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By Kirsten Corin, Belinda McFadzean, Cyril O’Connor, Jenny Wiese

The Bushveld Complex of South Africa contains almost 90% of the world’s reserves of platinum group minerals (PGMs). In the flotation of PGMs, there are significant challenges arising from the need to treat ever-decreasing grades of the relevant ore deposits. The major challenge in the flotation of these ore bodies is the control and management of the gangue minerals, particularly silicates such as orthopyroxene, plagioclase feldspar, and pyroxene which are often rimmed with talc which makes them naturally floatable. It has been shown that various polysaccharide depressants such as CMC and guar have different properties in terms of depressing the gangue minerals. Since the PGMs are often associated with sulphides, copper sulphate is widely used as an activator in PGM flotation but can inadvertently activate the gangue minerals as well as reduce the recovery of PtTe2 which accounts for up to 40% of the Pt in the Platreef ore body. Depressants also reduce the mass of solids reporting to the froth and can thus destabilise the froth. This effect on the froth can be mitigated by using higher frother dosages or water of higher ionic strength. Reducing chromite recovery is of critical importance since high levels may negatively affect the downstream smelting process. Chromite recoveries can however be reduced through the application of gravity separation or reducing entrainment through reduced water recovery. In summary, due care needs to be taken to carry out site test work to develop an optimum ratio of collector, frother, activator, and depressant to ensure that the highest grades and recoveries of the PGEs are obtained while reducing depressant dosage as much as possible.

By D. N. Trerice

The Electric Power Research Institute (EPRI) is sponsoring the construction and operation of a coal cleaning test facility at Homer City, Pennsylvania. The facility represents a major investment by the electric utility industry to advance the state of the art of conventional coal cleaning technology. The facility is unique in design and can process large quantities of coal in conventional flowsheet configurations, simulate full size plant conditions, and perform open and closed loop performance testing on conventional and advanced coal cleaning equipment. Computer operation will also be demonstrated. The facility objectives, initial complement, and operating plane are discussed as they relate to other coal cleaning projects at EPRI.

Jan 1, 1981

By J. Chai, Y. Qiang, D. D. Zhang

"In order to control Quaternary loose layer settlement in East China, there are monitoring results based on the 3 water level observation holes and 7 sand layer of fiber Bragg grating (FBG) strain sensor. Un-der the conditions of upper group water injecting to lower group of loose layer, the deformation characteristics of upper, middle and lower group of loose sandy soil layer changing with time and relationship with the water level are studied. The constitutive relation of stress-strain is also studied at different sand layers. Research results show that using water injecting from upper group into lower group of loose layer can ease the loose layer compression deformation. With the water level dropped, in East China soil creep deformation occurred, which accord with viscoelasto plastic model. The deformation of lower sand group has clear later effect and no direct relationship with water level. The results provide an important basis for the study East China stratum settlement model and water management. INTRODUCTION Ground-surface subsidence is a common geological disaster, which has the features of continuous, changing slowly, concealment (Y.P. Yin et al. 2005). Today, due to underground mining and constructions in formation compression, surface subsidence is wide-spread in the world, which is the environmental geological problems in the worldwide that cannot be ignored (Y.Q. Xu et al. 2006, D.L Gallo-way et al. 2000, Qiu, B. et al. 2011). The eastern region of China has generally geological disasters in coal mine geological caused by the thick loose layer settlement like as mine shaft failure. Stratum dehydration consolidation is a major cause of loose layer settlement (H.Y .Liu et al. 2007). A method of water injection using ground water to stable water level is proposed, which can effectively control the loose layer caused by compression settlement(J. Chai et al. 2012&.2013). Accurately knowledge the characteristics of strata deformation is the premise of settlement management (Q.C. He et al. 2006). Previous re-search (J.F. Miu et al. 1996, X.Y. Gu et al.1998, Y. Zhang et al. 2006), mainly studies are focused condition of the city pumping irrigation, de-formation characteristics of middle and up loose layers. On a group of aquifer in East China, the loose layer losing water is caused by coal mining, bottom water drainage and overlying strata water flowing fractured zone hydrophobic induced by mining, which the dehydration conditions have great difference from one to another. The Position of water loss is centralized in bottom aquifer, and the formers of ground subsidence geological environment and settlement mechanism are different. According to the study of stratum settlement, usually the de-formation of sand layer is ignored(C.H. Liu et al. 2004), but few studies show that the sand layer have the plastic deformation, and contains the creep deformation, water content of sand soil may become the main settlement layer (Z.X. Wei, 2002, C.H. Liu et al. 2004)."

