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By David W. Mogk, Tamara Darsow, Macgregor L. Fogelsong, Robert M. Hunter, Frank M. Stewart, Edwin H. Abbott, Courtney A. Young

Abstract: Development of cost-effective techniques for recovering precious metals from their ores has been the goal of metallurgists for hundreds of years. Today, metallurgists are increasingly called upon to design processes for ores that are refractory to conventional recovery techniques. These challenges and the addition of environmental costs (including site remediation) to the total cost of mining have stimulated a search for alternatives to conventional processes, such as cyanidation. This paper describes the progress made to date in development of an innovative alternative to cyanidation, termed bisulfide leaching, for extracting gold, silver and platinum-group elements from refractory ores and concentrates. While bisulfide leaching can be implemented abiotically, significant benefits accrue from its practice as a bioprocess that integrates the steps of precious-metals liberation and extraction. In many applications, bisulfide leaching appears to offer significant advantages over the traditional cyanidation process. Dissolved bisulfide and hydrogen sulfide are much less toxic than dissolved cyanide and hydrogen cyanide. Recommended workspace exposure limits and harmful concentrations for hydrogen sulfide gas are higher than those for hydrogen cyanide gas. While the facilities required to practice the bioprocess on an industrial scale would be similar to that of cyanidation plants, chemical reagent costs could be 80 percent less. The bioprocess may also offer advantages in the leaching of ores and concentrates that are not amenable to cyanidation. For example, bisulfide leaching of ores containing carbonaceous material may produce higher gold recoveries if the "preg-robbing" characteristic of the material can be controlled biologically or with dissolved sulfide binding. Moreover, in that precious metals are much more soluble than base metals in bisulfide solutions, bisulfide leaching offers distinct advantages over cyanidation for selective dissolution of precious metals from base-metal concentrates. Thus, the bioprocess uses the natural sulfur cycle to mitigate pollutant production and to enhance precious-metals recovery.

Jan 1, 1998

By Shae K. Kim

The aim of this study is to manufacture magnesium alloys with alkaline earth metal oxides (BeO, CaO, MgO or SrO) additions with the objectives of (1) ensuring safety during processing and applications by raising the ignition temperature and reducing oxidation, (2) protecting the environment by reducing or eliminating use of protective gases, (3) maintaining or improving elevated temperature properties with lower amount of Ca or Sr or rare earth metals when compared with conventionally developed high-temperature magnesium alloys, (4) developing cleaner strip casting and continuous casting processes without hot tearing and (5) obtaining all of these objectives without sacrificing mechanical properties or increasing the cost of magnesium alloys.

Jan 1, 2006

By S. E. Malouf, W. Thorpe

"The Chibougamau Explorers property comprises 35 claims or 1,726 acres in La Dauversiere and Rohault Townships along the west shore of Norhart Lake. The property is serviced by a twelve-mile all-weather high-way leaving the main St. Felicien-Chibougamau highway at mileage 121. This road junction will be a railway siding on the C.N.R. St. Felicien-Chibougamau branch line in early 1957. The property lies 30 miles due south from the town of Chibougamau. The mine-sponsored Chibougamau Explorers town has a population of 250 with 28 residences and a well equipped recreation centre.The original showing was found by Rider Storn, a prospector financed by Val d'Or interests during the 1950 field season. This showing did not stand up to detailed prospecting but it did lead to the discovery of the main zone by A. Oakley during the following winter.The company was incorporated in I 950 under the presidency of E. Ayrhart. Financing following the initial drilling involved an increase of capitalization from 3 to 5 million shares and the advent of financing and management control by Anacon Lead Mines Limited.Exploration and development to Jan. I, 1956, has included 42,331 feet of surface diamond drilling; 31,363 feet of underground drilling; a 3-compartment shaft to 1,245 feet, with 8 levels at 150-foot intervals; and I 1,054 feet of drifts, crosscuts, and raises. Ore reserves to the 900-foot level, proven and partly developed, total 546,725 tons averaging 0·30 ounces gold and 0·93 per cent copper. A mill with capacity of 500 to 750 tons will be installed by January 1956.GeologyThe Chibougamau Explorers property lies along the belt of Keewatin volcanics striking through Bachelor Lake, Opawica Lake, Doda Lake, Coapatina, Norhart Lake, and Rohault Lake, where it is in close proximity to the paragneisses of the Grenville series. The boundary of the paragneisses, a gradational contact, lies within a mile of the Chibougamau Explorers shaft collar."

