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By K. Kryst, K. Elkayar

The increasing need to process lower grade contaminated copper concentrates and simultaneously produce higher purity copper cathodes necessitates a more diligent control in the electrorefining process. Ion exchange processes can be a powerful tool in controlling electrolyte impurities to ensure trouble free operation within the tankhouse and to help maintain cathode purity. In addition, some impurities can be recovered as a value added product. The use of a short bed ion exchange process provides a unique opportunity for impurity management in copper refineries. Several metals are discussed in this paper, including Sb, Bi, As and Ni and their methods of control and recovery within the copper electrolyte circuit. INTRODUCTION To produce a high purity copper product by electro-refining a copper electrolyte, it is important to control the concentration of impurities such as arsenic (As), bismuth (Bi), antimony (Sb), and nickel (Ni). These impurities are introduced into the electrolyte from the copper anode and can affect the copper product and the production operation. The presence of As in the copper product results in a lower electric conductivity and reduced workability of the copper. High levels of Bi in the electrolyte will result in a copper cathode product containing Bi. High Sb concentration will cause undesired floating slimes. A variety of methods have been developed to control the level of these impurities in the copper electrolyte including precipitation, liquid extraction, and ion exchange. These impurities can be recovered and used. This paper discusses novel methods that utilize short bed ion exchange technology to control these impurities. Also, the use of ion exchange to recover acid from the liberator cells bleed for reuse in the tankhouse is reviewed. SHORT BED ION EXCHANGE Short bed ion exchange technology has been employed extensively in the metal finishing industries for over forty years. Unlike conventional ion exchange, short beds are fixed beds without freeboard space. The application of short bed technology results in significant benefits when compared to conventional ion exchange. The resin used in this technology has a significantly smaller diameter than conventional ion exchange resin. As a result of the smaller resin size, exchange kinetics improves dramatically. This facilitates operation at higher flow rates and the use of smaller beds with a small mass transfer zone length. Smaller beds are especially important for applications that use chelating resins due to the high cost of the resin.

Jan 1, 2019

By H. Aminian

Gold powders have many important industrial applications. In this paper the available processes for the preparation of gold nano and micron sized powders are described. The attention has been given to hydrometallurgy route and the recent works and achievements in controlling the powder morphology are highlighted.

Jan 1, 2011

By J P. Bolduc, P. E. Pelletier

Preceded by brief general considerations such as the development of the mining industry in. the Province of Quebec, the choice of plant location, the types of problems studied etc., the paper gives a complete description of this new research and treatment center for metallic, non-metallic and asbestos ores. Facilities for carrying out operations in the three sections of the plant -the sampling section, the ore treatment section and the asbestos section -are fully discussed as well as laboratory facilities for (a) the preliminary testing of ores prior to pilot plant treatment and (b) the grading and testing of asbestos fibre. AT THE beginning of the century, the annual value of the mineral production of the Province of Quebec stood at the $2,500,000 level. Twenty-five years later, it was just under $24,000,000. In 1950, half a century later, it was slightly in excess of $200,000,000. But in 1959, in the span of only nine years, it

