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By T. Bednarski, T. McCallum

"Physical impurity transfer in solvent extraction (SX) has a significant impact on operating costs, electrowinning (EW) performance, and cathode quality. Some operations use a wash stage to limit impurity transfer by diluting the entrained pregnant leach solution (PLS) to prevent direct transfer to EW. Wash stage operating conditions vary impacting impurity transfer. A number of factors impact dilution efficiency including mixer continuity, wash aqueous acidity, and organic quality. The impact of these variables on dilution efficiency was studied and compared to current industry practice. INTRODUCTION With the exception of iron, impurity transfer in copper SX is due to PLS carryover in the loaded organic via aqueous entrainment and crud movement. The quantity of impurity transfer is influenced by many variables including operating set points, organic quality, and settler housekeeping. Crud management and treatment is a common practice aimed at minimizing transfer of impurities to EW. Crud is a complex solid-stabilized emulsion of aqueous and organic[9]. As such, it contains a large aqueous component and the associated impurities (from the PLS). A common practice is to remove interfacial crud to prevent movement. Additionally, mixer continuity can be altered to enable compaction and improve the efficiency of interfacial pumping[10]. Understanding the factors impacting aqueous entrainment and optimizing the available controls should be a key focus for any operation. Aqueous entrainment in the loaded organic can be impacted by: • Mixer continuity • Mixer organic/aqueous (O/A) ratio • Mixer speed and impeller type • Organic and aqueous depths • Specific settler flow • Use of settler internals (picket fences, coalescing packs) • Organic quality • Design and operation of loaded organic tanks Conventional thought is to run the E1 mixer in aqueous continuity to reduce aqueous entrainment. Generally, O/A ratios close to 1:1 result in improved metallurgical and physical performance. Mixer speeds should be chosen to achieve acceptable stage efficiencies while minimizing over-mixing. Organic depths can be increased in the E1 stage to increase retention time and minimize aqueous entrainment. Settler internals can also be used, but require maintenance to maintain effectiveness. The quality of the plant organic inventory will impact physical performance. Poor organic quality can lead to higher phase disengagement times increasing impurity transfer to the electrolyte. Additionally, the design and operation of the loaded organic tank can impact impurity transfer[8]. Despite the variables that can be used to reduce aqueous entrainment and crud movement, impurity transfer is still an issue in some operations. For these operations with high PLS impurity concentrations, a wash stage may be beneficial to manage impurity transfer. Understanding factors impacting wash stage performance is important to optimize performance and limit impurity transfer."

Jan 1, 2016

By Dale R. Ralston, Roy E. Williams, Gerry V. Winter, George L. Bloomsburg

Jan 1, 1986

With commodity prices rising again and market conditions stabilizing, the Metals Economics Group (MEG) found that most mining companies increased their exploration budgets in 2010. In the groups 21st edition of the Corporate Exploration Strategies (CES), MEG found a 44-percent rise in the estimated worldwide exploration total for 2010. MEG found that the estimated total 2010 budget for nonferrous metals exploration reached $12.1 billion, reinstating almost two-thirds of the industry?s $6 billion in cuts to exploration in 2009. Nonferrous exploration refers to expenditures related to precious and base metals, diamonds, uranium and some industrial minerals; it excludes iron ore, aluminum, coal, and oil and gas. In 2008, exploration budgets were at an all-time high of $14.4 billion. This capped a six-year run in which budgets rose. In 2009, nonferrous exploration budgets dropped 42 percent in 2009 as the global economic crisis and declining prices for almost all commodities took their toll on the industry. Metals prices - the primary driver of exploration spending - have improved markedly since bottoming in early 2009, and have traded well above their long-term trends throughout 2010. In response, major, intermediate and junior companies have all increased their aggregate exploration allocations in 2010. In particular, the significant improvement in the availability of equity financings for the juniors over the past 12 to 18 months has allowed this group to account for the largest share of the overall increase in exploration spending this year.

