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By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By I. Ueda, S. Ishikawa, T. Nagata

“O-SR process” in which the S-Furnace of the Mitsubishi process is followed by existing reverberatory furnaces (RFs) and Peirce Smith (PS) converters has been operated since December 2007. The S-Furnace smelts copper concentrates to produce molten matte containing 58-62%Cu which is then settled in the RFs and converted to blister copper in the PS converters. The SO2 gas generated from the S-Furnace and PS converters is converted to sulfuric acid in the acid plants. In addition to the smelting copper concentrates, the O-SR process has advantages in terms of recycling various waste/secondary materials. Automotive Shredder Residue (ASR) has been treated in the RF to reduce fossil-fuel consumption in RFs, and to recover various metals included in ASR as well, since 1993. Electronic circuit boards (E-scrap) has also been processed in order to recover not only copper but also rare resources such as gold, silver and PGMs since 2013. Strategic modifications have enabled expansion of the processing volume of E-scrap. Enhancing recycling of wastes and scraps from urban mines while reducing the consumption of natural resources in the “O-SR” process will be demonstrated and discussed in the present paper. INTRODUCTION Onahama smelter and refinery has been operating as a custom smelter since 1965. Smelting facilities were subsequently expanded to two green-charged RF furnaces and five PS converters in 1973. Since RF is a conventional old-fashioned smelting furnace that necessarily consumes a huge amount of fuel to smelt copper concentrates, saving fuel cost has been an important objective. In early 1980’s the fuel was changed from bunker oil to pulverized coal, while utilizing the combustion heat of waste tires. Furthermore, treatment of combustible waste such as shredder residue (SR) was initiated in order to save fossil fuel for smelting concentrates in the RFs. Since enhancing of the treatment of SR requires a reduction in concentrate smelted in the RFs, most concentrates were dried and injected through tuyeres into the PS.converters. These modifications enabled to reduce the amount of the pulverized coal combustion and to increase SR treatment in the RFs. SR treatment capacity has increased to 12,000mt/month because the SR market has grown after the enforcement of the Vehicles Recycling Law. Such business environment has been attributed to establish the thermal-materials recycling system of SR in which the RFs have changed their role from copper concentrates smelting furnaces to waste materials combustion furnaces.

Jan 1, 2019

By John L. Rich

A New Field for the Mining Industry A new field for the mining industry is in prospect. This is the recovery of the petroleum which has been left in the ground in the older oil fields whose yield has declined until they are no longer profitable to operate in the ordinary way. The fact that an oil field has reached the economic limit for operation by pumping does not necessarily 'mean that the oil has ? been exhausted. In many such cases not over one-fifth, or even one-tenth, of the total oil content of the field may have been taken out when this stage has been reached. This means that there exists a large reserve of oil which can be recovered by whatever process best takes advantage of the natural conditions under which the oil occurs. Mine drainage is one of the processes by which this oil may be recovered. Its relative importance will depend partly on the ingenuity and wide-awakeness of mining engineers, and on mining capital. The opportunity is undoubtedly at hand. In order that we may be in a position to judge the possible advantages of mining methods for the recovery of this oil, I have reviewed, on the following pages, the methods now in use, and have discussed the physical conditions of the reservoir rocks in which the oil is found, and the suitability of the various recovery processes, in use or proposed, in the light of these reservoir conditions.

Jan 1, 1927

By Brian McIntrye, Bo Trygg

"The need for grinding mills of ever increasing capacity and greater feed openings has tended toward mill trunnion diameters being beyond the size limits for roller bearings.Hydrodynamic plain bearings need to be wide enough to achieve the necessary bearing pressure in order to obtain an oil film with sufficient carrying capacity at low rotational speeds. This greater width increases edge loading resulting from the deflection of the mill under load.Because of the high surf ace pressure involved, the life of support rollers and girth rings is often inadequate-fatigue leads to flaking on the contact surfaces. Heat treatment of the girth rings also has its problems.The hydrostatic shoe bearing permits unlimited trunnion diameter and a high carrying capacity. The self-aligning shoes compensate automatically for radial deviations and large deformations can be tolerated at the girth ring.The sliding surfaces are completely separated by oil under pressure, enabling negligible starting torque and good damping capacity to be achieved together with low rotational speeds.IntroductionHydrostatic bearings have been known within machine technology since 1865, when the Frenchman Girard received a patent for such a bearing. During the following 75 years, these types of bearings were used sporadically for thrust bearings, primarily in water turbines. The first usable radial bearing was not designed until 1938. Since the 1950s, when hydrostatic bearings started to come into use within the field of machine tools, extensive research and development work has been carried out at various institutions and research centres throughout the world. Many support problems are now solved by means of hydrostatic plain bearings and the primary factor in deciding to use them is their unique characteristics:• ability to carry high loadings• no starting torque• large damping capacity• no wear• large running accuracyThe hydrostatic shoe bearing has been developed specially for use in the heavy machine industry, with the requirements for high loadings and large support diameters which this market demands."

