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By A. Mykytiuk, I. E. Puddington, W. D. Macleod, F. W. Meadus

"A laboratory-scale continuous procedure for the up-grading of naturally occurring tin ores, based on the principle of spherical agglomeration, is described. High recoveries are indicated. A proposed second stage suggests useful fractionation steps.IntroductionA LABORATORY-SCALE batch process for the upgrading of a tin ore using the principles of spherical agglomeration has already been described (1). This procedure consisted of milling, for about an hour, a precrushed ore with at least 200 per cent water, 0.2 per cent of a reagent such as tall oil (to render the de-sired ore particles hydrophobic) and about 3 per cent of a viscous petroleum oil. The feed material passed an 8-mesh Tyler sieve, and the percentages of re-agents are based on the dry weight of the feed. Du-ring the grinding, the hydrophobic particles transfer into the oil phase to produce coherent semi-solid bodies while the gangue stays preferentially in the aqueous phase. The concentrate can be separated from the gangue easily by a mechanical operation. Using an ore containing about 0.3 -0.5 per cent tin, grades of from 1.5 to 7.0 per cent were obtained by varying the pH of the system. Recoveries fell from about 80 per cent to as low as 50 per cent as the grade in-creased."

Jan 1, 1966

By F. Osmond, R. Kelly

"Malcolm Knowles, the famous adult educator once wrote: ""What a challenge we in human resources development face if we are to avoid the obsolescence of our workforce. I can foresee this challenge requiring that we reconceptualize (...) and redefine the role of HRD, away from that of managing the logistics of conducting training activities to that of managing a system of learning resources"".The context in which this was written surrounds the subject of adult education and the need for business and industry to change its approach to the treatment of adults as learners. In explaining what 'managing a system of learning resources' means, Knowles refers to line supervisors and managers as the most ubiquitous resources for day-in and day-out employee development. In many organizations training has been largely a staff rather than line responsibility. Even where trainers reported to line management, it was still seen as a staff function performed by a few specialists.This change referred to by Knowles places a much heavier responsibility on line supervisors and managers for the development of their personnel than has traditionally been the case. Managing that change - handing over the responsibility to the line organization - is the supreme challenge for the HRD function.Just why is this change necessary? Because too often, the learner does not effectively use on the job what he or she learned in the classroom. In fact, learners often discard new methods and revert to the older ways. The reason training does not stick is that the systems for training and work management are most often separate entities and while one may support the other, they need to be a single integrated system in order to ensure the transfer to the job effectiveness of training and some real value for the training dollars.Because much training can be wasted, steps have to be taken to ensure that it fulfills its intended purpose. The effective and continuing application of knowledge and skills that learners acquire can only be realized when line supervisors and managers are at the centre of the training system.This paper describes how such a systemis being developed at the Iron Ore Company of Canada (IOC) as a functional training program is introduced. The following text provides background information on the IOC - who they are and where they are located, a definition of functional training, an evaluation of the suitability of this approach for adults in industry, a description of how the program is being implemented at IOC and some observations that have been made as this change is experienced."

Jan 1, 1995

By J. F. Wang, Y. Jin, Z. L. Wang

Smelting reduction as an ironmaking technology for the 21st century has been challenging the traditional blast furnace. The process has many attractive advantages over the blast furnace, however, the massive by-produced coal gas mainly containing CO, H2 and CO2 requires further treatment. From a chemical engineering view, coal gas is a valuable chemical stock and can be transformed into hydrogen-rich synthesis gas. Hydrogen can be directly used as clean fuel and synthesis gas can be used for the production of some important chemicals such as methanol, ammonia and dimethyl ether. Among those chemicals, dimethyl ether as an alternative clean fuel for diesel engine and liquefied petroleum gas has been drawing more attention. It has excellent environmentally-benign behaviours not only in compression ignition combustion, but also in the much lower emission of SOx and NOx. In this work, a combined technology of smelt reduction ironmaking and direct synthesis of dimethyl ether, which will strongly promote the energy efficiency, environmental protection and resource recovery, is proposed and described in detail.

