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By K. Poorhaydari, B. M. Patchett, D. G. Ivey

In this paper, some applications of carbon extraction replicas, as samples for transmission electron microscopy (TEM), are discussed. Modern high strength microalloyed (HSMA) steels, used as structural or pipeline materials, have very small grains with substructures. Replicas used in TEM can resolve the grain boundaries and can be used for grain size measurements in cases where the small size of the grains pushes the resolution of conventional optical microscopes. The grain size variations obtained from replicas correlated very well with mechanical property variations, indicated by hardness, in the fine-grained heat-affected zone and base metal of some welded HSMA steels. Replicas are also very suitable samples for precipitate examination with analytical TEM. Advantages and limitations of the application of replicas, as well as some corrections for the estimation of the volume fraction of fine precipitates, are discussed.

Jan 1, 2005

By Gabriel Zarate

"Los Bronces had two ROM dump leach operations designated Leach I and Leach II. Leach I was commissioned in 1998 and stopped in 2014 due to the mine requirements. Leach II plant, commissioned in early 2002, was built to treat around 700 million tons of marginal ROM ore averaging 0.45 % total copper. The mineralogy of this material was estimated to be 70% chalcopyrite, 20% chalcocite/covellite and the balance oxides.The original electrowinning plant design capacity for copper production was nominal 19,500 tonnes per year at a current density of 276 A/m2 and a current efficiency of 92%. Presently, Los Bronces San Francisco plant typically operates at current densities between 390 and 440 A/m2, much higher than the average in the industry, with current efficiencies around 93% and a maximum copper cathodes production of 37,200 tonnes per year.In order to accomplish these achievements, a number of modifications in the process conditions, in the cell hardware and in the operational procedures have been implemented. In the first case, the specific flowrate, copper concentration and temperature of the electrolyte were modified to accommodate the operational requirements facilitating the increased current density. Associated with the cell hardware, a six cells expansion was added, upgraded equipotential inner cell busbars were installed and the cross section of the cathode hanger bars was enlarged for increased current carrying capacity. Documented operational procedures like short circuit detection and cathode weight control were improved.The modifications implemented and the results obtained are discussed in this paper.INTRODUCTIONLos Bronces Division of Anglo American Chile is located up in the Andes Mountains, northeast of Santiago. It had two cathode plants, Los Bronces at an altitude of 3500 meters above sea level (m.a.s.l.) commissioned in 1998 and closed in 2014 and San Francisco at an altitude of 2800 m.a.s.l. and in operation since 2002.The process is leaching run off mine (ROM) low grade copper sulphide ore in dumps. The mineralogy of this material was estimated to be 70% chalcopyrite, 20% chalcocite/covellite and the balance oxides. The average grade is 0.45% total copper (Cut).At Los Bronces dump, Leach I plant, the pregnant leach solution (PLS) was collected and stored in an underground reservoir. From there, it was fed to a solvent extraction plant with a series-parallel configuration in two extraction stages and one stripping stage. The electrolyte produced was fed to the electrowinning plant having 30 cells and 60 cathodes per cell. Maximum capacity of this plant was 12,000 tonnes per year (tpy)."

Jan 1, 2016

By M. B. McClenaghan, O. P. Lavin, Ian Nichol

"Exploration in most areas of Canada has to contend with problems posed by glacial overburden. In many areas exploration for gold has been based on the sampling of tills, frequently by deep overburden drilling, and analyses of heavy mineral concentrates. Notwithstanding the significant role that till geochemistry has played in the discovery of some important gold deposits over the last few years, increased appreciation of the nature of the glacial history and stratigraphy and the character of gold within till has led to the recognition of a number of ways whereby the effectiveness of exploration can be improved upon.In order for till geochemistry to be useful in exploration, a number of conditions must be fulfilled, including:1. mineralization, or alteration halo related to mineralization, subcropping at the bedrock/overburden interface;2. glacial erosion and dispersal of a recognizable signature of mineralization into the glacial sediments;3. preservation of glacial sediments containing this geochemical component (trace metal or mineral) at positions subsequently selected for sampling (normally drill sites);4. correct identification of specific till units and associated ice movement history;5. collection of adequately large and representative samples;6. appropriate sample preparation and processing;7. appropriate geochemical analyses; and8. correct data processing and interpretation.While we have no control over the first two geological conditions, and only limited control over till availability, we can control the quality and thoroughness of sampling, sample identification, sample preparation, analysis and interpretation. In particular attention needs to be focussed on obtaining a large enough sample to be adequately representative, an unbiased sample must be collected, together with appropriate sample processing, analysis, data processing and interpretation. It is considered that by modifying or extending existing approaches to gold exploration the chances of exploration success can be increased. In particular, analyses of both the heavy mineral and minus 63 µ m fractions of till is recommended because gold in till may occur in different size fractions."

