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By Q. Han

Irradiation of high energy ultrasonic vibration in metals and alloys generates oscillating strain and stress fields in solids, and introduces nonlinear effects such as cavitation, acoustic streaming, and radiation pressure in molten materials. These nonlinear effects can be utilized to assist conventional material processing processes. This article describes recent research at Oak Ridge National Labs (ORNL) and Purdue University on using high intensity ultrasonic vibrations for degassing molten aluminum, processing particulate reinforced metal matrix composites, refining metals and alloys during solidification process, welding, and producing bulk nanostructures in solid metals and alloys.

Jan 1, 2014

By Neri Roux, Ross Gilders, Yemi Oyediran, Leo Cheung

Quest Rare Minerals Ltd. is developing their Strange Lake B Zone REE deposit located in Northern Quebec. An extensive batch bench scale testing program was launched to investigate open circuit rougher flotation performance under different conditions. The objective of the flotation study was to demonstrate the effectiveness of rejecting gangue minerals to flotation tailings while concentrating rare earth elements as well as yttrium, zirconium, and niobium into a concentrate suitable for further hydrometallurgical processing. Mineralization of interest at Strange Lake occurs within peralkaline granite-hosted pegmatites and minor aplite. The REE and high field strength element (HFSE)-bearing phases are hosted primarily in pegmatites as relatively fine-grained phases or pseudomorphs. The gangue phases comprise of quartz, feldspar, amphibole, and pyroxene. Potential ore minerals comprise predominantly of kainosite, gerenite, gadolinite, zircon, pyrochlore, and gittinsite. These complex mineralogical characteristics increase the difficulty for processing and provide a challenge for choosing the correct reagent scheme in rougher flotation. Process options including reverse flotation to reject the gangue minerals and de-sliming prior to the direct rougher flotation were investigated. Optimization trials were conducted using various reagent regimes and under different flotation conditions. Encouraging results were found using a combination of collector reagents supplied by Cytec Canada Inc.

Jan 1, 2014

By R. R. Dickson

Princess colliery, the largest mine operated by the Old Sydney Collieries, Limited, commenced operations in 1877. It was the first mine sunk in the Sydney coal field with the primary object of working submarine coal. Until 1925, coal was won by the room-and-pillar system. By that year, the depth of cover over the workings was 1,300 feet, and physical conditions had become such that it was impossible to extract completely the pillars formed by the working of the rooms. Because of this, the system of work was changed to longwall in the early part of that year. At first, an orthodox hand-pick method was used, with gate roads laid off at 50-foot centres and the mine cars loaded by hand directly on the longwall faces. Later in the year, the first machine-cut conveyor longwall faces were started.

Jan 1, 1946

By Yufeng Yao, Robert P. Lowell

Abstract - Conductive heat flow anomalies associated with hydrothermal sulfide mounds on the seafloor have been studied. Sulfide mounds tend to focus conductive heat flow because sulfide minerals have a greater thermal conductivity than country rock. The topography of the mound above the seafloor, however, leads to a reduction of heat flow, particularly near the center of the mound. Because the focusing effect is constant, whereas the topographic effect decreases with distance away from the center, the focusing effect dominates toward the edges of the mound. The magnitude of these effects depends upon the conductivity contrast and the height/radius aspect ratio of the mound. Conductive heat flow anomalies at sulfide mounds also result from fluid circulation within the edifice. For the active and relict mounds at the TAG hydrothermal field, which have an aspect ratio of approximately 0.3 and a conductivity contrast of 3, the heat flux through the center of the mound should be roughly 70% of the background heat flux. The maximum effect of heat flow focusing is to increase the heat flux by about 30% above background. By comparing these effects with conductive heat flow data at TAG, we find that advective processes dominate conductive heat flow at both the active and relict mounds. Advective circulation can also give rise to much larger lateral and vertical temperature gradients than would result from conduction alone.

