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By G. Bulut

The aim of this study is to produce desiccant clay from a well known Ca-bentonite deposit in Turkey. Towards this aim, bentonite samples were first procured and then subjected to some characterization tests. Various methods were applied to enhance the moisture adsorption capacity of bentonites to a desirable level. These methods include utilization of some additives namely calcium chloride and heat treatment at various temperatures. It is shown that the moisture adsorption capacity Ca-bentonites without any additive are between 14%~17 % (w/w) upon by heat treatment whereas the addition of calcium chloride significantly, raised the moisture adsorption capacities.

Jan 1, 2014

"The global demand for the copper metal is continuously increasing however, the high-grade copper ore deposits are constantly depleting. As a result, ore bodies with complex mineralogy characteristics and rich in arsenic-copper bearing minerals are increasingly processed. Arsenic-copper sulphides such as enargite can represent a significant amount of arsenic in concentrate, which causes high financial penalties by smelters. On the other hand, arsenic (As) is a highly toxic inorganic pollutant, which causes human health and environmental problems. Recent research studies have demonstrated promising results showing the possibility of separating arsenic-copper sulphides from copper sulphides using controlled pulp potential (Eh) flotation at laboratory scale. However, the selective removal of arsenic-copper minerals in real ore systems is not well understood. Two ore samples were selected from the Tampakan copper-gold deposit located in the Philippines named the HAS (high arsenic sample) and the LAS (low arsenic sample) samples and the mineralogical analyses were performed on both samples. The floatability of enargite in a batch flotation system under controlled pulp potential conditions was investigated for the HAS and the LAS samples. It was observed that it is possible to selectively separate enargite from other copper minerals after reducing the pulp potential to about -200 mV SHE at pH 11 in the LAS sample. However, no separation between enargite and other copper minerals was observed at a reducing potential for the HAS sample. Mineralogical analyses and surface chemistry studies were undertaken for both samples to find out the reasons for different observations. This study has an important implication in sulphide flotation to achieve sustainable development in the utilisation of arsenic-copper mineral resources. INTRODUCTIONAs the demand for copper is increasing, the extraction and development of resources including complex deposits is becoming necessary. These complex deposits often have issues such as: lower grade ores, floatable non-sulphide gangue, very fine-grained ore and therefore poor liberation and significant regrinding, mixed copper mineralogy, complicated galvanic interactions, economic levels of gold and silver, and high levels of impurities such as arsenic. There is currently no established methodology for separating arsenic-bearing copper minerals from other copper sulphide minerals by flotation. The possibility of separating arsenic-copper sulphides from other copper minerals by controlling the potential of the flotation pulp has been shown in previous studies. However most of these studies were conducted on single mineral systems and the selective removal of arsenic-copper minerals in complex ore systems is not well understood. The flotation behaviour of arsenic-bearing minerals within complex ores differs significantly from that of pure mineral systems due to the effects of mineralogical composition, the degree of liberation, and the surface oxidation. The understanding and manipulation of these effects can lead to improvements in the selective flotation recovery of arsenic-bearing species from complex ore systems."

Jan 1, 2018

By O. N. Mohanty, S. Mohan Rao, N. D. Rao, T. Mukherjee, P. V. T. Rao

"Tata Steel has its captive chromite resources at Sukinda, Orissa. They contain two ore types, i.e. (i) Ferruginous and (ii) Siliceous. The generation of off-grade ores is an increasing trend and simultaneously customer quality requirements are becoming ever more stringent. The ferruginous type ore also contains a considerable quantity of in-situ fines (~20% particles below 0.5 mm) that compound the beneficiation problem.In this paper, new strategies are discussed for producing additional value.added products after evaluating the present beneficiation practice in terms of changing market scenario, processing capability of the plant and ore characteristic. They would entail use of MGS - an enhanced gravity separator, for recovering additional products from plant tailings; production of ferruginous coarse concentrates (-3+0.5 mm with ~46% Cr2O3) using jigs; production of marketable grade lumpy (-40+10 mm size) concentrates from low grade siliceous ore using jigs and >2.8 Cr/Fe ratio siliceous ore fines treated in the Chrome Ore Beneficiation plant gravity circuit units and low intensity magnetic separator. The studies indicate that it is possible to recover 79-80% of the chromite, against a theoretical maximum of 82% from both the ore types, in the form of several marketable grade concentrates that would also include refractory grade."

