Search Documents

By T. A. Henrie

A technique was devised for measuring the rate of chemical reactions between reactive metals and molten-salt mixtures at high temperatures. The rate of the heterogeneous reaction between high-purity titanium metal and titanium trichloride in molten sodium chloride was determined. The reaction is surface-controlled, and the heat of activation is 8.29 kilocalories per mole TiC13. An active site or reaction nuclei is created by adsorbing a TiC13 molecule at the metal surface. Reaction of the second TiC13 species forms an activated complex that decomposes into three TiC12 molecules.

Jan 1, 1963

By Alton B. Cook

The practice of using partly depleted oil reservoirs for gas-storage operations is proving successful. Moreover, this practice provides a method of secondary oil recovery when gas is cycled at full-storage reservoir pressure. Because of the relative newness of this operation, a study was undertaken to assist engineers in developing improved gas-injection and production procedures and in calculating the amount of gas needed for completely repressuring reservoirs. This paper is the third in a series reporting the progress of a study by the Federal Bureau of Mines of reservoir performance during complete gas repressuring and gas cycling. A procedure for estimating secondary oil recovery by this method is also under study. One report (7)3/ describes the laboratory equipment. The other report (8) gives (1) data on the New York City field, Clay County, Tex., which has been converted to gas-storage operations; (2) laboratory data from research with a model oil reservoir, in which primary production, complete gas repressuring, and gas cycling for the New York City field were simulated; and (3) theory to explain reservoir performance during gas repressuring.

Jan 1, 1961

By J. R. Boyle

The Bureau of Mines developed cost estimates fur the disposal of phosphate rock washer slimes by pond settling, from a study of the method used at the International Minerals a Chemical Corp., Moralyn Phosphate Operations, Polk County, Fla. Data were obtained by basing phosphate production and slime generation statistics on plant capacity rather than on actual company records. Cost estimates, which were prepared as a guide in evaluating alternative disposal methods and in identifying needed areas of research, could be applicable to any Florida plant using the same disposal method. To conserve mineral resources and to improve environmental conditions, the Bureau recommends further research directed toward developing alternative methods of disposal, including the recovery of water and P205 values from the slimes.

Jan 1, 1969

By Rustu S. Kalyoncu

Nonoxide ceramics with improved high-temperature properties could substitute for high-temperature alloys and reduce toe Nation's dependence on imports of Cr, Co, Ni, and Mn. To meet this objective, the Bureau of Mines conducted research to synthesize u1trafine reactive boron nitride (BN) powders BN powders were prepared at temperatures ranging from -75? to 750? C. Low-temperature reactions (-75? to 200? C) between boron halides and N compounds led to formation of e1emento-organic compounds that were thermally decomposed to u1trafine (approximately 100-to 150-A particle size) reactive BN powders. BN powders were also prepared through the reaction of a 10w-me1tinginorganic B compound (boric acid, borax) with an organic N compound (carbimide and thiocarbimide) in N2 and/or ammonia (NH3) atmospheres at temperatures between 500? and 750? C.

Jan 1, 1986

By M. E. Tyrrell, C. W. Houck

Mixtures of zirconium diboride and refractory metals of group VI were resistance sintered to high - density compacts using modified electric welding equipment . To evaluate the use of chromium , molybdenum , or tungsten as binders for zirconium diboride the sintered compacts were examined in polished sections and tested for crushing strength , hardness , microhardness , oxidation rate , and resistance to mechanical shock . Chromium yielded the highest compressive strength , the greatest resistance to mechanical shock and oxidation , and a satisfactory Rockwell hardness . Molybdenum did not yield a satisfactory cermet . Tungsten yielded compacts having high microhardness but very low mechanical strength .

Jan 1, 1964

By Steven R. Ruggieri

This report documents the work performed and the results obtained during the field demonstration of the Remote Sealing System at the USBM's Jenny Mine near Inez, KY in the Fall of 1978. Although various portions of the Remote Sealing System had been used on a number of prior occasions, the field demonstration at Jenny Mine marked the first use of the complete upgraded system including the use of the inert gas generating system for seal placement and the first application of the new froth foam system. The objective of the field demonstration at Jenny Mine was to demonstrate the complete system by emplacing and evaluating several complete underground seals under conditions representing those of a mine fire situation. Several critical sealing conditions were identified including: ? High entry airflow ? Standing water (1 to 2 ft) in the entry ? Flowing water (150 gal/min) ? Irregular roof ? Sealing a 4-way intersection. Four seals were successfully placed under the conditions mentioned above. The demonstration served to verify proposed techniques to handle these conditions as well as to dispel any doubts about the system's capabilities. As a result of the successful field demonstration, the Remote Sealing Equipment is now under the jurisdiction of MSHA's Mine Emergency Operation ready for a mine fire emergency.

