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By E O. Foster

When roasting started at Giant Yellowknife Mines in 1949, it became apparent that, to prevent air and water pollution in the surrounding district, it would be necessary to collect the arsenic that was contained in the exit gases of the roaster. The arsenic collection problem was finally solved by the installation of both electrostatic and baghouse collectors. It was realized that a considerable quantity of gold-bearing dust was leaving the roaster with the exit gases. When the collection problem was solved, it was possible to measure this loss. The loss proved to be considerable and it became evident that a substantial quantity of gold could be recovered. Research programs on dust treatment began in 1958, and by May, 1960, the treatment process which is currently being followed was started in the plant. At present, the two electrostatic preci11itators, Operated at temperatures above 600°F, collect the gold-bearing dust.

Jan 1, 1963

"Shales play a major role in the stability of slopes, both natural and engineered. This paper attempts to provide a review of the state-of-the-art in shale slope stability. The complexities of shale terminology and classification are first reviewed followed by a brief discussion of the important physical and mechanical properties of relevance to shale slope stability. The varied mechanisms of shale slope stability are outlined and their importance highlighted by reference to international shale slope failures. Stability analysis and modelling of anisotropic rock slope masses are briefly discussed and the potential role of brittle rock fracture and damage highlighted. A short review of shale slopes in open pits is presented.INTRODUCTIONShales have been stated to form approximately 58% of sedimentary rock so it is not surprising that they are frequently encountered in both natural and engineered slopes. They represent challenging environments for slope stability due to the wide variation in their engineering properties, their changing behaviour with time due to geomorphic processes and the variation in the failure mechanisms as a function of both stratigraphy and tectonics. An extensive body of literature exists on the terminology and classification relevant to shales; it is not possible in the scope and length of the current paper to review these works in detail and the reader is referred to Farrokhrouz and Asef (2013), Bell (2000) and Goodman (1993) for detailed discussions. It is arguably the case that no universally accepted classification of shales exists today and depending on the field of application the terminology varies widely. Shales in slope stability, for the purpose of this keynote paper, are taken to include material varying in properties from weak rocks to soils and therein lies one of the most challenging aspects in shale slope characterisation for engineering purposes. They have been classified as “rock-like” or “soil-like’, (Underwood 1967) or compacted and cemented, Table 1, Yagiz (2001). Classifications have considered numerous factors including composition, cementation and a wide range of engineering properties.The propensity of shales to degrade with time due to geomorphic processes has resulted in an important aspect in their classification, that is, the attempts to incorporate slaking, durability and swelling and softening behavior through purpose developed testing methods (Gamble 1971, Morgenstern and Eigenbrod, 1974). Figures 1 and 2 show examples of terminology used to describe argillaceous materials and some proposed engineering classification schemes (Grainger 1984 and Bott 1986). Corominas (2014) provides a recent classification of argillaceous rocks and their durability relating five stages of slope deterioration to the texture of the rock on Ternary diagrams. No attempt will be made here to discuss the merits of the proposed terminology and classifications, suffice it to say, that the controversy and flux surrounding these issues is a strong indicator of the complexities in the behavior of these materials. In this paper the author will consider slope stability in the materials indicated in Table 1, Figures 1 and 2 without undue focus on terminology. At the lower strength limit of shales the engineer must design slopes using the principles of soil mechanics which may vary from the simple Mohr Coulomb plasticity constitutive criterion to modified critical state models, some even attempting to incorporate softening behaviour in the weaker clay shale materials. Given the transitional nature of shale materials several workers have treated overconsolidated clays and clay shales using concepts such as peak and residual shear strength, brittleness index and softening. Martin and Stacey (2013) provide a useful review of the importance of weak rocks in open pit mining, with mudrocks as a specific member, and note the importance of delayed failure, progressive failure and loosening in the stability of"

Jan 1, 2015

By Gordon R. Harris, Raymond Chalk

Descriptions of typical pulp and paper manufacturing processes are presented, with particular emphasis on the use of minerals and derived products. Some consideration is given to the future demand for these minerals by the pulp and paper industry. Possible influences of techno-logical change and social legislation are suggested and their effect on saltcake demand by the pulp industry is discussed. Predictions are made regarding trends for new and existing paper products.

