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By L. R. Burdick

This paper presents a review of published investigation dealing with the importance of sulfur compounds in the deterioration of materials or providing some basis for estimating the extent of loss shareable to such air pollution. Materials included are cement, stone, metals, paint, leather, paper, sand cloth. The investigations may be divided into two classes, one of the laboratory type in which the sulfur content and the humidity of the air were controlled and the other dealing with the exposure of materials to atmospheres not under control. The first type of work has shown that cement is subject to deterioration by the action of sulfur dioxide gas. The experiments with stone indicate that although limestone takes up sulfur dioxide, from the air, moist sulfur dioxide-air mixtures alone cannot be used for establishing- the comparative weathering- qualities of the different types of stone by accelerated test methods. Laboratory tests indicate that sulfur compounds in the air accelerate the corrosion of iron, steel, zinc, copper, and nickel at normal air temperatures and at certain relative humidities. It has also been indicated that certain types of paint are, affected by high sulfur dioxide concentrations, and that paper is attacked by sulfur dioxide in the atmosphere. The investigations of the second type show the amount or variation of corrosion in different localities and under different types of exposure. The investigations (10) (18)4/ during which sulfur determinations were made indicate that sulfur dioxide is a main controlling factor in the corrosion of iron and steel but according to Quick (18) may not be for some nonferrous metals. In general, the laboratory tests do not Jive definite data on the loss due to sulfur compounds at the concentrations normally found in the air. The data from atmospheric exposures are not complete from the standpoint of the exact effect of the sulfur compounds. Damage to materials so exposed is affected by factors such as other chemical contaminants, humidity, rainfall, solid deposits, and sunlight. A simple scheme has been devised in Great Britain which is considered to provide a measure of the attack of sulfur compound, on building materials (1). Small cylinders coated

Jan 1, 1939

By Paul T. Allsman

The Salt River range vanadium deposits are situated 3 to 6 miles east and southeast of Afton, Lincoln County, Wyo. The vanadium occurs in a continuous bedded shale zone of the Phosphoria formation extending from the vicinity of Afton into southeastern Idaho. The Bureau of Mines explored several of these vanadiferous-shale deposits between December 1942 and December 1943 and conducted metallurgical tests on the ores. The areas investigated were west Swift Creek, the Dry Creek, and the Cottonwood Creek. The vanadiferous-shale beds have been folded sharply into a series of tightly compressed, eroded anticlines and synclines, which form the Salt River range. The vanadium occurs in a series of narrow shale or mudstone beds contained within the phosphatic-shale member of the Phosphoria formation. Exploration by the Bureau of Mines consisted of surface trenching and underground work over 18 miles of outcrop of vanadiferous shale with an average assay value of 0.866 percent V2O5.

Jan 1, 1949

By John W. Buch

At a meeting of the Anthracite Investigations Advisory Committee in July 1944 at Washington, D. C., the initial work and objectives of the Anthracite Mechanical Mining Section of the Federal Bureau of Mines were discussed. It was learned that interest existed in an improved performance of mining thin, steeply pitching beds above the gangway by mechanical methods. One company offered the use of one of its mines for experimental work, and this offer was accepted. Following acceptance, an effort was made by Bureau engineers to devise a mechanical method with a performance better than that of a new hand method proposed by company engineers for an actual mining condition. The method proposed by the Bureau was to drive 30-degree slant chutes across a 10-foot bed pitching 85 degrees. These chutes were to be advanced by using a lightweight, compressed air-powered, shearing machine of German origin that had been tried in a flat Pennsylvania anthracite bed in 1934, and which did not then prove successful because of blasting difficulties. An attempt was made to obtain one of these machines from England, where it was known machines of this type had been used. Shortly thereafter John W. Buch was sent to Europe as a member of the Solid Fuels Mission to the European Theater of Operations organized by the Technical Industrial Intelligence Committee of the Joint Chiefs of Staff. Through his efforts the Bureau of Mines obtained two such machines, known as the Eickhoff model DEK, one from England and one from Germany. This report covers the preliminary testing of these machines in order to obtain mechanical operating data for use in determining the power requirements for cutting anthracite with machines of this design.