Jan 1, 1992

By I. Raheb, M. Y. Debili

"A set of Al-Co binary alloys (with respectively in weight percent 10%, 20%, 30%, 40%, 50% and 60% Co) have been studied by X-ray diffraction at the as compacted state. The structural evolution according to cobalt addition shows special features as the apparition of fcc cobalt and hcp cobalt beside aluminium in some cobalt compositions of the Al-Co mixtures using only cold compaction without sintering at high temperature. Figure 1 Cobalt is not a common alloying element in aluminium because its solubility is very low [1]. According to the pressure-temperature phase diagram, Co is known to exist in two allotropic forms: a low-temperature hcp phase and a high-temperature fcc phase [2-3]. At room temperature, Co is stable in the hcp form but it transforms to the fcc form when it is heated to above the transition temperature 695K. Powder aluminium and cobalt (99.999 %) were used in the proportions defined according to the required compositions. The total mass of the samples to be elaborated was between 8 g and 10 g. Cold compaction of mixed powder (Al-Co) under an uniaxial load of 10 MPa has been achieved to obtain a dense product (60%)."

Jan 1, 2015

By Mark Freberg

"IntroductionThis chapter is intended to provide information on the operation and maintenance of several pieces of equipment used in heavy media separation. Most heavy media separation circuits, particularly those involving bath separators can be considered as high maintenance areas. Because of this the efficient operation and maintenance of these circuits is very important if the cost per ton of material treated is to be kept to an acceptable level.Heavy media separation (HMS), is a process used to separate particles of different specific gravities. Under laboratory conditions the ideal way to separate two types of particles which have different specific gravities is to suspend them in a heavy liquid which has a specific gravity between those of the two types of particles. Those particles with the lower specific gravities will float on top of the liquid while the higher specific gravity material will sink to the bottom. Given enough time and a sufficient volume of heavy liquid this process will be essentially insensitive to the sizes of the particles involved.Heavy media separation circuits make use of the same principles described above. The material to be treated is introduced into a mixture of finely ground solids, called media, and water which takes the place of the heavy liquid; the mixture of solids and water is known as medium. The separating force can be either gravity or centrifugal force. The type of solids used as media varies but it is usually a high specific gravity material such as magnetite, galena or ferrosilicon.Heavy media separation is used extensively in the cleaning of coal and to a lesser extent as a preconcentration step in base metal and iron ore operations."

