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By U Berg, T Neumann, Y Song

Eutrophication of water bodies is one of the most severe environmental problems worldwide. It is well known that the availability of phosphate, as the limiting nutrient, is crucial for increased primary production and eutrophication. Calcite exhibits positive surface charge in most natural waters and can therefore be used for phosphate immobilisation. In this study, sorption experiments were performed in order to test different calcite materials regarding their suitability for use in restoration of eutrophic lakes. These short-term experiments were performed under different hydrochemical conditions (pH, SICC, initial dissolved P concentration) and with varying calcite properties (specific surface area and amount) in order to predict the long-term stability of the Ca-P-bonds. Peculiar shapes of isotherms that could not be explained only by adsorption processes were detected in the individual experiments. Depending on the residual P-concentration in solution, the isotherms can be divided into three sections indicating different processes responsible for the P-fixation on calcite surfaces. Adsorption prevails in equilibrium with lowest residual P-concentrations. The inflection of the isotherm at moderate residual P-concentrations suggests that precipitation and transformation of a Ca-P compound becomes dominant. This is supported by characteristic Ca/P-ratios for different Ca-P-compounds (b-tri- calcium-phosphate, octa-calcium-phosphate). On the new surface, phosphate ions again are fixed by adsorption. The observed transformation of P-bonding is crucial for sustainable phosphate immobilisation on calcite surfaces. While pure adsorption processes are reversible, the development of a thermodynamically stable Ca-P-phase, like hydroxylapatite, will lead to a lasting immobilisation of phosphate.

Jan 1, 2008

Titanium tetrachloride may be reduced to trichloride with hydrogen on a hot tungsten filament and other hot: surfaces. The effect of temperature, time and size of t.he filament on the rate of reaction has been studied. A laboratory unit for preparing a few pounds of trichloride at a time is described. The yield of trichloride is 2·2 - 2·4 gm/sq. cm. of hot surface/hour at 1,000°C. and the energy requirement 3'5-4 kWh/pound of trichloride produced.'INTRODUCTIONThe lower chlorides of titanium (titanium tri- and dichlorides) are amenable to electrolysis, being electrovalent in nature. Furthermore, relative to other oxygen-free titanium salts, they are easy to prepare in a pure state and their use has been investigated to prepare titanium. The experimentaJ work described in this paper deals with the preparation of titanium trichloride by reduction of titanium tetrachloride with hydrogen on hot surfaces.REDUCING AGENTS FOR TITANIUM TETRACHLORIDEThe free energy diagram (Fig. 1) for the formation of chlorides suggests that titanium' tetrachloride may be reduced to trichloride by various reducing agents such as aluminium, zinc, arsenic, antimony, tin, mercury, silver, hydrogen, sodium, potassium and magnesium. Ruff and Neumann (1923), Thorpe (1885) , Billy and Brasseur (1935) and Seurbert and Schmidt (1892) used various metals to reduce tetrachloride to trichloride and found that the yields were invariably low and the products difficult to separate.Besides the metallic reducing agents, hydrogen may also be used to reduce titanium tetrachloride to trichloride.Goerges and Stahler (1909) obtained a deposit of violet...

Jan 1, 1956

By D R. Lueking

A technology involving separate unit processes for the generation and use of ferric ions for the oxidation of sulphidic minerals has been developed. The technology utilises a stand-alone automated bioreactor for ferric-ion generation (termed SAAB-FIG) and produces a low pH, ferric ion-rich leach liquor with a high oxidation potential. This leach liquor is then employed, in a separate unit process, to oxidise sulphidic minerals and regenerate ferrous iron that may subsequently be recycled to the bioreactor for the continual generation of ferric ions. The technique was successfully applied for the recovery of copper from chalcocite (Cu2S) and chalcopyrite (CuFeS2), as well as other ores and concentrates containing copper sulphide minerals. Coarse ore, ground ore and concentrates were treated with acidic solutions containing 8 to 12 (g/L) Fe(III) ions at a variety of temperatures. This process yielded over 50 per cent of the contained copper from both chalcopyrite and chalcocite samples. Maximum reaction rates and copper recoveries were found to be highly dependent upon temperature and pH and leach liquors containing bacterial cells displayed little difference in their leaching efficiency when compared to cell-free leach liquors.

