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By Jessica Egan, Daniel Hodouin, Claude Bazin

"The recovery of gold by leaching is influenced by the size of the gold carrier particles and the chemical environment. Using the relationships between the leaching rate, infinite recovery and particle size for a given set of chemical conditions, it is possible to simulate gold recovery for various feed size distributions. However the use of these particle size relationships is only valid if the leaching of gold from a given size class is independent of the production history of this size class. For instance, to use these relationships it is necessary to verify that gold recovery from the leaching of the 200-270 mesh size class remains the same if the size fraction is taken from a coarse or finely ground ore sample. Several laboratory tests were carried out to answer that question. Results of the tests show that within the large error margin associated to gold content measurements, the history of the production of a size class does not affect the gold leaching from that size class. Emphasis of the discussion is put on the difficulty associated with the processing of data containing significant measurement errors as it is the case for gold assays of leaching tests.INTRODUCTIONMore than 75% of the gold produced in the world is extracted by cyanide leaching of gold ores. The ore is ground to expose the gold carriers and the ground material is reacted in an oxygenated cyanide solution that dissolves gold, leaving solids gangue minerals that are disposed to tailings ponds or returned in underground mines as paste fill. The gold contained in the solution is recovered by either the carbon in pulp process or by cementation onto zinc powder, before being melted and casted into a brick (Marsden and House, 2006)."

Jan 1, 2009

By J. B. Boisvert, P. Oshust

A significant source of uncertainty in the diamond resource contained in kimberlite pipes is the volume of the pipes. Often the material within a pipe will be mined as ore, leaving the actual geometry of the pipe as a significant source of uncertainty. It is desirable to use stochastic techniques, rather than deterministic methods, to model pipe geometry because stochastic techniques generate multiple realizations that are reproducible and can be used to assess uncertainty in pipe geometry. The proposed methodology uses sequential Gaussian simulation of pierce point locations interpreted from drillholes through a kimberlite pipe. Kimberlite pipes are approximately cylindrical in shape; therefore, the data are transformed to cylindrical coordinates to facilitate the simulation of pipe geometry. Rather than using xyz coordinates to define the pierce points, z, ??and pipe radius are used. The radius variable can be simulated in z-??space to generate multiple realizations of pipe volume. Uncertainty in the volume of the pipe can then be evaluated. This methodology is demonstrated with a kimberlite pipe at BHP Billiton’s Ekati diamond mine.

Jan 1, 2008

By G. Griffiths

"P. WitteWitteck DevelopmentThe implications of using a tower mill for fine grainding in the ore processing of tailings are significant. What can those of us who are in a research and development situation do when we recommend this equipment to a client? When this prototype is placed on stream next to a conventional grinding mill as you suggest how do we estimate the power requirements and the grind which will be achieved?ReplyLet me explain the Macassa circuit. The tower mill here was running in parallel with one of the ball mills. The feed entering the tertiary system is scalped in a primary cyclone. The finial cut is made in a secondary cyclone. The actual feed to the tower mill is the underflow from the two cyclones and was split to the ball mill and tower mill. During the testing we were unable to isolate the tower mill to determine its contribution to the overall system. We then started to look at the amount of material produced across the mill. We entered the mill at between 17% and 20% finished material and exiting at between 36% and 40% finished material. We were able to project, with a high efficiency classification system, and arrived at 6 Kwh/ton or better."

