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By A. Porvali, V. Agarwal, M. Lundström

Hydrometallurgical recovery of rare earth elements (REE) from NiMH battery waste can be performed using sulfuric acid leaching followed by selective precipitation as double salt (REENa(SO4)2•H2O) by adding Na2SO4 as a precipitating agent. The formed double salts can be treated further with NaOH solution to form REE hydroxides. This study focuses on metamodeling of a simulated flowsheet with design of experiments (DOE). Based on literature survey, a process flowsheet was developed using HSC Sim software. The created flowsheet focuses on circulation of solution containing Na+, K+, SO42- ions and impurities liberated in the NaOH treatment of double salt precipitate. The effect of seven parameters (P1-P7) on seven responses (R1-R7) were modeled using central composite design (CCD). INTRODUCTION Nickel metal hydride (NiMH) battery waste can be considered as an urban mineral due to the presence of valuable metals like: Ni, Co and rare earth elements (REE) (Larsson et al., 2013). In NiMH battery waste leaching experiments, sulfuric acid has often been employed as a lixiviant (Pietrelli et al., 2002,Zhang et al., 1999,Rodrigues and Mansur, 2010,Porvali et al., 2018). The key advantages of sulfuric acid are its stability and cost-effectiveness compared to other mineral acids such as HCl and HNO3. However, the usage of sulfuric acid in NiMH battery waste leaching poses simultaneous challenges and advantages. Limited REE solubility can be taken as benefit when recovering REEs double sulfates after solid-liquid separation. However, sodium and potassium hydroxide, present in electrolyte residues in the battery waste, can cause in-situ precipitation already during leaching due to limited solubility, thus decreasing the total REE recovery (Porvali et al., 2018). However, this problem can be circumvented by washing the electrolyte residues off the raw materials. Subsequently, the REEs may be precipitated in bulk as a mixed double salt out from the solution at very low pH with minimal co-precipitation of Ni and other metals. This relatively easy separation method can be extremely advantageous in the case of such a complex solution matrix with relatively high REE concentrations (conc.). Once REEs have been precipitated as double sulfates as per eq. (1) (Porvali et al., 2018), the resulting double salt precipitate lacks applications without further treatment. Direct thermal treatment would generate sulfur dioxide emissions and likely require high temperatures in order to transform double sulfates into REE oxides. Furthermore, the precipitate contains Na ions, which would need to be removed by chemical treatment from the calcined REE product. In the context of circularity of raw materials, it can be taken of a remarkable benefit if the sodium and sulfur present in the double salt could be reused instead of wasting them into the side streams. To that end, in this simulation study, the double salts are converted by dissolution and precipitation to hydroxides which are readily treatable, e.g. with total dissolution and solvent extraction, for further purification (Abreu and Morais, 2010):

Jan 1, 2019

By Marvin A. Ph. D. Friedman

The following paper describes an overview of evaluations for assessing the potential hazards associated with handling newly developed reagents used in the mining industry. Important factors in determining the risk and hazard associated with handling a particular chemical include hazard identification, dose-response assessment, exposure assessment, and risk characterization. The hazard evaluation step involves collecting and evaluating appropriate toxicology information on a chemical. This can include a comparison of the structure of a developmental chemical with that of a material with known toxicology information. Acute toxicology data, including oral, inhalation, and dermal LD50 values, eye and skin irritation data and sensitization or allergic potential information are typically generated for new chemicals. Environmental and in-vitro genetic toxicology data (e.g. Ames test) are also used to evaluate new mining reagents.

Jan 1, 1994

By William J. Kohan

Milling has traditionally been considered more art than science. In the last 10 years, significant improvements in process equipment have been made and we are finally taking significant steps toward approaching grinding as a science. Two machines have been at the center of this development. These are the roll press and the high efficiency separator. The former can be considered as a new technology or adaptation of existing i.e. roller mill. The latter is clearly an improvement of existing technology. Other machines have been introduced to a lesser degree and later. Among these are the CKP and Horomill. The purpose of this paper is to provide an over- view of the currently available modifications for operating systems and options for new milling circuits with some comments on their application and history.