Jan 1, 2015

By Shu Fan Chau, Innes Duncan, Harry Asche, Bill Newns

The North Auckland Line (NAL) in Northland, New Zealand, is being upgraded to pass Hi-Cube containers. The line includes many tunnels and bridges which need to be refurbished to improve structural clearances and line capacity. Tunnel 2 along the line, the Makarau Tunnel, has posed special challenges. Opened in 1898, the tunnel suffered multiple collapses during construction and has shown significant distortion during operation. The tunnel has been repaired many times since opening. Successfully enlarging this delicate and distressed structure has involved historical research, advanced analysis and design, and careful construction. The results provide lessons for dealing with brick lined tunnels and poor ground conditions

Jun 13, 2021

By D. Robert Weir, Verner B. Sefton

The reduction roast-ammonium carbonate leach-hydrogen reduction process for laterites has been under development by Sherritt Gordon for the past 20 years. The process can treat high iron or low iron laterites, with some process modification, and gives extractions of 88-93% Ni or 82-88% Ni, respectively. Five campaigns on a 1 tonne per day Pilot Plant and four campaigns on a 35 t/d Demonstration Plant have been carried out on laterite from three different deposits, and many other laterites have been investigated in the laboratory. The Marinduque Surigao Nickel Refinery in the Philippines was designed on the basis of this work. The process comprises roasting to selectively reduce the nickel and cobalt in the laterite, leaching the calcine in ammonium carbonate to dissolve the metals, recovery of cobalt by precipitation of a mixed metal sulphide, concentration of nickel from the carbonate solution by basic nickel carbonate precipitation and recovery of high purity nickel by hydrogen reduction of nickel from ammonium sulphate solution. Ion exchange has been developed as an alternative to BNC and for recovery of trace nickel from BNC barren liquor. Details of the development of some of the process steps through the laboratory to commercial plant are discussed. The process metallurgy has been confirmed in the commercial plant.

Jan 1, 1979

By Muhammad Azeem Raza, Samuel Frimpong

Underground mining environments are inherently hazardous and can lead to emergencies where effective rescue and self-escape become critical. Missouri University of Science and Technology is pioneering new technologies for effective self-escape. The rescuers and miners need to be trained in these new technologically driven environments. Previous research in fields like aviation, medical surgery, and oil and gas drilling has demonstrated the effectiveness of virtual simulation training, but the mining sector has yet to fully adopt advanced tools such as eye-tracking and immersive training modules. This research proposes a comprehensive training infrastructure incorporating these technologies to enhance situational awareness and decision-making during emergencies. The novelty lies in the application of advanced miner escape and communication technologies, specifically designed to monitor and enhance cognitive responses in high-stress situations. By leveraging these technologies, the proposed training infrastructure aims to prepare the next generation of underground miners and operators, by equipping them with the necessary skills to manage emergencies effectively.

Feb 1, 2025

By S. K. Kawatra

The use of inferential particle sizing for a closed wet grinding circuit control has been practiced for several years. This paper presents a review of some inferential sizing equations developed for pilot and industrial plants using regression analysis. An analytical development is then presented showing how the general inferential sizing model arises from the nature of the classifier model. The relation between the general sizing model and the individual equations is then discussed.

