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By James Y. Oldshue

"Very seldom is it possible when contacting a gas with a slurry to measure the dissolved gas concentration in the slurry, and even where possible, equilibrium data with a suitable Henry.s law constant are seldom available.In general, by assuming a reasonable value for the dissolved gas concentration in the slurry and a corresponding equilibrium gas partial pressure P*, KGa values can be calculated for the pilot plant and then scaled up. Then, with the same P* value at various reaction conditions, a mixer can be designed which is quite satisfactory, having a reasonable design factor for full-scale performance."

Jan 1, 2003

By M. Paymardi, A. Foroutan, T. P. Oladele, M. Abbaszadeh

"Reducing the amount of zinc and iron in lead concentrate is one of the important aspects of processing in lead and zinc flotation plants which results in improvement of lead concentrate quality and prevents zinc loss. In mineral flotation industries, lignin sulfonates are known for their depressant properties for both non-metallic and sulfide minerals such as pyrite and pyrrhotite.This paper investigates the effect of lignin sulfonate on flotation of galena, sphalerite and pyrite in sulfidic lead and zinc bearing ores. Batch flotation tests were carried out on a high pre-activated zinc samples. The feed contains 0.9% lead, 2.3% zinc and 7.5% iron. The dosage of all reagents such as sodium cyanide, zinc sulfate, ethyl xanthate and methyl isobutyl carbinol (MIBC) were kept constant for lead flotation step except calcium lignin sulfonate (CLS) that was varied between 0 and 80 gr/ton.Results for lead rougher concentrate showed that the grade of lead increased by 2.7% while the recovery decreased around 4 % at the highest dosage of CLS. Furthermore, zinc recovery decreased by 6.3% with no significant change in grade. Iron recovery in lead rougher concentrate decreased by 2.3 % while the grade changed around 1%. In sphalerite flotation step, CLS dosage was changed in the range of 0 to 80 gr/ton while the dosage of other reagents such as copper sulfate, lime, amil xanthate and MIBC were kept constant. In this step, no decreasing in grade and recovery of zinc was observed, while iron recovery decreased. It was suggested that CLS has a depression effect on sphalerite in conjunction with other zinc depressants such as zinc sulfate and sodium cyanide. CLS was further used in plant with non-pre-activated zinc minerals. Similar trends were observed in plant.INTRODUCTIONlead-zinc sulfide minerals play an important role in the production of lead and zinc metals in the mineral processing industry (Luo, Feng et al. 2016). Due to complexity of the lead-zinc ores mineralogy, in some situations, their flotation properties vary significantly from one deposit to another one even in itself (Bulatovic 2007)."

Jan 1, 2018

By P. Gao, J. W. Yu

"Magnetizing roasting-magnetic separation is an important route for the beneficiation of refractory iron ores. In this investigation, a pilot-scale fluidized magnetizing roasting reactor was introduced and used to study the effects of roasting temperature and the flow rates of reducing gas CO and fluidizing gas N2, on the magnetizing roasting performance of an Anshan-type carbonate-bearing fine iron ore. The results showed that the hematite was almost reduced to magnetite by a gas mixture of 4 m3/h CO and 1 m3/h N2 at a roasting temperature of 540 °C. Under the optimized conditions, a high-grade magnetic concentrate assaying 66.1 wt.% Fe with a recovery rate of 91.2% was achieved from an Anshan-type carbonate-bearing fine iron ore assaying 42.0 wt.% Fe. The XRD, VSM, and optical microscopy analyses revealed that the siderite was successfully converted to magnetite by roasting. Some coarse hematite particles were difficult to reduce to magnetite completely; however, these generated magnetite particles with a fine hematite core could also be effectively recovered by magnetic separation after liberation from gangue minerals due to their strong magnetism. INTRODUCTION Magnetizing roasting followed by low-intensity magnetic separation has been considered as an effective solution, both technologically and economically, when upgrading refractory iron ores (Zhang et al., 2012; Peng et al., 2012; Li and Zhu, 2012). According to the type of roasting reactor, the magnetization roasting can be divided into shaft furnace roasting, rotary kiln roasting, and fluidized bed roasting (Zhu and Li, 2014).Shaft furnace magnetization roasting system is mainly composed of heating and reduction processes. The hematite ore is first heated to 700~800 °C in the heating zone, then falls into reduction zone where the weakly magnetic hematite is reduced to magnetite by coke oven gas at 550~600 °C (Yan et al., 2012). However, several years of engineering practices indicate that the shaft furnace can only process the hematite ores with a granularity of 15 ~75 mm, and the shaft furnace roasting is also characterized by heterogeneity of roasted product. Hence, the shaft furnace magnetization roasting technology is gradually replaced by high-gradient magnetic separation with the development of high-gradient magnetic separator. The rotary kiln generally handles the hematite ores with a grain size of less than 30 mm (Zhu and Li, 2014), however the formation of clinker ring in the rotary kiln will affect the yield of iron resource. In the fluidized bed furnace, the hematite ore is shaken up by an upward current of gas which maintains the individual particles in suspension (Yu et al., 2018). The precise adjustment of the gas velocity to the particle size and the specific weight of the hematite ore, make it possible to generate a floating mixture of gas and solids which behaves almost like a liquid (Yu et al., 2017a). The process is reported to have the following advantages over the other roasting techniques: ease of control due to absence of moving parts within the reactor, homogeneity of roasted products, ability to handle fine particles, and high efficiency of heat transfer and mass transfer (Li et al., 2015; Yu et al., 2017b). However, the simultaneous heating and reductive magnetization of hematite ore occur at the same place in the conventional fluidized bed reactor. Therefore, the reductive atmosphere, as well as the safety and stability of anti-explosion are hard to be controlled. Besides, the roasting temperature for conventional fluidized bed furnace is usually up to 950~1150 °C (Liu et al., 2017). Thus, the formation of clinker ring caused by high temperature will affect the operating efficiency."