Jan 1, 1962

By J. P. Morris, J. T. Novak, E. A. Sarver

"A variety of reagents are utilized in coal preparation, but aside from performing their desired function relatively little is known about the behavior of these reagents within the processing circuits. Where exactly do reagents go once dosed? In this paper, we present preliminary results of partitioning studies on frother (i.e., MIBC) and collector (i.e., diesel) chemicals commonly used in coal flotation, and examine implications for water management (e.g., in closed-loop systems). Additionally, we discuss the usefulness of such data in predicting environmental transport and fate of chemicals – which is currently a top priority for industry.INTRODUCTIONThe purpose of coal preparation is to upgrade mined coal into more valuable products. Since coal is primarily used as a fuel source for electricity generation, product specifications are typically contracted to minimize unwanted constituents that detract from the overall heat value (e.g., ash and moisture) or that add to environmental pollution or other problems like corrosion at a power plant (e.g., sulfur) (Pitt & Millward, 1979). Failure to meet specifications results in a financial penalty for the coal producer (Szwilski, 1986), and thus preparation processes have evolved to simultaneously optimize recovery of valuable “clean” coal with rejection of mineral matter and moisture. In addition to advancements in equipment and circuitry, development and application of various chemical reagents has dramatically improved the performance of coal preparation processes.Contemporary preparation plants typically include multiple circuits that can be categorized by the size of particles they process: coarse, intermediate, and fine/ultra-fine (Figure 1). Coarse and intermediate circuits generally rely on size classification and gravity separations (e.g., dense-media cyclones), and do not require significant chemical reagents. However, fine and ultra-fine circuits often use froth flotation to separate coal from impurities, which requires chemical additives (Table 1). The primary additives include collectors, which coat the surface of the coal particles to render them (more) hydrophobic and thus more likely to attach to air bubbles and float; and frothers, which aid in the formation and stability of the froth that will accumulate the floated coal particles. Modifiers are also commonly added to flotation circuits to regulate pH in instances where coal or impurity characteristics may change water chemistries (Laskowski, 2001). Following flotation, coagulants and flocculants are often utilized in solid-liquid separations (i.e., dewatering or clarification) for coal products, and for tailings slurries prior to their disposal in impoundments. Coagulants function via double-layer compression1 to bring colloidal particles together, while flocculants promote bridging between the grouped colloids – and the combined result is enhanced sedimentation (Wills, 2006). Defoaming or anti-foaming agents may also be required to avoid fouling of dewatering operations."

Jan 1, 2012

By J. L. Jambor, E. J. Reardon, E. C. Appleyard, J. A. Cherry

Since the 1957 initiation of deposition of mill tailings at the Heath Steele mine, New Brunswick, periodic detailed studies of the tailings geochemistry and mineralogy have been conducted, thereby providing a unique opportunity to examine the geochemical evolution of a sulfide rich mine>tailings impoundment. When deposited, the tailings contained about 85 wt% sulfide minerals, 1 wt% to 3 wt% carbonate minerals, and 12 wt% to 14 wt% alumino silicate minerals. Mineralogical examination of samples of the tailings from deep in the impoundment indicates that little oxidation occurred prior to tailings deposition. The mill process-water deposited with the tailings was neutral to slightly basic and contained low concentrations of Cu, Pb, Zn and As. Sampling of the tailings five years after deposition indicated that sulfide-oxidation reactions, occurring near the tailings surface, had decreased the tailings-water pH and increased the concentrations of Fe, S042-, Cu, Zn and Pb (up to 10 000 mglL, 25 000 mg/L, 2.5 mg/L, 200 mg/L, and 4.5 mg/L, respectively). In 1975, ten years after decommissioning, the tailings could be divided into three zones: an upper oxidation zone in which sulfide oxidation is actively occurring, a hardpan layer, 15 cm to 20 cm thick, composed of tailings cemented by secondary Fe minerals, and an underlying reduction zone in which the tailings are relatively tin oxidized (Boorman and Watson, 1976). Chemical analyses indicated the presence of low-pH waters containing very high concentrations of SOi-, Fe, and other metals (up to 63 600 mg/L SO42-, 28 600 mg/L Fe, 10 mg/L Pb, 600 mg/L Cu and 4000 mg/L Zn), suggesting that there was a period of intense sulfide oxidation between five and ten years after tailings deposition. More recent sampling, conducted some 20 years after the end of tailings deposition, indicates that relatively little change has occurred in the last ten years, thereby suggesting that the hardpan layer has provided an impediment to the downward movement of dissolved constituents. Analyses of the tailings solids show increased accumulations of many metals at or near the depth of the hardpan layer. Evaluations of the long-term evolution of the tailings can be enhanced by comparison of descriptions of the tailings with descriptions of the gossan that overlay the massivesulfide orebody prior to mining. At Heath Steele, this comparison suggests that many of the mechanisms controlling the distribution of metals in the tailings will probably persist over geologic time.

