers. It is concluded that since the introduction of the outburst risk management systems in the Southern Coalfield in 1994 considerable reduction in outburst incidences have been experienced.

Jan 1, 2003

By R Berry

This paper looks at two ways to estimate the bulk mineralogy of the rocks for assay intervals. The aim is to find an efficient indicator of the most common minerals in the rock. Phase (modal) analysis has traditionally been done using visual methods such as point counting and image analysis. A modern version of this process is the X-ray point counting routine using the SEM-EDS based software. These methods are too slow and expensive for routine analysis of bulk sample mineralogy at the normal assay spacing.Two sources of data were considered that provide information that can be used to determine the mineral abundance in assay samples. The most widely applied method is (semi-) quantitative X-ray diffraction (QXRD). The QXRD method is most applicable to major minerals and has limited application to minerals at low abundance. The nominal detection limit is 0.5 per cent. Values below five per cent have large errors. A second, less common, method is calculation of mineralogy from chemical assay data. Conversion of chemical analyses to mineralogical analyses depends on the unique chemical composition of each mineral. Elements only found in one mineral are easily accounted for, but many compositions are ambiguous. Deciding on the actual mineralogy is not simple. Recalculation of mineral mode from chemical analyses is more accurate than QXRD when the correct minerals, and mineral compositions, are known.Where only a few QXRD analyses are available they can be used to setup a protocol for calculation of mineralogy from assay data. Linear programming works well in this environment. The best results are obtained when both H2O and CO2 are directly measured. Loss-on-ignition (LOI) should be included if these are not available.Where both QXRD and chemical analysis are available for all samples, the best results are obtained using the least squared method to merge the data sets assuming QXRD has much higher analytical errors than chemical assays. The combined method provides more robust results because the high abundance minerals are controlled by the QXRD measurements while the chemical assays improve the precision for low abundance minerals

Sep 5, 2011

By P Lamberg, M Lyyr, S Heimala, J Liipo

Since the introduction of froth flotation for industrial practice, the process has long been developed and improved by making cultivated guesses or by using trial and error methods to a varying degree. Fresh possibilities have emerged after development of new surface sensitive analysing methods and in situ electrochemical methods. Having had the possibility to combine different findings between science and everyday plant practice, Outokumpu has been able to develop a catch-all procedure to manage a flotation process taking into account the specific requirements set by different minerals in a slurry. A number of these procedures are available and offered globally to clients as part of a Plant Audit service. The Outokumpu Plant Process Audit (Process ef-X) concept comprises of mineralogical determinations from process samples and plant data analysis together with electrochemical process measurements using mineral electrodes. Automatic control loop analysis can also be included. The objective is to combine the results for a basis of flotation process improvement. Since this methodology has earlier been an in-house practice, it follows that the results are also reflected in the development and design of the OutokumpuÆs processing equipment. An increasing number of ores have a very intimate fine-grained texture and it may be physically impossible to combine high grade with acceptable recovery by a flotation process alone. For such cases, combinations of different hydrometallurgical û mineral separation û pyrometallurgical processes are available. Mineral specific information and chemical expertise of flotation technology can be utilised in development of other processes, as well.

Jan 1, 2005

I have chosen this topic for my address with the intention of preserving a rather extraordinary record of recurrent additions of capital in the financing of one of the world's important silver-lead-zinc mines. The recitation of the trials and tribulations which fore-shadowed the rise of Mount Isa Mines to a position of relative prominence in the realm of non-ferrous mineral production may, I hope, be of assistance to some of the younger members of the Institute who may be called upon during their careers to meet similardevelopmental and financial problems.Mount Isa Mines Limited was incorporated in New South Wales in 1924 with an Authorised Capital of 40,000 shares of £20 each.In November 1925 the Company acquired the leases and water rights of the Mount Isa Proprietary Silver-Lead Limited for 6,250 fully paid £20 shares. Shortly thereafter, but in the same year, the £20 shares were split up into £1 shares, thus bringing the Authorised Capital to £800,000.The leases purchased consolidated and brought under one management the principal ore bodies of the Mount Isa area.Transportation facilities were indispensable to the economic future of the field, so the construction of a railway extending the Government line from Duchess, 54 ,miles to Mo.unt Isa, was assured by the passage of a bill in October 1925 by the Queensland Parliament. Under the provisions of the so-called Mount Isa Railway Act the Company was required to idemnify the Government against national loss on this branch line for a period of 10 years.

Jan 1, 1953

The re-development of the Mount Charlotte gold mine in Kalgoorlie was carried out piece- meal as funds became available. Optimisation of productivity to offset the high risk which is a function of an indefinite gold price, has been the principal objective of the management.