Jan 1, 2003

By S. H. Morar

Froth flotation is a physico-chemical separation process that takes place in two phases; pulp and froth phase. It is widely recognised as a complex process, due to the range of interactions present within the system. Of critical importance is the role of the froth phase within the system. The pulp kinetics governs the maximum potential recovery within a flotation cell, while the froth phase governs the selectivity via the froth?s stability. Higher froth stability improves recovery at the expense of grade, and lower froth stability improves selectivity. It is well known that the two major factors affecting froth stability are attached particles and solution chemistry. This paper looks at a flotation bank at different froth depth and frother concentrations. The air recovery to the concentrate is determined at each condition and relates the effect of the operating conditions on froth stability and transport to the amount of solids that are recovered to the froth and concentrate by true flotation. The results presented show that, for a given process objective, which in this case was a consistent mass pull profile, depending on the operating conditions, solids recovery in the pulp is affected by the air rate required to maintain the target mass pull. To a smaller extent, the changes in the pulp composition affect down-stream pulp recovery. The variation in solids recovered into the froth drives the froth stability at the start of the flotation bank, while the frother drives the froth stability at the end of the bank. The performance in between these two extreme conditions arises from an interaction of these two effects. The consequences of these interactions can give rise to counter-intuitive responses that can confound efforts to optimise the performance of the bank.

Jan 1, 2014

By W. G. Liu

Phenyl malonic acid (PMA), a new chelating collector, which contains a phenyl structure and a malonic acid chelating group, has been synthesized and its collecting capabilities to calamine, hematite, quartz and hemimorphite are also studied in laboratory. From the experimental results, it can be seen that the PMA has somewhat flotation ability to calamine, hematite and quartz, while it nearly has no collecting ability to hemimorphite. With the increase of PMA concentration, the flotation recovery of calamine increases. When the dosage of PMA was 560g/t and at pH=7~9, the flotation recovery of calamine gets its maximum of 45.94%. The test results about the influence of pH on the flotation recovery of quartz show that the flotation recovery increases with the increase of pH, and the maximal flotation recovery can be gained in alkaline media. On the other hand, PMA has stronger flotation capability to hematite than to other minerals. The flotation recovery of minerals increases with increase of PMA concentration. When the dosage of PMA is 560g/t and at pH=5~7, the flotation recovery of hematite is 82.96%. Mean-while, the influence of pH on the flotation recovery of hematite was studied and test results showed that, as pH increases, the flotation recovery sharply rises until pH=4, then the increasing rate de-creases outstandingly, at pH=6 the flotation recovery reaches its maximum of 82.96% and it de-creases speedily in alkaline media. Finally, through the measurement of infrared spectroscopy and in terms of solution chemistry of collector, the flotation mechanism has been discussed. It was concluded that the adsorption of PMA on minerals surface is chemical adsorption in nature through two oxygen atoms in the polar group of phenyl malonic acid chelating with the metal ions of minerals surface to form a hexagon-cycle chelate complex: C(=O)-O-M-O-(O=)C.

