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By Xianglin Yang, Hong Zhong, Jingjing Xiao, Guangyi Liu

"The selective adsorption of a flotation collector to a mineral plays a crucial role in enhancing the hydrophobicity of targeted mineral particles for attaching air bubbles in pulp. The recent progress of the structure-reactivity relationship of flotation collectors, the characterization methods for mineral surfaces with adsorbed collectors and their commercial application are reviewed in this paper. Particular emphasis is placed on the density functional theory (DFT) for understanding the reactivity of new collectors, the surface analysis techniques including time-of-flight secondary ion mass spectrometry (ToF-SIMS), in situ scanning electrochemical microscopy (SECM) and atomic force microscope (AFM) to characterize mineral/collector interface, and the flotation technologies for optimizing recovery of valuable minerals. Especially, the recently developing collectors such as Gemini, alkoxyalkylthiourea, dithiourea, amide-hydroxamate and oximido-thiol surfactants, and their specificity to given minerals are evaluated. Based on this crucial review, it is evident that the structural modification approaches for minerophilic or hydrophobic groups, and combined surface analysis approach for further understanding the adsorption mechanism of collectors on mineral surfaces will lay a solid foundation for the future development of flotation collectors. INTRODUCTIONIn mineral processing, flotation is the main process for separation and recovery of valuable minerals from the ores contained them (Fuerstenau et al., 2007). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by collector adsorption so that these mineral particles can preferably attach to air bubbles in a slurry or pulp (Fuerstenau et al., 2007). Flotation collector is a kind of functional surfactant, which is composed of polar and non-polar groups (Somasundaran, & Wang, 2006). Non-polar portion, commonly being linear, branch or ring hydrocarbon group, is termed hydrophobic group. The polar portion, exhibiting strong affinity to mineral surfaces, is known as minerophilic group (Nagaraj, 1988). According to mineral types including saline, oxide and sulfide minerals, flotation collector divides into sulfide and oxide mineral collectors. For efficient recovery of valuable minerals from the refractory complex ores, insights into the adsorption mechanism, hydrophobic model and subsequent flotation approach of flotation collectors have been regarded as an indispensable issue in mineral processing."

Jan 1, 2016

By M. J. Steffens

ESPLIM is a novel separation technique that combines the advantages of solvent extraction and electrostatic dispersion but its application in the extraction of nickel by the direct solvent extraction route and the effect of high electrostatic field on the stability of organics have not been explored. These were investigated in this study and it was found that the technique allows 97% extraction of the nickel in a single stage compared with 3 stages by the conventional solvent extraction. Also, three months of exposure to 5.0 kV under simulated operational conditions had no adverse effect on the stability of organics.

Jan 1, 2005

By C. D. Kaeding

IN the summer of 1937, the Algoma Steel Corporation, Limited, decided to embark on the full-scale development o their Helen mine and the erection of plants to produce commercial iron sinter from its ores at a rate ? of fifteen hundred tons per day. The Helen deposit has long been known as one of the largest bodies of non-commercial iron ore in Canada, consisting almost entirely of siderite with a band of pyrite along the north wall and some lenticular inclusions of pyrite throughout the mass. It originally contained a nominal amount of hematite (2,800,000 tons), localized at the western end of the ore-body, but this was mined out during the years 1900 to 1918. For details of the:-geology of the Helen range and of the surrounding district, the reader is referred to Memoir 147, Michipicoten Iron Ranges, Geological Survey of Canada, 1926 (1). The siderite mass was explored by diamond drilling in 1917 and the portion so drilled was estimated to contain 67 million tons of siderite averaging 36.0 per cent Fe, 3.2 per cent S, and 8.2 per cent SiO,, without establishing its ultimate depth or extent. The variation in the sulphur content shown by drilling was from 1.5 per cent in 72 per cent of the tonnage, to 7.2 percent in the remaining 28 percent. The pyritic ore aver-aged about 38 percent iron, but otherwise its composition was substantially the same as that of the siderite mass.