Jan 1, 2004

By P. Gautier

Current feedstock in the aluminum hot forging processes can be used in the cast or extruded forms. The microstructural variation between as-cast and extruded materials could result in different mechanical properties and corrosion resistance for hot-forged products. Corrosion performances were examined for forged parts produced by two AA6082 feedstocks at different conditions using the following corrosion tests: open circuit potential, anodic polarization, salt spray exposure and corrosion fatigue. With the help of optical and scanning electron microscopes, metallographical investigations were carried out on cast-forged and extruded-forged materials before and after corrosion. The corrosion behavior of both materials was compared in both as-forged and aged tempers. Results show that there is no significant difference in the corrosion performance for final cast-forged and extruded-forged products.

Jan 1, 2011

By S. A. Bunk, E. C. Eccleston, J. J. Amsden

Fluidized bed technology has been widely applied to mineral and metallurgical processes. Over the years, modeling of fluidization technology has progressed to a level at which basic design parameters can usually be defined based on empirical correlations. In addition, scale-up considerations have become better understood, and significant advances have been made in the area of computer simulation. Despite these advances, fluidization is a complex phenomenon, and modeling tools remain limited in their ability to simultaneously model both fluidization and chemical process parameters. As a result, almost all mineral and metallurgical applications of fluidized bed technology require pilot testing prior commercial scale design. This paper outlines pilot plant testing requirements and process development considerations for development of low technical risk commercial designs.

Jan 1, 2011

By T. -W. Hong, Y. Son, S. -J. Hong, D. Choi

The characteristics of indium-tin-oxide (ITO) nanoparticles recovered from TFT-LCD panel scraps were investigated. The ITO was separated from TFT-LCD panel scraps by dissolving the color filter layer located between the ITO layer and the glass substrate. The solution was filtered to separate the ITO from the color filter component, and the filtered ITO was dissolved in the acid solution. ITO nanoparticles were then precipitated with ammonium hydroxide and organic dispersing agent, followed by heat-treatment at 600 °C. HRTEM, EDX and XRD analyses revealed that the 20 nm sized particle were composed of 90 % In and 10 % Sn, and were well crystallized to in the (222) preferred orientation.

Jan 1, 2014

By P. Van Marcke, X. Sillen, G. J. Chen, I. Troullinos, A. Dizier, J. Leysens, X. L. Li, J. Verstricht

"In Belgium, Boom Clay is considered as one of the potential host formations for the disposal of the High Level radioactive Waste (HLW). The URL HADES at 223 m depth at Mol site was constructed in order to study the feasibility of HLW disposal in Boom Clay. Since 1995, the URL R&D programme has focused on large scale demonstration tests like the PRACLAY experiment.The PRACLAY in-situ experiments include a set of three tests: The gallery and crossing test, PRACLAY Heater test and PRACLAY seal test. The main aim of the Heater test is to study at a large scale the thermal impact of a HLW repository on the host rock. The test is housed in the PRACLAY gallery. A hydraulic seal, made of compacted swelling and low permeable bentonite annular ring was installed at the intersection between the heated and the non-heated part of the gallery. The primary objective of the seal is to provide undrained hydraulic boundary conditions for the Heater Test.The PRACLAY gallery was constructed in 2007 and the hydraulic seal was installed in 2010. The bentonite is hydrated by natural and artificial process. The swelling, total pressure and pore pressure of the bentonite are continuously measured and analysed by numerical simulations to get a better understanding of this hydration processes. The performance of the seal is tested systematically by means of gas injection breakthrough tests and permeability tests at interface bentonite / Boom Clay and in the Boom Clay around the seal.The PRACLAY Heater will be turned on at the end of Oct. 2014, since a sufficient seal swelling has been attained to fulfill its role for the PRACLAY Heater test. This paper will focus on the PRACLAY Seal test: How we understand the process behind the hydration of the bentonite and how we test the performance of the bentonite seal."

