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By S. P. Kinney, P. H. Royster, T. L. Joseph

An investigation of the production of iron in the blast furnace is obviously not an easy subject for research . Enough is known of the mechanical , thermal and chemical conditions existing inside the furnace to say certainly that they are complicated. Furnace operators have found that the process is sensitive to a number of known and to many unknown operating conditions . In order to form any conclusions of value , it seems necessary to collect a large amount of data taken with considerable care and accuracy. These facts make a blast furnace research difficult but not impossible . The most serious obstacle in attacking the problem comes from the fact that it is useless in the design and operation of the blast furnace to use the method of " trial and error , which has proved valuable in so many other industrial problems . The variables are so interrelated and are so dependent one on the other that the number of experimental combinations to be tried is enormous . There are certainly not less than twenty factors in furnace operation and design that are known to influence the results . This is apparent if it is remembered that a phrase like " size and shape of the furnace" includes height of the furnace , height , diameter and angle of the bosh , inwall batter , stockline diameter , and furnace volume ; and that a phrase like " chemical and physical properties of the fuels charged " includes size and shape of the lumps , density, porosity and strength of the coke , in addition to its chemical analysis . Let us suppose that we need choose for each of twenty factors one of two values , for example , suppose we must say only that the furnace shall be " tall " or " short , " that the bosh angle shall be " flat " OF "steep , that the ore shall be " coarse " or " fine , " or that the blast has to be "hot" or " cold , " the number of resulting combinations is more than one million . In putting twenty pennies on the table , either heads up or tails up, the number of permutations possible is the twentieth power of two , slightly more than one million. It is obvious , therefore , that some sort of mathematical relationship , a set of rules of thumb , laws , curves or the like , are needed . Whether the relationships , curves or formulas are derived from experiment , from theory, or from mere guess -work, makes no difference provided they agree with the known facts . If they do not agree with known facts , they are worthless no matter what their origin or how weighty the " authority" vouching for them. Few such relationships have appeared in blast- furnace literature , and it may be doubted whether such formulas can be discovered .

Sep 1, 1923

By H. J. Heinen

This report summarizes preliminary research studies by the Bureau of Mines in electrowinning molybdenum directly from pure or impure molybdenum trioxide (MoO3) by fused-bath electrolysis in an open graphite cell without need of a protective inert atmosphere. A formulated electrolyte of the tertiary system containing 41.6 percent sodium pyrophosphate, 16.7 percent sodium tetraborat, 33.3 percent sodium chloride, and 8,4 percent molybdenum trioxide, by weight, electrolyzed at 1,000° C,, gave excellent results. Current density studies were made over a range from 20 to 260 amperes per square decimeter. Current efficiencies of 80 to 90 percent were obtained over the entire range. Yields up to 500 grams of molybdenum per kilowatt-hour were obtained. Higher current densities, however, reduced yields and produced a finer grained metal. The two most important facets in electrowinning molybdenum from MoO3, in an open cell, are temperature and electrode spacing to minimize or eliminate the formation of the suboxide MoO2, the major source of oxygen contamination. At temperatures of 1,000° C. and higher, together with the proper spacing of the electrodes, formation of oxides are practically eliminated. Molybdenum metal electrowon from pure MoO3 was 99.9 percent pure and contained 0,056 percent oxygen and 0,007 percent carbon. This metal, when arc-melted, had a Vickers hardness number of 175 and contained 50 parts per million oxygen and less than 10 parts per million carbon. Molybdenum metal electrowon directly from an impure MoO3 containing 90 percent MoO3 resulted in a metal of 99.8 percent purity.

Jan 1, 1961

By Bernard Porter

The rate of the heterogeneous reaction between reactor-grade yttrium and lithium fluoride in lithium fluoride-yttrium fluoride mixtures was measured using a quartz spring balance. At 950° C the magnitude of the rate of reaction is 10-5 grams of yttrium/cm2-sec. The heat of activation for the reaction is 38.3 kilocalories per mole of LiF. A surface-controlled mechanism is proposed in which LiF is adsorbed on the yttrium metal surface. An activated complex is formed when additional LiF reacts with the adsorbed LiF-metal site. The activated complex then decomposes to the products) which are lithium metal and YF3. The importance of the reaction in the electrowinning of yttrium metal from fluoride electrolytes is discussed.

