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By Wei Zhang, Jinhong Zhang

"The adsorption of ethyl xanthate on copper sulfides, i.e., chalcopyrite, chalcocite and bornite, has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). AFM images show that xanthate, such as potassium ethyl xanthate (KEX), adsorbs strongly on chalcocite and bornite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. This adsorption mechanism is totally different from the one obtained with chalcopyrite/xanthate system, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. The findings obtained from the present AFM study suggest that an AFM image analysis is a powerful tool for the study of the collector’s adsorption on mineral surface and as well the development of novel collector for copper sulfide flotation.INTRODUCTIONIn mining industry, copper sulfide minerals, i.e., chalcopyrite, chalcocite and bornite, are usually separated selectively from non-valuable gangue by froth flotation, which treats the highest throughput and produces the maximum economic outcome of any surface chemistry process. In flotation, collectors are added into the pulp (mixture of water and fine-grained minerals) to selectively adsorb onto the target mineral and render its surface with high hydrophobicity, which is generally beneficial for a strong mineralbubble attachment and thus a high flotation recovery.The adsorption of collector on mineral surface, therefore, is vital for a successful flotation process and it has been studied by applying various surface analysis techniques, such as IR (Infrared Spectroscopy), CV (Cyclic Voltammetry) and XPS (X-ray Photoelectron Spectroscopy). (Poling, 1963; Allison et al., 1972; Mielczarski et al., 1984; Leppinen et al., 1989; Kartio et al., 1996) These studies have revealed a lot of information, such as the reaction, product and mechanism, of the adsorption of chemicals on mineral surface. It is also of great interest to directly get the image of adsorbed collectors on mineral surface changing with pulp chemistry, such as pH, redox potential, ionic strength and chemical’s dosage."

Jan 1, 2016

By J. L. Jambor, M. J. Baker, M. J. Logsdon

"Abstract - Prior to the development of the Diavik Diamonds Project, baseline studies were conducted to determine the geochemical characteristics of four kimberlite orebodies as an aid in the design of both the water-management system and the facilities for containment of processed kimberlite and ore stockpiles. Materials tested included field samples of volcaniclastic and pyroclastic kimberlite, processed kimberlite (i.e., kimberlite ore which had been screened and washed as part of the processing procedure), and sedimentary mudstone (a minor xenolithic unit which was assimilated during kimberlite emplacement). Approximately 200 samples of kimberlite materials were collected as part of the geochemistry program. Test-work included whole-rock chemical analyses, acidbase accounting, kinetic leach tests using columns, and mineralogical analyses. Diavik kimberlite has major oxide and trace-element concentrations consistent with global averages for kimberlite. The mean total-sulfur content of the kimberlite material is 0.22 wt% S, but with a significant range. The kimberlite has an excess of carbonate minerals over sulfide minerals (average CO2 = 4 wt%, present mainly as calcite), and has a mean neutralization potential of 311 kg CaCO3 equivalent/tonne. A reactive form of framboidal pyrite associated specifically with the mudstone xenoliths is the primary source of sulfide-sulfur. Long-term kinetic tests confirmed the preliminary interpretations that were made from the static-test results. Kimberlite and processed kimberlite are net acid-consuming materials that produce alkaline drainages and have low but detectable leaching rates for SO4 and specific trace metals such as Al, Co, Cu, Ni, and Zn. If segregated from the kimberlite, mudstone xenoliths are acid-generating (pH = 3) and produce an effluent with elevated concentrations of SO4, Fe, Al, Cu, Ni, and Zn. The study demonstrates that xenolithic units in Diavik kimberlites have an important effect on the environmental geochemistry of the ore rock. The mineralogy and aqueous geochemistry of the kimberlite materials are such that they may not be suitable for general earthworks or as an alkaline agent and should report to an engineered facility to protect site water quality."

