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By lchiro Aoi, Hideo Nakae, Makoto Yoshida, Makoto Ishino

"The influence 6f gravity on the microstructure of unidirectionally solidified Cu-Pb monotectic, Ag-Si and Fe-C eutectic alloys is studied. In order to examine the influence of gravity in a lg environment, both the upward (opposite to direction of gravity) and downward (direction of gravity) unidirectional solidifications are carried out. The results are as follows: (1) For the upward solidified Ag-Si eutectic alloy, the eutectic Si continuously grows. On the other hand, in the downward solidified Ag-Si alloy, the Si grows discontinuously and disperses into the ex-Ag matrix. (2) No morphological difference in the eutectic growth is observed between the upward and downward solidified Fe-C eutectic alloys. (3) In the case of the upward solidified Cu-Pb monotectic alloy, a banded structure, which consists of Pb-rich layers and Cu-rich layers, is observed. However, such a banded structure -is not observed in the downward specimen. (4) The banded structure is not found in the upward solidified Cu-Pb-0.05 mass % Al and Cu-Pb-0.1 mass % Al alloys. In the Cu-Pb-0.05 mass% Al alloy, a fibrous -L 2 phase grows continuously parallel to the growth direction at low growth rate. Only 500 mass ppm addition of aluminum induces the morphological change of the monotectic L2 phase.IntroductionThe influence of gravity on the solidification of eutectic and monotectic alloys has been investigated in microgravity environments [l-9]. The purpose of these studies was to obtain a homogeneous microstructure of eutectic or monotectic alloys, most of which alloys tend to solidify with macro-segregation under gravity. However, in most of the previous experiments, e.g., in free fall systems, in aircraft or in space laboratories, the growth rate was too high to realize a planar solid/liquid interface. This would be due to the limited time for solidification. Thus, it was difficult to examine the influence of gravity on the planar coupled growth of the eutectic or monotectic alloy. In this study, both the downward U.D.S. (unidirectional solidification by gravity) and upward U.D.S. (opposite direction to gravity) are carried out in order to examine the influence of gravity on the coupled growth in a lg environment [l0, 11]. In the case of the downward U.D.S. using the current Bridgman method, the molten alloy must be confined between the crucible and the solid."

Jan 1, 2000

By J. L. Johnson

Remediation of small-arms firing ranges is being investigated by the Naval Civil Engineering Laboratory and the U.S. Bureau of Mines. Scheduled closures of military installations, as well as the management of active ranges, require the development of methodologies for heavy metals removal to prevent their entering the surrounding environment. The impact berms contain high concentrations of metals, and the soil and vegetation surrounding the berms were found to have slightly elevated levels. The heavy metals characterized are in the form of whole bullets, a wide size distribution of free fragments, smeared lead on the surface of the soil grains, and very finely attached particles. Gravity beneficiation can remove liberated metal contamination effectively. Weak acetic acid leaching shows promise in lowering the final metal contamination to allow the soil to pass the Environmental Protection Agency's (EPA) Toxicity Characteristic Leaching Procedure (TCLP) criteria.

Jan 1, 1991

The effect of change in slag composition upon metal losses to the slag and the relationship between slag composition and slag matte separation was investigated at 1400°C. The synthetic slags containing CaO, MgO, SiO2,, A1,0, and FeO were similar to those employed in the electric furnace smelting of sulphide Cu-Ni concentrates containing PGM (Precious Group Metals) from the Merensky Reef of South Africa. The matte with a grade of 9.3% Cu and 16.0% Ni was a typical electric furnace product. The results indicated that the Cu and Ni solubility in the slag increases with the increase of the basicity ratio and CaO and MgO contents of the slag. At constant CaO/MgO ratios the rise in basicity decreases the metal losses. When FeO and SiO2 contents of the slag are kept constant, the substitution of MgO with CaO decreases the metal losses. The relationship between slag composition and matte-slag separation was found to depend primarily on the basicity ratio and the FeO content of the slag. The net effect comes from a strong interaction of the two in such a way that increasing basicity and decreasing FeO contents deteriorate the clean separation of the two phases.

Jan 1, 1994

By Paul S. Korinko, Simona E. Hunyadi Murph

To address a radiological contamination event, a materials and process project was initiated. During the course of this project, processes and materials were developed that successfully captured zinc vapors physically and chemically, respectively. However, the physical traps were placed in an undesirable area and it was determined that the chemically captured zinc reactions was reversible. Consequently, advanced nanomaterials are being developed to capture zinc vapors. The current state of the art of the science and engineering of these materials and their efficacy for zinc capture and retention is discussed in this paper.