Jan 1, 1949

By Maurice Hall Haycock

ONE result of the higher price of gold has been the exploitation of many low-grade deposits, the successful treatment of which depends upon obtaining high recovery of the contained gold. Modern methods have made it possible to recover gold from many ores formerly regarded as impossible to treat economically, but in order to apply these methods efficiently it has become desirable, and indeed in many cases indispensable, to gain precise information concerning their mineralogical and physical character. The most successful means of doing this is the use of the reflecting microscope. Reflecting microscopes had long been employed by metallurgists for studying polished surfaces of iron and steel when, thirty years ago, Dr. W. Campbell, of Columbia University, advanced the idea of using similar methods for studying opaque minerals (1). The immediate result was the completion of two microscopic studies, the first on Cobalt silver ores (2) and the second on Sudbury nickel ores (3). The idea was surprisingly slow in being adopted, and not until 1911 did it begin to spread through the universities of this continent. From then on, ore microscopy, or 'mineragraphy', made rapid progress, and, during the next fifteen years, research in universities of North America and Europe led to the development of somewhat specialized apparatus and technique. This phase of development, which resulted largely in contributions of a descriptive nature, furnished a mass of data from which the possibility of economic applications was soon recognized. Ore microscopy became an aid to the mining geologist in solving many problems of ore deposition. This soon led to its application in the study of ores and mill products in connection with their treatment. Its usefulness in this latter field has been very marked and has led to its widespread adoption by the mining industry.

Jan 1, 1937

By M Reza Afshar

In this work a mathematical model was developed to study the effect of electromagnetic force on the magnesium melt containing nonmetallic inclusion in an electrical isolated channel. The electromagnetic force exerted on the inclusion induced by DC current field was calculated. A three dimensional turbulent flow equations were solved numerically to compute the velocity field within the channel. On the basis of computed velocity and magnetic fields, the trajectories of inclusions were calculated using the equations of motion for inclusions. Parametric studies were carried out to evaluate the effect of various parameters such as current density, channel diameter and particle density on the removal efficiency of inclusions from magnesium melts.

Jan 1, 2004

By S. J. Buckler

Many metallurgical processes use submerged gas injection to increase the contact area between gas and liquid phases in order to promote faster overall reaction rates. The work presented in this paper is part of an experimental investigation to measure the gas-liquid interfacial area available in bubble plumes within molten metal baths. Measurements of the nitrogen absorption rate during submerged injection into molten iron baths have been used to estimate the interfacial areas of the bubble plumes. A theoretical model was used to predict the superficial nitrogen transfer rate under mixed liquid phase mass transfer -interfacial reaction control. The interfacial area was calculated by dividing the overall nitrogen absorption rate by the superficial rate. Reasonable agreement was obtained between the interfacial areas measured in our laboratory with data from a comparable system reported in the literature. The experimental results were compared with the predictions of three theoretical models and one empirical correlation. The models of Turkdogan (3) and Zhao and Themelis (5) gave the best agreement with our data.

Jan 1, 2004

By I. Spector, A. J. Smith

In 1967, BACM Industries Limited started producing walboard at Saskatchewan's first gypsum products plant, located in Saskatoon, using, as a basic raw material, gyp-sum rock supplied from the company's mine near Amaranth, Manitoba. This paper describes the geology of the Amaranth gypsum deposit, the method of mining the rock and the manufacturing facilities used to produce wall-board.

