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By Brian Putland

Single stage semi-autogenous / autogenous (S/AG) milling has become a common design for a variety of ore types with the advantages of being comparatively low capital cost and flexible for future expansion. The single stage SAG/AG milling option is ideal for starter projects with significant exploration and expansion potential. Currently a number of the largest SAG mills designed are installed in single stage configuration. This paper discusses the challenges associated with the process design of single stage SAG/AG milling circuits, the design flexibility required to ensure a robust circuit and the operating techniques adopted at successful installations.

Jan 1, 2012

By M. P. Rennick, D. M. Burton

The Murray Brook massive sulfide deposit, which was the first geochemical discovery in the Bathurst camp, is one of the largest sulfide deposits in the area. The massive sulfides are hosted by quartzose metasedimentary rocks in the lower part of the Ordovician Tetagouche Group. This thick succession of sedimentary rocks is overlain conformably by felsic volcanic rocks, and is structurally overlain by mafic volcanic rocks. The massive-sulfide body is polydeformed, but primary metal zoning is still discernable and may permit future exploitation of discrete lead-zinc and copper zones. Although it was discovered in 1956, the deposit was not developed until 1989, when Murray Brook Resources commenced processing of gossan containing precious metals. Recovery of gold, silver, and mercury is accomplished by indoor vat leaching on a year-round basis.

Jan 1, 1992

By L. Torres, C. S. R. Rondestvedt, M. Bustos

In February 2010, Teck’s newest Concentrator at Mina Carmen de Andacollo (CDA), Andacollo, Chile was commissioned. The Concentrator is a single line configuration, comprising of one 36 ft diameter x 20 ft long SAG mill driven by an 18,000 hp gearless drive. The SAG mill feeds two ball mills each 25 ft in diameter x 40.5 ft long, each driven by a total of 19,000 hp through dual pinion drives. A series of four phases will be reviewed from operational readiness, mechanical completion, commissioning, and ramp-up. Also, now after 6 months of operation, this paper will review the significant steps taken during ramp-up enabling the announcement of commercial production, in October 2010.

Jan 1, 2012

The mechanism of thiosulfate decomposition and the products formed were investigated in the presence of pyrite or pyrrhotite in copper-ammonia solutions used for leaching gold. The presence of the sulfides significantly increased the decomposition of thiosulfate. The sulfide-surface-catalyzed oxidation of thiosulfate to tetrathionate by dissolved oxygen or the cupric tetra-ammine complex was proposed to be the dominant thiosulfate decomposition mechanism. The catalysis of the sulfides in this reaction could originate from their strong affinity for aqueous sulfur species and their semiconducting properties. Oxygen was found to be the initial driving force for thiosulfate decomposition in the absence of cupric ions and the driving force for the continuous decomposition of thiosulfate in the presence of cupric ions. Under an oxygen free atmosphere, the decomposition of thiosulfate was limited to reduce the cupric ions and the catalytic effect of the sulfides was also marginal. The dominant oxidative product of thiosulfate was trithionate in alkaline solutions especially in an oxygen rich or cupric ion rich environment. Tetrathionate was found in relatively smaller amounts in an oxygen and cupric ion deficient environment. Tetrathionate was not stable and would further decompose after extended periods. Trithionate concentrations increased almost linearly with time.