Jan 1, 1949

By L. G. Trudell, J. W. Smith, K. E. Stanfield

Oil- yield data are presented for 40 sets of core samples and 83 sets of drill cuttings collected in 1952-62 from drilling operations in the Uinta basin of eastern Utah . This accumulated information on the location , extent , and richness of oil shales of the Green River formation is used to appraise the deposits as a source of oil and related products . Core samples used in the study were obtained specifically for evaluating oil shale , and they were satisfactory for this purpose , except they did not completely penetrate the formation . The drill- cutting samples were inferior to the core samples and yielded more erratic results . Consequently, oil yields based on cuttings should be regarded as indicative , rather than definite , until substantiated by other means . In general , the oil- yield data indicate Green River oil shale in Uinta basin is not as thick or as uniform as that in the Piceance Creek basin of western Colorado . However , it is an important potential source of oil . Estimates that beds 15 feet or more thick that average 25 gallons of oil per ton represent at least 120 billion barrels of oil in place are supported by the recent oil- yield data .

Jan 1, 1964

By Larry D. Nichols

Poroplastic membranes containing ion exchange liquids were studied for separating cobalt from nickel-containing solutions similar to ammoniacal laterite leaches. The driving force for cobalt transport was differences in pH and composition between the leach and extraction streams. Using a diketone ion exchange liquid, a leach pH of 6.5 to 7.0, and a strip pH of 2.3, cobalt was extracted from a 750 ppm solution containing 2500 ppm of nickel at rates ranging from 1 to 10 µg/cm2 .min in single membrane cells, and from 10 to 100 in more closely spaced multiple membrane cells. Rates were variable, with evidence that cross -membrane flow pasterns were a key factor; a reproducible rate of 30 pg/cm .min would be economically viable. Loss of transport observed after several days of continuous operation was restored by flushing membranes with fresh ion exchange liquid. A major effort was devoted to preparation of thin, leak-free membranes; the resulting membranes endured operating conditions without mechanical failure.

Jan 1, 1982

By M. J. Lempel

A theoretical study of the heat-transfer characteristics of a dilute gas-solids mixture in an externally heated tube is reported. Detailed equations are developed describing the system, and a numerical method is presented to solve the equations using a digital computer. The methods are applied to a system containing fine coal particles entrained in hydrogen, flowing through a hot tube. Heat-transfer coefficients and several other physical constants are evaluated in detail.

Jan 1, 1967

By Robert L. Rough, William E. Eckard

Laboratory data obtained from a Bureau of Mines rotary air core of a well near Sugar Grove , Warren County , Pa . , were instrumental in initiating hydraulic fracturing in the area to stimulate oil recovery from Glade sand oil reservoirs . This report outlines the general geology , lease development , reservoir- rock characteristics , and oil - production history of Glade and Clarendon sand reservoirs in Warren County . The methods of well completion for single- stage and multiple- stage hydraulic fracturing of old and new wells are discussed , and a range of hydraulic fracture treatment data from 29 Glade sand and 10 Clarendon sand wells is presented . A composite decline curve representing oil - production data from six wells shows probable results of hydraulic fracturing . Average cumulative oil production during the first 100 days after hydraulic fracturing with a sand - carrying liquid is compared with production after conventional shooting with liquid nitroglycerin .

Jan 1, 1964

By Fieldner. A. C.

"In preparing this paper, an attempt was made to obtain results of plant-scale carbonization tests on washed and unwashed coal tram to same mine. A letter. in which the following questions were asked, was sent to some 50 coke-oven superintendents and others who might be interested:“What is the influence of washing coal on:(1) The chemical and physical properties of coke, as for example, the size, the amount of breeze, the fracture, strength, cell-structure, etc.(2) The quantity and quality of gas and by-products.(3) The capacity of the ovens.(4) The composition of the coal..""Your general opinion, as well as any specific data or results of testa, on this important subject will be greatly appreciated.""Of the 45 replies received, 24 stated that they had never used washed coal; 11 had used washed coal but had no comparative data on similar coals washed and unwashed; 7 answered some of the questions based on their general experience; and 3 gave some test data on Pittsburgh bed coal from western Pennsylvania. In none of the three tests did the washed coal come from the same mine as the unwashed. The washed coals in the three tests were from the same washery - one of modern construction in which the operations are under careful technical control in order to give a uniform product containing a minimum of surface moisture. The unwashed coals which were previously used in these plants were from different nearby mines in the same coal bed, and were supplied by the same company. Obviously, no sweeping or finale conclusions can be drawn from these few tests on coal from a single washery. Therefore, the writer vas obliged to consult the literature, coal-carbonization and coal-washing engineers, and other authorities to supplement the fragmentary information gleaned from the questionnaires in order to present a picture of chat gas engineers may expect from the use of washed coal in a carbonizing plant."