Jan 1, 1999

By E. V. Manlapig, U. Erol, V. Ross, K. Tshimanga

Lonmin RoM ball mills are treating two types of feed ore produced by conventional mining and mechanised mining methods. It was reported that reduction in mill throughput was observed when treating the mechanised mining ore. Detailed grinding surveys were conducted for troubleshooting. Ore samples were collected for breakage characterisation using a JKRBT based on different particle density components. XRD analysis was conducted to investigate the association of minerals with density components. The plant surveys and the breakage characterisation tests all suggested that the two mining methods did not significantly affect either the ore breakage properties or the RoM mill performance. Instead, the mill discharge open area exerted a remarkable influence on mill throughput. The RoM ball mill operated at Lonmin K4 Concentrator has been proven to be a versatile mill that performed stably with variations in feed size distribution and feed ore changes by different mining techniques. The reasons are elucidated by the multi-component breakage characterisation and the plant surveys data.

Jan 1, 2012

By Henry Brehaut

"It is difficult to know how much environmental information is absorbed by those in a position to put it to use. The following information may seem like ""old stuff"" to those whose companies are taking steps to improve their environmental performance. This paper is directed in particular to those people who are interested in determining what further changes are required to make improvements as concerned environment citizens.IntroductionUntil recently, the author was comfortable with the fact that none of the operations for which he was responsible had any environmental charges against them. It was not until one of his operations was charged with non-compliance that the author discovered due diligence as a way to avoid a second charge, and when an unfortunate spill occurred at another operation, the meaning of risk prevention was learned. Knowledge was gained step by step to the point where finally environmental information is being heeded, rather than waiting to learn from sad experience. With the appreciation of what it takes to do a good environmental job, comes an understanding of the challenge that lies ahead, and the fact that there is a lot to learn.At a recent environmental gathering, comments from the participants varied considerably. Some just didn't understand why government was being so unreasonable, while at the other end of the spectrum one individual whose company was well along the path to becoming a good environmental citizen remarked that it was all very basic. What was immediately understandable to one went right over the heads of others, indicating the different stages that have been attained in the acceptance of environmental responsibilities."

Jan 1, 1991

By O. Laitinen, M. Rudolph, J. A. Sirviö, H. Liimatainen, R. Hartmann, University of Oulu

The increasing complexity of the ores composition worldwide calls for suitable collectors with specific properties, such as selectivity, wettability, and in regard to current regulations, environmental sustainability. Therefore, collectors have to satisfy many features to improve the efficiency of flotation processes. Cellulose nanocrystals gain more and more interest due to the versatile synthesis routes which enable the integration of specific functional groups and components with different degrees of hydrophobicity within the molecular structure. Consequently, cellulose nanocrystals can be employed in flotation processes as depressant or collector molecules, respectively. Nonetheless, the usage of cellulose nanocrystals is still limited due to a lack of the characterization of nanocrystal-mineral interactions and the change of the surface wetting properties of minerals after adsorption phenomena between nanocrystals and minerals. In these studies, butyl-amine cellulose nanocrystal (BAC) and quartz are used as model system to investigate physicochemical properties of both, BAC and quartz, and examine the applicability of BAC in flotation processes. Therefore, the surface charge distribution and electrophoretic mobility of BAC and quartz are investigated and compared to understand the effect of electrostatic interactions between BACs, and BAC and quartz. Based on this, the adsorption of BAC on quartz is examined. Finally, microflotation experiments test the efficiency of BAC to be used in flotation processes. The flotation response is correlated to the specific surface charge of BAC revealing the dominant effect of surface charges on effective particle-bubble adhesions.

Jan 1, 2016

By P. E. Weidmark

Allard, M., Hucka, V.J., Das, B., and Borchtch-Komponietz, V.I., "Investigation of seismic vibration due to large blasts in Gaspe Copper Mines"; (in Russ); The Industry of Chemical Raw Materials; Referativnyi sbornik; 5:18-20: 1978. Askew, J., McCarthy, P.L. , and Fitzgerald, D.J ., "Backfill research for pillar extraction at ZC/NBHC"; Mining with Backfill; Proc 12th Cdn Rock Mech Symp; May 23-25, 1978; Sudbury; CIM Spec Vol 19:100-lJO; 1978. Barrett, J.R., Coulthard, M.A., and Dight, P.M., "Determination of fill stability" ; Mining with Backfill; Proc 12th Cdn Rock Symp; May 23-25, 1978; Sudbury; CIM Spec Vol 19:85-91; 1978.