Jan 1, 2005

By Kenta Suzuki, Toshiya Anami, Daisuke Shimosaka

"In an Al-Mn alloy heat exchanger fin stock, the effect of annealing conditions for as-cast and 0.1%Zr addition on recrystallization behavior is investigated using metallurgical analysis. Refinement of post-brazed recrystallized grains in fin stocks with Zr addition are suppressed for long-time annealing. In 0.1%Zr fin stocks, there was a decrease in the number of fine a-Al(Mn,Fe)Si dispersoids for pinning of sub grain and grain boundary. In addition, relatively homogeneous distribution of Al3Zr dispersoids was observed with increasing annealing time in as-cast. Homogeneous distribution of Al3Zr dispersoids can have a major effect on pinning of sub grain and grain boundary during brazing heat treatment. The homogenous distribution of fine dispersoids prior to brazing heat treatment is effective in causing the suppression of refinement of post-brazed recrystallized grain structure in aluminum alloy fin stocks.INTRODUCTIONAl-Mn based alloys are widely used as fin stocks in automotive heat exchangers because of their superior mechanical properties, braze ability, sagging and so on. In particular, coarsening of recrystallized grain structure is beneficial to avoid erosion, and achieve excellent sagging resistance (Lee, Yoon, Kim & Jung, 2002). For resisting grain coarsening, the alloys should contain a dense and homogeneous distribution of fine dispersoids to retarder crystallization (Humphyreys& Hatherly, 2004). It has been demonstrated that addition of Zr to Al-Mn alloys can shift recrystallization to higher temperatures because of the distribution of fine Al3Zr dispersoids in matrix(Pokoba, Cieslar& Lacaze,2012). According to Tohma, Asanoand Takeuchi (1987), coarsely recrystallized grain structure was obtained in 3003alloy with Zr addition after heat treatment. However, fine Al3Zr dispersoids are usually heterogeneously distributed because of segregation during casting and low diffusion rate of Zr in aluminum. Therefore, a homogeneous distribution of Al3Zr dispersoids can be achieved through long-time precipitation annealing(Jia, Hu, Forbord& Solberg, 2008)."

Jan 1, 2018

By J. L. Luo, D. G. Ivey, A. H. Adeleke

Double-edge-notched flat tensile samples of X70 steel were used for both slow strain-rate testing (SSRT) and cyclic loading testing with the notch located in the zone of interest, i.e., the weld metal (WM), base metal (BM) and heat affected zone (HAZ). By using both optical and scanning electron microscopy, the stress corrosion cracking (SCC) behaviour with respect to crack morphology and various forms of microstructure was investigated. In all the samples considered, the mode of failure was predominantly transgranular with cleavage facets around the edges of the fracture surface. The BM, with a bainitic microstructure, had the highest resistance to SCC when compared with the mixed microstructures of acicular ferrite-primary ferrite and acicular ferrite-grain boundary ferrite observed in the WM and HAZ, respectively. The effect of microstructure on stress corrosion cracking behaviour is discussed based on experimental observations.

Jan 1, 2005

By J. Shibata, N. Murayama

"Rare earth elements are present in more than 100 minerals, of which monazite, bastnaesite and xenotime are typical. Rare earth elements have excellent chemical and physical properties for industrial use in functional materials such as phosphors, magnets, electronic components, abrasives and catalysts. China produces more than 90 % of the world’s rare earths, and Chinese trends significantly influence the demand and price of rare earths. From the viewpoint of resource securement, it is desirable to separate and recover rare earth elements from low-grade resources and wastes. Phosphate gypsum, which is a by-product of wet phosphoric acid manufacturing, contains low concentrations of rare earth elements. In this research, the separation and recovery of rare earth elements from phosphate gypsum were investigated. A series of recovery methods including washing of phosphate gypsum, leaching of the rare earth elements with sulfuric acid, adsorption and desorption of rare earth elements by using ion-exchange resin, and precipitation of rare earth oxalates were carried out. The separation of rare earth elements from Ca2+ simultaneously leached from phosphate gypsum was also investigated."