Jan 1, 2014

By Magnus Evertsson, Rebecka Stomvall, Josefine Berntsson

"Understanding the effect of particle shape on dry rheology is considered to be an important aspect in order to replace natural sand used in concrete with manufactured sand. Crushed particles from solid rock are normally less rounded and have less equally shaped dimensions compared to natural sand. Thus, the flowability and workability of the concrete will be different. In previous research, it has been demonstrated how different crushing techniques affects the shape of the particles. In many cases it is believed that Vertical Shaft Impact (VSI) technology is a way forward to replace natural sand. To be able to study the effect of VSI at the smaller fractions (63-2000 µm) sufficient measurements methods to determine particle shape are required. Optical tools to analyze the aggregates would make it possible to study a large amount of particles at small fractions. The determination of particle shape of aggregates is challenging since the shape is highly irregular and the size span of particles are very large. This study aim to evaluate one of the available optical tools, the Camsizer, for digital imaging determination of shape and size distribution. The available default shape parameters of the Camsizer are studied to understand the meaning of the parameters and their suitability for determining the quality of manufactured sand. To evaluate the capacity to determine particle shape, tests are made with 35 different materials. The results are compared with the dry rheology measured with the standardized "flow cone" test. Dependence has been previously proven between particle shape and the mass flow rate in the cone. Three different shape parameters, aspect ratio, sphericity and symmetry, are studied with the Camsizer and the results are compared with the mass flow rates in the cone. The results indicate a strong linear relationship between the optical parameters and the flow cone test."

Jan 1, 2014

By Z. Cheng, Y. Han

"For non-sulphide minerals such as oxidized minerals, fluoride minerals, and oxysalt minerals, there are generality in the molecular structure of their floating collectors, and similarity in crystal structure of the minerals. In the paper, adsorbing mechanism of these collectors on the surface of these mineral particles in different pH pulp was investigated by means of Pauling's rules & valence bond theory, Valence-shell electron pair repulsion theory (VSEPR) theory, Crystal and ligand field theory, and quantum chemistry simulation by DMol3 and CASTEP modules of Material Studio software. Besides, the role and status of hydrogen bond in the floating adsorption mechanism were studied emphatically, and the confirmation and characterization of hydrogen bond were explored also based on the test results. What is more, the conclusion “the effect of hydrogen bond can not be overlooked in adsorbing mechanism of flotation collectors on the minerals” and a new viewpoint of multi-polarity collaboration and hydrogen bond coupling were summarized eventually based on analysis of the measurements. Finally, a novel collector 2-Amino-3-Methyl Heptyloxy-Propylamine (AMHP) was developed based on the new viewpoint of molecular structure design, and its collecting performance was exhibited.INTRODUCTIONWhen it comes to the recovery of flotation, it is necessary for researchers to investigate the flotation mechanism of collectors. In traditional theory, when collectors were used to collect minerals, the attractions between collectors and minerals were divided into chemical, electrostatic and physical attractions (Wills, B.A., 2006). Especially, because of the reaction between sulphide minerals and sulphydryl collectors is complex and various mechanism has been proposed (Yoon and Basilio, 1993), when collectors were used to collect non-sulfide minerals, it can be classified into oxyhydryl anionic collectors and cationic collectors. In traditional theory, the adsorption of oxyhydryl anionic collectors were due to water-repulsion, and the adsorption of cationic collectors were due to electrostatic attraction between the polar head of the collector and the charged electrical double layer on the mineral surface (Wills, B.A., 2006)."

Jan 1, 2018

By Yuhe Tang

High Gradient Magnetic Separator with Horizontal Magnetic Line is a new type High Gradient Magnetic Separator product. It has many specific advantages, such as water-air joint discharging technique, double pulses pulp dispersion technique, multi-magnetic gradient for collecting matrix with different diameter rods, better discharging rate with the especial matrix dispose, high separating accuracy and wide applicability. In this paper, the author makes a description of High Gradient Magnetic Separator with Horizontal Magnetic Line, and puts its emphasis on analyzing industrial production data using high gradient magnetic separator with Horizontal Magnetic Line to separate weakly magnetic minerals. It is found that as the rougher for weakly magnetic minerals separation, High Gradient Magnetic Separator with Horizontal Magnetic Line has more stable metallurgical performance and cheaper running costs than other types of High Gradient Magnetic Separator when the properties of the ore change greatly and there is in the case of embedded fine particle size distribution. Keywords: high gradient magnetic separator, self cleaning technology, horizontal magnetic line, water air discharging technique