Jan 1, 1980

By D J. Williams, E M. Rykaart

Soil cover systems are routinely used to reduce acid rock drainage (ARD) from mine waste rock dumps and tailings impoundments. A technology for the analysis, design, instrumentation and monitoring of barrier-type (oxygen limiting) and store/release-type covers has rapidly developed and the number of covers under construction has grown extensively during the past ten years. Mine operators are currently investing in this relatively new technology with the expectation that these covers will reduce long-term liability with respect to acid generation, drainage and treatment costs. While the design life for cover systems may extend into hundreds of years, we have less than ten years of construction experience and proven performance. Some cover designs appear to be functioning well; however, the performance of many more is now being called into question. The paper presented herein evaluates the integrity of cover systems from a global perspective. Soil cover systems for the control of ARD are being constructed at mine sites located within high rainfall equatorial regions, deserts ranging from low to high latitude, humid temperate regions, and cold-continental climates. While the technology for analysis and design of soil cover systems is well developed, factors that compromise the performance of cover systems (in addition to the paramount issue of climate) relate to material selection and availability, cost and construction practices. Long-term performance is also strongly affected by physical stability (ie erosion), volume change (ie cracking, desiccation, settlement and freeze/thaw cycling), vegetation, soil evolution and ecological stability. This paper provides a review of the application of soil cover systems for the control of ARD. Cases where cover systems have been constructed with both success and failure are illustrated. General criteria and recommendations for cover selection, design, construction, and maintenance are provided.

Jan 1, 2003

A process was developed based on the thermal hydrolysis and precipitation of iron from solutions resulting from the leaching of zinc plant residue. A study was made of the hydrolysis of iron, at temperatures in the range 140-220°C, in both pure solutions of ferrie sulphate and in leach solutions derived from plant spent electrolyte.At 200°C hydrolysis of pure ferric sulphate solutions results in the precipitation of ferric oxide, Fe2O3, at low acid. concentrations, and a basic salt, Fe2O3.2S03.H20, at hIgher acid concentrations. At 180°C ferric oxide is precipitated at low acid concentrations, but at higher acidities. carphosiderite, 3Fe203.4SO.3.9H20, is the stable phase. Frequently a mIxture of ferric oxide and carphosldente IS produced at 180°C, the ratio of phases being dependent on the non-equilibrium experimental conditions.With solutions derived from plant spent electrolyte hydrolysIS at elevated temperatures results in the precipitation of jarosite compounds of the type NaFe3(S04)2(OH)6 The precipitation of natrojarosite jarosite, and ammonio-jarosite was studied in detail. Temperature, free acidity, and the concentration of sodium potassium, and ammonium ions are critical factors which affect the extent of precipitation.A process based on ammonio-jarosite precipitation was tested in a pilot plant.An alternative method of iron removal based on the addition of zinc oxide calcine, to neutralize excess acidity, and the precipitation of ferric oxide was also tested in the pilot plant. Both processes appear economically favourable...

Jan 1, 1967

In 1985 a 2.5-tonne top blown rotary converter was installed in the silver refinery at Cominco's Trail Operation to carry out the final cupellation of burndown metal to Dore metal. The furnace is fired with an oxygen-natural gas lance which is capable of achieving a variety of furnace conditions, varying from reducing to highly oxidizing. Reaction rates are about 4 times greater than using conventional cupel furnaces. The faster reaction rates improve productivity and reduce in-process precious metal tie-up. The furnace is also used to reduce litharge slag for bismuth recovery.

Jan 1, 1989

By K H. Esbensen

During the next five years Denmark will implement a significant reduction in the national CO2 emissions to fulfil the Kyoto Protocol. The energy sector is central for achieving this goal and extensive use of renewable energy is the most important single factor contributing to reduce emissions of greenhouse gases. DenmarkÆs renewable energy sources comprise wind energy and biomass. Wood chips and straw are the dominant type of biomass in Denmark. More than 500 000 tons of wood chips are used annually, currently with rapidly growth prospects. This contribution focuses on sampling of wood chips.

Jan 1, 2005

The need to describe shape properties of solid particles arises in many applications in the mining and minerals industry. This paper presents a technique for describing the shape of 2D particle profiles from digital images, based on traversals of the circumference of the profile boundary at a succession of different scales. The traversals are undertaken in such a way as to establish a more stable set of results than usually arises from conventional fractal multi-scale shape characterisation techniques. The resulting values can be used to provide compact information on various generic shape features of the particle profile.

