Search Documents

By K. B. Han, S. Winkler, M. J. Benoit, M. J. Worswick

"Automotive heat exchangers are fabricated by forming multi-layered aluminum (Al) alloy brazing sheets into the desired geometry and subsequently passing the assembly through a furnace for brazing. As manufacturers seek to use thinner gauge and higher strength sheet to reduce vehicle weight, forming of the Al alloy sheets has become a challenge. Warm forming has previously proven to allay these forming concerns, but no consideration was given to the effect of increasing the forming temperature on brazing. Recently, it was shown that annealed sheet was more susceptible to the detrimental phenomenon of liquid film migration (LFM) during brazing if formed above 150°C, while work hardened sheets showed no increased susceptibility to LFM with increasing forming temperature, up to 250°C. In the current study, the brazing performance of simulated battery cooling plates was investigated. The plates were fabricated both from fully annealed and work hardened sheets. Brazing was assessed by microstructural evolution during a brazing cycle. The post-brazed microstructure varied with strain and forming temperature in plates made from annealed sheets, while no variation in microstructure with location or forming temperature was observed in plates formed from work hardened sheets.INTRODUCTION Since the 1970’s, one common method of fabricating automotive heat exchangers has been by forming multi-layered aluminum (Al) alloy sheets, and subsequently brazing the formed components together in a controlled atmosphere furnace. The Al alloy sheets used are comprised of at least two Al alloys roll bonded together, but can consist of additional layers, depending on the application; at minimum, the sheets are comprised of a core and clad layer. The core layer, often an AA3xxx alloy, remains solid throughout processing and provides strength to the assembly. The clad layer is always one of the AA4xxx series alloys which, due to their high silicon (Si) content, have a melting temperature range well below that of the core alloy. When the sheet is passed through the brazing furnace, the clad alloy melts to provide the brazed joint filler metal throughout the assembly, while the core alloy remains solid. In order to achieve cost and weight savings, heat exchanger fabricators have used Al alloy sheets with reduced thickness. However, deformation and brazing of these increasingly thin components remains a concern (Zhao & Woods, 2013). Furthermore, springback has been observed after forming sheets of higher initial strength (i.e. work hardened conditions), leading to flatness issues of formed components. Consequently, the ability to form high quality brazed joints is difficult in components formed from higher strength brazing sheets."

Jan 1, 2018

By G. R. Baiden

"An Automatic Haulage Truck (AHT) has been developed for manless tramming of run-of-mine material in an operating mine. The AHT has a 70-ton capacity and uses an electric trolley system in combination with a computer control system to operate the vehicle. The purpose of the AHT was to provide a high capacity, high productivity material transfer system where conveyor belt applications are not immediately practical.The AHT project was started in 1983 at Inco Limited, Ontario Division as a result of the need for rapid material transport to match increased extraction rates resulting from bulk mining methods. The original concept was to use a continuous loader with the truck. However, in order to minimize development problems the truck project was considered a stand-alone project.The AHT project consisted of concept development, preliminaryand detailed design, manufacture, surf ace testing and mine implementation.The AHT was manufactured and ready for testing in 1988. At this point the truck was first moved onto the test track for debugging. This proved successful and in 1989the decision was made to install the AHT at Little Stobie mine on 2000 level. Commissioning of the system was started in 1990and at present a fully functional automated haulage system is in place at Little Stobie mine producing 3000 tons/day.This paper describes the project presenting results achieved to date."