Jan 1, 1980

By C. C. Stevenson, Thomas Varley

"The art of treating ores by the chloride volatilization process is still in the experimental stage. The process has not been sufficiently developed along chemical and metallurgical lines to state definitely just what place it will occupy in the metallurgical industry. The theory upon which the process operates has received the attention of prominent metallurgists for the past twenty years, and research and experimental work has been conducted by many investigators.Much of the experimental work done has never been published, and it seems that the accumulation of such results if made known would be an important aid to the further development of the process. The object of this paper is, therefore, to bring salient features of the process to the attention of the metallurgical industry, both for the purpose of furnishing information, and receiving from interested parties any comments which the reading of this article may suggest. A bulletin covering the work done at the Intermountain experiment station of the U. S. Bureau of Mines, situated at Salt Lake City, Utah, is in course of preparation.The chloridizing roast is usually accompanied by appreciable losses due, to the volatilization of the metals as chlorides during the roast, these losses often running as high as 30 per cent, depending upon the temperature, the character of the ores and the associated gangue material. It was not until 1891 that Croasdale, (Croasdale, Stuart, Engineering and Mining Journal, Aug. 29 1903) by observing this and stack deposits from the chloridizing roast, recognized the possibility of making volatilization a major instead of a minor feature of the roast. He then made tests on a large number of tires from different, localities, the result of which showed the, general application of the process. The main difficulty, as stated, by Croasdale, was the lack of a suitable means for recovering the fume from the furnace gasesIn 1913, Cottrell (See Mining and Scientific Press, March 29, 1913; alsoTrans. American Institute of Mining Engineering, September 1918. (Additional informa-tion is available from the owners, The Research Corporation of New lark, and Western Precipitation Co., .Los Angeles, Calif.), announced his invention of the electrostatic precipitator, which solved the problem of separating the solids from the furnace gases."

May 1, 1921

To evaluate the effectiveness of dust collector bags for reducing dust liberation from a roof bolter dust collection system.

Jan 2, 2007

By R. V. Higgins

In a recent report3/ the authors presented a rapid method of calculating, by means of a desk calculator, the future performance of oil reservoirs in which the motivating agent was gas. The accuracy of the method was tested by data obtained from an electronic computer. Because of the accuracy obtained for the limited number of calculations performed, considerable interest has been expressed in the electronic computer program used to obtain the comparative data by an analytical solution. Accordingly, the computer procedures for the analytical solution are presented in this report. In an earlier report, 4/ a reservoir appraisal procedure was published in which an iterative method was used. Many requests were received for the computer program used to obtain the values given in that paper. That program, with some modifications, also is presented in this report. The modifications are given because of the progress that his been made in computers, and because much of the program for the analytical solution is usable for the iterative procedure.

Jan 1, 1960

By Edwin M. Murphy

Methods are described for filling underground cavities remotely with dry material pneumatically injected through a borehole to seal openings, prevent air movement, and reduce subsidence; this often brings underground fires under control by limiting the access of air. Large-scale tests were made in the Bureau of Mines Experimental Coal Mine, Bruceton, Pa., in an operating mine, and in an abandoned Pennsylvania mine. Supplemental trials were made aboveground in galleries and in the laboratory. The parameters studied include horizontal and inclined passageways, obstructions in the entry, water leakage into the borehole, dry material, and grout and slurry mixes. The materials studied were fly ash, crushed and pulverized limestone, and sand. Best results were obtained with dry fly ash, though satisfactory seals were obtained with the other materials. When a borehole is dry and ends at an open void, casing is not necessary. If more than 5 gpm of water flows in the borehole, if the void contains loose debris, or if coarse material is injected, a material feedpipe should be inserted through the borehole. Fly ash was most suitable for remote filling because of its low angle of repose (8°) and its good flow characteristics. The depth of borehole through which the fly ash is injected has no appreciable effect on the filling operation.

Jan 1, 1968

By Gerald W. Elger

This report describes development of the fusion-leach crystallization precipitation process for producing a hafnium content feed material for hafnium-zirconium separation plants. Mixtures of zircon, potassium silicofluoride, and potassium carbonate (or potassium chloride) were fused to prepare soluble potassium zirconium hexafluoride-potassium hafnium hexafluoride salts. High extraction of these salts was obtained by countercurrent leaching the fused material in dilute hydrofluoric acid. About one-half of the hafnium was recovered in hafnium-enriched mother liquor by cooling clarified lead: liquor to crystallize most of the zirconium salt. Additional hafnium was recovered from the primary crystals in a multiple dissolution-recrystallization step. Hafnium-enriched oxides having a hafnium-zirconium ratio of more than three times that of zircon were precipitated from the combined mother liquors. The hafnium and zirconium recoveries in the precipitate were 83 and 24 percent, respectively. About 71 percent of the zirconium and the remainder of the hafnium were recovered in potassium zirconium hexafluoride crystals of low-hafnium content.