Jan 1, 1982

By M. Portal, L. Goicochea

This study is carried out in the Zenit mining concession, which is located in the city of San Pablo in the department of Cajamarca in Peru. The Project has 33 mineralized structures and according to laboratory analyzes we have the presence of gold and silver. The geostatistical evaluation provides an analysis on the distribution of precious metals in the vein. This information is used to improve the efficiency of metal extraction and to reduce costs. The general objective is to evaluate the polymetallic veins (Au and Ag), for which the classification of resources (measured, indicated, and inferred) has been carried out, taking into account the parameters of minimum distance from the composite, corresponding volume and tonnage calculation. In addition, an inventory of estimated geological resources was carried out with the block grades obtained to generate the tonnage-grade curves.

Feb 1, 2024

By Mehmet Ali Recai Önal, MAHMUT CAMALAN

Mineral liberation is one of the primary objectives in comminution circuits for the downstream separation of valuable minerals. Breaking minerals through their grain boundaries (grain-boundary breakage) enables mineral liberation in their natural grain size, removing the need for intensive grinding. This study aimed to evaluate if gaseous carbon dioxide, oxygen, or hydrogen can be used as grinding additives to promote the liberation of chromite grains by grain-boundary breakage. For this purpose, chromite ore particles in the −9.53 + 6.35 mm size fraction were pretreated by exposing them to carbon dioxide, oxygen, or hydrogen flow. Then, the untreated and pretreated samples were broken in a drop-weight tester under the same conditions. Finally, the graderecovery plots of chromite grains in the selected progeny size fractions and the overall progeny distributions were measured and compared. Pretreatment with carbon dioxide flow was found beneficial for grain-boundary breakage. It significantly enhanced the liberation of coarse chromite grains along with the overall progeny fineness. EPMAanalysis showed that the adsorption of carbon dioxide seems to reduce aluminum concentration at grain boundaries, which could be the reason for grain-boundary weakening. These results suggest that carbon dioxide can be used as a grinding additive, reducing the carbon footprint of the mining industry.

Oct 29, 2020

By W. E. Bardelmeier

The high speed conveyor type self unloading bulk carrier concept has been around for about 70 years. Although the design was developed, refined and steadily improved in the Great Lakes, to date limited numbers of such vessels have emerged in the bulk ocean trades, and these have tended to concentrate within specific mineral trades. For example, North American gypsum companies have embraced conveyor self unloaders to the point where such vessels almost exclusively carry the gypsum requirements of this part of the world. One major aluminum company has developed an impressive fleet capability in self unloaders. Application of other ships tends to be fragmented through several mineral trades. A few years ago a new phenomonen began to appear on the Great Lakes. Whereas it had historically been accepted in that region that self unloaders were effective vessels for the minor bulk trades including limestone, coal, salt, gravel and sand; they had seldom been employed heavily in the big volume iron ore trades. Suddenly, however, the new generation of 60,000 ton Lakers which emerged were all designed as high speed self unloaders. The new vessels intended to trade especially in ore, or alternatively especially in coal, have somewhat different internal features, but the important point is that all are self unloaders.

Jan 1, 1979

By Dongjie Zhang, Zeyu Liu, Shuxin Liu, Yang Liu

Lateral pressure provided by caving rocks plays an important role in keeping the stability of the sidewall rock mass and controlling the rock movement. Taking Xilinhot Fluorite Mine as an engineering background, we studied the control mechanism of the granular media lateral pressure on the rock movement by combining physical experiments, theoretical analysis, and field monitoring. The results indicated that with the increase of the granular media depth, the lateral pressure provided by the static granular media presented two stages of rapid growth and slow growth. The lateral pressure on the footwall was negatively correlated with the dip angle of the orebody, and the lateral pressure on the hanging wall was positively correlated with the dip angle of the orebody. Ore drawing only caused the granular media lateral pressure near the drawing point to decrease. As the granular media moved, the granular media lateral pressure outside the pressure reduction area further increased, and this part of the granular media would play a key role in limiting surface rock movement. On this basis, the improved calculation formula of GLMP was given, which could be better applied to calculate the GLMP and critical granular media column with different dip angles. The action mechanism of the GLMP in the control of the surface rock movement was clarified. The granular body in the collapse pit was mainly composed of three parts: the bottom loose granular media column, the middle compaction granular media column, and the upper critical granular media column. The critical granular media column was the most important area to control surface subsidence and rock movement. Finally, through field practice, after effective filling of the collapse pit, the surface vertical displacement of the hanging wall and footwall was decreased by 56.8% and 55.6%, respectively, and the control effect of surface rock movement was remarkable.