Jan 1, 1992

By L. Nastac, Y. Xuan

"The metal-matrix-nano-composite (MMNCs) in this research work consists of an A356 alloy matrix reinforced with 1.0 wt. % SiC 50 nm diameter nanoparticles that can be dispersed within the molten alloy matrix via ultrasonic stirring technology (UST) and induction melting and stirring processing. The necessary ultrasonic parameters to achieve the essential cavitation for adequate degassing and refining of the A356 alloy as well as the optimum fluid flow characteristics for uniform dispersion of the nanoparticles into the A356 alloy matrix have been investigated in this study by using computational fluid dynamics (CFD) modeling with a magneto-hydro-dynamics (MHD) model and an UST cavitation model.The MHD model accounts for turbulent fluid flow, heat transfer and solidification, electromagnetic field as well as the complex interactions between the solidifying alloy and nanoparticles by using ANSYS Maxwell and ANSYS Fluent Dense Discrete Phase Model (DDPM) and a particle engulfment and pushing (PEP) model.INTRODUCTIONAluminum matrix nanocomposites can offer outstanding properties, including low density, high specific strength, high specific stiffness, excellent wear resistance and controllable expansion coefficient, which make them attractive for numerous applications in aerospace, automobile, and military industries field (Bozic, 2010, De Cicco, 2009, Elshalakany, 2014, Goh, 2006, Jia, 2013 and 2015, Liu, 2014, Reihani, 2006, and Su, 2010).As shown in literatures (Aki, 1999 and Mussert, 2002), it is highly advantageous to use nano-sized ceramic particles to produce metal matrix nano-composites (MMNCs) since similar ductility and higher strength with the metal matrix can be achieved. Currently, there are several fabrication methods of MMNCs, including mechanical alloying with high energy milling (Chen, 1997) , ball milling (Filho, 2003), nano-sintering (Groza, 1999), spray deposition, electrical plating, sol-gel synthesis, laser deposition, etc. The mixing of nano-sized ceramic particles is normally lengthy, expensive, and energy consuming.Ultrasonic Stirring Technology (UST) has been extensively used in purifying, degassing, and refinement of metallic melt (Jian, 2005, Khalifa, 2008, Eskin, 2002, Xu, 2004, and Meek, 2006) mainly because introducing the ultrasonic energy into a liquid will induce nonlinear effects such as cavitation and acoustic streaming. SiC nanoparticles are widely used as reinforcement particles due to their relatively good thermal and chemical stability. Ultrasonic vibration can improve the wettability between the reinforced nanoparticles and the metal matrix (Lan, 2004, Cao, 2008, and Yan, 2011), which will assist to distribute the nanoparticles more uniformly into the metal matrix. Ultrasonic cavitation in liquids causes high speed liquid jets of up to 1000 km/h. Such jets press liquid at high pressure between the particles and separate them from each other (Hielscher, 2005)."

Jan 1, 2016

By H. Utsunomiya, Mehdi Sanjari, Abu Kabir, Steve Yue, Jing Su, L. Kestens, In-ho Jung

The microstructure and texture evolution of low temperature rolled AZ31 magnesium alloy during annealing were investigated. The specimens were rolled at the temperature of 100? at a high rolling speed of 1000m/min with a reduction of 30% in one pass. Annealing was conducted at various temperatures ranging from 200? to 500? for different time. To study the effect of fast speed rolling, the same annealing procedures have been applied for the specimens rolled at a significantly lower speed of 15m/min. The microstructure was characterized by optical microscopy and scanning electron microscopy, while the texture was analyzed by X-ray diffraction analysis and electron backscattered diffraction analysis. Texture weakening occurred during annealing at both fast and slow rolling speeds. However, at the same annealing condition, fast rolled specimens always had weaker intensity of basal texture than slow rolled ones.

Jan 1, 2014

By M. Hashemzadeh

The efficiency of water use is a top priority for the global minerals industry, especially in regions with limited freshwater supplies. In these areas, the freshwater shortage has prompted mining companies to search for alternatives to freshwater sources. Seawater has been proven to be a potential water source for mineral beneficiation and metal extraction processes. This study compares chalcocite leaching behavior with ferric chloride to that with cupric chloride. We carried out leaching tests with a highly pure chalcocite sample in jacketed reactors under fully controlled pH and solution potential. The effect of chloride concentration, oxidant concentration, and temperature on copper extraction was quantified in both cupric and ferric chloride systems. In the ferric chloride system, increasing ferric concentration showed a positive effect on the first stage of chalcocite leaching. In the second stage, increasing temperature markedly enhanced copper extraction. In the cupric chloride system, chloride concentration presented a considerable effect on both the first and second stages of leaching, while temperature had a remarkable effect only on the second stage. The findings of this study would be beneficial to mine operations aiming to replace fresh water with seawater for heap leaching of chalcocite. INTRODUCTION Mineral processing operations/plants are normally operated adjacent to mines which are often located in remote and arid area, such as northern Chile, southern Peru and Australia with limited access to fresh water (Liu, Moran, & Vink, 2011, 2013). Water scarcity in these areas has prompted mining companies to invest in sustainable technologies to reduce the water use and/or increase the water use efficiency. One of the current sustainable approaches in mineral processing operations is to replace fresh water with seawater. Seawater is now being increasingly used for mineral beneficiation and metal extraction processes (Hernández et al., 2015). Another application of seawater could be for heap leaching of copper secondary sulfides, mainly chalcocite. However, the high concentration of chloride ion in seawater may significantly affect leaching kinetics of copper sulfide concentrates and ores (Watling et al., 2014). Therefore, it is essential to develop a fundamental understanding of the leaching of chalcocite in chloride media.