Jan 1, 2011

By P. C. O. Chukabarah

Many aerodynamic and thermodynamic properties, such as temperature, pressure, velocity and density vary widely, and in random spatial and temporal manner for a given underground mine environment. Such variabilities are seldom evaluated statistically, even though the relevant theories and principles for such an approach are both available and feasible. The main purpose of this paper was to introduce the new methodology of applying aerostatistics to the analysis of multiple fan system in mine aerology and/or ventilation. Pertinent data were obtained from a small multilevel coal mine. Results proved and confirmed that aerostatistical methodologies are computationally more efficient, grounded in solid engineering statistical theories, and can be used to analyze networked parameters in mine environmental engineering.

Jan 1, 1994

By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk, T. Punt

This study investigated the performance of citric acid as lixiviant for cathode material from end-of-life lithium-ion batteries (LIBs). Black mass containing 84.2 weight percent MNC (LiNi0.45Mn0.4Co0.15O2) and 15.8 weight percent LCO (LiCoO2) material was leached at solid-to-liquid ratios of 20, 50 and 100 g/L. Leaching with 1.5 M citric acid, 2 volume percent H2O2 and a solid-to-liquid ratio of 20 g/L at 95 °C extracted 90 percent Co, 95 percent Li, 94 percent Mn and 94 percent Ni within 20 min. At the highest solid-to-liquid ratio of 100 g/L with 1.5 M citric acid, 10 volume percent H2O2 and 95 °C, 84 percent Al, 84 percent Co, 87 percent Li, 86 percent Mn and 96 percent Ni were leached after 40 min, producing a leach solution containing 0.68 g/L Al, 20.0 g/L Co, 6.0 g/L Li, 13.6 g/L Mn and 19.3 g/L Ni. Using stepwise addition of H2O2, instead of initial bulk addition, did not significantly improve the leaching efficiency but did reduce the required leaching time. Temperature control of the reactor was also more manageable with stepwise addition of H2O2, and evolution of gas was less vigorous. It was observed that the leaching efficiencies of Co, Li and Mn decreased slightly at solid-to-liquid ratios of 50 and 100 g/L, while the leaching of Ni increased slightly. The solution leached at 20 g/L could be stored for six weeks without any spontaneous precipitation. However, solutions leached at 50 and 100 g/L showed changes in concentration after one month of storage, suggesting that processes that have a large material throughput and use high solid-to-liquid ratios around 100 g/L must ensure that the solutions are not stored for extended periods of time.

Apr 1, 2025

By Alfred W. Hefferan

A longwall face conveyor system serves the primary function as all material handling systems; i.e., to transport material between the source and its destination. However, the conveyor system must provide many other functions as opposed to the traditional belt conveyor system. In this paper, we will attempt to contrast the longwall face conveyor system with a belt conveyor system. In addition, the unique problems encountered along with the solutions to these problems will be covered. Table 1 lists the characteristics required of each conveyor system. The table demonstrates the contrast in the two systems. Both must be designed specifically to encounter its unique problems. The balance of this paper will explain how the longwall face conveyor is designed to address its requirements.

Jan 1, 2000

By H. Evans

It is well known that iron-ore pellets are considered one of the best blast-furnace burden materials used today. The demand for pellets is demonstrated by the increase in pellet output from one million tons in 1955 to approximately 37 million tons in 1964. This growth continues as new plants are placed on-stream each year. The consumer generally specified (1) the acceptable content and range of chemical constituents, (2) a minimum strength determined by some standard testing procedure, (3) the size range of pellets, and (4) perhaps a measure of reducibility.