Sep 18, 2023

By Vanessa Viterbo, Lia Walker, Hassan Khaniani, Vitor Viterbo

Fatigue is a major contributor to haul-truck incidents in mining, with up to 65% of fatigue-related events associated with operator drowsiness or microsleep episodes, Williamson et al. (2011) and Caterpillar (2007). This study examines whether operator fatigue produces measurable and repeatable signatures in haul-truck telemetry. Eight confirmed fatigue-related disengagement events were analyzed using 20-minute telemetry windows centered around the incident. Statistical descriptors, Z-score normalization, first- and second-order derivatives, sliding-window variability, and cross-signal correlations were extracted from engine speed, throttle position, fuel rate, ground speed, and brake indicators. A logistic regression classifier was trained and evaluated using leave-one-event-out cross-validation. The model achieved a receiver operating characteristic (ROC) area under the curve (AUC) scores of 0.75–0.79, demonstrating consistent discriminative capability. A characteristic shutdown sequence characterized by sudden throttle collapse, fuel-rate decay, RPM reduction, and unbraked coasting was observed across all events, indicating operator disengagement rather than mechanical malfunction. Earlywarning indicators appeared 90–500 seconds before shutdown in the events analyzed, suggesting practical potential for real-time fatigue prediction. These findings provide initial evidence that telemetry-based fatigue detection is feasible and could enhance safety in mining operations.

Feb 22, 2026

By Eric Lundgren

The mining paradigm is changing on the continent of Africa. Jessica Kogel?s closing statement from her September 2013 President?s Page (ME, September 2013, pp. 6) has never been more appropriate, ?Africa is shaping up to be the next mining powerhouse, and there is huge opportunity for local communities, national governments and private industry to work together to create a win-win situation for all.? Supporting this notion, attendance at numerous industry conferences around the world demonstrates the shift toward a more sustainable, more environmentally conscious extractive model. But questions remain: How effectively is the industry making this transition, and how willing are companies to learn from the experiences of others? The international development community, as we like to call ourselves, is going through a parallel shift. We are experiencing our own funding crisis; governments are not as flush with resources as they were pre-economic meltdown. But more importantly, after a half century of implementing development programs, we must admit that while some of our programs have been fantastically successful, too many still fail to achieve the goal of poverty alleviation for the world?s poorest. Moving forward, we are forced to recognize that achieving success in scale and sustainability is not always accomplished from our work alone. As the director of international programs for Africare, a nonprofit with more than 40 years of experience implementing community-based development programs in Africa, I can report that our organization is changing the way we think about successful development partnerships. Africare recognizes that for too long the mining sector and nonprofits have been at odds, choosing noncommunication as a ?solution? to the problem. Both sides now recognize that this standoff is outdated, and Africare, specifically, is ready to cross the proverbial line. We see the potential benefits of mining for local communities and, when done responsibly, the opportunity to properly manage Africa?s resource boom as a benefit to all. There are challenges in this conversation. Many mining professionals view nonprofits as whistle-blowers, ready in a pinch to speak to news sources and complain about poor operational standards. Those are advocacy organizations, and while their role is important, they are not the only nonprofits interested in mining operations in developing countries. Organizations like Africare, with decades of experience implementing poverty reduction programs, approach this differently. We know we can work with mining companies to promote economic opportunity in the communities where mining operations are occurring. We recognize that the conversation is difficult, and we are open to discussions about how we can bring our unique experience to bear on the problems faced by mining companies in carrying out their investment programs.