May 1, 1930

By Frank G. Horino

The Bureau of Mines studied the uniaxial compressive strength of model rock pillars as a function of the angle and spacing of noncohesive planes of weakness. The model pillars were prepared from NX 2-l/8-inch diameter drill core of limestone, sandstone, and granite, and the planes of weakness were diamond saw cuts ground flat and smooth. The angle of the planes of weakness, measured from the horizontal, varied from zero to 57° in approximately 15° increments. When two planes of weakness were used, the thickness-to-diameter ratio of the wafer was 1/4, 1/2, and 1, Approximately 400 model pillars were tested in uniaxial compression. The results indicate that the uniaxial compressive strength of model pillars decreases rapidly as the angle of the plane of weakness increases from 30° to 57°, and that the spacing of these planes of weakness has only a minor effect on the strength. The effect of the number of horizontal planes of weakness, with a spacing of 1/4 and 1/2 of the diameter, upon the compressive strength of model pillars was also investigated. These results indicate that as the number of planes of weakness increases the compressive strength of the pillar decreases. Normalizing the data provides useful estimates of model pillar strengths for any rock type.

Jan 1, 1968

By Michael S. Miller

In 1985, at the request of the Bureau of Land Management, the Bureau of Mines studied a 50,57U-acre portion of the 90,345-acre Twin Peaks Wilderness Study Area (CA-020-619A) in order to evaluate its identified resources. The area studied is located about 45 miles northeast of Susanville, CA, in Lassen County, CA, and Washoe County, NV. The area is underlain by Tertiary volcanic, volcaniclastic, and intrusive rocks. Quaternary stream, lake, and landslide deposits overlie the older rock. There are no mines or mining claims in the study area. One mineral resource, pozzolan, was identified. Mining claims, inactive in 1985, have been staked adjacent to or near the northwest corner of, and also southeast of, the study area. Examination and sampling of 17 mineralized sites, delineated mostly by prior geochemical surveys, showed at least 30 million tons of subeconomic pozzolan resources and small or low-grade occurrences of gold, silver, copper, lead, zinc, nickel, molybdenum, zeolites and clay.

Jan 1, 1986

By Craig S. Compton

The failure of the immediate roof or "roof skin" between installed primary and secundary roof supports causes hundreds of injuries and, on average one or two fatalities each year in U.S. underground coal mines. Conventional roof supports cannot cover enough roof area to adequately control these relatively small, but very dangerous rock falls. The 2006 Mine Safety and Health Administration (MSHA) accident database lists a total of 542 ground fall injuries, including 10 fatalities. An analysis of the database suggests that 434 of the injuries and three of the fatali­ties can be attributed to roof skin falls (See Figure 2). The key to controlling falls of the immediate roof or roof skin is maximizing the area of roof coverage ilnd confining these relatively small loose rocks. Roof screen offers maximum coverage of the immediate roof. Depending on the size and configuration of the screen panels, coverage of up to 100% of the roof area is possi­ble. Screen also offers a first line of defense for machine operators working in the face area by confining or deflecting small rocks that can come loose during mining or roof bolt installation. Figure 1 shows an example of the protection screen provides dur­ing bolt installation. Although the benefits of screen are well-known, mining com­panies in some areas of the U.S., mainly Northern Appalachia and the Illinois basin, are not convinced that roof screen is the best tool for dealing with roof skin control issues. The logistics of material handling, possible ergonomic injuries to workers, and the costs associated with installation are delaying the acceptance of screen as an on-cycle roof support tool. Other mines however, have concluded that installing roof screen can be cost-effective when compared to the cost of lost time accidents, training of replacement workers, or returning to already developed entries for the cleaning and rebolting process.