Jan 1, 2000

By A Yame, P J. Pollard, E Atase, J Garu, M Tangwari, D R. Hastings, R W. Smillie

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Townsville prospect is situated approximately 4 km north of the Ok Tedi copper-gold mine in Western Province, Papua New Guinea. Drilling in the 1990s delineated a resource of >1 Moz of gold within shallow, skarn breccia-hosted mineralisation associated with quartz-carbonate infill, together with pyrite, chalcopyrite, pyrrhotite, sphalerite, galena, tennantite-tetrahedrite, arsenopyrite, marcasite, and a variety of Au-, Ag- and Bi-telluride minerals. The deepest of these historical holes (TVL034) also intersected copper-gold-silver mineralisation more than 100 m below the gold-rich zone that is associated with calc-silicate skarn breccia. Although copper-gold-silver mineralisation in DDHTVL034 is associated with clinopyroxene-rich skarn, it was also noted that garnet in the skarn breccia became progressively darker in colour with depth, ranging from green at shallow levels to dark red-brown at depth. This indicated that the skarn breccia is zoned, with more proximal garnet skarn at depth possibly indicating an association with porphyry-style copper-gold mineralisation.Based on this skarn zonation model, recent drilling at the Titan prospect, located approximately 500 m south of TVL034, was targeted at potential copper-gold silver mineralisation beneath shallow skarn breccia-hosted gold mineralisation. DDHTVL 081 intersected 46 m at 6.36 g/t Au from 68 m and 80.7 m and 1.67 per cent Cu, 1.27 g/t Au and 20.32 g/t Ag from 184 m. Exploration is now attempting to define the extent of copper-gold-silver mineralisation by defining structural controls on the skarn breccia together with paragenetic and mineral zoning data.CITATION:Smillie, R W, Pollard, P J, Hastings, D R, Yame, A, Tangwari, M, Garu, J and Atase, E, 2015. Exploration of the Townsville Cu-Au-Ag skarn, western province, Papua New Guinea – preliminary observations of paragenesis and zoning, in Proceedings PACRIM 2015 Congress, pp 593–600 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

Blasting has been the most frequently used method for rock breakage since black powder was first used to fragment rocks, more than two hundred years ago. This paper is an attempt to reassess standard design techniques used in blasting by providing an alternative approach to blast design. The new approach has been termed asymmetric blasting. Based on providing real time rock recognition through the capacity of measurement while drilling (MWD) techniques, asymmetric blasting is an approach to deal with rock properties as they occur in nature, ie randomly and asymmetrically spatially distributed. It is well accepted that performance of basic mining operations, such as excavation and crushing rely on a broken rock mass which has been pre conditioned by the blast. By pre conditioned we mean well fragmented, sufficiently loose and with adequate muckpile profile. These muckpile characteristics affect loading and hauling (Scott, 1996). The influence of blasting does not end there. Under the Mine to Mill paradigm, blasting has a significant leverage on downstream operations such as crushing and milling . There is a body of evidence that blasting affects mineral liberation (Djordjevic, N, 2001). Thus, the importance of blasting has increased from simply fragmenting and loosing the rock mass, to a broader role that encompasses many aspects of mining, which affects the cost of the end product. A new approach is proposed in this paper which facilitates this trend æto treat non-homogeneous media (rock mass) in a non-homogeneous manner (an asymmetrical pattern) in order to achieve an optimal result (in terms of muck-pile size distribution)Æ. It is postulated there are no logical reasons (besides the current lack of means to infer rock mass properties in the blind zones of the bench and onsite precedents) for drilling a regular blast pattern over a rock mass that is inherently heterogeneous. Real and theoretical examples of such a method are presented.