Jan 1, 2014

By Youngsoo Song, Hyunjung Kim, Junhyun Choi, Siyoung Q. Choi, Gahee Kim

In this study, for the first time, to confirm the effect of bacterial growth phase on the malachite flotation were investigated in a well-controlled Hallimond tube system. The test results showed that the bacteria in the stationary phase exhibit two-fold greater floatability than those in mid-exponential phase. To understand the observed flotation behavior, complementary cell characterization tests and cell attachment tests were conducted. Interestingly, the bacteria at both phases exhibited similar surface properties as well as almost identical amount of cells attached onto the malachite, suggesting that the growth phasedependent flotation behavior cannot be attributed to the variation of cell surface properties and the extent of cell adsorption. On the other hand, cell detachment tests revealed that the amount of cells detached from the malachite surface is greater for the mid-exponential phase than the stationary phase due to the higher fluid drag applied to the cells at the mid-exponential phase, which was explained by the differences in the size and shape of attached bacteria onto the malachite surface. These morphological characteristics were found to cause the bacteria of mid-exponential phase to be separated highly sensitive and easy from malachite surface due to the fluid flow. Second, scale-up selective bioflotation tests were carried out in a 1 L Denver cell in malachite–silica binary mixture systems. Through the tests, we optimized the cell concentration and the malachite fraction in the feed. Overall, high malachite selectively was observed under optimized conditions (both recovery and grade showed more than 90%). The trend was in agreement with classical DLVO interaction energy profiles, which show the relative magnitudes of the adhesive forces between the mineral and the attached cell under equal hydrodynamic conditions.

Jan 1, 2016

By D. Kovachevich, M. A. Pfeifer

"A t remote locations typical of mines and associated ore processing plants, diesel electric generators are ideally suited for power plants due to their inherent operating flexibility, efficiency and reliability. In recent years rapid escalation in fuel and related transportation costs has made extensive waste heat recovery from generating sets financially attractive to a much greater extent than previously.The paper outlines key considerations during planning and design stages for utilizing the various waste heat sources available to best advantage. Based on two /980 mining projects built in the Canadian Arctic, data is presented on potential operating and capital costs savings. A review of heat balances, engineering flow diagrams and major equipment selections for process and building heating systems utilizing waste heat is included.IntroductionResource projects increasingly occur in remote areas requiring on-site self sufficiency in electrical power generation. For such projects, the low- or medium-speed turbo-charged diesel engine is very often the preferred choice as a prime mover for the generating sets . It is inherently reliable, has good response to load changes and has comparatively high fuel efficiency over a wide load range . From a project execution standpoint, It is capital cost- competitive and procurement lead-time normally ' fits ' within tight schedule constraints. In addition, its potential for waste heat recovery is excellent , particularly in northern climates where space heating requirements are usually substantial, and also where there a re requirements for heat for process and plant services.The high cost of fuel , with add-on transportation costs , provides a major incentive to fully exploit the available waste heat recovery potential o f such installations.As a result of the rapid escalation in the price of petroleum products following major crude oil price increases in 1973 and again in 1978-79, liquid petroleum fuels, having the desirable properties of comparatively high heat content and transportability, are no longer 'cheap' commodities and have become so valuable that industry has widely undertaken serious conservation efforts.Currently, it appears that petroleum cost trends of the 1970s may not continue, at least in the near term, and that we may see somewhat reduced energy costs for a time. In the longer term , and certainly within the life spa n of major projects, however, it is generally believed to be inevitable that these fuels will be increasingly expensive . Energy costs are today a major operating cost for remote minerals processing plants and will remain so for the foreseeable future.In order to meet the economic challenge posed by high energy costs, future projects should be thoughtfully planned from the outset with the goal of minimizing energy requirements and maximizing the use of waste heat recovery to meet such requirements. There is also considerable potential for significant energy savings by retrofitting of existing installations."