Jan 1, 2015

By L. Long

Stirred milling of nickel laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a Netzsch LME4 stirred mill on siliceous goethitic (SG), goethitic (G), and saprolitic (SAP) nickel laterite samples (- 2000 ?m particle size) to evaluate the effect of stirrer speed, solid content, water salinity and grinding time. A fine mineral product (-38 µm) was used to evaluate the effect of selective grinding and Ni upgrade. The optimum grinding time for the highest Ni upgrade was 0.25 min, 0.1 min and 0.1 min for the SG, G, and SAP nickel laterite, respectively. A new feed (38-2000 µm) for each nickel laterite sample was prepared for batch grinding tests under the optimum grinding conditions. Upon grinding the 38-2000 µm feed, the - 38 µm product confirmed the effect of selective grinding and nickel upgrade. Size classification followed by stirred milling is a suggested process for Ni upgrade. The best Ni upgrade result was achieved on the SG nickel laterite among the three samples. The Ni grade increased from 0.85% to 1.37%, with 27.8% Ni recovery. Bottle roll leach tests showed that for SG and SAP samples selective grinding had no dramatic effect on Ni extraction due to the slow leach rate of hard mineral particles. Stirred milling of G sample increased the surface area of goethite, resulting in higher Ni extraction. Gravity concentration through a Knelson Concentrator was not effective in the further treatment of the stirred milling products either due to the poor operating conditions or due to the mineralogy characteristics of the feed samples. The energy requirement in the stirred milling was investigated. The first pass of the signature plots study is critical for the purpose of selective grinding, because the best result on selective grinding is achieved in the early stage of the grinding process.

Aug 1, 2013

By D. K. Sarkar, Jiawei Xiong

"Self-assembled monolayers (SAM) on the aluminum substrates are used as the adhesion promoter between two aluminum substrates when bonded with the adhesive in adhesive bonding technology. Traditional surface analysis tools are not capable of identifying the presence of SAM on a surface; therefore, EIS has been used to determine their presence on the aluminum substrates. In this study SAMs have been deposited on aluminum using the monomer of (3-Glycidyloxypropyl)trimethoxysilane (GPTS) organosilane. AA6061 aluminum alloys substrates were chemically cleaned with NaOH and HNO3 to remove the native oxides, followed by immersion in silane solutions. In a second method, SAMs were prepared by applying a spin coating of silane solution to the samples. The prepared SAM coated aluminum samples were analysed by EIS in the three electrode corrosion cell using a diluted alkaline solution. The impedance of the SAM coated aluminum is found be higher than the as-received aluminum. It has been also observed that the open circuit potential (OCP) of the SAM coated aluminum is higher than the as-received aluminum. Both elevated values of the impedance and OCP confirm the presence of SAM on aluminum.INTRODUCTIONSelf-assembly (Schreiber, 2000) is defined as the spontaneous formation of complex hierarchical structures from pre-designed building blocks, typically involving multiple energy scales and multiple degrees of freedom. Generally speaking, SAMs are created by the chemisorption of ""head groups"" onto a substrate from either the vapor or liquid phase followed by a slow organization of ""tail groups"" of a molecule. Typically, head groups are connected to a molecular chain in which the terminal end can be functionalized with groups such as –OH, –NH2, –COOH, or –SH to vary the wetting and interfacial properties (Chauhan et al., 2007; Ulman, 1996; Vashist, Lam, Hrapovic, Male, & Luong, 2014). Though there exist several methods to prepare SAM (Chauhan et al., 2007; Chen, Yang, & Zhang, 2014; Cho, Park, Jon, & Choi, 2007; Igor Luzinov, 2000; Reis, de Melo, & Costa, 2006; Song, Zhai, Wang, & Jiang, 2006; Sugimura, Hozumi, Kameyama, & Takai, 2002; Vashist et al., 2014), the two methods vapor phase (Song et al., 2006; Sugimura et al., 2002) and solution(Chen et al., 2014; Igor Luzinov, 2000) are commonly used. Recently, many articles have been published on the fabrication of superhydrophobic surfaces with SAM technology (Cho et al., 2007; Pan, Shen, Shang, & Xing, 2012; Siddaramanna, Saleema, & Sarkar, 2014; Song et al., 2006). Brassard, Sarkar, and Perron (2011) successfully obtained a superhydrophobic film by applying fluoroalkylsilane via self-assembly on monodispersive silica. SAMs are also reported as good candidates for anti-corrosion and adhesion promotion (Chen et al., 2014; Saleema, Sarkar, Paynter, Gallant, & Eskandarian, 2012). However, papers on the characterization of SAM properties are rarely seen. The most commonly used substrate for SAM is silicon and the method implemented is scanning probe microscopy (SPM) such as atomic force microscope (AFM) (Igor Luzinov, 2000; Moores, 2011; Zhang, 2003, 2005). Igor Luzinov (2000) analyzed the epoxysilane SAMs’ surface morphology and microstructure properties using scanning probe microscopy (SPM) and ellipsometry on single-crystal silicon wafers. SAMs have been used to improve the adhesion bonding of aluminum or plastics but no characteristic data have been presented yet (Saleema et al., 2012; Telegdi, 2007; Wang, Xu, Luo, Wang, & Wang, 2009). Recently, Reis et al.(Reis et al., 2006) have studied SAM of alkane diphosphonate (Gardobond X4661) on Al 5052 alloy samples by EIS in a naturally aerated sodium sulfate solution."