Jan 1, 1966

By D. J. Bauer

The Bureau of Mines has conducted extensive studies on the recovery of alumina from kaolinitic clay by a HCI leaching-HCI sparging process. The current study reports a modification of the process, which involves a double-leaching system. The first leach of the calcined clay is made at as high a HCI acid strength as possible so that the dissolution of aluminum chloride hexahydrate (AlCI3*6H20) is suppressed, Most of the impurities, but very little aluminum, are soluble in the strong acid. After liquid-solid separation and washing, the solids are leached with recycled weak HCI, which dissolves the AICI3'6H2O. The pregnant liquor is separated from the gangue, and AICI3'6H2O is crystallized from solu-tion by injecting HCI gas. A proposed flowsheet is presented, and the effect of bleedstream size on AlC13'6H20 purity is discussed.

Jan 1, 1984

By G. Richards Gwinn

The mineral graphite, a form of carbon, has been known for hundreds of years, and, was first used commercially as a coloring agent. Its true identity, however, was not recognized until the end of the eighteenth century, and its commercial development did not become extensive until near the close of the ninteenth century.

Jan 1, 1943

By S. H. Ash

[On December 2, 1932, the Governor of California called upon the representatives of the mining industry of the State to attend a meeting at Sacramento to discuss ways and means of assisting is relieving some of its perplexing and extremely distressing problems, particularly the mounting cost of accidents which faces the industry with an industrial insurance rate for classification of $11.85 per $100 of pay roll, effective January 1, 1033. The significance of this fact is at once apparent when it is realized that the classification rates per $100 of pay roll for mining have steadily increased for some time, as follows: $3.91 in 1924, $5.54 in 1925 and 1926, $8.04 in 1927, $8.53 in 1928, $9.05 in 1929, $9.42 in 1930, $10.54 in 1931, $10.99 in 1952, and $11.85 in 1133. In other words, the cost rates have acre than doubled, wile statistics indicate that the accident rates nave shown an entirely different trend. At the meeting mentioned, one of the management officials sounded an effective keynote when he declared that a spade should be called: a spade. The perplexing problems of any industry can be approached best and remedies applied if that policy is kept to the front. It is appropriate to mention that high accident rates and a decrease in wages in recent years have unquestionably accounted in part for a unit cost rate, on a pay-roll basis; it also is well to explain that the policy years3 1926 to 1930, inclusive, are the years on which the accident-cost experience for 193: is based. That accident rates :lave not undergone the expected beneficial chance in California's experience is apparent in the words of a Bureau of Mines report:4]

Jan 1, 1933

By Ronald H. Church

The Bureau of Mines tested & ground penetrating radar (GPR) system in the central Florida phosphate district. to determine the feasibility of utilizing GPR technology for subsurface cavity detection. The test area is located in karst topography where sinkhole development is prevalent. State regulations require subsurface drilling of damsites to identify underground anomalies; however, this method is not totally accurate in locating subsurface cavities that could lead to sinkhole development. An electromagnetic method of identifying anoma-lous subsurface conditions could reduce or eliminate the possibility of dam failure due to sinkhole development. The Bureau devised a GPR system that successfully penetrated over 50 ft of overburden and gave recognizable radar return signals characteristic of a rock-cavity interface.

Jan 1, 1986

By E. G. King

This publication presents original thermal data for a typical variety of perlite and supplies basic information for use in computing energy requirements in processes for expanding perlite. Perlite has been defined by Raiston 4/ as any silicious lava containing dissolved water in sufficient amount to errand into bubbles when the material is quickly heated to a suitable point in the softening range." The uses of expanded perlite in) the construction and ceramic industries have been discussed by Ralston 4/ and King. 5/ The work described here had a dual purpose: (1) It was desired to ascertain quantitatively, using a typical variety of perlite, just how firmly the contained water is held, and (2) it was desired to obtain basic thermal data sufficient for energy-requirement calculations in processes for expanding perlite.