Jan 1, 1968

By Gae On Kim, Ki Baik Kim, Suk Hoon Kang, Tae Kyu Kim, Sanghoon Noh

"Advanced radiation resistant oxide dispersion strengthened steel (ARROS) is being developed as a fuel cladding tube material for future nuclear reactor system applications. The research activities consist of advanced radiation resistant ODS steel development and fabrication technology development of ODS steel structural components. One candidate material with a chemical composition of (in wt%) Fe-10Cr-1Mo-0.5Mn-0.1V-0.25Ti-0.35Y2O3and was selected as representative materials, and this material was named as the advanced radiation resistant ODS steel (ARROSTM).On the basis of this ODS steel composition, an optimized fabrication process of structural components such as plates, sheets and tubes has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. These R&D activities are expected to contribute to the realization of ODS materials in the future.INTRODUCTIONA sodium-cooled fast reactor (SFR) is being developed at the Korea Atomic Energy Research Institute (KAERI) with a view to economics, safety, reliability, and sustainability. The prototype Gen-IV SFR with a capacity of 150 MWe is under design, and this prototype reactor is scheduled to operate from 2028. For a commercial SFR system application, it is necessary to develop an advanced structural material having both high creep strength and irradiation resistance at high temperatures (Jeong, 2014). Oxide dispersion strengthened (ODS)steel is one of the most promising structural materials because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperatures under a neutron irradiation environment for a prolonged operating period(Kim, 2016). As the first step, several batches of ODS steel were designed and the candidate samples with a 2 kg scale each were fabricated by mechanical alloying, hot isostatic pressing and hot rolling processes. The mechanical properties of these samples were evaluated. Up to now, two candidate materials with chemical compositions of (in wt%) Fe-10Cr-1Mo-0.5Mn-0.1V-0.25Ti-0.35Y2O3 was selected as representative materials, and these materials were named as the advanced radiation resistant ODS steel (ARROSTM).The next step was to optimize the fabrication process of the ARROS compositions for in-core structural components such as the fuel cladding tubes of a SFR. An optimized fabrication process of fuel cladding tube with a composition of ARROS has been established through various process conditions in mechanical alloying, hot consolidation, hot/cold working and heat treatment processes. Joining technologies of the ODS steel tubes is being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. It is expected that the development of ARROS will contribute to the realization of a commercial SFR with high economics and sufficient safety in the future. In this paper, the study of fabrication process of ARROS structural components is introduced."

Jan 1, 2017

By C. R. Whittemore

PROGRESSIVE industrial organizations have recognized the importance of maintaining an adequate reference library of volumes covering all phases of their particular branch of industry, but it has been the experience of the writer that few engineers know how to use to the best advantage this store of extremely -valuable information which has been accumulated for their service. Nor does the average engineer appreciate the fact that it is only through the current technical literature that he can keep abreast of the rapidly developing fields of engineering. The present-day ramifications of the engineering field are of such wide scope that the human mind is not capable of storing away more than a small fraction of the information available on any particular topie; yet, from time ? to time, such information would prove invaluable. An engineer can know intimately only a small part of his own branch of engineering; but he cannot afford to neglect to take the fullest possible advantage of all that is already known in his own particular field. Technical information may be obtained by one or more of the following methods: (1) by enquiring of the individual who knows; (2) by performing the experimental investigations necessary to ascertain the facts; (3) by consulting the technical literature, where a record may be found of the work of others. This last method is the one we wish to examine. Our main consideration is the question of how to use the library, but first it is necessary to give some attention to the kind of enquiries one takes to the library, and to the nature of the sources of information available.

Jan 1, 1938

By W. G. Hubler

It has been within only the last two or three years that enough progress has been made in preferential flotation to warrant metallurgists in recommending the installation of commercial-sized plants for the treatment of copper-zinc-iron ores. Until the new processes had been worked out successfully, the treatment of this type of ore had proved a stumbling block in the path of metallurgical progress. Separation of lead-zinc ore is comparatively simple. A lead-zinc ore low in iron may be separated and concentrated by gravity con-centration, provided it is not necessary to grind too fine. Owing to the specific gravity of chalcopyrite and sphalerite being so nearly the same, however, their separation by gravity concentration is out of the question. Complex lead-zinc-iron ores in which the several minerals are intimately associated, requiring fine grinding to free them, have been successfully treated by flotation for the past fifteen years. Galena is easily floated, and its flotation, unlike that of chal¬copyrite, is not affected by the reagents used to inhibit the flotation of sphalerite and iron sulphides. When an attempt was made to use the methods of lead-zinc se-paration on copper-zinc ores, it was found that the depressant re-agents added to inhibit the flotation of the iron and zinc minerals would, under certain conditions, depress a large part of the copper. It was also recognized that, in the grinding of copper-zinc ore, soluble salts were generated which were detrimental to flotation unless properly controlled. The main part of this paper will be a discussion of solutions in the grinding circuit in relation to the pro¬duction of soluble salts and their effect on flotation.