Jan 1, 2016

By J. A. Finch, R. R. Cunningham

The amount of foam volume generated in relation to the gas flowrate has long been used to define the foaminess of a solution and to characterize surfactants. The vessel geometry and gas flowrate range can affect the foam volume results. A fixed area column was tested alongside a variable area conical vessel with two surfactants. It was found that the fixed area vessel will cause foam volume to expand or contract which masks the effect of the surfactant. The conical vessel showed two regimes of foam volume production dependant on gas flowrate. The low gas flowrate regime revealed the physiochemical nature of the surfactant while a high gas flowrate revealed kinematic properties. Foaming properties of a surfactant is best determined with a variable area vessel at low gas flowrate.

Jan 1, 2009

By G. Avramovic-Cingara, H. J. McQueen

The microstructure of commercially pure aluminum was investigated by using polarized optical microscopy (POM), orientation imaging microscopy (OIM), and transmission electron microscopy (TEM) techniques. Specimens were deformed in torsion at 400°C and equivalent strain rate of 0.1 s-1, to various strains of 0.2, 0.5, 1, 4, and 6. The results indicate that POM can usefully reveal grain and subgrain structures over a large field in aluminum. TEM is most suitable to study dislocation substructure and evolution of subgrains. While TEM microscopy and OIM are capable of resolving individual subgrains, OIM can not reliably distinguish subgrains with small misorientations, particularly in samples with low strain. On the other hand, the OIM technique is very useful in the analysis of many regions surrounded by high, medium, and low angle boundaries (HAB, MAB, LAB). Various misorientation maps were studied using different data processing methods. The analysis revealed that the subgrain size is relatively insensitive to strain. The fraction of low LAB ( < 5°) decreased and HAB (>15°) increased conversely with increasing strain, whereas MAB (5-15°) remained stable. The development of an increasingly bimodal grain boundary misorientation distribution is consistent with the predominance of dynamic recovery (DRV) in the evolution of microstructure, combined with geometrical dynamic recrystallization (gDRX), now called grain-refining DRV.