Jan 1, 1998

By Sinha NH

ICI Australia and CSIRO have developed a novel process for extraction of zirconia from zircon sands. The two stage process involves a high temperature step and a wet chemical processing step. A pilot plant has been operating since November 1985 at CSIRO Division of Mineral Chemistry, Port Melbourne and construction of a full scale plant isplanned at Kwinana, WA.The plant has a high degree of flexibility and is capable of producing high purity zirconia up to about 99.99% and withinspecific particle size ranges. The products are being marketed by the joint company, 2-TECH Pty Ltd.

Jan 1, 1986

By Stein A

The general mechanism of recrystallisation for cold worked metal is well established, and need be only briefly summarised with a few references to recent articles which clarify minor points. The types of extension, whether by stretching, drawing, hammering, rolling, etc., do not alter the general principles (1), although quantitative results may differ somewhat, particularly with regard to differences between the surface and interior of samples.These principles can be summarised as follows: The first stage in annealing is a recovery (sometimes known as relaxation) of physical properties such as hardness, elongation, etc., without any appearance of recrystallisation; the second stage involves a further alteration in physical properties, accompanying the formation of new recrystallised grains which replace the original structure; a possible third stage involves an increase in the grain size of the completely recrystallised structure by absorption of smaller grains by larger ones. These three stages will be referred to as recovery, recrystallisation, and grain growth. Depending on conditions, the three stages may be clearly marked or may occur more or less simultaneously.For a given annealing temperature, cold deformations below a certain amount fail to give recrystallisation, and the final structure consists of the original grains which have recovered and possibly become more equiaxed. When a certain deformation, critical for that annealing temperature, is given, recrystallisation can occur, and will give the maximum recrystallised grain size.Increasing deformations beyond this give progressively smaller grain sizes.For each material there is a minimum recrystallisation temperature, below which recrystallisation will not occur whatever the deformation or time of annealing. For a given deformation there is a temperature, critical for that deformation, below which recrystallisation will not occur, and above which it will take place with increasing rapidity.

Jan 1, 1947

Mining is still a significant economic activity within the Hauraki District. The Martha project is particularly significant. Estimates are that in the order of 850 direct and indirect jobs are derived as a consequence of the Martha project within the Waikato Region. The Resource Management Act 1991 (RMA) is New Zealand's primary piece of environmental legislation. It sets out to provide the framework for the control of the use, development and protection of almost all physical and natural resources. Minerals are excluded from the sustainability requirements of the legislation but as mining invariably involves the use of land, all the other elements of RMA apply. The Council's role in dealing with mining changed with the introduction of RMA. It became responsible for administration of those matters that fell within the functions set out in section 31 of the RMA in respect to existing authorisations. Mineral development needed to be considered in the development of the District Plan that the Council is required to prepare. Implementation of the Act has been a challenge for not only local government but for many industries and resource users since it came into force in 1991. There have been, and are, differing views on both the way it is administered and its intent. The Hauraki District Council has been at the forefront of some of the challenges that are a consequence of the Act. Its reactions to these challenges have been consistent. It treats mining in the same why it treats any other industry. At times this approach has not been understood and without challenge from sections of the community.

Jan 1, 2000

By A McRae

Much of western New South Wales is characterised by an extensive regolith formed during more than 60 million years of exposure, weathering and erosion. This cover includes intensely weathered in situ regolith and superimposed transported materials of variable thickness, commonly in complex palaeochannel systems. Mineral exploration in this region has been considerably hampered by the cover, which can complicate or maskgeochemical anomalies and also obscure geophysical signatures. A detailed multi-disciplinary study of part of this region, centred on the Cobar-Girilambone area has demonstrated a methodology for exploring through this regolith. The approach involves regolith-landform mapping to establish the main landscape and palaeolandscape elements and to determine the nature and spatial occurrence of different regolith materials. By combining knowledge of the surface distribution of different regolith-landform units with available 3D information on the regolith and geophysical data it is possible to construct simplified derivative maps or exploration ægoÆ maps, which can be used to advise appropriate exploration strategies or help interpret acquired exploration data. This study has also established the major regolith controls on geochemical dispersion and determined key background element associations. These regolith-related element associations can result in highly variable background levels for many trace elements and need to be understood and factored into the analysis of geochemical data for different regolith sampling media. With better knowledge of the regolith it is possible to select the most appropriate exploration techniques and sampling media for a given area, as well as apply appropriate normalisation procedures to the acquired data. Exploration success can be greatly improved by using many existing techniques in æregolith smartÆways.