Jan 1, 1982

By D. Chakravarty, B. Samanta, D. Ghosh

Autonomous robots are useful for 3D underground mine mapping to avoid human exposure to hazardous spaces. To prepare a precise mine map, a self-navigating robot must navigate an arduous path, avoiding obstacles and sensing the environment. A prototype laboratory-scale robot was built and evaluated through a mock-up in a test mine gallery. It was outfitted with a 2D laser scanner, a stereo camera for obstacle avoidance, and a high-precision, laser-based imaging and digitizing system for collecting 3D point cloud data. Various algorithms were used for scan matching to facilitate simultaneous localization of the robot for mapping.

Jan 1, 2014

By M. Tadie, J. Wiese, K. Corin

The use of potential control in the flotation of ores has been applied in a variety of operations and presents an opportunity for improvement of selectivity and recovery of valuable minerals. Although it is possible to vary the redox potential (Eh) using chemical additives such as sodium hypochlorite or hydrogen peroxide this is more commonly done by varying the pH and dissolved oxygen (DO) concentration. The present study involves an investigation into the effect of varying dissolved oxygen concentration, ionic strength (IS) and pH on the flotation response with the aim of application to a South African lead-zinc ore. In all cases the Eh is measured as a function of the different DO, IS and pH values. The main objective was to achieve selective flotation of galena from sphalerite. The first part of the work was micro-flotation tests conducted on single minerals with galena used as the basis for effect of the factors studied on redox potential and ultimately recovery. The DO was varied by alternating between the use of air and nitrogen as the gas source to the micro-flotation cell. PH was varied between pH 9.2 and pH 11.8 using sodium hydroxide. In the first part of this study a factorial design approach was used to determine the interactive effects of the variables tested, viz. DO, ionic strength and pH, on the Eh and on the recovery. Redox potential was measured using a combination electrode made up of platinum wire and Ag/AgCl reference combination. Recoveries indicated that pH had the most significant effect on recovery and Eh. The influence of redox potential on recovery was found to be of relevance to the condition of high dissolved oxygen concentration and less so at low dissolved oxygen concentrations. It was also noted that that the combined interaction between ionic strength and dissolved oxygen concentration had a positive effect on recoveries, however this was not so with Eh. The chemistry of the ions in solution was observed to play a dominant role on the recovery due to changes in solubility arising to pH modification. The longer term objective of this work is to determine the optimal Eh conditions for the separation of galena from sphalerite.

Jan 1, 2016

By D. F. Hambley

"In designing are passes f or underground mines specific consideration should be given to unimpaired flow of broken rock, the dump point, and typical practices f or overcoming operational difficulties. Design features such as branches, bends, and knuckles should also be considered. This paper pro vides engineering information and various criteria for designing are passes, draw points. feeders, and support systems, together with several illustrative examples.IntroductionOre passes are the primary mean s o f vertical transfer of mined ore to the ore bins and loading pocket from which the o re is hoisted to the surface (Fig. 1) . While the words "" ore"" and ""ore pass"" are used here, such transfer systems ca n be used for any broken rock.The most extensive ore pass systems are found in caving and sublevel stoping mines. Extensive ore pass systems are also found in multilevel mines having steeply dipping orebodies. In more flat-lying orebodies , ore pass systems are sometimes used in conjunction with conveyor systems .Two decades have passed since the principles of the flow of bulk solids were formulated (Jenike, 1961, 1964; Johanson and Colijn, 1964; Kvapil , 1965). However, few published papers are available that discuss the design criteria for ore pass systems. Therefore, the aim of this paper is to provide the information necessary for good o re pass design .Rock Flow in Ore Pass SystemsIf an ore pass system is to fulfill its function, the transfer o f material must occur in an orderly fashion and in such a way that the full size of the opening is employed effectively. Apart from un controlled flow at the drawpoint, or outlet , whose design will be considered later in this paper, two occurrences may impede flow in an ore pass, namely:• Hangups due to interlocking arches.• Hangups due to cohesive arches.Prevention of each of these problems will be discussed in succeeding sections of this paper. A third problem piping, is related to the ratio of the drawpoint size to the o re pass size and will be discussed under drawpoint de sign."

