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By G. M. Swinkels

Sherritt Gordon and Cominco, with financial assistance from the Canadian Government through PAIT, have developed a hydrometallurgical process for refining copper from sulphide concentrates. The main objective of the project was to develop a process applicable to a wide range of concentrates with respect to copper content, other metals content and impurities, within the economic parameters set by present smelting and refining practice. Other important objectives were to recover sulphur in its elemental form and not as sulphur dioxide to assure improved hygienic conditions and a negligible impact on the environment. For the most abundant and relatively refractory chalcopyrite concentrates, the first step of the process is thermal activation with hydrogen to decompose chalcopyrite and pyrite, commonly associated with it, into more reactive sulphides more amenable to leaching. The iron is then selectively extracted by sulphuric acid leaching and subsequently rejected as jarosite. High-bornite concentrates do not require thermal activation and acid leaching; they are subjected to another hydrometallurgical iron removal step. The high-grade copper sulphide resulting from iron removal, and containing all of the initial precious metals, is then leached under oxygen pressure to produce elemental sulphur and copper sulphate solution . After suitable solution purification, the copper is recovered by high-current-density electrowinning as wire-grade product. Precious metals remain in the leach residue and are recovered after separation of the gangue materials and elemental sulphur. The laboratory and pre-piloting test work had indicated copper and precious metals recoveries comparable to those achieved in current practice. The process was shown to be suitable for handling relatively low-grade concentrates and, in addition, it was capable of high recoveries of associated zinc, molybdenum, nickel and cobalt in saleable form.

Jan 1, 1978

By Christiaan Zeilstra, Jan van der Stel, Koen Meijer, Gerard Louwerse, Tim Peeters

The steel industry is producing about 5% of the world wide CO2 emission. Therefore the European steel industry has defined a research program to reduce the CO2 emission by 50% per ton: ULCOS. Since its start in 2004 ULCOS has identified four technologies for further development. Two of these technologies which produce liquid hot metal are discussed. The ULCOS blast furnace is based on recycling of decarbonated topgas and the capture and storage of CO2. The concept has been demonstrated during three campaigns at LKAB EBF in Luleå, Sweden. The smelting reduction process HIsarna is a combination of the cyclone-technology and Hismelt. The process has been demonstrated successfully in four campaigns at a pilot installation on the IJmuiden steelmaking site.

Jan 1, 2015

By Larry J. Hulbert, Louis J. Cabri, John L. Campbell, Gilles Laflamme, Chris G. Ryan, Soey H. Sie, Rolando Lastra

"Abstract- The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fme-grained minerais which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700Jo of the major Ni carriers and 78% of the major Cu qmier will be liberated at a grind of 80% -'}f,.7 J.Uil (-500 mesh) for typical low-grade gabbro (West zone, sample No. 1). For typical ""clinopyroxenite"" (West zone, sample No. 2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3) the liberation would be 71""lo and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total24.5% for typicallow-grade gabbro (West zone, sample No. 1), 15% for typical ""clinopyroxenite"" (West zone, sample No. 2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fme grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as sorne would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No. 2 and No. 3 is closely associated with magnetite.Palladium occurs in diverse ways. It occurs in the form of several Pd minerais (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tel­ lurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chal­ copyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerais and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate. However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No. 2 and No. 3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No. 3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No. 3, in order to improve Pt and Pd recoveries.Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefmed Re-Ir-Os-Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By L. Furtenbach, T. Möller

"Grinding mills are the heart of the mineral processing plant, and are production-critical machines which are required to achieve high availability. Liner wear life and a liner design that promotes ease of installation are important variables to achieve a high level of mill availability. Increased mill size results in more mill internal surface to protect, and more liner components to install and remove. This drives designers toward an increase in liner size to minimize the number of components to be installed by the liner handler. The liner attachment method can also have a large impact on mill availability as well as safety during installation.This paper outlines the experience from the development, installation and follow-up of liners installed in two 38' x 45' AG Mills at Boliden Aitik in Sweden. A new Poly-Met shell liner concept has been developed to minimize the number of liner components. The new Poly-Met shell liner components are made much larger than conventional Poly-Met or steel liners. This reduces the number of components to be installed/removed by the liner handler and helps to minimize installation time and consequently down- time. A new attachment system has also been developed to eliminate the need for the installation crew to be in the “drop-zone” of the shell liners while installing the liner bolts.One interesting aspect of this project was the requirement to predict liner life for these new large format AG mills. The existing 22' diameter mills at Aitik provided a base-line reference for this purpose, and DEM studies were used in the project development stage to predict the wear life of shell liners for the new 38' diameter AG mills. The results from this study are included."