Jan 1, 1967

By H. W. Leavenworth

Research was conducted by the Bureau of Mines to develop a technique to grow metallic fibers from a sulfide mineral. In this research, chalcopyrite (CuFeS2) was made sulfur deficient, and the remaining sulfur partitioned to the iron in the mineral to liberate metallic copper, or to the copper to liberate metallic iron. The metals formed on the surface as fibers and in the interior as spherical particles. Fiber growth is very fast. Lengths of 3 to 4 cm form in a matter of minutes, and the diameter of individual fibers is less than 1 µm. The mechanism of fiber growth is explained, and the reactions are reversible as predicted. Copper fibers can be made to grow from the surface at 400° C or to dissolve back onto the solid surface and be replaced by iron fibers at 625° C. Growth and dissolution can also be controlled to form copper/iron duplex fibers.

Jan 1, 1974

By L. W. Kelly

The purpose of this circular is to show that, under the conditions prevailing in the Stony Point mine, wooden bolts were just as satisfactory as steel bolts or conventional timbering, with a reduction of approximately 80 percent in cost of material. This one fact alone is enough to justify an experiment with wood. This circular will show that production records have remained constant with both wooden and steel roof bolts. INTRODUCTION The successful use of steel roof bolts is now an accomplished fact in the coal industry, but the use of wooden bolts in place of steel is a rarity. The first experiment with wooden roof bolts was mane in 1949 in the Rio Verde mine, Norton Coal Corp., Nortonville, Ky.2/ This experiment was successful; the company obtained excellent results, but operations in the mine were suspended before enough time had elapsed to prove the value of wooden roof bolts conclusively. It is obvious that, if wooden roof bolts could be used in place of steel bolts or conventional timbering-methods, every mine operator would use word, as the cost is only a fraction of the other two methods. The Stony Point experience has proved conclusively that, under certain conditions and with a certain type of roof, wooden roof bolts can be used successfully.

Jan 1, 1952

By Ted C. Briggs

A removable-jacket distortion apparatus was constructed and used to measure distortion coefficients for two high-pressure vessels. The measured distortion coefficients were used to compute distortion coefficients for volumes VI and (V1+V2) of a 1,000-atmosphere Burnett compressibility apparatus for the temperature range 0° to 75° C. Young?s modulus for Armco 17-4 PH stainless steel, heat treated to condition H1150-M, was computed from experimentally determined distortion coefficients. A 10-to 14-percent correction to the values obtained for Young's modulus may be required because pressure vessel end effects were neglected. The distortion coefficients of the compressibility apparatus are believed to be accurate to about 1 percent.

Jan 1, 1970

By O. P. Hood

The spontaneous combustion of coal lies at the bottom of the subject of storage. It is useless to store coal that is to be lost by fire from spontaneous combustion. Every engineer is familiar with the phenomena of the self-heating of coal, yet, for all that, spontaneous combustion is relatively rare. If we counted the times a portion of cod was stored where it would be undisturbed for a few weeks, the number of such storage operations in any one year would mount into the millions. Of these, a relatively small number show the phenomena of spontaneous combustion and time risk per ton is very small. It is extremely rare that in the smaller operations involving; only a few tons there is any heating. There is no spontaneous combustion of anthracite, and very rarely does the domestic consumer of bituminous coal find troublesome heating. The main interest in the subject lies in the large piles needed as reserves for public-service utilities, and the industries. Everyone desires to have directions for storage that are perfectly simple and yet will insure against loss. Unfortunately, the problem is too complicated for a simple solution. Many of the factors involved are difficult to determine, as we have no practical means of quantitative measurement. The factors involve chemistry, physics, and engineering, and the man who is

Jan 1, 1939

By Andrew Cecala

Miner?s exposure to dust remains a top concern among regulatory agencies, particularly at production facilities with high levels of silica. This respirable dust is present in almost all operations and is a direct cause of the deadly disease silicosis. Silica is one of the most abundant minerals on Earth and is a threat at all operations, especial-ly granite and sand and gravel facilities. The National Institute for Occupational Safety and Health continues to analyze silica?s threat. The institute?s research indicates that heavy-equipment operators have an increased risk to dust exposure, especially when drilling or breaking rock, even when working from an enclosed cab. However, there are methods to reduce an operator?s exposure further, according to recent NIOSH research, which is detailed in its report, Improving Air Quality in Enclosed Caps with Uni-Directional Filtration/ Pressurization System. NIOSH indicates that when surface mining equipment is new, the operator?s dust exposure is normally at accept-able levels. As the equipment ages and components such as gaskets and seals deteriorate, the level of protection can degrade to a point where it is no longer acceptable. However, the institute indicates that at least two critical factors necessary for an effective system.