Jan 1, 2015

By Hongbo Zhu, Jinhui Peng, Linqing Dai

"To optimize the process variables for making direct reduced iron (DRI) by microwave heating, the reduction temperature, reduction time and the ratio of coal to material were studied with the central composite design (CCD) and their interactions on the Metallization rate were also investigated. The predictive polynomial quadratic equations model was analyzed by ANOVA. Optimal conditions of making DRI can be concluded as follows: 28 min at 1139?, the ratio of coal to material is 20.95%. Under these conditions, the metallization rate is up to 97.06%.1. IntroductionThere are some technical problems in making direct reduced iron (DRI) or sponge iron using iron ore concentrates containing coal and lime. In reduction of the iron ore concentrates containing coal with microwave heating, the strength of pellets needn’t to be considered. It reduces the costs and improve quality of materials, but also eliminates the need for pellet preparation process, simplifying the process and achieving a cleaner production.Microwave energy is a clean energy, and has characteristic of selective heating. The speed of heating is also fast. It researched by Chen Jin that when the mole mass of C: O is 0.627 and the microwave power is 15KW, it only spends 15min from 15? to 1021.6? with 1 kg iron ore containing coal with microwave heating [1]. There are many factors affecting metallization rate. In order to find a suitable condition for reduction process, it is necessary to design a series of suitable experiments.Response surface methodology (RSM) is one of the relevant multivariate techniques which can deal with multivariant experimental design strategy, statistical modeling and process optimization [2–5]. It is used to examine the relationship between one or more response variables and a set of quantitative experimental variables or factors. This method is often employed after the identification of the vital controllable factors to find the factor settings that optimize the response. Designs of this type are usually chosen when a curvature in the response surface is suspected. The process optimization of the microwave reduced iron ore was seldom reported in literature. Hence the present work intends to assess the effects of variables such as reduction time, reduction temperature and the ratio of coal to identify the optimum conditions using a central composite design (CCD). The characteristic of product was assessed using scanning electron microscope (SEM)."

Jan 1, 2011

By Rolf R. von Oppenfeld

Onsite hazardous waste processors often find obtaining a Treatment Storage and Disposal (TSD) permit one of their first major challenges. Some processors may spend the time and money required by the permitting process, only to find out later that a permit was not necessary. This paper will present and analyze four strategies that processors may use to avoid obtaining a TSD permit. Some facilities will be able to remove their waste streams from RCRA's oversight by ensuring the material is not "hazardous" waste. Parties that treat waste while it is in process may be able to avoid generating "waste" altogether. Certain treatment facilities have been specifically exempted by EPA. Finally, treatment of waste while it is in generator storage tanks may be allowed without a RCRA TSD permit. Hazardous waste point of generation, an important determination relating to these strategies, will also be discussed. Generators and processors will find this paper useful when evaluating their permit exemption potential

Jan 1, 1996

By John M. Boyle

The use of high vacuum mercury retort recovery as a safe and effective means of removing mercury from mercury hazardous waste solids rendering them non-hazardous and recovering mercury suitable for recycling.

Jan 1, 1995

By J. M. Floyd

"Top submerged lance furnace developments started in CSIRO in the early 1970s and was given the name Sirosmelt. In the early work the technology was developed for tin smelting and processing tin slags but once a small pilot plant was established other slag processing applications were soon recognised and evaluated for various copper, nickel, zinc and cobalt-containing slags. The process was tried for copper smelting and converting, which was proven in the small pilot plant in 1978. In the same year the first commercial application of the technology was established for the recovery of tin from slags at Associated Tin Smelters, Sydney. Work on lead smelting was initiated by the CSIRO team in the late 1970s and laboratory work led to pilot plant trials by Mount Isa Mines.In the second decade of the technology the focus of development became commercial acceptance of the technology through marketing, development and application by Ausmelt and Mount Isa Mines; the former commercialising and developing the technology for a wide range of applications, while the latter concentrated on its own commercial needs of copper and lead smelting. This decade saw a number of commercial plants built in Australia, with considerable interest becoming evident from other parts of the world. Towards the end of this decade Mount Isa also entered into the business of marketing of the technology through rights dating to the joint work with CSIRO in the late 1970s.So far, after five years, the third decade of the technology has been characterised by diversification of applications of the technology to areas outside the non-ferrous and precious metals production industry. The waste processing and recycle industry and the iron and steel industry have recognised that the top submerged lancing system is a new type of reactor with many significant features which provide new opportunities for processing a range of materials under good environmental controls in a cost effective manner.I hope this audience will excuse my boldness in talking about the third decade of the technology when we are only half way through! I am aiming in this paper to not only talk about the past, but to try illustrate the future directions which I envision."