Jan 1, 1979

By H. E. (Buzz) Neal

"Abstract - The Labrador Trough contains world-class iron deposits which have been mined since 1954. The direct shipping of Knob Lake ores were mined at Schefferville from 1954 to 1982. Concentrate production began in 1961 in the southwest end of the Trough, with three mines currently producing concentrate and pellets at a rate of 35 Mt per year. West and north of Schefferville, several billion tonnes of taconite have been outlined in fine-grained, cherty magnetite iron formation. Several deposits of highly metamorphosed magnetite-specularite iron formation are located west of Ungava Bay. Numerous studies have shown that this medium- to fine-grained iron formation can be beneficated to 66% to 68% iron. In the area from Wabush Lake to Mont-Wright, a medium- to coarse-grained friable specularite-quartz iron formation is repeated by folding to form several large deposits. In this area, three mining operations are located with reserves and resources in the order of 5 billion tonnes.The iron deposits occur within iron formation in sediments in the extensive Proterozoic geosyncline called the Labrador Trough. Several facies of iron formation within the Sokoman Formation reflect variations in chemical composition and depositional conditions. The correlation between the mineralogy and textures is discussed to illustrate the development of different types of iron ores. This band extends for about 1100 km southeast of Ungava Bay through both Quebec and Labrador. Further south, it turns southwest past the Wabush and Mont-Wright areas to within 300 km of the St. Lawrence River. The iron formation is essentially folded and faulted along most of its length. The degree of metamorphism is variable, ranging from intense in the northern and southern portions to greenschist facies in the central portion.The stratigraphy, structure and mineralogy of the producing mines are described along with the history of discoveries. Geological input is required to achieve the strict specifications of the international iron ore market."

Jan 1, 2000

By Tom Setterfield

Monster Copper Resources ?Junior focused solely on IOCG deposits ?Founded by ex-WMC geoscientists ?Properties in Brazil, Wernecke Breccias (Yukon), Central Mineral Belt and Nova Scotia Nova Scotia ?JV with Wallbridge Mining Company ?Ongoing Story ?Presented as a case study in generation and implementation of IOCG exploration program

Apr 1, 2005

Applications of proven real time, through-conveyor elemental analysis technology and benefits achieved will be discussed using case studies in base metals, iron ore and phosphate operations. PGNAA (Prompt Gamma Neutron Activation Analysis) technology and its background in minerals applications and applications which are expected to further improve its utilization will be reviewed. Short payback through operational benefits such as removal of waste from feed, increased feed grade and overall improved productivity will be demonstrated based on results achieved at several processing operations. PGNAA technology is most applicable to conveyed flows as it is unaffected by belt speed, particle size, segregation/layering, mineralogy or dust. As a transmission method able to penetrate in excess of 500mm of rock it provides extremely representative results continuously measuring through the full conveyed cross section and reporting results typically on one to five minute accumulated increments to the control room. Multi-elemental results and moisture content are used for active process control: diverting conveyed flow increments(bulk sorting), blending ore types in plant feed, and providing advance warning of significant quality changes to the downstream plant operators (e.g. flotation). Elements of interest may include deleterious components as well as target metals. Ore feed quality measurements are also useful in metal accounting, ore reconciliation and real time feedback to mining operations. Further benefits can result when combined with other technologies such as particle sorters, to upgrade diverted increments of subeconomic material to achieve higher feed grades and lower deleterious content to the main process. Measurement of elements (e.g. silica) which correlate with ore hardness or grinding characteristics can be used to moderate feed rate to grinding mills to prevent overload, hence optimizing grinding performance and reducing energy and grinding media consumption. Pebble flows can be analysed and uneconomic increments diverted to prevent recirculating flows consuming mill capacity unnecessarily. This also increases average feed grade.

Jan 1, 2016

By Al Gagnon

Since start-up in 1972, many circuit problems have been encountered, most of which were related to the abundance of fines (-28 mesh), which the circuit had not been designed to treat. The major problems associated with the original circuit included excessive loss of magnetite, reduced throughput during periods of a high proportion of fine coal in the plant feed and low yield in the fine coal circuit. This paper outlines the coal processing circuit at Fording Coal Limited as it exists today, with emphasis on the changes to the original fine coal treatment circuit.