Jan 1, 1948

By D. Harrington

Misuse of explosives and heedless disregard of well-known safety rules covering the use of commercial explosives cause many avoidable accidents resulting in the death or maiming of men who can ill be spared by already undermanned industry at present, and who cannot be spared by their families at any tire. Blasting accidents, when not fatal, are usually serious; the past and present needless loss of life and maiming of men from this cause are appalling and types of waste that can and should be virtually eliminated. Dead, crippled, and maimed men are distinct losses to society as well as to industry, and compensation payments for such accidents represent only a portion of the financial loss, because the value of their lost potential production can only be surmised. By their very nature, explosives are dangerous to handle, otherwise they would not perform the services for which they are used; all men on a blasting crew are subjected to the results of the carelessness of any one member, and in many instances the misuse of explosives by one person has killed scores of fellow workers. Inexperienced men should be assigned to blasting operations only under the close supervision of men well-experienced in the work and familiar with its inherent hazards. Men should be selected for blasting crews that are known to be careful, willing to follow instructions, cool-headed, and unlikely to become excited in an emergency; they should be instructed in the safe handling of explosives in accordance with the safety rules established by the explosives -manufacturing companies or the safety codes of the various industrial organizations. Unfortunately, American industry has never adopted a uniform code for the safe handling of explosives; however, many mining companies have made rules that will eliminate most unsafe practices if established safe procedure is followed carefully. The Bureau of Mines has issued numerous pamphlets giving information on the causes of accidents due to explosives in the mining industry and indicating the ways in which a good proportion of those accidents can be avoided.

Jan 1, 1943

By S. S. Todd

[The purpose of this investigation was to obtain, heat-of-formation values a four Common titanates and, to conjunction with other requisite data, to derive free-energy-of-formation values In tem peratures in the range of 1,600°-1,800° K. T ht four titanites are tricalcium ?ditanite !['a¬spheremr?raritanar( rint-tir.rniurn rill( 1 This rc rr,rt sul,rlc?nu?nIs :r },r; vinu~ hul,lrc.irse,n3i n wlti h eht-rmnnIN-ti i n c {ar.a ai?rc? pu -,csseeri (or, 11 in(c-rnxiLIic co mrc+unrls conraininL~ rir:,niurrl. 'f Lac? !1~:)mc? c?xpcrirnc'ntnl n-ut rhod w,i. rna~loycul. lic?.ats of for rn:ltion of rlre comi?c,unr4~ it 29S.N. ut re mca,urc?,l by tioItl[ion e':iIorrr)utrv, using a ctrneaR }ryrlrc,fllanric-hY rir~chlorie- ,aci l mixttrrt .is rhr c-zle~rinrrrric- fluid and rc.actic~n rtu,liura}.]

Jan 1, 1956

By Irven A. Jacobson

This literature survey consists of references dealing with gaseous state thermal decomposition reactions of organic nitrogen and sulfur compounds. The reference source for the survey was the Chemical Abstracts from 1930 to 1956, inclusive. Original articles were not studied. The starting date was set at 1930 because previous to this time much of the work is questionable. This report is in three parts: Part I lists nitrogen compounds; Part II, sulfur compounds; and Part III, compounds containing both nitrogen and sulfur. The organization of the classes of compounds is alphabetical: Part I - amides, amines, amino acids, ammonia, azides, azines, azo compounds, heterocyclic nltrogen compounds, hydrazine, nitrates, nitriles, nitrites, nitro compounds and miscellaneous nitrogen compounds; Part II - disulfides, sulfides (including double and triple sulfides), thiols, thiophenes and xanthates; Part III - thioacid amides, thiazoles, thiocyanates and thiuram disulfides. A class formula is included with each class name. The R's used in these class formulas may refer to hydrogen or to the same or different radicals when more than one R appears.

Jan 1, 1960

By M. H. Kersten, G. A. Brady, Jerry W. Ramsey

Anthracite samples were oxidized with nitric acid to prepare products representing intermediate stages of oxidation . Similar oxidizing conditions affected different anthracites to varying degrees as characterized by peptization behavior with 0.1 N NaOH . Techniques used in attempts to separate and characterize the products included esterification , absorption spectrophotometry , sublimation , chromatography , electrophoresis , metal salt formation , and solvent extraction . Mellitic acid , either free or in the form of metallic salts , was identified in the acid- soluble products from 10 tests in which the anthracite was treated with nitric acid for periods varying from 24 to 1,000 hours . pentacarboxylic acid was also found in some products . Other benzene carboxylic acids were not present in amounts detectable by the methods used in this study . The acid- insoluble residue from nitric acid treatment varied significantly in solubility behavior toward different classes of solvents . The most effective ones tried included polar oxygenated solvents and pyridine . Infrared spectra of the extracted material indicated that similar compounds were extracted by the different solvents . Aliphatic amines and aniline peptized the residue and o- toluidine reacted with it . Organic material separated from the residue by peptization with dimethylformamide contained 1 percent ash , consisting of more than 50 percent zirconium .

Jan 1, 1964