Jan 1, 2009

By A. W. Fahrenwald

Coarse sand flotation, both alone and in conjunction with gravity concentration, is a subject of research at the U. S. Bureau of Mines Field Office, Moscow, Idaho. One of the most important results of this work which is being carried out in cooperation with the University of Idaho, has been the development of a concentration process embodying flotation, classification, and tabling, in the order named. The flow sheet of the process is given in Figure 1. The type of feed desired for this process is coarser than is common in present "all flotation" practice, and is about the size of table feed.

Jan 1, 1929

By H. B. Brunot

One of the many difficult problems that confront the present day coal-mine operator is the safeguarding of his employees and property from disasters such as fires, explosions, squeezes, and inundations. Those operators having gaseous or ev en dusty mines have a double responsibility resting upon them in this respect. The introduction of electrical machinery and appera tus in mining operations has been very rapid, and at the present time it is difficult to mention any kind of mining work in which electrical machinery is not used. This extended introduc- tion of electrical equipment has added not a little to the mine operators' safety problem, and it is the desire of the United States Bureau of Mines to aid the mine operator, and the inspection departments having jurisdiction, in solving their electrical safety problems. With this idea in mind, the Bureau has prepared and published schedules setting forth the qualities it considers essential to the safety of various classes of mining equipment, and the conditions under which it will test and give the stamp of its approval to satisfactory designs. Portable electric lamps of the permissible* type are almost universally used in gaseous mines, but the use of permissible electrical machinery has not been so widespread. Until recently the Bureau had issued approvals for only one class. of machinery involving the use of electric motors that is, permissible coal- cutting machines. However, the day is undoubtedly not far distant when the operator, who so desires, will be able to obtain a permissible room hoist, pump, or coal- loading outfit. During the year 1921 the first of a growing list of storage-battery locomotive approvals was granted by the Bureau, and it is with considerable satis- faction that the Bureau how announces the approval of a third class of motor equip- "merit- namely, slectric drills.

Jan 1, 1923

By Peter D. Lohn

The Bureau of Mines conducted both laboratory and field investigations to study the effectiveness of medium-pressure (up to 30,000 psi) water jets in controlling the generation of airborne respirable dust during the hydraulic fragmentation of coal. Laboratory studies were conducted at the Farmington High Energy Test Site of the Twin Cities Mining Research Center, and field studies were carried out at the Humphrey No. 7 mine, Mount Morris, Pa., in the Pittsburgh coalbed. The water jets were produced by commercially available triplex pumps. The dust samples were collected by midget impinger samplers, and analyzed by electronic and optical counting techniques. Respirable dust concentration for a full-scale production model was projected at below 2 mg/m3, the maximum exposure allowed by the Federal Coal Mine Health and Safety Act of 1969.

Jan 1, 1975

As part of its regular program to provide timely information on domestic mineral commodities, the Bureau of Mines conducted an engineering appraisal of more than 1,300 lode and placer gold deposits in the United States to deter-mine their gold production potential. While these deposits were estimated to contain over 400 million ounces of gold, only 9 million ounces, or slightly more than 2 percent, was found to be producible at $35 per ounce under prevailing mining and metallurgical technologies. The study revealed that any significant increase in available gold in the United States is most likely to come from the discovery of new sources, intensive exploration and development of the more promising known mineralized areas, and development of new or improved mining and metallurgical techniques.

Jan 1, 1967

By Victor Kalcevic

A gas-flow retort for thermal processing of oil shale to recover shale oil was developed by the Bureau of Mines at its Oil-Shale Demonstration Plant, Rifle, Colo., from 1948 to 1952. The retort is a crossflow gas-to-broken-solids heat exchanger. The heating medium is the gas produced in the shale retorting process. The gas is heated in specially designed stoves outside the retort and recycled to the retort. Oil shale from the Mahogany ledge section of the Green River formation in northwestern Colorado was the material processed. Indicated maximum oil recoveries for 20-to 25-gallon-per-ton shale in a l2-inch-thick shale bed and a 20-inch bed are 96 and 91 weight-percent of Fischer assay, respectively. Heat requirements for maximum recovery are 600 to 750 B.t.u. per pound of shale. Properties of the recovered shale oil are affected slightly by shale-bed thickness and extent of retorting. Oil recovery from oil shales assaying over 30 gallons per ton is lower than that from leaner shales.