Jan 1, 1996

By den Bulck A. Van

In Europe, 50% of the copper originates from recycling. High-Cu containing scraps are regularly rich in impurities like Fe, Ni, Sn and Pb. Many high-Cu containing scraps are fed directly into anode-furnace casting installations or furnaces with limited refining capability. The impurities levels of the anodes produced in these processes should however remain acceptable for further electro-refining. The distribution of Sn between copper and slag has been investigated for conditions relevant to copper converting. Unlike previous studies, this work focuses on the behavior of Sn relevant to fire refining conditions, which are essential for anode refineries.In this study, liquid Cu–1Sn and CuOx–FeOy–SiO2 slag, with CaO additions, were equilibrated at 1300 °C in vacuum sealed SiO2 ampoules. After metal–slag equilibration, the samples were quenched in water. The composition of the slag and Cu metal was investigated with Electron Probe X-ray Microanalysis. The distribution coefficients of Sn between slag and Cu metal were determined as a function of slag composition.

By Kimio Itagaki, Makoto Ohtsuka, Kouki Chiba, Minoru Matsumoto

"The properties of Ni-Mn-Ga films such as chemical composition, crystal structure, microstructure and transformation temperature were investigated with respect to sputtering conditions in the present study. The Ni-Mn-Ga films were deposited on a polyvinyl alcohol substrate with a radio-frequency magnetron sputtering apparatus using the NisoMn2sGa2s and Nis2Mn:«1Ga24 targets. After separating from the substrates, the films were annealed at the temperature between 873 and 1273 K for 3.6 ks. The chemical composition of the films depended on the radiofrequency generating power, however, there was no dependence on the heat treatment temperature. Each deposited film had a columnar grain structure. After heat treatment, the width of columnar grains widened and then became indistinct with increasing heat treatment temperature. The Heusler type cubic crystal structure of the fi4n with heat treatment at 1073 K changed to the tetragonal one through the martensitic structural transformation during cooling. The martensitic structural transformation temperature increased with increasing nickel content of films, while the Curie temperature decreased. The film obtained at 200 W using the Nis2Mn24Ga24 target after heat treatment at 1073 K showed one-way shape memory effect through the reverse martensitic structural transformation during heating.IntroductionThe ternary intermetallic compound NiiMnGa has a Heusler-type crystal structure and is an intelligent material, which has a shape memory effect and a ferromagnetic property. The martensitic structural transformation occurs within the ferromagnetic temperature region. The cubic crystal structure of L21 at high temperature changes to a tetragonal one through the martehsitic structural transformation during cooling. The films of this compound can be applied for an actuator of micro-machines."

Jan 1, 2000

By Mark Tsirlin

Kinetics of the initial oxidation stages of diffusive silicide coatings on 8 molybdenum and niobium at 1100 - 1700 and under the pressure of 400 and 1330 Pa has been studied using methods of gravimetry and gas phase analysis of oxygen, as well as by SEK, XRD and EDMA methods. The first oxidation stage described by asymptotic equation in case of NbSi coating changed over to the stage described by parabolic equation. The asymptotic law was shown to depend on non - stationary conditions on the oxide layer boundaries. Interconnection between silicides and quartz structures, on the one hand, and peculiarities of oxidation kinetics, on the other, is [discussed. The possibility of estimation oxygen atom jump frequency in quartz and fractions of oxygen reacting with metal and with silicon proceeding from the analysis of the kinetic data was ascertained. Conditions of oxidation kine- tics transfer from asymptotic (or parabolic) stage to a non - protective "linear" stage, associated with volatile ~roduct formation, are also discussed.

Jan 1, 1995

By Jerold L. Johnson

Remediation of small-arms firing ranges is being investigated by the Naval Civil Engineering Laboratory and the U.S. Bureau of Mines. Scheduled closures of military installations, as well as the management of active ranges, require the development of methodologies for heavy metals removal to prevent their entering the surrounding environment. The impact berms contain high concentrations of metals, and the soil and vegetation surrounding the berms were found to have slightly elevated levels. The heavy metals characterized are in the form of whole bullets, a wide size distribution of free fragments, smeared lead on the surface of the soil grains, and very finely attached particles. Gravity beneficiation can remove liberated metal contamination effectively. Weak acetic acid leaching shows promise in lowering the final metal contamination to allow the ,soil to pass the Environmental Protection Agency's (EPA) Toxicity Characteristic Leaching Procedure (TCLP) criteria.