Jan 1, 1984

By F. D. Ford, Z. Dai

"Vale’s Ontario Operations re-introduced Cu/Ni separation at Clarabelle Mill in 2006. The mill processes ores from a number of mines in the Sudbury basin. A saleable Cu concentrate is produced at 30-60% Cu recovery from mill feed, which has to meet the quality specification. In particular, Ni content in Cu concentrate must be less than 0.6%, otherwise, penalties will apply and diminish the value of Cu concentrate, in addition to the lost Ni value. Generally, a Ni grade of less than 0.4% is obtained in Cu concentrate. More recently, while processing Cu-rich ore, Cu concentrate contained more than 0.6% Ni which is abnormally high. Detailed mineralogical investigation shows that Cu-rich ore contains more millerite in comparison to typical Sudbury Ni sulphide ore. Millerite is found to be more floatable than pentlandite and is much more difficult to depress using high-lime aeration conditioning, which is the standard practice in Cu/Ni separation to float chalcopyrite while depressing pentlandite. The current operation uses sodium cyanide at 20 g/t to depress pentlandite and pyrrhotite. However, it is found that a high dosage is required to depress millerite. It is also shown that starch and dextrin are promising in millerite depression.INTRODUCTIONPrior to bulk smelting in 1991, Cu/Ni separation was carried out at Vale’s Copper Cliff Mill, Ontario Operation. The typical Cu concentrate grade was around 30% Cu and 1% Ni. This is very high in comparison to today’s value of 0.4% Ni and would not be acceptable for external processing. However, the Cu concentrate was processed internally at the Copper Cliff smelter/refinery, so the Ni contained in Cu concentrate was not lost and no actual penalties applied. During the SO2 abatement initiative, bulk smelting was chosen because of the perceived simplicity and consequently, Cu/Ni separation was eliminated (Agar, 1991) and the Copper Cliff mill was subsequently demolished. In 2005 and after more than one decade of bulk smelting, business changes required the removal of some Cu concentrate from Clarabelle Mill bulk concentrate to provide smelter capacity for Voisey’s Bay concentrate in the Copper Cliff smelter. In essence, this strategy calls for Cu removal at Clarabelle Mill (Lawson, 2006). In this case, Cu concentrate is sold externally and it must meet the quality requirement of less than 0.6% Ni."

Jan 1, 2011

By B. H. Kim

It is hypothesized that the standard approach adopted to characterize the ground and to determine the rock strength properties at depth are flawed and generally tend to underestimate the rock strength and possibly the stiffness, particularly when the rock mass is characterized as massive to moderately jointed or blocky to very blocky. It is therefore necessary to conclusively established that the hypothesis, that the rock strength in highly confined rocks is greater than generally anticipated, is actually valid and generally applicable, and then to develop new procedures to establish rock parameters that can be reliably used for the design of deep excavation.

May 1, 2009

By John Lindsay

Outline ??Recovery plant requirements and concepts ??Common recovery plant unit processes ??Recovery plant design considerations ??Peripheral issues Process Design ??Liberation ??Separation ??Recovery Processing ??Density 3.5 g/cm3 ??Luminescent under x-ray ??Hydrophobic (non wettable) surface ??Non-magnetic ??Inert to strong acids / bases

Apr 1, 2005

By P. W. Jensen

Gold deposits in Interior Alaska are commonly coincident in time and space with reduced, mid-Cretaceous granitoids. The True North deposit of the Fairbanks district is several km from such granitoids, but yields mineralization ages indistinguishable from the Fort Knox granite-hosted deposit. True North, however, resembles sediment-hosted epithermal Au, demonstrating the variability of intrusion-related Au deposits in metamorphic rocks. The True North deposit (14M tons at 1.5 gpt) is hosted within a carbonaceous thrust complex separating eclogite facies from amphibolite facies rocks, located > 5 km from mineralized granite outcrops. The ores contain anomalous Sb, As, and Hg (stibnite is the most common sulfide) with ankerite-sericite alteration in steep NE-striking ?feeder? shears and low angle thrust shears. Nearest hornfelsed rocks are located > 1 km away, and across several high-angle faults. Fluid inclusion data indicates trapping temperatures of ~250C from low-density, low-salinity fluids at P < 0.5 kb. Au was originally present as solid solution in sulfides; minable ores are restricted to the oxidized upper 100 m of the deposit. The considerable differences between this deposit and the temporally equivalent Fort Knox intrusion-hosted deposit indicate no one description adequately characterizes this deposit type.