Jan 1, 2019

By P. R. A. Andrews

"The sillimanite group minerals, kyanite, sillimanite and andalusite are identified as alumino-silicate minerals with the common chemical composition AIP3.Si02' so that each possesses similar physical properties. Kyanite is the most abundant mineral and mainly occurs in Quebec, Ontario and British Columbia; sillimanite occurs in Ontario and Manitoba; and andalusite in Nova Scotia. The main use for the sillimanite-group minerals is in refractory applications for the production of refractory bricks and shapes. In refractory applications, the main performance criterion is the relative percentage of mullite formed within the material during firing. This phase gives a greater degree of resistance to creep deformation and slag attack, and improves the ability of the refractory to withstand high temperatures under load. The beneficiation of refractory silicate minerals has been the subject of many investigations at CANMET, and the former Mines Branch. Eighteen kyanite, two sillimanite, and three andalusite evaluation studies were conducted between 1933 and 1987. A review of some of the more important studies is presented, which includes information concerning mineralogy, beneficiation methods and flotation data."

Jan 1, 1995

By G. Heinrich

Size by size recoveries and pentlandite liberation data from image analysis were used to evaluate plant tests of pentlandite flotation and pentlandite/pyrrhotite middlings flotation from pyrrhotite in a circuit treating low grade magnetic intermediates at the Strathcona Mill. Raising the pH with lime gave improved selectivity for liberated pentlandite but there were major losses of middlings unless the circuit was pulled hard indicating the need for finer regrinding. However, size by size recoveries at the normal regrind showed that, while the pentlandite recovery improved in the finer ranges, the pyrrhotite recovery also increased leading to little selectivity in any size range. A much finer regrind gave greatly improved selectivity in all size classes suggesting that 'surface polishing' as well as liberation effects were being seen. Using liberation data from image analysis of the products, surface polishing accounted for over 99 % of the improvement in selectivity. Unreasonable recoveries of more highly liberated particles were observed for liberation analysis by volume fraction but showed the expected trend in recovery when the analysis was based on surface liberation. The surface liberation data showed that the improved pentlandite recoveries after finer regrinding were to more than 90 % caused by improved liberation with the remainder contributed by surface polishing effects. The practical implications of this work are that i) the comparison of particle grades with product grades allows to estimate the effect of regrinding on co-flotation/entrainment, ii) surface liberation models should be used for evaluating recoverabilities by flotation and iii) regrind circuits may be set up to ensure that all particles go through the mill or that only the coarse fraction is reground depending on the surface scrubbing found to be required.

Jan 1, 1993

By M. C. Villeneuve, P. A. Siratovich

We present an integrated analysis of laboratory-based thermally induced fracturing and results of numerical models to give insight to the role of thermal shock fracture on geothermal reservoir rocks. Thermal stimulation is a reservoir permeability enhancement technique applied to commercial geothermal reservoir rocks to enhance fluid injection capabilities for spent power plant working fluids. The process is well known to enhance permeability but the thermodynamic and physical constraints of the process are less certain. In an attempt to constrain the interaction and the ideal conditions that lead to permeability enhancement, experimental procedures were carried out to mimic the conditions that a reservoir rock would experience during a thermal stimulation using temperature differentials ranging from 50-300°C. Samples underwent such thermal gradients under controlled laboratory conditions and were characterized for the changes to permeability, porosity, ultrasonic velocities, dynamic elastic moduli and petrological changes. The thermal stimulation was simulated in a FLAC2D thermal numerical model to investigate the nature of the thermally induced changes in the sample. The development of this model also allows us to investigate the relationship between geological characteristics and the ability to thermally stimulate any type of rock. The results indicate that numerical thermal shocking experiments are corroborated by laboratory-based results. The implication of this study is that the refined numerical models present an insight to the conditions and constraints under which thermal stimulation can prove to enhance permeability that could not be gained through purely laboratory-based studies.