Jan 1, 2001

Drum winders have now been built to attain depths of 3000 m and more in a single lift in accordance with the South African Code of Practice SABS 0294, which was introduced at the time of the last hoisting conference in 2000. Since then, this code has not only been followed for several winders in South Africa but was also followed in deep mines in Canada. Design of winders and their braking systems are described in the paper. Koepe winders are in use for high payloads of up to 50 t and to hoisting depths of around 2100 m. As known, the stress range of the hoisting ropes is the key parameter for rope fatigue. However, as per the SABS Code of Practice 0294, relying on static design is not the answer to the question of where the limits are for Koepe installation. The paper describes factors that are recognised to have influence in rope life and suggests definition of new design criteria for friction winders in order to get viable solutions for high-capacity hoisting from deep mines similar to drum hoisting.

Jan 1, 2005

The geology of an area in north-western New South Wales, bounded by the South Australian and Queensland borders, latitude 32° S. and longitude 14° E. is discussed.The area involved includes sixteen 1:250,000 standard military sheets and covers approximately 96,000 sq. miles.The geology of the Willyama Complex is not dealt with but a small area of metasediments previously included in this unit is separated and a possible correlation with Precambrian to the east is suggested. Torrowangee Group sediments are described and the problem of nomenclature using a glacial implication is raised.Nine areas of proven Lower Palaeozoic sediments are considered and their relationship to the boundaries of the Bancannia Trough outlined. It is possible that some exposures not yet substantiated by fossil evidence may prove to be Lower Palaeozoic rather than Precambrian in age.The sediments of the Lachlan Geosyncline in the area of the Cobar massif are described and new concepts on the age and distribution of some of the established stratigraphic units are introduced. The absence of rocks of Middle Silurian age probably indicates the time of a major orogeny in this area.Lithology, thickness, and distribution of the Upper Devonian sediments is considered and some of the more recently found fish plate localities are listed.Mesozoic sediments occur in isolated areas of Lower Jurassic age and in the Great Australian (Artesian) Basin. A four-fold subdivision of sediments of the basin has been possible in some areas but lack of sub-surface information at present, precludes the possibility of correlation with the type sections in Queensland.Units in the Cainozoic are subdivided and a five fold subdivision of the Quaternary, at present being used throughout western New South Wales, is described.

Jan 1, 1969

Anodic stripping voltammetry is an analytical technique which has established some popularity for trace analysis of metals because of its sensitivity, selectivity and capability for simultaneous analysis of some elements. The technique can be readily adapted for field use because of its relative simplicity and low power requirements. This paper describes a relatively new instrument, the Portable Digital Voltammeter, developed by CSIRO, which utilises the glassy carbon electrode in a novel cell design and provides parts per billion (ug/L) sensitivity in an instrument which can be field operated. Ten elements, Zn, Cd, Tl, Pb, Cu, Sb, Bi, Hg, As and Au can be routinely analysed. Many of these elements are of interest to the mining industry, and to exploration geochemistry in particular. Case histories where the instrument has been successfully employed for stream and stream sediment analysis of Cu and Pb, for soil surveys of Cu and Au, and for Au in stream sediments and drill chips indicate there are advantages in having on-site data, during Exploration.

Jan 1, 1987

In the past few years the Rietveld method emerged as a routine tool for quantitative phase analysis (QPA) from X-ray diffraction data. Fast and reliable results became possible by combining modern computer technology and optimised mathematical algorithms with the fundamental parameters approach in the Bruker AXS TOPAS software. Here the routine analysis of bauxite raw material and of aluminium bath electrolyte is presented. The accuracy of bauxite quantification was tested by analysing the IUCr round robin sample. An agreement of better than one per cent was obtained for minor constituents and a maximum deviation of 2.5 per cent for the major phases. This is excellent agreement with expected results from weighting. Ten different phases were quantified in natural samples from Turkey with a precision better 0.5 per cent for the major phases and one per cent for the minor phases. Additionally, crystallite sizes were obtained from the peak profiles that give valuable information for the processability of the material. XRD data from solidified aluminium electrolytes were rapidly measured using silicon strip detector technology. With the LynxEyeTM detector full patterns were collected in 90 seconds and analysed with TOPAS. It is shown how to derive well-established measures such as bath ratio and excess AlF3 from the Rietveld results. These measures are widely used in aluminium production and readily available with very high precision. The excellent agreement with ALCAN reference data demonstrates the outstanding accuracy of the method. The mean deviation between here presented results and reference data is below 0.5 per cent for total CaF2, below 0.25 per cent for excess AlF3 and 0.02 for the bath ratio. The precision of the method was evaluated by repeated measurements.