Jan 1, 1993

By Xun An

Slag from an electric slag cleaning furnace was injected with methane and air mixtures to facilitate the recovery of copper and cobalt. The effects of methane-to-air ratio, gas flow rate and temperature on the reduction and metal separation were investigated. The results showed that over 90 percent copper and up to 60 percent cobalt could be recovered from the slag with a gas utilisation of around 70 percent, as calculated by thermodynamic simulation. Methane-to- air ratio was a major factor affecting the rate of reduction under the present experimental conditions. Further, injection of gaseous reductants greatly enhanced the coalescence and settling of entrained metal droplets. A reduction mechanism is proposed and the factors influencing the coalescence of copper droplets are discussed.

Jan 1, 1998

By Y. Maeda

Kosaka Smelter is a copper smelter located at the nothern part of Japan? and has been treating. complex sulfide concentrates using flash smelting technology for a long time. The flash smelting technology has an advantage in the point of controllability of matte grade and heat balance in the reaction shaft. But the disadvantage of this process, is that the dust generation ratio is high compared with other smelting process such as injection smelting technology. This reason why is that the flash smelting process is the oxidation process for the fine sulfide concentrates applying flash reaction in the oxygen enriched stream In addition of this disadvantage, the sulfide concentrates contains much volatile impurities is resulted the dust; eneration ratio more. This paper outlines the recent improvement of the flash reaction in the furnace and the behavior of impurities in Kosaka Smelter.

Jan 1, 1998

By G. L. Hundley, D. N. Nilsen

The U.S. Department of Energy investigated the use of liquid-emulsion membranes (LEM) for the selective removal and recovery of metals such as copper and zinc from mine waste waters. This investigation included field tests of a mobile, pilot plant-scale, continuous-flow LEM system. The system was tested at copper mines with solutions containing from 100 to 1,400 ppm Cu, and at a zinc mine with a solution containing 115 ppm Zn. Typical results from the copper tests were >90% copper recovery, and zinc extraction from waste water also was typically>90%. Although all of these waste waters contained high impurity levels, pure products were produced. On several of these field tests, integrated systems were tested that resulted in recovery of metal by-products, selectiv~ precipitation of iron, and polishing to reach discharge targets for essentially all of the contained metals. In addition, some results are included from laboratory-scale tests.

Jan 1, 2000

By Guangwei Wang, Changle Zheng, Yifan Chai, Jian Guo, Weiwei Geng, Jianliang Zhang

In this paper, characteristic and kinetics of CO2 reaction with four different kinds of coke such as top-loading coke, dry quenching tamping coke, wet quenching tamping coke and semi-coke were investigated based on isothermal method. Electric resistance reduction furnace was used to heat the sample. Volume Model (VM) and Shrinking Core Model (SCM) were used to calculate the kinetic parameters and to contrast with the experimental results. The results showed that the Volumetric Model (VM) was much suitable for the reaction of top-loading coke, dry quenching tamping coke and wet quenching tamping coke, while Shrinking Core Model (SCM) was much suitable for semi-coke.

Jan 1, 2015

By N. Bazzanella

The hydrogen desorption kinetics of pure and Nb-doped magnesium hydride film samples was investigated by using a Sievert-type apparatus. The overall activation energy and the reaction order controlling desorption are (141±5) kJ mol-1H and n 4 for Mg hydride and (51±5) kJ mol-1H and n 1 for Nb-doped (5% at) Mg hydride indicating that, in the doped sample, hydrogen desorption is controlled by the H migration in transformed h-Mg layers. Structural analysis performed by X-Ray Diffraction (XRD) and Extended X-Ray Absorption Fine Structure spectroscopy (EXAFS) show that the catalytic effect of the Nb dopant is connected with the formation of NbH0.89 nanoclusters dispersed in the Mg hydride matrix. It is suggested that the catalysis process is also connected to the presence of Mg-Nb hydride interfaces where the transfer of H atoms preferentially occurs by connecting h-Mg grains and by the role of the MgH2-NbH0.89 interface as preferential site for the dissociation of the hydride phase.