Jan 1, 2006

By Jin Li

The tensile properties and microstructure of AZ91 Mg alloy before and after equal channel angular extrusion (ECAE), and the fracture behavior during tensile testing for as-extrusion and ECAE AZ91 were investigated. The alloy was performed ECAE from one to eight passes at 498K. The elongation decreased with the pass number increasing after ECAE. Grains were refined, partial coarse ß-Mg17Al12 phase fell to pieces, fine ß-Mg17Al12 precipitated in the AZ91 Mg alloy after ECAE. During tensile test the a-Mg/ ß-Mg17Al12, a-Mg/Al8Mn5 interface and the grain boundaries in a-Mg matrix acted as the crack initiation sources. The frequency of micro-cracks at the a-Mg/ß-Mg17Al12 interfaces and grain boundaries increased after ECAE, which accelerated the growth and coalescence of the micro-cracks during tensile test and resulted in the decrease of elongation of AZ91 Mg alloy by ECAE.

Jan 1, 2006

By David M. Parkes, George E. Davies

"Mathematically, the proposed formula is: ""Human Effectiveness + Technological Improvement = Success in the Nineties"". A brief review is made of geology, level of technology, management and labour situations, and range of production costs in coal producing countries. This comparison shows keen competition for Canadian coals, especially from the People&apos;s Republic of China, South Africa and Australia. Domestic competition comes from nuclear energy, hydro-electric generation, natural gas (if permitted) and eastern United States coal.The huge increase in the size and power of surface mining equipment in the last forty years led to modern large-scale open pit mining. While conventional truck and shovel operations will continue to be widely used, more continuous mining and conveying systems will be installed as pits become deeper and haul distances longer. Computer systems will become more sophisticated and their applications more widespread, leading to higher productivity and closer control of all operations and equipment performances and to partial or complete automation of certain operations.The underground revival will be driven by a new generation of mining people, cooperating to produce over 3 million t/y from 300 m longwall faces retreating over 3 km resulting in mine productivities of over 40 tonnes per man shift, as is already achieved in several mines throughout the world. Continuous operation using on-line control system will assist in consistent production with availabilities over 75%."

Jan 1, 1991

By R. S. Douglas

Introduction The mine at Copper Mountain of the Granby Consolidated Mining, Smelting and Power Company was one of the pioneers in the use of blast-hole diamond drilling for ore breakage. This method of mining has now been brought to a high degree of perfection. The system in use has?been described in a previously published paper which has become an important part of the literature o the blast-hole drilling method. At the time of the establishment of the system at Copper Mountain, standardized loading and drilling procedures were set up. These procedures were based partly on the results of experiment and partly upon the judgment of men experienced in breaking rock in the mine. The success of the method has been proof of their adequacy. With the progress of scoping in the mine, the diamond drill method of breaking was applied to other ore blocks where different conditions obtained. It was found necessary to make adjustments in the standard procedures to get the best results under the new conditions. The following paper attempts to express, in terms of mathematics, the relations of the variable factors. Until recently, estimations of drilling required were based upon the tonnage to be broken and the proposed rate of explosive loading. A revised method of estimating is outlined below which is direct and which involves no unrelated variable factors.

Jan 1, 1947

By George A. Guess

The making of contracts for the purchase of ores is a business which the metallurgist usually understands better than the miner. Companies in the custom ore business often employ an ore buyer who is aware of the class of ore which the smelter needs, and is thoroughly conversant with the business. The miner on the other hand makes ore contracts but seldom, and it is often only after a settlement has been made that he realizes the meaning of the terms of the contract under which he has sold his ores. He has expectations usually greatly in excess of the amount &apos;net proceeds&apos; shown at the bottom of the settlement sheet. Seldom does the occasional shipper really know his contract. A somewhat similar parallel is to be found in insurance policies. We all have insurance policies; we never know the conditions contained in them until after the fire. The clauses in the policy are for the protection of the Insurance Company. An Insurance Company has no friends.