Jan 1, 1940

Inco Limited has been evaluating options for streamlining the overall flowsheet at its Sudbury, Ontario operations to improve productivity and to minimize the cost of at¬mospheric emissions reduction. Some of the flowsheets being considered include vari¬ous levels of copper/nickel separation at the Clarabelle Mill where all Inco's Sudbury Basin ores are processed. This paper reports on the laboratory and miniplant studies car¬ried out during the flowsheet development for a commercial Cu/Ni separation plant. There are two potential feed streams for Cu/Ni separation. It was determined that Cu/Ni separation from the rougher concentrate requires no regrind, and a very clean copper concentrate is produced, but the recovery of copper is limited to about 70% from ore. Cu/Ni separation is more difficult from the bulk concentrate because of the presence of excess flotation reagents in the slurry and due to locked particles. By replacing the slurry water with clean process water, and by addition of some hydrogen peroxide, entrainment is minimized and excess reagents are removed from the surface, providing a satisfactory separation of copper from nickel. Fine regrinding is required to increase liberation of the locked particles and to obtain 85% copper recovery with minimal nickel contamination of the concentrate.

Jan 1, 2005

By M. S. Ünal

Creation of 3D model of coal seams is a tedious and time consuming operation. Computer aided 3D solid modelling of coal seams can be performed in a fast and detailed manner. However, in case of having tectonically disturbed coal seams where faults may be observed, expert opinion is necessary to decide the geometry of the coal seam. The aim of this study is detection of fault zones with computers by using drill hole data. Firstly, a digital database is generated by using the drill hole data. Surface models of the layers are produced by applying triangulation method on coal seam roof elevations. The generated surface is divided into small squares and consequently dip and dip direction values are calculated for each square. Variograms for dip and dip direction are determined and maps showing the variation of dip and dip direction are generated by using geostatistical methods such as kriging and co-kriging. Examination of disconformities observed on estimation maps created by kriging and co-kriging clearly reveals the extension of faults. The method used in this study is applied to detect fault lines of a known mine field. 3D solid modelling of the coal seam has also been performed by using conventional cross-section method. The results of both methods were in good agreement. Identification of major faults by using the method introduced in this study could certainly simplify 3D solid modelling of coal seams.

Aug 1, 2013

By H. Houali

Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items: ? Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists; ? Range of protection (potential of protection along the pipeline); ? Influence of the isolation resistance of the coating on the range of protection; Effect of the aging of the coating and its influence on the current of protection

Jan 1, 2005

By Frank D. Shepherd

THE Gunnar Gold Mines property is on the west shore of Beresford lake, in the Rice Lake mining division, southeastern Manitoba. Gold was first discovered in place in the Rice-Beresford Lakes area in 1911 on the Gabrielle claim, now included in the San Antonio Mines property at Rice lake. Following an eastward trend of favourable prospecting ground, promising showings were next staked in the vicinity of Long lake during the years 1915 and 1916. At that time, William Walton and associates, among them Gilbert LaBine, staked the Eldorado vein, north of Long lake, and Eldorado Gold Mines, Limited, was formed to develop the property a Company that, later, was to become widely known through successful operation of its radium-silver mine at Great Bear lake, Northwest Territories. Continuing eastward from Long lake, Walton and his partners, Gunnar Berg, Leo Seaberg, and Wm. Quesnel, staked claims during the years 1920-24 in the vicinity of Beresford lake which, later, were to become incorporated into the Gunnar Gold Mines property. The presence of gold-bearing quartz on these claims had been known from the time they were staked, but an opportunity to consolidate them into a group was not forth-coming until early in the year 1933. Although promising gold showings had been disclosed during the performance of assessment work on individual claims, no continuous mineralization having mine-making possibilities was discovered until after the consolidation of the entire group. From this stage onward, progress was rapid. Active exploration was begun on August 1st, 1933, and late in October James Houston reported favourably on the property. On October 27th, Gunnar Gold Mines, Limited, was incorporated in the Province of Ontario to develop and operate the property. The Company is also registered in Manitoba. The authorized capitalization is 3,000,000 shares of $1.00 par value. Gilbert LaBine was appointed president of the Company, with James Houston as mine manager. Following completion of a diamond-drilling programme, planned in 1933, it was decided to install a mine plant capable of carrying development to a depth of 1,000 feet. A transmission line, 5 miles in length, was built to the Great Falls-Central Manitoba line of the Manitoba Power Company, Limited.

Jan 1, 1939

By F. Czerwinski

Mechanically fragmented chips of an AZ91D magnesium alloy were transformed into a semisolid slurry within the Thixomolding® system. Microstructural analysis of a material at various processing stages revealed that the cold deformation of the alloy, experienced during chipping, led to the recrystallization and growth of equiaxed grains which were subsequently converted to the globular structures by melting the grain-boundary network.

Jan 1, 2004

By Free. Michael L.