Jan 1, 2014

By John Hanna

The Mineral Resources Institute (MRI) has developed a unique process for selective fatty acid flotation of phosphate minerals from siliceous ores. The process takes advantage of preferential adsorption and high reactivity of fatty acid collectors towards apatite over silica surfaces under slightly acidic conditions of pH 5-6.5. The process was successful in upgrading various phosphate samples from Florida and North Carolina containing 7.7-15.3% P205 and 62.3- 77.2% Insol to concentrates assaying 28.1-33.1 % P205 and 4.1-9.9% Insol with high P2O5 recovery of 81.8-92.2%. Depending on the type of silica impurities present one or more cleaning steps, with or without sodium silicate, would be required to improve the grade of the rougher phosphate concentrate.

Jan 1, 1992

By George Mandarakas, Johan van Zyl, Karl-Heinz Becker

The world’s climate today has changed compared to 10 or 20 years ago. Many countries face water shortages; water sourcing for mining activities has become harder to secure. ESG’s focus on the industry has made us more aware of the need to preserve and responsibly use the water needed for wet processing in our milling and sorting activities. In a recent greenfield project in South Australia, 10 Gigalitres per annum would be required to process 5Mtpa of magnetite [1]. Published information indicates that the mining industry consumes approximately 12 EJ per year—or 3.5% of total global final energy consumption globally [2] or 3.33 trillion kilowatt hrs. This energy consumption is significant, considering the critical role mining plays in extracting and processing essential minerals for economic development and human progress. The perception of the mining industry is that not only does it consume significant power, but it also consumes a lot of the freshwater in the world. In fact, it consumes approximately 5% [3] of the total freshwater demand. According to the Intergovernmental Panel on Climate Change (IPCC), by 2050, 60% of the world’s population will be living in countries that are classed as water-stressed [3]. As more and more emphasis is placed on renewable energy sources, the amount of water used in mineral processing will increase because more and more raw materials require a water-intensive process. This increases the pressure on the mining industry to try and find water-saving initiatives. As part of this review, recent advancements in magnets have enabled magnetite processing facilities to achieve between 30 to 40% dry gangue material rejection before the wet beneficiation process (grinding and sorting). This reduction in energy consumption allows the reduction of energy consumption. Secondly, there is less material ground in the mills, which requires less water for mineral downstream processing.