Jan 1, 1989

By J. Álvarez, J. Mesías, C. O. Gómez

"Operations routinely run flotation tests in laboratory mechanical cells to determine adjustments to plant operation based on feed flotation response or the effect of new reagents and dosages. The metallurgical results of these tests are certainly affected by changes in bubble size, which simultaneously impact the recoveries of the collection and froth zones. It is known that bubble size depends on the characteristics and operation of the machine in use, particularly on the gas flow rate delivered to the unit and the selected frother type and dosage. Although flotation rate constants have been related to bubble size, bubble surface area flux seems to be a more fitting variable to correlate flotation kinetics and cell performance, as it integrates bubble size and superficial gas velocity effects. However, although some evidence has been provided, a categorical relationship between cell recovery and bubble surface area flux has not been established. Our interest is to demonstrate this relationship to use it as a basis for developing soft sensors to track on-line collection zone recovery in cells. Flotation tests were designed to produce Cu concentrates for a range of bubble surface area flux values, obtained through changes in frother concentration at a constant gas flow rate, and by increasing gas flow rate at the same frother concentration. The tests were run on samples prepared from an ore batch supplied by a local operation, following strict grinding and flotation procedures, with a shallow froth to approximate cell recovery to that in the collection zone. Bubble sizes were determined using the sampling-for-imaging technique developed at McGill. The results unequivocally showed a consistent positive correlation between cell recovery and bubble surface area flux, and significant variations in performance when frother addition and gas flow rate were changed.INTRODUCTIONMineral flotation is a separation process to produce concentrates of valuable minerals by selective attachment of particles to the surface of bubbles. The process is carried out in machines where air is injected through a mineral pulp to form bubbles, and operated to create two zones: a bottom one (collection zone) where bubbles are continuously generated under conditions adequate to form bubble-particle aggregates by collision of the rising bubbles with suspended particles; and a top one (froth zone) where bubbles and bubble-particle aggregates continue to rise while concentrating and forming a froth layer for water and entrained particles to drain back to the collection zone, before overflowing as a concentrate stream. The phenomena occurring in these zones are complex and, in many cases, interactive, as they simultaneously affect stages of the particle separation sequence occurring in both zones. Although there have been significant advances in instrumentation to characterize particle and bubble populations, these have not resulted in knowledge to explain or models to describe phenomena from fundamental principles. Measurements continue to be limited to the development of empirical models for predicting the effect of operating variables on performance."

Jan 1, 2016

By Fred E. Gray

The mill of Bralorne Mines, Limited, is located on the government highway in the Bridge River mining district of British Columbia, approximately fifty miles northeast of Shalalth, the shipping point on the P.G.E. railway. Prior to 1931, the property now owned by Bralorne Mines, Limited, was operated by Lorne Gold Mines, Limited. During the early operation of the mine, the ore had been treated at various times in one of three small amalgamation mills on the property. With the succession to ownership by the Bralorne Mines, Limited, work was started on construction of a new mill of approximately 100 tons capacity per day. The new mill was put into operation in the month of February, 1932, and since that date has been in continuous operation, milling an average of slightly over 3,000 tons of ore a month. The ore treated in the Bralorne mill is a gold-bearing quartz containing a very small amount of silver. About 75 to 80 per cent of the gold is in the form of free gold, the principal remaining portion being intimately associated with pyrite and arsenopyrite. The gangue rock is quartz, together with varying but relatively small amounts of altered diorite or albitite. In some of the ore, usually the higher grade portions, there is also considerable talc, which forms much slime in grinding. The mill is situated near the portal of the main haulage tunnel and the ore is received directly from the mine ore-trains, which dump on to the grizzly over the coarse-ore bin of the crushing plant. Figure 1 shows the flow-sheet of the mill as it is now being operated. Various changes have been made in the flow-sheet and in the reagents since the commencement of operations, and doubtless minor changes will continue to be made in order to increase the efficiency of the mill. Among the more important changes were those from two-stage to single-stage grinding, and from amalgamation plates to blankets. The change in the crushing was made because too much crushing was done when both primary and secondary mills were employed.

Jan 1, 1933

By F. Doxey

Introduction In order to improve outputs and to reduce or hold mining costs, many attempts have been made to mechanize the getting and loading of coal in the major coal producing countries, and machines of various kinds and sizes have been designed and manufactured. Some of the most important are: Joy Continuous Miner Joy Coal Auger Goodman Mining Machine Lee-Norse Koal-Master Jeffrey Colmol Cardox Hordsecg Recovery Drill German Coal Plough British Coal Plough with agitated blades M. & C. Samson Stripper AB Meco-Moore Cutter Loader Joy Gloucester Getter The three last named are the chief longwall machines in use and the AB Meco-Moore and the Samson Stripper are doing a good job in their respective applications. It is understood that the Gloucester Getter recently installed in a British colliery also shows reasonable promise. It was felt, however, that to meet the conditions of the mines in Nova Scotia, any machine developed must have certain distinctive characteristics. It must: ( 1) Be able to cut and deliver coal in quantity and of the right sizes ( 2) Be easily manoeuvrable ( 3) Be suitable for longwall operations ( 4) Not interfere with timbers already set ( 5) Cut its own stable (6) Work on reasonably heavy gradients