Jan 1, 1987

By Jeonghwan Kim

Intelligent Excavation System (IES) has been considered to be one of the desirable solutions to improve the productivity, quality and safety of the current earthwork processes. IES is composed of various hardware and software modules including task planner (work command generator), local and global work environment sensors, GPS and other sensors to acquire the excavator?s status, robotic controller and electronic valves, and the manipulator (excavator). A data communication manager was required to coordinate the signal or data-flow in between these modules considering the operational status of IES such as; excavation start/completion, truck detection, terrain model update, emergency stop, local sensing, GPS/motion sensor data handling, and so on. This paper presents the role and functions of this data communication manager. After every possible operational status of IES operation was identified, a protocol of each communication process in the form of string-type was made. The components of IES are connected with either wired or wireless network. Therefore, they can communicate with the manager using socket (TCP/IP) communication. The data communication manager is also capable of accessing a web-based project management information system, which constantly updates the performance of excavation robot to online database.

Aug 1, 2013

By Gulshan Kumar Pradhan, Yogendra Pratap Singh, Dhawanm Nikhil

"Potassium (K) is one of the essential elements for the growth of plants and thereby for humans. In fertilizers, potash demand has been steadily increasing at ~3.5% annually. Water soluble potash deposits are rare and highly localized. India is neither present on the world potash production map nor it has adequate potash rich rocks. The K-bearing minerals are recovered either by using conventional underground mining methods or though solution mining methods. India possesses a vast resource of silicate rocks such as glauconitic sandstone and Feldspar. These rocks are basically a group of alumino silicate of potassium, sodium and calcium (K2O%: 5-12, Na2O%: 3-10%, SiO2%: 52-65, Al2O3%: 15-20, Fe2O3%:, 5-7 and MgO%: 2-3.5).The K extraction from silicate rocks has received little attention probably due to the slow release, the locked structure of alumina-silicate minerals, and the unavailability of appropriate economic processes & their know-how. In fact due to this India imports all of its potash demand (about 3.5 million tons per annum) from different countries.In the present work, an attempt has been made to identify the structural and chemical alteration of desired K mineral phase in silicate rock (~K2O%: 10.5, Na2O%: 2%, SiO2%: 55, Al2O3%: 19, Fe2O3%, 5-6, MgO%: 2.5) under different conditions such as acid leaching, thermal treatment and chemical processing. Different treatments are aimed to increase K availability which is related to the modifications in mineralogical composition. The modifications in the feed sample and treated samples are studied through SEM-EDAX, XRD, EPMA and optical microscope. With the combination of treatments, it is possible to extract more than 90% K and the formation of sylvite phase (water soluble) confirms the dissolution of potash values."

Jan 1, 2016

By P. J. Adams

Environmental regulations require means for controlling emissions of SO2 NOx and particulate when burning coal. The combustion of coal in limestone fluidized beds is one of the most promising techniques for the necessary reduction in emissions. Fluidized-bed firing, furthermore, offers potential economies in capital equipment. The world's largest steam generator applying fluidized-bed techniques was built under the sponsorship of ERDA and installed in Rivesville, West Virginia. This paper describes the design and discusses the start-up and development difficulties which were experienced during the period from initial operation to current readiness for commercial operation. Other developments leading to utility and industrial fluidized-bed steam generating equipment are reviewed. The future potential of this promising technique is discussed.