Jan 1, 2018

By Xuliang Yang, Yuemin Zhao, Bo Zhang, Liang Dong, Cheng Sheng, Gongmin Li, Zhenfu Luo, Yaqun He, Chenlong Duan

Coal plays an important role in the primary energy consumption of all over the world. In 2012, coal reached the highest share (29.9%) of global primary energy consumption since 1970. Coal burning mainly contributes to the emission of SO2, NOX, Hg and other impurities that jeopardize the future of environment. . Beneficiation before coal utilization is the most economical and effective technology for removing the hazardous material and gangue. In this paper, a novel process of dry beneficiation based on gas-solid two-phase flow composed of the compound dry cleaning separator (FGX), the air dense medium fluidized bed separator (ADMFB) and the vibrated fluidized bed with autogenous medium (VFB) is proposed. The main equipment and the flowsheet of the united system are described in detail. Separating principle of the FGX, ADMFB and VFB devices are all based on gas-solid two-phase flow. In FGX, gassolid suspension is composed of continuous gas flow and coal powder in feed coal. Large size coal (+6- 80mm) can be pre-separated effectively, and large size gangue can be removed effectively. Moreover, - 6mm particles fed serve as autogenous medium in FGX. The probable E value is 0.13 for -80 mm raw coal. In ADMFB, magnetic powder with -0.3 + 0.045 mm size fraction and coal powder in feed coal are compound medium solids. The separation density can be adjusted and controlled according to properties of raw coal. -50 + 6 mm raw coal can be cleaned efficiently, the probable E value is 0.05. In VFB, -6 + 1 mm coal can be separated. Generally, -80 mm raw coal can be cleaned efficiently in the united system based on gas-solid two-phase flow.

Jan 1, 2014

By Milind Chikhale, Yogesh Reja, Keshav Tyagi

"Using computer models for process design is a well-established practice in the mineral industry. In recent years, there has been emphasis on modeling of processing plant as a whole. This paper covers development of a model for iron ore processing plant. Basic purpose of this model is to use simulation for efficient plant design and help in minimizing risk at the very initial stage of project. Feed to the plant is Hematite iron ore from a deposit located in Eastern India. Major processes in plant include multi-stage crushing, screening, grinding, classification, gravity and magnetic separation. Models for different process equipment were developed using METSIM and Bruno simulation software. Customized black box models and known mathematical models were used for predicting behaviour of processes. Data needed was identified based on the model type. The required data was arranged as per project requirement and processed for development and validation of model. Equipment models were developed and validated on the basis of process design basis, theoretical and empirical data from technical references, and bench scale and pilot scale testwork results. Validated process circuits were assembled to simulate and represent the entire plant process. The result shows expected variation in plant output as a result of variation in the feed. Study concludes by discussing potential applications of the model in plant design."