Jan 1, 2001

By B. Das

"Computers have been used extensively in the mineral industry in exploration, reserves calculation, mining technology, mineral processing, etc. With respect to coal mining, there are also various applications for evaluating rock slope stability of open pits, design of open pits, underground operations, mine ventilation, ground control, data processing and management information, operations control and certain technological applications. Mine ventilation appears to be the field in underground coal mining touched on most; on the other hand, underground coal mining methods evaluation is represented only sparingly.It is therefore essential to review the status of the computer in underground coal mining methods evaluation in order to define its scope for further application. The paper discusses the roles of the mining engineer, programmer, computer operator and analyst as well as that of the computer. The important parameters will be identified and discussed along with their application for different underground coal mining methods, with their individual unit processes. Mainly, longwall face operations have been covered. Although many models have been of academic interest, they can be considered as important steps in a transition stage which will be followed by more practical applications for computers for underground coal mining method evaluations in the future. This calls for a coordinated effort from all concerned."

Jan 1, 1981

By J. F. Fiset, N. Bouzoubaâ, N. Reynier, C. Laviolette, Canadian Nuclear Laboratories

Canadian Nuclear Laboratories (CNL) is developing a disposal strategy for radioactive wastes, which contain significant amounts of uranium, cesium, and mercury. There are safety and economic incentives for the extraction of these elements before permanent storage in deep underground repositories. In addition, the actinide elements are also an important component in rare earth element (REE) ores and considered as impurities. Actinides separation from REE tailings is a significant concern in order to manage radioactive nuclides. Reprocessing mine wastes may present significant financial and environmental benefits. Experiments were carried out with radioactive cemented wastes (RCW) prepared at CanmetMINING. For all of the tested RCW batches, solubilisation yields are above 97% for Cs and 98% for U and Hg. Sulphuric acid leaching with potassium iodide improved the solubilisation of Hg by oxidation and formation of the tetraiodide complex (e.g. HgI4 2-, Kf = 2.1030). Cs and Hg were removed selectively by using potassium cobalt hexacyanoferrate (KCFC) and Lewatit TP214 ion-exchange resin respectively. U recovery using the chelating resin Lewatit TP260 was the most efficient. The presence of high iodine concentration improved the U uptake by the resin. The best U elution was obtained using 1 M Na2CO3, which resulted in 99% U recovery. U was then precipitated as sodium diuranate. A counter current effluent recirculation was performed successfully on RCW. The process was also applied to submerged tailings collected from two U mines and an REE ore. This paper presents an innovative process, using sulphuric acid and potassium iodide, for U, Cs, a

Jan 1, 2016

By L. Hacini

The start-up is the most critical phase of the cell life, as an uncontrolled start-up could lead to early infiltrations, instabilities, and in some cases to the cell death. Lots of efforts are put to increase the lifespan of cells, as it has a major impact on both the operating costs and the environmental footprint of the aluminum industry. Obviously, a true size test on a cell is a resources- and time-consuming approach that could be used only to validate mature concepts. Moreover, numerical modelling is a low-cost and versatile tool capable to test a wide range of potential ideas and concepts. In the present article, a thermal electrical mechanical slice model is presented. This model describes the preheating and bath periods of a P155 aluminum cell start-up, as used at the Grande Baie smelter. The impact of sodium diffusion and expansion is also included in the model. This model will be useful to study different problematical issues such as the global behaviour of lining materials, shell and cradle deformations during start-up and several start-up scenarios. Such a model will also be able to answer some interrogations regarding early infiltrations and their impact on the lifespan of the electrolysis cell.

Jan 1, 2011

By Zorigtkhuu Davaanyam, Fisher Wang, Bern Klein, Amit Kumar

"The High Pressure Grinding Roll (HPGR) is an increasingly popular energy efficient solution for comminution of competent ore deposits that primarily competes with conventional crushers and tumbling mills. A significant barrier to increased adoption of HPGRs is the requirement for large amounts (one tonne or more) of sample for pilot testing which may not be feasible for most early staged projects.Various researchers have worked towards developing piston-die and JK drop weight tests to model and predict the energy requirements for an HPGR. Two small scale laboratory test procedures (the SMC test (Morrell, 2009) and the piston press tests (Davaanyam, 2015)) have been developed in recent years to provide necessary information to size an HPGR.These two methods were used to estimate the required specific energy for an HPGR unit and compared to HPGR pilot scale test results from a copper deposit. The comparison provides insight into the benefits and limitations of these tests.INTRODUCTIONHigh pressure grinding rolls (HPGR) have gained popularity in recent years because of their energy efficiency in comminution. Various researchers have suggested that approximately 50–80% of the total energy consumed in a mineral processing plant is used by the comminution equipment (Haque, 1999; Abouzeid & Fuerstenau, 2009; Wang, 2013). Haque (1999) showed that the efficiency of grinding equipment can be as low as 1%. Due to the energy intensive nature of comminution, mining industry has been forced to explore alternative energy efficient processes.An HPGR based circuit has been shown to be 10–25% more energy efficient than a conventional SABC circuit (Von Michaelis, 2009; Wang, 2013). A significant barrier to the increased adaptation of HPGRs is the requirement for a large amount of sample for pilot testing (up to 5 tons), even on a prefeasibility level. Numerous studies have been performed to utilize piston press test to analyze the performance of the HPGR circuit and to predict the energy consumption for an industrial application. This paper uses two small scale laboratory test procedures, the SMC test and a piston press test, to compare the energy requirement to the pilot HPGR data."