Jan 1, 1926

By Fulchand Shende

Around the world many potash mines experience brine inflow problems. The presence of brine in underground excavations may induce structural and stability problems. A study has been carried out to simulate the effect of brine on the performance of pillar support. The testing program consisted of loading potash specimens in a creep frame, and simulating inflows by continuously pumping brine into an experimental cell. Brine temperatures and load conditions were varied to simulate several mining and inflow conditions. Specimens were fitted with acoustic emission transducers to monitor energy emissions during an eight-hour test duration. Samples of brine were also collected to provide K+ and Na+ concentration data necessary for an accurate assessment of the dissolution process. Test results indicated that dissolution rates are highly dependent on brine temperature and load conditions. Loads approaching 50% UCS tend to generate very high rates of energy emissions, often leading to the failure of the simulated pillars. This study demonstrated that acoustic emission could be effectively used for predicting the performance of pillars when exposed to inflow brine.

May 1, 2001

By M. Sokoto, H. Hata, K. Nishina, K. Haiki

Fluoride ions in zinc electrolyte cause corrosion to aluminum cathode plates at zinc electrowinning process, so we have developed an iron compound as a fluoride ion adsorbent used in zinc sulfate solution. The iron compound is synthesized from FeC13 solution with a small amount of sulfate ion by neutralizing reaction with Na2CO3 solution. The fluoride ions adsorbed on the surface of the iron compound are desorbed in alkaline solution and the iron compound can be reuse as a fluoride ion adsorbent. Moreover, if adsorption capacity of the iron compound decreases, it can be dissolved in HCl solution and re-synthesized.

Jan 1, 2008

By K. S. Coley, M. A. Rhamdhani, G. A. Brooks

Interfacial phenomena in high temperature reactions such as between iron alloy and slag is well documented but not fully understood. It is believed that a gradient of oxygen concentration plays an important role to the occurrence of such phenomena. This article describes the results from the continuation of the study of interfacial phenomena between Fe-Al alloy droplets and CaO-SiO2-Al2O3 slag. Materials characterization techniques involving microscopic observations, depth profiling, bulk, point analysis and were carried out. The roles of oxygen as well as other factors that contribute to the interfacial phenomena were evaluated. The results and their implications to steelmaking will be discussed.

Jan 1, 2004

By W. D. Robbson

DR. G. W. RAMSEY (l): A study of our non-treatment silicosis autopsy material for the years 1940-43 inclusive, in addition to the common findings of fibrosis, nodules, and emphysema, shows marked thickening of the alveolar walls. This change is due to one or more of the following factors: congestion, edema, accumulation of both small and large monocuclear cells within the interstitial tissues and large monocuclear cells attached to the lining membrane of the alveolar sacs. This alteration in the alveolar walls, we believe, is one of the most important factors in producing impaired pulmonary function. Comparison of our first autopsy material of a case receiving twenty aluminium treatments beginning June, 1943, shows a striking change in the alveolar walls. In all areas free of silocotic nodules and fibrous tissue, the alveolar walls approach normal thickness and are free of cellular deposits. No change was noted in the old processes and none was expected. We believe that these changes in the alveolar walls were brought about by the aluminium therapy and that they constitute a major factor in the improved pulmonary ventilation noted in treatment cases.

Jan 1, 1945

By A. M. Reyes

Flow field hydrodynamics of serpentine flow channels was investigated numerically using computational fluid dynamics (CFD). The velocity profile simulated by the CFD model was evaluated with respect to experimental results from the literature. Rectangular and tapered flow channels were compared with respect to mixing and water management capabilities, and pressure drop. The CFD model was further developed to account for electrochemical reaction on the cathode side to determine which channel configuration was most effective in reactant conversion. The velocity profile differences between the channels were found to impact reactant conversion, as the rectangular channel had the highest conversion. With respect to water management, although the tapered channel was found to have a higher overall pressure drop, the rectangular channel was found to have higher shear and pressure forces acting on simulated liquid water droplets in the channel.

Jan 1, 2005