Jan 1, 1959

By W. J. McConnell, C. P. Yaglaglou

"IntroductionThis paper on the kata thermometer is issued by the Bureau of Mines on account of the general interest in this instrument and the fact that it is frequently used in studies of mine ventilation conditions with regard to comfort and health of miners. It has been used in the studies being conducted along this line by the Bureau of Mines on the effects of high temperatures and humidities of air in mine working on the comfort conditions, as well as in studies of atmospheric conditions in mine, railway and vehicular tunnels.The study of the various physiological responses of the human body to different degrees of temperature combined with different percentages of relative humility in still and in moving air, now being conducted at the Pittsburgh experiment station of the bureau in the research laboratory of the American Society of Heating and Ventilating Engineers, cooperating with the Bureau of and the U. S. Public Health Service, presents an added opportunity of investigating the instruments that have been devised to measure atmospheric conditions as they affect the comfort and health of human beings.The ordinary mercury thermometer, as pointed out by Heberden3 almost hundred years ago is a very inadequate instrument for measuring the physiological effects of atmospheric conditions. It merely accounts for that part of the body heat lost by raliation and convection, while as a matter of fact greater part of the body heat resulting from the metabolic process within the body is eliminated by means of evaporation from the surface of the body."

Jan 1, 1924

By Boyd Guthtrie

[Methods of distilling topped crude oils and distillates under vacuum, accompanied by good fractionation, have taken a place of major importance in the refining industry. In the refining of petroleum products it is generally desirable to produce a distillate of good quality, and this objective is attained by fractionation of a high degree. The laboratory and commercial practice have proved chat by varying the amount of fractionation the quality of the distillate car be changed, and refiners are cognizant of the advantages of good fractionation. Distillation-under high vacuum, however, is a relatively new practice in petroleum refining, and only during the last few years has there boon an indication that that this method ray become a general practice in the industry. Vacuum distillation offers many advantages over older methods of distilling petroleum products. Vacuum combined with steam distillation, for example, is replacing straight-stream distillation because the quality of the products of vacuum and, steam distillation surpasses that of those produced by straight-steam distillation. Although the injection of varying amounts of steam in a vacuum unit is common practice, the amount of steam used is becoming less as the vacuum within the unit is increased. This report describes tie construction of a visible-action laboratory batch still and fractioning; column and. gives curtain data pertaining to the operation of the apparatus under vacuum for the production. of lubricating distillates. The apparatus was designed and built to produce lubricating distillates under as nearly ideal conditions as possible, in order that a subsequent study of the characteristics of the distillates could be made.]

Jan 1, 1932

By L. C. IlsLey

Investigations for safety of electrically operated mine equipment, safety lamps, and gas detectors are made at the Pittsburgh Experiment Station in accordance with published regulations termed "schedules." These schedules are revised from time to time, not only to keep in step with the progress of the industry, but also to permit much freedom of design as possible without lowering standards of safety. The following schedule covering electrical equipment, safety lamps, and gas detectors are now active: Schedule 2D. Explosion-Proof Mine Equipment. Requirements for Approval of of Storage-Battery Locomotives and Power Tucks, Junction Boxes, and Electric Motor-Driven Equipment.

Jan 1, 1939

By J. M. Stuve

Thermodynamic properties were determined by the Bureau of Mines for the intermetallic compound, TiA13. Heat capacities were obtained from 5 to 303 K by adiabatic calorimetry. The derived value of S2 1s is 22.08±0.07 cal/deg¬mole. Enthalpies relative to 298 K were obtained from 298 to 1,413 K by copper-block drop calorimetry. No anomalous thermal behavior was noted in the temperature ranges investigated. Low- and high-temperature data were combined with a known enthalpy of formation at 298 K to give values of enthalpy of formation and Gibbs energy formation, 0 to 1,400 K.

Jan 1, 1974