Sep 1, 2012

By K. Amano, K. Haga, Y. Watanabe, A. Shibayama, A. Batnasan, A. Battsengel

"Apatite is an important host mineral in igneous and metamorphic rocks for production of phosphate fertilizers and phosphoric acid, and a potential source of rare earth elements (REE) production. For dissolution of REEs, sulfuric acid is better leaching reagent to develop the economical viable process for recovering of rare earth elements from apatite ore. However, the efficiency of rare earth elements dissolution in H2SO4 is about 30 % due to the formation of calcium phosphate or calcium sulfate as precipitate. On the other hands, phosphorus is mainly produced from phosphate ore. However, when treating rare earth elements containing phosphate ore, rare earth elements were discharged. Hence, development of novel apatite ore treatment process is required for effective utilization of natural resources. In this study, apatite deposit associated with REE was treated with sulfuric acid leaching and two stage precipitation by oxalic acid (C2H2O4) and magnesium chloride (MgCl2) for recovering REE and phosphorus, individually. Results showed that it can be seen the vast majority of La (87.5%), Ce (87.3 %), Pr (86.1 %), Nd (85.2 %) and Y (90.9 %) were dissolved in 1 mol/L diluted H2SO4 solution from the apatite ore. As average leaching rate of REE, over 85% of REE were leached by the condition. In the first stage precipitation using the obtained pregnant leach solution from leaching, over 90% of REE was precipitated by oxalic acid addition after controlling pH to 1 by NH4OH solution. After pH changed to 8.5, over 90% of phosphorus was recovered as precipitate by magnesium chloride addition in second stage precipitation"

Jan 1, 2018

By T. Niedoba

The ash contents in coal particles were examined in the paper dependably on particle size and its density. So, the two-dimensional regressive function Z=Z(?, D) was the searched object, where Z is random variable describing ash contents, ? - density and D ? particle diameter. This dependence is determined basing on experimental data concerning the coal of type 31. For this coal, the method of ordinary kriging is applied to calculate the values of a random variable Z. This method requires the proper selection of so-called variogram function, which 4 forms are considered in this paper in purpose to select the best solution. The given results were then evaluated by the residual deviation value and so compared with empirical data.

Sep 1, 2012

By Li Tianxia, Zhou Jing, Zhu Yimin

"A typical low-grade of high sulfur bauxite fr contains 54.71% Al2O3, 11.35% SiO2 while the ratio of aluminum and silicon was 4.25, and harmful components such as Fe and S graded 7.3% and 1.33% respectively. The ore is characterized by complex mineral compositions, fine dissemination of particle size of pyrite and diaspore, low desulfurization efficiency, and difficult separation of aluminum and silicon. In order to improve the degree of concentration, recovery and desulfurization efficiency on the basis of process mineralogy studies, the floatation behavior of high sulfur bauxite in the process of desulfurization and desilication were studied through laboratory tests and pilot plant tests. KEYWORDS high-sulfur bauxite; low grade; flotation; desulfurization;desilicication INTRODUCTION In order to solve the selection problem of bauxite mine area, we carried out technological mineralogy, laboratory test, small-expansion Dalian test to solve the problem of the refractory ore. Main research contents and conclusions were presented as followings :(1)Process mineralogy research shows: the main mineral components include diaspore, kaolinite, chlorite, pyrite, limonite. (2)Batch flotation tests indicated that slime can be dispersed well during desulfurization floatation when Na2CO3 was used as modifying agent. (3)Poilot plant tests shows that Batch flotation tests results are correct. 2?PROCESS MINERALOGY 2.1 Chemical Composition of Ore 2.1.1 Spectral Analysis of Sample The results of the semi-quantitative analysis of X-Ray -fluorescence spectra of the original ore are shown in Table 2-1. The results of spectral analysis show that the main components of the sample are O, Al, Si, followed by Fe, Mg, Ti, S and so on, while the content of other elements is very small. The value is Al, and maybe Ti, for bauxite, while Fe and S are unfavorable elements, and Si and Mg and Ca are the main impurity elements."