Jan 1, 2014

By R. X. Li

The overall flow-sheet of producing chromium (III) sulfate is described in this paper. The suitable conditions of each process such as sintering, leaching, aluminum removal, reduction, and de-composition conditions were experimentally studied. The results show it is reasonable to produce chromium (III) sulfate with the flow-sheet pointed out in this research work. The final product is Cr2(SO4)3 solution contained 150~250g/L Cr.

Jan 1, 2014

By Anuttam Patra, Romain Bordes, Andreas Fredriksson, Tommy Karlkvist, Krister Holmberg, Kota Hanumantha Rao

Almost all of the flotation reagents used today were discovered by continued application of empirical methods and/or trial and error experimentation. Moreover, with the metal-ion specific approach used so far, it is difficult to separate the minerals containing the same constituent metal ion. A critical assessment of molecular recognition processes involved in biomineralization suggested the possibility of using reagents which are surface specific. The concept that the molecules consisting of two or more functional groups having appropriate spacing between those so as to achieve structural/stereochemical compatibility during interaction with the mineral surface exhibit structure-specificity is thought to be extended to the design of specific collectors in flotation processes. In the present study, for the first time, a rational design of surface active molecules, and thereby the recognition of crystal faces (of minerals) by these molecules through structural and stereochemical matching is being utilized successfully to selectively float various minerals. For this purpose, carboxylate-based collectors (for mineral specific flotation of calcium minerals) as well as xanthate-based collectors (for mineral specific flotation of sulphide minerals) with a fixed alkyl chain length but having two functional groups with varying geometrical distances (separated by a spacer of one, two and three carbon atoms) between them have been synthesized. In this article, we have discussed the design, synthesis, purification of these novel mineral specific collectors as well as their important solution parameters in relation to flotation processes.

Jan 1, 2014

By Grigori I. Voiloshnikov

"The long-term studies on development of the technology for precious metals recovery using activated carbons executed by Irkutsk Research Institute of Precious and Rare Metals and Diamonds (IRGIREDMET) were finished by successful introduction of ""Carbon-In-Pulp"" process in Russia (1984).The review of some studies, accompanied by development, testing, introduction and subsequent improvement of considered technology, carried out by IRGIREDMET is submitted in this paper.The basic regularities of gold and silver adsorption onto activated carbons from cyanide, thiourea, chloride and other solutions are investigated using various phisical-and-chemical methods ( X-ray photoelectron spectroscopy, Voltammetry, X-ray microanalysis etc.). Using voltammetry it was found that gold cyanide is adsorbed onto activated carbon without chemical changes and partial reduction of gold is possible only during drying of carbon samples before analysis. Metallic gold and silver may be dissolved in boiling cyanide solution at argon atmosphere when they are in contact with activated carbon surface. Gold adsorption mechanism for activated carbons has great differences from that for the ion exchange resins. So the most probable mechanism for gold adsorption from cyanide solution is adsorption of neutral molecules Me n+[Au(CN)2-]n.X-ray quantitative microanalysis technique was developed to investigate gold adsorption kinetics onto spherical activated carbon. Gold profiles in granules of activated carbon for various adsorption conditions were tested (carbon particle size, mixing efficiency, adsorption time etc.). Mathematical methods were used to determine gold diffusion coefficient within activated carbon granule.The properties of various types domestic and foreign activated carbons were tested and the demands to activated carbons suitable for gold extraction were determined. As a result foreign and Russian activated carbons AG-90, AG-95 were recommended for use at Russian gold plants. Domestic adsorbents are cheaper in comparison with foreign activated carbons. The methods to restore carbon adsorption activity including acid treatment and thermal reactivation were tested and implemented."