Jan 1, 1978

By C. Gu

Flow field design is critical for PEM fuel cells. The flow field design can affect reactant distribution to the catalyst surface, water management, thermal management and current collection. Therefore, it has tremendous impacts on the fuel cell performance and durability as well as reliability and operational flexibility. In this paper, an optical method is used to study the reactant distribution in the flow field channels of two commonly used flow field designs, straight channel design and serpentine channel design. Images of the flow patterns are shown followed by discussions of the flow patterns.

Jan 1, 2005

By André Chagnon, Héroux. Yvon

"Résumé - Cette étude porte sur l'altération de la matière organique et des argiles dans les boues carbonatés dévoniennes du facies ""F' de la Formation de Pine Point et ses équivalents stratigraphiques la Formation d'Evie et l'unité bitumineuse de la base de la Fonnation de Hom River. La matière organique se compose principalement de bituré solide et de quelques fragments de fossiles (organaclastes). La majorité des échantillons ne renfement que de l'illite et des inter-stratifiées illite/smectite.Si on compare les températures d'homogénéisation (Th = 100°C) des inclusions fluides de la sphalérite et des dolomites associées a la minéralisation aux températures estimées à partir de la réflectance de la collinite (84°C à 117°C), l'on ne peut pas conclure à la présence d'une anomalie thermique dans le district minier de Pine Point. De plus, la réflectance des organoclastes n'est pas plus élevée dans le district minier de Pine Point que dans les localités plus éloignées des gites. L'analyse des minéraux argileux conduit à la même conclusion: aucune anomalie thermique n'est décelable dans les unités échantillonnées à l'intérieur du district minier de Pine Point quelque soit l'indicateur utilisé.La kaolinite et la matière organique altérée, affichant des valeurs anomales de sa réflectance, se trouve essentiellement en présence de soufre et de sulfures. Cela suggère une origine authigène de la kaolinite et une altération de la matière organique reliées au phénomènes de minéralisation.Abstract - The alteration of organic matter and clays is studied in the Devonian Pine Point Formation carbonate muds, ""F"" facies, and its lateral equivalents the Evie Formation and the bituminous unit at the base of the Hom River Formation. The organic matter is mainly composed of solid bitumen with few fossil fragments (organoclasts). Most samples contain only illite and mixed layer illite/smectite.If we compare the Th (100°C) from fluid inclusions of sphalerite and dolomites associated with mineralization to the temperatures calculated from the reflectance (Ro) of the collinite (84°C to 117°C), we cannot detect a thermal anomaly in the Pine Point mining district. This result is based on the reflectance values of organoclasts from the mining district that are not higher than those reflectance values measured on organic matter (OM) away from the ore deposit. A similar conclusion is reached from the clay study: none of the parameters used allow us to identify a thermal anomaly in the samples from the mining district.The kaolinite and the altered OM showing anomalous Ro values mainly occur with sulfides and sulfur. This association suggests an authigenic origin for the kaolinite and an alteration of the OM due to the mineralization events."

Jan 1, 1994

By R. J. McLeod

"Grinding at Giant Yellowknife is done in two stages. The first stage consists of two ball mills in closed circuit will: mechanical classifiers, the classifier overflow goes to flotation. The tailings from this flotation circuit are separated into slime and sand portions, the slimes go to an additional flotation circuit while the sand portion goes to the secondary grinding mills.Milltronic automatic sound control units were installed on each of the two primary ball mills and put into operation September 3, 1966. After about two months adjustments to the control units the operators were taken off the grinding circuit on November 1, 1966. The operators duties were taken over by the automatic control units while miscellaneous work was taken over by the helpers in the mill. The labour saving by the installation is approximately $2250.00 per month.After a short period of operation it was apparent there was a slight change in grind. The screen analysis of the primary classifier overflows for the period May to August 1966 averaged 62.23% minus 200 mesh while for the period September to December 1966 averaged 62.0% minus 200 mesh. This is a slight coarsening of the grind. The change in the primary grind has manifested itself also in the screen analysis of the final grind. Before automation the final grind was 80% minus 200 mesh, while after automation it was 7 5% minus 200 mesh. A change of grind was also noted in the flotation concentrates. Before automation the screen analysis of the concentrates was 35% plus 200 mesh and 50% minus 3 25 mesh. A ft er automation it was 35% plus 200 mesh and 47 .5% minus 325 mesh. In other words the grind got coarser or perhaps we should say there was less overgrinding. Another significant change took place in the assays of the slime and sand portion of the primary flotation tailings. It was usual under manual control for the slime portion to assay higher in gold than the sand portion. The reverse is now true."