Jan 1, 1970

By Sudarshan Martins

The measurement of acoustic signals produced by a tumbling mill has been previously used to determine the operating state of the mill and correlate the variations of the sound intensity with the operating conditions of the mill. Separately, the discrete element model (DEM), a software simulation of the mill, was developed to provide insight into the operation of the mill. Presently, there has not been much work reconciling the DEM simulation of the mill with the acoustic signal. Working from basic principles of linear, time-invariant systems, agreement between an acoustic DEM simulation and the measured signal is sought. First, the impulse response function of the mill is measured. The DEM provides the forces applied to the mill shell as a function of time. A convolution of these simulated shell forces and the transfer function gives the simulated acoustic signal. This signal is compared to the measured acoustic signal, both in the time domain and the frequency domain. Finally, a discussion of the results is given.

Jan 1, 2012

By R. F. Favreau

"After a blast, the volume of the blasted rock normally occupies more space that it did before the explosion. The degree of such swell significantly affects the efficiency of digging the muck with a shovel or dragline. This paper explains why swell occurs, and describes the new subroutine SWELL of the blast simulator BLASP A which can simulate blast-induced swell. Results are also presented which display the effect of various blasting parameters on the degree and distribution of the swell within the muck pile of a bench blast. IntroductionIt is a common opinion that fragmentation is the most important of the various aspects which affect the efficiency of excavating rock with explosives. This paper proposes that, in fact, displacement and swell of the blasted rock are as important as fragmentation if the excavation process is to be rapid and efficient. It must ""a priori"" be recognized that a minimum degree of fragmentation is indeed necessary. For a given shovel or dragline, this minimum degree of fragmentation may be defined as follows: even the largest fragment of rock must be easily contained within the bucket. Once this criterion is met, however, there are good reasons to believe that displacement and swell take over as the key criteria which influence the rate of mucking, in cubic metres/hour. If the muck pile is not well displaced and swelled, the teeth of the bucket have difficulty penetrating between the rock fragments even if fragmentation is good and, as a result, the mucking is slow and inefficient. The purpose of this paper is to use computer simulations on the model BLASP A to demonstrate the effect of the blast design parameters on the displacement and swell of the blasted rock."

Jan 1, 1993

By A. Monballiu, J. A. Martens, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, B. Meesschaert

In this work, bioleaching of non-sulphidic materials by applying chemoheterotrophic bacteria and fungi is studied. It was found that the tested fungus, Aspergillus niger, leached substantially more nickel from olivine than the tested bacterium, Bacillus mucilaginosus. A. niger also outperformed fungal species Humicola grisae and Penicillium chrysogenum in the leaching of olivine. Contrary to traditional acid leaching, the microorganisms leached nickel preferentially over magnesium and iron. On average, a selectivity factor of 2.2 was achieved for nickel compared to iron. This can potentially facilitate postprocessing of the leach liquor and reduce the cost. The impact of ultrasonic conditioning on bioleaching was also tested, and substantial increase in nickel extraction with A. niger was observed. This was credited to an increase in the fungal growth rate, the promotion of particle degradation, and the detachment of the stagnant biofilm around the particles. Furthermore, ultrasonic conditioning enhanced the selectivity of A. niger for nickel, resulting in a selectivity ratio for Ni/Fe equal to 3.5. The chemical resistance of the selected microorganisms to several heavy metal and metalloid (As(III,V), Cd, Cr(III,V), Ni, Pb, Zn) was evaluated. It was found that, with the exception of As(v) and Cd, A. niger has high tolerance to these components. Therefore, this biohydrometallurgical route can potentially be applied to non-sulphidic wastederived materials, such as industrial slags, ashes and sludges.

Jan 1, 2014

By T. -W. Hong, Y. Son, S. -J. Hong, D. Choi

The characteristics of indium-tin-oxide (ITO) nanoparticles recovered from TFT-LCD panel scraps were investigated. The ITO was separated from TFT-LCD panel scraps by dissolving the color filter layer located between the ITO layer and the glass substrate. The solution was filtered to separate the ITO from the color filter component, and the filtered ITO was dissolved in the acid solution. ITO nanoparticles were then precipitated with ammonium hydroxide and organic dispersing agent, followed by heat-treatment at 600 °C. HRTEM, EDX and XRD analyses revealed that the 20 nm sized particle were composed of 90 % In and 10 % Sn, and were well crystallized to in the (222) preferred orientation.