Jan 1, 2003

By David I. Verrelli, Boris Albijanic

"Froth flotation is an exceedingly complex physicochemical process. The convenience of distilling much of the complexity of the bubble-particle interactions into a single parameter has led to the continuing popularity of the classical ‘induction time’ to quantify the threshold for bubble-particle attachment to occur. Despite this popularity and the simplicity of the concept, there is no single universal method of evaluating the induction period. In this paper, we begin with a critical review of the available techniques for estimating the induction period. These are: back-calculation from experimental (micro) flotation tests; pushing a particle toward a stationary bubble (or vice versa) using an atomic force microscope (AFM); pushing a bubble toward a stationary bed of particles in the ‘Induction Timer’; pushing a bubble toward a stationary solid surface using the ‘integrated thin film drainage apparatus’ (ITFDA); and dropping particles onto a submerged stationary bubble using the ‘Milli-Timer’ device. Each one of these methods has advantages and disadvantages, and the best choice depends on the application. In the experimental section, we present quantitative comparison of the induction periods estimated using two different techniques, namely the Induction Timer and the Milli-Timer. The same particles were tested in each device, under the same conditions. It was found that by tuning the operation of the particle pick-up device, similar estimates of induction period could be obtained to the estimates made by direct observation with the Milli-Timer. In the former device a bubble is driven toward a particle bed at a controlled rate, whereas in the latter a particle’s motion is governed by the hydrodynamics. The potential to match these presents an intriguing prospect for better understanding the bubble-particle interaction, and the possibility to ‘calibrate’ the simpler Induction Timer against direct observations."

Jan 1, 2014

By K. Sasaki, H. Miki, Y. Muta, T. Hirajima, G. P. W. Suyantara

"Selective flotation of chalcopyrite and molybdenite is continuing problem since its selectivity is not perfect and current NaHS process needs closed system flotation plant because of hydrogen sulfide emission on acidic condition. Some alternative additives investigated as chalcopyrite became hydrophilic and molybdenite kept hydrophobic. XPS analysis indicated chalcopyrite became hydrophilic since iron and copper sulphate, hydroxide was covered on the surface whereas molybdenite kept hydrophobic since only molybdenite can be seen. Flotation experiments of chalcopyrite and molybdenite mixture sample indicated excellent separation that 95% of molybdenite can be recovered as froth and 93% of chalcopyrite can be recovered as sink. Flotation experiments with real bulk flotation concentration indicated similar separation result compared with current NaHS additive system. Possible mechanisms and detailed phenomenon were investigated based on the surface analysis and thermodynamic calculation etc. this alternative additive is easy to handle compared with NaHS since it does not emit effluent gas and commercially preferable.INTRODUCTIONMany copper mine often associates molybdenite (MoS2) as trace mineral. It is important to separate molybdenite and copper mineral efficiently since molybdenite is valuable mineral and also contamination of molybdenite into copper concentrate decrease concentrate value. Conventional separation of copper sulfide and molybdenite has been achieved with sulfide bulk flotation followed by selective molybdenite flotation with NaHS addition since NaHS works as a depressant for copper sulfide (Bulatovic, 2010; Ansari and Pawlik, 2007b). However, this current process shows imperfect molybdenite recovery (Liu et al., 2012, Zanin et al., 2009) and depressant such as NaHS needs to be used under specific flotation plant since it might be environmental contaminant (Ansari and Pawlik, 2007a). there are still unknown on the effect of depressant NaHS, but one of the theory is NaHS reductant effect. It is worth to investigate the effect of other reductant as depressant on chalcopyrite. On this research, typical reductant, Na2SO3 are added to utilize for selective flotation of chalcopyrite and molybdenite."

Jan 1, 2018

By Y. E. Brylyakov, M. A. Kostrova

"The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. In this connection, the magnitude of cation exchange, along with the content of P2O5 and CO2, is an important property of apatite staffelite ore, which largely determines the performance of concentration processes. In the examined ASO samples, the magnitude of cation exchange measured in terms of Ca2+ is 2546-4790 g/ton. The conducted laboratory studies of apatite staffelite ores with various mineral composition showed that adding calcined soda improves the recovery of P2O5 into the flotation concentrate. Full-scale tests were conducted at the apatite staffelite ore processing plant at Kovdor Mining and Concentration Operation and demonstrated the high performance of the proposed agent treatment. The test results showed that in the flotation of apatite staffelite ores, the optimum calcined soda feed rates range from 3,500 to 5,000 g/ton of the flotation feed. With close flotation feed and concentrate grade parameters, the P2O5 recovery gain is 17%. The effect of adding soda is associated with the desorption of the hardness cations from the minerals, precipitation in the pulp and, accordingly, improvement in the ionic composition of the liquid phase of the flotation feed due to a reduced content of calcium ions. Based on the test results, the proposed agent treatment with an elevated feed rate of calcined soda was implemented at Kovdor Mining and Concentration Operation in the flotation of apatite staffelite ore. The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. These minerals have certain properties requiring a more detailed examination for a better understanding of the flotation properties of apatite staffelite ores."