Jan 1, 2012

By C. D. Rowe, H. S. Mitri, J. Malki, I. Vennes

Ore extraction at great depths creates high stresses around mine openings, which can result in violent rock failure in one of various forms of strainburst. This is especially true with strong and brittle rocks, which can store a large amount of strain energy that is suddenly released at failure. The strength and brittleness of rocks have been extensively investigated in the past. The most widely accepted method for the determination of rock burstability is the strain energy storage index obtained from a non-destructive uniaxial load–unload test. However, the results of this method are not always conclusive, showing less repeatability when the target test load is changed. This study concerns itself with the introduction of microscopic analysis as a tool to help validate the strain energy index results when burstability cannot be warranted based on mechanical property tests alone. In this study, two types of rocks, namely, basaltic komatiite (BK) and felsic norite (FNOR) obtained from Canadian underground mines are examined. The selection is based on the premise that felsic norite is known to be burstable from the mine experience, whereas basaltic komatiite is not necessarily burstable. A total of 60 mechanical properties tests were conducted including uniaxial compressive strength, Brazilian tensile strength, and load-unload tests. Laboratory tests on FNOR consistently exhibit high burstability; however, the results for the BK tests are not conclusive. To seek explanations for the mechanical rock behavior, 18 thin sections were examined with optical microscopy and image analysis. The findings show the tested BK specimens are dominated by alteration products, and all primary igneous minerals are lost. There is minor quartz, garnet, carbonate minerals, talc, and serpentine, which give the rock its ductile properties. The FNOR specimens are found to be relatively fresh and supported by a strong network of plagioclase with minor pyroxene, biotite, and secondary micas, explaining the higher stiffness. This study demonstrates how optical microscopy can complement mechanical property tests to evaluate burstability of rocks.

May 4, 2025

By C. M. Bartley

Fluorspar, in addition to its familiar uses as a metallurgical flux and as a source of the electrolyte for aluminum production, has become important as an essential raw material in the rapidly growing fluorine chemical industry. The unique ability of fluorine to react and form compounds with al-most all other chemicals has made it one of the important elements in modern chemistry. Research and development over the past thirty years have resulted in a current annual production of fluorine chemicals that is both technically and economically important to industry. Because many of these chemicals and products are relatively new, and most have properties that are not duplicated by other materials, the present uses are expanding rapidly and new applications are being reported continually. Fluorspar, the only immediate and practical source of fluorine, is therefore an important mineral. This fact has been recognized in major industrial areas such as the United States and Western Europe, but has received little attention in Canada.

Jan 1, 1962

By A. H. Mumin, A. Prikhodko

"This paper provides an understanding of interpreting and evaluating airborne time domain electromagnetic (TEM) surveys as applied to massive sulfide exploration. Variations in the conductive morphologies of massive sulfide ore systems are discussed, followed by forward modelling exercises examining the derived TEM response to these morphologies and discussion of the subtleties of data interpretation. Deposit morphology in the orientation at formation and the variations occurring due to later deformation are considered. Images of corresponding resistivity–depth models are provided. The combined modelling results provide a low-cost method for initial interpretation and screening of TEM anomalies. RÉSUMÉ Cet article nous permet de mieux comprendre l’interprétation et l’évaluation des levés élec-tromagnétiques aéroportés en domaine temporel (TDEM, de l’anglais time-domain electromagnetic) appliqués à l’exploration du sulfure massif. Y sont débattues les variations au niveau des morphologies conductrices des systèmes de minéralisation du sulfure massif, suivies d’exercices de modélisation prospective qui examinent la réponse dérivée des TDEM à ces morphologies et d’une discussion sur les subtilités de l’interprétation des données. L’étude envisage la morphologie de l’orientation originelle non déformée des gisements ainsi que les variations résultant d’une déformation ultérieure. Des images des modèles correspondants de résistivité-profondeur sont fournies. Les résultats combinés relatifs à la modélisation proposent une méthode peu onéreuse d’interprétation et de contrôle initiaux des anomalies dans les TDEM.INTRODUCTION Electromagnetic geophysical surveys are an indispensable foundation of many mineral exploration programs and can account for as much as half of the predrilling exploration costs. Quantitative mass interpretation of the survey results remains difficult due to the infinite variation of deposit morphologies, their complex physical properties, and the presence of barren conductive materials that can mimic or mask the response of targeted ore. Many modern geophysical investigations that focus on time domain electromagnetic (TEM) data interpretations are devoted to problems with inversion and modelling and their algorithms. Although a few of these investigations have resulted in commercial software products, these require highly qualified and experienced users and usually include geometric assumptions. Furthermore, without the input of known physical properties and geometric constraints, the inversion results are highly ambiguous. A number of case studies document the geophysical responses to known targets in well-defined and diverse geo-electrical environments, providing a high degree of correlation between field obser-vation and the results of the modelling used in this style of investigation (Hone, 1980; Schneider & Emerson, 1980; Tyne, Idnurm, & Malone, 1981; Bishop & Lewis, 1992; Hopgood & Hungerford, 1994; Meju, 2002; Yang & Oldenburg, 2016). The uniqueness of the target/environment parameters and their specific features limits the use logy is poorly understood. The responses are therefore that are devoid of complicating environmental factors (e.g., highly conductive overburden and hostrocks or nonuniform target conductivity) as a first approach to the interpretation process of such case studies as the main reference for interpreting TEM survey responses in areas where the underlying geomodelled from generalized and typical geological models"