May 1, 2003

By Tony Moore, Peter Riccio

"MMG (Minerals and Metals Group) operates the LXML Sepon’s mineral processing facility located 40 kilometers north of the town of Sepon, in the Savannakhet Province, Lao PDR. The Sepon copper plant produces 70,000 tons/year of LME grade A copper cathode using leachautoclave- SX/EW-flotation technology (Baxter et al., 2003). Pyrite recovery in the flotation circuit is critical to the operation, as it is used to generate acid and soluble ferric ion for the leach circuit. Low pyrite recovery has been an on-going challenge in the flotation circuit. Final tailings characterization work done by Ian Wark Research Institute (Bassell et al., 2006) showed that the pyrite losses to the tailings are made up of a combination of coarse liberated particles and finer particles that have been coated by clay fines.In December of 2005, a joint Cytec-MMG technical program was initiated to address the pyrite recovery issue. A series of diagnostic tests were performed in the Cytec Stamford Research Facility using synthetic plant water showing that the collector was precipitating as a metal salt and was unavailable for mineral attachment. The tests also identified several collector chemistries that would likely be robust in the low pH (< 1), high dissolved metal ion environment and will not complex with metal ions in solution. With the support of the Sepon on-site engineers, an extensive, successful laboratory program was completed, which was subsequently followed by on-plant testing that showed a step wise improvement in pyrite recovery.INTRODUCTIONLow pyrite recovery has been an ongoing problem in the flotation circuit at Sepon. Sulfur recovery (indirect measure of pyrite) was improved from 40% to 65%-75% in mid-2005 when on site laboratory work confirmed that AERO® 8045 Promoter was a more effective collector then AERO® 407 Promoter. However, sulfur recoveries above 65% could never be achieved. Sepon requested the Ian Wark Research Institute to complete a surface analysis study using Scanning Electron Microscopy, X-ray Photoelectron Spectroscopy, and Time-of-Flight Secondary Ion Mass Spectroscopy to determine if clay coated pyrite played a role. It was concluded that the pyrite losses to the tailings are made up of a combination of coarse (+ 100µm) liberated particles and finer (-74µm) particles that have been coated by clay fines. The majority of the losses appear to be due to the former. In December of 2005, a series of diagnostic tests were performed in Stamford using synthetic plant water in order to identify what chemistries would likely be robust in the slimy low pH and high dissolved metal ion solution environment. Results showed that several chemistries would not complex with ferric, ferrous or copper in solution and therefore should perform well in the Sepon flotation. The incumbent collector, AERO® 8045 Promoter was complexing with metal ions in solution. This resulted in the collector not being available for adsorption onto pyrite."

Jan 1, 2011

By Weng Fu, James Vaughan, Stefan Lakemond

Uranium bearing copper sulphide flotation concentrates produced from iron oxide copper gold uranium (IOCG–U) ore contains radionuclides such as 238U, 230Th, 210Pb, 226Ra, 210Po, which have the potential to reduce their marketability, thus posing a challenge to the industry. Thus, a two–stage leach process has been proposed in this study. In first stage, a sulphuric acid leach process effectively dissolve most of the 238U and 230Th into solution, but other radionulclides (mainly 210Pb, 226Ra and 210Po) remain associated with copper sulphide minerals owing to their low solubilities in sulphuric acid solution. In the second leaching stage, the use of methanesulfonic acid (MSA, CH3SO3H) is investigated to selectively dissolve the 210Pb, 226Ra and 210Po from the residue of the first stage. The results indicate that 96% of 238U, 87% of 230Th, 90% of 210Pb, 86% of 226Ra and 17% of 210Po are dissolved using 3 mol/L MSA solution at 90°C for 3 hours, which represents a dramatic decrease in the radioactivity of the copper concentrate. INTRODUCTION Australia is host to one of the largest iron oxide copper–gold–uranium (IOCG–U) deposits in the world. Most of the value in these deposits is associated with copper. In mineral processing, the gangue minerals are separated from copper sulphide minerals that report to a copper flotation concentrate. However, due to the strong association of uranium with copper minerals and hematite, even clean copper concentrates can contain significant amounts of uranium (238U) and its radioactive decay elements, of which thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) are the long life radionuclides. These hazardous radionuclides negatively affect the marketability of the copper concentrates. Customer copper smelters in China, Japan and Europe may consider the radionuclides penalty elements or may not be able to process the feed. Therefore, there is a strong motivation to remove radionuclides from copper concentrates at the mine site before shipping to custom smelters in global market. Hydrometallurgical leaching has been widely employed to remove radionuclides from different kinds of minerals such as copper concentrates (Ragozzini & Sparrow, 1987), zircon concentrates (Aral, Sparrow, McDonald, & Norgate, 2007), and coal ash (Lei, Qi, Sun, Xu, & Wang, 2014). Leaching using sulphuric acid (H2SO4) solutions is the most widely used process for the extraction of uranium from uranium ores due to the relatively low cost and wide availability of the acid (Bhargava et al., 2015; Gilligan & Nikoloski, 2015). The leach process involves treating ground ore slurry with sulphuric acid at elevated temperatures (typically 60–90 °C) under oxidising conditions in order to convert the uranium in the minerals 2+ from the relatively insoluble tetravalent form (UO2) into water–soluble hexavalent state (UO2), which then complexes with SO42- and forms UO2(SO4)22- in solution. The uranium oxidation is generally carried out in the presence of ferric ion (Fe3+), regardless of the reagent and oxidant used. The most commonly used oxidants for uranium include sodium chlorate, pyrolusite and oxygen (Ring, 1980). These oxidants act indirectly by converting ferrous sulphate, formed by the oxidation reaction of UO2 in slurries, into ferric sulphate. The presence of Fe–containing gangue minerals such as hematite in the ore usually provides sufficient Fe required for the oxidation of UO2. After sulphuric acid leaching, the locked thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) elements are chemically liberated from hematite and uranium mineral grains (Ciobanu, Wade, Cook, Schmidt Mumm, & Giles, 2013). However, the extraction rate of radium (226Ra), lead (210Pb), and polonium (210Po) in sulphate solution is very low due to the limited solubilities of (Ra, Pb, Po)SO4 (Bagnall & Freeman, 1956; Liu & Papangelakis, 2006; Nikitin & Tolmachev, 1933).