Jan 1, 1931

By F. E. Senftle

Introduction The usual laboratory methods of uranium analysis are either tedious, time-consuming chemical procedures or elaborate physical methods requiring sensitive equipment. There is thus an urgent need for a method of estimating the uranium content of ore samples by approximate analysis in the field. When a new property is being developed, it is desirable to know, with the least possible delay, the uranium content of channel samples in order to guide the diamond drilling and digging operations. Prospectors, too, require approximate analyses of their hand specimens to evaluate their discoveries. To satisfy the demand for these types of analyses, several field procedures have been tried. Two general plans can be followed. One is fast but will yield only a rough estimate. The other is slightly longer but, if done carefully, will give an assay probably within 10 per cent of the true value. For field operation it is necessary to strip the more accurate laboratory methods of analysis of all refinements because of the limited equipment and skilled techniques at hand. Most of the corrections normally applied, with the exception of that for equilibrium, will not alter the gross analysis to any appreciable extent. When uranium atoms in pitchblende disintegrate, they break down into other radioactive elements, and eventually the number of elements being formed is equal to the number breaking down. The ore is then said to be in equilibrium. Certain geological processes, however, such as leaching, may selectively remove some of these elements and hence reduce the radioactivity of the ore sample. The ore is then said to be out of equilibrium. The field analysis may then be in error by as much as 50 per cent since the apparatus is calibrated with standards that are in equilibrium. However, such a large error due to loss of equilibrium is the exception, and in most cases uncorrected field types of analyr.is are justified.

Jan 1, 1949

By T. S. Smith

INTRODUCTION IN PREPARING this paper for the District 4 Meeting, three factors had to be considered. First, the paper must fit the time alloted; second, it must give a general picture of the geology for those unfamiliar with the property; and third, it must contain some new material in order to be of interest to local delegates. The most comprehensive extant discussion of the geology of the property of McKenzie Red Lake Gold Mines, Limited, is contained in Horwood's report on the general Red Lake area ( 1). This report is the 'bible' of the area, and a general paper on the geology of this particular mine would almost certainly appear to be a condensation of it. It was thought, therefore, that the most suitable procedure would be to base the general outline on Horwood' s report, to extend that outline where possible from information gained since its publication, and finally to leave dangling for the contemplative geologist some of the ideas and problems which ?are currently under consideration. LOCATION AND HISTORY The property of McKenzie Red Lake Gold Mines, Limited, is in Dome township, in the Red Lake mining division of northwestern Ontario. The mine is on McKenzie Island, about four miles north, by water, of the Hasaga mine and old Howey mine.

Jan 1, 1951

By A. I. Collins, D. Danninger

Newmont has installed advanced control and online optimization on the dry grinding circuit and both roasters on its Carlin Trend refractory ore treatment plant. Subsequently, Newmont has developed a master plan for institutionalizing advanced control and optimization on all its processing units. Newmont is committed to a program of applying advanced control and optimization from crushing of ore to pouring of gold. This paper describes Newmont's experience with implementing advanced control and optimization and the benefits received. In addition, identification of advanced control and optimization opportunities and their economic justification is discussed.