Jan 1, 1966

By L. Eros, R. H. King

The US Bureau of Mines has funded several research and development projects in computerized mine monitoring and control. Hardware and software components have been sufficiently developed so that mine operators have been provided with an efficient means to comply with federal regulations and increase mine safety. Several cost benefits have been realized as well, particularly with increased conveyor belt haulage availability. Western Fuels-Utah Inc. approached the Bureau to assist in planning, installing, and evaluating a computerized mine monitoring and control system because of the agency's research experience in this area. The installation was planned for Western Fuel's Deserado mine, located in Rangely, CO. Since a large, complex, underground mine producing about 2.4 Mt/a (2.7 million stpy) of coal was projected, the company anticipated significant benefits in safety and efficiency through a computerized monitoring and control system. A major part of the cooperative program was to document and evaluate the system design, installation, and operation. This will assist others to adequately design, specify, install, and operate future systems. Mine description The Deserado mine plan and layout have important impacts on the monitoring system requirements. Long range plans are to produce 2.4 Mt (2.7 million st) of clean coal annually from two longwall sections and four continuous sections. Presently, two continuous miner sections operate under 213 m (700 ft) of overburden in the 2.3 to 2.5 m (7.5 to 8.5 ft) thick D seam to develop main, submain, and panel entries have developed for a longwall. These began operation in December 1986. Belt conveyors haul the coal from the mining sections to a 1.4-m (54-in.) belt located in the upper compartment of the slope. The lower compartment contains a hoist for men and material transport. From the slope, the coal moves to two 9 kt (10,000 st) raw coal storage silos, then to a 680-t/h (750-stph) preparation plant. After cleaning, a 5.5-km (3.5-mile) overland conveyor carries the coal to a clean coal slot storage and rail load-out facility. An electric locomotive then transports the coal to the Bonanza Power Plant in Utah. Allen-Bradley monitoring and control hardware and software controls the preparation plant, with two PLC-3 programmable controllers and a Process Control Industries D-1200 color graphics interface. The system operator uses three "smart" color video display units and an alarm printer for hard copy records. Originally, it also monitored and controlled the conveyors from the bottom of the slope to the top of the raw coal silos, the preparation plant, the overland conveyors, the main mine ventilation fan, and the hoist. Some of these features, though, were later transferred to the mine system.

Jan 2, 1988

By H. E. Epstein, B. K. Parekh, W. M. Goldberger

Comminution is the single most expensive operation in mineral processing. It consumes about 50% of the energy required for mineral extraction (Agar, 1976). Current comminution technology is both energy-intensive and inefficient. A novel noncontact comminution process concept was developed in this study, whereby selective lib¬eration of minerals from an ore could be potentially achieved. The process involves application of electric and ultrasonic energy to liberate minerals from gangue particles. Introduction The mineral industry is a large user of energy in the US. Energy usage is increasing as the grade of ores processed decreases. It is es¬timated that comminution of ores uses about 32 000 kWh (115 trillion kJ), or 2% of the electric power produced in the US (NMAB-365, 1981). Among other minerals, ce¬ment, iron, and copper processing plants are the largest users of en¬ergy in comminution. Very little of this energy used in conventional grinding (about 1%) is used to gen¬erate new surface. The remainder is wasted (Table 1). Thus, there are substantial energy-saving and economic incentives to improve the efficiency of crushing and grinding techniques for mineral recovery. With an energy efficiency of only 1%, it would seem possible to devise methods to significantly improve comminution technology. This requires that breakage force be applied only where needed, not indiscriminately as in a conven¬tional ball mill (NMAB-365, 1981). Can apparatus and methods be de¬ veloped for large-scale commer¬cial use that allow energy to be fo¬cused at intergranular bounda¬ries? If this can be done, mono¬mineral grains would remain in¬tact and the grinding action would be selective and substantially more efficient. The novel comminution process concept described in this paper uses a combination of electric and ultrasonic energy. This energy breaks the ore and selectively lib¬erates minerals. The process has also been termed a two-stage or electroacoustical comminution process (Goldberger, Epstein, and Parekh, 1982). The mineral grain boundary is usually the weakest area in an ore. By applying electri¬cal energy to the ore, the rock frac¬tures mostly at grain boundaries. At the same time, the electric shock creates secondary hairline fractures in the ore. Additional application of ultrasonic energy to this ore provides further break¬age. The concept was proven on a molybdenum porphyry ore but needs additional study. Technical Background There have been substantial im¬provements in milling machinery and grinding operations, but rela¬tively few attempts have been made to develop alternatives to conventional impact milling. Sev¬eral methods, however, have been investigated that relate to this study. In the early 1970s there was considerable interest in a size re¬duction method known as the Snyder Process (Cavanaugh, 1972). It involved charging coarse ore into a pressure chamber, pressur¬izing with a gas, and activating a quick-opening (15 msec ) dis¬charge valve that connected the chamber to a discharge duct. This allowed solids to fluidize and ac¬celerate, subjecting the material to a variety of impulse phenomena that caused the desired size reduction. Other nonimpact means of achieving breakage and selective size reduction have been de¬scribed in technical and patent literature. Kanellopoulos and Ball (1975) considered using heat to induce thermal stress in quartz¬ite. This would cause cracking and, thus, increase grinding efficiency. The use of electrical energy to induce thermal stress was studied by the General Elec¬tric Co., in cooperation with the Montana School of Mines, under a research grant from the Anaconda