Jan 1, 2008

Sample preparation for gold samples, where the distribution and size of gold particles is often irregular, usually demands that a relatively large sample weight is taken to produce a representative sample for analysis. Traditional sample preparation of gold samples incorporated multiple stages of coarse particle size reduction followed by subdivision of the sample prior to final fine pulverising. This technique developed because of the limited equipment options available to laboratories. As a result significant errors are introduced and the final sample size being pulverised is a small fraction of the original sample weight. Three significant developments have occurred in the last 25 years to significantly improve sample preparation of gold samples: 1.  large capacity fine pulverising,2.  fine jaw crushing, and3.  whole sample coarse pulverising. In the mid-1980s an Australian manufacturer developed large capacity pulverising bowls which had the ability to reduce samples with a mass of 1.5 - 3.5 kg to a nominal 0.075 mm product in approximately three to five minutes. Laboratories were able to produce a large homogeneous pulverised sample which significantly reduced the error in sampling. However, exploration and mine samples are usually 7 to 10 kg and the sample requires a subdivision stage following crushing to produce the 3.5 kg for the pulverising step, thus introducing potential for significant error. The development of fine jaw crushing allowed particle size reduction to -2 mm which reduced the subdivision error of the bulk sample prior to fine pulverising. Subdivision of the crushed sample at -2 mm still results in potential sampling errors, where the gold particles are not sufficiently liberated to be representatively sampled. Clearly the best option would be to reduce the particle size small enough to ensure a representative sample prior to final pulverising. Continuous mills offer a partial solution but are relatively slow and subject the sample to differential pulverising prior to subdivision. Clearly this does not provide the best solution for routine laboratory applications where high volumes of samples are to be processed. The recent development of a large capacity coarse pulverising system allows samples of up to 10 kg to be reduced to -0.25 mm prior to subdivision, and fine pulverised to -0.075 mm. Laboratories now have the necessary equipment to perform reliable large capacity sample preparation of gold samples. The exact choice of a sample preparation scheme may still depend on particular ore types but the need for multiple crushing and subdivision stages is redundant.

Jan 1, 2008

The Yilgarn Block of Western Australia presents (figure 1) a number of problems for conventional diamond exploration based on heavy indicator mineral sampling. These problems are due to the geology and unique geomorphological development of the Yilgarn Block.Essentially the Yilgarn Block is a pene- plain developed on a craton composed of Archaean intrusive granitoid rocks with meta- morphosed greenstone; which, apart from regional uplift, has not been tectonically disturbed since planation by glaciation in the Permian. Therefore since the early Plesozoic the Yilgarn Block has been subjected to terres- trial weathering conditions. Bettany et al., (1984) identify two phases of particular importance in the development of the present landforms: 1. Periods of lateritization during the Tertiary which result in the ~lassi~al laterite profile (figure 2). Duricrust indurated : Fe and Al oxides Mottled zone : Clay and Fe oxides Saprolite or pallid zone : leached clay grading into fresh rock. 2. Subsequent periods of aridity and semi- aridity during which laterite development was truncated and reworking of laterite Occurred.

Jan 1, 1988

About 60 persons are admitted to the graduate course every year after passing the entrance examinations. The entire course of studies is free of charge and the universities provide accommodation for the students who need it. The five years of studies are divided into 10 semesters. One semester lasts 15 weeks. Automatics can be studied at three separate faculties. At the University of Mining and Metallurgy, it is offered by the Faculty of Electrical Engineering, Automatics and Electronics as well as the Faculty of Mining and Metallurgical Machines (metrology can also be studied there); at the Silesian Technical University in Gliwice, the Faculty of Mining offers the course. The educational plans and programmes comprise 3 groups of subjects: common for a given course of studies (foreign languages, political science and the basic technical knowledge) common for the speciality and subjects of diploma courses. The whole time of studies covers about 4400 hours excluding 3 periods of professional training and the physical training. The classes, laboratory classes, seminars and design classes are obligatory and the attendance is strictly checked. Students may extend their knowledge by participating and working in the Science Clubs. The students' work is checked not only during the classes but also by the examinations held at'the end of respective semesters. Those who fail the exams can repeat them only if very important reasons are presented. At the very end of the studies there is a diploma examination together with a discussion on the diploma thesis, written by the student. The successful result entitles the student to recieve the title of "magister inzynier",M.Sc. of his speciality. The graduates, after working for 2 years, can attend another course of studies lasting 2 semesters and called "Postgraduate Course", or start "Doctoral Studies" finished by the defence of a doctor's thesis. In'these cases the expenses are usually covered by the graduates' employers.