Jan 1, 1997

By K. Morsy, S. S. Peng

A new method of pillar stability evaluation was proposed. The unique feature about the method is that it estimates two types of stability factors for the pillar. The first stability factor is to measure how much the applied stress at that point is smaller than its strength, and the second stability factor is to predict whether or not the pillar will fail violently. The strain-softening behavior of coal pillars was simulated by the Drucker-Prager yield criterion. A new algorithm that simulates the strain-hardening behavior of the gob was used. A numerical technique to estimate the local mine stiffness (LMS) was introduced and verified by both numerical and analytical methods. A case of massive pillar failure in a room-and-pillar mine was used to define the stability limits for the proposed method.

Jan 1, 2003

The main goal of this paper is to present readers with recommendations for choosing coaxial cables appropriate for mining applications of Time Domain Ref 1 ectometry (TDR) to monitor rock mass movements. Prior to discussing the recommendations, mining applications are illustrated with examples and the operating principle of TDR is discussed briefly. Items that affect the result of the monitoring system performance include the coaxial cable selected, the grouting material used, and the installation procedure.

Jan 1, 1986

By David B. Ashley

Risks in underground construction are often viewed as technical in nature; "running ground, " "squeezing ground" and "chimneys" are terms that appear in construction managers' nightmares, and occasionally in their underground projects. Financial consequences of these and other project risks are reviewed. Special attention is paid to sources of cost overruns. From this study a structure evolves for setting priorities for risk management actions; these actions can also be tested for impact and potential effectiveness. Finally, case study reviews of six underground projects indicate the "state of the practice" for financial risk management.

Jan 1, 1983

By M. J. Lowe

National Institute for Occupational Safety and Health (NIOSH) studies show that 43.5% of surveyed coal preparation plant workers had noise exposures exceeding the Mine Safety and Health Administration Permissible Exposure Level. Sound levels around vibrating screens in these plants often exceed 90 dB(A). NIOSH is currently developing noise controls for horizontal vibrating screens. To characterize noise sources, NIOSH researchers performed sound pressure level (SPL) measurements on a vibrating screen at their Pittsburgh Research Laboratory. The results show that the entire screen contributes to noise below 1 kHz and the vibration mechanism housings are most significant above 1 kHz. Constrained layer damping (CLD) treatments and an enclosure were used to reduce mechanism housing noise. These were evaluated using sound power level measurements according to ISO 3744. The CLD treatments reduced the A-weighted sound power level by 3.1 dB in the 1 to 10 kHz one-third-octave bands. A panel-on-frame vibration mechanism enclosure using various types of panels further reduced the A-weighted sound power level from the CLD configuration in the 1 to 10 kHz one-third-octave bands by 3.7, 4.0, and 3.9 dB for aluminum, steel, and Dynalam panels, respectively. The combination yielded a 7 dB reduction from baseline in A-weighted sound power for the same frequency range.

Jan 1, 2010

By John A. Shuster

INTRODUCTION Controlled ground freezing for mining and construction applications has been in use for over a century. Despite the great technological evolution which has occurred during this period, ground freezing is still used on projects today with much the same basic technology as that used originally over 100 years ago. Major developments have occurred in the separate fields of frozen soil mechanics, refrigeration, and heat transfer analysis. However, except for a few projects in Europe and Asia, these developments have not been combined to upgrade ground freezing techniques to their potential level. In view of this situation, it is believed desirable to examine the art of ground freezing in light of recent technical developments, together with highlights on some of the apparent advantages, disadvantages and economics of the various alternative approaches. The purpose of this paper is to attempt such an examination, with particular emphasis on the practical application of presently available technology. GENERAL ADVANTAGES AND DISADVANTAGES Ground freezing may be used in any soil or rock formation, regardless of structure, grain size or permeability; however, it is best suited to soft ground rather than rock conditions. Freezing may be used for any size, shape or depth of excavation and the same physical plant can be used from job to job despite wide variation in these factors.

Jan 1, 1997

By E. J. Donovan, O&apos

The use of Dynamic Analysis techniques in the design of conveyor systems is extremely limited. The most frequent use of the technique is in large and expensive systems where the emphasis is on insurance against failure caused by catastrophic tension waves. This paper sets out to illustrate a much wider range of applications where dynamic analysis has been successfully employed. The examples chosen deal with identification and correction of dynamic low tension problems, the variability in take-up movement as other system parameters change, the requirement for proper tuning of starting controls and finally the absolute necessity for a complete understanding of the entire system when specifying brakes for critical applications. The intent of the paper is to get designers to view a conveyor as a system of interacting flexible components rather than as a single rigid body.