Jan 1, 2016

By Bhawani Singh, Mahendra Singh, N. K. C Samadhiya

"Inherently anisotropic rocks occur in abundance at many rock engineering project sites in Himalayan region. These rocks pose difficulty in analysis and design due to their direction dependent strength behaviour. Moreover the strength varies in a non-linear manner with confining pressure. Mohr- Coulomb strength criterion is widely used by geotechnical engineers for defining strength of rocks subjected to given confining pressure. However, the conventional Mohr-Coulomb (MC) criterion suffers from the limitation that the strength is treated to be linearly dependent on confining pressure. In the present article, the MC criterion has been modified by incorporating non-linear term while retaining the original parameters c and ?. The non-linearity with confining stress level has been imbibed through critical state concept (Barton, 1976). The criterion has been applied to a triaxial test data base comprising of more than 1140 triaxial tests conducted world-wide on anisotropic rocks. Statistical evaluation of the goodness of fit of the proposed criterion to the data-base has been carried out. Further the predictive capabilities have been evaluated by determining the error in estimation of triaxial strength if only few triaxial test data are available for determining the criterion parameters. The data base has also been back-analysed to assess the critical confining pressure for anisotropic rocks. Statistically the critical confining pressure, for the present criterion, may be taken nearly equal to 1.25?cmax, where ?cmax is the maximum value of the UCS out of all orientations of planes of anisotropy. It is concluded that reasonably good estimates of the anisotropic strength are possible through the proposed criterion.INTRODUCTIONMany rocks encountered in Himalayan region like shale, slate, schist and phyllite are inherently anisotropic and exhibit direction dependency in their strength behaviour. In addition, the strength of the rock also depends on the confining pressure and, the strength response is non-linear especially when the confining pressure may vary over large range. Conventionally, Mohr-Coulomb criterion is the most widely used criterion for rocks. However, the limitation of this criterion in its present form is that the strength is treated to be linearly dependent on the confining pressure. The present study attempts to address the following two main objectives: i) Include nonlinear response in the Mohr-Coulomb criterion while retaining parameters c and In their original form; and ii) consider anisotropic response of the rock for a given confining pressure. A nonlinear strength criterion, which uses shear strength parameters c and as per Mohr-Coulomb criterion, has been suggested based on critical state concept for rocks."

Jan 1, 2015

Stope performance and geotechnical information at Xstrata Zinc George Fisher Lead-Zinc-Silver mining operations have been analysed in detail since the beginning in October 2003. This work has been included in a joint dilution study between Xstrata Zinc and the University of Saskatchewan. This paper presents an analysis of site geotechnical data and stope reconciliation that led to major changes in stope design, a reduction in dilution, and a significant increase in mining efficiencies. Detailed geotechnical data collection for a mine site or particular stoping area represents a large amount of information which is time consuming to review. However, it is this data that can make a significant difference in rock mass behaviour understanding. Simplification and averaging of conditions into zones of similarity, called structural domains, are common approaches for managing large amounts of data. There is a tendency to average rock mass properties to obtain inputs for numerical modelling and empirical design tools. This approach may be misleading if the inhomogeneity of the rock mass is contributing to the failure mode. This paper summarizes a novel approach for rock mass characterisation and stope design in a bedded sedimentary rock mass.