Jan 1, 2005

By J. G. Cullain

Inco Limited is an integrated mining, smelting, refining and manufacturing company with operations located worldwide. The Ontario Division operations consist of 13 mines and 10 processing facilities located in Sudbury, Port Colborne and Shebandowan. The scope of our utilization of energy in the Ontario Division in 1976 included in excess of 2.2 billion kilowatt hours of electric power, 12 billion cubic feet of natural gas, 60 million Imperial gallons of residual oil and smaller quantities of other fuels. In addition to the primary energy consumption, waste-heat energy is recovered in various operations throughout the Division, thereby reducing our primary energy requirements. Total expenditures for primary energy alone in 1976 exceeded 60 million dollars. Energy management studies were initiated by Inco's Utilities Department in late 1972, and resulted initially in a program of electric power cost reduction. This program produced significant results by improving the use of the water available for our hydraulic generation facilities and by a comprehensive peak reduction program. Our experience showed that a program of peak power control creates an awareness of both peak and energy costs, and thereby encourages a general reduction in the electric energy consumption as well as lowering the peak demand. Energy management is a continuing program at Inco and, recently, a formal energy management policy and program was instituted. Energy management committees were formed in each plant or mine area to identify the major areas for energy; consumption, thereby isolating areas with large potential energy losses, and determining immediate action which will improve the energy efficiency or reduce the energy waste within their respective areas. A decentralized program with good cross-communication between all committees was felt to be the best method of providing an on-going effective energy management program. In the future, the projections of dwindling fossil-fuel supplies in Canada and the resultant spiralling energy costs will further emphasize the need of sound energy management practices for all Canadian industry.

Jan 1, 1977

By Andrew D. Lapworth

The use of geological and grade models has been standard practice in mine design for many years now, with a wide range of software available to create and analyze the models. Although geotechnical parameters are also of vital importance for mine planning, there has been very little in the way of commercially available systems for integrating geotechnical data into the mine planning and design process. Sirovision is a new technology based on digital photography for automated, safe and accurate 3D mapping of geological and geotechnical features in rock faces. Datamine has integrated this capability into its product range so that Sirovision becomes an integral part of day-to-day face mapping, mine geology and geological / geotechnical modeling in both open pit and underground mines. This results in improved fragmentation for loading, hauling and processing, and for open pits local geotechnical conditions can be taken into account to improve slope design and control. This paper describes some of the ways that geotechnical modeling can be used to create more refined and cost effective mine designs and then discusses the role of Sirovision in enabling the raw data required for such modeling to be collected quickly, safely and reliably.

May 1, 2007

By F. A. Auld

"Traditionally deep shaft sinking from the ground surface was carried out using drill and blast methods. Although large diameter blind shaft drilling has been carried out successfully on numerous occasions previously, including as early as 1852 in Germany (Auld, 1995), little attempt has been made until more recently to mechanise the shaft sinking excavation process using down-the-hole machines. This paper reviews the development of deep shaft sinking machines from the early 1970’s up to the present day. INTRODUCTION Mechanical excavation methods can significantly improve excavation performance, in order to access natural resources faster, and labour safety is increased compared to drill and blast operations. However, shaft sinking machines need to be capable of accommodating all the basic requirements for deep shaft sinking, namely: 1. Excavation and muck removal 2. Ground stability control 3. Groundwater ingress control 4. Temporary lining installation 5. Permanent lining installation and watertight sealing 6. Ventilation 7. Secondary means of egress for personnel In addition, how the machine operates in the shaft is an important factor, either slung on ropes from a surface headgear or on its own in the bottom of the shaft. An all-embracing machine which can deal with all of the above conditions is impossible but many of these requirements can be incorporated into a single machine. Deep shaft sinking also differs greatly from normal tunnel construction which employs the use of either a roadheader arm installed within a shield or a full-face tunnelling machine for excavation. Hydrostatic pressure and ground stability problems increase with depth, whereas in tunnelling the depth is normally relatively shallow and the aforementioned factors remain approximately constant along the tunnel length. DEEP SHAFT SINKING MACHINES All the shaft sinking carried out previously in the UK was by the traditional method of drill and blast. Elsewhere, in other parts of the world, attempts have been made to mechanise the process."

Jan 1, 2019

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT: As part of an overall study of properties and processes influencing consolidation of oil sands fine tailings resulting from different extraction processes, self-weight consolidation tests were per-formed. Fourteen 2 m and 1 m high standpipe tests were instrumented to monitor the rate and magnitude of consolidation of seven fine tailings materials. Tests provided valuable information about the variation of consolidation related to differences in fine tailings material properties that result from a change in bitu-men extraction process (caustic versus non-caustic). In addition, the effect of adding a coagulant to caustic fine tailings was measured. Test results are presented and discussed in terms of consolidation rate long-term volume decrease, compressibility, and downward drainage. Non-caustic fine tailings had fasterinitial consolidation, which is important in tailings ponds for reducing storage capacity and returning decant water at a faster rate to the extraction plant. Similar results were obtained for caustic fine tailings with a coagulant addition. However, long-term settlement of the different fine tailings appears to con-verge to a similar value over time because it is then governed by effective stress.