Jan 1, 2009

By G. W. Jones

Phthalic anhydride is a solid having the formula C8H4O3. It is an important intermediary in production of anthraquinene, alkyd reins, and plasticizers. The combined annual production of phthalic anhydride reported by 10 major manufacturers for 112,250 tons. The raw materials in the manufacture of phthalic anhydride have been the source of numerous fires and explosions. Consequently, the need was felt to determine the temperature flammability and the ignition temperatures crude basic raw material in most phthalic anhydride production crude phthalic anhydride, and pure phthalic anhydride.

Jan 1, 1950

By W. H. Engelmann

The electrokinetic (zeta) potentials of a charcoal granite in an aluminum chloride (AlCl3) solution and in an oleylanunonium acetate (C18H35NH3+ -OCOCH3) solution have been correlated with the specific damping values as measured by the pendulum sclerometer. This investigation shows that the pendulum specific damping attains a minimum at the isoelectric point for the charcoal granite-aluminum chloride and charcoal granite-oleylammonium acetate systems, and thus indicates that the penetration of the diamond points is a maximum at the isoelectric point.

Jan 1, 1967

By Wm. W. Odell

A study of certain gas making and fuel problems peculiar to the gas industry of California has been made by the Bureau of Mines. The work was done at the request of, and in cooperation with The California Gas Research Council 2, for the purpose of obtaining basic information on the gas-making fuels available to California, and their applicability to the present and future needs of the gas industry in that State. The data obtained have been applied in outlining a construction program, and indicate the possibilities in efficiently utilizing fuels in making gas by other than the oil-gas process. This paper presents an outline of the study and a summary of the principal results obtained, with some of the more important conclusions and recommendations based on this data. Gas is produced in California by processes which are both unique and different from those common to other parts of the United States. The bulk of the manufactured gas is made in and distributed from two main districts which are centers of population - namely, the Los Angeles district and the San Francisco Bay district. The gas manufactured in the Bay district is, almost exclusively oil-gas, whereas that produced in the southern part of the State, where natural gas is available, is mostly mixed natural gas and reformed-gas, but oil-gas is the chief product when the supply of natural gas is inadequate. Practically all of the gas companies are equipped with oil-gas generating apparatus, and anticipate using it in the future. As the continued use of the oil-gas process to the exclusion of all other processes, depends upon a continued supply of oil at a low cost, and the prospect of obtaining such low-priced oil in the future is somewhat uncertain, the questions have arisen: What will the future gas-making process or processes be? When will it be necessary to make plans for the installation of different gas generating equipment, and what will that equipment comprise?

Jan 1, 1926

By R. A. Beall

Homogeneous zirconium-alloy ingots have been cast on a production basis by the consumable-electrode arc-melting process at the Northwest Electrodevelopment Experiment Station, Bureau of Mines, Albany, Oreg. This paper describes the various methods used to introduce alloying materials into the ingot and evaluates 1 each method by the degree of homogeneity of resulting ingots, as determined in tests on sections cut from the ingots. As many as 30 or more ingots, each 6 to 10 inches in diameter and weighing 300 to 500 pounds, were melted, using each method; and, as most of them subsequently were fabricated to strip 0.1 inch thick, the test results are considered to be representative of production practice. Ingot homogeneity has been considered more difficult to achieve in arc-melting practice than by methods where the molten metal is poured into molds and the addition can be stirred into the total mass of metal before casting. Owing to the unique requirements of consumable-electrode arc melting the addition can be made only to that part of the total mass of the ingot that is molten at one time. Observation of the flowlines in 500-pound ingots produced at Albany indicates that the molten pool has a maximum depth about equal to the ingot diameter. The weight of metal molten at one time is, therefore, not over 100 pounds. Characteristically, the arc-melting process is conducive to segregation, which can be overcome, at least partly, by adding the alloy constituents almost continuously during casting.