Apr 1, 2005

By Feng Tianran, Lu Shijie, Shen Zhengchang, Han Zhibin, Tan Ming

"As a kind of non-metallic material, high-purify quartz sand has been widely used in many fields. Flotation is a popular way to process quartz sand. But it is in difficult position for flotation to get high-purify quartz product due to large amount of coarse particles contained in the feed. In this paper, a design principle of special flotation cell for high-purify quartz sand has been put forward base on ore property analysis and laboratory test, and the pilot scale special flotation cell has been developed to meet the requirement of the quartz sand flotation process. The special flotation cell for high-purify quartz sand is featured by middle positioned impeller, false bottom and draft tube, which could decrease the rising distance of mineralized bubble and strengthen the circulation capacity of the lower part of the flotation cell. Hydrodynamic study indicates that high air dispersion degree and strong lower slurry circulation could be produced by pilot scale special flotation cell, which is helpful to create a suitable hydrodynamic environment for quartz sand processing.INTRODUCTIONNatural quartz is a non-metallic mineral, which is widely used as raw material in multiple industry process (Shifu, 2006). High purity quartz, especially containing more than 99.9% silicon dioxide, is characterized by high temperature resistance, small thermal expansion coefficient, highly insulating and so on. The demand of high purity quartz has been rising along with social and economic development, now high purity quartz is widely used in the field of photovoltaic industry, electronic information, communications and aerospace industry.Quartz is a kind of main rocking-forming minerals in the nature. There are seven genetic types, such as natural crystal, quartz sandstone, quartzite, vein quartz, konilite, natural siliceous sand, granite quartz (Baolei, Shuilin, & Dianchao, 2012). The natural crystal is primarily used as raw material to refine high purity quartz, but it is not available for two reasons. On the one hand, the natural crystal is extremely expensive and poor in resources reserves, which can not satisfy the need of large-scale industrial production. On the other hand, the chemical component of natural crystal is instability, it may lead to low stable product performance in large industrial applications, and it is also difficult to achieve raw materials standardization. Therefore, there are a lot of studies to search for other technological methods to obtain high purity quartz from other genetic quartz types."

Jan 1, 2016

By Ian Sherrell, Michael Pirie, Riddhika Jain

"Conventionally, direct reduced iron (DRI) mixed with char from rotary furnace discharge is cooled down before separating the char via magnetic separator. The DRI must then be reheated for further downstream processing (i.e. smelting). Outotec has developed the PyroMagTM specifically to conserve thermal energy during this separation process. DRI is cleaned by feeding hot particles directly after reduction onto a rotating surface just above a stationary magnet assembly. This allows hot feeding of the clean DRI to the downstream equipment which renders the entire process more energy efficient.Continuous testing of the PyroMagTM was performed to verify design and separation. Because the use of DRI/char was not practical for test use, the pilot plant testing was conducted using a magnetite/sand mixture heated up to and beyond the Curie temperature of magnetite. The separation was efficient for both cold and hot processing with recoveries varying from 98.6% to 99.74%. As expected, the recoveries decreased to as low as 83.99% as the temperature was increased beyond the curie temperature of magnetite (585°C). Long term separation was thermally efficient and sustainable.INTRODUCTIONMagnetic drum separators are widely used in the mineral processing industry. These low to high intensity magnetic separators are used to concentrate various magnetic material, such as iron ore, and less magnetic materials, such as ilmenite and garnet from silica and other contaminantsThere are multiple classes of magnetism based on the effect that each material displays while in and out of a magnetic field. In a simplified fashion, which is more appropriate for mineral processing, the magnetic susceptibility of a mineral is used to define it as being ferromagnetic, paramagnetic or nonmagnetic. In this respect, minerals with varying degree of magnetic susceptibility can be selectively separated with different types of magnetic separation equipment in different stages of a process flow sheet. The lower strength magnets are employed early in the process to remove highly magnetic fractions. Later stages utilize greater magnetic fields for capture of less magnetically susceptible material."