Jan 1, 2018

By K. Lillkung

The use of secondary sources has become a very attractive option in the production of platinum group metals as the demand for these metals has increased. One of the promising sources are the spent catalysts, which provide an attractive source as they have relatively high metal content compared with the ores where the metal is originally extracted from. The concentration of platinum group metals in catalytic converters is in the range of 0.1-1 mg/g as the concentration in ores is usually less than 10 ppm. Aqueous chloride solutions are claimed to be a cost effective way in which platinum group metals can be brought into solution and concentrated. In this work the effect of different parameters on the dissolution rates of Pt, Pd and Rh were investigated. The parameters investigated were the Cl- concentration, the temperature and applied potential. Chloride concentrations used were 62.5, 90, 125 and 250 g/l. Temperatures were 25, 40, 60, 80 and 94°C. Potentials were 950, 1050, 1150 and 1250 mV vs. SCE for Pt and Rh and 380, 410, 440 and 470 mV vs. SCE for Pd. Dissolution rates were calculated from the current densities determined by potentiostatic measurements. Thin wire electrodes were used in the measurements. As expected, higher temperature, higher potential and higher chloride content generally increasedthe dissolution rate. However, the effect was nonlinear and slightly different for different metals. The results show that strongly oxidizing conditions are needed in order to achieve reasonable dissolution rates. With the highest chloride content and at potential of 1250 mV vs. SCE and 94°C the dissolution rate of Pt was nearly 1 mm/h, whereas in similar conditions Rh achieved a rate of only nearly 100 µm/h. Similarly, with the highest chloride content and at potential of 470 mV vs. SCE at 94 °C the dissolution rate of Pd was nearly 1 mm/h. Keywords: Pt, Pd, Rh, redox potential

Sep 1, 2012

By G. N. Jadhav

In India, bauxite deposits are concentrated in Central India, Western Ghats and Eastern Ghats. Bauxites from various regions in Gujarat were identified during the present investigations of geochemical mapping. Different types of Bauxites samples were collected from Kachchh, Jamnagar, Porbunder, Junagarh, Bhavnagar and Amreli areas of Gujarat state and were studied in detail for their geochemical signatures to plot the data on Geochemical map. Raw bauxites were characterized by using powder XRD, XRF, ICP and optical microscopy techniques (with the help of Model microscope having both transmitted and reflected light setups) and were later examined to grade their quality. Most of the bauxites from Kachchh region were of high-grade (gibbsitic) type; while those of Sourashtra region were of low-grade (lateritic / calcitic) types. Most of these bauxites were either of ferruginous/lateritic or of calcareous/calcitic types. Based on the mineralogical composition, such as gibbsite, hematite and/or goethite, Kaolinite and calcite minerals present in particular bauxites, the deposits were graded. Finally, the Geochemical mapping of Bauxites for Gujarat region was prepared and discussed.

Sep 1, 2012

By Ataollah Nosrati

Agglomeration of fine mineral particles is an important step in heap leaching processes employed for a cost-effective hydrometallurgical extraction of value metals from low-grade ores. In this study, the effect of acidic binder composition and feed ore particle size on binder dosage requirement and isothermal, batch agglomeration behavior of siliceous goethite nickel laterite has been investigated. Agglomeration tests performed with tap water and 30, 44 and 98% w/w H2SO4 solutions as binders revealed the key role of binder formulation in controlling ore particle wettability, nucleation and granule growth behavior. Both lower binder acid content and higher dosage led to greater wetting, nucleation and granule growth rates. Variation of feed ore fine/coarse particles? mass ratio dramatically impacted on binder dosage requirement for effective particle wetting, nucleation, and growth agglomeration behavior. Increasing fine (-150 µm) fraction mass content in a -2 mm feed ore, led to higher binder dosage requirement and enhanced nucleation, however the overall agglomeration rate/granule size growth decreased. In contrast, the presence of coarse (5 ? 15 mm) particles in feed ore led to (i) lower binder dosage requirement, (ii) enhanced initial agglomerate size growth rate, and (iii) reduced coalescence. For dry agglomerates of similar sizes, competent coarser feed particles led to remarkably higher compressive strength than did finer feed particles. Microstructure analyses indicated that the granules containing coarser particles exhibited a distinctive, competent core/shell (fines) structure which led to their structural reinforcement. The appropriation of the findings for optimizing agglomeration behavior for enhanced heap leaching of complex, low grade laterite ores are discussed in this context.