Jan 1, 2018

By J. A. Venter

Mineralogical studies indicate the Pt-Pd-Bi-Te class to react poorly on the flotation stimuli and indications are that these minerals are slow floaters. However, recent studies performed on a number of minerals from this class indicated strong interactions with potassium ethyl xanthate resulting in the formation of dixanthogen (only one of several xanthate species). The poor flotation response is not a result of poor interaction of xanthate with the surface. It is proposed that the oxidation products of sulfides in the process water interact with the PGM surface. To test this, the effect of thiosulfate (an important oxidation product of sulfides) was investigated by employing electrochemical measurements and FTIR spectroscopy. The electrochemical investigations indicate no strong effect of thiosulfate on the interaction of xanthate with the minerals surface as well as the reduction of oxygenthiosulfate is likely not responsible for the poor flotation response of these minerals in industrial plants.

Jan 1, 2014

By S. Gerl

Since Schönert, 1980 a multiplicity of scientists have dedicated themselves intensively to the scientific investigation of wet grinding in agitated media mills. The achieved research results led to a clearly improved understanding of the comminution mechanism in wet operated agitated media mills and in consequence also to clearly more efficient machines. In contrast to this the standard of knowledge on dry grinding in agitated media mills is still very small. The practical experience from numerous plants shows however that the transferability of knowledge from wet grinding to the dry grinding regarding transport phenomena and comminution behaviour, influence of the operating parameters and also wear is very limited. In the industrial application above all the continuous mode of operation is preferred. The main problem which has to be solved in agitated media mills is minor the comminution itself, than rather the question of the trouble free material supply and material extraction as well as the cooling of the mill. The agitated media mill MaxxMill® offers an innovative concept to overcome the feeding and extraction problem with its rotating grinding chamber, the eccentrically mounted agitators as well as the eccentric flow deflector with integrated material supply. Because of the pneumatic extraction of the ground materi-al cooling of the milling chamber is not necessary. On a MaxxMill ® laboratory mill with a 5 litre grinding chamber volume extensive parameter studies were carried out to study the influence of operating parameters on the continuous dry grinding of quartz sand. The test were performed in a continuous single pass operation without classification of the final product. Apart from the influence of the throughput rate on fineness above all the influence of the agitator and grinding chamber speed as well as the grinding media size was examined.

Jan 1, 2014

By S. Kelebek, A. Khan, J. Caceres, D. Beckett

"Pyrrhotite in nickel-copper sulphide ores is nickeliferrous and intimately associated with pentlandite. Due to its low nickel content, pyrrhotite rejection is an important step in processing of these ores. In our laboratory, various reagents were investigated for their effect on pyrrhotite depression. Among these, a combined use of triethylenetetramine and sodium metabisulphite was found highly promising.The work described in this paper has two parts. The firs part is a summary of results obtained on process samples from the pyrrhotite rejection circuit at Falconbridge’s Strathcona Mill. The second part involves simulation of the circuit performance based on the reagent conditions used in the experimental work and the concept of split factors.Two sets of reagent conditions were evaluated. The first one involved baseline conditions, simulating the current reagent performance. The second one simulated the impact these new reagents can have on the circuit performance.The simulation results obtained under baseline conditions indicated a good agreement with the current circuit performance (Figure 1). The simulation results suggest that at practically the same pentlandite recovery and tailing grades, the circuit concentrate nickel grade can be doubled through effective pyrrhotite rejection by these new reagents (Figure 2)."

Jan 1, 2003

By Silvia França, Hudson Couto, Renata Barbosa

"The flotation process, largely used for mineral concentration processes, which is based on air bubble adhesion to the dispersed solid phase, is also being used for wastewater treatment purposes. Dissolved air flotation (DAF) is based on the separation of the solid-liquid phases with the aid of small air bubbles (10-100 µm), with high values of interfacial contact area, improving the process efficiency. In the process, the air bubbles and particles or flocs form aggregates, which rise to the surface of the flotation cell to be collected. The advantage of producing small bubbles is directly related to the fact that smaller bubbles result in greater bubble-particle interaction. Wastewater produced in alumina refinery - from the red mud filtration step - has a red colored aspect due to the presence of very fine particles of red mud and also dissolved matter that still remain in the filtrate. This wastewater might be treated, aiming to reuse the water in the refinery or discharge it properly in the environment. The aim of this study was to evaluate the DAF process efficiency for the treatment of red mud wastewater in order to decrease suspended particles and dissolved solids contents, in addition to mitigate the high causticity of this wastewater. The process efficiency was evaluated by comparing turbidity removal and total solids concentration in the treated wastewater to the feed. The influence of important variables of the DAF process as type and concentration of coagulant and flocculant were evaluated. It was possible to obtain good turbidity removal efficiencies (up to 90%) using low concentrations of coagulant (50 mg/L) and flocculant (0.5 -1.0 mg/L). In addition, for most of the experiments, the specification for effluent diposal, according to the Brazilian environmental regulation 430 (Conama, 2011): pH range 5 to 9 and turbidity < 40 NTU, was attained. These results emphasize the possibility of using the DAF as an alternative technique to settling and filtration process, that are traditionally used, for treating wastewater from the alumina industry, allowing the reuse of water in the plant or adequate discharge with less environmental impact."