Jan 1, 2016

By Victor Rudenno

"Previous methods have employed statistical analysis to model future mineral resources. The method presented in this paper uses Zipj's Law to determine the size and grade of tin deposits still to be discovered. The law is applied independently to both known deposit tonnage and grades. A probability distribution for both 'tonnage and grade is computed/or those deposits still to be located and then, by applying a correlation between tonnage and grade, a distribution of the probability of metal content discovery is obtained.By considering an economic cut-off in metal contained in a deposit, the probability of economic success for the next tin discovery is computed, both for a world discovery and for the special case of Tasmania, Australia. The results indicate a probability of 11-37% on a world-wide basis and 18% chance of economic success in Tasmania.IntroductionIn the past , most attempts to determine the probability of success in finding an economic mineral deposit have relied on the accumulation of statistical data. These data are then used to predict a suitable frequency distribution to assess the probability of finding a deposit of a given size and grade (Singer,1975).The method not only relies on one having sufficient data, but also on the assumption that the data are not biased and that the distribution (usually log-normal) is a correct one. The method presented in this paper, to analyze tin deposits, uses Zipf's Law, which has been recently applied to oil, uranium, lead-zinc and gold deposits by Folinsbee (1977) and to Western Australian gold deposits by Rowlands and Sampey (1977). Tapp and Koniuszko (1978) have applied Zipf's Law to mineral distribution patterns in the Northern Australian orogenic provinces, which has enabled them to make predictions with a relatively small data source."

Jan 1, 1981

By W. F. J. Cosser

AN agreement having been arrived at in 1935 whereby McIntyre Porcupine Mines would purchase gravel for back-filling purposes from Hollinger Consolidated Gold Mines, the aerial gear as described below was installed. As originally discussed, the plan called for installation of a loading bin at the junction to the Hollinger tram, so making the McIntyre tram an entirely separate unit. The experience of the Hollinger engineers, however, went to prove that the operation of a bin (remote from sources of heat) should be avoided if possible, owing to the severe winter conditions (35° to 40° F. below zero).

Jan 1, 1938

"Process specifications for classification system design f or closed circuit grinding are identified. A computer-assisted, mass balance procedure for estimation of material size distributions and required hydrocyclone separation performance is presented.GeneralClassification equipment application involves a large number of variables, but can be greatly simplified by consideration of the following two major steps:(A) Process analysis, in which the so lids and liquid material balances and solids size distributions in the three classifier streams are determined in order to establish the required classifier separation performance.(B) Equipment selection, in which the cyclone dimensions and feed conditions are selected to yield the de sired separation, and the number of units then determined by their capacity rating."

Jan 1, 1984

By D. Madsen, B. Salamondra, A. Moss, D. Etienne

"Raise mining at the Namew Lake Nickel Mine in Manitoba uses 3 m diameter bored raises driven at 45 to 50 degrees dip for stope access and drilling. These raises are developed within the orebody on 20 m centres to accommodate electric-hydraulic longhole jumbos and charging wagons. Critical elements of stope development include delineation of are contacts, control of deviation during raise development, optimal stope sequencing to permit a high extraction rate, drill anchorage installation, production drilling and blasting, and ground control. Procedures to deal with these elements are described, with emphasis on the geotechnical investigation for design of open stopes and pillars.Although mining with drilled raises does not have the flexibility to follow large variations in orebody dip, results to date indicate that it can be used successfully in the thicker ore zones. Thinner zones are currently mined using a modified Avoca method. Some flexibility to accommodate variations in orebody dip in thin are zones may be obtained by using alimack raise climbers to drive access raises, and carry longhole drills and charging equipment. Rock quality has been sufficiently good to maintain stable stope walls for full-height mining of primary stapes at 20 m strike length.IntroductionThe Namew nickel deposit is located 60 km south of Flin Flon, Manitoba. It is a moderately dipping (45 to 50 degrees) pipe-like ultramafic intrusion with a sulphide halo enrichment. The diluted recoverable ore reserves at January I, 1990 are 2.2 million tonnes grading 2.05% Ni and 0.7% Cu. The operation is a joint venture between Hudson Bay Mining and Smelting (60%) and Outokornpu Mines Ltd. of Toronto (40%). The mine is budgeted to produce 530 000 tonnes in 1990. The deposit was discovered in 1984 and mine development commenced in 1987.In the raise mining area, primary stopes will be filled with a high quality backfill consisting of cement and quarried limestone. Secondary stopes will be mined out between the primaries in the second pass of mining. The design extraction rate is 94% over all.The orebody above 120 level has an average mining width of 2.4 m, so is too narrow for raise mining. A modified form of Avoca stoping is used."