Jan 1, 2018

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015

By Larry A. Morris

The environmental impacts of industrial activities have become very serious concerns of the public over the past few decades. Not surprisingly, governments have responded with legislation and regulations to force industry to operate in a more environmentally responsible manner and, more recently, have prompted industry to initiate voluntary measures in response to specific environmental issues. The concept of Product Stewardship has evolved as a system or vehicle for the industrial sector to demonstrate an active concern about the environmental impact of their products, services and processes.

Jan 1, 1996

By W. L. Single

"LET ME FIRST OF ALL thank you for sending this invitation to me to participate in this Annual Meeting of The Mining Society of Nova Scotia. As an engineer, although I don't get an opportunity to practice very much engineering these days, I am, of course, always pleased to be able to meet with my fellow engineers to exchange views, but I must admit that today I feel a little bit out of place in the midst of all the experts that are here today. Let me make one thing clear - I'm a generalist! Your program states that I am to make a keynote address. I have always thought that a keynote speech is one that says something that has not been said before - announces some new program or policy, or says something startling. I am sure you will understand when I tell you that keynote addresses are made by politicians and that civil servants speaking publicly are usually expected to give an account of what is, or what is likely, to happen as a result of policies that have been announced in keynote speeches by politicians. I am reminded of a statement by a distinguished parliamentarian who said, ""However exalted a civil servant may be, he is not above the elected officials."" So today I will confine myself to giving you an overview with particular emphasis on the development side of oil and gas. The theme of ""Oil and Gas"" is a topical one these days. I suppose it's because of all the copy that is being generated by the media on the U.S. energy crisis, the Mid-East situation, the fact that most of the world's proven oil reserves are in Arab hands and, of course, the accelerated exploration activity that is taking place in the North Sea, in the Arctic, and off the coast of Newfoundland and Nova Scotia."

Jan 1, 1973

By R. M. BUCHANAN

The segment of Canadian industry based on smelting of alum in um and manufacture of consumer products is based entirely on imported alumina and bauxite. In the absence of Canadian bauxite deposits, consideration of anorthosite, a less desirable aluminous rock, is being undertaken as one alternative in maintaining assurance of supply. Anorthosites in Canada cover many thousands of square kilometres of the Precambrian Shield. Although compositions vary widely among Canadian anorthosites, many appear to exceed the specified minimum of 25% A I 20 3 in bodies containing more than the required JOO million tonnes. A lthough most Canadian anorthosites are of Precambrian age, one located in British Columbia has been identified as being Middle _Cretaceous.

Jan 1, 1984

By D. A. Temple, G. O. John

Until recently, the approach to the problem of treating complex ores bas been to produce, insofar as is possible, mono-metal concentrates which are treated in traditional zinc, lead and copper smelting circuits, with the residues and by-products from some of these circuits being retreated for the recovery of contained values either by a separate residue treatment process or along with the primary feed to the appropriate circuit. The continued development of the Imperial Smelting Process, with its ability to treat poly-metal concentrates, calls for a re-examination of the traditional approach to this problem, and this the paper attempts to do. A survey of recent progress in the technical development of the process is made and a summary of current operational performance is included.