Crushing ore prior to heap leaching enhances mineral liberation and creates fine particles that may require agglomeration to avoid permeability problems during leaching. Conventional modeling is relatively successful in describing general fluid flow and extraction in heaps. However, most models do not adequately account for the effects of mineral liberation and exposure or the effects of agglomeration, curing, and loading on heap leach performance. This paper will discuss methods to account for mineral liberation and exposure as a function of comminution. It will also discuss methods for incorporating liberation, exposure, and mineral locking as well as curing and fluid flow in heap leach modeling. It will also provide information regarding agglomeration and the effect of loading in heap leach modeling.

Jan 1, 2014

By O. Bouaziz, O. Magnea, P. Cugy, E. F. Rauch

The experimental difficulty to perform Equal Channel Angular Extrusion (ECAE) of a bulk sample of hard material such as steel was overcome. The original method proposed in this paper consists in replacing the bulk sample by a stack of alternated hard metal (steel) and soft metal (aluminium) sheets. By applying this procedure to an Interstitial Free steel (IF steel), 2.7µm grain sized material was obtained after recrystallisation. Its mechanical properties (hardness, formability in shear, hardenability and faigue limit) were investigated and compared with the properties of the same IF steel with conventional grain sizes (12m and 25µm).

Jan 1, 2004

By H. J. Rowley

THERE are many varieties of limestone, but for the general purposes of the pulp and paper industry, two classifications are sufficient: (1) High-calcium stone, which should be quite free from impurities and contain not less then 90 per cent calcium carbonate. (2) High-magnesium stone, containing not less than 25 per cent of magnesium carbonate. Before proceeding with detail on the use of limestone and lime in the industry, a few words regarding the pulp products made in Canada are desirable. By far the largest tonnage is made by grinding spruce and balsam logs on rotating sandstones or on artificial abrasive stones of the Norton or Carborundum types. This mechanical or groundwood pulp finds its largest use in the production of newsprint paper, of which it comprises about 80 per cent of the total fibrous substance employed-the remaining 20 per cent being unbleached sulphite pulp. No limestone or lime is directly employed in making groundwood pulp, as contrasted with the chemically prepared pulps, all of which require one or the other form of the base for their processing. Sulphite pulps comprise the next largest tonnage group. They are produced by boiling, under pressure and at elevated temperatures, spruce and balsam wood in chip form in solutions of bisulphites and sulphurous acid. The usual bisulphites employed are those of calcium and magnesium. Sodium, potassium, and ammonium bisulphites give progressively better pulps, but to date, in the absence of efficient recovery methods, cost has precluded their use.

Jan 1, 1939

By Fred G. Hewett

Cassiar Mine in northern British Columbia began development in 1952. The deposir is found on rhe west limb of rhe McDame Synclinorium in a Mississippian serpentinite body. The serpenltntte, one of the McDame l ntrusives, imrudes Sylvester Group . rocks, which comprise a Lare Devonian to Early M1ss1ss1pptan eugeosync/inal sequence of argillites, quarrzires and volcanics. The foorwall conracr berween Sylvester Group rocks and rhe serpenrinire is a marked zone of broken and incomperent argillite and graphitic schist. The less marked hang- 111gwall contacr 1s a band of indurated argillite. The JurassicCretaceous emplacemenr of the Cassiar Graniric Barholilh is responsible for mosr of the numerous )aims, faulrs and shear zones found in the serpentinite body. Faulting occurred borh before and after asbestos formation. Asbestos is mined from an open pit ar rhe rate of 4,535 ronnes daily. It passes from the pir along a rramline to the mill, where it is concen/rared into nine direcr milling grades. Packaged fibres travel ro over 40 counrries around rhe world for use in the texrile, cemenr and other industries.

Jan 1, 1984

By Li Chongyang, Liu Baolan, Jia Xiaolin, Li Suping

An Al/Al2O3 gradient coating applied on a heat-resistant stainless steel was prepared through a slurry process by using aluminum and ?-Al2O3 powders as the transition filler material, alpha alumina as the surface coating material, aluminum dihydrogen phosphate as the binder, and sodium molybdate as the corrosion inhibitor. The effects of heat treatment temperature, adhesive/filler ratio and ?-Al2O3 content on the bonding strength, microhardness and thermal shock resistance were investigated. The crystal phase and microstructure were characterized by XRD and SEM. The results indicated that the composition of the coating changed continuously from surface to coating-substrate interface. The coating could offer high bonding strength and good thermal shock resistance when heat treated at 700°C.