Jan 1, 2014

By J. Shibata

The behavior in electric field of fine particles present in aqueous solution was measured in order to apply to the classification of fine particles. The sample particles used are spherical polystyrene particles with the average diameter of 0.03 µm, 0.1 µm, 1.0 µm, 4.3 µm and 9.6 µm. Electrophoretic mobility and zeta potential of various particles are measured by an instrument based on the principle of the laser Doppler effect. The influence of temperature, electrolyte concentration on the electro-phoretic mobility was investigated for various polystyrene particles. The electrophoretic mobility increases with increasing pH and temperature of suspensions. The measured electrophoretic mobilities are different from electrolyte concentration and particle size. The electrophoretic retardation effect and relaxation effect are considered to explain the behavior of fine particles in electric field by applying the electro kinetic theory of Wiersema et al. For all particle size, the electrophoretic mobility decreases rapidly in high concentration of KNO3 such as 0.1 mol/dm3due to the compression of electric double layer The forces acting the particles in electric field are considered to be electrical force, friction force and some other forces like relaxation effect and electrophoretic retardation effect which appear in ionic behavior. It is considered that the particle moving velocity depends on the particle size. When the particle size is less than 1µm, the velocity increases with increasing the particle size. On the oth-er hand, the velocity deceases with increasing in particle size, when the particle size is larger than 1µm. This phenomenon is considered to be interesting from the viewpoint of classification for fine particles. We found that the electrophoretic mobility of 1.0µm particles is larger than that of 0.1µm particles, and that it is possible to classify fine particles by using the difference of electrophoretic mobility by many experimental results. The phenomena can be explained by the forces acting the fine particles in the electric field. We can apply the behavior to classification of fine particles.

Jan 1, 2014

"The effect of operational conditions, such as air flow rate, impeller speed and solid concentration, as well as the effect of solids concentration and frother dosage, on the bubble size distribution produced in a lab scale flotation cell, were investigated. The cell was operated under batch conditions. The measurement of bubble size was accomplished using an automated photographic technique. The technique enabled fine and coarse bubble distributions to be measured in two-phase (liquid-gas) and three-phase systems (solid-liquid-gas). In each experiment, around ten thousand bubbles were characterized.This paper discusses the main results obtained using the new photographic technique and compares these with previous findings available in the literature. The results indicate that photographic techniques combined with digital imaging processing might become a standard technique for measuring bubble size distribution in flotation machines.HUT BUBBLE SIZE ANALYSERThe importance of having precise and reliable equipment for measuring bubble size distribution in industrial flotation machines has been widely recognized. The measurement of bubble size, particularly in three-phase systems, is rather complex due to the opaque nature of the pulp. However photographic techniques combined with ingenious sampling techniques are utilized for overcoming this difficulty. The technique named HUT, combines previously developed visualization methods with digital image processing procedures. In this technique bubbles and aggregates are exposed to a monochrome progressive scan camera. The acquired images are directly stored in a computer connected to the camera for post-processing. The sampling apparatus consists essentially of a vertical tube for collecting bubbles, a viewing chamber and a collection chamber, where particles carried by the bubbles are released. The function of the collection chamber is to maintain the viewing chamber clear for imaging purposes. Each image is automatically processed off-line, using digital image tools. In this paper the advantages and limitations of this new technique are described."