Jan 1, 1993

By J. Hazen, R. Jenner

This project was developed at the PCS Phosphate Mine in Aurora, NC. This site includes a surface mining operation, beneficiation plant and chemical processing facility located in the coastal plain of eastern North Carolina. The phosphate ore being mined at this operation is a 10 to 12 meter (35 to 40 foot) thick colloidal deposit located approximately 30 meters (100 feet) below the ground surface. The ore is pumped to the beneficiation facility where it is separated into clay, sand and concentrate streams. The concentrate product is utilized at the chemical plants to produce a wide range of products including fertilizer, industrial phosphates and animal feed products. The Cyclone Dike Builder (CDB) project developed a technique for dewatering the beneficiation tailing sand stream and providing innovative placement for dike construction. Future material balance requirements at the PCS Phosphate mine required an improvement in tailing sand placement technique to accomplish strategic objectives. The water volume of the sand slurry forces significant quantities of sand out of the dike profile during deposition. PCS Phosphate and MetPro Supply of Florida developed a mobile high-density hydro-cyclone station to remove most of the water and significantly increase the density of the sand being placed for dike construction. This high-density sand slurry is then effectively controlled using minimal heavy equipment operation.

Jan 1, 2004

By Surendra K. Mishra

Recent land ban act has put pressure on industry to decontaminate the waste streams before they could be discharged. However, for both metal and organic contaminated wastes, there are commercial incentives to recover usable resources. Recent technology developments have helped meeting such objectives. This paper reviews developments in treatment technologies for industrial wastes. Major chemical groups used in waste treatment are summarized.

Jan 1, 1994

By K. C. Carriere

INTRODUCTION The purpose of this paper is to introduce the reader to basic control strategies for solid/liquid separation in mineral processing and to indicate some of the implementation difficulties to be encountered, without becoming overly involved in details of process, equipment or software. It is assumed that the reader has some familiarity with control systems and with dewatering processes, since exploration of these topics would require considerably more length. The paper is organized into three parts: first a general discussion on the need for control of dewatering processes and of the general criteria involved, next a more detailed elaboration on control strategies for the various unit operations, and finally a case study showing a specific approach towards such a project. Motivation & Objectives The justification for implementing any control system in an industrial plant is to improve operations and thereby to increase profitability. Without this motivation, the system will likely be perceived as unnecessary and will decline into disuse, an expensive and troublesome monument to someone's ill-conceived ideas. However, when a control strategy is correctly conceived, implemented and integrated into operations, it can provide significant advantages in operating ease and efficiency, and a handsome return on investment. In general terms, the objectives in establishing a control system are: • stabilization of process disturbances maintenance of product quality • maximization of throughput • dearer definition of process • protection of personnel and equipment A successful control strategy must address at least some of the above criteria. However, the most important requirement is a commitment on the part of plant personnel and management to start up, operate and maintain the system, and to upgrade it to reflect current process status and operational philosophy. Process Applications In this paper, control strategies will be explored for the most common methods of dewatering of mineral pulps. These unit operations include: drying, centrifuging, filtering and sedimentation. While the first three are important, they do not tend to be as complex as sedimentation, and thus will not be as exhaustively treated. Sedimentation is very widely applied, not

Jan 1, 1986

By Richard Keith Corbin

INTRODUCTION With the world media full of predictions that the price of gold will quadruple in three years (Maybury, R.J., 1988), and with financial forecasters and strategists touting opportunities to make 400% in gold (Skousen, M., 1988), explorationists and entrepreneurs are scurrying to find enough gold to feed the global gold fever created. At the same time, gold deposits in the United States and other developed and intermediate countries are becoming less attractive because of environmental restrictions, radical reductions in tax incentives, and depleting reserves, causing people in the mining industry to begin looking at opportunities for foreign investment in gold mining concessions in lesser developed countries (LDCs). Meanwhile, LDCs are responding with chamber-of-commerce aplomb in marketing their opportunities. In the face of all this frenzy and hype, targeting gold mining concessions in LDCs for foreign investment may be done more objectively by employing a systematic approach. For this paper the SHOP rating system (Corbin, R.K., 1987), which considers factors of the LDC's stability, hospitability, ore occurrence, and profitability potential is used. The result is that a tiny banana-growing republic in Central America, first discovered by Columbus and named the "Rich Coast'' because of the many gold adornments worn by its Indians, has been rediscovered and emerges as a classic LDC gold target.