Jan 1, 2015

By A. Mular, T. Bond, G. D. Farnell, J. F. Kingston

"ABSTRACT:-A 60—cm semiautogenous grinding-(SAG) mill was designed -for continuous wet operation in closed circuit with a vibrating screen. The circuit is fully instrumented and automated. Part of the control system incorporates Foxboro SPEC 200 controllers around the pump box to maintain level. The rest of the control system involves an ACTION model BC2 basic direct digital controller that handles all other inputs/outputs and contact closure sensing:·The success of the control system is attributed to the uniqueness of specially designed mass flow metering systems. Various control strategies are possible. Employed to date has been control of a mill load set-point by cascading the deviation from load set-point as the set-point to the fresh feed rate ""controller"". Mill feed water is ratioed to total flow rate of solids fed to the mill. The performance of the circuit is being correlated with the performance of full scale SAG circuits in British Columbia to develop models, to assess the feasibility of scale up and to investigate the effects of design variables on responses such as circuit throughput. 1 INTRODUCTIONWhere ore types are appropriate, semiautogenous grinding and/or autogenous grinding (AG) has replaced conventional grinding. Secondary/Tertiary crushing plants are thereby eliminated so that capital expenditures are less and overall comminution costs can be lower (Barratt 1982). To establish the suitability of an ore for SAG circuits, pilot scale tests with 1.7 to 1.8 M diameter mills are often conducted. At least one test per ore type in a deposit has been necessary. Often, each test involves a large amount (up to 50 tonne) of sample, so that the testwork can be expensive and may discourage the use of SAG or AG circuits. However, MacPherson (1977) has employed a continuous 45 cm dry Aerofall mill circuit closed with screens and an air classifier to determine whether ores are suitable for SAG milling. The amount of sample per ore type is of the order of 60 kg or less. Thus an established SAG mill scale up procedure that employs small circuits is highly desirable.The purpose of this paper is to describe a small 60 cm wet continuous SAG/ AG mill pilot circuit assembled at the University of British Columbia to study the feasibility of scale up, to assess the influence of design variables, to develop mathematical models and to evaluate the effects of alternative control strategies on circuit performance"

Jan 1, 1988

By R. Druffel, P. Wittke-Gattermann, M. Wittke

"The two tubes of tunnel Hirschhagen along the highway A44 in Germany, underpass the federal road B7, a railway line and the valley of the river Losse close to the city of Hessisch Lichtenau. The ground in the area consists of Triassic sand- and siltstones (""Buntsandstein"") as well as tertiary clays. Prior to tunneling, the groundwater in the area is planned to be lowered by means of a gallery of deep wells. As a basis for the design of this dewatering gallery, two large pumping tests have been carried out. The results of these tests have been evaluated by means of 3D-Finite Element analyses. By means of the large-scale model, the influence of the anisotropy resulting from jointing and bedding and the influence of fault zones in the area have been taken into account, which lead to a thorough basis for the design of the dewatering gallery.INTRODUCTIONThe 4.2 km long Tunnel Hirschhagen of the highway A 44 crosses below the federal road B7, a railway line and the river Losse close to the city of Hessisch-Lichtenau in central Germany. Both tunnel tubes are located in a subrosion depression in which Triassic sandstone and tertiary clay prevail. It is planned to lower the groundwater table in the area of the meadow of the Losse prior to tunnel heading [1]. Groundwater lowering is planned to be achieved by means of a series of large pumping wells. The bottom of the river Losse will be sealed in order to avoid direct inflow of water from the river into the ground (Fig. 1 and 2)."

Jan 1, 2015

Orebody classification systems ? Modern classification systems ? Genesis and environment of deposition (Important in economic geology) ? Shape and structure / Form, texture and mineral content ? Mining and geomechanics ? Size ? Massive versus tabular Requirements for mining method selection ? Classification of ore deposit ? Shape, size, attitude, continuity ? Grade and distribution, strength and large scale structures present, mineralogy and small scale structure, host rocks ? Classification of mining method ? Method of support (Stress ? strength ratio) ? The method selection ? Geographical and economic factors of the location

Feb 1, 2008

By P. Chollet, A Constant

THE RESULTS of a previous investigation ( 1) on the work-softening of some heat-treated steels have led to the conclusion that the occurrence and intensity of the phenomenon is possibly governed by the work-hardening capacity of the material, and the relative amount of retained austenite. The first assumption is compatible with Polakowski's theory (2) that the absence of work-softening, in steels quenched and tempered at relatively low temperatures, may be attributed to the high rate of work-hardening which compensates for, and even out-weighs, the loss of internal energy associated with the simultaneous rearrangement of the original system of internal stresses. Indeed, Polakowski first considered the work-softening as a manifestation of a partial release (by cold-working) of the latent strain energy stored in