Jan 1, 2003

By V. Sovmen

The gold-ore Olympiada deposit is located within the Yenissei range (Krasnoyarsk Region, Russia). Primary sulphides ores are metasomatic changed rocks, mica-calcite-quartz structure with impurity amphiboles, chlorites, carbon, the rare thin grains of sulfides (up to 3%~5%) and native gold. The structures of ores are fine-grained, prevailing texture of ores - interspersed, vein-interspersed, band-interspersed, veinlet. The most important minerals in the deposit are: gold, arsenopyrite, pyrrhotite, antimonite, Sb-sulphosalt, quartz, muscovite, calcite, siderite, titanium minerals, chlorite and minor sulfides like chalcopyrite, galena, sphalerite, etc. A common problem in mineralogical studies applied to mineral processing (concentration, cyanidation, etc.) is the characterization of gold in ores and technological products. This paper discusses the behavior of minerals during technological process at operating factory in Olympiada Mine and gold distribution in the ores and products. For the mineralogical characterization of minerals ? combination of analytical techniques was used. Gold is encountered in the primary ores as free grains among rocks, growth with sulfides and nonmetallic minerals, inclusions in sulfides, sulphosalt, and nonmetallic minerals. The gold-sulphide ores of Olympiada deposit can be quite complicated for enrichment. With the purpose to increase the extraction of metal from concentrates by liberating the dispersed gold, forming inclusions in sul-fides, there is used technology of biooxidation of flotation concentrates in Olympiada Mine. Gold and the basic ore-forming minerals in the ores feed, sulphidic concentrates, biocakes, tailings of concentrates of flotation and products of hydrometallurgical leaching have been studied in the mineralogical research. During researches it is established that pyrrhotite was completely oxidized while arsenopyrite was oxidized almost completely in the bacterial oxidation process. Pyrite and antimony minerals behave similarly and were oxidized only partially. The main oxyhydroxides in the bacterial oxida-tion process are goethite, limonite and jarosite. The results of mineralogical researches showed reasons of losses of gold during hydrometallurgical enrichment.

Jan 1, 2014

By Gülay Bulut, Mustafa Özer, Yunus Emre Benkli, Olgaç Kangal, Istanbul Technical University, Mustafa Tarkan

"Zeolites are naturally occurring as hydrated aluminosilicate minerals. They belong to the class of minerals known as “tectosilicates” and are related to the common minerals feldspar and quartz. Seven natural zeolites that occur in large, commercially exploitable deposits, are: clinoptilolite, chabazite, mordenite, phillipsite, erionite, analcite, and ferrierite. Among them, clinoptilolite is the most abundant one and is not the best known, but is one of the more useful natural zeolite. Clinoptilolite [(Na3K3) (Al6Si30O72) 24 H2O] is very closely related to heulandite and is currently being considered for disuse it self as it may just be a variety of heulandite. It differs from heulandite significantly only in its enrichment in potassium and slightly more silica and it is argued that a separate mineral is not needed.There are large zeolite deposits in western part of Turkey. The sample used in this study was taken from the Gördes region of these deposits. Screen, chemical, XRD and mineralogical analyses were used to determine properties of the natural zeolite sample used in this work.According to the size distribution of the sample, it is found that the zeolite sample used in this study is below 1 mm in size and almost 80% of it is below 0.5 mm. X-Ray Diffraction (XRD) and mineralogical analyses show that the natural zeolite is found to be in the forms of clinoptilolite and heulandite. Clinoptilolite forms as a devitrification product of volcanic glass in tuffs. Quartz, clay minerals, orthoclase, plagioclase, biotite, seruzite-muskovite and epidote were observed as impurities. XRD analysis also shows that the sample contains approximately 58-60% clinoptilolite, 5% quartz, 5% feldspar, 10% smectite, 5- 10% illite and mica and remaining volcanic tuffs. Several types of mineral processing methods were performed in order to remove impurities from the natural zeolite sample to produce high purity zeolite. Gravity separation methods such as shaking table and superpanner were carried out for separating heavy minerals, while high intensity dry magnetic separation was used for discarding magnetic minerals."

Jan 1, 2003

By T. A. Penzov

As a result of recent scientific and experimental studies new technical devices have been developed for monitoring and control the process of grinding. The description of microprocessor module MILLCONT 1 for control of the loading of the mill and microprocessor density control module DENSIMETER is given in the paper. The improved variant of the automatic system for ore grinding control in single-stage ball mill working in close cycle with a classifier with above mentioned technical means is shown in the paper. The loops for measuring and stabilization of the basic technological parameters (density of the ready pulp ? and fineness of grinding of the pulp ß) are described in the paper. The nowadays economic results in ore grinding process automation are given as well.

Jan 1, 2014