Jan 1, 2011

By L. Tong

The nickel laterite ore is composed of soft and hard minerals, and nickel distributes preferentially into the soft mineral rather than in the hard. Selective comminution of saprolitic and goethitic nickel laterites is investigated to upgrade nickel into the fine fraction using stirred milling. The optimal selective grinding conditions were determined through a kinetic study and the limit of selective grinding and nickel upgrade was analyzed. The breakage rates of minerals, grinding time, and the weight ratio of soft and hard minerals in the feed play an important role in selective grinding. A small breakage rate on hard minerals and a large breakage rate difference between the minerals are optimum for selective grinding. The soft mineral grade decreases with grinding time and the optimum grinding time is a trade-off of the soft mineral upgrade and recovery. The minerals weight ratio determines the limit of selective grinding. The effect of nickel upgrade is determined by both the conditions that influence selective comminution and the nickel grades in both the soft and hard minerals. The nickel grade in the soft mineral determines the limit of nickel upgrade.

Jan 1, 2015

By C. Riveros, H. Henein

Bulk Metallic Glasses have a high potential as advanced engineering materials due to their various properties including strength and corrosion resistance, to name a few. This paper investigates amorphous phase formation and rapid solidification characteristics of impulse atomized Co-based alloys in order to understand and control the application properties of the final products. Amorphous fraction and kinetic crystallization properties of the atomized Co-based alloy powders were quantified by means of Differential Scanning Calorimetry. In addition, different but complementary characterization tools were used to analyze microstructures of the powders. These include optical microscopy, X-ray diffraction and micro-hardness tests. While the amorphous fraction within the powders is promoted by high cooling rate and smaller powder size as expected, hardness is found to decrease with the fraction of amorphous phase.

Jan 1, 2015

By Guoxiang Chi

The Cornwallis Fold Belt in the Canadian Arctic Archipelago contains numerous Mississippi Valley-type (MVT) Zn- Pb occurrences and the world-class Polaris deposit. The occurrences are mainly hosted by the dolostone in the Thumb Mountain Formation which spreads over 25000 km2. Success in exploration requires further understanding of the genesis of these occurrences and an assessment of their parentage with the giant Polaris deposit. Syn-sulfide dolomites in regional occurrences share C-O-Sr isotopic characteristics similar with Polaris dolomites, indicating warm basinal brines enriched in 87Sr. The dolomites and sphalerites contain fluid inclusions with ice-melting temperature between ?45° and ?25°C, which is significantly lower than for most MVT districts in the world (?30° and ?10°C). These characteristics indicate that all the Cornwallis occurrences were produced by fluids of the same sources and/or aquifers. The deposit size was largely controlled by the rate and duration of the metal-carrying fluid flow, and by the availability of reduced sulfur at the site of mineralization.

May 1, 2001

By R. Agius, A. Nacu

"Cyanide destruction technologies are implemented at gold and silver operations to comply with the International Cyanide Management Code and meet ever more stringent discharge limits. Currently, the most common chemical cyanide destruction processes used in industry are sulfur dioxide/oxygen, hydrogen peroxide, and Caro’s acid. The cyanide destruction process used at an operation must reliably generate streams of acceptable quality at all times, and depends on numerous factors, including permit discharge requirements, tailings chemistry, location, site-specific climatic conditions and size of the operation. Selecting the most appropriate cyanide destruction process and determining the process design criteria requires accurate laboratory testing. This paper presents and discusses the results of a number of cyanide destruction evaluations that have been conducted to reduce cyanide concentration in process solutions or cyanidation tails. Laboratory testing provides important insights into reagent consumption and other factors required to achieve the target residual weak acid dissociable cyanide (CNWAD) levels.INTRODUCTION Process solutions associated with the extraction of gold and silver contain several forms of cyanide. The most toxic form of cyanide is free cyanide, which can be present as a dissociated cyanide anion (CN-) or gaseous or aqueous HCN. Weak or moderately stable cyanide complexes such as those of zinc, copper and nickel are classified as weak acid dissociable (CNWAD). Although less toxic than free cyanide, weak acid dissociable cyanide complexes are considered “ecologically sensitive” forms of cyanide and are regulated in most jurisdictions. In practice, reported WAD cyanide values comprises both free cyanide and weak acid dissociable cyanide complexes. Cyanide complexes with gold, mercury, cobalt and iron are referred to as strong acid dissociable complexes (CNSAD) and are much more stable, even under mildly acidic conditions. Another term commonly used in cyanide chemistry is total cyanide, which represents all cyanide compounds present in solution. Total cyanide levels in solutions are always equal to or higher than WAD cyanide values and the difference between the two usually indicates the presence of iron-cyanide compounds. Typically in Canada, CNTOTAL levels cannot exceed 1 mg/L in solutions discharged to the environment."