Jan 1, 1951

By John H. McKillop

Industrial minerals production in Newfoundland in--creased in gross value by a total of 175 per cent during the ten-year period from 1954 to 1964. The Province accounts for all of ?Canada's fluorspar production and contains one of the most important fluorspar districts in North America. It is also the only producer of pyrophyllite in Canada, and quite recently has become an important producer of asbestos fibre. Limestone, gypsum, brick shale, sand and gravel also ?Contribute appreciably to the expanding industrial minerals phase of the Province's rapidly growing mining industry. Geological diversity characterizes Newfoundland's industrial minerals: Pyrophyllite deposits were formed by contact metamorphism of predominantly volcanic Proterozoic rocks. Fluorspar deposits are fissure-filling veins having the characteristics of typical epithermal deposits. Chrysotile asbestos production comes from one of the Island's serpentinized ultrabasic belts. Limestone is produced at three localities; two of them in the extensive carbonate rocks of the west coast. Gypsum production comes from a thick evaporite (gypsum and anhydrite) sequence in the Carboniferous rocks of the St. George's Bay area. Introduction

Jan 1, 1965

By I. Ciabatti

Inorganic salts of hexavalent iron (ferrate (VI)) are versatile reagents for water and industrial effluent treatment because of the strong oxidising effect of the ferrate ion (FeO42-) and the well-known coagulation properties of the resulting ferric ion. Among other applications, ferrate can effectively remove arsenic, cyanide and phenols from industrial effluents. Furthermore, ferrate salts can be prepared from ferrous sulphate, a common byproduct of the steel and titanium industries, and possibly from other iron wastes. Notwithstanding their many potential advantages, the industrial-scale application of ferrate salts, such as potassium ferrate (K2FeO4), for effluent treatment has been hindered by the difficulties inherent in their synthesis and stabilisation. Within a project co-funded by the European Commission, the large-scale synthesis of stabilised potassium ferrate was realised through a new synthesis process, and different applications of the resulting ferrate to effluent and wastewater treatment are under investigation. This paper reports the results of the application of stabilised potassium ferrate for the purification of textile effluents. Laboratory and pilot-scale tests were carried out and the performance of the ferrate was compared to that of chemicals currently used in wastewater treatment. According to these experiments, potassium ferrate is a promising reagent for an effective treatment of textile and other industrial effluents.

Jan 1, 2006

By G. K. Herzog

THE problems relating to the construction and use o{ mining equipment are basically the same as those pertaining to equipment in other industries. It is true that much mining equipment is subjected to an unusually severe combination of shock, high stresses, abrasive wear, and corrosive ? conditions, but in other industries, also, equipment must operate under similar adverse conditions, so that their experiences may readily be applied to the problems of the mining industry. Steel and iron are for obvious reasons the most suitable materials for the construction of the greater part of the equipment used in the mining industry. For a large percentage of uses, the ordinary plain carbon-steels and ordinary or unalloyed cast-iron are, and probably will continue to be for a long rime, entirely satisfactory materials. There are, however, many. conditions which cannot be satisfactorily taken care of by these materials, and alloy steels and irons must be used where the greatest possible economy is desired. In general, alloy steels and irons are used where it is necessary or economically desirable to use materials possessing properties superior to plain carbon-steel or ordinary cast-irons, such as: (a) better strength (b) better wear resistance (c) better corrosion resistance (d) better resistance to high temperatures (e) better resistance to low temperatures or combinations of two or more of these advantages. There are also conditions where materials having other special properties are required, such as, for example, certain magnetic or electrical properties for electrical machinery; but in the great majority of cases, one or more of the five advantages listed are the most desired.