Jan 1, 1992

By Ramin ArameshAsl

Urumieh-Dokhtar is the well-known vast metallogenic belt extended from NW to SE of Iran and basically is referenced in copper mineralization studies in Iran. Hashtjin 1:100000 sheet (NW Iran) is located on this belt and rock units are consisted of Oligocene intrusive, volcanic rocks and Eocene Sedimentary rocks. Concerning the significance of identifying the alterations and faults zones in copper exploration, the aim of this study is identifying the copper mineralization by multi-spectral analysis of ASTER (Advanced Space borne, Thermal Emission and Reflection Radiometer) satellite images in the limitation SD-SWIR (Spectral Domain of Short Wave Infrared). Several analytical methods are implemented in this study such as SAM (Spectral Angle Mapper), MF (Matched Filtering) and PCA (Principal Components Analysis). These methods have been utilized for recognizing the Argillic, Propylitic and Sericitic alteration zones and all of them are relying on the remote sensing methods as well as geological studies of new targets for copper mineralization identification in the area.

Aug 1, 2013

By D. Auerswald, M. Kotze, V. Yahorava, T. Udayar

Uranium can be recovered from lower grade uranium ores (<800 mg/kg U3O8), leach residues, and waste dumps cost-effectively via resin-in-pulp (RIP). Using this technology, no solid/liquid separation or washing of the leach residues are required. Furthermore, the uranium recovery can be higher than with conventional methods. RIP technologies have, however, been perceived negatively due to concerns around potential resin fouling and losses. This paper highlights the advancements made in RIP and discusses a number of potential applications where the technology could deliver economic and consequential environmental benefits by reducing the uranium levels in the waste.

Jan 1, 2014

By M. Mirnezami, J. A. Finch, M. S. Hashemi A.

The surface of -30µm silica suspension (2% v/v) treated with 100 ppm Mg2+ at pH 11 was fully coated with Mg(OH)2. Under this condition, the silica is strongly positively charged (+30 mV) and the suspension is dispersed. Subsequent addition of Ca2+ promoted aggregation and reduced the surface charge. At this pH calcium is present as Ca2+ and CaOH+, i.e., positively charged ions interacted with the positive surface. Aggregation by a chemical bridging mechanism is proposed. The observation may be relevant to the widespread practice in mineral processing of adding lime to promote aggregation and settling in concentrate thickeners.

Jan 1, 2004

By Ming’an Wei, Qifu Duan, Jianmin Wu, Lusheng Zhou, HMR Group Limited / HMR Technology Canada Ltd., Wenjian Wu

"The development and industrial applications of magnetic liners have been around for decades. A Swedish company Skega first introduced rubber magnetic liners, and then followed by the Chinese invention of metal magnetic liners. Traditionally, both liners were used in secondary ball mills and regrind ball mills for industrial applications, especially for ores containing magnetic materials. Mostly steel balls or equivalent forged steel balls, usually below 60 mm in diameter, were used as grinding media. With the development of mineral resources over the years, SAG mills and larger ball mills have become the dominating components for comminution circuit design. Due to the development of larger diameter ball mills and thus larger ball charge diameter (up to 80mm) especially in non-ferrous metal mining operations, the application of magnetic liners have been very limited. Based on “Magnetism theory” and the development of new materials, the HMR Group Limited has been conducting researches on examining the structures of magnetic liners, associated materials and magnetic circuits which led to the invention of the Nano Alloy Steel Magnetic Liner (NSML). Recently, NSML had a successful application in a 5.5 m diameter × 6.5 m ball mill at the Erdenet Copper Mine in Mongolia. The NSML successfully handled a ball size up of to 80 mm, while achieving a service life of nearly 24 months, which is almost 3 times wear life of the original manganese steel liners.INTRODUCTIONDuring the development and utilization of mineral resources, mineral processing is an indispensably operation. The effective separation of various useful minerals depends on sufficient monomer dissociation of minerals in the ores. The crushing and grinding operation is prior operation of mineral processing. Ball mills are used in different concentrators. As the main consumption parts of mill, liners have been studied constantly. As a new kind of liners, magnetic liners besides can meet the requirement of production, and also have characteristics with maintenance-free, saving energy and increasing efficiency. So the magnetic liners are worth to be spread and applied world widely."