Jan 1, 2010

By X. W. Yi, Z. J. Li, G. W. Ma

In this paper, the compressive strength and failure patterns of reinforced cemented paste backfill (CPB) were studied aiming to promote the stability of backfilled stopes. The concept of ductile backfill was proposed and a series of unconfined compression tests were carried out on both non-reinforced and reinforced cemented paste specimens. Portland cement (3% to 5% by weight of tailings) and five different types of ductile materials (0 to 0.5% by weight of solids) were employed in this experiment for the specimen preparation. The test results showed that inclusion of ductile materials enhanced the unconfined compressive strength (UCS), reduced the post peak stress loss and transformed the failure behaviour of specimens from classical brittleness to ductility. The strength of CPB reinforced with different proportions of polypropylene fibres was compared. The stress-strain curves illustrated that both cement and fibres contributed to the increase of UCS, but higher strain values at the peak stress were achieved by fibre reinforcement. CT sliced images acquired from X-ray computed tomography (CT-scan) demonstrated that the reinforced specimen developed irregular crevices at the edge of cross sections and gained the capacity of bearing large displacements owing to the mobilised tensile strength of fibres. It leads to the potential of avoiding unexpected falling blocks of CPB when adjacent mining occurs. This finding highlights a strategy to improve the self-supporting capacity of the fill mass with less cement usage and reduce the ore dilution rates when excavating to adjacent stopes.

Jan 1, 2015

By J. B. Mitchell

Using digital image correlation the evolution of strain and strain at the onset of localisation resulting in a hot tear has been determined for alloys AA6111 and Al¬0.5wt% Cu during solidification. High resolution images of hot tear formation and growth were captured during a constrained bar test that incorporated a glass window above a central hot spot region. The images were analysed using digital image correlation software to measure the evolution of displacement and strain based on tracking the motion of discrete features on the as-cast surface of the sample. Temperature data was also acquired with a thermocouple cast into the sample in close proximity to the hot tear. The interval starting from the point immediately after solidification shrinkage ends (the metal pulls away from the glass) and finishing when the first sign of a crack or hot tear is visible to the eye was used to determine strain data. The minimum strain at which strain localisation occurs was found to be 0.0069 in AA6111 and 0.0021 for A1-0.5%Cu.

Jan 1, 2007

By K. Niboucha, M. Zergoug, S. Brick-Chaouch, H. Houali

"Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items:•,Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists;•,Range of protection (potential of protection along the pipeline);•,Influence of the isolation resistance of the coating on the range of protection;•,Effect of the aging of the coating and its influence on the current of protection."

Jan 1, 2005

By R. Neumann, O. Gomes, S. Gaydardzhiev

"Phosphorus in iron ores is considered as a deleterious component to iron making reflecting in cold shortness of the produced steel. The present study investigates the phosphorus migration pattern resulting from thermal treatment of an oolitic-type iron concentrate with and without additives. To this end focused mineralogical and microscopic observations were performed. The results have shown that roasting with alkaline additive drives phosphorus outside the hematite hosting mineral, however it remains evenly distributed inside the volume of the oolites. It penetrates inside the newly formed cementing phases of Al- Na-Si-Fe-type and also fills the interstices between the crystals. Other than phosphorus, aluminum, calcium and iron tend also to migrate towards the amorphous-type cementing phase. Finally, the possibilities for P removal by means of magnetic separation and acid leaching of the roasted concentrate were evaluated. The obtained final product presents a standard iron concentrate suitable for steelmaking with its phosphorous being dropped from 0.71% to 0.05% and iron grade of a nearly 66% being reached. INTRODUCTIONSignificant proven reserves of iron ores are still not exploitable due to lack of an economically viable and efficient technology for removal of phosphorus. Among them are the oolitic iron ores with high phosphorus which are estimated to nearly 377 billion tons (Hernandez et al., 2012). Phosphorus is a deleterious component giving a cold shortness to steel and often is penalized if exceeding 0.07%. Most of the high-P iron ores are considered refractory since phosphorus is finely disseminated and is evenly met as phosphate groups inclusions inside the limonite structure. Studies on inclusion of phosphorus in artificially synthesized goethite have shown that it is adsorbed as [HPO4]2- groups bridging the adjacent iron ions (Parfit et al., 1975). The high-phos iron ore originating from Lisakovsk deposit, Kazakhstan presents a similar mineralogical issue because the quantity of P, met as solid solution, is substantially higher than the one in P-containing minerals. A potential reason for that is the ore body formation process from the slow deposition of iron-rich precipitates together with clastic erosional sediments in rivers. There is significant quartz and clays inside and around the oolites. The deposit contains about 1.7 billion tons of measured and indicated reserves at 35–41% iron and 1.1 billion tons of inferred ore have been delineated possessing nearly the same chemical composition (Golubovskaya, 2003; Kokal et al., 2003)."