Sep 1, 2012

By T. Neesse

In many cases, the use of hydrocyclone control is desirable for the stabilization of separation in the setting of changing feed conditions. Control concepts based on exact mathematical models are not satisfactory due to the complexity of the physical process. In this case, fuzzy control is a suitable solution. The data are primarily derived from an optical sensor that monitors the outside view of the free underflow stream. A throttling valve, serving as an actuator, is installed in the overflow pipe that regulates the volume split of the cyclone. Applications in closed circuit grinding and in separation plants for tunnel driving, fine sand dewatering, and classification of kaolin demonstrate the typical use of this development. Additionally, the technological characteristics of the cyclone may be improved by this control, which is mainly caused by the increased discharge capacity of the un-der flow nozzle. A further advantage is the option to operate at an optimal operation point. In many cases, this point is located at the transition spray/rope discharge. The improved operation characteristics present new options for extensive applications of fuzzy cyclone control.

Jan 1, 2014

By Liu Fan, Shang Yanbo, Wang Zhongming

"Besides valuable metals of Cu, Sn, WO3, Zn, there are S, Ag, CaF2, In and so on in a complex ore deposit in south China (which belongs to Hu Nan Shizhuyuan Non-ferrous Metal Limited Liability). Although it proved reserve amounts to 3.5×107 ton, its crystal character limits its utilization in large-scale. It features complex relationships between valuable minerals, finest crystallized particle size, low-graded valuable metals (Cu 0.30%, Zn 0.5-0.7%, Sn 0.2%, W<0.1%). If only tungsten minerals are considered, it means WO3 grade is too low (the cut-off grade of WO3 is 0.1% in China). Only Cu and Sn minerals are recovered from 2006 and Cu recovery is less than 70%, Sn 15-20%. Other valuable metals of W, Zn, S and CaF2 were lost in the tailings. To make good use of the ore, the technology of fully recovering Cu, Sn, W, Zn, CaF2 and rare metals are in urgent need. After systematic researches, the flow sheet of "bulk flotation of Cu-Zn minerals at first, then Cu-Zn separation, then recovering sulphide by flotation, then recovering iron minerals by magnetic separation, then bulk flotation of Sn-W minerals after desliming" is developed. Furthermore, specific Sn-W collectors of BK411 and BK412 are applied into the processes and better indexes are obtained. The industrial indexes are listed as followings: the content of Cu, Zn, Sn, WO3 of ROM ore is 0.31%, 0.65%, 0.13%, 0.03%; Cu and Zn recovery are 82.23% and 37.79% respectively; 63.76% of Sn and 34.34% of WO3 go into the Sn-W bulk concentrates. Economic benefits are remarkable."

Jan 1, 2014

By A. Koizhanova

Kumistinskoye gold- and silver bearing ores (Republic of Kazakhstan) as well as standardized test solutions containing gold, silver, copper, zinc and iron were studied. The best results in silver and gold recovery from Kumistinskoye gold- and silver bearing ores were achieved through use of complex cyanide-thiosulfate solutions as compared to individual cyanide solutions and thiosulfate solutions. It was found that such complex solutions substantially step up leaching process herewith increasing precious metals recovery rates. Thermodynamics of studied chemical processes was calculated. Reaction order, kinetic constant and activation energy of gold leaching process through use of cyanide-thiosulfate solutions were identified. We managed to prove that the sorption rates and holding capacity in process of gold anions recovery with anionite AM-2B are comparable to sorption characteristics for cyanide solutions. Keywords: gold, silver, copper, zinc, iron, cyanide-thiosulfate solutions, anionite AM-2B