Jan 1, 2016

By Unknown

Diesel locomotives for underground haulage have been used in coal mines in Continental Europe for twenty-five years or more. In Great Britain, it was not until 1935 that permission was granted to use them in gassy coal mines, but since that time they have been employed in increasing numbers both in gassy and non-gassy coal mines and in metal mines. Their use underground in coal mines in the United States is still prohibited and the same was the case in Canada until 1946, when permission was granted to operate a Diesel underground in the Adanac mine of West Canadian Collieries, Limited, at Bellevue, Alberta. The locomotive used here is a 50 h.p. Hunslet Mark II. More recently, a 100 h.p. Diesel was placed in operation for underground haulage at No. 18 Colliery of the Dominion Steel and Coal Corporation, in the Sydney coalfield, N. S. Thus, on this continent, Canada has been a pioneer in the use of these locomotives underground in coal mines and there is no doubt that more and more of them will be employed as time goes on. We feel, therefore, that the following notes concerning their design and performance, which we have received from the High Commissioner for the United Kingdom, will be of interest to our members.

Jan 1, 1949

By T. Xue

429 As part of Inco&apos;s S02 abatement project for its Sudbury operations, a weak acid treatment plant (W ATP) was commissioned at the Copper Cliff smelter in August of 2004 to treat the weak acid streams generated by the flash furnaces, the MK reactor and the fluidized bed roaster (FBR) gas cleaning plants. The W ATP process was developed by Inco Technical Services Limited (ITSL) by means of laboratory and mini-pilot plant programs. In the W ATP process, the feed solution containing arsenic, sulphur dioxide, iron and other impurities is treated by oxidation and neutralization to form a stable precipitate for disposal in Inco&apos;s tailings impoundment area. During the commissioning of the WATP, a team of operations, maintenance, engineering, project and R&D personnel was formed, and the designed capacity was achieved in less than a month. Since then, the W A TP has been operating smoothly and the impurities, specifically arsenic, in the Copper Cliff smelting process have been effectively removed.

Jan 1, 2006

By R. V. Tomkins

Introduction In the past fifteen years, bentonite production in the United States has increased very rapidly. From l50,000 tons in l934, it rose to 400,000 tons in l 942 and to a record 920,000 tons in 1948. Occurrences of bentonite ?in western Canada were described in the early part of the century by Ries and Keele (3), Ells (2), Spence (4). and other officer of the Dominion Department of Mines, and, in Saskatchewan, Professor W. G. Worcester (6), of the University of Saskatchewan has explored and carried out tests on deposits of the material at various times during the past thirty years. Nevertheless, Canadian developments have not kept pace with those in the United States. Exact figures for total Canadian production are not released, but it is probably under l0,000 tons annually. There are a great number of uses for bentonite, but in the United States three alone account for 90 per cent of the consumption. These are for drilling gel, foundry sand bond, and oil decolorizer. The tremendous oil exploration programme on the Canadian prairies has increased the possibility of an adequate domestic market for drilling gel. Therefore, in Saskatchewan, our efforts have been directed mainly to the production of a good drilling gel, with a minor part of the project devoted to activation of bentonites for oil decolorizing.

Jan 1, 1952

By D. R. Murray

A four-year study was carried out to determine the ability of coniferous trees to aid in the reclamation of uranium tailings at Elliot Lake. Five species were planted: white cedar, white spruce, jack pine, scotch pine and red pine. More than 570 bare-root, two-year-old seedlings were planted on bare tailings and in areas of established grasses. A further division was made between areas of coarse and fine tailings. Over-all survival and growth of the trees has been far below expectations based on previous experience with several varieties of grasses. The criteria for assessment have been per cent survival and yearly growth as determined by plant height. Pine was superior, with 68% survival when planted in bare coarse tailings, 45% for vegetated coarse tailings and 34% for vegetated fine tailings. Cedar had the worst survival rates at 49%, 14% and 7% respectively. No species survived on bare fine tailings. The survival and growth of the coniferous trees have been related to species, environmental conditions and tailings properties.