Jan 9, 1984

By Michael C. Stanley

The set of discoveries for a mining district or camp is a reflection of the exploration history. In the western Abitibi greenstone belt of Ontario, future exploration can be guided by a study of statistical trends of known gold deposits. In this area simple trends indicate a strong decrease in the contained quantity of gold discovered through time. Much of this decrease is attributed not to falling mining grades but to smaller tonnages of ore. A plot of the largest discovery in each ten year time period suggests that deposit discoverability is following a size-biased sampling model. Cumulative ounces of discovered gold indicate that an asymptotic value has been reached where exploration is not expected to add significantly to known reserves. This is substantiated by a downward trend in the exploration success ratio of the number of new deposits discovered versus the number of new mineral prospects. The set of discovered deposits reflects a non-random sampling process where size- biased modeling suggests that the largest deposits will be discovered early in the exploration effort. It is the exceptionally large deposit contributing to the observed size-biased distribution. Although this pattern is observed for the western Abitibi the model is complicated by recent, large reserve additions that are attributed to the original discovery. There is present in this area a subtle learning process in exploration leading up to the largest discovery. For comparison a learning model was estimated using cumulative size of discovery per unit of time. This model yielded results consistent with the statistical trends and is thought to be a superior forecast of future discoveries in this region.

Jan 1, 1992

By R. Martinez

The Alligator Ridge Mine was discovered in 1976 by a prospector grubstaked by Amselco Exploration Inc. in eastern Nevada 116 km (72 mi.) northwest of Ely in White Pine County. The mine is operated as a 50-50 Joint Venture by BP Gold, the operator, which is a subsidiary of British Petroleum Minerals America and Nerco Inc., a subsidiary of Pacific Power and Light.

Jan 1, 1988

By George McArthur

GEOLOGY One of the largest copper resources in North America occurs in the Bingham mining district, located 40 km (25 miles) southwest of Salt Lake City, UT. Anaconda's present contribution to the development of this resource is the Carr Fork mine. (Fig. 1, Bingham district plan map.) The Carr Fork story began about 300 million years ago when a thick sequence of sedimentary quartzite and limestone was deposited in the Oquirrh Basin. Subsequent earth stresses formed a series of west-northwest-trending overturned anticlines and synclines that were later offset by northwest-striking thrust faults and northeast-trending normal faults. (Fig. 2, Bingham district cross section.) About 38 million years ago the Bingham stock was intruded into some of the folds, resulting in the formation of porphyry ore in the intrusive, and fissure, replacement, and skarn ore deposits in the sediments. The Carr Fork skarns were formed preferentially in two limestone units, called the Yampa and Highland Boy, which average about 46 m (150 ft) in thickness, separated by about 76 m (250 ft) of quartzite. Copper mineralization consists almost entirely of chalcopyrite associated with pyrite and molybdenite in a gangue of garnet, diopside, magnetite, quartz, and carbonate. Molybdenum, gold, and silver are economic byproducts. (Figs. 3 and 4, indicated ore in plan and section.) EXPLORATION HISTORY The West Mountain mining district, of which Carr Fork is a part, was organized in 1863, after leaf-silver ore was discovered in the Carr Fork of Bingham Canyon. However, it was not until 1873, when the Bingham and Camp Floyd railroad to the town of Bingham was completed, that the mining camp flourished. Many small mining companies in the district were reduced, often through consolidation. By 1937 only the National Tunnel and Mines Co. was active in the Carr Fork area. In 1948 it declared bankruptcy, and was later purchased by The Anaconda Co. Anaconda conducted geologic investigations in the Bingham district until 1968, when a concerted diamond drilling program was initiated to fully evaluate the geologic potential of the Carr Fork area. The exploration program commenced with one diamond drill, but was enlarged to three drills following discovery of the first major ore intercept. Near completion of the exploration effort, large oil well rotary drills were used to drill to depths of 762 to 914 m (2500 to 3000 ft), after which the holes were completed by standard diamond drilling techniques. All holes were collared vertically, but considerable deviation occurred because of structure and rock conditions. Wedging and directional drilling were used to keep the holes on target and to provide multiple ore intercepts in the deeper holes. Geophysical surveys, in-