Jan 1, 2014

By J. Y. Kim

This paper presents a novel action recognition method for observing human workers using interactions between actions and related objects on an internal construction site. This method can be used to measure work rates for labour productivity monitoring. This monitoring is critical because the performance of a construction project is significantly impacted by labour productivity. However, construction sites are generally crowded with a large number of workers and objects. Such congestion disrupts the accurate, automatic recognition of construction workers? actions. This congestion is one reason that existing automatic action recognition studies of construction areas mainly focus on workers? actions themselves. However, the crowded conditions mean that sites could offer a great deal of clues that could be used for automatic action recognition. According to psychological studies, interactions clearly take place between human actions and related objects, such as between hammering and a hammer. Humans use these interactions to recognize actions or objects more accurately. On the construction site, workers, materials, tools, and equipment are carefully planned out ahead of actual construction. The categories of workers and objects are pre-defined and, as noted, specific interactions define relations between worker actions and objects. In this paper, the interactions are limited to human workers and their hand-held objects. Action recognition results can be combined with hand-held object information to improve recognition accuracy. With the limited interactions, experiments in this paper show a significant improvement in action recognition. This paper describes the utilization of these interactions to improve construction action recognition accuracy based on human skeleton data and 2D color video from Microsoft KINECT sensor.

Aug 1, 2013

By Fulchand Shende

Around the world many potash mines experience brine inflow problems. The presence of brine in underground excavations may induce structural and stability problems. A study has been carried out to simulate the effect of brine on the performance of pillar support. The testing program consisted of loading potash specimens in a creep frame, and simulating inflows by continuously pumping brine into an experimental cell. Brine temperatures and load conditions were varied to simulate several mining and inflow conditions. Specimens were fitted with acoustic emission transducers to monitor energy emissions during an eight-hour test duration. Samples of brine were also collected to provide K+ and Na+ concentration data necessary for an accurate assessment of the dissolution process. Test results indicated that dissolution rates are highly dependent on brine temperature and load conditions. Loads approaching 50% UCS tend to generate very high rates of energy emissions, often leading to the failure of the simulated pillars. This study demonstrated that acoustic emission could be effectively used for predicting the performance of pillars when exposed to inflow brine.

May 1, 2001

By D. R. Schmitt, N. Ong, R. S. Kofman

Shales and mudstones comprise about 75% of all the sedimentary rocks. In, particular, organic rich shales are considered as a petroleum source rock and more recently with the advent of hydraulic fracturing technology to be a reservoir in their own right. In this sense, the aforesaid motivates our work with laboratory measurements of elastic properties of these geologic materials, which are known to be anisotropic. As such, assuming Vertical Transverse Isotropy (VTI) symmetry, the dynamic and static moduli of a series of cores from various geological formations in Alberta, Canada are simultaneously investigated as a function of confining pressure using the ultrasonic pulse transmission method and strain gages. Dynamic moduli were obtained from ultrasonic P- and S-wave velocities measured on a prism cut with faces perpendicular, parallel and oblique to the assumed vertical axis of symmetry. Static moduli were calculated from strain-stress curves obtained along the directions perpendicular and parallel to the assumed axis of symmetry as well. Velocity measurements show that samples are highly anisotropic, but that the pressure-dependent behaviour of the wave speeds differs. VP(90°) and VSH(90°) both with layer parallel propagation and polarizations change little with pressure while VP(0°) and VS(0°) (both with layer perpendicular propagation) display significant nonlinear responses particularly at pressures < 25 MPa. These characters transfer to the derived full set of elastic constants. In order to effect a proper comparison of the dynamic and static moduli, we convert the dynamic elastic constanst to linear compressibilities pependicular (Kdyn1) and parallel (Kdyn3) which are directly comparable to the static tangent compressibiities obtained by differentiation of the observed strains. Both sets highlight the anisotorpic nature of the material but most interestingly Kdyn1 _ Ksta1 but Kdyn3 > Ksta3 by nearly 40% for one of the samples. The other samples measured respond similarly suggesting that conceptually the structure of such materials could be considered to be constructed of alternating stiff or compliant layers. This finding has implications in the response of the formation to stress particularly during hydraulic fracturing and the interpreation of acoustic logs in providing appropriate measures of elastic properties for engineering purposes.