Jan 1, 1938

By W. A. Padgham, J. A. Brophy

About 85 % of the 350 tonnes of gold produced by 25 mines in the onhwe t Territories (NWT) since 1935 has come from the Yellowknife-area mines, Con and Giant , which exploit shear zones in Archean mafic volcanic of the Slave Structural Province. Four percent of the total production has been from Archean iron formation-hosted depo its, mainly from Lupin Mine, which today produces more gold than Con and Giant combined and has been primarily responsible for the increase of WT gold output from 5 to 12 tonne per year since 1981. The remaining gold ha been won from the following deposit typesall but the last being in Archean rock : sedimentary-volcanic contact depo its uch a Discovery and Salmita (10 %); turbidite-hosted quartz-vein depo its uch a Camlaren and Ptarmigan (1%); Proterozoic deposits such as Shear Lake and Fox (1#) . All but I% of WT gold has come from the Archean Slave Structural Pro ince, which is also the premiere exploration area for gold deposit types that have yet to be productive in the NWT. These types include stratabound gold in mafic and in felsic volcanic rocks (eg. , at Indin Lake and Courageous Lake, respectively) as well as gold in plutonic rocks (eg. Anialik Gnei Complex). Deposits similar to those in the Slave have al o been found in the Archean Ennadai Belt of the Churchill Structural Province. In the Cordillera. there is potential for placer gold and for gold associated with Cretaceou intrusions.

Jan 1, 1986

By G. O. Crowell

This paper gives the history of the celestite deposit, now being mined by Kaiser Celestite Mining Ltd., near Sydney, Nova Scotia. Mining and milling procedures are covered, and the regional and local geology of the area are described, including the origin of the celestite.

Jan 1, 1971

By P. L. Drake

This paper comprises a discussion of the role which mineral resources will play in Canada's future export trade and the growing demand for minerals in Canada.

Jan 1, 1979

By Nural Kuyucak, Graham A. Johnson

Noranda's Geco Division is presently developing a comprehensive reclamation plan for closure of its Manitouwadge, Ontario operation, expected late in 1995. As part of a program of progressive rehabilation, the existing 20 year old water treatment plant will be upgraded from a low density to a high density lime neutralization process treating AMD and excess site water. The process, developed by the Noranda Technology Centre, utilizes a two step rather than a single step process to bring the Ph to the required neutralization level, a variation which contributes to improved sludge properties such as higher density and decreased viscosity. This is of particular significance where sludge pumping or storage volumes may present a concerns.

Jan 1, 1995

By Z. Xie

Gas diffusion electrodes (GDEs) for high temperature polymer electrolyte fuel cells (PEFCs) have been prepared using ZrP-modified Nafion ionomer. The performances of these GDEs as cathodes and anodes were evaluated and compared with conventional Nafion ionomer GDEs using Nafion 112 as the PEM under elevated temperature and reduced relative humidity. ZrP-modified Nafion ionomer was incorporated into the catalyst layer to enhance water retention and/or increase the protonic conductivity. The fabrication of ZrP-GDEs was implemented by the ion exchange of Nafion solution with zirconyl chloride, followed by the impregnation of GDEs in H3PO4 solution. The composite electrolytes in the catalyst layer possessed a ZrP content of 20% by weight. GDEs were characterized by TGA, SEM, XRD, and CV. Scanning electron microscopy (SEM) indicated evenly distributed elemental Zr and P within the catalyst layer. Cyclic voltammetry shows a reduced electrochemically-active surface area when the ZrP is incorporated into GDEs. Polarization and impedance analyses indicate the cathode with ZrP-modified Nafion ionomer did not show an enhanced or decreased performance, compared with conventional Nafion ionomer GDEs under elevated temperature and decreased humidity. However, when GDEs with ZrP¬Nafion ionomer were used as the anode, an improved performance was observed. Preliminary experiments show that the anode is more sensitive to dehydration than the cathode under elevated temperature and/or low humidity. Improving the anode water retention capability will help to reduce losses at the anode. However, the incorporation of hygroscopic agents in the cathode catalyst layer is not essential because it is self-humidified by electrochemically-produced water even under elevated operating temperature and lower humidity.

Jan 1, 2005

By Martin Irving

Adding Value to Canadian Diamonds - A Changing Diamond Industry - Diamond Mining - Diamond Manufacturing - Diamond Jewellery Markets - NWT Diamonds Changing Diamond Industry - De Beers ? privatization - Oppenheimers (45%), Anglo-American (45%), Botswana (10%) ? going retail - LVMH joint venture - New Players ? jurisdictions - Canada ? companies - BHP-Billiton - Aber Diamonds