Feb 1, 2025

By Xie Longshui

INTRODUCTION The gold production is from the state-owned gold mines, the local gold mines and the by-product of metal mines. Since 1975, the small gold mines have developed in rapid strides. Currently, there are about 3000 small gold mines in China. Most of them are operated by the local, and the production is about 50% of China's gold output. In the small gold mines, the normalized mining equipments are employed at most of mines, but some mines still use such backward tunnelling and mining tools as pick, shovel and hand hammer etc.. The mining techniques have developed from the primitive to the advanced, especially the methods of open stope, shrinkage and filling have been widely used. Such new mining techniques as bolting, vibrating draw, non-electric ignition and diamond drilling etc. are also introduced in the wall gold mines. In recent years, the development of small gold mines is very fast under the guidance of new mining policy which is ' rapid and great development of large-sized mines, helping small mines to develop, and quick mining for the existing mines; and encouraging the collective and the individual to operate a mine.' GEOLOGICAL FEATURES The gold veins are dominant, which are divided into two types, ie. the mesothermal deposit with altered rock in a crushed zone and the hypothermal deposit with quartz veins. The orebody distribution is not centralized, and the size of deposit and single minable orebody is small respectively. Most of deposit dip at 30° to 50°, characterized by expansion and shrinkage, ramification and compound, thinning out and reappearance, separation and composite at the parallel veins etc.. The ore grade is variable, and the factor of grade change is above 100%. The waste zones with lean or submarginal ore usually exist in deposits. As for the gold deposits with altered rock, the ore boundary is indistinct. Most of gold deposits, particularly the gold deposits with altered rock, are intruded by the late structural rock, thus the faults and joints are developed, and the rock and ore are crushed, especially the host rock of roof wall is very crushed. It ie obvious that the conditions of both formation of deposit and mining are considerably complicated. HISTORY With a long mining history and rich experiences, the local gold sectors are small, but they play an important role in China's gold mining industry. Dated from Xia and Shang Dynasty, the gold goods was made. In the Tang Dynasty, the development of gold mining industry was very fast. A Chinese poem , written by Liu Yuxi -- one of famous poets in the Tang Dynasty, says: As sun is shining over Dengzhou land, The fog on river slowly goes away, The panning girls together meet at bay, The beauty's jewels and stamps of king are gold from river sand. This poem shows the local gold mining was flourishing at that time. In 1888, the local gold mining sectors were all the rage at the moment, and the annual output of gold was as high as 21.5 tons. Since the founding of New China, the development of local gold mining was subjected to several back- sets, but certain advances are made on the whole, especially since 1970. Round about 1970,the simple, backward and indigenous mining was dominant in the small gold mines; for instance, the hand-hammer drilling, the hand-operated winch hoisting and the hand haulage etc.were main methods of gold mining . Up until the late 1970s,great changes took place in stoping, haulage and so on. Currently, some advanced technology and large-sized equipments are adopted in the local gold mines. Generally, the local small gold mining sectors play an important role in development of China's gold mining industry, and are important and attractive sectors. PRESENT DEVELOPMENT

Jan 1, 1987

By C. J. Pritchard

The Office of Mine Safety and Health Research (OMSHR) investigated ways to increase mine airflow to underground metal/nonmetal (M/NM) mine working areas to improve miners? health and safety. One of those areas is controlled recirculation. Because the quantity of mine air often cannot be increased, reusing part of the ventilating air can be an effective alternative, if implemented properly, until the capacity of the present system is improved. The additional airflow can be used to provide effective dilution of contaminants and higher flow velocities in the underground mine environment. Most applications of controlled recirculation involve taking a portion of the return air and passing it back into the intake to increase the air volume delivered to the desired work areas. OMSHR investigated a Nevada gold mine where shaft rehabilitation was in progress and one of the two main fans was shut down to allow reduced air velocity for safe shaft work. Underground booster fan operating pressures were kept constant to maintain airflow to work areas, inducing controlled recirculation in one work zone. Investigation into system behavior and the effects of recirculation on the working area during times of reduced primary ventilation system airflow would provide additional information on implementation of controlled recirculation into the system and how these events affect M/NM ventilation systems. The National Institute for Occupational Safety and Health monitored the ventilation district when both main fans were operating and another scenario with one of the units turned off for maintenance. Airflow and contaminants were measured to determine the exposure effects of induced recirculation on miner health. Surveys showed that 19% controlled recirculation created no change in the overall district airflow distribution and a small reduction in district fresh air intake. Total dust levels increased only modestly and respirable dust levels were also low. Diesel particulate matter (DPM) levels showed a high increase in district intake mass flow, but minor increases in exposure levels related to the recirculation percentage. Utilization of DPM mass flow rates allows input into ventilation modeling programs to better understand and plan for ventilation changes and district recirculation effects on miners? health.