Jan 1, 2019

By Andrea McGlynn

Iron Ore Company of Canada, Labrador City 2011?Canada&apos;s largest iron ore producer, leading global supplier of iron ore pellets and concentrates ?Rio Tinto (58.7%), Mitsubishi Corporation (26.2%), Labrador Iron Ore Royalty Income Fund (15.1%)

May 1, 2011

By B. M. Coombes

The McCracken and Stacey (1989) method of assessing geotechnical risk for largediameter raisebored shafts has been the basis for most Australian pre-construction raisebore investigations for the past 20 years. At the time of its publication, the McCracken and Stacey (M&S) Method did not include a database of raisebore diameter and rock mass conditions versus actual performance. It did, however, provide a chart that quantified geotechnical risk in terms of proposed shaft diameter and the raisebore rock quality index, QR. Two parameters, RQD/Jn and Jr/Ja were identified as being critical to raisebore stability, but the contribution of these to overall raisebore stability was not quantified. Peck and Lee (2008) published a database of raisebore performance from Australian case histories. Raisebore diameter and ground conditions, in terms of a Lower Bound QR value, were presented for 50 cases versus raisebore performance. This paper updates the database with further case histories and corrected SRF values. This paper further evaluates the reasons for the variable raisebore performance for similar RSR values. For all case histories, three parameters, RQD/Jn, Jr/Ja and Jw/SRF are investigated to assess their influence on raisebore performance.

May 1, 2011

By Nicolae Dobritoiu

The literature in this field and the practical activity record that a method, respectively the technology used for an underground mining work have many components which, in order to be applied, demand that for each of the parameters that describe the environment of the mining work and that influence the chosing of that method and that technology of execution, must have values in an interval well determined. There are situations when one or many parameters of the set of parameters that describe the environment of the mining work, can modify its values, and, as a result, one or more components of the methods or technology cannot be applied anymore, making necessary a replacement of their values. The information offered by this graphical-analytical model allow the determination of optimum solutions for the process of digging of the underground mining work and thus it will result the incresing of the technical-economical efficiency of the digging process and, also the increasing of the quality of the underground mining work.