Jan 1, 1988

By Rudolf E. Greuer, Xintan Chang

Mine fires have always been of great concern to mining engineers and their behavior has been studied for a long time. Although an abundance of observations exist, no satisfactory mathematical model for their interpretation and extrapolation has become known. The paper presented here tries to close this gap, making use of the laws of chemical kinetics, energy and momentum conservation. To overcome the mathematical difficulties, the fire zone is axially divided into segments and radially into sections, each one with an extension of only a few inches. Conditions in segments and sections are updated in time intervals of one second or less. To solve the large number of resulting equations, a numerical solution is performed. The model has so far been tried on timber fires. It confirms experimental observations on the ignition phases and equilibria of these fires.

Jan 1, 1987

By David J. Starbuck

For small precious metals mining to show a comeback a different perspective must be taken than that of larger mining companies. This perspective must be much the same as that of past successful smaller mining enterprises such as when the US had a need for Uranium. Abandoned mines and environmental concerns in older mining districts have discouraged many from entering with the attitudes of why try there if so many unsuccessful mines exist. A small mining venture can be successful there but must have a "think smart'' attitude. There must be a thorough understanding of deposits, utilization of advanced technology and a properly managed mining operation. "THINK SMART" MINING The small mine operator is usually looking for small high grade deposits, consequently, long term success depends on a series of small successful mining operations. The small miner must succeed right-off or credibility and future project funding will suffer. No veteran of even a few years in the mining industry needs to be told that a dollar spent on production today fails to yield as much as it once did. More efficient equipment and techniques have helped soften the problem, but there is little likelihood that a mining company can do much to control inflation, wages, regulations, or grade. That leaves the small miner to "think smart" as one area where operating dollars can still be stretched to produce more than they presently do (Gardner. 1981). In the planning stage of a mining venture, when most options are still open, the main controllable elements are market timing, deposit selection, cutoff grade, mining method, mine design, mining sequence, rate of production build up, process design, project financing structure, project management, and project ownership structure. During planning, optimum criteria can be established for each of these. Once a mine is in production, these options are foreclosed or at least severely constrained. The more thought given to a mining program using all information available the less the risk of encountering disabling surprises. Thus the intent of this paper is to suggest the "think smart" attitude most small mine operations use for long term success. If one looks at a number of successful mining ventures, whether large or small, there is a general logic most have followed to be successful. They have used proven exploration, mining and processing techniques along with economic evaluation and experienced personnel to improve their odds. LOGIC IN DEVELOPING A FEASIBLE VENTURE Most successful small mine ventures achieve positive cash flow as quickly as possible by seeking out those deposits which require the least time and expense on activities leading up to production. To do this they look for deposits that are the most accessible, easily investigated, mined and processed with the cheapest fundamental methods. The general sequence of events starting with district selection are deposit selection, preliminary feasibility, exploration, detailed economic feasibility, mine planning, development and production. Each successive step becomes more costly requiring intermediate decisions along the way. District Selection Small operations should look for known deposits which favor the occurrence of the type deposit sought rather than efforts in unproductive areas. Known deposits in developed areas have some advantages over remote areas: 1. More alternative methods of transportation are available. 2. A larger stable work force is available. 3. The area is usually more pro-mining. 4. Power, water, housing, technical services, skilled services, schools, recreation and shopping are available.

Jan 1, 1987

By John E. Urbanic, William D. Faulkner, Robert W. Ruckel

Guidelines are presented for the selection, handling and regeneration of activated carbon used in gold recovery operations. The guidelines are based on Calgon Carbon Corporation's own investigations and experience gained in working with gold mine operators all over the world. Gold adsorption rate and adsorption capacity are shown to be independent variables thereby requiring testing of both properties when selecting activated carbon. Means of measuring these properties are provided. Historical activity tests on activated carbon are shown to be minimally useful in selecting carbon for gold recovery. Proper thermal regeneration techniques to maximize recovery of adsorption rate without weakening the carbon structure are suggested. Simple positive means of measuring efficiency of regeneration are presented. The subject of hardness measurement as a predictor of "in process" abrasion is discussed. The cost/benefit issue of carbon activity level is addressed.

Jan 1, 1986

By D. C. Yang, J. Ye

A comprehensive flotation study has been conducted on a Chinese fluorspar ore using the packed flotation column developed at Michigan Technological University (MTU). The results are compared with those for a conventional mechanical flotation method on the same feedstocks. Key factors controlling flotation performance of both methods are evaluated based upon a simple statistic design. The flotation concentrate produced in one stage of the packed column has 4% to 5% higher recovery and much lower silica impurity than the concentrate produced by up to six stages using a conventional mechanical cell. The results also show that the packed-column flotation process is particularly suitable for the recovery of finer fluorspar particles.