Jan 1, 2004

By J Jeffrey, G W. Wilson, L Gilbert, C

Prior to the commencement of mining, the acid rock drainage (ARD) potential of the waste rock to be produced by an open cut mining operation is assessed by a variety of techniques carried out on drill-hole samples. These include, among others, acid base accounting (ABA), net acid generation (NAG) testing, and kinetic testing. Based on the results obtained, a strategy for the identification, separation and selective placement of waste rock having different potentials to form ARD is developed. During the course of mining, the waste rock classification scheme will be re-assessed periodically to confirm that it is appropriate. This re-evaluation may result in a change in classification scheme, and waste rock dump samples may be obtained for ARD assay purposes to confirm the appropriateness of the revised scheme. The paper describes the evolution over time of the scheme used to classify waste rock at a major open pit gold operation in New South Wales, Australia, including the development of a hydrological model. To confirm the appropriateness of the revised scheme, ARD assay testing was carried out on drill-hole samples collected from dumps having different ARD potential designations, including Non-Acid Forming (NAF), Potentially Acid Forming (PAF), and Low Grade Ore stockpiles. The results of the ARD assay testing and water quality monitoring confirmed the appropriateness of the ARD potential designations and the revised classification scheme, which has been adopted.

Jan 1, 2003

By G K. Robinson

Variations in many aspects of physical and chemical grade are often of concern to mining operations and mineral processing plants. In most circumstances these amounts of variation are predictable. At the time of planning new operations, we should be able to predict the amount of sampling and testing variation which our sampling devices, laboratory procedures and on-stream analysis devices will achieve. We should know how well our stockpiles, reclaimers and bins will homogenise material (or whether segregation will actually increase the amount of variation). We should be able to predict the amounts of variation that will occur on the important time or tonnage scales at the crucial p oints in our proposed operation. And once these amounts of variation are reliably known, mine planning will seem a little bit more like dealing with known knowns rather than like dealing with unknown unknowns.The first step towards quantifying amounts of variation for planned operations is to assess amounts of variation for existing operations. How many operations have estimates of amounts of variation in their databases? How often are people able to partition amounts of variation into amounts due to sampling error, amounts due to sample preparation, amounts due to assaying, and the amount of real variation in the stream of material?CITATION:Robinson, G K, 2012. Making sure that the amount of grade variation is a known known, in Proceedings Project Evaluation 2012 , pp 159-162 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 24, 2012

By P Gnnther, A M. van Niekerk

Coal mining operations in the Upper Olifants River Catchment in the Mpumalanga Province of South Africa are challenged with the increasing production of excess mine water that cannot be fully managed by existing practices of pollution control at source, recycling, and reuse on mining sites, storage and limited release to the natural water course. In contrast to this, the Olifants River Catchment is experiencing water stress and insufficient water is available to satisfy all water quantity and quality requirements for future industrial and municipal growth. It is estimated that the catchment has a deficit of 192 million m3 per annum if the reserve water requirements are taken into account. The future increased water requirements can be met by water transferred to the Olifants River Catchment from adjacent catchments. The cost of transferred water is likely to be substantially higher than the current cost of water supplied to local municipalities, commerce and industry. BHP Billiton and Anglo Coal Corporation are working together to jointly implement water management strategies that will contribute to the achievement of in-stream and dam water quality and aquatic objectives for the catchment. Consideration is now being given to the treatment and beneficial use of excess mine water. This will inaugurate a new era for the coal mining industry in South Africa, in which a pollution threat to the water resources in the Upper Olifants River Catchment is converted into a water source for beneficial use. Three potential mine water reclamation and reuse schemes have been identified and this paper details the technical, institutional, legal and financial considerations in the implementation of these schemes.

Jan 1, 2006

By D S. Clarke, K B. Sporli

Structure is an important control in the localisation of gold mineralisation in epithermal systems. There has been, however, only limited investigation of the structural elements involved; such a study is currently directed at the gold deposits of the Coromandel Volcanic Zone (CVZ). Here, mineralised veining and brecciation ranges up to tens of metres in thickness. Dips of veins are mostly steep, but not vertical, and there is a significant number of low angle veins. The structural control of epithermal deposits may be considered on four scales. At the mega-tectonic scale, pre-volcanism fault patterns mostly relate to separation of the New Zealand micro-continent from Gondwana. The major structural controls on mineralisation at this scale, however, are associated with the volcanic arc processes responsible for the CVZ. Post-mineralisation faulting are linked to the Hauraki Rift and the Colville Ridge-Havre Trough system. Regional scale faults controlling the distribution of gold deposits are the product of these tectonic events; much of the faulting may relate to rifting and calderas, but further work is required to demonstrate this. Detailed study is also needed on vein systems at the prospect scale to validate models of brittle deformation responsible for such systems. Evidence that a variety of structural mechanisms dominated in different deposits is found at the vein scale, with Coromandel gold deposits being classified according to their different styles of vein-fill texture.

Jan 1, 1990