Jan 1, 1991

By R. Simard

"Conventional exploration strategies identify many mineral deposits as potentially interesting, although only a few of them turn out to be of economic importance. In the context of exploration for sulphide nickel deposits in the Canadian Shield, a decisional model, based on a statistical study of parameters relative to nickel deposits as well as to barren sulphide occurences, has been developed.Because such geophysical variables as gravimetry, aeromagnetism and topography could be related to the relative importance of nickel-bearing deposits, a statistical analysis of 13 such variables was carried out for 98 targets which were considered promising after conventional exploration. Among these 98 targets are36 sulphide nickel deposits in the Canadian Shield and 62 drill-tested non-economic occurrences. The results of this study led to the development of a linear logistic model that permits evaluation, for each of the targets, of the probability of finding a nickel deposit of potential commercial interest. This decisional model can thus complement conventional exploration strategies.RésuméLes stratégies conventionnelles d'exploration définissent un très grand nombre de cibles comportant un inténet minier potentiel dont seules quelques-unes correspondent à des gisements économiquement importants. Dans Ie cadre de l'exploration des dépôts nickélifères du Bouclier Canadien, nous avons défini un modelé de décision fonde sur l'étude statistique de divers paramètres relatifs tant aux gisements d'importance qu'aux cibles dites stériles.Ayant fait l'hypothèse que certaines variables géophysiques (gravimétrie, aéromagnétisme et topographie) peuvent suffire à fournir des indications sur l'importance relative d'un gisement nickélifère, nous avons entrepris l'analyse statistique de 13 variables évaluées sur un échantillon de 98 cibles considérées comme potentiellement intéressantes par les stratégies conventionnelles d'exploration. Ces 98 cibles se composent de 36 dépôt nickélifères d ‘importance recontrés sur tout Ie Bouclier Canadien et de 62 cibles stériles reconnues par forage. Nous avons défini à l'aide de ces données un modèle logistique linéaire. Ce dernier nous permet d'évaluer pour chacune des cibles les chances de trouver un gisement. Ce modèle de décision peut done s'inscrire comme outil complémentaire aux stratégies conventionnelles d ‘exploration."

Jan 1, 1980

By C. Chapman, P. Cowx

"INTRODUCTIONTetronics Research and Development Co. Limited has installed several plasma torches for steel heating in continuous caster tundishes. An extensive demonstration program on a 14 tonne tundish reported the following advantages of plasma heating.• close control of steel temperature to ± 5°C;• a reduction of the furnace tapping temperature of up to 20ºC, leading to savings in energy and refractories costs ;• improvement in steel quality, to produce a slab product with an equi-axed crystal structure and a reduced number of large sub-surface slag inclusions;• the virtual elimination of oxygen pickup in the tundish; and• the capability of making ferroalloy trim additions to the tundish to permit a change of steel grade during casting, greatly decreasing inventory costs.The Need for Tundish HeatingIn the continuous casting of steel, the function of the tundish is to transfer the molten metal between the ladle to one or more continuously fed casting moulds. Figure I shows a typical temperature profile of molten steel in the tundish over the first cast cycle. It is observed that a rapid drop in temperature occurs both at the start of the cast, due to the tundish refractories absorbing heat, and also during ladle changeover. In addition, as a result of thermal losses through the ladle sidewalls, there is a gradual decline in the bulk steel temperature over the entire heat cycle. Consequently, in normal tundish operation, it is necessary to cast with a high superheat (25°C to 30°C + above steel liquidus temperature) in order to prevent freeze-up of the strand. Problems of high temperature variation and the potential of the steel solidifying in the tundish are greater for small caster units of low thermal mass . A high steel superheat increases the steelmaking vessel process time and refractory wear and prevents the formation of a uniform equi-axed solidification structure in the cast steel, resulting in centre line segregation and porosity. The large drop in the casting temperature that occurs during unsteady state operation causes an increase in the number of sub-surface inclusions, reducing the value of the product. Accordingly, plasma heating may be employed to maintain the molten steel at an optimum temperature to produce a slab of consistent quality."