Jan 1, 1993

By Gordon M. Pugh, David G. Rasmussen

INTRODUCTION Shrinkage stope mining can be employed in steeply dipping veins where both the wall and the vein material are sufficiently strong to stand with only minimal ground support. Shrinkage stope mining takes advantage of the swell in volume produced in breaking in-place ore. This expanded volume of ore is allowed to occupy part of the mined-out vein, and in so doing provides ground sup¬port and a working surface for the miners. Only enough of the ore is drawn after each stoping cut to allow work¬ing room. Not until the entire mining block has been broken is the full amount of broken ore drawn from the stope. DEVELOPMENT PRACTICES FOR SHRINKAGE STOPING The vein is developed into stoping blocks, each of which is 76 to 91 m (250 to 300 ft) in length and 61 m (200 ft) between levels. Level development, described later, is either on the vein or parallel to it with crosscuts periodically driven over to the vein. There are usually two exits from each stope. The first entry is a raise at one end driven either conventionally by raise climber, or by a raised borehole. Present practice is that this raise, put in from level to level, is either a 2.1- x 2.1-m (7- x 7-ft) Alimak raise or a 1.2- to 1.8-m (4- to 6-ft) diam borehole. Either raise system will require pro¬visions for an ore chute carried with the stope to the haulage level or the scram drift. At 9- to 12-m (30- to 40-ft) vertical intervals, dogholes are developed from the raise so that when stoping breaks back into these dogholes, timber or steel sets and necessary service facilities can be installed. The second entry to the stope may be either a similar raise at the stope endline, or more economically, a cribbed raise carried with the stope. As previously stated, development of the ore block is achieved by either drifting on the vein or by paralleling the vein with a footwall lateral and then crosscutting over to the vein at specified intervals. In the following discussion, three basic cases are illustrated in Figs. 1, 2, and 3. In Fig. 1, development is in the footwall by a 3- x 3-m (10- x 10-ft) trackless lateral. A heading is also driven on the ore and taken either full width or driven a standard size and slabbed to the vein width. Approxi¬mately 9-m (30-ft) long crosscuts on 7.6-m (25-ft) cen¬ters are driven from the lateral to the vein. For ease in muck handling they are usually put in on a slant rather than at right angles. A single orepass, located off the lateral and in the center of one stope block, can serve not only that stope, but also one on either side, up to a tramming distance of not more than 137 m (450 ft). Raises are put at the stope endlines on 91-m (300-ft) centers. The back of the vein is shot down and just enough broken material is drawn off to permit access for men to work off the broken ore. Development in Fig. 2 progresses by driving a 3- x 3-m (10- x 10-ft) trackless heading on the footwall side of the vein. The ore block is delineated by raises on 91-m (300-ft) centers. Crosscuts are again driven on 7.6-m (25-ft) centers over to the vein. Approximately four rounds are then taken up to the vein and each round is successively belled out so that all the crosscuts (pockets, in this case) connect. In this development, as opposed to that in Fig. 1 where there were no belled

Jan 1, 1982

By David L. Gefvert

A general review of the role of cationic flotation reagents in the beneficiation of phosphate, iron, and potash ores. The three major types of cationic collectors-amines, ether amines, and condensates will be compared and contrasted. The effect of particle size, water chemistry, and water temperature on the choice of cationic flotation reagents for each industry will be discussed.

Jan 1, 1986

By S. Di Muzio

Sulphate Reducing Bacteria (SRB) are hetero-trophic anaerobic micro-organisms that can be used to remove sulphates and heavy metals from Acid Mine Drainage (AMD), heavy metal-bearing streams with high iron and sulphate contents and low pH, generated by sulphur bio-oxidation in abandoned mine districts. After the preliminary chemical precipitation of iron with carbonate stones (I step, chemical precipitation) SRB can be used to reduce sulphates to sulphurs then favouring heavy metal removal as sulphur precipitates (II step, biologically mediated precipitation). In this work the experimental results of heavy metal and sulphate removal from column tests were reported. Sulphate and heavy metal abatement in fixed bed column was performed using chemically pre-treated samples of synthetic AMD. Attenuation of toxic effects of treated samples was also ascertained by toxicological tests of germination and radical growth with Lepidium sativum.

Jan 1, 2006