Jan 1, 1956

By M. M. Jones

Natural brines are potential domestic resources of minerals. The brines of Searles Lake, CA, for example, contain an estimated one-fourth of our current reserve of tungsten. A key to Bureau of Mines research to recover this critical mineral is the ability to quantitatively measure concentrations of particular constituents in the large number of brine samples and process solutions produced under a multiplicity of test conditions. This paper describes procedures used to determine arsenic, boron, phosphorus, silicon, and tungsten in these solutions by simultaneous inductively coupled plasma spectrometry. A variable in-ternal standard method was used to compensate for tungsten interference on the other analytes in tungsten concentrates, and matching standards were used to determine tungsten in raw brine. Other solutions were analyzed using normal techniques. Analytes were determined down to 1 mg/L with an average precision of 2.5 pet relative standard deviation. Accuracy, estimated using synthetic solutions and by comparison with values obtained by other methods, averaged about 2.5 pet. The methods were rapid, required little sample preparation, and provided the needed sensitivity.

Jan 1, 1985

By A. J. Miscoe

A unique machine for inducing bending fatigue in wire ropes was built at the U.S. Bureau of Mines' Pittsburgh Research Center. This machine can produce nine levels of degradation through repetitive cycling of long samples of wire ropes of the types used in the mining industry. This report provides an analysis of the results of the first wire rope to be fatigued on this machine. These results have indicated that as a wire rope accumulates bending cycles, its strength first decreases because of wear and then in-creases due to cold working of the wires. As the amount of cold working increases, more and more of the embrittled wires break and the strength of the rope decreases rapidly. In this test, application of several of the regulatory retirement criteria to various sections of the rope suggests that there may be some inconsistency among them.

Jan 1, 2010

By John P. Harmon

Vehicles traveling on untreated dirt and gravel roads at open-pit mines disseminate high concentrations of dust (fig. 1). Excessive dust creates safety hazards by reducing visibility and may endanger the health of the men who breathe it. If the dust contains free silica, it can cause silicosis. In addition, maintenance costs of mechanical equipment are increased if equipment is operated in extremely dusty places. Dust on haulage roads in hot, arid country can be controlled if the surface of the road is sprinkled frequently and adequately with water. Often, when roads are sprinkled with water to control the dust, hazards are caused through reduced traction and skidding because of the mud that is formed on the surface of the road. Reducing the amount of water used will help to reduce the hazard of skidding.

Jan 1, 1957

By G. B. Goodman, W. H. Pailes, P. D. Kaplan, I. Stachura, V. Castronova

"The risk of developing silicosis in underground coal miners, tunnel workers and some foundry workers is well-known. These persons generally develop the classic form of the disease over a prolonged period of time. Workers involved in abrasive blasting of bridges and those polishing tombstones have been reported to develop an acute form of silicosis within a few years of commencing exposure. Not well-appreciated is the potential for development of acute silicosis among drillers at surface coal mines. We report the case of a 33-year--old man who worked primarily at surf ace drilling, developed acute silicosis within three years of beginning exposure, and who initially responded dramatically to corticosteroid therapy. CASE REPORTThe patient is a 33-year-old white man who worked as a rock driller at a quarry and also at surface coal mines in western Pennsylvania since 1975. Prior to 1983, much of his work was done with a wet process in which water was applied to reduce dust generation. After 1983 he worked primarily as a driller at a surface coal mine using a dry process. He never wore a respirator. He described the dust as being so dense that he ""couldn't see anything.- In August 1986, he presented to his local physician with a complaint of pleuritic chest pain and shortness of breath. A chest x-ray film was obtained showing only a few p and q opacities. He continued working and these symptoms subsided, but the patient noted the onset of progressive weight loss. By May 1987, he had lost approximately 50 lb. In addition, he suffered profound malaise, dyspnea, migratory chest pain and arthralgia, fevers and drenching night sweats.A course of erythromycin therapy given in the hospital resulted in only fleeting improvement. Studies for Legionella and Mycoplasma infections were negative, as was a tuberculin skin test. The patient was transferred to Allegheny General Hospital in Pittsburgh on June 4, 1987.There was no history of serious medical illness, including tuber¬culosis. The patient admitted to smoking between I and 1 1/2 packages of cigarettes daily for 2 1/2 years prior to May 1987 when he stopped smoking. He denied intravenous drug abuse, homosexual activity or receiving transfusions of blood or blood products.On physical examination the patient was a thin, febrile white man who appeared chronically ill. Bilateral axillary and cervical lymphadenopathy was present. Chest examination showed restricted expansion and bilateral crackles. Examination of the heart and abdomen disclosed no abnormalities."