Jan 1, 1979

By Donald S. Cameron

By dispersing gold in high surface area form supported on metal oxides, its inert character can be transformed to make economical, effective catalysts. Gold has already been demonstrated in a number of fuel cell applications such as gas phase catalysts, electro-catalysts, and electrical connectors. In this paper, the various types of fuel cell systems are reviewed, and several opportunities for gold identified. Low temperature fuel cells, including alkaline and solid polymer electrolyte types rely on high surface area platinum group metal catalysts which are highly susceptible to poisoning by low concentrations of carbon monoxide in the fuel supply. Hydrogen is frequently obtained by steam reforming hydrocarbons, followed by the water gas shift (WGS) reaction. A promising initial use for supported gold catalysts is in catalysing this WGS reaction. Research has shown that gold supported on iron oxide (Au/a-Fe2O3 ) WGS catalysts are more active than the current commercial copper oxide / zinc oxide catalysts, and effective at temperatures as low as 120oC. Products from reformer/ water gas shift reactors can be further purified by removing traces of carbon monoxide. If a small proportion of oxygen is introduced into the fuel gas stream, carbon monoxide can be preferentially oxidized to carbon dioxide even in the presence of hydrogen. Gold nanoparticle catalysts on iron oxide support (Au/a-Fe2O3 ) have exhibited higher activity than commercially available platinum on alumina (Pt/?- Al2O3 ) preferential oxidation catalysts. The low temperature of this reaction may make it feasible to incorporate these catalysts within the fuel cell itself. Proton exchange fuel cells provide several possible applications for catalytically active gold and its alloys. Carbon supported platinum group metals would benefit greatly from improved electrical conductivity if gold replaced some or all of the carbon support material. As electrode current densities are raised, electrical resistance constitutes an increasing proportion of voltage losses within the fuel cell. Dramatic reductions in cell stack voltage losses have already been demonstrated by reducing inter-cell contact resistance using gold plating. The low temperature oxidation properties of gold catalysts have been investigated in controlling gaseous emissions from direct methanol fuel cells, and gold also provides essential catalysis in building direct borohydride oxidation fuel cells. The prospect of a range of other applications for gold in fuel cells to contribute useful improvements in corrosion resistance and conductivity is assessed. Globally, fuel cells have been developed for a wide range of applications including stationary generators, cars and buses, industrial vehicles and small portable power supplies, each of which represents a substantial market. Hence there are likely to be many and varied opportunities for gold catalysts to contribute to the performance and economics of the systems being commercialized.

Oct 1, 2003

By Christopher W. N. Anderson

Induced hyperaccumulation of gold by plants was first reported in 1998 by researchers from Massey University in New Zealand who proposed the idea of mining gold using plants (phytomining). Since that time research has been conducted to understand the conditions under which plants can be made to take up economic amounts of the metal. One key focus has been on the geochemistry of gold-rich soils, leading to a diagnostic test that can predict how suitable a particular soil might be to gold phytomining. Field trials have been conducted at several locations around the world in collaboration with industry partners. A Decision Support System has been developed to assist in the design and management of phytomining operations, and economic modeling has been carried out to set targets levels for phytomining technology. Novel studies are now examining the form of gold in plants. Research suggests that plants may store gold as discrete metallic nanoparticles in leaf and stem tissues, an observation that may lead to new ways to recover the metal from harvested biomass.

Oct 1, 2003

By Charlie Jefferson

Main Goal: Resource Assessment 1. Incorporate existing data & results, old process. 2. NEW Quantitative Analysis (Chung and Chen) 3. Try mass balance of U and geochemical tracers 4. Use holistic process approach ?with key foci ?Targeted basin / belt assessments ?Is there as much in the Athabascaas they say? ?Athabasca reference for other basins (Thelon, etc) ?Compare sandstone & volcanic with USA, Kazakhstan etc: do their models apply here? ?Which IOCG systems are prospective for uranium? 5.Consider Groundwater, Environment; 6.Communicate

May 1, 2006

By B. Coupal, F. D'Hennezel

Sorption measurements show that peat moss has much stronger affinity for oil than straw, which is currently used. Microscopic studies of peat moss show a highly porous and fibrous material, and this property, associated with the phenomenon of selective absorption, had been used to absorb oil. Laboratory experiments show that peat moss absorbs up to eight times its weight of oil. Field tests have proved that peat moss can be an effective absorbent and can be used on a large scale.

Jan 1, 1972

By O. Bernal

The Sociedad Minera Cerro Verde S.A.A, a subsidiary of Phelps Dodge Mining Company, operates a copper mining facility located in southern Peru. This "mine-forleach" operation currently produces 90,000 mtpy of copper cathode from secondary sulfide ore utilizing crushing, leaching, solvent extraction and electrowinning processes. The leach solution handling and application rates have undergone constant development over the years. This paper discusses the improvements in leach application designed to: 1) satisfy the needs of the "lixiviant request rate", which requires the use of application rates as low as 3.5 L/h/m2 and as high as 15 Llhlm2 with variable rest periods according to the leach kinetics, and 2) alleviate the poor solution distribution on the surface of the leach heaps inherent to drip emitters. Low application rates result in poor surface solution distribution and the formation of upside down cones of dry, non-leached material in the top meter of stacked ore, with heavy jarosite and iron salt precipitation; moreover, ferric iron is lost as insoluble precipitates. On the other hand, high unit flows associated with poor agglomerate quality can lead to uneven solution flow patterns within the heap leading to solution short-circuits, fines migration, and ponding with adverse effects on acid consumption and recovery.