Jan 1, 1967

By Jean-Francois Magnan

"The old conventional process to produce lithium raw material dates from 1954 (CA patent #504477A). This process produces low purity lithium carbonate (Li2CO3) only. To obtain battery-grade carbonate, another polishing process is needed. To further obtain lithium hydroxide, another chemical conversion process is needed. That is why historically, the value of lithium hydroxide has always been higher than that of the lithium carbonate precursor. With the old conventional process, the low quality lithium carbonate is precipitated from a lithium sulfate solution (Li2SO4) by adding soda ash (sodium carbonate and its impurities). The resulting reaction produces significant quantities of sodium sulfate (salt cake) as a by-product with amounts larger than the impure Li2CO3 recovered with part of the soda impurities. When this conventional process was invented, the salt cake by-product was not an issue: it was discarded in a river near the plant. This practice cannot be done today in North America. While looking to find a solution for salt cake, electrolytic salt splitting of Na2SO4 into NaOH and dilute sulfuric acid appears as a technically feasible solution to get a rid of the salt cake. However, the sodium sulfate salt splitting process has difficulties to economically compete with the chlor-alkali process, which produces millions of tons of NaOH from sodium chloride (NaCl) every year.In contrast, the process developed by Nemaska to directly produce LiOH by Li2SO4 salt splitting not only solves the environmental problems related to the conventional process to produce lithium carbonate raw material, it also produces very high purity lithium hydroxide monohydrate directly at very competitive OPEX cost in comparison with industry peers (Figure 1). It also drastically reduces the amount of reagent and the direct greenhouse gas emissions."

Jan 1, 2016

By F. S. Hoseinian, M. Irannajad, M. Safari

In this study, the effect of chemical interactions of materials used in ion flotation on the removal of Ni(II) ions from low concentration synthetic wastewater was studied. Sodium dodecyl sulfate (SDS) and ethylhexadecyldimethylammonium bromide (EHDABr) as collectors and methyl isobutyl carbonyl (MIBC) and Dowfroth250 as frothers were used. To investigate the effective parameters and interactions of them, 16 experiments including 6 level variables were performed by supporting DX7 software and on the bases of 2-level factorial method. In the first step, the tests were conducted in a Hallimond tube. The result showed that collector of SDS and frother of Dowfroth 250 had appropriate interaction with each other at pH = 3. In the second step, optimal results from the first step were evaluated in a mechanical flotation cell. The removal of Ni(II) ions increased by increasing the time of flotation and they have a direct relation with the water removal. The kinetics study shows that the order and the rate of removal of the reaction do not follow any of the zero-order, first-order and second-order equations. The flotation rate curve on the removal of Ni(II) ions will divide the separation process to two stages, a fast flotation rate at the first stage and a slow flotation rate at the second stage. Ni(II) ions removal was obtained 88% at the best condition.This study showed that the use of ion flotation was a very effective method for Ni(II) ion removal from industrial wastewaters.

Jan 1, 2016

By BARRY BANNATYNE

Non-swelling bentonite has been quarried in Manitoba by Pembina Mountain Clays Limited since 1941. It occurs in several thin layers near the base of the Pembina Member of the Upper Cretaceous Vermilion River Formation, and is quarried from the narrow outcrop belt along the slope of the Manitoba Escarpment. It is marketed both as natural and activated bentonite for a variety of specialized uses. Percolation of acidic water through bentonite has produced a naturally activated bentonite with good absorbent properties; these properties are enhanced by treatment with sulphuric acid to produce an activated bentonitefor decolourizing petroleum and vegetable oil.