Jan 1, 1985

By M Fuchs

Roadheaders were introduced to mining and tunnelling in the early-1960s. Since this period their main field of application has been for roadway drivages in coal mines and for mineral production, for instance in coal, rocksalt, potash and gypsum mines. Their main field of application in tunnelling is in softer and partly friable rock formations, a suitable area for non-blasting excavation. However, in longer tunnel sections excavators with high ripping forces have replaced roadheaders in many situations. The main arguments against roadheaders have been and still are:a sharp increase in excavation cost with increasing rock strength and increasing abrasivity; and greater risks in conditions which have not been, or could not be, investigated to a sufficient extent. These arguments have, to a great extent, restricted practical roadheader application in production mining and in a lot of æstandardÆ tunnel projects. To address these limitations, factors which could make roadheaders attractive for such conditions and could overcome existing technological difficulties have been investigated. Extension of the economic field of application in hard rock was found to be the most important and the most effective step forward.

Jan 1, 2002

By Smith E. L

The Ore Reserve/Exploration System implemented at Mount Isa for M.I.M. Holdings Limited is a comprehensive computer system designed to process assay, geological, structural and survey data input via special purpose logging sheets from daily activities at Isa Mine, Hilton Mine and various Carpentaria Exploration Company prospects. The system performs two basic functions; (1) data acquisition, validation and file maintenance to prepare the data for retrieval, and (2) generation of routine and optional reports. The types of reports available range from masterfile detail printouts and retrieval of data by key items to survey computations, structural analyses, cutoff calculations, statistical analyses and ore reserve calculations by the polygonal, inverse square or moving average techniques. The use of various optional reports available through the system is illustrated by several examples, and planned future development is discussed.

Jan 1, 1973

By M, C Silveira, C Ellice, D Christensen

Peak Gold Mines (PGM), a member of the Rio Tinto Group, is an underground and open cut gold mining operation located near Cobar, NSW. A multi-phase study was initiated in 2001 in support of developing a dry æmoisture store and releaseÆ cover system design for the PGM tailings dam, which contains potentially acid-forming tailings material. The first phase consisted of characterising the tailings and potential cover material (waste rock from an open cut operation) as well as soil-atmosphere cover design modelling. The second phase involved construction of two cover system field trials on the tailings dam and installation of a variety of field instruments to monitor the hydraulic performance of the test covers during all seasons of the year. Field performance monitoring commenced in April 2002 and will continue for a minimum of two wet-dry climate cycles (third phase), prior to using the field data for calibration and subsequent validation of numerical models developed for the cover system trials (fourth phase). This paper describes the work completed for the first two project phases and also discusses the initial performance of the cover system trials.

Jan 1, 2003

By Chapman RL

A new process has been developed to remove the impurities copper, cadmium, cobalt and nickel from a zinc plant electrolyte by cementation on zinc dust. The process has been tested in the laboratory and in a continuously operated pilot plant. It has been found that cadmium, in the presence of small amounts of antimony in solution, assists the removal of cobalt. Cementation is conducted in two stages: the first stage for removal of copper with a small excess of zinc dust to produce a relatively high grade product, the second stage for removal of cadmium, cobalt and nickel by addition of zinc dust in the presence of anti- mony. The excess zinc and the cadmium present in the second stage cementate can be selective- ly recovered by slow leaching in spent electrolyte. Zinc dust processes in use elsewhere are described and compared with the present system for use in the Risdon circuit.