Jan 1, 1962

By M. Jackman

"Froth stability is critically important for an effective separation of fine and ultrafine particles using column flotation. While a desirable froth stability is required to facilitate the drainage of entrained gangue particles for secondary cleaning, excessively stable froths could create problems in separation efficiency and down-stream processing. In this work, we demonstrate that a stable foam was produced using a poly (N-isopropylacrylamide) (PNIPAM) solution at the temperatures below the critical solution temperature. In contrast, very little foam was produced at the temperature above the critical solution temperature (~32 oC) of PNIPAM. We can also tune the foam stability by changing the temperature of wash water. When warm water of temperature of 50 oC was applied, the foam collapsed and diminished. This is probably attributed to the switching of PNIPAM molecules from coiled to a globule conformation as the temperature is increased. Our results indicate that the foamability and foam stability can be tuned by tempartureresponsive PNIPAM. This is the first time that thermo-responsive PNIPAM has been shown to have potential as a modifier of froth stability in column flotation.INTRODUCTIONIn mineral processing, column flotation has become a more prevalent process in the separation of fine mineral particles (typically < 100µm). Traditional flotation cells are sometimes less efficient in selective separation of ultra-fine particles (Kohmuench et al., 2009). The efficiency of flotation columns is dependent on the froth stability at the top of the cell to drain the unwanted gangue particles entrained in the froth. The greater froth height in flotation columns, compared to mechanical flotation cells, gives a longer froth residence time, allowing more of the drainage process to take place before the froth reports to the launderer. Secondary cleaning, by applying a wash water shower to the froth, enhances drainage of gangue particles entrained in the froth, and improves the recovery of the targeted minerals (Finch et al., 2007).While a stable froth is desirable to facilitate drainage of entrained gangue particles, greater amounts of fine particles have been found to contribute to excessively stable froths which could create problems for down-stream processes (Bethell et al., 2012). Operators have tried spraying additional wash water on the froth, and reducing frother dosage to destabilize the froth and to prevent backup at the launderer. The former is sometimes inefficient, and the latter results in unacceptable recovery loss. Currently, the best practice is often the installation of larger froth launderers, adding expensive defoaming agents, and/or using deaeration tanks (Bethell & Luttrell, 2005)."

Jan 1, 2016

By Xiaolin Cheng, A. J. Sinclair

"Norm calculation procedures originally designed principally for igneous rocks are very rigid in their application and, in general, do not utilize important alteration minerals. For instance, volatile components are essential constituents of many metasomatic rocks but either are not used or are not used effectively in determining normative minerals by the CIPW norm or Niggli-Barth norm procedures. Our approach to determining norms for metasomatic rocks allots all major, minor and volatile constituents to a set of standard normative minerals which are commonly observed as products of hydrothermal alteration. A useful procedure is to have a metasomatic norm approximate the mode as closely as possible. Petrographic information helps to provide the necessary mineralogical constraints. With the recognition of an immobile component and knowledge of sampling and analytical errors in lithogeo chemical data, it is possible to recast norms into amounts of alteration minerals relative to a given amount (100 grams) of parent rock. Combining these results with the calculations of absolute loss or gain of individual chemical constituents and considering errors (e) for an appropriate confidence level, an overall (net) material exchange equation can be presented as follows:<equation>where all items have extensive units (e.g., grams). The model includes the initial and final mineralogy of rocks (evident in the field) as well as gains and losses of specific elements. Only those constituents whose calculated losses and gains are significantly different from zero are retained in the above model, and only the normative minerals with abundances significantly different from zero are included in the model (equation). One advantage of the chemico-mineralogic model is that parent rock and product are modeled in mineralogical terms that are familiar to and easily usable by exploration geologists."