Jan 1, 1984

By Tommee Larochelle, Henry Kasaini

"Simulation of rare earth element solvent extraction processes for plant design and optimization is complex, requires extensive bench scale and pilot scale testing, and is traditionally performed using proprietary algorithms. The complexity of simulation is mainly due to traditional simulation software solvent extraction modules not being designed to simulate rare earth separation processes because of the interaction between each element. This paper presents an alternative method for designing and optimizing rare earth element solvent extraction separation processes using METSIM to converge each stage of the battery individually until the full battery reached ultimate convergence. A feed-forward controller is used to control the organic to aqueous flow ratio feeding the solvent extraction modules. This method minimizes the complexity of simulating such processes by using inexpensive batch solvent extraction data, and allowing for rapid theoretical optimization, by varying the process configuration and parameters from a graphic interface instead of the traditional code-based interface of most proprietary models. Comparison of the model predictions to pilot plant data reveals that the method can be used to accurately model rare earth solvent extraction processes, as illustrated by its application in the development of Rare Element Resources innovative process.INTRODUCTIONThe Rare Earth Elements (REEs) consist of 16 metals, specifically the 15 lanthanide elements and yttrium, which is typically found in the same mineral deposits as the lanthanides. Scandium can be associated with the rare earth elements, but is usually only present in trace amounts, and therefore omitted. The term “rare earths” originates from an old term used to designate minerals (earths) and their believed scarcity upon their initial discovery. The rare earths designation is now considered a misnomer because it was demonstrated that the crustal abundance of some rare earth elements, such as cerium, is known to be higher than many common metals, such as copper. However, enriched deposits are fairly uncommon compared to other similarly abundant metals. The REEs are typically divided into groups commonly consisting of light rare earths (LREEs), medium rare earths (MREE), and heavy rare earths (HREEs). Light rare earth elements include lanthanum to neodymium, medium rare earths include samarium to gadolinium and the heavy rare earth elements include terbium to lutetium, and yttrium. The REEs exhibit similar chemical characteristics and are usually extracted from the ore and processed into a mixed rare earth concentrate. The rare earth concentrate requires further processing in order to separate the REEs from each other and produce a series of single element products."

Jan 1, 2016

By Elisabeth Kolar, Rik Catthoor, Frederik H. Kriel, Rossen Sedev, Gareth Hatch, Army Research Laboratory, Craig Priest, Scott Middlemas

"This paper reports solvent extraction of rare earth elements (REEs) carried out using a microfluidic device and considers the REE loading limit of the organic phase under laminar flow. The microfluidic device contacts aqueous and organic phase streams for a precisely defined contact time (subsecond resolution) and then separates them for offline analysis. Experiments are reported examining the effect of contact time on extraction. We focus on three REEs: one ‘light’ (Nd), one ‘mid’ (Dy), and one ‘heavy’ (Yb) REE, which are extracted using Cyanex® 572. It appears that loading limits may be locally exceeded in the organic phase near to the liquid-liquid interface, where third phase deposits are observed. Third phase formation was also observed close to the liquid-liquid interface in two-dimensional confinement, showing similar third phase adsorption on glass plates. It is also shown that, under microfluidic flow, a typical first ‘split’ between heavy REEs and light REEs can be carried out without exceeding loading limits.INTRODUCTIONMicrofluidic solvent extraction has emerged as a useful tool for studying extraction of metals in a mineral processing context (Ciceri, Mason, Harvie, Perera, & Stevens, 2013; Ciceri, Perera, & Stevens, 2011; Kriel et al., 2015; Mason, Ciceri, Harvie, Perera, & Stevens, 2013; Priest, Zhou, Klink, Sedev, & Ralston, 2012; Priest et al., 2011). The main advantages are the extremely well-defined and tunable flow behaviour, large surface-to-volume ratios, short contact times, and minimisation of sample and reagent amounts. Two main flow configurations have been studied to date: droplet-based and co-flowing streambased extraction. In the former, droplets are formed at a microchannel junction (usually a T-junction or flow-focusing junction) and flow downstream as plugs or ‘free’ droplets. In our case, stream-based extraction, the chip is a plate (often glass) with embedded microchannels (i.e. with cross-sections of tens of micrometres) that carry the aqueous and organic phases in contact without forming droplets. Thus, these chips play the role of a mixer in a conventional mixer-settler and phase separation takes place by branching the streams or collection in a vessel at the chip outlet. Stream-based extraction requires stable streams that are usually supported by a particular channel geometry (e.g. guide structure or small ‘pillars’) or surface chemistry, and flow parallel bounded by the liquid-liquid interface(Aota, Nonaka, Hibara, & Kitamori, 2006; Hibara et al., 2005; Hibara et al., 2002). Phases are disengaged downstream at a Y-junction, which is a qualitative difference between microfluidic and bulk extractions."

Jan 1, 2016