Jan 1, 2016

By A. Saigal

The effect of temperature on the cutting forces during machining of alumina reinforced aluminum composites was investigated, Aluminum 6061, 10% Al2O3 reinforced composite and 20% Al2O3 reinforced composite were tested, A 5/8-inch diameter high-speed steel end mill, a Micro 100 TiN coated single edge endmill cutter and a two-fluted solid carbide insert cutter were used for tooling, The results, in general, showed an increase in the cutting forces as the temperature of the material increased, From the raw data, there are temperatures ranges in which the force data did decrease but they were insignificant with regards to predicting a downward trend. A regression analysis was used to understand which variables had the greatest affect on the forces being generated, The correlation and regression analysis showed that at 600 rpm (velocity: HSS- 98,2 sfpm, Micro 100 cutter - 78,5 sfpm, solid carbide cutter - 192,4 sfpm) the tooling, the workpiece material, built up edge, and temperature were statistically significant factors in the test, Tooling was a significant variable in all testing, The smallest forces recorded during machining were generated with the solid carbide two-fluted endmill cutter, Visually, the solid carbide tooling produced a better surface finish during the testing which made it the tool of choice, In addition, the force data proved that as the cutting speeds were increased, the cutting forces decreased.

Jan 1, 2005

By S. Balideh

A good understanding of the behavior of broken rock helps to make more informed decisions regarding slope stability and waste dump issues in mines. The cohesion coefficient of rock has little influence on the strength of broken rock; therefore, a criterion based on friction and cohesion of intact materials does not provide an accurate analysis for the strength of broken rock. This paper illustrates the effective strength of broken rock through a brief literature review about failure of intact rock and rock masses. The complete stress- strain curve and some important points of residual strength of rock are summarized in this paper.

Jun 1, 2012

By G. Guiglionda, A. Deschamps, F. De Geuser, M. Langille, B. J. Diak

"Increased demand for light-weighting in passenger vehicles has created a need for strong, light, ductile materials to be used in body-in-white applications. The AA6xxx-series of aluminum alloys are suitable candidates meeting most requirements but can fall short of the formability demands of designers, necessitating an understanding of what controls the formability in this alloy series. This work examines the effect of copper alloying in AA6xxx on the pre-ageing and natural ageing responses of the microstructure and mechanical properties. The changes in microstructure observed by differential scanning calorimetry and hardness testing are related to the work-hardening and strain-rate sensitivity parameters for these alloys measured by tensile testing. An observed asymmetry in the measured strain-rate sensitivity associated with increasing versus decreasing strain rate changes suggests that a different mechanism operates for the two conditions. It is postulated how this asymmetry in strain-rate sensitivity will impact the necking and ductility behaviour of these alloys.INTRODUCTION The widespread use of AA6xxx series alloys in the form of sheets has provided the need for a more thorough understanding of the complex interactions between composition, processing, resulting microstructure and ultimately, the mechanical properties of the alloys. Conventional industrial practices involve the production of rolled AA6xxx sheet (typically 1 mm thick) to be used for body-in-white (BIW) applications for auto body panels (Hirsch, 2004, 2014). The final metallurgical step prior to the shipment of these panels to manufacturers involves a solution heat treatment (SHT) reverting the ageing products of the alloys into solid solution and the product is then shipped to the customer. During this shipping time and while sheets are waiting to be used, the natural ageing (NA) process occurs whereby the strength of the alloys increases resulting in reduced formability. This can result in a product that is unable to meet the formability demands of the automotive manufacturer. As a result, industry has moved towards performing pre-ageing (PA) treatments to prolong the “shelf-life” of the material prior to it having insufficient formability. Once formed into BIW panels, the parts are then painted and subsequently undergo the paint curing heat treatment which consists of a short period of time at medium temperature, typically 20 minutes at 170–190°C. This short artificial ageing (AA) treatment, known as the paint bake (PB), provides additional strength and improved dent resistance for the material, but reduced formability. The PB result is strongly dependent on the PA treatment performed prior to the forming operation. Furthermore, the addition of copper (Cu) to a base Al-Mg-Si composition is known to increase the alloy’s strength. The goal of this work is to study the effect of Cu on strength, strain hardening, and strain-rate sensitivity (SRS) of these alloys, to understand the strength-formability compromise, for two separate heat treatment schedules; one including and one excluding the PA treatment, both followed by NA."

Jan 1, 2018