Jan 1, 1982

By Nicholas T. Camicia

A career in the coal mining industry today offers students one of the most interesting and challenging opportunities available in the industrialized world. As reserves of other fossil fuels dwindle in face of the world's demand for energy, it has become apparent that coal, once the king of energy sources, must be relied upon again as the major fuel for powering industrial growth in developed and developing nations. Centuries of coal supplies lie beneath the earth's surface, assuring the world of a steady, plentiful supply of energy until science and technology can produce a way to harness and efficiently use renewable sources, such as solar. The need to increase our use of coal during the last two decades of the 20th century is reason enough to believe that the future growth of the coal industry is assured. A major impediment to that growth might be backward national public policies that could restrict the full utilization of our coal reserves. These policies could result from overregulation and a failure of the public to recognize that coal use, with proper techno- logical safeguards, is compatible with our society's environmental-quality objectives. Communication of this problem and its solution is a major undertaking of the coal industry in the 1980s. At the end of the 1970s, the American coal industry was producing approximately 635 Mt/a (700 million stpy) of coal. To meet the nation's projected energy needs by 1985, the annual tonnage must be doubled. A similar scenario is predicted for the rest of the world. Such growth in the modern international business world will require huge additional amounts of capital, equipment, and people who know how to wisely raise and apply the capital ; use the equipment productively; and deal with the many community, public, and governmental problems such expansion will create. Whether a student's interest is in actual mining operations, business administration, engineering, finance, law, industrial relations, marketing and sales, or public affairs, a career opportunity is available in the industry.

Jan 1, 1981

By Peter Krag, Rob Henson

It is well known that titanium and zirconium alloys offer superior corrosion resistance in the oxidizing sulfuric acid environments present in sulfide pressure leaching operations. The use of these materials is limited, however, due to their pyrophoricity; several accidents attributed to titanium equipment have been described in technical literature, and other, minor incidents·occur regularly1 • We describe an application of a commercial titanium alloy, Nb-55 Ti, with suitable mechanical properties, corrosion resistance similar to Grade 2 Ti, and featuring a significantly reduced field of ignition conditions

Jan 1, 1992

By P. T. Luckie

More efficient classification with a single hydrocyclone through equipment and/or operating design changes does not appear possible. However, improvement in classification efficiency by increasing the sharpness index and decreasing the apparent by-passing while changing the cut size is possible through proper staging of inefficient hydrocyclones. But feasible multistaging requires achieving the necessary material balances around the units. Because of the interactions among the units, these balances require extensive iterations. The final step before commerical installation should be a laboratory demonstration, in order to define the control algorithm required to maintain stability. However, eventually a sufficient knowledge base should be developed that will permit simulation in place of laboratory testing as well as the incorporation of a feed forward strategy.

Jan 1, 1989

By H. Hejny

The objective of the project is to construct and operate a pan-European underground drainage and minewater management research centre, which would be the hub for data gathering and dissemination in real time of new data to users for analysis and interpretation, as well as serving as a model for consistency, for other centres at key water management sites throughout Europe which would feed data in real time through the hub. The data from the centre will be essential for informing River Basin Management Plans arising from the EU Water Framework Directive, which is an important driver for the project. The implementation of this Directive sets out a requirement for all Member States to develop River Basin Management Plans for all water resource systems. The facility would be a major contribution to sustainable water management in Europe.