Jan 1, 1984

By Smith KS

Mineral-deposit geology, geochemical processes, and biogeochemical processes are fundamental controls on the environmental conditions that exist naturally in mineralized areas prior to mining, and that result from mining and mineral processing. Input from economic geologists and geochemists is therefore crucial to effectively predict, assess, mitigate, and remediate the environmental effects of mineral-resource development. Recent open pit gold mining at Summitville, Colorado, has received intense public scrutiny for a variety of environmental problems, most important of which has been extreme acid drainage. Now a Superfund environmental cleanup site, Summitville exemplifies how economic geology and geochemistry principles (1) could have been better utilized to first predict and minimize the environmental problems, and (2) can now be used to optimize the environmental cleanup.

Jan 1, 1995

By Abdurazakov A, Avrakhov A, Solozhenkin P

The flotation properties of acetic acids modified by xanthic and dithiocarbamic fragment in regards to copper and ferrous minerals and their noble metal containing ores have been investigated. The effectiveness of the co-using of these reagents with xanthates and dithiocarbamates has been shown, ie using of proposed reagent regimes for the flotation of Au-containing ores increases gold recovery by 4.2 - 4.7 per cent, and in the case of flotation of copper Re-containing ores copper recovery increases by 3.3 per cent, rhenium recovery - by 15.5 per cent. The mechanism of the action of these reagents has been explained by the data of UV and ESR-investigations of their sorption on mineral surface. The information on structure and properties of co-ordination compounds of some metals with (Diethyldithiocarbamato) acetic acid were used also for the explanation of flotation mechanism.

Jan 1, 1993

The Gj0vik Olympic Mountain Hall is the world's largest underground cavern for public use and was created primarily to facilitate the ice hockey tournaments for the 1994 winter Olympics in Norway. The cavern has a span of 61 m, is 91 m long and is 25 m high. Ordinarily, rock caverns have a span width of 15 to 25 m, however, temporary mining caverns of up to 60 m have been excavated and natural caves with even greater dimensions occur. The Gj0vik Olympic Mountain Hall is unique as it is for public use with a capacity for 5800 spectators. Blasting was conducted with a high production rate at normal costs due to detailed planning and strict supervision of each round. The initiation system and vibration monitors were the main tools to control vibration levels and to facilitate a high production rate. It was of utmost importance that the rock remaining in the roofs and walls was of high quality after blasting to avoid rock fall, rock slides and excessive maintenance work.

Jan 1, 1995

By B Banerjee, H Masoumi, X Shen, S Raval, D Tannant

Structural mapping of pit walls can be performed using digital images and photogrammetry software, but the performance is limited by weather and environmental conditions including dust, rain and light. On the other hand, active sensors such as terrestrial laser scanners (TLS) and total stations (TS) suffer from vertical orientation bias and occlusions when persistent discontinuities dip at the same angle as the scanner line-ofsight. The recent development of the compact light detection and ranging (LiDAR) systems has made it possible to mount these sensors on unmanned aerial vehicles (UAVs) or drones which offer the potential to overcome limitations that are inherent in existing mapping systems. This study details the research involving integration and application of an advanced UAV-LiDAR system for structural mapping of a highwall. A state-of-the art laser scanner with an inertial measurement unit (IMU) and real-time kinematic global positioning system (GPS) was integrated on to a UAV. The system was first tested in a laboratory condition. Then the UAV-LiDAR system was employed to map a highwall of a coal mine. The planned flight trajectories tested the system at variable distances from the highwall face and at various speeds. The raw data collected from individual sensors were fused, filtered to remove noise, and segmented to produce a surface scan model. Finally, the point density and surface coverage were measured using the surface scan model of the highwall. The parameters were compared with equivalent measurements computed from a reference TLS data. The study demonstrates the capabilities of a UAV-LiDAR system to generate accurate and occlusion free data for mapping highwall geological structure with very quick and efficient flights in the field. CITATION:Raval, S, Banerjee, B, Shen, X, Masoumi, H and Tannant, D, 2018. Evaluation of a UAV-LiDAR system for mapping geological structures in an open pit highwall, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 496–503 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018