Jan 1, 1989

By Robin Perry, Claude Bazin

"Discrete transfer functions which use the grinding circuit feed tonnage to predict mass flowrates at reagent addition points in a flotation circuit were calibrated using a dynamic grinding/flotation circuit simulator. Predicted mass flow values are multiplied by reagent addition ratios to obtain actual reagent flow. The transfer functions are currently integrated into the distributed control system of Les Mines Selbaie.IntroductionThe development of adequate tools for the control of flotation processes is a continuous challenge. Since the early 1970s there have been numerous publications dealing with practical aspect of control of flotation processes. Most plants use a combination of feedback and feedforward controls to reduce the effect of the following flotation process disturbances (McKee, 1991):• changes in throughput;• changes in feed grade;• changes in particle floatability (size, liberation, surface oxidation ... ); and • deliberate changes of setpoint;Feedforward control manipulates variables such as reagent and/or air flow rate to attenuate the effect of disturbances such as changes of feed rate and mineral content. The feed forward strategy is driven by measurements of these disturbances. Feedback control is used to maintain process variables to targeted set-points of concentrate or tails grades. The feedback control action is driven by deviation from the set-point, caused by a deliberate change of set-point or disturbances.This paper proposes a method to improve feed forward control schemes by the addition of a simple model for solids transportation. The feedforward strategy considered in this paper is the ratio type, in which the manipulated variable is changed according to a predefmed ratio between this variable and the measured disturbance. A typical example is the ratio of the reagent addition to mass flow of ore.The paper reviews the state of the art in feed forward control strategy applied to flotation processes and describes the method used for predicting mass flow rates. The last section shows an application of the method in the Les Mines Selbaie flotation circuit."

Jan 1, 1994

By H. Ardehali, P. Lind

Many gold deposits also contain significant quantities of deleterious elements such as arsenic. Several biological pathways are possible for arsenic exposure; special care and caution must be used while undertaking metallurgical testwork on ores and concentrates that contain high levels of arsenic. Laboratory precautions pertaining to handling of airborne dust concentrations, necessary personal protective equipment, and effluent treatment are discussed.

Jan 1, 2014

By Eiichiro Mizushima

Catalyst systems comprising (Ph3P)AuCH3 and acid co-catalysts were found to be highly efficient for hydration of alkynes to give ketones. Methanol was the best choice of solvents. Introduction Hydration of carbon-carbon unsaturated bonds is one of the environmentally benign routes to the carbon-oxygen bond formation. Hydration of alkynes forming carbonyl compounds, an important variation in this category, is a well known reaction which has been extensively studied. The reaction by acid-catalysis is the most conventional method, while it is applicable only to electron rich acetylenes to obtain satisfactory yields (1,2). The hydration of simple alkynes usually requires another catalyst (co-catalyst), typically a mercury(II) salt (3), which is inconsistent with the guiding principle of Green Chemistry (4).

Oct 1, 2003

By N. A. McPherson, P. C. Stevens, A. J. Rigby

"There has been a consistent move in recent years to continuously cast small billets while utilizing ceramic stream protection between tundish and mould. The need to have ceramic stream protection has developed from a need to improve billet surface quality by submerged pouring. The need to protect the ladle to tundish stream in conjunction with tundish to mould protection is explained.The continuous casting of thin slabs is at the development state and will require a great deal of ceramic development to ensure the economic viability of the project. An insight is given to the main problems.IntroductionDuring the early development period o f the continuous casting of steel in the late 1940s and 1950s, much of the work was carried out on small cross section products. For example, the continuous casting of 50 mm square billets was carried out on a production scale in the United Kingdom at Barrow. Slab casting was initiated on a production basis on 100 mm thick stainless steel slabs at Atlas Steel, Weiland, Ontario. In the case of slab casting the thickness increased gradually until it was similar to Slabbing Mill feedstock , i.e. in the range 200 mm to 250 mm , although stainless steel continued to be lower at around 185 mm thick.For billets , a significant proportion of steel is now cast at around 100 mm square which creates specific difficulties when casting with a submerged pour - mould powder practice. The move back to smaller cross sections is further emphasized by the current interest in "" Near Net Shape Casting"" . If this move continues, then significant development will be required to create the refractories used between tundish and mould in the continuous casting process.Two specific areas which will receive attention are; (I) the casting of small cross section billet s; and (2) the casting of thin slab."

Jan 1, 1990