Oct 1, 2009

By Erwin L. Zodrow

"The neglect of including the toxic metal mercury in the list of escaping elements (Zodrow, CIM Bulletin, September 1982, pp. 138-140) was pointed out to the author in a private letter by J.E. Rehder, dated September 21, 1982. I welcome this opportunity to present my preliminary mercury research data based on coal investigations supported by N.S.E.R.C and the University College.As mercury is a volatile element and liquid at room temperature, special analytical techniques are required to determine concentrations in whole coal. In the investigation, the coal is analyzed by flameless atomic absorption with a lower detection limit of approximately 10 parts per billion, which, however, is a function of the ash contents of the coals (personal communication, J.L. Brooker, XRAL, 1981).Coal seams of the Sydney Coalfield studied so far include: the Point Aconi, a thin shaly coal, the Upper Bonar, an overrider of the Harbour seam, and the Harbour, Shoemaker and McAulay seams, all of which are shown in stratigraphic succession in Figure 1. The seams have been channel-sampled taking 15-cm coal intervals as one sample for analysis. One channel sample has been investigated from each of the seams listed (two channels were taken from the Point Aconi seam), resulting in 38 samples. Table 1 shows the results, which include mercury contents, ash and total sulphur per sample interval. Figure 2 is a frequency distribution of the 38 determinations."

Jan 1, 1982

By Jose R. Hernandez-Aguilar, Chris J. Martin, Rob Thorpe

"This study presents an approach to establishing relationships between metallurgical performance and the characteristics of the bubble population (gas dispersion) inside flotation cells. Bubble size Db, superficial gas velocity Jg, and bubble surface area flux Sb (Sb = 6Jg/Db) measurements were obtained along with metallurgical samples in full-size equipment processing different ore types. The gas dispersion was manipulated by changing the operating conditions of the cells (gas flowrate and frother type) and the metallurgical performance (grade-recovery) was determined. In two cases, the Sb had a strong relationship with grade and recovery, hence, Sb could be used as practical operating parameter. In another case, Sb did not correlate with recovery. The reasons were attributed to creating small bubbles using frothers with desired anti-coalescence properties. This illustrated that bubble size was the key parameter for metallurgy rather than Sb.INTRODUCTIONUnravelling the mechanisms that govern the relationships between metallurgical performance and the characteristics of the bubble population (gas dispersion) inside a flotation cell remains a major challenge. Information on this subject is scarce in the literature, particularly, plant-scale data. The report of Jameson and Allum (1984) appears to be the first gas dispersion study conducted in industrial (mechanical) cells. To introduce concepts, some aspects of their work are reviewed here.The prime motivation of that study was to establish whether any particular cell design (among 44 cells surveyed) could produce very small bubbles (< 0.1 mm), which laboratory research suggested would increase the recovery of fine particles. Although one of the outcomes was that the (examined) cells did not seem to produce such small bubbles (Sauter mean1 D32 ˜ 0.9 mm), the analysis highlighted the importance of including other factors. Jameson and Allum indicated that, besides bubble size (Db), other characteristics of the bubble dispersion should be considered, namely: gas holdup ?g – the fraction of cell volume occupied by bubbles, superficial gas velocity Jg – is the gas flowrate divided by the cross-sectional area of the cell and, bubble surface area flux Sb – the rate of production of (new) bubble surface area (m2/s) per m2 of cell cross-sectional area. It should be noted that, whereas Jg, ?g and Db can be measured directly, the Sb is derived: Sb = 6Jg/Db, where Db is usually substituted by the Sauter mean diameter (D32)."

Jan 1, 2006

By R. Sharon, P. M. Hawley, X. Ochoa

"Development of Barrick Gold’s Pierina gold mine in north-central Peru requires construction of a waste dump for disposal of nonore grade materials stripped from the open pit to expose the ore. The waste dump site is located near the open pit in a U-shaped valley that is underlain by thin colluvial and morainal soils with locally thick peats and glaciolacustrine deposits. Bedrock underlying the site consists of variably weathered volcanics. The site is subject to moderately high seasonal rainfall and significant seismicity. The geotechnical quality of the waste rock is highly variable, ranging from low-quality, degradable, soil-like materials containing appreciable quantities of silt and clay, to high-quality, hard, durable, blocky waste rock.A hybrid dump design concept was developed that requires in-pit segregation of highand low-quality waste, and selective placement of materials in the dump to maximize stability and enhance internal and subsurface drainage. The design includes a rock drain beneath the dump along the axis of the valley and a series of connected finger drains. Extensive peripheral diversions and stormwater control measures to inhibit infiltration of precipitation are also included.This paper discusses the unique challenges presented by the site and waste materials, the design methodology and stability analyses, and planned monitoring systems."