Sep 1, 2012

By Hoon Lee

Laboratory tests were conducted to evaluate the breakage characteristics of pyrophyllite in a laboratory ball mill. In grinding tests, the breakage characteristics were analyzed using the mathematical kinetic models based on the two breakage functions; the specific rate of breakage and the primary breakage distribution. Two samples having similar chemical composition show identical values in specific rate of breakage. In comparison, there are different values of primary breakage distribution for each sample. The size distributions of the product with various grinding time are well described by the parameters from non-linear searching.

Sep 1, 2012

By Luo Chuansheng, Rao Jinshan, He Xiaojuan, Qiu Xianyang

The dissemination grain size of chalcopyrite is really fine and refractory grains of -10µm take up 25%. Dissemination relationships among chalcopyrite with pyrrhotite, pyrite, marcasite and gangue minerals are complex. Content of Fe-bearing sulphides and Fe-bearing silicates associated with chalcopyrite reaches to about 60%. It’s hard to liberate and separate chalcopyrite from pyrrhotite. The above four are the main mineral processing difficulties of a copper ore in China. Because of the similar floatability and poor separation effect between chalcopyrite and pyrrhotite, enhanced depressing and collecting method was adopted in Cu-S separation before 2009. Due to the different magnetism among chalcopyrite, pyrrhotite and Fe-bearing silicates, magnetic separation is creatively induced in Cu floatation circuit based on the in-depth study of process mineralogy. High efficiency and new Cu-S separation technology of "Rough concentrate regrinding-pyrrhotite rejecting from middling by magnetic separation" and a highly selective copper minerals collector YL-1 had been developed to solve the difficult problems of refractory Cu-S separation, which are heavy load of middling recirculation,difficulty in upgrading Cu concentrate, unstable locked cycle and low separation indexes. And grade of Cu concentrate has been increased by 3.33%, recovery of Cu and Ag has been increased by 19.32% and 10% respectively.

Jan 1, 2014

By Z. S. Abisheva

Results of the study targeted to development of universal acidic-extraction-precipitation technology for gallium recovery from the sublimates are presented in the paper. This will let to utilize a new non-traditional source for gallium production. Phase composition of gallium containing dust was studied. Forms of gallium in the sublimates were determined. The main form is Ga2O3, however, GaP form is also present in the cottrel dust and Na5Ga3F14 form is present in the dust of aluminum electrolysis. The possibility of gallium concentration was established via secondary pyro-selection of the dust. Kinetics of interaction of dust components with sulfuric acid was studied. The products of the interaction subsequently were leached with water. Optimum conditions for direct leaching with HCl and H2SO4 were determined providing gallium recovery from the cottrel dust and the ash carry outs up to 95 %. Gallium recovery from the primary dust and the secondary dust of aluminum electrolysis was at 52; 64 % and 63; 83 % respectively. Effect of Fe, P, K, Na and Al admixtures for gallium extraction from hydrochloric acid solutions was studied. It was shown that gallium chloride complex (GaCl4-) is extracted into the organic phase from the following acid mixtures: HCl + H2SO4, HCl + H3PO4, HCl + H2SO4 + H3PO4, HCl + HF. Kinetic regularities of gallium extraction in the system (tri butyl phosphate) TBP ? HCl - Ga were studied using diffusion cell method with agitation. Optimum conditions for gallium extraction from complex hydrochloric acid solutions with TBP were found providing 99.9 % recovery and separation coefficient for gallium and iron (III) of more than 25 in one stage. Sodium hydroxide and water were selected as reagents for re-extraction of gallium from the organic phase. Different options for disposal of by-products that are formed in the processing of cottrel dust, ash sublimates and dust of aluminum electrolysis were proposed and tested. Keywords: gallium, kinetic, sulfatization, leaching, extraction, technology

Sep 1, 2012