Jan 1, 2007

By D. Cruden

DISCODAT is a system of computer programs written for CANMET, Canadian Department of Energy, Mines and resources, to be used in analyzing geological data for rock slope design. The programs were written in Fortran IV for an IBM 360/67 computer. A program conditions field data from field forms for storage in a line file. Data may be selectively retrieved from the line file by a general retrieval program which uses a variety of relational operators. The retrieved data may be displayed as structural diagrams or histograms produced on a line printer or in a number of maps produced on a drum plotter. There is a logical sequence which leads to the characterization of those elements of the subfabrics of a rock mass which may be kinematically active. Structural domains within the rock mass can also be outlined by a procedure described as areal analysis. Costs for a complete analysis are usually substantially less than $l/discontinuity.

Jan 1, 1978

By B. Huffman

This paper examines several new trends in the design and application of linings for copper melting shaft furnaces including the use of large shapes, monolithic back-up linings and improved refractory engineering to significantly reduce refractory installation time, diamond saw blade costs, fuel and down-time. The net results are shown to be dramatically increased refractory service life, reusable safety linings, elimination of hot spots and lower refractory disposal costs.

Jan 1, 2007

By F. Charette

The paper reviews the requirements of the instrumentation required to monitor mining excavations in a high stress environment, and the development plan to instrument the D-Bolt in such a fashion as to be able to follow the behaviour of the bolts in relationship to the ground movements and support performance. Recent field observations of D-Bolts under static and dynamic conditions are also presented. Also discussed is the assumed mechanical behaviour of the D-Bolt. D-Bolts are used in two (2) Canadian underground mines operating in high stress environments and tested in three (3) other operations.

Jun 1, 2012

By W. R. Tyson

Imperfections such as lack-of-fusion and undercut are inevitable in field welding of pipelines. Above a certain size, such defects must be removed or repaired. In the present state of the art, determination of allowable defect size is done by Engineering Critical Assessment (ECA). This requires measurement of toughness, and comparison of toughness with crack driving force. ECA methods used in current international pipeline standards will be reviewed and compared.

Jan 1, 2010

By J. Groppo, W. Zhang, R. Honaker

"The flotation of monazite is depressed when using hydroxamic acid as a collector in the presence of calcium ions which may exist due to the dissolution of minerals such as calcite. Minor dosages of sodium hexametaphosphate (SHMP) were found to effectively depress calcite, whereas the flotation of monazite was not impaired in single mineral flotation tests. However, in a mixed mineral flotation system, monazite flotation was depressed significantly. The mechanism of hydroxamate adsorption on monazite and calcite, the depression mechanism of calcite on monazite, as well as the depression mechanism of SHMP on calcite and monazite were studied using micro-flotation, electro-kinetic, and adsorption tests. Findings indicate that the adsorption of hydroxamate on monazite was due to chemisorption while adsorption on calcite was a result of physical interaction. SHMP significantly increased the negative charges of calcite surfaces which depressed the adsorption of the hydroxamate anions on the calcite surfaces due to an elevated electrostatic repulsion force. When calcium-rich minerals such as calcite are mixed with monazite, the calcium ions dissolved from the mineral surfaces specifically adsorb onto the phosphate oxygen sites on the monazite mineral surfaces thereby causing depressing effects. The addition of SHMP to suppress collector adsorption on the calcite surfaces interacts with the calcium species that were specifically adsorbed onto the monazite surface, which prevents hydroxamic acid adsorption onto the rare earth oxygen sites due steric hindrance and results in the flotation depression of monazite. INTRODUCTIONAs one of the commercial rare earth ores, monazite has been widely exploited to produce additives for catalysts, batteries, alloys, etc. Because of the complexity and the fine nature of some monazite ores, methods such as gravity, magnetic, and electrostatic separation to treat beach sand monazite fail to produce satisfactory concentrates, suggesting the use of floatation is warranted (Cheng, Holtham, & Tran, 1993). The primary associated minerals of monazite ores include ilmenite, quartz, zircon, rutile, sillimanite (Dixit & Biswas, 1969; Pavez a& Peres, 1994, 1993). Using sodium oleate as collector for monazite has been reported in many studies (Cheng et al., 1993; Dixit & Biswas, 1969; Pavez & Peres, 1994, 1993). Several investigations have reported maximum floatability of monazite occurring at pH values between 8 and 9 (Cheng et al., 1993; Dixit & Biswas, 1969). A study conducted by Pavez and Peres (1994) compared the use of hydroxamate and sodium oleate for the treatment of a monazite ore and found that hydroxamate significantly improved the grade of rougher concentrate."

Jan 1, 2016