Jan 1, 2003

By E. S. Yan, R. Graley

"The StackCell was developed to overcome the engineering and design challenges that are commonly associated with existing flotation technology such as pneumatic, self-aspirating cells, mechanical cells, and flotation columns. These challenges include high energy consumption, large floorspace requirements, and size. They are most evident when designing systems to process streams containing a high volumetric flow rate coupled with a significant float yield. Unlike many metalliferous and industrial mineral applications, fine coal flotation circuits are typically characterized by feed streams containing a low solids content (<5%, by weight) where up to 85% of the feed can report to the product launder. With input from major engineering houses and end-users, the Eriez Flotation Division (EFD) developed the StackCell technology with the goal of providing an additional flotation option for end-users. This technology was designed specifically to overcome these challenges by providing an efficient method of separation in terms of metallurgy, but also with respect to equipment size, energy consumption, and installed costs. Besides being placed in tandem with existing cells to provide cost-effective supplemental capacity, this technology can be installed in a stand-alone arrangement as recently demonstrated at Patriot Coal’s Kanawha Eagle preparation plant. This manuscript provides an understanding of the underlying fundamentals of this new technology and presents data from Kanawha Eagle in addition to other industrialscale installations.INTRODUCTIONOver the past decade, column flotation has continued to gain acceptance as an alternative method for recovering fine coal due to superior metallurgical performance as compared to mechanical flotation cells. This point has been proven on numerous occasions by comparison of plant flotation data with the release analysis separation curve (Dell et al., 1972). Data from a release analysis test approximates the ultimate flotation response of a coal sample. In North America, a number of investigations have been published that document bottom-line improvements achieved using column cells (Luttrell et al., 1999; Kohmuench et al., 2004; Baumgarth et al., 2005). According to these reports, the benefits are derived from an overall increase in plant yield that can be achieved due to the improved product grade in the flotation circuit. In particular, the application of wash water to a deep froth utilized in column flotation minimizes the nonselective recovery of high-ash ultrafines that are hydraulically entrained in the froth by conventional flotation machines."

Jan 1, 2013

By M. Rantapaa

Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the open pit and process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput. Better fragmentation and a subsequent increase in mill throughput were achieved through the use of electronic caps for more precision and flexibility, as well as for allowing extremely fast shots; explosives with a higher velocity of detonation (VOD) to provide for improved shock energy; and improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by 6 tph in 2003 due to the improved fragmentation of the hard ore. Barrick Goldstrike?s D2M initiative includes roaster hard ore (BWI>17), as well as autoclave hard ore (BWI>15). Approximately 6 million tons of D2M material were shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs.

Jan 1, 2005

By R. Mckinstry, M. Rantapaa, T. Bolles

"Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the open pit and process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput.Better fragmentation and a subsequent increase in mill throughput were achieved through the use of electronic caps for more precision and flexibility, as well as for allowing extremely fast shots; explosives with a higher velocity of detonation (VOD) to provide for improved shock energy; and improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by 6 tph in 2003 due to the improved fragmentation of the hard ore.Barrick Goldstrike’s D2M initiative includes roaster hard ore (BWI>17), as well as autoclave hard ore (BWI>15). Approximately 6 million tons of D2M material were shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs."