Jan 1, 1971

By P. Kobylin, K. Haavanlammi, K. Valkama

"Base metals and precious metals can be recovered from a nickel matte or nickel concentrate using the Outotec nickel chloride leaching process. The raw material is leached with hydrochloric acid and the metals are recovered by solvent extraction, where ammonia is used to control the pH. Ammonium chloride is regenerated to ammonia and the side product of this step is calcium chloride solution. The regeneration utilizes either calcium oxide or calcium hydroxide. The calcium chloride solution is used to convert sulfuric acid into a hydrochloric acid solution while producing pure gypsum as a side product. The regeneration and reuse of ammonia and hydrochloric acid in this process will have a positive impact, from the point of view of both operating costs and environmental sustainability. This paper concentrates on the test work and technical concept development performed by Outotec to implement and develop chemical regeneration and recycling into a vital part of the nickel chloride leaching process.INTRODUCTION According to a nickel market analysis, the nickel market is expected to grow in the future. Main driver for this growth is the increase in stainless steel consumption as the living standards are equalizing globally. The expected increase in the amount of electrical cars and the need for nickel in the batteries of electrical cars also gives potential for the increased need for nickel in near future. At the moment the use of nickel in nickel-cobalt-manganese (NCM) and nickel-cobalt-aluminium (NCA) Li-ion batteries is in the range of 14 ktpa. It is estimated to increase to the level of 90 ktpa by 2025. In every era of the nickel industry, Outotec has been constantly developing new processes to create environmentally sustainable and economically viable processing routes. The Outotec® Nickel Matte Chloride Leaching process is a great example of a process that is flexible regarding raw material and could also treat nickel raw materials that are difficult for smelters. Outotec’s main options for pyrometallurgical nickel treatment include the Outotec® Direct Nickel Flash Smelting process (DON) and the Outotec® Ausmelt TSL process. The DON process is operated in Boliden Harjavalta Nickel Smelter in Finland. Ausmelt process is in use for example in Daye nonferrous plant in China. In the Outotec® Direct Nickel Flash Smelting Process, a sulphide nickel concentrate is processed in an Outotec Flash Smelting Furnace (FSF). Producing concentrates and processing them by Outotec Direct Nickel Flash Smelting to matte followed by hydrometallurgical refining offers a reliable route from concentrate to product. In the DON process, high-grade matte with low Fe content is produced in the FSF and the valuable metals in the slag are recovered in an electric furnace (EF). The Outotec® Ausmelt TSL process can use a large variety of raw materials (concentrates, secondary material and scrap metal) as feed. Fuel and oxygen are injected into the furnace through TSL (Top Submerged Lance) and this enables efficient smelting. Both Flash Smelting and TSL plants produce nickel mattes, which can be refined with Outotec hydrometallurgical processes."

Jan 1, 2017

By S. Makni, S. Koppalkar, A. Bouajila

This paper reviews briefly the gravity recovery involving conventional gravity separators and centrifugal gravity separators. The advantages of semi-continuous gravity separators will be discussed. Techniques for upgrading the gravity concentrates will be addressed briefly. The research efforts in optimizing semi-continuous gravity separators will be recalled. Innovative gravity circuit for eliminating or minimizing the use of complex processing schemes will be reviewed. On-going gold gravity research at COREM has revealed that gold particle shape transformation is the main factor explaining the lower recoveries of the plant units. Efforts to devise possible remedies for improving gravity recovery at plant will be discussed.

Jan 1, 2011

By R. F. Favreau, L. C. Lang

"In modern blasting technology blasts are designed and analysed on an energy-mass-time relationship. The energy of the explosive is derived by computer analysis and the work potential of the available energy is expressed in numerical values. The mass involved in the blast is determined by the geometry of the blast and by the rock density. Time is also a relevant parameter, because time is required to complete the three basic stages of the breakage process.For successful application of the blasting parameters the basic mechanism of the breakage process must be understood.The physical-mechanical properties of the rock, local structural geology and the thermodynamic properties of the explosives can be brought together to create a computer model of a blast with which it is possible to predict separately the results of each parameter and to express the predicted degree of change in any parameter by actual numbers.A long-range project has started to create a ""bank"" of rock properties for as many Canadian and foreign mines as possible. A computer model has been successfully applied to predicting the effect of varying the ratio of spacing to burden at constant rock volume and significantly improved results are achieved, as the S/B ratio is increased up to about 2 to 2.5.High-speed photography has been applied to determine the time that has elapsed between zero time and the beginning of movement of the mass. The results assist in determining minimum and optimum delay time required for multiple-row blasting.The approach as described in the paper is now well proven and is clearly superior to previous methods based on powder factors and human assessment."