Jan 1, 1984

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016

By K. B. Han, S. Winkler, M. J. Benoit, M. J. Worswick

"Automotive heat exchangers are fabricated by forming multi-layered aluminum (Al) alloy brazing sheets into the desired geometry and subsequently passing the assembly through a furnace for brazing. As manufacturers seek to use thinner gauge and higher strength sheet to reduce vehicle weight, forming of the Al alloy sheets has become a challenge. Warm forming has previously proven to allay these forming concerns, but no consideration was given to the effect of increasing the forming temperature on brazing. Recently, it was shown that annealed sheet was more susceptible to the detrimental phenomenon of liquid film migration (LFM) during brazing if formed above 150°C, while work hardened sheets showed no increased susceptibility to LFM with increasing forming temperature, up to 250°C. In the current study, the brazing performance of simulated battery cooling plates was investigated. The plates were fabricated both from fully annealed and work hardened sheets. Brazing was assessed by microstructural evolution during a brazing cycle. The post-brazed microstructure varied with strain and forming temperature in plates made from annealed sheets, while no variation in microstructure with location or forming temperature was observed in plates formed from work hardened sheets.INTRODUCTION Since the 1970’s, one common method of fabricating automotive heat exchangers has been by forming multi-layered aluminum (Al) alloy sheets, and subsequently brazing the formed components together in a controlled atmosphere furnace. The Al alloy sheets used are comprised of at least two Al alloys roll bonded together, but can consist of additional layers, depending on the application; at minimum, the sheets are comprised of a core and clad layer. The core layer, often an AA3xxx alloy, remains solid throughout processing and provides strength to the assembly. The clad layer is always one of the AA4xxx series alloys which, due to their high silicon (Si) content, have a melting temperature range well below that of the core alloy. When the sheet is passed through the brazing furnace, the clad alloy melts to provide the brazed joint filler metal throughout the assembly, while the core alloy remains solid. In order to achieve cost and weight savings, heat exchanger fabricators have used Al alloy sheets with reduced thickness. However, deformation and brazing of these increasingly thin components remains a concern (Zhao & Woods, 2013). Furthermore, springback has been observed after forming sheets of higher initial strength (i.e. work hardened conditions), leading to flatness issues of formed components. Consequently, the ability to form high quality brazed joints is difficult in components formed from higher strength brazing sheets."

Jan 1, 2018

By N. Giguère

Until recently, the heat treatment of pressure die cast parts has always been considered unpractical because the solution heat treatment resulted in unacceptable blistered parts. This was due to the presence of massive porosity associated with the die casting process where the inflow of metal inside the mold cavity is extremely turbulent. With the steady improvement of foundry practices and the generalization of vacuum die casting, porosity defects have been reduced to the point that a partial solutionizing heat treatment can be applied without any damage to the casting. However the solutionizing temperature must be lower than that applied to macroporosity free castings and for much shorter time. The object of the present study was to determine the optimum solutionizing temperature that can be applied to aluminum 383 die cast brackets along with the optimal temperature and time of aging resulting in the highest improvement in mechanical properties (both strength and ductility). This was done by testing strength and deformation on the casting itself using a specially designed jig; the crushing force to deformation curve was analyzed so as to quantify the improvement in both strength and ductility gained with the partial precipitation hardening heat treatment.

Jan 1, 2011

By D. Letzig

Wrought magnesium alloys are of special interest as lightweight structural components as a result of their more homogeneous microstructures and improved mechanical properties compared to cast components. Extrusion as a shaping technology offers the possibility to produce a wide variety of magnesium alloy profiles. In this contribution we describe the role of extrusion parameters such as extrusion speed, ratio and temperature as well as the type of extrusion process on the microstructural development of AZ-series magnesium alloys and the resulting mechanical properties. The effect of microstructure on the tensile/compression deformation behavior of the alloys has also been investigated. Aspects of process optimization designed to overcome technical and economic limitations and thus establish magnesium alloy profiles for industrial applications will also be discussed.