Jan 1, 1978

By S. Kashani-Nejad

The kinetics of the thermal decomposition of samples of Mg2(OH)3Cl.2H2O that were obtained by a novel leaching technique applied to a commercial magnesium electrolysis feed were investigated under ambient atmosphere. Thermogravimetric (TG) Analysis showed that decomposition of Mg2(OH)3Cl.2H2O exhibited a single intermediate stage wherein crystalline water was lost at roughly 108 °C. Conversion of the resulting Mg2(OH)3Cl to MgO, HCl and 1120 occurred at temperatures above 398 °C. Thermal decomposition of anhydrous Mg2(OH)3Cl was seen to be consist of two stages. Both stages exhibit first order kinetics with respect to the weight percent of Mg2(OH)3Cl remaining in the sample. However, the rates of decomposition in the two stages were significantly different. Detailed analysis of the kinetic data suggested that the rate of decomposition of Mg2(OH)3C1 was controlled by the rate of removal of the gases released. The change in decomposition rate during the course of the experiments was explained by HCI being released in stage 1 and followed by release of H2O in stage 2.

Jan 1, 2004

By L. K. Daneshmend

Key issues in managing information systems in the minerals industry will likely continue to be those relating to the integration and interoperability of disparate systems. This paper argues that, in order to harness the promised benefits of information technologies, the mining industry should adopt a set of open systems standards to define data formats and protocols for seamless data exchange. This is in direct contrast to the present situation where mining equipment, software and instrument suppliers rigidly adhere to proprietary standards for fear of losing competitive advantage. Benefits to the mining sector resulting from the adoption of such standards would be: the provision of near-time data for executive decision support, and the freedom to choose best technologies. The principal benefits to the leading mining software suppliers will be increased market share as a result of “captive sites” converting to open systems standards. Examples are given of open systems standards developed for related industries such as the Petroleum Open Systems Corporation (POSC) and the Machinery Information Management Open Systems Alliance (MIMOSA).

Jan 1, 2000

By C. J. Brown

Regeneration of hydrochloric acid steel pickle liquors has traditionally been accomplished by pyrohydrolysis. However, a number of factors have recently conspired to reduce the attractiveness of this approach. Moreover, the process is not amenable to small-scale operations. On the other hand, the standard technique for regeneration of sulfuric acid pickle liquors, which is the low-temperature crystallization of ferrous sulfate is applicable to any size operation. A similar technique has recently been developed to regenerate hydrochloric acid. Sulfuric acid is added to the ferrous chloride-bearing spent HCl pickle liquor. The temperature is then reduced to below 0°C, resulting in the crystallization of ferrous sulfate heptahydrate and liberation of free hydrochloric acid. Depending upon the crystallization temperature, variable concentrations of sulfate are left in the regenerated acid. Although this residual sulfate has an impact on the pickling characteristics of the regenerated acid, tests have shown that by adjusting the conditions, pickling rates will be at least equal to those using pure HCI, and an acceptable surface finish will be produced.

Jan 1, 2006

By L. H. Smith, D. S. Taylor

"AbstractSherritt has been applying hydraulic drives to concentrator equipment since 1967. The initial application was made on a bank of 5- by 5-in. slurry pumps. This has now been extended to all slurry pumps requiring less than 40 hp and several conveyors which require variable-speed or low-speed/high-torque characteristics. The pump motors are directly connected through a flexible coupling, whereas the conveyor systems are directly mounted onto the head-pulley shaft extension.The different applications and design concepts will be described, with outlines of the operating and maintenance advantages and disadvantages and costs. The paper also outlines future possible applications, together with the limiting conditions, of such systems.IntroductionSHERRITT GORDON MINES LIMITED has been operating a mining division in Northern Manitoba for almost 50 years. The original mining operation was at Sherridon, Manitoba and was a copper-zinc producer. This mine was exhausted in 1948 and the mining plant was moved north to its present location at Lynn Lake, Manitoba. The Lynn Lake Mine is a nickel-copper producer. Since 1960, two new mines have been discovered and brought into production in the general vicinity of Lynn Lake. The first of these was the Fox Mine, a copper-zinc property operating at 3,000 tons per day from an underground operation. This mine started production in May 1970."