By A. Bieg, M. Samson, Z. Bell, A. Zinsser, J. Schuyler

As the world progresses toward the renewable energy transition, the demand for minerals increases exponentially. According to the International Energy Agency (IEA) 2021 Net Zero by 2050 Report, critical mineral production needs to grow six times to combat climate change. It’s estimated that four to seven percent of global greenhouse gas (GHG) emissions come from the mining sector’s Scope 1 and 2 (direct and indirect) emissions. Including Scope 3 (upstream, downstream, and embedded) emissions, the sector accounts for 28% of global GHG emissions. In a typical mining operation, diesel fuel is the biggest source of direct GHG emissions, and haulage is often the main source of diesel emissions. Large haul trucks have been the industry standard for over 50 years and offer flexibility, relatively low capital cost (especially with equipment lease options), and guaranteed technology with known maintenance. The challenge will be to justify their continued use when there are more economical options that lead to significant reductions in GHG emissions. The purpose of this study is to compare five haulage options in terms of GHG emissions, using the methodology defined by the Greenhouse Gas Protocol Scopes 1, 2, and 3 (Category 2). Additionally, this analysis compares operating and capital costs associated with the five haulage options (emerging and proven technologies): 1) Diesel-Electric Haul Trucks, 2) Battery-Electric Haul Trucks, 3) Fuel Cell Haul Trucks, 4) Railveyor, and 5) Conveyor. This analysis looks at the emissions and costs associated with operating the equipment (fuel and electricity), the embedded emissions and costs associated with the construction and installation of the equipment itself, and the associated infrastructure (roads, powerlines, and rail).

Feb 1, 2023

By I. H. Warren

The high temperature lubricant molybdenite, MoS2, is usually produced by a complex sequence of processes involving mineral dressing of molybdenite concentrates followed by leaching with hydrofluoric acid to remove abrasive impurities such as silica (1). Many attempts have been made, mostly by techniques involving, direct fusion of molybdenum compounds with sulphur, to produce synthetic molybdenite. However, apart from some experiments of geochemical interest (2) in which aqueous solutions of sodium sulphomolybdate, Nat MoS4, were decomposed under pressure at temperatures between 300°C and 700°C, no attempts to produce the mineral by hydrometallurgical procedures have been reported. Since molybdenite is nominally a compound of tetravalent molybdenum with sulphur, and the most common state of molybdenum is +6, production of molybdenite is likely to involve reduction and sulphidization. The present study, therefore, describes the reduction, with hydrogen and carbon monoxide, of molybdenum in the hexavalent state in alkaline aqueous solutions containing sulphide ion. In these

Jan 1, 1972

By K. Heatwole, D. Shier, A. Davis, J. Kidder, S. Sunkavalli

"Acid rock drainage (ARD) is produced when sulfides are exposed to oxygen and water. Oxidation reactions typically result in a depression of pH and leaching of solutes and metals. Many oxidation models have been developed based on oxygen diffusion, but in environments with high permeability, other transport processes (i.e., convection and advection) can play an important role. Multiple sulfide mineral phases with differing oxidation rates should also be incorporated. WROC, a finite-difference model, was developed to account for these factors in predicting ARD. The program includes sulfide mineral oxidation using a shrinking core mechanism, heat transfer by conduction, heat of reaction and oxygen transport by diffusion and advection. The model was validated using data from the literature. After validation, the WROC model was used to simulate several different waste rock scenarios, including different forms of sulfide mineralization and the effect of implementing a waste rock cover. The results demonstrate that including specific sulfide mineral phases can have a significant effect on oxidation and that implementation of a cover can also aid in reducing waste rock oxidation.IntroductionAcid rock drainage (ARD) is a notable environmental concern in areas where rock or other material with acid generation potential is disturbed. ARD is defined as drainage that occurs as a result of sulfide oxidation in rock exposed to air and water. ARD is characterized by low pH, elevated metals concentration (especially aluminum, iron and manganese), sulfate and high total dissolved solids. The low-pH water that results from acid generation is capable of solubilizing heavy metals contained within the rock. The principal sulfide mineral in mine wastes is pyrite (FeS2). Pyrite oxidation is complex and can involve chemical and biological reactions. Oxidation of pyrite by atmospheric oxygen produces one mole of Fe2+, two moles of SO4 2- and two moles of H+ for every mole of pyrite oxidized, as described by Eq. (1)."

Jan 1, 2015