Jan 1, 1972

By J. Robison, H. Pieterse, C. C. Smith, M. Luque, S. Chipman

Phase change during pressure let down releases significant amounts of energy that must be controlled to avoid undo wear and tear on equipment. Hydrometallurgical slurries require flow control equipment (valves and tanks) made of expensive materials to withstand the abrasive, and often corrosive nature of the slurry. Presented is a model of the nozzle of a let-down choke which is designed to control the flow pattern that exits the choke (valve) as it enters the receiving tank. This model can be used to design chokes which allow for the dissipation of the energy released during pressure let down by spreading the stream over a significant portion of the slurry pool in the receiving tank to minimize wear on equipment near the nozzle exit and the bottom of the slurry tank. An example uses the model to choose the nozzle expansion (area) ratio to select the outlet slurry velocity and slurry expansion angle.

Jan 1, 2004

By C. M. Offenhauer

Abstract Zirconium markedly affects the formation of graphite in cast iron and may promote the formation of normal flake gaphite, fine flakes of eutectiform graphite, or spheroid nodular graphite, according to the composition of the Iron and the amount of the zirconium addition. Usually, it is employed in the form of a complex addition agent in order to facilitate its introduction and to guide its effect. The reported applications of zirconium as an inoculant for the production of pearlitic high-strength cast iron indicates that it is most effective as a silicon-manganese-zirconium alloy. Added in this form it reduces chill and minimizes zones of ferrite and eutectiform graphite. In low-sulphur cast iron, zirconium in amounts greater than 0.10 per cent tends to promote the development of eutectiform graphite. These irons are characterized by freedom from primary cementite or normal flake graphite and exhibit very little tendency to shrinkage on solidification. In hyper-eutectic low-sulphur cast iron, zirconium causes the formation of a partially nodular graphite structure. A combination of magnesium with silicon-zirconium alloy was found to produce completely nodular graphite structures without the hazards associated with the addition of elemental magnesium.

Jan 1, 1949

By G Anders

Underground tests of slusher cables at first might seem to be quite simple and inexpensive. They do, however, take a long time and give results that may be ambiguous and unreliable. Also, because underground test conditions are not exactly duplicable, tests carried out at different times or in different mines could not be compared. An attempt was made to develop a laboratory test method that would provide for all factors affecting slusher cable performance underground in such a way as to make it possible to achieve comparable results from different series of tests by exactly duplicating test conditions. Such a method should also make it possible to vary individual factors systematically in order to give a proper assessment of the effect of changing conditions on cable performance. A set of tests, comparing the same two types of cable both underground and in the laboratory, is described. AN assignment at the Algom Nordic mine called for the comparison of two types of %-in. slusher

Jan 1, 1964

By Louis Frost

"A FIRE which forced the sealing -of the east side of Dominion No. 16 Colliery in the Town of New Waterford, Nova Scotia, occurred on October 6th, 1952 (Figure 1).So far as can be ascertained, the fire was first noticed in the roof of No. 7 East Lateral, after a brushing shot had been fired in the pavement. There appears to .be no doubt that this shot •blew out, igniting a small feeder in the roof.Regular air measurements and air samples, taken over a long period prior to the fire, indicated that the ventilation was adequate, for at no time had the percentage of CH4 in the general air current exceeded one per cent in this location. The last regular monthly samples and air measurements, taken at the end of September, showed the condition of the ventilation to be:Return at the Top of No. 8 East WallQuantity .... 27,700 cu. ft. per min.CH4 .......................... 0.32 per centC02 ................................ 0.10 per centHowever, in the week preceding the fire the mine examiner on four occasions had reported small feeders of gas at the face of the brushing in No. 7 East Lateral.Figure 2 is a diagram of the working place where the shots were fired. The face brushing had been shot down at 3 :45 p.m. and cleaned up. Two 'hurdle screens' had also been erected, one close to the face brushing and the other fifteen feet from the face."

Jan 1, 1953

By J G. Brady

This paper discusses the ceramic products used in the construction industry in Canada, as well as the main raw materials used in their manufacture. The products include the! following: (1) clay prorlucts -such as facing brick (glazed and unglazed), common brick, facing tile (glazed and un-glazed), terra cotta, load-bearing tile, non-load-bearing tile, structural clay floor tile, quarry tile, drain tile, sew-er pipe, conduits .and flue liners -which are made mainly from domes-tic common clays and shales and from domestic or imported stoneware clays and low-grade fire clays; (2) floor and wall tiles of the whiteware type, which are produced from ingredients such as kaolin, ball clay, feldspar, nepheline syenite, talc, pvro-phyllite and wollastonite; (3) glass products -the major ones being sheet glass, plate glass and mineral wool (glass wool, and rock or slag wool) -which are made from such materials as silica sand, soda ash, salt cake, feldsspar, nepheline syenite, dolomitic limestone, high-calcium limestone. borax and (for rock and slag wool) various rocks or slags;

Jan 1, 1963