Jan 1, 2006

By Wei Gao, Qing-cai Liu, Cun-fang Lu, Jian Yang, Hinmi Zheng

"The mode of occurrence of sulfur and mercury in 57 Chinese bituminous coals have been examined using X-ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), and Zeeman atomic absorption mercury spectrometer. Mercury levels in coal are related to the geographic location of the coals and types of the coals. A synthesis of result indicated that most likely occurrence modes of mercury in high-sulfur and high-mercury coals are in solid solution in pyrite. Our study from 57 coal samples showed that most values of mercury concentration in coal varied from 100 to 1000 ng/g with an average of approximately 500ng/g, and mathematical model about correlation between mercury and sulfur was gained by mathematical statistics. This is apparent that mercury and sulfur vary concomitantly from coal data (table 3) , the high correlation between them in all coals at confidence of 95% ( a=0.05 ) .1. INTRODUCTIONThere contained about one trillion ton abundant coal resources in China. As a leading level of proven coal reserves in the world, the coals mainly distributed in north China and northwest China, especially in Shanxi, Guizhou, Shanxi provinces and Inner-Mongolia autonomous region. At the same time, China has the largest production and consumption of coal, and has the output of coal nearly accounted for 37 percent of the world's production. Coal-fired power plants are the major source of energy generation in China, and the proportion of coal combustion is up to 75 percent in the total energy configuration. Therefore, the mercury pollution caused by coal-fired has become a topic of wide-spread discussions since 1990. The contamination of mercury of human activities accounted for 10 to 30 percent [1], and the mercury emissions of coal-fired flue gas has made the greatest contribution to the pollution of atmosphere[2] In the past 30 years, the global increasing concentration of mercury pollutant in atmosphere maybe result from coal combustion[2]. The mercury emissions caused by coal-burning has become the main reason of China's mercury pollution, and the characteristics of mercury pollution is closely related to China's energy configuration, additionally, the features of mercury pollution have changed from the point pollution in 1970's to diffused pollution today[3]. Mercury can be found in various types of coals, and it is evaporated into gas phase during the combustion process."

Jan 1, 2011

By John L. Watson

The dewatering of steel industry waste sludges prior to discard or recycling often presents significant problems due to the fineness of the sludge particles, which may blind the filter medium and/or produce a cake with limited porosity, Several steel plant wastes, such as sludges from BOF and EAF gas cleaning operations exhibit not only a very fine particle size, but also some degree of magnetic character, A novel process has been developed to utilize the magnetic character of such sludges to enhance dewatering through a multi-force operation involving magnetic, chemical and vacuum forces, The process consists essentially of undertaking vacuum filtration of a flocculated sludge in a magnetic field, This is achieved by installing a permanent magnetic in a fixed position on the axis of a vacuum drum filter, thus effecting filtration of magnetic and non- magnetic particles, bound together in flocs, in a magnetic field, Previous tests using a modified laboratory vacuum drum filter treating artificial (magnetite) and industry waste (BF sludge) feeds have demonstrated that filtration capacity may be enhanced significantly with increases of up to 3000/0, An explanation of the mechanisms associated with the enhanced filtration was not obvious, and this research was undertaken to permit the cake formation in the magnetic field to be monitored to provide an insight into the manner in which particles agglomerate to form the cake. These tests revealed that the magnetic field caused magnetic particles to be aligned perpendicular to the filter surface and to form channels through which filtrate could freely pass thus increasing capacity, The effects of various magnetic fields and field strengths on the filtration process were also investigated. A simple computer model was constructed to demonstrate the proposed theory of multi-force dewatering, The model output graphically illustrated the suggested mechanism and confirmed the enhanced capacity of the novel dewatering process,

Jan 1, 1996

By George P. Demopoulos

n this study we have sought to highlight the critical linkage between individual reaction kinetic parameters (usually determined in small bench scale experiments) and large continuous reactor performance by focusing on the industrially significant zinc pressure leach process. To this end a comprehensive mathematical model previously developed for the description of this process was employed. In this paper we have examined in particular how small variations in key kinetic parameters impact on the autoclave&apos;s performance, i.e. attainment of autogenous steady-state temperature, zinc conversion and solution chemistry. The reaction parameters studied were: (i) stoichiometry of the marmatite leaching reaction; (ii) the activation energy of the same reaction, E,; (iii) the rate constant of the ferrous to ferric oxidation reaction, k,; and (iv) the apparent equilibrium constant for ferric precipitation, K,. This parameter sensitivity analysis was done under no oxygen mass transfer control limitations. Model predictions were found to be more sensitive to the kinetic parameters under certain conditions than others. The most dramatic finding was the one related to the small amount of sulfate produced during marmatite leaching. In connection to this it was found that the small percentage (< 5 %) of sulfate produced enhances the autothermal operational stability of the autoclave. The need for accurate kinetic parameter determination under conditions similar to those encountered in industrial zinc pressure leaching was demonstrated.

Jan 1, 1999