May 1, 2002

By M. Mahdi Aboutalebi, Roderick I. L. Guthrie, Mihaiela Isac

"A preliminary computational fluid flow model has been developed to simulate the flow field of liquid steel in the mold region of billet mold casting. This study reports the effect of different Submerged Entry Nozzles (SEN) on the fluid flow in round and square billet, curved mold, casters. In this study, ANSYS Fluent 14.5 software was used to model the 3-D turbulent flow of liquid steel. The standard k-0 model was used to simulate turbulence in the mold region. Similarly, the species transport equations were discretized to simulate the dye injection test into the mold cavity. The behavior of flow in the mold region was validated against previous experimental work. Predicted results showed that different nozzle types plus the slight curvatures in the molds can significantly influence the flow patterns generated within the mold region, and thereby affect the finished quality of the billet products.INTRODUCTIONConventional Continuous Casting (C.C) processes are presently used to solidify more than 95% of the 1.5 billion tons of steel now produced in the world annually (World Steel in Figure, 2014). This overwhelming contribution of C.C processes for steel production is the prime motivation for this study, in order to understand and optimize the casting processes and thereby reduce internal defects and minimize energy consumption. The primary objective of all C.C processes is to maintain liquid metal purity during the casting process and to create a uniform flow within the caster so as to avoid internal and external defects. In this regard, studying fluid flows in the mold region of continuous caster has attracted many research groups, in both academia and industry, in recent years. The mold region is one of the most critical parts of the C.C. process, in which the transport phenomena associated with this region can significantly affect the quality of the final products. Thus, proper control of fluid flows within this region can be expected to greatly decrease both internal and surface defects such as Oscillation Marks (OM), inclusion entrapment, and Mold Powder Entrapment (MPE). In the casting process, the fluid flow in the mold region can be affected by a number of variables, such as; the flow control system (stopper rod or slide gate), nozzle geometry, SEN (Submerged Entry Nozzle) depth, casting speed, mold dimensions, gas injection, and the application of electromagnetic fields. One of the most influential and easily-changed fluid flows are the jets of steel issuing from the SEN. Nozzle geometries are variable, consisting of a number of exit ports, different port angles, and/or port sizes, the bottom shape of the nozzle, and the SEN immersion depth (Thomas, 2001). The SEN characteristics can markedly affect meniscus surface velocities, surface level profiles, and turbulence levels that can vary in terms of the frequency and the magnitude of their fluctuations."

Jan 1, 2016

By R. A. Mantz, V. N. Balbyshev, A. N. Khramov, N. N. Voevodin

Corrosion protection properties of the hybrid organo-silicate coatings on aluminum substrate can be significantly improved by means of encapsulation of organic corrosion inhibitors within the coating material. In order to achieve sustained release of corrosion inhibitor and long-term corrosion protection, a secondary chemical equilibrium of either ion-exchange interaction with the coating matrix or cyclodextrin-assisted molecular encapsulation of the inhibitor has been employed. Several organic corrosion inhibitors, such as mercaptobenzothiazole, mercaptobenzimidazole, mercaptobenzimi¬dazolesulfonate, and thiosalicylic acid have been examined by a group of electrochemical methods including potentiodynamic scan, electrochemical impedance spectroscopy, and scanning vibrating electrode technique. It has been found that the formulations that contain ß-cyclodextrin demonstrate superior corrosion protection capabilities as the complexation equilibrium results in a continuing delivery of inhibitor to corrosion sites. The approach is considered a promising way for active corrosion protection of high-strength aluminum alloys when integrity of barrier coating is compromised.

Jan 1, 2004

By M. Mirnezami, J. A. Finch, M. S. Hashemi A.

This study examined the effects of pH and sulphate concentration on the surface charge and stability of alumina and pyrite dispersions. The relationship between these properties was investigated using measurements of electrophoretic mobility and settling velocity. The maximum aggregation for both minerals was observed near the iso-electric point (iep) where the force of repulsion is at a minimum. Aggregation decreased at pH values away from the iep, where an increased surface charge causes electrostatic repulsion between particles. Zeta potential data revealed that sulphate ions were adsorbed only on positively charged surfaces for both minerals. Adsorption of sulphates on the alumina surface increased aggregation by reducing the surface charge from >+25 mV to close to zero. These results indicate an electrostatic bonding of sulphate ions to alumina surface. Preliminary results on the interaction of pyrite and sulphate ions indicate a similar response.

Jan 1, 2004