Jan 1, 2007

By R. K. Singhal

The underground coal mining systems have kept pace with the developments that have occurred in other types of mining industry. A diversified group of machines with high horsepower motors, built-in microprocessor technology and with numerous options to satisfy the miners need in a varying geological environment are now available. A brief review of this existing technology and its likely status within the next 21 years is presented. Discussed also are some of the on-going advanced developments in electronic mechanization, remote control and automation together with mine wide data monitoring and management systems and facilities to process and transmit data to remote computerized stations.

Jan 1, 1989

By J. Andres

"Freeport-McMoRan’s Sierrita operations refines molybdenum disulfide in a ferric chloride leach to remove impurities. To understand bottlenecks in the leach process and the true capacity of the leach system, a cross-functional team was established to look at theoretical models, kinetics of the leaching process, equipment limitations and operational strategies. A series of in-plant tests were run which resulted in a road map for improved throughput. INTRODUCTION Molybdenum, a vital component in the steel industry, is often found in nature as molybdenum disulfide (MoS2). Molybdenum disulfide deposits can exist as standalone components in an ore body, or can also be found within copper porphyry nodes. Processing for these copper/molybdenum porphyry ore bodies involves a first stage of flotation to produce a bulk concentrate before separation of the copper and molybdenum concentrates in a second stage of flotation. In this second stage of flotation, a reagent is added to suppress the copper particles, while allowing the molybdenum disulfide particles to remain hydrophobic and continue to float. This separation is very good at keeping the molybdenum out of the copper concentrate; however a portion of the copper continues to float through the circuit. As a result, there is typically some amount of copper in the final molybdenum concentrate. This copper must be removed in order for the molybdenum disulfide product to meet product quality specifications. Once the raw molybdenum disulfide product has been made, a separate process must be applied to remove any copper, lead, or other impurities remaining in the concentrate. This process usually involves the selective leaching of impurities out of the bulk solid. Gupta mentions three specific types of leaching agents, sodium cyanide, ferric chloride, and hydrochloric acid for the removal of sulfide impurities. Sodium cyanide is useful for the removal of copper compounds such as bornite, covellite, and chalcocite.1 Sodium cyanide solution dissolves these copper compounds, and the remaining molybdenum solids are filtered to produce a pure molybdenum concentrate. Ferric chloride works similar to that of sodium cyanide, but is particularly efficient in removing chalcopyrite and galena compounds. These compounds are easily chlorinated at elevated temperatures, producing copper chloride and lead chloride, through the reactions presented below:"

Jan 1, 2015

By X. Cui, H. Ding, J. Wen, Q. Gu

This study is a continuation of previous work designed to further explore the mechanism of the bioleaching of sulfide concentrate at neutral pH by heterotrophic bacteria Bacillus megaterium QM B1551. The concentrate contained 13.2 percent nickel (Ni) and 0.2 percent cobalt (Co), which presented primarily as pentlandite and pyrrhotite. Contact and noncontact bioleaching experiments were conducted with finely ground ore at an initial pH of 6, resulting in 44.7 percent of Ni and 38.2 percent of Co leached in the contact-bioleaching treatment. Oxidation experiments of sulfur, thiosulfate (S2O32−) and ferrous ions (Fe2+) by cell membrane were performed to verify whether sulfur transferase, thiosulfate quinone reductase and enzyme cytochrome B558 on the surface of the bacteria could be expressed to oxidize the sulfide. The results show that thiosulfate quinone reductase and cytochrome B558 could be expressed to oxidize S2O32− and Fe2+ to SO42− and Fe3+, respectively.

By Patricia T. Foley

An analysis of the demand for copper shows a widely varying pattern of end use. For example, copper tube is the most popular material for hot water supply in the US and northern Europe, but galvanized steel is used in Japan and plastics are used in developing countries. In addition to such peculiarities of end use, the demand for copper varies among countries depending on the stage of industrialization and the extent that the copper processing industries are developed. Brazil, with its abundant supplies of bauxite and hydroelectric power, uses aluminun in place of copper wherever possible. South Korea, with its export oriented economy and its advanced custom smelting and fabricating industries, favors copper. Understanding the details of demand in different countries enhances statistical derived forecasts and illustrates potential new markets.

Jan 1, 1986