Jan 1, 2006

By K. Sugawaral, W. Tongampl, K. Hiruta, Takasaki Y., A. Hosoi, T. Katol, A. Shibayamal

Printed circuit boards of discarded personal computers, televisions, mobile phones and so on contain a significant amount of valuable metals. For the recycle of valuable metals contained in the printed circuit board wastes (P CB W), the effect of temperature on chlorination-volatilization of metals under chlorine gas flow was studied. The experimental sample used was powder of two types: crushed PCBW (Sample 1) made from PC and industrial machines, and crushed-combusted PCBW (Sample 2) made from Sample 1. The principal element in Sample 1 and Sample 2 was copper, about 13 wt% and 20 wt% respectively. Sample 1 was composed of pure metals such as copper, tin and lead. In comparison, Sample 2 consisted of oxide metals such as copper oxide, tin dioxide and silicon dioxide. The two samples were heated at predefined temperatures (ranging from 300 °C to 900 °C) in chlorine gas. The chlorine gas flow into the furnace was set at a rate of 100 mL/min. As a result, copper in Sample 1 began to volatilize at 600 °C and completely vaporized at 700 °C. While in Sample 2, copper started to volatilize at 600 °C and reached 100% vaporization at 800 °C. For Sample 1, zinc finished volatilizing at 500 °C, while for Sample 2, zinc volatilization reached only about 80% (maximum). Also, lead, nickel and titanium showed similar results. Consequently the volatilization rate of Sample 1 is higher than Sample 2 and the temperature dependency was verified for copper, lead, zinc, nickel, antimony, titanium and chromium. In fact, the volatilization rate of these metals increased with the temperature. This result reflects the difference between pure metal and metal oxide, as Sample 2 was combusted before the chlorination-volatilization test. Moreover, the chlorination reaction may be accelerated by a reductive atmosphere because Sample 1 contains carbon. In this study, the volatilization behavior of some valuable metals in PCBW by chlorine gas was observed. Further improvement in the rate of volatilization can be achieved by optimizing the experimental conditions.

Jan 1, 2011

By C. Juers

Laboratory chromate coating was applied on AM50 and AZ91D alloys and compared to phosphate-permanganate one. Evaluation of the corrosion behaviour was performed using electrochemical DC and AC methods in ASTM water D1384-87. This electrolyte was chosen because it was moderately aggressive and found to give generally good correlations with long period exposure results in atmospheric conditions. Electrochemical impedance spectroscopy was used to determine more accurately the corrosion rates from the analyses of the high frequency capacitive loop. Anodic polarization was applied in order to evaluate the pitting resistance of the different coatings. These results were correlated with weight loss data evaluated from experiments performed by immersion tests in ASTM water D1384-87 and climatic cyclic chamber tests.

Jan 1, 2006

By P. Chollet, A Constant

THE RESULTS of a previous investigation ( 1) on the work-softening of some heat-treated steels have led to the conclusion that the occurrence and intensity of the phenomenon is possibly governed by the work-hardening capacity of the material, and the relative amount of retained austenite. The first assumption is compatible with Polakowski's theory (2) that the absence of work-softening, in steels quenched and tempered at relatively low temperatures, may be attributed to the high rate of work-hardening which compensates for, and even out-weighs, the loss of internal energy associated with the simultaneous rearrangement of the original system of internal stresses. Indeed, Polakowski first considered the work-softening as a manifestation of a partial release (by cold-working) of the latent strain energy stored in

Jan 1, 1962

By Neil Schofield

"The estimation of recoverable ore reserves for feasibility in precious metal deposits such as Pine Creek must account not only f or the extreme variability of the ore grade but also for the complexity of the geology. Compatible models f or both must be adopted. Further, very selective mining demands reserve estimates be based on small selection units whose individual grades cannot be estimated reliably from the exploration drilling data.Multigaussian kriging is one method based on a multivariate normal model for estimating recoverable reserves under such conditions. In this paper, a non-mathematical description of the multigaussian model is presented together with its application to the Pine Creek Gold Deposit. The results, when compared to the first year of production, are encouraging for the model but not without surprises.Together, Part 1 and Part 2 of this study combine a detailed and geologically conditioned variogram analysis with an appropriate estimation method for a highly variable low-grade gold deposit. This and other studies of gold deposits familiar to the author show convincingly both that while the appropriate geostatistical skills and techniques are necessary to tackle the question of reserves, equally important but often discounted is the need for an appropriate and compatible geological model. IntroductionThe Pine Creek gold mineralization is associated with saddle reefs, and quartz and quartz- sulphide veining within the Enterprise Anti cline. The anticlinal structure is complex and, prior to mining, the mineralization was considered to be mainly strata controlled. Grades vary up to 160 grams in l .5rn core samples with coefficients of variation in excess of three.The estimation of the recoverable reserves for such a depo sit must account for both the geological complexity and the extreme variability of the gold grade.Part 1 of this work presented the geological model for the deposit and summary statistics 0 f the gold data. A detailed structural and variogram analysis considered both gold grades and the normal score (or gaussian transform) of these gold grades for different composite sizes."