Jan 1, 2017

By Mory M. Ghomshei

"The cost of deep underground mine cooling depends on a number of geological, environmental and economic factors such as the temperature gradient in the mine, the outside air temperature, and the local price of energy. While geological factors, being static, can be controlled to some extent during the mine design, the environmental and economic factors dynamically change and therefore can only be controlled through a flexible mine ventilation system.With an average temperature gradient of 20–25°C/km, the virgin rock temperature at 2,000 m can reach 45–60°C. Conventional cooling at such depths could lead to exorbitantly high costs. In-mine geothermal heat pumps can considerably reduce the cost of cooling through energy communication with the centralized absorption chillers, which service the mine from the surface.It is shown that in-mine heat pump systems can be a viable option for reducing operating expenses and providing some degree of flexibility to cope with fluctuating energy costs. The price of Natural gas and electrify are the most important variables for optimizing the level of interaction between the surface and inmine cooling systems. Deep mine waters can be used to carry a portion of the mine heat to the surface, where the heat from mine can be used as a supplementary energy source for absorption chillers. As an extra benefit, the heat output of the chillers can be used for district heating and or greenhouse growing.The case of cooling deep levels of deep mines in Sudbury Canada (e.g. Creighton Mine) has been discussed. It is shown that an initial 1MW in-mine geothermal heat pump system can save significantly on the cost of cooling. Such a demonstration project will allow R&D on viability of larger similar systems to be incrementally added in the future.INTRODUCTIONThe amount of heat generated in deep and ultra-deep mines depend primarily on the regional temperature gradient and the thermal conductivity of mine rocks. The conductive heat flow is quantifiable and can be minimized or optimized in the process of mine design. Another important heat source can be related to underground equipment such as diesel machinery which often have low efficiencies (approximately 25–35%). This heat source can be controlled and reduced though improving efficiencies or using electrical equipment, which offer a much better efficiency (approximately 80–90%). Mine waters can also be a significant heat source (convectively bringing large amounts of heat into the mine workings)."

Jan 1, 2019

By John L. Hatton

The author will introduce and describe the nature of Fiberglas-Reinforced Plastics. Successful applications of corrosion-resistant structures will be shown and described, including pipe, ducts, tanks and other equipment. These structures are generally designed to handle corrosive liquids and gases and have proved both satisfactory and economical in service in various industries in Canada. The specification of structures will be discussed in relation to materials, construction and workmanship, physical properties and methods of testing.

Jan 1, 1970

By L. D. van Dyk, G. S. Tshofu

Iron ore fines are by-products of iron ore mining operations. Unlike iron ore lumps, fines cannot directly be used in conventional iron making processes, and consequently large quantities accumulate around the world. Pelletizing and sintering can be used to convert iron ore fines into agglomerates or briquettes for processing with lump ore, but these techniques are energy intensive and produce greenhouse gases. This research investigated the extraction of iron from iron ore fines using acetylacetone (a ß-diketone) as an environmentally friendly alternative process for fines utilization. A 2k factorial experiment design was used to identify the significant extraction variables. It was found that the reaction temperature and solid to liquid ratio had significant effects on the extraction process. The extraction kinetics were studied at different temperatures and the highest iron extraction (97 %) was obtained after 48 hours at 413 K and 0.025:1 (g:mL) solid to liquid ratio for a particle size range of +106 to -150 µm. The extraction products were easily separated from the unreacted acetylacetone by flash distillation and iron(III) acetylacetonate crystals were recovered. An economic evaluation showed that selling the crystals was profitable. Alternatively, the crystals can be reduced with hydrogen to iron particles and acetylacetone (for reuse).

Jan 1, 2015