Jan 1, 1977

By K. Soldenhoff, M. Fainerman-Melnikova

The use of strong base resins for uranium recovery is severely affected by the presence of chloride ions in solution. In areas where high-quality process water is not readily available, the use of saline water would extend the potential application for ion exchange in uranium processing. This study presents measurements of uranium uptake, using a wide range of commercially available weak base anionic exchangers, from solutions with chloride concentrations ranging from 2.5 to 22 g/L Cl. Out of 14 weak base anionic resins tested, 3 were identified that were not severely impacted by the presence of chloride and significantly outperformed a gel strong base resin typically used for uranium recovery in high-chloride environments. The uranium loading was sufficiently high for the consideration of development of the application of uranium recovery from uranium ores leached with seawater.

Jan 1, 2012

By John O. Galloway

"The year 1947 was a momentous one in the history of the petroleum industry in Canada. It was in that year that Imperial Oil Limited made its discovery at Leduc, the forerunner of other discoveries, large and small, and the spark wl1ich started a most intensive exploration and development programme there.If, to use boxing parlance, Leduc was the first blow of a one-two combination which left doubting Thomases groggy, then Redwater was the number two blow which achieved the knockout. The oil industry's exploration leaders did about-face without delay and the rush of oil operators of all classifications to western Canada began. It is still continuing, and the influx of capital which the operators have brought in and are bringing in has a bouyant effect upon the over-all economy. The boom is on, but it is a sound one, and it is difficult to conceive that it will have anything but the most beneficial effect on Canada, and particularly western Canada.The petroleum industry is an important segment of the general economy. Its activities call for tremendous amounts of capital; its employees are well paid; it is a large customer for a wide range of products of other industries; its commodities are essential to the citizens and the nation.The industry is carried on by highly aggressive and independent groups and individuals, of which a small minority are integrated while the majority are relatively small operators engaged in only one or two phases of the business. Competition is the rule and, since the nature of the business is mass production, the industry is faced from time to time with serious problems, many of which are peculiar to it."

Jan 1, 1950

By Neil Campbell

"The Pine Point area is on the south shore of Great Slave Lake, 510 air miles north of Edmonton and J JO miles south of Yellowknife, N.W.T. The occurrence there of lead and zinc was reported in J 899 by R. Bell (5) of the Geological Survey of Canada, and in the following years several claims were staked and some prospecting was done. In 1928 Atlas Exploration Co. took over the property containing the discovery occurrences. In 1929 The Consolidated Mining and Smelting Company of Canada Ltd. (""Cominco"") and Ventures Ltd. participated with Atlas in forming the Northern Lead-Zinc Co., which, under the direction of J. M. Bell, carried out 24,499 feet of drilling in the discovery and surrounding areas. Two shafts and many surface pits were also sunk. This work showed that the discovery deposits contain about 500,000 tons of lead-zinc ore, but no new orebody was found.In 1936 D. F. Kidd (11) drew attention to the highly significant space relations between the base-metal discoveries at Pine Point and the projections of certain major Precambrian faults mapped earlier by C. H. Stockwell. Geological work by Cominco in 1940 and subsequent years suggested the presence of mineable deposits within a belt of land including part of the area of earlier field work and extending far beyond it. Between 1946 and 1954 exploration financed by Cominco and Ventures Ltd. included 182,950 feet of diamond drilling, 383 feet of sinking, and 240 feet of drifting, raising, and crosscutting. This work was successful in finding substantial quantities of new ore in places where bedrock is completely concealed.The topography is one of low relief, characterized in many places by swampy muskeg and shallow, marl-bottomed ponds. The area where ore has been found is generally higher ground which, though not well drained, is comparatively dry. It is also marked by raised beaches and a few sand dunes overgrown by small spruce and pine. Bedrock is generally overlain by a variable thickness of hard, glacial boulder clay. This in turn is covered by silt, sand, and gravel, probably deposited from the waters of Great Slave Lake, which formerly extended many miles beyond its present southern shore."

Jan 1, 1949