Jan 1, 1988

By E. Ghali, B. Arsenault

Aluminum alloys play an important role in the manufacturing of air and ground vehicles. However, with such alloys, corrosion damage is often found on structural components subjected to fatigue loading. The alloying provides large benefit in terms of the high specific tensile strength (ultimate strength/density ratio) to the aluminum alloy but causes the aluminum alloy to be more sensitive to localized corrosion due to complex microscopic heterogeneities such as secondary phases. This paper investigates thermal spray coating namely arc spraying to evaluate the protection against environmentally assisted cracking (EAC) and localized corrosion on Aircraft structural 7075 T651 aluminum alloys. In particular, EAC and pitting corrosion at the interface coating-substrate are a challenge for thermal spray protective coatings on aluminum alloys under cyclic load and immersion. To address these issues, different surface preparation techniques prior to arc spraying were considered such as chemical de-oxidation, laser ablation, shot peening and grit blasting. Results indicate that surface preparation and improved coating process parameters play an important role to provide a coating conferring a protection against both localized corrosion and EAC.

Jan 1, 2006

By Nabeel Khan

Annual oil production from the Canadian Oil Sands in Northern Alberta has been rising for several decades, and more ore and overburden are excavated each year from an increasing number of open pit mines. Overburden meeting certain specifications will be used to dam tailings and fill open pits, but the remaining material must be stored in overburden storage structures (OBSS). Well-designed overburden storage structures are more stable and cost less in the short- and long-term. The purpose of this paper is to explore OBSS designs that will be stable yet economical in the short- and long-term. The geological background of the site is briefly discussed, including the effect of each of the main geologic layers (recently deposited till and muskeg, Clearwater Formation clay shales, McMurray Formation oil sands, and the Devonian limestone) on the slope stability of the OBSS. Cost is considered in the analysis when balancing between minimizing costs (steeper slopes) and acceptable factors of safety (flatter slopes), all the while considering the financial consequences of failure. Potential failure planes are identified and probabilistic analysis is conducted on the critical failure surface. The variations in the factor of safety caused by varying pore water pressure, friction angle, and cohesion, are plotted and discussed.

Jun 1, 2012

A study was made to determine the effect of increasing concentrations of dissolved oxygen on the floatability of galena pyrite and chalcopyrite. Adsorption, flotation and contact-angle tests were done in deoxygenated, in air-saturated and in oxygen-saturated solutions. The results showed that the adsorption of collector increased as the concentration of oxygen increased. Adsorption followed the exponential law r = kC'/"• Discontinuities in the curves were observed after the adsorption of several monolayers of collector. Although adsorption increased with increasing oxygen concentration, the floatability of the pyrite minerals did not increase, because oxidation had adverse effects on the floatability of these minerals. The floatability of galena was maximum in oxygen-saturated solutions, pyrite was depressed and chalcopyrite was also slightly depressed. Contact-angle tests proved that a bubble could not be attached to large flat surfaces in deoxygenated solutions, because sufficient surface free energy was not available for adhesion after the deformation of the bubble. In the presene of air, all the minerals yielded the same maximum angle of 72 degrees, characteristic of isopropyl xanthate.

Jan 1, 1970