Jan 1, 2015

By George J. Thompson

This pa per deals with the internal characteristics of steel and its response under cold northern temperatures. General maintenance procedures and specific repair techniques are covered.

Jan 1, 1973

By Jin Li

The tensile properties and microstructure of AZ91 Mg alloy before and after equal channel angular extrusion (ECAE), and the fracture behavior during tensile testing for as-extrusion and ECAE AZ91 were investigated. The alloy was performed ECAE from one to eight passes at 498K. The elongation decreased with the pass number increasing after ECAE. Grains were refined, partial coarse ß-Mg17Al12 phase fell to pieces, fine ß-Mg17Al12 precipitated in the AZ91 Mg alloy after ECAE. During tensile test the a-Mg/ ß-Mg17Al12, a-Mg/Al8Mn5 interface and the grain boundaries in a-Mg matrix acted as the crack initiation sources. The frequency of micro-cracks at the a-Mg/ß-Mg17Al12 interfaces and grain boundaries increased after ECAE, which accelerated the growth and coalescence of the micro-cracks during tensile test and resulted in the decrease of elongation of AZ91 Mg alloy by ECAE.

Jan 1, 2006

By H. Fujiwara, T. Ito, T. Mizuguchi, K. Kawasaki

"In this study, we characterize the high-temperature deformation of typical “Class I” solid solution Al-Mg alloys as a superplastic elongation attributable to the solute drag creep of dislocations. The second-phase particles formed by adding Fe or Si as impurity atoms to the Al-Mg alloys impeded the gliding motion of dislocations, thereby decreasing their hot ductility and resulting in cavity formation. High-temperature tensile tests were performed with initial strain rates in the range of 1×10–3 to 1×10–1 s–1 at air temperatures 673–723 K. The dominant high-temperature deformation mechanism in these alloys was the solute drag creep controlled by the interdiffusion of Mg in Al. In this study, the calculation of critical length, defined by the diffusion-based relaxation of the stress concentration region around second-phase particles, is reported using the Needleman–Rice parameter. An analysis of the impact of cavity formation based on a comparison of the Needleman–Rice parameter and second-phase particle size is also reported.INTRODUCTION Aluminum alloys with high specific strengths are utilized as structural materials for transportation machines to minimize their weight, which consequently maximizes fuel efficiency, environment preservation, and so on (Miller et al., 2000; Heinz et al., 2000; Starke & Staley, 1996; Polmear, 1996; Immarigeon et al., 1995; Burger, Gupta, Jeffrey, & Lloyd, 1995; Ye, 2003). Microstructure refinement by severe plastic deformation (SPD) has been performed on a laboratory scale to achieve a higher strength of crystalline materials (Valiev et al., 2006; Song, Ponge, Raabe, Speer, & Matlock, 2006; Beyerlein & Toth, 2009; Sabirov, Murashkin, & Valiev, 2013; Sauvage, Wilde, Divinski, Horita, & Valiev, 2012). At room temperature, grain refinement strengthens the material, as given by the Hall-Petch relationship (Hall, 1951; Petch, 1953); at higher temperatures, superplasticity can be expected (Sherby & Wadsworth, 1989; Edington, Melton, & Cutler, 1979; Furukawa, Horita, Nemoto, & Langdon, 2001; Langdon, 2006). However, the synthesis of large-size materials by SPD processes is not yet feasible."