Jan 1, 1995

By S. S. Rahman, A. Gholami, M. A. Aghighi

"This paper provides a foundation for studying the growth of fractures in presence of other discontinuities and different anisotropies of low permeable hydrocarbon formations and helps to improve the design strategies for multistage fracturing.The multistage fracturing technology has recently been used to exploit low permeable hydrocarbon reservoirs. However, the mechanism of hydraulic fractures interaction and the impact of local heterogeneities on ultimate trajectory of the growing hydraulic fractures are not yet understood in depth. A fully coupled poroelastic Finite Element based model is developed to investigate the mixed mode propagation behaviour of growing hydraulic fractures. This model takes advantage of an explicit representation of the fracture which enables us to take the effects of rock and fluid related parameters into account. Moreover, impact of fracture geometry and leak-off phenomenon is investigated. The refined mesh around the crack provides the added advantage of more detailed stress distribution, pore pressure change and back stress in the vicinity of the fracture and in particular at the fracture tip. The potential deviation propensity of the fractures is evaluated based on the fundamental rule that fractures propagate perpendicular to the direction of the minimum horizontal stress.This study shows that pressurization of transverse hydraulic fractures results in the reorientation of local principal stresses, particularly in vicinity of fracture tips. Variation of flow patterns clearly influences the evolution of shear stress around the fracture tips which will potentially lead to mixed-mode I and II fracturing and consequently, fracture deviation. The presence of local heterogeneities such as preexisting fissures and/or fractures is a main source of such pore pressure induced stress redistribution and reorientation and potential deviation of hydraulic fractures.Most existing models ignore or simplify the effect of pore pressure/stress coupling as well as the fracture geometry and fluid flow within the fracture. Also, the fluid leak-off from the hydraulic fracture into the formation, which is a controlling factor in fracture growth, is often considered using analytical models. Taking advantage of a fully coupled porelastic model along with an explicitly discretized fracture, this study provides a more realistic insight into the complex fracture propagation processes of multistage fracturing operations particularly in presence of reservoir geo-mechanical complexities."

Jan 1, 2015

By Mori Fresko, Stuart M. Jones Jr

"This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded.A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.INTRODUCTIONThis paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide. The list is maintained by Stuart M. Jones, Jr. (author), and is included in the appendix. This list has been the inspiration for similar papers in the past several SAG Conferences. Updates have been solicited from all major mill manufacturers and most have responded. Information from this list is compiled to illustrate the growth of the AG/SAG mill market and the use by industry and selected geographic areas. It covers the market growth through the end of 2010."

Jan 1, 2012

By Daniel B. Leznoff

The cyanoaurate anions [Au(CN)2]- and [Au(CN)4]- are shown to be useful building blocks for synthesizing supramolecular coordination polymers. For the gold(I) unit, aurophilic interactions often increase the structural dimensionality of the system and can impart increased thermal stability to the metal-polymers produced. A series of polymers of the form M[Au(CN)2]2(Ligand)x have also been prepared and show large colour changes upon changing the ligand, thus illustrating a sensor-type application. Both building blocks can mediate significant antiferromagnetic and ferromagnetic interactions between transition-metal centres in the polymers. For the gold(III) unit, no metal-metal interactions are observed, although weak Au-N(cyano) interactions control the intermolecular packing. Several structural examples of cyanoaurate-based coordination polymers are presented, including 2-D and 3-D arrays and a supramolecular square.

Oct 1, 2003

By Kathy Pomeroy

Sharing?? l Maybe not the first image that comes to mind when we think about the historical corporate mind set and track record of many corporations ? ! A Fundamental Change in Relationships l From a worldview of independence to one of recognized interdependence l Collaborative action with communities for long range mutual goals l Acceptance of greater accountability for the whole l Community and government relationships based on trust, mutuality, respect for human rights, equity, sustainable agreements

May 1, 2002

By A. Chaisantikulwat

Most solid-oxide fuel cell (SOFC) modeling emphasizes steady state cell operation. However, understanding the dynamic behavior is essential to predict the performance and limitations of SOFC power systems. In this work, we demonstrate a dynamic model of a SOFC, and we simulate a feedback control scheme that can maintain output voltage despite load changes. Dynamic response is determined as the solution of coupled partial differential equations derived from conservation laws for energy, mass and electric charge. From such a model, the step responses to system input variables can be determined. Low order dynamic models that are sufficient for feedback control design can be derived from the step responses. The development of the partial differential equation model is outlined, and the limitations of the control system are discussed.

Jan 1, 2005

By Z. Sun

The hydrogen embrittlement and stress-corrosion cracking (SCC) behavior of an a -titanium alloy and its two kinds of welding samples have been investigated. The results show that this alloy has very low susceptibility to SCC, and the values of Kiscc for the alloy are 46.4 MPa ? m&apos; 65.86 MPa ? mu2 in the direction of T-L and L-T, respectively. The scanning electron fractographs show transgranular and quasi-cleavage fracture. The hydrogen embrittlement results show that the notch sample of the alloy is not sensitive to hydrogen, but the electro-beam welding and diving-arc welding samples are sensitive.

Jan 1, 2005