Mar 1, 1992

By D. N. Nilsen

The Bureau of Mines is developing a method to recover Ni, Co, and Cu from laterites containing less than 1.2 pct Ni and 0.25 pct Co. The method consists of the following basic unit operations: (1) reduction roasting, (2) leaching, (3) solvent extraction, and (4) electrowinning. The method reflects three Bureau of Mines objectives: (1) recovery of critical minerals that are domestically in short supply from low-grade domestic laterites, (2) lower processing energy requirements, and (3) solution recycling. This report deals with the extraction of cobalt and the preparation of a suitable cobalt electrolyte by solvent extraction from liquor produced by this method. Nickel and copper are coextracted with LIX64N from an ammoniacal ammonium sulfate leach liquor containing about 1.00 g/l Ni, 0.30 g/l Co, 0.03 g/l Cu, and 0.02 g/l Zn. Cobalt (III) in the nickel-copper barren raffinate is reduced to cobalt (II) with cobalt metal. Reduction of cobalt (III) to cobalt (II) greatly aids subsequent extraction. Commercially available XI-51 extracts about 94 pct of the cobalt from the treated raffinate in one stage in a laboratory mixer-settler continuous circuit. Ammonia loaded on the solvent is removed in two washing steps. About 94 pct of the cobalt then is stripped from the XI-51 in one stage with spent cobalt electrolyte containing about 77 g/l Co and 18 g/l sulfuric acid (H2S04), Electrolytes containing less H2S04 also may be used. Preliminary data indicate that coextracted zinc may be removed from pregnant cobalt eletrolyte containing 3 g/l or less H2S04 with di-(2 ethylhexyl) phosphoric acid (D2EHPA).

Jan 1, 1980

By L. G. Marshall

The geology, mining, beneficiating, types of products, and costs in terms of percent of total costs and of labor, power, and supplies of two crushed-limestone operations in Madison County, Iowa, are described in this paper. The operations are basically similar, differing in refinements in mining, product types, and markets. The operations are comparable as to personnel and as to weighted costs in terms of percent of total costs and in terms of man-hours, power, and sup-plies. The waste-to-stone stripping ratio is 1 to 0.8 at both operations, the powder factor is 0.29 pound of explosives per ton of stone, and daily production is 95 tons per man-shift. Both companies use crawler-mounted diesel shovels for loading, truck transportation, wagon drills, and dry screening.

Jan 1, 1963

By L. G. Marshall

The geology, mining, beneficiating, types of products, and costs in terms of percent of total costs and of labor, power, and supplies of two crushed- limestone operations in Madison County, Iowa, are described in this paper. The operations are basically similar, differing in refinements in mining, product types, and markets. The operations are comparable as to personnel and as to weighted costs in terms of percent of total costs and in terms of man-hours, power, and supplies. The waste-to-stone stripping ratio is 1 to 0.8 at both operations, the powder factor is 0.29 pound of explosives per ton of stone, and daily production is 95 tons per man-shift. Both companies use crawler-mounted diesel shovels for loading, truck transportation, wagon drills, and dry screening.

Jan 1, 1963

By A. J. Keast

This circular is one of a series dealing with the exploration, equipping, and development of mining properties, prepared and published by the United States Bureau of Mines in cooperation with various mining and exploration companies in the United States and Canada. This series of papers will supplement an earlier one which covered the methods and costs of mining and milling at a large number of producing mines. The present paper describes the exploration, equipping, and developing of a group of 18 claims remote from rail transportation, and the transport of equipment and heavy supplies for a distance of 120 miles by tractor over ice and winter roads, and of men and lighter supplies by airplane.

Jan 1, 1933