Jan 1, 2005

By T. Hidayat, D. Shishin, S. Sineva, M. Shevchenko

The effects of the slagging components Al2O3, CaO and MgO on the thermodynamics and phase equilibria of the gas/slag/matte system with major elements “Cu2O”-“FeO”-SiO2-S are characterised using an integrated experimental and thermodynamic modelling approach. The experimental technique included high-temperature equilibration experiments using a spinel substrate in controlled gas atmosphere (CO/CO2/SO2/Ar), quenching of the sample and subsequent measurement of the compositions of equilibrium phases with Electron Probe X-ray Microanalysis (EPMA). Thermodynamic modelling is undertaken using the computer system FactSage. In previous experimental studies on this system, the separate effects of Al2O3, CaO and MgO were determined. In the present investigation, the combined effects of these additional components are investigated at 1200oC and P(SO2) = 0.25 atm and a range of P(O2)’s. Special attention is paid to ensuring chemical equilibrium is achieved in each case, for this reason possible kinetic factors are systematically analysed. The results obtained are presented in the form of graphs showing the compositions of matte and slag phases as functions of copper concentration (matte grade). The new experimental data are used for the improvement of the thermodynamic database for multicomponent copper-containing systems. The effects of the slagging elements on this multicomponent system will be presented in the paper. INTRODUCTION Whilst Fe-O-Si form the principal components of copper smelting and refining slags, additional impurities are present in industrial practice typically at 2–5 wt.% Al2O3, 1–4 wt.% CaO and 1–2 wt.% MgO levels (Davenport, King, Schlesinger, & Biswas, 2002). These elements are introduced into the slag as impurities in concentrates and other feedstocks, in fluxes added to the process and in refractory materials. Understanding, and accurate description, of the changes that take place in the smelting process in the presence of these additional elements is of major importance to the optimization of industrial operations. Although experimental data are available on slag/copper matte equilibria, further work is needed to accurately characterise the influence of Al2O3, CaO and MgO on phase equilibria and elemental distributions of elements in gas/slag/matte systems. The individual effects of the Al2O3, CaO and MgO slagging components on equilibrium phase assemblages under selected conditions have been quantified in a recent series of studies on the Cu–Fe–O–S–Si-(Al, Ca, Mg) gas-slag-matte-metal system (Fallah- Mehrjardi, Hayes, & Jak, 2018; Fallah-Mehrjardi, Hidayat, Hayes, & Jak, 2017a, 2017b; Hidayat, Fallah-Mehrjardi, Hayes, & Jak, 2018a, 2018b; Jak et al., 2016; D. Shishin, Decterov, & Jak, 2018; Denis Shishin, Hayes, & Jak, 2018). Since, thermodynamically, the condensed phases do not behave ideally, it is to be expected that the effects of individual elements may not be additive, and the additional interactions between the Al2O3, CaO and MgO slagging components will also have to be taken into account. These additional effects are expected to be smaller than those of the individual components, so higher accuracy is needed. The present paper describes analysis of the precision and accuracy of the experimental technique on multi-component, multi-phase equilibria in these systems to enable the combined effects of Al2O3 + CaO + MgO on slag/matte/spinel equilibria, i.e. for high Fe/SiO2, to be accurately measured. The effects of Al2O3, CaO and MgO on the gas - slag - matte are analysed using a thermodynamic modelling approach with the computer package FactSage.

Jan 1, 2019

By N. Romani, R. Provost

"Commissioning of a circulating dry scrubber (CDS) plant was recently completed at an existing facility in Québec, Canada. The CDS plant treats the sulphur dioxide off-gas emitted from rotary kilns in order to meet increasingly stringent environmental requirements. This installation enables the existing facility to reduce their sulphur emissions by over 90%.Proper planning of the different commissioning stages and staffing an integrated team are the most important factors required for a successful plant start-up. A strong Operational Readiness plan must be in place as early as the start of construction in order to ensure a smooth transition from commissioning to operations. Plant performance can meet or exceed performance criteria within the required timeframe if the proper group dynamic and good communication is established between construction, commissioning and operations teams.The road blocks encountered are often from systems that one assumes will operate without trouble such as air-conditioning, or design assumptions that were taken years earlier in feasibility process stages, namely the capacity of existing systems that will connect the new plant to the existing facilities. The challenges associated with rectifying these issues in addition to the requirements to properly start-up and operate a new plant without impacting production are great, and it is imperative to have the necessary resources to react quickly to any problems.IntroductionCommissioning of a circulating dry scrubber (CDS) plant was recently completed at an existing facility in Québec, Canada. The CDS plant treats the sulphur dioxide off-gas emitted from rotary kilns in order to meet increasingly stringent environmental requirements. This installation enables the existing facility to reduce their sulphur emissions by over 90%.The CDS ProcessA general overview of the CDS process is presented in Figure 1 below. The combined, de-dusted off-gas from multiple kilns is sent to the CDS, which acts as an entrained fluid bed, where the gas is contacted with a water mist, re-circulated solids and hydrated lime. The SO2 from the gas stream and the available calcium hydroxide (Ca(OH)2) from the hydrated lime dissolve in the water and react to ultimately form calcium sulphites and gypsum. The solid residue (referred to as CDS residue), is the primary by-product of the process."

Jan 1, 2016