Jan 1, 2018

By G. R. Guillet

Salt is restricted to five major beds in south western Ontario, totalling as much as 200 m in thickness. These beds are located at depths ranging from 270 m to 750 m below the surface, fringing Lake Huron and the Detroit River from Windsor to Kincardine, and extending inland as far as London. Manitoulin Island, the Bruce Peninsula and the north part of the Niagara Escarpment form the northeastern rim of the Michigan Basin, a major structural depression in which the salt was deposited 400 million years ago when much of North America was covered by the Silurian sea. Salt is mined underground at Windsor and Goderich; it is also brought to surface as brine through deep wells at Windsor, Samia and Goderich. Artificially- created caverns in salt beds are extensively used for storage of liquid hydrocarbons at Windsor and Samia.

Jan 1, 1984

By T. Miura, Y. Mori, H. Aoki

In a flash smelting furnace, easily combustible concentrate particles excessively oxidized and melt. The excessively oxidized molten particles then collide with less oxidized solid ones to create uniform oxidized molten particles. This collision phenomenon plays a very important role in achieving high smelting performance. The authors developed a mathematical model describing above combustion phenomena. This model incorporated fluid flow, heat and mass transfer, chemical reactions and collisions of concentrate particles. Both gas flow and particle motion were calculated using the Eulerian method. Copper concentrate was assumed to consist of chalcopyrite(CuFeS2). Considered in the concentrate reactions were the decomposition of CuFeS2, and the oxidation of the resulting sulfur(S) and pyrrhotite(FeS) to produce magnetite(Fe30 4) and sulfur dioxide(S02). Moreover a reaction due to concentrate particle collisions, in which Fe304 in the excessively oxidized molten particle reacts with FeS in the less oxidized particle, was also considered. The particle collisions were assumed to occur according to a collision probability rule obtained by computational experiments. Particle growth in diameter was described as a change in the volume fractions of particle phases. When applied to a commercial flash smelting furnace, this model reproduced the particle growth and component transfer as observed in the actual furnace.

Jan 1, 2007

By A. Hartikainen, M. Rinne, F. Johansson, R. Yorke, L K. T. Uotinen, E. Korpi, J. Antikainen

"In order to determine the in-situ shear strength of rock joints, large scale testing is required. However, this is both expensive and difficult to execute. One possible method to overcome this may be to use photogrammetry to capture large joint surface roughness in-situ and downscale it to replica samples, which could be sheared in laboratory. In this paper, as a first part in such a method, a technique to digitize surface roughness and to produce replica samples for laboratory shear testing from a larger joint sample are presented. First, a thin granitic rock slice with dimensions of 1.75 m x 0.95 m of granitic intact rock was chosen for the study. The joint surface is fresh and created through tensile induced splitting. The large joint sample is digitized using photogrammetry. Then, one fullscale 1.7 m x 0.6 m geometry is cropped from the digitized joint geometry and then subsamples at 10x, 7.5x, 5x, 2.5x and 1x scales. All sub-geometries are scaled down digitally to produce 0.17 m by 0.06 m geometries. The geometries are used to make casting molds both positive and negative to produce samples with perfect matedness. The casting molds are 3D printed in polylactic acid plastic and C60/75 concrete is cast to produce a replica series. In addition to the creation of this replica series, two pilot replicas are also tested using a portable shear box with a 0.5 MPa normal pressure. The results from the pilot rounds are presented and discussed. Finally, suggestions for future research are given.INTRODUCTIONThe rock mass strength is in many cases controlled by the shear strength of rock joints, especially in hard rock masses. The shear strength is generally found to be influenced by several parameters, including normal stress, the basic friction angle of the intact rock, the joint surface roughness, the joint wall compressive strength, the matedness of the joint surfaces, weathering and infilling. The effect of these parameters for the joint shear strength can be evaluated in laboratory scale. However, the shear strength is known to be scale dependent. How the scale effect influences the strength is not fully understood. The general consensus is that the shear strength decreases when sample size increases, i.e. a negative scale effect (Bandis et al. 1981). However, some studies have presented contradictory results, see for example Hencher et al. (1993) and Kutter & Otto (1990). The extent and nature of the scale effect is still a question of debate (Tatone & Grasselli 2013)."

Jan 1, 2015